Coupling device for degrading organic impurities in sodium aluminate solution through ultrasonic enhancement

By using ultrasonic enhanced degradation of organic impurities coupling device in sodium aluminate solution during the alumina production process, combined with the ultrasonic and jet joint system, the problem of difficulty in removing organic carbon in alumina production is solved, efficient organic degradation is achieved, and the quality of alumina products is improved.

CN222855416UActive Publication Date: 2025-05-13KUNMING UNIV OF SCI & TECH
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Patent Information

Application Number
CN202421679265.4
Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
Filing Date
2024-07-16
Publication Date
2025-05-13
Estimated Expiration
2034-07-16

AI Technical Summary

Technical Problem

During the existing alumina production process, it is difficult to effectively remove the organic carbon in the sodium aluminate solution, resulting in quality problems of alumina products, such as particle size refinement, sodium oxide content exceeding the standard, and aluminum hydroxide coloring, etc.

Method used

The coupling device for the organic impurity degradation in sodium aluminate solution is adopted to enhance the contact area and reaction efficiency of the oxidant and organic matter by coupling the combined ultrasonic and jet system, and achieve efficient degradation of organic matter.

Benefits of technology

It significantly improves the degradation rate of organic matter, solves problems such as low mass transfer efficiency, short contact time, and low oxidation efficiency, and has the advantages of high mass transfer efficiency, long contact time, simple operation, and easy industrialization.

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Abstract

The utility model relates to an ultrasonic enhanced coupling device for degrading organic impurities in a sodium aluminate solution. The device comprises an ultrasonic device and a jet device, the ultrasonic device comprises an ultrasonic generator and an ultrasonic reaction chamber, and the ultrasonic generator is fixedly arranged at the bottom end of the ultrasonic reaction chamber; a vertical through hole is formed in the center of the top end of the ultrasonic reaction chamber, a raw material liquid inlet is formed in the top of the side A of the ultrasonic reaction chamber, and a sodium aluminate solution outlet is formed in the top of the side B of the ultrasonic reaction chamber; a gas outlet is formed in the top end of the ultrasonic reaction chamber, an impurity liquid outlet is formed in the bottom of the ultrasonic reaction chamber, and a temperature sensor is arranged in the ultrasonic reaction chamber; the jet device comprises a jet device motor, a centrifugal pump and a jet pipeline which are connected in sequence; the jet pipeline penetrates through a vertical through hole in the center of the top end of the ultrasonic reaction chamber and is vertically downwards inserted into the ultrasonic reaction chamber. The device solves the technical problems of a traditional chemical oxidation method through a coupling ultrasonic and jet flow combined system.
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Description

Technical Field

[0001] The utility model relates to a device for producing aluminum oxide, in particular to a coupling device for ultrasonically enhancing the degradation of organic impurities in a sodium aluminate solution. Background Art

[0002] In the production of alumina, the organic carbon in the sodium aluminate solution mainly comes from the ore, and a small amount comes from various organic additives added during the production process. The organic matter content in imported bauxite is high and the composition is complex. When the imported bauxite is dissolved, 70-80% of the organic carbon will be converted into low molecular weight compounds such as oxalate and acetate, as well as high molecular weight humate, which seriously threatens the Bayer process of producing alumina; increases the difficulty of key operating processes such as dissolution, sedimentation, decomposition and evaporation; causes a significant increase in power consumption and alkali consumption; significantly reduces the seed decomposition rate; and causes product quality problems such as fine particle size of alumina products, excessive sodium oxide content and color of aluminum hydroxide.

[0003] Alumina manufacturers that use bauxite with high organic carbon content as raw materials have conducted a lot of research on this. The main methods include: calcination, oxidation, adsorption, ion exchange, crystallization, etc. Among the many methods, chemical oxidation is the most promising method for removing organic matter in the alumina production process because of its advantages such as simple process, clean and environmental protection, and easy industrialization. However, at present, various oxidants have problems such as low mass transfer efficiency, short contact time, and low oxidation efficiency in the process of oxidizing organic impurities. Therefore, the development of efficient and low-cost comprehensive organic impurity removal technology has scientific value and practical significance for the rational use of foreign ores and the improvement of the competitiveness of domestic alumina production. Utility Model Content

[0004] The utility model aims at the problems of low mass transfer efficiency, short contact time and low oxidation efficiency in the process of oxidizing organic impurities in the current chemical oxidation method, and proposes an ultrasonic enhanced degradation coupling device for organic impurities in sodium aluminate solution. The device effectively enhances the degradation of organic impurities in the sodium aluminate solution by coupling ultrasound and a jet joint system, and has the advantages of high mass transfer efficiency, long contact time, simple operation, and easy industrialization.

[0005] The technical solution adopted by the utility model to solve its technical problems is:

[0006] A coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution comprises an ultrasonic device and a jet device, wherein the ultrasonic device comprises an ultrasonic generator and an ultrasonic reaction chamber 13, wherein the ultrasonic generator is fixedly arranged at the bottom of the ultrasonic reaction chamber 13; a vertical through hole is provided at the center of the top of the ultrasonic reaction chamber 13, and two opposite sides of the ultrasonic reaction chamber 13 are respectively an A side and a B side, a raw material liquid inlet 21 is provided at the top of the A side of the ultrasonic reaction chamber 13, and a sodium aluminate solution outlet 16 is provided at the top of the B side of the ultrasonic reaction chamber 13, and the raw material liquid inlet 21 is located above the sodium aluminate solution outlet 16; a gas outlet 19 is provided at the top of the ultrasonic reaction chamber 13, and the gas outlet 19 is close to the A side of the ultrasonic reaction chamber 13; an impurity liquid outflow outlet 17 is provided at the bottom of the ultrasonic reaction chamber 13, and a temperature sensor is provided in the ultrasonic reaction chamber 13;

[0007] The jet device comprises a jet device motor 2 , a centrifugal pump 3 and a jet pipeline which are connected in sequence. The jet pipeline passes through a vertical through hole at the top center of the ultrasonic reaction chamber 13 and is vertically inserted downward into the ultrasonic reaction chamber 13 .

[0008] The jet pipeline includes a jet liquid / gas inlet pipe 1, a jet vacuum pump 4 and a jet tail pipe 5 which are connected in sequence. The jet liquid / gas inlet pipe 1 is externally connected to a liquid / gas storage tank. The jet tail pipe 5 passes through the vertical through hole at the top center of the ultrasonic reaction chamber 13 and is vertically inserted downward to the bottom of the ultrasonic reaction chamber 13. The inner diameter of the jet tail pipe 5 is much smaller than the inner diameter of the jet liquid / gas inlet pipe 1.

[0009] Preferably, the inner diameter of the jet tail pipe 5 is 1 / 5 to 1 / 15 of the inner diameter of the jet liquid / gas inlet pipe 1 .

[0010] Preferably, the impurity liquid outflow outlet 17 is provided with an electromagnetic valve 20 .

[0011] Preferably, the impurity liquid outflow outlet 17 is externally connected to the filtering device 15 , and a filtrate outlet 18 is provided at the bottom of the filtering device 15 .

[0012] Preferably, a plurality of filter plates 14 are arranged in the filter device 15 along the liquid flow direction.

[0013] The ultrasonic generator includes an ultrasonic cavity 8, a transducer 9 and an ultrasonic probe 6. A thermal insulation layer 10 is arranged at the bottom end of an ultrasonic reaction chamber 13. The ultrasonic cavity 8 is arranged at the lower end of the thermal insulation layer 10. The ultrasonic probe 6 is fixedly arranged in the ultrasonic cavity 8. The ultrasonic probe 6 passes through the thermal insulation layer 10 upward. A horn 7 is arranged at the bottom end of the ultrasonic cavity 8. The transducer 9 is fixedly arranged at the bottom end of the horn 7. A plurality of magnetrons 12 connected in series are evenly arranged on the side wall of the ultrasonic cavity 8. An exhaust port 11 is opened on the side wall of the ultrasonic cavity 8. The exhaust port 11 passes through the gap between adjacent magnetrons 12.

[0014] The ultrasonic enhanced degradation coupling device for organic impurities in sodium aluminate solution also includes a control panel 22 , and the ultrasonic generator, the temperature sensor and the ultrasonic reaction chamber 13 are all connected to the control panel 22 by signals.

[0015] Preferably, the control panel 22 is provided with a temperature display instrument 23, an ultrasonic system control button and a jet system control button, the ultrasonic system control button is connected to the ultrasonic device, and the jet system control button is connected to the jet device.

[0016] More preferably, the ultrasound system control buttons include an ultrasound power button 26, a power display meter 24, a power adjustment knob 28 and an ultrasound operation warning light 27; the jet system control buttons include a flow display meter 25, a power button 30, a jet operation warning light 29, and a jet speed adjustment button 31.

[0017] In the ultrasonic treatment process, the total ultrasonic power is 1-100kW and is continuously adjustable, and the working temperature of the ultrasonic device is controlled at 25-100°C; in the jet treatment process, the jet air volume of the ejector is 21000~27000m 3 / h, working temperature is 25-100℃.

[0018] Ultrasound is an elastic mechanical wave with a frequency higher than 20kHz. It can cause a series of physical and chemical changes in the solution based on the cavitation effect. During the implosion and annihilation of cavitation bubbles, local high temperatures of more than 5000K can be generated, about 5×10 7 Pa local high pressure, strong shock waves and microjets with speeds up to 400 km / h, and instantaneous temperature gradients up to 10 9 K / s, and at the same time caused turbulence effect, perturbation effect, interface effect, and energy gathering effect; the utility model utilizes ultrasound to strengthen the mass transfer process of the oxidant, increases the contact area between the oxidant and the organic matter, and realizes rapid and efficient degradation of the organic matter.

[0019] When the oxidant liquid flows into the jet tube at a certain flow rate, it is subjected to high-speed impact, cavitation, strong shear crushing, high-frequency oscillation, puffing and vortex effects, and is crushed into extremely small droplets, thereby increasing the contact area between the oxidant and the organic matter; in addition, the oxidant liquid flow flowing out of the jet system has strong hydraulic shear force, tension and shear stress, which can also destroy the carbon bonds on the main chain of macromolecular organic matter, thereby achieving efficient degradation of organic matter in the sodium aluminate solution.

[0020] In summary, by coupling the ultrasound and jet combined system, a uniform and efficient acoustic cavitation process can be achieved by regulating the sound field and bubble field. At the same time, the introduction of ultrasound can also solve problems such as weak convective mixing and low concentration of active free radicals produced by oxidant decomposition. The ultrasound and jet combined system has a significant synergistic effect, and the two enhanced technologies are integrated with each other to form a more efficient, more stable and more industrially promising organic matter degradation device in sodium aluminate solution.

[0021] Beneficial effects of the utility model:

[0022] (1) The utility model solves the technical difficulties of the traditional chemical oxidation method by coupling the ultrasound and jet combined system, and can effectively enhance the degradation of organic impurities in the sodium aluminate solution. It has the advantages of high mass transfer efficiency, long contact time, simple operation, and easy industrialization.

[0023] (2) In the utility model, the ultrasonic device solves the problems of weak convection mixing and low concentration of active free radicals generated by oxidant decomposition through processes such as high-temperature pyrolysis, free radical oxidation, supercritical water oxidation and sonic mechanical effect, and enhances the attack frequency of active free radicals, thereby significantly improving the degradation rate of organic matter in sodium aluminate solution;

[0024] (3) In the utility model, since the aperture at the outlet of the jet device becomes narrower, a high-speed micro jet can be formed at the end. This process can form two low-pressure areas before and after: one is the tangential area when the jet is formed; the other is the vortex area formed when the jet enters a relatively static fluid. This low-pressure area can cause the oxidant liquid flow to be subjected to strong physical and chemical effects and transformed into extremely small micro droplets, significantly increasing the reaction rate of the oxidant and organic matter. BRIEF DESCRIPTION OF THE DRAWINGS

[0025] Figure 1 This is a schematic diagram of the structure of the coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution;

[0026] In the figure, 1-jet liquid / gas inlet pipe, 2-jet device motor, 3-centrifugal pump, 4-jet vacuum pump, 5-jet tail pipe, 6-ultrasonic probe, 7-amplifier, 8-ultrasonic cavity, 9-transducer, 10-insulation layer, 11-exhaust port, 12-magnetron, 13-ultrasonic reaction chamber, 14-filter plate, 15-filter device, 16-sodium aluminate solution outlet, 17-impurity liquid flow outlet, 18-filtrate outlet, 19-gas outlet, 20-electromagnetic valve, 21-raw liquid inlet, 22-control panel, 23-temperature display instrument, 24-power display instrument, 25-flow display instrument, 26-ultrasonic power button, 27-ultrasonic operation warning light, 28-power adjustment knob, 29-jet operation warning light, 30-power button, 31-jet speed adjustment button. DETAILED DESCRIPTION

[0027] The utility model is further described below in conjunction with specific implementation methods.

[0028] Example 1: Figure 1 As shown, a coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution comprises an ultrasonic device and a jet device, wherein the ultrasonic device comprises an ultrasonic generator and an ultrasonic reaction chamber 13, wherein the ultrasonic generator is fixedly arranged at the bottom end of the ultrasonic reaction chamber 13; a vertical through hole is provided at the center of the top end of the ultrasonic reaction chamber 13, and two opposite sides of the ultrasonic reaction chamber 13 are respectively the A side and the B side, a raw material liquid inlet 21 is provided at the top of the A side of the ultrasonic reaction chamber 13, and a sodium aluminate solution outlet 16 is provided at the top of the B side of the ultrasonic reaction chamber 13, and the raw material liquid inlet 21 is located above the sodium aluminate solution outlet 16; a gas outlet 19 is provided at the top end of the ultrasonic reaction chamber 13, and the gas outlet 19 is close to the A side of the ultrasonic reaction chamber 13; an impurity liquid outflow outlet 17 is provided at the bottom of the ultrasonic reaction chamber 13, and a temperature sensor is arranged in the ultrasonic reaction chamber 13;

[0029] The jet device includes a jet device motor 2, a centrifugal pump 3 and a jet pipeline connected in sequence, and the jet pipeline passes through the vertical through hole at the top center of the ultrasonic reaction chamber 13 and is vertically inserted downward in the ultrasonic reaction chamber 13;

[0030] The raw material liquid is added into the ultrasonic reaction chamber 13 through the raw material liquid inlet 21, the jet device motor 2, the centrifugal pump 3 and the jet pipeline of the jet device are turned on, the ultrasonic generator of the ultrasonic device is turned on, and the liquid or gaseous oxidant is introduced into the ultrasonic reaction chamber 13 through the jet pipeline. The ultrasonic power and the jet velocity of the ultrasonic device are adjusted to couple the ultrasonic power with the rate of the jet oxidant. The raw material liquid (organic impurities in the sodium aluminate solution) undergoes ultrasonic oxidation reaction under the oxidation conditions of the oxidant, and the reaction temperature is monitored in real time by a temperature sensor. The generated gas escapes from the gas outlet 19. When the sodium aluminate solution containing organic impurities completes the reaction in the ultrasonic reaction chamber 13, the sodium aluminate solution after impurity purification flows out from the sodium aluminate solution outlet 16, and the remaining liquid and precipitated crystals flow out through the impurity liquid outlet 17.

[0031] Example 2: The coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution in this example is basically the same as the coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution in Example 1, except that:

[0032] The jet pipeline includes a jet liquid / gas inlet pipe 1, a jet vacuum pump 4 and a jet tail pipe 5 which are connected in sequence. The jet liquid / gas inlet pipe 1 is externally connected to a liquid / gas storage tank. The jet tail pipe 5 passes through the vertical through hole at the top center of the ultrasonic reaction chamber 13 and is vertically inserted downward to the bottom of the ultrasonic reaction chamber 13. The inner diameter of the jet tail pipe 5 is much smaller than the inner diameter of the jet liquid / gas inlet pipe 1.

[0033] Preferably, the inner diameter of the jet tail pipe 5 is 1 / 5 to 1 / 15 of the inner diameter of the jet liquid / gas inlet pipe 1;

[0034] The liquid / gas oxidant in the liquid / gas storage tank is sprayed into the raw material liquid (sodium aluminate solution) in the ultrasonic reaction chamber 13 through the jet liquid / gas pipe 1 and the jet tail pipe 5 to form a jet under the conditions of the jet device motor 2, the centrifugal pump 3 and the jet vacuum pump 4; when the oxidant liquid flow flows into the jet tube at a certain flow rate, it is subjected to high-speed impact, cavitation, strong shear crushing, high-frequency oscillation, puffing and vortex action, etc., and is crushed into extremely small droplets, thereby increasing the contact area between the oxidant and the organic matter; in addition, the oxidant liquid flow flowing out of the jet system has a strong hydraulic shear force, tension, and shear stress, which can also destroy the carbon bonds on the main chain of the macromolecular organic matter, thereby achieving efficient degradation of the organic matter in the sodium aluminate solution.

[0035] Example 3: The coupling device for ultrasonically enhancing degradation of organic impurities in sodium aluminate solution in this example is basically the same as the coupling device for ultrasonically enhancing degradation of organic impurities in sodium aluminate solution in Example 2, except that:

[0036] The impurity liquid outflow outlet 17 is provided with an electromagnetic valve 20; the impurity liquid outflow outlet 17 is externally connected to a filter device 15, and a filtrate outlet 18 is provided at the bottom of the filter device 15; a plurality of filter plates 14 are provided inside the filter device 15 along the liquid flow direction;

[0037] When the sodium aluminate solution containing organic impurities completes the reaction in the ultrasonic reaction chamber 13, the electromagnetic valve 20 is opened, and the remaining liquid and precipitated crystals flow out through the impurity liquid outflow outlet 17, enter the filter device 15, and are filtered through several layers of filter plates 14. The solids are retained by the filter plates 14 to achieve solid-liquid separation, and the filtrate is discharged through the filtrate outlet 18.

[0038] Example 4: The coupling device for ultrasonically enhancing degradation of organic impurities in sodium aluminate solution in this example is basically the same as the coupling device for ultrasonically enhancing degradation of organic impurities in sodium aluminate solution in Example 3, except that:

[0039] The ultrasonic generator comprises an ultrasonic cavity 8, a transducer 9 and an ultrasonic probe 6. A thermal insulation layer 10 is arranged at the bottom end of an ultrasonic reaction chamber 13. The ultrasonic cavity 8 is arranged at the lower end of the thermal insulation layer 10. The ultrasonic probe 6 is fixedly arranged in the ultrasonic cavity 8. The ultrasonic probe 6 passes through the thermal insulation layer 10 upward. A horn 7 is arranged at the bottom end of the ultrasonic cavity 8. The transducer 9 is fixedly arranged at the bottom end of the horn 7. A plurality of magnetrons 12 connected in series are evenly arranged on the side wall of the ultrasonic cavity 8. An exhaust port 11 is opened on the side wall of the ultrasonic cavity 8. The exhaust port 11 passes through the gap between adjacent magnetrons 12.

[0040] First, the transducer contains piezoelectric crystals or piezoelectric ceramic materials. When an external alternating voltage (high-frequency electrical signal) acts on these materials, they will generate mechanical vibrations, namely ultrasonic waves, due to the piezoelectric effect. These mechanical vibrations propagate outward through the surface of the transducer. Subsequently, the ultrasonic probe can amplify the particle displacement or velocity of the mechanical vibration, thereby amplifying the amplitude by multiples and reducing the resonant impedance, and finally introducing high-frequency ultrasonic waves into the ultrasonic reaction chamber.

[0041] Example 5: The coupling device for ultrasonically enhancing degradation of organic impurities in sodium aluminate solution in this example is basically the same as the coupling device for ultrasonically enhancing degradation of organic impurities in sodium aluminate solution in Example 4, except that:

[0042] The ultrasonic enhanced degradation coupling device for organic impurities in sodium aluminate solution also includes a control panel 22, and the ultrasonic generator, the temperature sensor and the ultrasonic reaction chamber 13 are all connected to the control panel 22 by signal;

[0043] The control panel 22 is provided with a temperature display instrument 23, an ultrasonic system control button and a jet system control button, wherein the ultrasonic system control button is connected to the ultrasonic device, and the jet system control button is connected to the jet device;

[0044] The control buttons of the ultrasound system include an ultrasound power button 26, a power display meter 24, a power adjustment knob 28, and an ultrasound operation warning light 27; the control buttons of the jet system include a flow display meter 25, a power button 30, a jet operation warning light 29, and a jet speed adjustment button 31;

[0045] The ultrasonic power button 26 can control the working time of the ultrasonic device, the power adjustment knob 28 can control the ultrasonic working power, the power display meter 24 can display the ultrasonic working power online in real time, and the ultrasonic operation warning light 27 can monitor the operation of the ultrasonic device online in real time, and cut off the circuit in an emergency when the device fails. The power button 30 can control the working time of the jet device, the jet speed adjustment button 31 can control the jet speed, the flow display meter 25 can display the jet speed online in real time, and the jet operation warning light 29 can monitor the operation of the jet device online in real time, and cut off the circuit in an emergency when the device fails.

[0046] In the ultrasonic treatment process, the total ultrasonic power is 1-100kW and is continuously adjustable, the working temperature of the ultrasonic device is controlled at 25-100°C, the reaction temperature is monitored in real time by a temperature sensor, and displayed by a temperature display instrument 23; in the jet treatment process, the jet air volume of the ejector is 21000~27000m 3 / h, working temperature is 25-100℃.

[0047] The specific embodiments of the present invention are described in detail above in conjunction with the accompanying drawings, but the present invention is not limited to the above embodiments, and various changes can be made within the knowledge scope of ordinary technicians in this field without departing from the purpose of the present invention.

Claims

1. A coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution, characterized in that: The ultrasonic device comprises an ultrasonic generator and an ultrasonic reaction chamber (13), wherein the ultrasonic generator is fixedly arranged at the bottom end of the ultrasonic reaction chamber (13); a vertical through hole is provided at the center of the top end of the ultrasonic reaction chamber (13); two opposite side surfaces of the ultrasonic reaction chamber (13) are respectively an A side surface and a B side surface; a raw material liquid inlet (21) is provided at the top end of the A side surface of the ultrasonic reaction chamber (13); a sodium aluminate solution outlet (16) is provided at the top end of the B side surface of the ultrasonic reaction chamber (13); the raw material liquid inlet (21) is located above the sodium aluminate solution outlet (16); a gas outlet (19) is provided at the top end of the ultrasonic reaction chamber (13), and the gas outlet (19) is close to the A side surface of the ultrasonic reaction chamber (13); an impurity liquid outlet (17) is provided at the bottom end of the ultrasonic reaction chamber (13); and a temperature sensor is provided in the ultrasonic reaction chamber (13); The jet device comprises a jet device motor (2), a centrifugal pump (3) and a jet pipeline which are connected in sequence. The jet pipeline passes through a vertical through hole at the top center of the ultrasonic reaction chamber (13) and is inserted vertically downward into the ultrasonic reaction chamber (13).

2. The coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution according to claim 1, characterized in that: The jet pipeline comprises a jet liquid / gas inlet pipe (1), a jet vacuum pump (4) and a jet tail pipe (5) which are connected in sequence. The jet liquid / gas inlet pipe (1) is externally connected to a liquid / gas storage tank. The jet tail pipe (5) passes through a vertical through hole at the center of the top of the ultrasonic reaction chamber (13) and is inserted vertically downward to the bottom of the ultrasonic reaction chamber (13).

3. The coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution according to claim 1, characterized in that: The impurity liquid outflow outlet (17) is provided with an electromagnetic valve (20).

4. The coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution according to claim 3 is characterized by: The impurity liquid outflow outlet (17) is externally connected to the filtering device (15), and a filtrate outlet (18) is provided at the bottom of the filtering device (15).

5. The coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution according to claim 4 is characterized in that: A plurality of filter plates (14) are arranged in the filter device (15) along the liquid flow direction.

6. The coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution according to claim 1, characterized in that: The ultrasonic generator comprises an ultrasonic cavity (8), a transducer (9) and an ultrasonic probe (6); a thermal insulation layer (10) is arranged at the bottom end of an ultrasonic reaction chamber (13); the ultrasonic cavity (8) is arranged at the lower end of the thermal insulation layer (10); the ultrasonic probe (6) is fixedly arranged in the ultrasonic cavity (8); the ultrasonic probe (6) passes through the thermal insulation layer (10) upward; a horn (7) is arranged at the bottom end of the ultrasonic cavity (8); the transducer (9) is fixedly arranged at the bottom end of the horn (7); a plurality of magnetrons (12) connected in series are evenly arranged on the side wall of the ultrasonic cavity (8); an exhaust port (11) is opened on the side wall of the ultrasonic cavity (8); and the exhaust port (11) passes through the gap between adjacent magnetrons (12).

7. The coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution according to claim 1, characterized in that: It also includes a control panel (22), and the ultrasonic generator, the temperature sensor and the ultrasonic reaction chamber (13) are all connected to the control panel (22) by signals.

8. The coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution according to claim 7, characterized in that: The control panel (22) is provided with a temperature display instrument (23), an ultrasonic system control button, and a jet system control button. The ultrasonic system control button is connected to the ultrasonic device, and the jet system control button is connected to the jet device.

9. The coupling device for ultrasonic enhanced degradation of organic impurities in sodium aluminate solution according to claim 8, characterized in that: The control buttons of the ultrasound system include an ultrasound power button (26), a power display meter (24), a power adjustment knob (28), and an ultrasound operation warning light (27); the control buttons of the jet system include a flow display meter (25), a power button (30), a jet operation warning light (29), and a jet speed adjustment button (31).