Aqueous dispersion and cosmetic preparation containing the same

Abstract

To provide: an aqueous dispersion of fine inorganic powder that exhibits excellent dispersibility in an aqueous medium and has high dispersion stability; and a cosmetic preparation containing the aqueous dispersion, which is highly stable and excellent in transparency, usability (non-stickiness), and water resistance.SOLUTION: An aqueous dispersion contains: (a) 10-70 mass% of hydrophobized titanium oxide fine particles which have a number average primary particle diameter of 8-200 nm as determined by an image analysis method of a transmission electron micrograph and are obtained by hydrophobizing titanium oxide particles with silicone; (b) 1.0-30 mass% of an aqueous component which has two or more alcoholic hydroxyl groups; (c) 1.0-20 mass% of a polyglycerol-modified silicone which can be dissolved in the component (b); and (d) 8-82 mass% of water.SELECTED DRAWING: None

Description

[Technical field]

[0001] The present invention relates to an aqueous dispersion containing hydrophobized titanium dioxide fine particles, and to a cosmetic preparation containing the aqueous dispersion. [Background technology]

[0002] In general, in sunscreen cosmetics, inorganic powders such as titanium oxide and zinc oxide are widely used as fine inorganic powders to improve transparency and enhance ultraviolet shielding effect (Patent Document 1). However, as the surface area of ​​these inorganic powders increases, the interactions between the particles become stronger, and as a result, the inorganic powders tend to aggregate easily.

[0003] These fine inorganic powders may be subjected to hydrophobic surface treatment for the purpose of blending into the oil phase of cosmetics or for improving water resistance. By blending such powders that have been subjected to hydrophobic surface treatment, it is expected that the ultraviolet shielding effect can be maintained even when wetted with water (Patent Documents 2 and 3). On the other hand, when blending fine inorganic powders into the aqueous phase, powders that have been subjected to hydrophilic surface treatment with silica or the like may be used. However, this hydrophilic powder has problems with water resistance and usability. In addition, as a method for dispersing hydrophobically treated powders in water, aqueous dispersions of hydrophobically treated fine titanium oxide particles using polyether-modified silicone have been considered. However, this aqueous dispersion of titanium oxide has problems with water resistance and usability (Patent Document 4).

[0004] Furthermore, a technique for obtaining dispersible powders by surface-treating powders with silicone surfactants is known. However, there has been insufficient research into the dispersion and water resistance of hydrophobically treated inorganic powders (Patent Document 5).

[0005] In addition, dispersions containing nonionic surfactants have been investigated, but sufficient dispersibility has not been obtained (Patent Document 6). For these reasons, there has been a demand for dispersions that have good long-term stability and provide a good feel when incorporated into cosmetics. [Prior art documents] [Patent documents]

[0006] [Patent Document 1] JP 2006-1886 A [Patent Document 2] JP 2014-201569 A [Patent Document 3] International Publication No. 2016 / 178380 [Patent Document 4] International Publication No. 2015 / 125622 [Patent Document 5] JP 2020-002031 A [Patent Document 6] Japanese Patent Application Publication No. 7-247119 Summary of the Invention [Problem to be solved by the invention]

[0007] The present invention has been made in view of the above circumstances, and aims to provide an aqueous dispersion of fine inorganic powder having excellent dispersibility in aqueous media and high dispersion stability, and to provide a cosmetic preparation containing the aqueous dispersion, which is highly stable, transparent, has a feeling of use (non-sticky), and is excellent in water resistance. [Means for solving the problem]

[0008] As a result of intensive research to achieve the above object, the present inventors have found that even a dispersion of titanium oxide fine particles, which is difficult to disperse, can provide an aqueous dispersion that is excellent in dispersibility in an aqueous medium, has high stability (viscosity stability), has long-term stability, and is excellent in feel when used (non-sticky) and water resistance. They have found that when this dispersion is used as a cosmetic dispersion, it results in a cosmetic that is easy to apply and has excellent transparency, feel when used, and water resistance, and have completed the present invention.

[0009] Accordingly, the present invention provides the following aqueous dispersion and cosmetic preparation. 1. (a) Hydrophobized titanium oxide fine particles: 10 to 70 mass %, in which the number average primary particle diameter measured by image analysis of transmission electron micrographs is 8 to 200 nm and the titanium oxide particles are hydrophobized with silicone; (b) an aqueous component having two or more alcoholic hydroxyl groups: 1.0 to 30% by mass; (c) a polyglycerin-modified silicone that is soluble in the component (b): 1.0 to 20% by mass, and (d) Water: 8~82% by mass An aqueous dispersion comprising: 2. The aqueous dispersion according to 1, wherein the component (a) is hydrophobized fine titanium oxide particles obtained by subjecting hydrous silica-coated titanium oxide particles to a hydrophobization treatment. 3. The aqueous dispersion according to 1 or 2, wherein the silicone in component (a) is hydrogen dimethicone. 4. The aqueous dispersion according to any one of 1 to 3, wherein the component (b) is an aqueous component having two alcoholic hydroxyl groups. 5. The aqueous dispersion according to any one of 1 to 4, wherein the component (c) is a component that is not soluble in the component (d). 6. The aqueous dispersion according to any one of 1 to 5, wherein the component (c) is polyglyceryl-3 disiloxane dimethicone. 7. The aqueous dispersion according to any one of 1 to 6, wherein the mass ratio (c) / (b) of the content of the component (c) to the content of the component (b) is 0.2 to 0.9. 8. The aqueous dispersion according to any one of 1 to 7, wherein the total content of the components (a), (b), (c) and (d) is 90 mass % or more based on the entire aqueous dispersion. 9. A cosmetic preparation containing the aqueous dispersion according to any one of 1 to 8. Effect of the Invention

[0010] According to the present invention, an aqueous dispersion can be obtained which has excellent dispersibility in aqueous media, high stability (viscosity stability), long-term stability, and excellent feel when used (non-sticky) and water resistance. When this aqueous dispersion is used as a dispersion for a cosmetic product, it is easy to apply and can provide a cosmetic product which is excellent in transparency, feel when used, and water resistance. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0011] The present invention will be described in detail below. In the present invention, the names of ingredients may be described in cosmetic display names or International Nomenclature of Cosmetic Ingredients (INCI). When the cosmetic display name and the INCI correspond to each other, the English description may be omitted.

[0012] [Component (a)] The component (a) of the present invention is a hydrophobic titanium oxide fine particle having a number average primary particle diameter of 8 to 200 nm as measured by image analysis of a transmission electron microscope photograph, in which titanium oxide particles have been hydrophobized with silicone, and can be used alone or in combination of two or more. Titanium oxide fine particles used as an ultraviolet scattering agent having an ultraviolet shielding effect are generally any raw material that can be blended in cosmetics, and may be a composite powder of two or more types with zinc oxide and cerium oxide, or a composite powder with other powders.

[0013] In order to reduce the coagulation property or suppress the activity of the powder, the titanium oxide fine particles may be surface-treated with silica, hydrous silica, alumina, aluminum hydroxide, etc. before the hydrophobization treatment. Note that alumina and aluminum hydroxide are not preferable as surface treatment agents when the swelling of the water-soluble polymer compound used in combination is inhibited or there is a concern of a decrease in water resistance when blended into a cosmetic. Hydrous silica-coated titanium oxide particles that are surface-treated with hydrous silica are preferable because they suppress the activity of the powder and are unlikely to inhibit the swelling of the water-soluble polymer. Note that the term "coated" refers to covering a part or the whole of the titanium oxide particles.

[0014] In the present invention, the titanium oxide particles are hydrophobized with silicone. Examples of the silicone used for the hydrophobization include silanes or silylation agents such as triethoxycaprylylsilane (AES-3083, manufactured by Shin-Etsu Chemical Co., Ltd.), dimethyl silicone (KF-96AK series, manufactured by Shin-Etsu Chemical Co., Ltd.), methyl hydrogen type polysiloxanes such as hydrogen dimethicone (KF-99P, KF-9901, etc., manufactured by Shin-Etsu Chemical Co., Ltd.), branched silicones such as triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone and triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone (KF-9908, KF-9909, etc., manufactured by Shin-Etsu Chemical Co., Ltd.), and the like. In particular, if the component contains one or more selected from triethoxycaprylylsilane, triethoxysilylethyl polydimethylsiloxyethyl dimethicone, triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone, and hydrogen dimethicone, the hydrophobic treatment is good, and it is preferable in terms of dispersibility with the (c) component. The hydrophobic treatment method is not particularly limited, and can be treated by a known method. For example, a wet treatment method, a dry treatment method, a gas phase method, etc. can be mentioned.

[0015] These surface-treated titanium oxide particles are also available as commercially available products. For example, they are commercially available under the trade names MT-01, 02, 050OTS, 100Z, 100TV, 100SAS, 150EX, 200ST, 500SAM, 505SAS, 700Z, 700BS (manufactured by Teika), ST-455, 455WS, 457ECS, 457SA, 495M, 455FA (manufactured by Titanium Industries), STR-100A-LP, 100C-LP, 100W-LP, 100C-LF, 40-LP (manufactured by Sakai Chemical Industry Co., Ltd.). Hydrophobized titanium oxide particles obtained by hydrophobizing hydrous silica-coated titanium oxide particles include STR-100W-LP. It is preferable that the particles are not included as the (a) component in the form of a dispersion in which the particles are dispersed in an oil agent in advance.

[0016] The number-average primary particle diameter of component (a) measured by image analysis of a transmission electron microscope photograph is 8 to 200 nm, preferably 10 to 150 nm. If it exceeds 200 nm, the ultraviolet protection function is reduced and white residue is left. If the particle diameter is less than 8 nm, the feeling of dryness may become strong and the feeling of use may become poor. The average primary particle diameter of component (a) of the present invention is the average diameter of 200 particles measured by image analysis based on a transmission electron microscope photograph. If the powder is not spherical, the average value of the minor axis of the particles is taken as the average primary particle diameter. Examples of the shape of the fine particle titanium dioxide include spindle-shaped, needle-shaped, straw-bundle-shaped, rectangular, approximately spherical, and rod-shaped.

[0017] The content of component (a) in the aqueous dispersion is 10 to 70% by mass, and from the viewpoint of usability, it is preferably 10 to 65% by mass, more preferably 15 to 60% by mass, and even more preferably 20 to 55% by mass. If it is less than 10% by mass, a sufficient ultraviolet shielding effect cannot be obtained, and if it is blended in more than 70% by mass, the spreadability during use may deteriorate, the stability over time of the dispersion may decrease, and the viscosity may increase.

[0018] [(b) Component] The component (b) of the present invention is an aqueous component having two or more alcoholic hydroxyl groups, i.e., a component that dissolves in water at 25° C., and can be used alone or in combination of two or more. Specifically, it includes sugar alcohols such as sorbitol (INCI), maltose (INCI), xylitol (INCI), glucose (INCI), glyceryl glucoside (INCI), sodium chondroitin sulfate (display name (INCI: Sodium Chondroitin Sulfate)), methyl gluceth-10 (INCI), methyl gluceth-20 (INCI), hyaluronic acid, phosphatidylglycerol, and phosphatidylinositol, BG (display name (INCI: Butylene Glycol)), PG (display name (INCI: Propylene Glycol)), and DPG (display name (INCI: Dipropylene Glycol)). Examples of suitable glycols include glycols such as pentylene glycol (INCI), 1,10-decanediol (INCI), octanediol (INCI), and 1,2-hexanediol (INCI), and polyhydric alcohols such as erythritol (INCI), glycerin (INCI), diglycerin (INCI), and polyethylene glycol. Among these, glycols such as BG (butylene glycol) and DPG (dipropylene glycol), and polyhydric alcohols such as glycerin are preferred because they dissolve in water at any ratio and have a good feel when used and are versatile as a cosmetic ingredient. In particular, glycols having two alcoholic hydroxyl groups in the molecule are more preferred.

[0019] The content of the (b) component in the aqueous dispersion is 1.0 to 30% by mass, preferably 5 to 25% by mass, and more preferably 7 to 15% by mass from the viewpoint of water resistance. From the viewpoint of stability over time, 15 to 25% by mass is more preferable, and 15 to 20% by mass is particularly preferable. If it is less than 1.0% by mass, the stability of the dispersion is deteriorated, and if it exceeds 30% by mass, the cosmetic product feels sticky when used, and the (b) component inhibits the (c) component described below from orienting in the (a) component, which may increase the viscosity or impair dispersibility in the aqueous medium. By blending the (b) component, the (c) component can be uniformly oriented on the surface of the (a) component.

[0020] [(c) component] The component (c) of the present invention is a polyglycerin-modified silicone that dissolves in the component (b), and can be used alone or in combination of two or more. By using a polyglycerin-modified silicone that dissolves in the component (b), the polyglycerin-modified silicone can be blended in water and can function as a dispersant for hydrophobic titanium oxide particles in water. In addition, when the component (c) is mixed with the component (b) at a concentration of 20% by mass and then left to stand at 25°C for 1 hour, the component (c) is considered to be in a transparent to semi-transparent state without a boundary, and the component (c) is considered to be in a non-transparent state ... non-transparent state is considered to be in a non-transparent state, and the non-transparent state is considered to be in a non-transparent state, and the non-transparent state is considered to be in a non-transparent state, and the non-transparent state is considered to be in a non-transparent state, and the non-

[0021] In terms of chemical structure, polyglycerin-modified silicone may be modified in a block or graft type by using polyglycerin and modifying the silicone chain, which is the main chain. From the viewpoint of maintaining uniform dispersion of the (a) component in the cosmetic, it is preferable to use a branched chain type. The silicone main chain may have a branched chain such as a silicone chain. Specifically, polyglyceryl-3 disiloxane dimethicone (INCI) and the like can be mentioned. From the viewpoint of water resistance, it is preferable that the (c) component dissolves at 25°C when mixed in BG at a concentration of 20% by mass and does not dissolve at 25°C when mixed in water at a concentration of 20% by mass.

[0022] Furthermore, the polyglycerin-modified silicone used in the present invention preferably has an HLB (Hydrophile-Lipophile Balance) value of 3 or more and less than 17, more preferably 5 or more and less than 15, and even more preferably 8 or more and less than 12. By making it 3 or more, dispersibility is further improved, and by making it less than 17, water resistance is further improved. The HLB is calculated by "(sum of formula weights of hydrophilic group moieties / total molecular weight)×20".

[0023] The content of the (c) component is 1.0 to 20% by mass of the aqueous dispersion, preferably 3 to 15% by mass, more preferably 4 to 10% by mass, and even more preferably 5 to 8% by mass. If it is less than 1.0% by mass, the stability of the dispersion may be deteriorated, and if it exceeds 20% by mass, the (c) component may be further oriented on the (c) component oriented on the (a) component, or the (c) component oriented on the (a) component may be easily peeled off due to the (c) component not oriented on the (a) component. As a result, the viscosity of the dispersion may be increased, or the dispersibility in the aqueous medium may be affected.

[0024] Furthermore, the mass ratio (c) / (b) of the content of the component (c) to the content of the component (b) is preferably 0.2 to 0.9. In particular, from the viewpoint of dispersibility and water resistance, it is more preferably 0.3 to 0.8, and even more preferably 0.4 to 0.5. By making this ratio 0.2 or more, the component (c) is easily oriented to the component (a), the increase in viscosity is suppressed, and the stability is further improved. On the other hand, by making it 0.9 or less, the component (c) is dispersed by the dispersion medium, it is easily oriented to the component (a), the increase in viscosity is suppressed, and the stability is further improved.

[0025] [(d) component] Component (d) of the present invention is water. Examples of water that can be used include ion-exchanged water, distilled water, deionized water, purified water as defined in the Japanese Pharmacopoeia, hot spring water, and deep sea water.

[0026] The content of component (d) is 8 to 82% by mass of the aqueous dispersion, preferably 18 to 72% by mass, and more preferably 28 to 40% by mass. Although a stable dispersion can be obtained even with a content of less than 8% by mass, it is difficult to achieve the purpose of lowering the viscosity by blending component (d). On the other hand, if the content exceeds 82% by mass, problems may occur in the stability over time.

[0027] The total content of the components (a), (b), (c) and (d) is preferably 90 to 100% by mass, more preferably 95 to 100% by mass, and even more preferably 99 to 100% by mass, based on the entire aqueous dispersion of the present invention. By making the total content of the components (a), (b), (c) and (d) 90% by mass or more, the influence of components other than the components (a), (b), (c) and (d) is small, and a dispersion with better stability and usability can be prepared.

[0028] In addition, an antifoaming agent may be added to the aqueous dispersion for the purpose of improving the handling during preparation or filling. Examples of antifoaming agents include salts such as simethicone (INCI), dimethicone (INCI), sodium chloride (display name (INCI: Sodium Chloride)), polyether-modified silicone, etc. In addition, an emulsion type in which the oil-based agent such as dimethicone is pre-emulsified may be used, and a self-emulsifying type in which the compound-based agent such as simethicone is pre-mixed with a silicone activator, etc. may be used. Among these, simethicone and sodium chloride are particularly preferred in terms of foam breaking and foam suppression properties, and simethicone is most preferred in terms of affinity with cosmetic ingredients. When an antifoaming agent is added, the amount is preferably 0.0001 to 1% by mass of the entire aqueous dispersion, more preferably 0.0025 to 0.6% by mass, and even more preferably 0.005 to 0.01% by mass.

[0029] [Aqueous dispersion] The aqueous dispersion of the present invention is easy to blend into an aqueous medium. The "dispersion" in "aqueous dispersion" refers to a composition containing 8 to 82 mass% of water, in which temporary settling is observed in the method described in the dispersibility test in the examples described later, but which disperses uniformly when stirring is continued.

[0030] [Mold of aqueous dispersion] The dispersion of the present invention is preferably liquid with a viscosity of 10 mPa·s or more and less than 200,000 mPa·s, more preferably 10 mPa·s or more and less than 10,000 mPa·s, and even more preferably 10 mPa·s or more and less than 5,000 mPa·s. By making the viscosity 10 mPa·s or more, the stability of the dispersion is further improved. On the other hand, from the viewpoint of handling, a viscosity of 200,000 mPa·s or less is preferable. The viscosity is measured at 25°C using a B-type viscometer (TVB-10 model, manufactured by Toki Sangyo Co., Ltd.) according to the method described in JIS K 7117-1:1999.

[0031] [Method for producing aqueous dispersion] When preparing the aqueous dispersion of the present invention, the method and the apparatus are not particularly limited, and can be carried out by a known method. For example, any stirrer, grinder, mixer, medium stirrer, rotation-revolution stirrer, disperser, etc., such as a Henschel mixer, ball mill, kneader, planetary mixer, ribbon blender, disperser, homomixer, jet mill, roll mill, bead mill, high-pressure disperser, etc. can be used. In particular, from the viewpoint of mixing efficiency, it is preferable to disperse using a bead mill or a high-pressure disperser.

[0032] [Cosmetics] The aqueous dispersion of the present invention can be used for various purposes, but is particularly applicable as a raw material for all cosmetics that are applied externally to the skin or hair.

[0033] The amount of the aqueous dispersion of the present invention when blended in a cosmetic is preferably 0.5 to 60% by mass, more preferably 1.0 to 50% by mass, and even more preferably 5.0 to 40% by mass, based on the total amount of the cosmetic. By making it 0.5% by mass or more, a sufficient ultraviolet protection effect can be expected, and by making it 60% by mass or less, the feeling during use is further improved.

[0034] The form of a cosmetic containing the aqueous dispersion of the present invention may be, for example, any of a water-in-oil emulsion cosmetic, an oil-in-water emulsion cosmetic, an aqueous cosmetic, or a multiple emulsion such as a W / O / W type or an O / W / O type. In particular, when used as a dispersion of an oil-in-water emulsion cosmetic, it is easy to apply, and a stable cosmetic having excellent transparency, usability, and water resistance can be obtained.

[0035] The cosmetic of the present invention may have various properties, such as liquid, milky, creamy, solid, paste, gel, powder, pressed, multi-layered, mousse, spray, stick, pencil, etc. Multi-layered refers to a cosmetic that separates into two or more layers when left to stand, and is filled in a container containing a stainless steel ball or the like, and used after shaking. The dispersion of the present invention has good dispersibility, so it is easy to redisperse even in such a dosage form. It is called a shaking type, etc., and is easy to stabilize, so it is a cosmetic that has an excellent feel when used, but it requires a lot of shaking. The cosmetic of the present invention is preferably stable, so it can be used without being separated into multiple layers. Sprayed refers to a spray-type cosmetic that is filled in a dispenser container, an aerosol container, etc., and sprayed from a nozzle. The cosmetic filled in the dispenser container is sprayed in a mist from the nozzle of the dispenser. The aerosol container is filled with the cosmetic and a propellant. The propellant is not particularly limited, and for example, various liquefied petroleum gases (LPG), dimethyl ether, nitrogen gas, carbon dioxide gas, etc. can be used. These can be used alone or in appropriate combination of two or more. The aqueous dispersion of the present invention has high dispersibility, so it can be used in such a dosage form.

[0036] The aqueous dispersion of the present invention is applicable to various cosmetics, and is particularly preferably used in cosmetics applied to the skin, such as skin care cosmetics, makeup cosmetics, antiperspirant cosmetics, and UV protection cosmetics, and cosmetics applied to the hair, such as hair cosmetics. Examples of skin care cosmetics include lotions, milky lotions, creams, cleansing, packs, oil liquids, massage products, beauty essences, beauty oils, cleaning agents, deodorants, hand creams, lip balms, and wrinkle concealers. Examples of makeup cosmetics include makeup bases, concealers, face powders, powder foundations, eye colors, eye shadows, mascaras, eyeliners, eyebrows, and lipsticks. Examples of antiperspirant cosmetics include antiperspirant cosmetics of roll-on type, cream type, solution type, and stick type. Examples of UV protection cosmetics include sunscreen oils, sunscreen milky lotions, and sunscreen creams. Examples of hair cosmetics include shampoos, rinses, treatments, and setting agents. Among these, UV protection cosmetics are preferred.

[0037] The cosmetic of the present invention may contain various components used in ordinary cosmetic products within a range that does not impair the effects of the present invention. For example, it may contain (1) an oil agent, (2) an aqueous component other than components (b) and (d), (3) a surfactant other than component (c), (4) a powder other than component (a), (5) a composition consisting of a crosslinked organopolysiloxane and an oil agent that is liquid at room temperature, (6) a film-forming agent, and (7) other additives. These may be used alone or in appropriate combination of two or more. In addition, the components contained in the above dispersion may be blended. However, even if the components (a) to (d) of the present invention are blended without blending the dispersion of the present invention, the remarkable effects aimed at by the present invention cannot be obtained. The amounts of the components (a) to (d) other than the dispersion are not particularly limited as long as they are within a range that does not impair the effects of the present invention. When blended into a cosmetic separately from the dispersion, the amount of the component (a) excluding the amount in the dispersion is, for example, preferably 0.0 to 20% by mass, more preferably 0.0 to 10% by mass in the cosmetic. The amount of component (b) in the cosmetic is preferably 0.0 to 70% by mass, more preferably 0.0 to 50% by mass, and even more preferably 0.0 to 25% by mass. The amount of component (c) in the cosmetic is preferably 0.0 to 3.0% by mass, and more preferably 0.0 to 1.0% by mass. The dispersion of the present invention is highly stable, and when blended in a cosmetic, it does not inhibit the performance of the emulsifier or dispersant in the cosmetic, so that the amount of component (c) other than the dispersion can be reduced.

[0038] (1) Oil The oil may be volatile or non-volatile and may be solid, semi-solid, or liquid at room temperature (25° C.). Examples of the oil include silicone oil, silicone wax, natural animal and vegetable oils and semi-synthetic oils and fats, hydrocarbon oils, higher alcohols, fatty acids, ester oils, fluorine-based oils, and ultraviolet absorbers.

[0039] Silicone oil Examples of silicone oils include alkyl-modified silicones such as dimethicone (INCI), trisiloxane (INCI), methyl trimethicone (INCI), ethyl trisiloxane (INCI), ethyl methicone (INCI), and hexyl dimethicone (INCI), long-chain alkyl-modified silicones such as caprylyl methicone (INCI), low- to high-viscosity linear or branched organopolysiloxanes such as phenyl trimethicone (INCI), diphenyl dimethicone (INCI), diphenylsiloxyphenyl trimethicone (INCI), tetraphenyldimethyldisiloxane (INCI), and methylhydrogen polysiloxane, cyclotetrasiloxane (INCI), cyclopentasiloxane (INCI), and silanes. Examples of such organopolysiloxanes include cyclic organopolysiloxanes such as cyclohexasiloxane (INCI), amino-modified organopolysiloxanes such as amodimethicone (INCI) and aminopropyl dimethicone (INCI), pyrrolidone-modified organopolysiloxanes such as PCA dimethicone (INCI), antifoaming agents such as simethicone (INCI), pyrrolidone carboxylic acid-modified organopolysiloxanes, silicone rubbers such as gummy dimethylpolysiloxanes with high degrees of polymerization, gummy amino-modified organopolysiloxanes, and gummy dimethylsiloxane-methylphenylsiloxane copolymers, as well as low-viscosity organopolysiloxane solutions of silicone gums and rubbers, amino acid-modified silicones, fluorine-modified silicones, silicone resins, and silicone resin solutions.

[0040] Examples of commercially available silicone oils include KF-96L-1cs, KF-96L-1.5cs, KF-96L-2cs, KF-96A-6cs, KF-4422, KF-4418, KF-54, KF-54HV, KF-56A, and KF-995 manufactured by Shin-Etsu Chemical Co., Ltd.

[0041] Solid oily ingredients In the present invention, when it is desired to solidify the cosmetic preparation, it is preferable to blend an oily component that is solid at 25° C. The oily component that is solid at 25° C. is preferably one that has a melting point of 40° C. or higher, more preferably 60 to 110° C., and examples of such oily components include wax, hydrocarbons, esters, higher alcohols, and higher fatty acids, and are not particularly limited as long as they are raw materials that can be normally blended into cosmetic preparations. Specifically, examples of such waxes include carnauba wax (INCI: Copernicia Cerifera (Carnauba) Wax), sugarcane wax, candelilla wax (INCI: Euphorbia Cerifera (Candelilla) Wax), refined candelilla wax, rice wax, wood wax, jojoba wax, kapok wax, rice bran wax, white bayberry fruit wax, shea butter, cacao butter, Japan wax (INCI: Rhus Succedanea Fruit Wax), montan wax (INCI: Montan Wax), vegetable waxes such as hydrogenated castor oil isostearate, beeswax, beef tallow, beef bone fat, lard (INCI: Lard), horse fat (INCI: Horse Fat), and the like. Fat), sheep tallow, lanolin (INCI:Lanolin), rambutanol, shellac wax, spermaceti, and other animal waxes, lanolin esters, lanolin fatty acid esters, beeswax acid esters, and other semi-synthetic waxes, hydrogenated oils, such as hydrogenated castor oil and hydrogenated coconut oil, solid paraffin, polyethylene, ceresin, ozokerite, and other hydrocarbon waxes, such as microcrystalline wax, wax esters, such as synthetic beeswax, amino acid stearyl alcohols, such as dioctyldodecyl lauroyl glutamate, dioctyldodecyl lauroyl glutamate, and dioctyldodecyl lauroyl glutamate, fatty acids, such as stearic acid and behenic acid, and silicone waxes, such as acrylic silicone resins of acrylic-silicone grafts or block copolymers (Shin-Etsu Chemical Co., Ltd.: acrylic-silicone graft copolymer: KP-561P, etc.), or derivatives thereof, and it is preferable to use one or more selected from these.

[0042] Natural animal and vegetable oils and semi-synthetic oils Natural animal and vegetable oils and semi-synthetic oils, アボガド oil (indicated name (INCI: Persea Gratissima (Avocado) Oil)), アマニ oil (indicated name (INCI: Linum Usitatissimum (Linseed) Seed Oil)), アーモンド oil (indicated name (INCI: Prunus Amygdalus Dulcis (Sweet Almond) Oil)), エゴマoil (indicated name), オリーブoil (indicated name (INCI: Olea Europaea (Olive) Fruit Oil)), アメリカガヤ oil (indicated name (INCI: Torreya Californica (California Nutmeg) Oil), Cymbopogon Nardus (Citronella) Oil), Torreya Nucifera Seed Oil), Kyounin Yu Oil (INCI: Kyounin Yu), Comu Germ Oil (INCI: Triticum Vulgare (Wheat) Germ Oil), Goma Oil (INCI: Sesamum Indicum (Sesame) Seed Oil), Comu Germ Oil (INCI: Triticum Vulgare (Wheat) Germ Oil), Comme Germ Oil (INCI: Oryza Sativa (Rice) Germ Oil), Oil), Comerca Oil (Indicative Name (INCI: Oryza Sativa (Rice) Bran Oil)), Sazan Oil (Indicative Name (INCI: Camellia Kissi Seed Oil)), Saffron Oil (Indicative Name (INCI: Carthamus Tinctorius (Safflower) Seed Oil)), Daizu Oil (Indicative Name (INCI: Glycine Soja (Soybean) Oil)), Chia Oil (Indicative Name (INCI: Camellia Sinensis Seed Oil)), Tsubaki Oil (Indicative Name (INCI: Camellia Japonica Seed Oil)), Evening Primrose Oil (Indicative Name (INCI: Oenothera Biennis (Evening Primrose)Germ oils such as quinoa oil (INCI: quinoa oil), natan oil (indicative name), tomologous germ oil (INCI: Zea Mays (Corn) Germ Oil), corn germ oil (INCI: Triticum Vulgare (Wheat) Germ Oil), palm oil (INCI: Elaeis Guineensis (Palm) Oil), palm kernel oil (INCI: Elaeis Guineensis (Palm) Kernel Oil), hematuria oil (INCI: Ricinus Communis (Castor) Seed Oil), and hematuria seed oil (INCI: Helianthus Annuus (Sunflower) Seed Oil), Budo seed oil (INCI: Vitis Vinifera (Grape) Seed Oil), Hohoba seed oil (INCI: Simmondsia Chinensis (Jojoba) Seed Oil), Macadamia seed oil (INCI: Macadamia Ternifolia Seed Oil), Medowfoam oil (INCI: Limnanthes Alba (Meadowfoam) Seed Oil), Sponge oil (INCI: Gossypium Herbaceum (Cotton) Seed Oil), Yam oil (INCI: Cocos Nucifera (Coconut) Oil), Piper nats oil (INCI: Arachis Hypogaea (Peanut) Oil), Oil)) and other natural vegetable oils, サメ liver oil (indicated name (INCI: Shark Liver Oil)), タラ liver oil (indicated name (INCI: Cod Liver Oil)), cod liver oil (indicated name (INCI: Fish Liver Oil)), タートル oil (indicated name (INCI: Turtle) Natural animal oils such as Mink Oil (INCI: Mink Oil), Mink Oil (INCI: Egg Oil), water-added coconut oil (INCI: Hydrogenated Coconut Oil), liquid ラノリン (INCI: Lanolin Oil)) and other semi-synthetic oils, etc.

[0043] Hydrocarbon oil Examples of the hydrocarbon oil include linear or branched hydrocarbon oils, and may be volatile or non-volatile hydrocarbon oils.Specific examples include isoparaffins such as olefin oligomers (INCI), (C13,14) isoparaffin (INCI), isododecane (INCI), undecane (INCI), tridecane (INCI), dodecane (INCI), isohexadecane (INCI), hydrogenated polyisobutene (display name (INCI: Hydrogenated Polyisobutene)), squalane (INCI), mineral oil (INCI), coconut alkane (INCI), (C13-15) alkane (INCI), and other alkanes.

[0044] Higher alcohols Examples of higher alcohols include alcohols having preferably 6 or more carbon atoms, more preferably 10 to 30. Specific examples of higher alcohols include lauryl alcohol (INCI), myristyl alcohol (INCI), palmityl alcohol (INCI), stearyl alcohol (INCI), behenyl alcohol (INCI), oleyl alcohol (INCI), isostearyl alcohol (INCI), octyldodecanol (INCI), cholesterol (INCI), phytosterols (INCI), batyl alcohol (INCI), and the like.

[0045] Ester oil Examples of ester oils include n-alkyl glycol monoisostearates such as diisobutyl adipate (display name: INCI: Diisobutyl Adipate), dihexyldecyl adipate (display name: INCI: Diheptylundecyl Adipate), and isostearyl isostearate (display name: INCI: Isostearyl Isostearate), isocetyl isostearate (display name: INCI: Isocetyl Isostearate), trimethylolpropane triisostearate (display name: INCI: Trimethylolpropane Triisostearate), glycol diethylhexanoate (display name: INCI: Glycol Diethylhexanoate), cetyl ethylhexanoate (display name: INCI: Cetyl Ethylhexanoate), and trimethylolpropane triethylhexanoate (display name: INCI: Trimethylolpropane Triethylhexanoate), pentaerythrityl tetraethylhexanoate (display name (INCI: Pentaerythrityl Tetraethylhexanoate)), cetyl octanoate (display name (INCI: Cetyl Ethylhexanoate)), octyldodecyl stearoyloxystearate (display name (INCI: Octyldodecyl Stearoyl Stearate)), and other octyldodecyl esters, oleyl oleate (display name (INCI: Oleyl Oleate)), octyldodecyl oleate (display name (INCI: Octyldodecyl Oleate)), decyl oleate (display name (INCI: Decyl Oleate)), neopentyl glycol dioctanoate (display name (INCI: Neopentyl Glycol Diethylhexanoate)), neopentyl glycol dicaprate (display name (INCI: Neopentyl Glycol Dicaprate), Diisostearyl Malate (Indicated Name (INCI:Diisostearyl Malate)), Triethyl Citrate (Indicated Name (INCI:TriethylCitrate), diethylhexyl succinate (Inci: Diethylhexyl Succinate), amyl acetate (Inci: Amyl Acetate), ethyl acetate (Inci: Etyl Acetate), butyl acetate (Inci: Butyl Acetate), isocetyl stearate (Inci: Isocetyl Stearate), butyl stearate (Inci: Butyl Stearate), diisopropyl sebacate (Inci: Diisopropyl Sebacate), diethylhexyl sebacate (Inci: Diethylhexyl Sebacate), cetyl lactate (Inci: Cetyl Lactate), myristyl lactate (Inci: Myristyl Lactate), isononyl isononanoate (Inci: Isononyl Isononanoate), isotridecyl isononanoate (display name (INCI: Isotridecyl Isononanoate)), isopropyl palmitate (display name (INCI: Isopropyl Palmitate)), ethylhexyl palmitate (display name (INCI: Ethylhexyl Isopalmitate)), hexyldecyl palmitate (display name (INCI: Isocetyl Palmitate, Hexyldecyl Palmitate)), and other palmitic acid esters, cholesteryl hydroxystearate (display name (INCI: Cholesteryl Hydroxystearate)), isopropyl myristate (display name (INCI: Isopropyl Myristate)), octyldodecyl myristate (display name (INCI: Octyldodecyl Myristate)), myristyl myristate (display name (INCI: Myristyl Myristate), ethylhexyl laurate (INCI:Ethylhexyl Laurate), hexyl laurate (INCI:Hexyl Laurate), dioctyldodecyl lauroyl glutamate (INCI:Dioctyldodecyl Lauroyl Glutamate),Lauroyl Glutamate), Lauroyl Sarcosine Isopropyl Ester (Display name (INCI: Isopropyl Lauroyl Sarcosinate)), Coco-Caprylate / Caprate (Display name (INCI: Coco-Caprylate / Caprate)).

[0046] Furthermore, among the ester oils, examples of the glyceride oil include triethylhexanoin (display name (INCI:)), tri(caprylic / capric acid)glyceryl (display name (INCI: Caprylic / Capric Triglyceride)), cocoglyceryl (INCI), (caprylic / capric / succinic acid) triglyceride (display name (INCI: Caprylic / Capric / Succinic Triglyceride)), and (caprylic / capric acid) glycerides (display name (INCI: Caprylic / Capric Glycerides)).

[0047] Fluorine-based oils Examples of fluorine-based oils include perfluorodecalin (INCI), perfluorononyl dimethicone (INCI), and perfluoromethylcyclopentane (INCI).

[0048] ·UV absorber Examples of ultraviolet absorbers include oxybenzone-1 (label name: INCI: Benzophenone-1), oxybenzone-2 (label name: INCI: Benzophenone-2), oxybenzone-3 (label name: INCI: Benzophenone-3), oxybenzone-4 (label name: INCI: Benzophenone-4), oxybenzone-5 (label name: INCI: Benzophenone-5), oxybenzone-6 (label name: INCI: Benzophenone-6), oxybenzone-9 (label name: INCI: Benzophenone-9), homosalate (INCI), octocrylene (INCI), t-butyl methoxydibenzoylmethane (label name: INCI: Butyl Methoxydibenzoylmethane), ethylhexyl salicylate (label name: INCI: Ethylhexyl Salicylate), Diethylamino Hydroxybenzoyl Hexyl Benzoate (Inci: Diethylamino Hydroxybenzoyl Hexyl Benzoate), Polysilicone-15 (Inci), Octyl Dimethoxybenzylidene Dioxoimidazolidine Propionate (Inci: Ethylhexyl Dimethoxybenzylidene Dioxoimidazolidine Propionate), Terephthalylidene Dicamphor Sulfonic Acid (Inci: Terephthalylidene Dicamphor Sulfonic Acid), Ethylhexyl Triazone (Inci), Bis(trimethylsiloxy)silylisopentyl Trimethoxycinnamate (Inci: Isopentyl Trimethoxycinnamate Trisiloxane), Drometrizole Trisiloxane (Inci), Ethylhexyl Dimethyl PABA (Inci: Ethylhexyl Dimethyl PABA), isopropyl paramethoxycinnamate (display name (INCI: Isopropyl Methoxycinnamate)), ethylhexyl methoxycinnamate (display name (INCI: EthylhexylMethoxycinnamate), bisethylhexyloxyphenol methoxyphenyl triazine (INCI), phenylbenzimidazole sulfonic acid (display name (INCI: Phenylbenzimidazole Sulfonic Acid)), methylene bisbenzotriazolyl tetramethylbutylphenol (INCI), glyceryl dimethoxycinnamate ethylhexanoate (display name (INCI: Glyceryl Ethylhexanoate Dimethoxycinnamate)), glyceryl PABA (INCI), methyl diisopropyl cinnamate (display name (INCI: Diisopropyl Methyl Cinnamate)), cinoxate (INCI), and ethylhexyl dimethoxybenzylidene dioxoimidazolidine propionate (display name (INCI: Ethylhexyl Dimethoxybenzylidene Dioxoimidazolidine Propionate)).

[0049] (2) Aqueous components other than components (b) and (d) The aqueous component is not particularly limited as long as it is an aqueous component other than the above (b) and (d) components and can be normally incorporated into cosmetics. Specific examples include moisturizers such as betaine (INCI), PCA-Na (display name (INCI: Sodium PCA)), egg yolk lecithin, soybean lecithin, phosphatidylcholine, phosphatidylethanolamine, phosphatidylserine, and sphingophospholipids. In addition, examples include water-soluble polymers such as gum arabic, guar gum, carrageenan, agar, quince seed, locust bean gum, xanthan gum, pullulan, sodium carboxymethylcellulose, hydroxyethylcellulose, and vinyl polymers such as carboxyvinyl polymers, and acrylic polymers such as (ammonium acryloyldimethyltaurate / vinylpyrrolidone) copolymers, (sodium acrylate / sodium acryloyldimethyltaurate) copolymers, (hydroxyethyl acrylate / sodium acryloyldimethyltaurate) copolymers, (acrylamide / sodium acryloyldimethyltaurate) copolymers, and polyacrylamide. Among these, the use of acrylic polymers makes it relatively easy to stabilize oil-in-water cosmetic compositions.

[0050] (3) Surfactants other than component (c) The surfactant may be a nonionic, anionic, cationic or amphoteric surfactant, but is not particularly limited thereto. Any surfactant other than the above component (c) that is used in ordinary cosmetics may be used. Among these surfactants, one or more selected from non-crosslinked silicone surfactants or crosslinked silicone surfactants are preferred because they can provide a stable cosmetic. In either case, when a surfactant is added, the amount is preferably 0.1 to 20% by mass of the entire cosmetic. If the amount is 0.1% or more, the function of dispersion and emulsification can be fully performed, and if the amount is 20% by mass or less, it is preferred because there is no risk of the cosmetic becoming sticky when used. The HLB of the surfactant is not limited, but is preferably 2 to 14.5 for the purpose of maintaining the water resistance of the cosmetic.

[0051] The non-crosslinked silicone surfactant is one in which some of the methyl groups in a linear or branched silicone main chain have been substituted with hydrophilic groups such as polyethylene glycol or polyglycerin, and specifically, preferred are linear or branched polyoxyethylene-modified organopolysiloxanes, linear or branched polyoxyethylene-polyoxypropylene-modified organopolysiloxanes, linear or branched polyoxyethylene-alkyl-co-modified organopolysiloxanes, linear or branched polyoxyethylene-polyoxypropylene-alkyl-co-modified organopolysiloxanes, linear or branched polyglycerin-modified organopolysiloxanes, linear or branched polyglycerin-alkyl-co-modified organopolysiloxanes, and linear or branched pyrrolidone-modified organopolysiloxanes. Examples include PEG-11 methyl ether dimethicone (INCI), PEG / PPG-20 / 22 butyl ether dimethicone (INCI), PEG-3 dimethicone (INCI), PEG-10 dimethicone (INCI), PEG-9 polydimethylsiloxyethyl dimethicone (INCI), lauryl PEG-9 polydimethylsiloxyethyl dimethicone (INCI), cetyl PEG / PPG-10 / 1 dimethicone (INCI), polyglyceryl-3 polydimethylsiloxyethyl dimethicone (INCI), lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (INCI), and isostearyl polyglyceryl-3 dimethicone (INCI).

[0052] Commercially available examples include KF-6011, KF-6011P, KF-6012, KF-6015, KF-6017, KF-6043, KF-6028, KF-6038, KF-6048, KF-6104, KF-6106, KF-6105, KF-6180, and KF-6115 manufactured by Shin-Etsu Chemical Co., Ltd.

[0053] Examples of crosslinked silicone surfactants include (dimethicone / (PEG-10 / 15)) crosspolymer (INCI), (PEG-15 / lauryl dimethicone) crosspolymer (INCI), (PEG-10 / lauryl dimethicone) crosspolymer (INCI), (PEG-15 / lauryl polydimethylsiloxyethyl dimethicone) crosspolymer (INCI), (dimethicone / polyglycerin-3) crosspolymer (INCI), (lauryl dimethicone / polyglycerin-3) crosspolymer (INCI), (polyglycerin-3 / lauryl polydimethylsiloxyethyl dimethicone) crosspolymer (INCI), etc. In addition, when a crosslinked silicone surfactant is used, in a composition consisting of the crosslinked silicone surfactant and an oil agent that is liquid at room temperature, it is preferable that the crosslinked silicone surfactant swells with the liquid oil agent by absorbing more than its own weight.

[0054] As the liquid oil agent, liquid silicone oil, hydrocarbon oil, ester oil, natural animal and vegetable oil, semi-synthetic oil, or fluorine-based oil in the optional component (1) oil agent can be used, and examples thereof include cyclopentasiloxane (INCI), dimethicone (INCI), caprylyl methicone (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (display name: INCI: Isotridecyl Isononanoate), squalane (INCI), etc.

[0055] Examples of commercially available cross-linked silicone surfactants that swell when they contain a liquid oil include KSG-210, KSG-240, KSG-270, KSG-310, KSG-320, KSG-330, KSG-340, KSG-320Z, KSG-350Z, KSG-710, KSG-790, KSG-810, KSG-820, KSG-830, KSG-840, KSG-820Z, KSG-850Z, and the like, manufactured by Shin-Etsu Chemical Co., Ltd.

[0056] (4) Powder other than component (a) Examples of powders other than component (a) include color pigments, inorganic powders, metal powders, organic powders, inorganic-organic composite powders, etc. Specific examples are as follows.

[0057] Color pigments The color pigment is not particularly limited as long as it is a pigment that is normally used for the purpose of coloring cosmetics, and examples thereof include red iron oxide (display name (INCI: Iron Oxides)), yellow iron oxide (display name (INCI: Iron Oxides)), white titanium oxide (display name (INCI: Titanium Dioxide)), black iron oxide (display name (INCI: Iron Oxides)), ultramarines (display name (INCI: Ultramarines)), ferric ferocyanide (display name (INCI: Ferric Ferrocyanide, Ferric Ammonium Ferrocyanide)), manganese violet (display name (INCI: Manganese Violet)), cobalt titanate (display name (INCI: Cobalt Titanium Oxide)), chromium hydroxide (display name (INCI: Chromium Hydroxide Green)), chromium oxide (display name (INCI: Chromium Oxide Greens)), aluminum / cobalt oxide (display name (INCI: Cobalt Aluminum Any of the following pigments can be used: inorganic brown pigments such as titanium nitride (display name (INCI: Titanium Nitride)), ferrous hydroxide (display name (INCI: Iron Hydroxide)), γ-iron oxide, inorganic yellow pigments such as ocher, and colored pigments such as lakes of tar-based pigments and lakes of natural pigments. The shape of the pigment may be any shape, such as spherical, approximately spherical, rod-like, spindle-like, petal-like, rectangular, or irregular, and there is no particular limitation on the geometric form as long as it is capable of imparting color to the cosmetic.

[0058] ·Inorganic powder Inorganic powders include zirconium oxide (display name: INCI: Zirconium Dioxide), zinc oxide (display name: INCI: Zinc Oxide), cerium oxide (display name: INCI: Cerium Oxide), magnesium oxide (display name: INCI: Magnesium Oxide), barium sulfate (display name: INCI: Barium Sulfate), calcium sulfate (display name: INCI: Calcium Sulfate), magnesium sulfate (display name: INCI: Magnesium Sulfate), calcium carbonate (display name: INCI: Calcium Carbonate), magnesium carbonate (display name: INCI: Magnesium Carbonate), talc (INCI), mica (INCI), kaolin (INCI), and synthetic fluorophlogopite (display name: INCI: Synthetic Synthetic fluorphlogopite (display name), biotite (display name (INCI:Biotite)), potassium silicate (display name (INCI:Potassium Silicate)), silica (INCI), aluminum silicate (display name (INCI:Aluminum Silicate)), magnesium silicate (display name (INCI:Magnesium Silicate)), aluminum / magnesium silicate (display name (INCI:Magnesium Aluminum Silicate)), calcium silicate (display name (INCI:Calcium Silicate)), aluminum / calcium / sodium silicate (display name (INCI:Aluminum Calcium Sodium Silicate)), lithium / magnesium / sodium silicate (display name (INCI:Lithium Magnesium Sodium Silicate)), sodium / magnesium silicate (display name (INCI:Sodium Magnesium Silicate), Borosilicate (Ca / Al) (Display name (INCI: Calcium Aluminum Borosilicate)), Borosilicate (Ca / Na) (Display name (INCI: Calcium SodiumExamples of such fine particles include those made of aluminum hydroxide (display name (INCI: Aluminum Hydroxide)), boron nitride (display name (INCI: Boron Nitride)), glass (display name (INCI: Glass)), etc.

[0059] Examples of inorganic colored pearl pigments include pearl agents such as mica (INCI) coated with titanium oxide (display name (INCI: Titanium Dioxide)) and synthetic fluorophlogopite (display name (INCI: Synthetic Fluorphlogopite)) coated with titanium oxide (display name (INCI: Titanium Dioxide)), as well as pearl pigments such as bismuth oxychloride (display name (INCI: Bismuth Oxychloride)), bismuth oxychloride (display name (INCI: Bismuth Oxychloride)) coated with titanium oxide (display name (INCI: Titanium Dioxide)), talc (INCI) coated with titanium oxide (display name (INCI: Titanium Dioxide)), fish scale foil (display name), and colored mica coated with titanium oxide (display name (INCI: Titanium Dioxide)), and may be untreated or may have been subjected to a known surface treatment generally used in cosmetics, without any particular limitation.

[0060] ·Metal powder Examples of metal powder include fine metal particles made of Al (display name: INCI: Aluminum, Aluminum Powder), copper (display name: INCI: Copper Powder), silver (display name: INCI: Silver Powder), gold (display name: INCI: Gold), etc.

[0061] ·Organic powder Examples of organic powders include powders made of silicone, polyamide, polyacrylic acid / acrylic acid ester, polyester, polyethylene (INCI), polypropylene (INCI), polystyrene (INCI), styrene / acrylic acid copolymer, divinylbenzene / styrene copolymer, polyurethane, vinyl resin, urea resin, melamine resin, benzoguanamine, polymethylbenzoguanamine, tetrafluoroethylene, polymethylmethacrylate, cellulose (INCI), silk (INCI), nylon (display name), phenolic resin, epoxy resin, polycarbonate, etc. In particular, examples of silicones include silicone resin particles; polymethylsilsesquioxane (INCI), silicone rubber powder, silicone resin-coated silicone rubber powder; (vinyl dimethicone / methicone silsesquioxane crosspolymer) (display name: INCI: vinyl dimethicone / methicone silsesquioxane crosspolymer), (diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane crosspolymer) (display name: INCI: diphenyl dimethicone / vinyl diphenyl dimethicone / silsesquioxane crosspolymer), polysilicone-1 crosspolymer (INCI), polysilicone-22 (INCI), and the like.

[0062] Examples of commercially available silicone powders include KMP-590, KMP-591, KMP-592, KMP-597, KMP-598, KSP-100, KSP-101, KSP-102, KSP-105, KSP-100W, KSP-300, KSP-411, KSP-441, KM-9729, KM-440, and the like, manufactured by Shin-Etsu Chemical Co., Ltd.

[0063] Further examples include metal soaps, and specific examples thereof include powders made of zinc stearate (display name (INCI: Zinc Stearate)), aluminum stearate (display name (INCI: Aluminum Stearate)), calcium stearate (display name (INCI: Calcium Stearate)), magnesium stearate (display name (INCI: Magnesium Stearate)), zinc myristate (display name (INCI: Zinc Myristate)), magnesium myristate (display name (INCI: Magnesium Myristate)), zinc / sodium cetyl phosphate (display name (INCI: Sodium Zinc Cetyl Phosphate)), potassium cetyl phosphate (display name (INCI: Potassium Cetyl Phosphate)), and the like.

[0064] Further, organic dyes and the like are also included, and specific examples thereof include Red 3, Red 104(1) (display name (INCI:Red 28, Red 28 Lake)), Red 106, Red 201 (display name (INCI:Red 6)), Red 202 (display name (INCI:Red 7)), Red 204, Red 205, Red 220 (display name (INCI:Red 34)), Red 226 (display name (INCI:Red 30)), Red 227 (display name (INCI:Red 33, RED 33 Lake)), Red 228 (display name (INCI:Red 36)), Red 230(1) (display name (INCI:Red 22, Red 22 Lake)), Red 230(2) (display name), Red 401 (display name), Red 505 (display name), Yellow 4 (display name (INCI:Yellow 5)), Yellow 5 (Display name (INCI: Yellow 6, Yellow 6 Lake)), Yellow 202 (1) (Display name (INCI: Yellow 8)), Yellow 203 (Display name (INCI: Yellow 10, Yellow 10 Lake)), Yellow 204 (Display name (INCI: Yellow 11)), Yellow 401, Blue 1 (Display name (INCI: Blue) 1, Blue 1 Lake)), Blue 2, Blue 201, Blue 205 (Display name (INCI:Blue 4)), Blue 404 (Display name), Green 3 (Display name (INCI:Green 3, Green 3 Lake)), Green 201 (Display name (INCI:Green 5))), Green 202 (Display name (INCI:Green 6)), Green 204 (Display name (INCI:Green) 8), Green 205 (Display Name), Orange 201 (Display Name (INCI: Orange 5)), Orange 203 (Display Name (INCI: Pigment Orange 5)), Orange 204 (Display Name), Orange 205 (Display Name (INCI: Orange 4, Orange 4 Lake)), Orange 206 (Display Name (INCI: Orange 10)), Orange 207 (Display Name (INCI: Orange 11)) and other tar dyes, cochineal (INCI), laccaic acid (Display Name (INCI: Laccaic Acid)), safflower red (Display Name (INCI: Carthamus Tinctorius (Safflower) Flower Extract)), purple root extract (Display Name (INCI: Lithospermum OfficinaleExamples of natural pigments include Gardenia Root Extract), Gardenia Yellow (display name), and Gardenia Blue (display name (INCI: Hydrolyzed Gardenia Florida Extract)).

[0065] ·Inorganic / organic composite powder An example of the inorganic-organic composite powder is a composite powder in which the surface of an inorganic powder is coated with an organic powder by a publicly known method.

[0066] The above-mentioned powders may be surface-treated. The surface treatment agent is preferably one that can impart hydrophobicity from the viewpoint of water resistance of the cosmetic, and the treatment agent that can impart hydrophobicity is not particularly limited, and examples thereof include silicone treatment agents, waxes, paraffins, organic fluorine compounds such as perfluoroalkyl and phosphates, surfactants, amino acids such as N-acyl glutamic acid, and metal soaps such as aluminum stearate and magnesium myristate.

[0067] Preferred are silicone treatment agents, and examples thereof include silanes or silylation agents such as triethoxycaprylylsilane (INCI), dimethicone (INCI), methicone (INCI), hydrogen dimethicone (INCI), triethoxysilylethyl polydimethylsiloxyethyl dimethicone (INCI), triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone (INCI), (acrylates / tridecyl acrylate / triethoxysilylpropyl methacrylate / dimethicone methacrylate) copolymer (display name (INCI: Acrylates / Tridecyl Acrylate / Triethoxysilylpropyl Methacrylate / Dimethicone Methacrylate Copolymer)), and the like. Specific examples of these silicone treatment agents include AES-3083, KF-99P, KF-9901, KF-9908, KF-9909, KP-574, KP-541, and the like, all of which are manufactured by Shin-Etsu Chemical Co., Ltd.

[0068] Furthermore, the above surface hydrophobic treatment agents may be used alone or in combination of two or more. Specific examples of surface-treated color pigments include the KTP-09 series manufactured by Shin-Etsu Chemical Co., Ltd., in particular, KTP-09W, KTP-09R, KTP-09Y, and KTP-09B.

[0069] ·UV absorbing and scattering agent In addition to the dispersion of the present invention, a dispersion in which the particles that absorb and scatter ultraviolet light, which are component (a), are dispersed in an oil agent in advance can also be used. As the oil agent, liquid silicone oil, hydrocarbon oil, ester oil, natural animal and vegetable oil, semi-synthetic oil, and fluorine-based oil in the optional component (1) oil agent can be used. Specific examples of dispersions in which particles that absorb and scatter ultraviolet light are pre-dispersed in an oil agent include the SPD series (product name) manufactured by Shin-Etsu Chemical Co., Ltd., in particular SPD-T5, SPD-T5L, SPD-Z5, SPD-T6, SPD-Z6, SPD-T7, and SPD-Z7L.

[0070] (5) A composition comprising a crosslinked organopolysiloxane and an oil that is liquid at room temperature In a composition comprising a crosslinked organopolysiloxane and an oil that is liquid at room temperature, the crosslinked organopolysiloxane preferably swells with the liquid oil by absorbing more than its own weight of the liquid oil. The liquid oil may be a liquid silicone oil, a hydrocarbon oil, an ester oil, a natural animal or vegetable oil, a semi-synthetic oil, or a fluorine-based oil, which is included in the optional component (1) oil, and examples of such oil include cyclopentasiloxane (INCI), dimethicone (INCI), mineral oil (INCI), isododecane (INCI), isohexadecane (INCI), triethylhexanoin (INCI), isotridecyl isononanoate (display name (INCI: Isotridecyl Isononanoate)), squalane (INCI), and (caprylic acid / capric acid) cocoalkyl (display name (INCI: Coco-Caprylate·Caprate)).

[0071] Unlike the crosslinked silicone surfactant of component (3) described above, component (5) is a compound that does not have a polyether or polyglycerin structure in its molecular structure. Specific examples include dimethicone / vinyl dimethicone crosspolymer (INCI), dimethicone / phenyl vinyl dimethicone crosspolymer (display name: (INCI: Dimethicone / Phenyl Vinyl dimethicone crosspolymer)), vinyl dimethicone / lauryl dimethicone crosspolymer (INCI), and lauryl polydimethylsiloxyethyl dimethicone / bisvinyl dimethicone crosspolymer (INCI).

[0072] Examples of commercially available compositions consisting of a crosslinked organopolysiloxane and an oil that is liquid at room temperature include KSG-15, KSG-1510, KSG-16, KSG-1610, KSG-19, KSG-016F, KSG-18A, KSG-41A, KSG-42A, KSG-43, KSG-44, KSG-45, KSG-042Z, KSG-045Z, KSG-048Z, and KM-116 manufactured by Shin-Etsu Chemical Co., Ltd.

[0073] (6) Film-forming agents The film-forming agent is mainly blended for the purpose of further maintaining the effect of the cosmetic. Although there is no particular limitation, it is preferable that the composition is a silicone-based composition from the viewpoint of imparting water repellency. Specifically, trimethylsiloxysilicate, acrylic-silicone film-forming agent, silicone-modified norbornene, silicone-modified pullulan, silicone-modified polyvinyl alcohol, etc. can be used.

[0074] Examples of film-forming agents for silicone-based compositions include trimethylsiloxysilicate (INCI name), acrylates / dimethicone copolymer (INCI), norbornene / tris(trimethylsiloxy)silylnorbornene copolymer (INCI), tri(trimethylsiloxy)silylpropylcarbamate pullulan (INCI name (INCI name)).

[0075] The film-forming agent may be dissolved in a liquid oil at room temperature beforehand and then blended into the cosmetic. The liquid oil may be liquid silicone oil, hydrocarbon oil, ester oil, natural animal and vegetable oil, semi-synthetic oil, or fluorine-based oil, which is included in the optional component (1) oil. Specific examples of commercially available silicone film-forming agents include KF-7312J, KP-545, KP-549, KP-543, NBN-30-ID, TSPL-30-ID, and TSPL-30-D5, all of which are manufactured by Shin-Etsu Chemical Co., Ltd.

[0076] (7) Other additives Other additives include oil-soluble gelling agents, preservatives / bactericides, antiperspirants, fragrances, salts, antioxidants, pH adjusters, chelating agents, cooling agents, anti-inflammatory agents, skin beautifying ingredients (skin whitening agents, cell activators, skin roughness improving agents, blood circulation promoters, skin astringents, antiseborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds, etc.

[0077] Oil-soluble gelling agent Examples of oil-soluble gelling agents include metal soaps such as aluminum stearate, magnesium stearate, and zinc myristate; amino acid derivatives such as lauroyl glutamic acid (labeled as (INCI: Lauroyl Glutamic Acid)) and α,γ-di-n-butylamine; dextrin palmitate (labeled as (INCI: Dextrin Palmitate)), dextrin isostearate (labeled as (INCI: Dextrin Isostearate)), dextrin myristate (labeled as (INCI: Dextrin Myristate)), inulin stearate (labeled as (INCI: Stearoyl Inulin)), and dextrin (palmitic acid / ethylhexanoic acid) (labeled as (INCI: Dextrin dextrin fatty acid esters such as sucrose palmitate, sucrose stearate, and the like; fructooligosaccharide fatty acid esters such as fructooligosaccharide stearate, fructooligosaccharide 2-ethylhexanoate, and the like; benzylidene derivatives of sorbitol such as monobenzylidene sorbitol, dibenzylidene sorbitol, and the like; disteardimonium hectorite (INCI), stearalkonium hectorite (INCI), and organically modified clay minerals of hectorite; stearalkonium bentonite (INCI), and the like.

[0078] · Preservatives · Disinfectants Examples of preservatives and disinfectants include alkyl paraoxybenzoate, benzoic acid, sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, imidazolidinyl urea, salicylic acid, isopropylmethylphenol, carbolic acid, parachlormetacresol, hexachlorophene, benzalkonium chloride, chlorhexidine chloride, trichlorocarbanilide, iodopropynyl butylcarbamate, polylysine, bisabolol, ethylhexylglycerin, glyceryl caprylate, caprylhydroxamic acid, hexyl dimethylolpropanoate, polyaminopropyl biguanide, photosensitizer, silver, plant extract, etc. Preservatives may be used alone or in combination of two or more types. In particular, polylysine, bisabolol, ethylhexylglycerin, glyceryl caprylate, caprylhydroxamic acid, hexyl dimethylolpropanoate, polyaminopropyl biguanide, ethylhexylglycerin, and phenoxyethanol are preferred because they are easy to incorporate into cosmetics and are expected to have a preservative effect, and ethylhexylglycerin, phenoxyethanol, and glyceryl caprylate are particularly preferred in terms of compatibility with the dispersion of the present invention. The incorporation of a preservative is expected to suppress bacterial contamination and improve the storage stability of the dispersion.

[0079] Antiperspirant Examples of antiperspirants include hydroxyaluminum halides such as chlorohydroxyaluminum, aluminum halides such as aluminum chloride, aluminum allantoin salts, tannic acid, persimmon tannin, sulfate (Al / K), zinc oxide, zinc paraphenolsulfonate, burnt alum, tetrachloro(Al / zirconium) hydrate, trichlorohydrex glycine (Al / zirconium), etc. In particular, as components that exhibit high effects, hydroxyaluminum halides, aluminum halides, and their complexes or mixtures with zirconyl oxyhalides and zirconyl hydroxyhalides (e.g., tetrachloro(Al / zirconium) hydrate, trichlorohydrex glycine (Al / zirconium)) are preferred.

[0080] ·Fragrance Fragrances include natural fragrances and synthetic fragrances. Natural fragrances include plant-based fragrances separated from flowers, leaves, wood, peels, etc., and animal-based fragrances such as musk and civet. Synthetic fragrances include hydrocarbons such as monoterpenes, alcohols such as aliphatic alcohols and aromatic alcohols, aldehydes such as terpene aldehydes and aromatic aldehydes, ketones such as alicyclic ketones, esters such as terpene esters, lactones, phenols, oxides, nitrogen-containing compounds, and acetals.

[0081] ·salts Examples of salts include inorganic salts, organic acid salts, amine salts, and amino acid salts. Examples of inorganic salts include sodium salts, potassium salts, magnesium salts, calcium salts, aluminum salts, zirconium salts, zinc salts, and the like of inorganic acids such as hydrochloric acid, sulfuric acid, carbonic acid, and nitric acid; examples of organic acid salts include salts of organic acids such as acetic acid, dehydroacetic acid, citric acid, malic acid, succinic acid, ascorbic acid, and stearic acid; examples of amine salts and amino acid salts include salts of amines such as triethanolamine, and salts of amino acids such as glutamic acid. In addition, salts of hyaluronic acid, chondroitin sulfate, and the like, aluminum zirconium glycine complexes, and further neutral salts of acids and alkalis used in cosmetic formulations can also be used. In particular, sodium chloride is preferred in terms of solubility, feeling of use, and suppression of foaming. When a large amount is added, it may inhibit the swelling of water-soluble polymers.

[0082] Antioxidants The antioxidant is not particularly limited, but examples thereof include carotenoids, ascorbic acid and its salts, ascorbyl stearate, tocopherol, tocopherol acetate, tocopherol, pt-butylphenol, butylhydroxyanisole, dibutylhydroxytoluene, phytic acid, ferulic acid, thiotaurine, hypotaurine, sulfite, erythorbic acid and its salts, chlorogenic acid, epicatechin, epigallocatechin, epigallocatechin gallate, apigenin, campherol, myricetin, quercetin, etc. The antioxidant may be used alone or in combination of two or more kinds.

[0083] pH adjuster Examples of pH adjusters include lactic acid, citric acid, glycolic acid, succinic acid, tartaric acid, dl-malic acid, potassium carbonate, sodium hydrogen carbonate, and ammonium hydrogen carbonate.

[0084] Chelating agents Examples of the chelating agent include alanine, edetic acid sodium salt, sodium polyphosphate, sodium metaphosphate, phosphoric acid, and the like.

[0085] · Cooling agent Cooling agents include L-menthol, camphor, menthyl lactate, and the like.

[0086] Anti-inflammatory Anti-inflammatory agents include allantoin, glycyrrhizic acid and its salts, glycyrrhetinic acid and stearyl glycyrrhetinate, tranexamic acid, azulene, and the like.

[0087] ·Skin-beautifying ingredients Examples of skin-beautifying ingredients include whitening agents such as placenta extract, arbutin, glutathione, and saxifrage extract; cell activators such as royal jelly, photosensitizers, cholesterol derivatives, and calf blood extract; rough skin improving agents; blood circulation promoters such as nonylic acid valenylamide, nicotinic acid benzyl ester, nicotinic acid β-butoxyethyl ester, capsaicin, zingerone, cantharides tincture, ichthammol, caffeine, tannic acid, α-borneol, tocopherol nicotinate, inositol hexanicotinate, cyclandelate, cinnarizine, tolazoline, acetylcholine, verapamil, cepharanthine, and γ-oryzanol; skin astringents such as zinc oxide and tannic acid; and antiseborrheic agents such as sulfur and thianthrol.

[0088] Vitamins Vitamins include vitamin A oil, retinol, retinol acetate, retinol palmitate, and other vitamin A derivatives, riboflavin, riboflavin butyrate, flavin adenine nucleotide, and other vitamin B2 derivatives, pyridoxine hydrochloride, pyridoxine dioctanoate, pyridoxine tripalmitate, and other vitamin B6 derivatives, vitamin B12 and its derivatives, vitamin B15 and its derivatives, and other vitamin B derivatives, L-ascorbic acid, L-ascorbic acid dipalmitate, sodium L-ascorbic acid 2-sulfate, and dipotassium L-ascorbic acid phosphate diester. vitamin C such as ergocalciferol and cholecalciferol; vitamin E such as α-tocopherol, β-tocopherol, γ-tocopherol, dl-α-tocopherol acetate, dl-α-tocopherol nicotinate, and dl-α-tocopherol succinate; nicotinic acids such as nicotinic acid, benzyl nicotinate, and nicotinamide; vitamin H, vitamin P, pantothenic acids such as calcium pantothenate, D-pantothenyl alcohol, pantothenyl ethyl ether, and acetyl pantothenyl ethyl ether; and biotin.

[0089] Amino acids Examples of amino acids include glycine, valine, leucine, isoleucine, serine, threonine, phenylalanine, arginine, lysine, aspartic acid, glutamic acid, cystine, cysteine, methionine, and tryptophan.

[0090] ·Nucleic acid The nucleic acid includes deoxyribonucleic acid and the like.

[0091] ·hormone Hormones include estradiol, ethenyl estradiol, and the like.

[0092] ·Inclusion compounds An example of the inclusion compound is cyclodextrin. EXAMPLES

[0093] The present invention will be specifically described below with reference to examples and comparative examples, but the present invention is not limited to the following examples. In the following examples, unless otherwise specified, "%" in the composition indicates mass %, ratio indicates mass ratio, and the amount described in the product name is the amount of the blended product.

[0094] [Whether or not aqueous dispersants can be dissolved] When the following components are mixed in water and BG at 20% and then allowed to stand for 1 hour at 25°C, a transparent to semi-transparent state without any boundary is rated as "dissolved", and a cloudy state or separation into two layers is rated as "not dissolved". A "transparent to semi-transparent state" means that the mixed liquid is filled into a 1 cm thick cell and the total light transmittance measured according to the method described in JIS K7361-1:1997 is 50% or more.

[0095] [Table 1]

[0096] [Example] A slurry was prepared using a bead mill based on the composition shown in Table 2 below, to obtain an aqueous dispersion. The dispersibility of the obtained aqueous dispersion was evaluated according to the following evaluation criteria. The results are also shown in the table.

[0097] [Can aqueous dispersions be prepared?] A: A dispersion can be created (temporary settling is observed, but continued stirring will result in a uniform dispersion). D: Dispersion cannot be produced An "A" was considered a pass.

[0098] [Long-term stability evaluation] 75 g of the aqueous dispersion was placed in a 50 mL container and stored in a thermostatic chamber at 25° C. for one month, and the long-term stability was evaluated according to the following criteria. [Judgment criteria] Viscosity change rate (%) = [{(initial viscosity) - (viscosity after 1 month)} / (initial viscosity)] x 100 Therefore, the following criteria are used for judgment. A: Viscosity change rate after one month is less than 20% B: Viscosity change rate after one month is 20% or more but less than 30% C: Viscosity change rate after one month is 30% or more D: There is floating matter in the upper layer. A grade of "C" or above was considered a pass.

[0099] [Water resistance evaluation] The water resistance when the aqueous dispersion was applied was evaluated according to the following evaluation criteria. The results were judged according to the following criteria. [Judgment criteria] A: It does not come off even if it is exposed to running water for more than one minute. B: Does not come off even when exposed to running water for 30 seconds or more but less than 1 minute C: When exposed to running water, it falls off in 10 to 30 seconds. D: Falls off in less than 10 seconds when exposed to running water A grade of "C" or above was considered a pass.

[0100] [Usability evaluation] The feel of the product when applied (non-stickiness) was evaluated by 10 expert panelists according to the following criteria. The results were judged based on the average of the 10 panelists' ratings and in accordance with the following criteria. [Evaluation Criteria] 5 points: very good 4 points: Good 3 points: normal 2 points: slightly poor 1 point: Defective [Judgment criteria] A: Average score is 4.5 or higher B: Average score is between 3.5 and 4.5 points C: Average score is between 2.5 and 3.5 points D: Average score is less than 2.5 points A grade of "C" or above was considered a pass.

[0101] [Table 2]

[0102] [Table 3]

[0103] (Note 1) Fine particles of titanium dioxide (labeled as "Titanium Dioxide") coated with hydrated silica (labeled as "INCI: Hydrated Silica") and further treated with hydrogen dimethicone (labeled as "INCI: Hydrogen Dimethicone"). Number-average primary particle size measured by image analysis of transmission electron microscope photographs: 15 nm (average diameter of 200 particles measured by image analysis of transmission electron microscope photographs) (Note 2) Fine particles of titanium dioxide (labeled as "INCI: Titanium Dioxide") treated with stearic acid (labeled as "Stearic Acid" in Japanese). (Note 3) Fine particles of titanium dioxide coated with hydrated silica (labeled as INCI: Hydrated Silica) (labeled as INCI: Titanium Dioxide)

[0104] As is clear from Table 2, all of the examples of the present invention provided aqueous dispersions (slurries) that were well dispersed in an aqueous medium. On the other hand, in Comparative Example 1, which did not contain the (a) component, no dispersion could be produced, and in Comparative Example 2, a dispersion could be produced but was poor in long-term stability, water resistance, and usability. In Comparative Example 4, which did not contain the (b) component, Comparative Example 3, which contained 70% or more of the (a) component, and Comparative Examples 5 to 7 and 9 to 11, which did not contain the (c) component, no dispersion could be produced, and in Comparative Example 8, a dispersion could be produced but was poor in water resistance and usability. The number average primary particle diameter of the fine titanium dioxide particles used in the following examples was in the range of 8 to 200 nm.

[0105] [Example 11, Comparative Example 12] An O / W cream was prepared according to the formulation shown in Table 4 below. [Manufacturing method] [Example 11] A: Components 5 to 12 were mixed. B: Component 4 was added to the composition obtained in A and emulsified. C: Component 1 was added to the emulsion obtained in B and mixed to obtain an O / W cream. [Comparative Example 12] A: Components 5 to 12 were mixed. B: Components 2 to 4 were mixed using a three-roll mill. C: The composition obtained in B was added to the composition obtained in A and emulsified to obtain an O / W cream.

[0106] [Usability evaluation, water resistance evaluation] The feel when applied (non-stickiness) and water resistance of the cosmetic were evaluated in the same manner as in the evaluation of the aqueous dispersion described above.

[0107] [Transparency evaluation, usability evaluation] The transparency during application and the feeling of use (non-stickiness) were evaluated by 10 expert panelists according to the following criteria. The results were judged according to the following criteria based on the average of the 10 panelists. [Evaluation Criteria] 5 points: very good 4 points: Good 3 points: normal 2 points: slightly poor 1 point: Defective [Judgment criteria] A: Average score is 4.5 or higher B: Average score is between 3.5 and 4.5 points C: Average score is between 2.5 and 3.5 points D: Average score is less than 2.5 points A grade of "C" or above was considered a pass.

[0108] [Table 4] (Note 1) Fine particles of titanium dioxide (labeled as "Titanium Dioxide") coated with hydrated silica (labeled as "INCI: Hydrated Silica") and further treated with hydrogen dimethicone (labeled as "INCI: Hydrogen Dimethicone"). The number-average primary particle diameter measured by image analysis of transmission electron micrographs was 15 nm (average diameter of 200 particles measured by image analysis of transmission electron micrographs).

[0109] As is clear from Table 4, the cosmetic of Example 11 using the dispersion of the present invention was highly transparent when applied, had a good non-sticky feel, and was confirmed to be water resistant. On the other hand, Comparative Example 12, which contained the essential components (a) to (d) of the present invention but was not formulated as the aqueous dispersion of the present invention, was poor in all evaluations.

[0110] [Example 12, Comparative Example 13] A W / O cream was prepared according to the formulation shown in Table 5 below.

[0111] [Manufacturing method] [Example 12] A: Components 4 to 8 were mixed. B: Components 9 to 13 were mixed. C: Component 1 was added to the composition obtained in B and mixed. D: The composition obtained in C was added to the composition obtained in A and emulsified to obtain a W / O cream. [Comparative Example 13] A: Components 5 to 8 were mixed. B: Components 9 to 13 were mixed. C: Components 2 to 4 were mixed using a three-roll mill, and then mixed with the composition obtained in A. D: The composition obtained in B was added to the composition obtained in C and emulsified to obtain a W / O cream.

[0112] [Table 5] (Note 1) Fine particles of titanium dioxide (labeled as "Titanium Dioxide") coated with hydrated silica (labeled as "INCI: Hydrated Silica") and further treated with hydrogen dimethicone (labeled as "INCI: Hydrogen Dimethicone"). Number-average primary particle size measured by image analysis of transmission electron microscope photographs: 15 nm (average diameter of 200 particles measured by image analysis of transmission electron microscope photographs) (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of approximately 70-80% by mass of dimethicone (6cs) + approximately 20-30% by mass of (dimethicone / polyglycerin-3) crosspolymer (Note 3) Shin-Etsu Chemical Co., Ltd.: A mixture of about 80-90% by mass of dimethicone (6cs) + about 10-20% by mass of (dimethicone / vinyl dimethicone) crosspolymer

[0113] The cosmetic of Example 12, which used the dispersion of the present invention, was highly transparent when applied, had a good feeling of use without stickiness, and was confirmed to be water resistant. On the other hand, Comparative Example 13, which contained the essential components (a) to (d) of the present invention but was not formulated as the aqueous dispersion of the present invention, was poor in all evaluations.

[0114] [Example 13] Oil-in-water sunscreen Composition % 1.KSG-15 (Note 1) 8.0 2.KSG-16 (Note 2) 19.0 3.KSG-45 (Note 3) 5.0 4. Cyclopentasiloxane 10.0 5. BG 3.0 6.KF-6100 (Note 4) 0.6 7.KF-6104 (Note 5) 0.3 8. (Acryloyldimethyltaurate ammonium / VP) copolymer Aqueous solution (Note 6) 13.0 9. (Acrylamide / sodium acryloyldimethyltaurate) copolymer / Isohexadecane / Polysorbate 80 aqueous solution (Note 7) 0.6 10. Sodium chloride 1% solution 8.0 11.Wednesday 12.5 12. Silicone-treated titanium dioxide microparticles (Note 8) 5% BG1% Polyglyceryl-3 Disiloxane Dimethicone (HLB10) 0.7% ·Water 3.3% 10.0 13. Silicone-treated zinc oxide microparticles (Note 9) 5% BG1% Polyglyceryl-3 Disiloxane Dimethicone (HLB10) 0.7% ·Water 3.3% 10.0 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 90-96% by mass of cyclopentasiloxane + 4-10% by mass of (dimethicone / vinyl dimethicone) crosspolymer (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 70-80% by mass of dimethicone + 20-30% by mass of (dimethicone / vinyl dimethicone) crosspolymer (Note 3) Shin-Etsu Chemical Co., Ltd.: A mixture of 60-70% by mass of coconut alkyl caprylate / caprate and 30-40% by mass of dimethicone / vinyl dimethicone crosspolymer. (Note 4) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 disiloxane dimethicone (Note 5) Shin-Etsu Chemical Co., Ltd.: Polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Note 6) Clariant: Aristoflex AVC (Note 7) Seppic: Simulgel 600 (Note 8) Fine particles of titanium dioxide (labeled as "Titanium Dioxide") coated with hydrated silica (labeled as "INCI: Hydrated Silica") and further treated with triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone (INCI). (Note 9) Shin-Etsu Chemical Co., Ltd.: AES-3083 (triethoxycaprylylsilane) treatment

[0115] (Manufacturing method) A: Components 1 to 4 were mixed uniformly. B: Components 5 to 11 were mixed uniformly. C: Components 12 and 13 were uniformly dispersed in a bead mill. D: A was added to B and emulsified, and C was added and dispersed uniformly. The oil-in-water sunscreen thus obtained was highly stable, highly transparent, non-sticky, and had a good feel when used, and was excellent in water resistance. Components 12 and 13 were highly stable and easy to handle and dispense.

[0116] [Example 14] Oil-in-water base cream Composition % 1.Water remainder 2. Glycerin 3.0 3. Microcrystalline Wax 3.0 4. Xanthan gum 0.2 5. Pentylene glycol 2.0 6. BG 5.0 7. Hydrous silica / hydrogen dimethicone treated fine titanium dioxide particles 5.0 8. BG 1.0 9. Polyglyceryl-3 Polydimethylsiloxyethyl Dimethicone (HLB12) (Note 1) 0.1 10. Polyglyceryl-3 Disiloxane Dimethicone (HLB10) 0.7 11.Wednesday 3.3 12. Sucrose palmitate 0.2 13. Sorbitan stearate 3.0 14. PEG-60 Glyceryl Isostearate 0.5 15. Behenyl alcohol 0.5 16. Ethylhexyl palmitate 3.0 17.KSP-101 (Note 2) 3.0 18. Triethylhexanoin 6.0 19. Polyhydroxystearic acid 0.5 20.KTP-09W (Note 3) Appropriate amount 21.KTP-09R (Note 3) Appropriate amount 22.KTP-09Y (Note 3) Appropriate amount 23.KTP-09B (Note 3) Appropriate amount 24. Polysorbate 60 0.3 25. (Hydroxyethyl acrylate / Sodium acryloyldimethyltaurate) コポリマー(Note 4) 0.6 Total 100.0 (Note 1) Dissolves in water and BG (Note 2) Shin-Etsu Chemical Co., Ltd.: (vinyl dimethicone / methicone silsesquioxane) crosspolymer (Note 3) Shin-Etsu Chemical Co., Ltd.: KF-9909 treated colored inorganic pigment, W: white, R: red, Y: yellow, B: black (Note 4) SEPPIC: SIMULGEL EG

[0117] (Manufacturing method) A: Components 7 to 11 were uniformly dispersed in a bead mill. B: Components 1 to 6 were mixed uniformly, and then A was mixed and made uniform. C: Components 12 to 16 were heated and dissolved, and component 17 was mixed in and homogenized. D: Ingredients 18 to 23 were mixed and roll processed. E: The material obtained in the above step D was added to the material obtained in the above step C and mixed uniformly. F: The heated product obtained in the above step E was added to the heated product obtained in the above step B, and emulsified uniformly. G: The product obtained in the above step F was cooled to room temperature, after which ingredients 24 and 25 were added and mixed uniformly. H: The product obtained in step G above was defoamed and then filled into a container to obtain an oil-in-water base cream. The oil-in-water base cream thus obtained was highly stable, highly transparent, non-sticky, and had excellent water resistance. The dispersion obtained in A was stable and easy to handle and pour.

[0118] [Example 15] Aqueous gel Composition % 1. Dispersion of Example 4 5.0 2. Ethanol 3.5 3. BG 4.0 4. Glycerin 2.0 5. (Acryloyldimethyltaurate ammonium / VP) copolymer 0.2 6. Xanthan gum 0.2 7.KSP-100W (Note 1) 1.0 8. Phenoxyethanol 0.3 9. Water Residue Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: (vinyl dimethicone / methicone silsesquioxane) crosspolymer

[0119] (Manufacturing method) A: Components 1 and 2 were mixed uniformly. B: Components 3 to 9 were mixed uniformly. C: The material obtained in the above step A was added to the material obtained in the above step B and mixed uniformly. D: The product obtained in the above step C was degassed and then filled into a container to obtain an aqueous gel. The aqueous gel obtained in this manner had excellent freshness when applied, high stability, high transparency, a good feeling of use without stickiness, and excellent water resistance. Component 1 had excellent stability and was easy to handle and pour.

[0120] [Example 16] Oil-in-water sunscreen emulsion Composition % 1. Hydrous silica / hydrogen dimethicone treated fine titanium dioxide particles 7.5 2. Ethanol 0.5 3.BG 1.0 4.KS-66 (Note 1) 0.001 5.Wednesday 4.999 6. Polyglyceryl-3 Disiloxane Dimethicone (HLB10) 1.2 7. Ethylhexylglycerin 0.1 8. Ethanol 9.5 9. BG 5.0 10. Sodium acrylate, sodium acryloyldimethyltaurate Copolymer composition (Note 2) 2.5 11. Water remainder 12.KF-7312J (Note 3) 1.0 13.KF-56A (Note 4) 3.0 14.KSG-016F (Note 5) 1.0 15. Cetanol 2.0 16. Ethylhexyl methoxycinnamate 5.0 17. Diethylamino hydroxybenzoyl hexyl benzoate 1.0 18. Polyoxyethylene (60) hydrogenated castor oil 1.0 19.KF-6011 (Note 6) 0.5 20.Token 0.05 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: Simethicone (Note 2) SEPPIC: SIMULGEL EG (Note 3) Shin-Etsu Chemical Co., Ltd.: 50% by weight trimethylsiloxysilicate dissolved in cyclopentasiloxane (Note 4) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (Note 5) Shin-Etsu Chemical Co., Ltd.: A mixture of 70-80% by mass of dimethicone + 20-30% by mass of (dimethicone / vinyl dimethicone) crosspolymer (Note 6) Shin-Etsu Chemical Co., Ltd.: PEG-11 methyl ether dimethicone

[0121] (Manufacturing method) A: Components 1 to 7 were uniformly dispersed using a bead mill. B: Ingredients 8 to 11 were heated to 85°C, and A was added and mixed uniformly. C: Ingredients 12 to 20 were heated to 85°C and mixed uniformly. D: C was added to B and emulsified at 85°C, then cooled slowly with stirring to obtain an oil-in-water sunscreen emulsion. The oil-in-water sunscreen emulsion obtained in this manner had high stability, high transparency, a good non-sticky feel when used, and excellent water resistance. The dispersion obtained in A had excellent stability and was easy to handle and pour.

[0122] [Example 17] Oil-in-water base Composition % 1.KP-545(Note 1) 3 2.KSG-19 (Note 2) 5 3.KF-56A (Note 3) 5 4. Cyclopentasiloxane 10 5. Hydrous silica / hydrogen dimethicone treated fine titanium dioxide particles 7.2 6. BG 1.8 7. Polyglyceryl-3 Disiloxane Dimethicone (HLB10) 1.6 8.Wed 20 9. BG10 10. Betaine 1 11.KF-6043 (Note 4) 1.5 12. Sodium acrylate, sodium acryloyldimethyltaurate Copolymer composition (Note 5) 1 13. (Acrylates / Alkyl acrylate (C10-30)) Cross Polymer (2% aqueous solution) 20 14. Arginine (10% aqueous solution) 15. Bisabolol 0.1 16. Ethylhexylglycerin 0.1 17.EDTA-2Na (10% aqueous solution) 0.1 18. Water Residue Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: (Acrylates / Dimethicone) Copolymer 30% by weight dissolved in cyclopentasiloxane (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 80-90% by mass of dimethicone + 10-20% by mass of (dimethicone / vinyl dimethicone) crosspolymer (Note 3) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (Note 4) Shin-Etsu Chemical Co., Ltd.: PEG-10 Dimethicone (Note 5) SEPPIC: SIMULGEL EG

[0123] (Manufacturing method) A: Components 1 to 4 were mixed uniformly. B: Components 5 to 8 were uniformly dispersed using a homomixer. C: Ingredients 9 to 18 and B were mixed uniformly. D: A was added to C and emulsified to obtain an O / W base. The oil-in-water base thus obtained was highly stable, highly transparent, non-sticky, and had excellent water resistance. The dispersion obtained in A was stable and easy to handle and pour.

[0124] [Example 18] Oil-in-water liquid foundation Composition % 1. Stearic acid 1.0 2. Behenyl alcohol 0.4 3. Glyceryl stearate 0.3 4. Mineral oil 10.0 5. Glyceryl trioctanoate 5.0 6.KP-561P (Note 1) 3.0 7. Sorbitan Sesquioleate 0.5 8. Sorbitan monooleate 1.0 9. Acrylates Copolymer 2.2 10. Triethanolamine 1.0 11.KF-6013 (Note 2) 0.2 12. Alkyl POE palmityl ether phosphate 0.1 13.POE hydrogenated castor oil 0.5 14. Silicone-treated titanium dioxide (Note 3) 8.5 15. Silicone-treated red iron oxide (Note 3) 0.4 16. Silicone-treated yellow iron oxide (Note 3) 1.0 17. Silicone-treated black iron oxide (Note 3) 0.1 18. Hydrous silica / hydrogen dimethicone treated fine titanium dioxide particles 5.0 19. DPG 3.0 20. Polyglyceryl-3 Disiloxane Dimethicone (HLB10) 0.7 21.Wednesday 3.3 22. BG 7.0 23. Preservatives (appropriate amount) 24.Fragrance (appropriate amount) 25. Water Residue Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: (Acrylates / Stearyl Acrylate / Dimethicone Methacrylate) Copolymer (Note 2) Shin-Etsu Chemical Co., Ltd.: PEG-9 Dimethicone (Note 3) Shin-Etsu Chemical Co., Ltd.: Triethoxycaprylylsilane treatment

[0125] (Manufacturing method) A: Ingredients 11 to 13 were mixed with a portion of 22, ingredients 14 to 17 were added, dispersed uniformly, and heated. B: Components 1 to 8 were mixed and heated to dissolve uniformly. C: Ingredients 9 to 10, the remainder of 22, 23 and 25 were mixed and heated. D: Components 18 to 21 were dispersed using a disperser. E: While stirring, B was added to C and emulsified, A was added, and then D and component 24 were added to obtain an oil-in-water liquid foundation. The oil-in-water liquid foundation obtained in this manner had high stability, high transparency, a good feeling of use without stickiness, and excellent water resistance. The dispersion obtained in D had excellent stability and was easy to handle and pour.

[0126] [Example 19] Water-in-oil sunscreen emulsion Composition % 1.KSG-210 (Note 1) 2.0 2.KSG-790 (Note 2) 1.0 3.KSG-15 (Note 3) 2.0 4.KF-6028 (Note 4) 1.0 5. Dimethicone 6CS 3.0 6.KF-4418 (Note 5) 2.0 7. Cyclopentasiloxane 5.0 8. Isotridecyl isononanoate 4.0 9.SPD-T5 (Note 6) 5.0 10.SPD-Z5 (Note 7) 15.0 11. SPD-Z7L (Note 8) 20.0 12. Sodium citrate 0.2 13. Sodium chloride 0.5 14. Dispersion of Example 5 20.0 15. Preservatives (appropriate amount) 16.Fragrance (appropriate amount) 17. Water Residue Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 70-80% by mass of dimethicone + 20-30% by mass of (dimethicone / (PEG-10 / 15)) crosspolymer (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 65-75% caprylyl methicone by mass and 25-35% (dimethicone / polyglycerin-3) crosspolymer by mass. (Note 3) Shin-Etsu Chemical Co., Ltd.: A mixture of 90-96% by mass of cyclopentasiloxane + 4-10% by mass of (dimethicone / vinyl dimethicone) crosspolymer (Note 4) Shin-Etsu Chemical Co., Ltd.: PEG-9 polydimethylsiloxyethyl dimethicone (Note 5) Shin-Etsu Chemical Co., Ltd.: Caprylyl methicone (Note 6) Shin-Etsu Chemical Co., Ltd.: Dispersion of 40% by weight of fine titanium dioxide in cyclopentasiloxane (Note 7) Shin-Etsu Chemical Co., Ltd.: 60% by weight zinc oxide fine particle dispersion in cyclopentasiloxane (Note 8) Shin-Etsu Chemical Co., Ltd.: Dimethicone dispersion containing 60% by weight of fine zinc oxide particles

[0127] (Manufacturing method) A: Components 1 to 8 were mixed uniformly. B: Ingredients 12 to 17 were mixed uniformly. C: With stirring, A was added to B and emulsified, and ingredients 9 to 11 were added to obtain a water-in-oil sunscreen emulsion. The water-in-oil sunscreen emulsion obtained in this manner was highly stable, highly transparent, non-sticky, and had excellent water resistance. Component 14 was stable and easy to handle and dispense.

[0128] [Example 20] Oil-in-water sunscreen emulsion Composition % 1. Hydrous silica / hydrogen dimethicone treated fine titanium dioxide particles 10 2. BG 2 3. Polyglyceryl-3 Disiloxane Dimethicone (HLB10) 1.4 4.KM-72 (Note 1) 0.001 5.Wednesday 6.599 6. Cyclopentasiloxane 10 7.KF-56A (Note 2) 3 8. Cetanol 0.5 9. Polyoxyethylene sorbitan monooleate 2.5 10. Glyceryl stearate (SE) 0.5 11.KF-6011 (Note 3) 1 12. DPG 6 13. BG6 14. Carboxyvinyl polymer 0.3 15. Acrylic polymer compounds 0.3 16. Methylparaben 0.2 17. Phenoxyethanol 0.3 18.EDTA-2Na appropriate amount 19.Water remainder 20. 10% sodium hydroxide solution (appropriate amount) 21.KM-116 (Note 4) 2 Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: Simethicone Emulsion (Note 2) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (Note 3) Shin-Etsu Chemical Co., Ltd.: PEG-11 methyl ether dimethicone (Note 4) Shin-Etsu Chemical Co., Ltd.: (Dimethicone / vinyl dimethicone) crosspolymer emulsion

[0129] (Manufacturing method) A: Components 1 to 5 were uniformly dispersed using a high-pressure disperser. B: Components 6 to 8 were mixed uniformly. C: Ingredients 9 to 19 and A were mixed uniformly. D: Add B to C and emulsify, then add ingredient 20 and mix uniformly. E: Component 21 was added to D and mixed uniformly. The oil-in-water sunscreen emulsion obtained in this manner had high stability, high transparency, a good non-sticky feel when used, and excellent water resistance. The dispersion obtained in A had excellent stability and was easy to handle and pour.

[0130] [Example 21] Oil-in-water sunscreen emulsion Composition % 1.TSPL-30-D5 (Note 1) 3 2.KSG-18A (Note 2) 5 3.KF-56A (Note 3) 5 4. Cyclopentasiloxane 10 5. Hydrous silica / hydrogen dimethicone treated fine titanium dioxide particles 10 6. BG 2 7. Polyglyceryl-3 Disiloxane Dimethicone (HLB10) 1.6 8.Wed 20 9. Sodium chloride 0.2 10. BG10 11.KF-6043 (Note 4) 1.5 12. Sodium acrylate, sodium acryloyldimethyltaurate Copolymer composition (Note 5) 1 13. (Acrylates / C10-30 alkyl acrylate) crosspolymer (2% aqueous solution) 20 14. Arginine (10% aqueous solution) 15.EDTA-2Na (10% aqueous solution) 0.1 16. Water Residue Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: Tri(trimethylsiloxy)silylpropylcarbamic acid pullulan 30% dissolved in cyclopentasiloxane (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 80-90% by mass of diphenylsiloxyphenyl trimethicone + 10-20% by mass of (dimethicone / phenylvinyl dimethicone) crosspolymer. (Note 3) Shin-Etsu Chemical Co., Ltd.: Diphenylsiloxyphenyl trimethicone (Note 4) Shin-Etsu Chemical Co., Ltd.: PEG-10 Dimethicone (Note 5) SEPPIC: SEPILIFE NUDE

[0131] (Manufacturing method) A: Components 1 to 4 were mixed uniformly. B: Components 5 to 9 were dispersed uniformly using a paint shaker. C: Components 10 to 16 were mixed uniformly. D: A was added to C and emulsified, then B was mixed in to obtain a sunscreen emulsion. The sunscreen emulsion obtained in the above manner had high stability, high transparency, a good feeling of use without stickiness, and excellent water resistance. The dispersion obtained in B had excellent stability and was easy to handle and pour.

[0132] [Example 22] Water-based sunscreen mist Composition % 1. Dispersion of Example 4 15.0 2. Ethanol 5.0 3. BG 4.0 4. Glycerin 2.0 5. Sodium citrate 0.1 6. Citric acid 0.02 7.Fragrance 0.2 8. Ethylhexylglycerin 0.1 9. Water Residue Total 100.0

[0133] (Manufacturing method) A: Mix ingredients 2, 3, 4, 7, and 8 evenly. B: Mix ingredients 1, 5, 6, and 9 evenly. C: Add the material obtained in the above step A to the material obtained in the above step B and mix uniformly. D: The product obtained in step C above was filled into a container to obtain an aqueous sunscreen mist. The water-based sunscreen mist obtained in this manner had excellent freshness when applied, high stability, high transparency, a good non-sticky feel when used, and excellent water resistance. Component 1 was excellent in stability and easy to handle and apply.

[0134] [Example 23] W / O liquid foundation Composition % 1.KSG-210 (Note 1) 3.0 2.KSG-15 (Note 2) 5.0 3.KF-6038 (Note 3) 3.0 4. Dimethicone 6CS 13.8 5. Ethylhexyl methoxycinnamate 5.0 6. Diethylaminohydroxybenzoylbenzoic acid 2.0 7.KF-6115 (Note 4) 1.5 8. Silicone-treated titanium dioxide (Note 5) 8.5 9. Silicone-treated red iron oxide (Note 5) 0.4 10. Silicone-treated yellow iron oxide (Note 5) 1.0 11. Silicone-treated black iron oxide (Note 5) 0.1 12. Sodium citrate 0.2 13. Sodium chloride 0.5 14.Hydrogen dimethicone treatment with hydrated silica, aluminum hydroxide Titanium dioxide particles 10 15. BG 2 16. Polyglyceryl-3 Disiloxane Dimethicone (HLB10) 1.6 17.Wed 20 18. Methylparaben (appropriate amount) 19.Fragrance (appropriate amount) 20. BG 2 21. Water Residue Total 100.0 (Note 1) Shin-Etsu Chemical Co., Ltd.: A mixture of 70-80% by mass of dimethicone + 20-30% by mass of (dimethicone / (PEG-10 / 15)) crosspolymer (Note 2) Shin-Etsu Chemical Co., Ltd.: A mixture of 90-96% by mass of cyclopentasiloxane + 4-10% by mass of (dimethicone / vinyl dimethicone) crosspolymer (Note 3) Shin-Etsu Chemical Co., Ltd.: Lauryl PEG-9 Polydimethylsiloxyethyl Dimethicone (Note 4) Shin-Etsu Chemical Co., Ltd.: Lauryl polyglyceryl-3 polydimethylsiloxyethyl dimethicone (Note 5) Shin-Etsu Chemical Co., Ltd.: Hydrogen dimethicone treatment

[0135] (Manufacturing method) A: A portion of ingredients 4 and 7 to 11 were mixed uniformly in a roll mill. B: Components 14 to 17 were dispersed uniformly using a paint shaker. C: Components 1 to 6 were mixed uniformly, and A was added and mixed uniformly. D: Mix 18 to 20 uniformly, add 21, 12, 13 and B and mix uniformly. E: D was added to C and emulsified to obtain a W / O liquid foundation. The W / O liquid foundation obtained in this manner was highly stable, highly transparent, non-sticky, and had excellent water resistance. The dispersion obtained in B was stable and easy to handle and pour.

Claims

1. (a) Hydrophobized titanium oxide fine particles: 10 to 70% by mass, in which titanium oxide particles selected from hydrous silica-coated titanium oxide particles and hydrous silica and aluminum hydroxide-coated titanium oxide particles are hydrophobized with a silicone selected from triethoxycaprylylsilane, dimethyl silicone, hydrogen dimethicone, triethoxysilylethyl polydimethylsiloxyethyl dimethicone, and triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone, and have a number-average primary particle size of 8 to 200 nm as measured by an image analysis method of a transmission electron microscope photograph; (b) one or more selected from BG (display name), DPG (display name), and glycerin: 1.0 to 30% by mass, (c) polyglycerin-modified silicone (excluding organopolysiloxanes having a (poly)glycerin group and a polyoxyalkylene group) that is soluble in the component (b): 1.0 to 20 mass %, and (d) Water: 8 to 82% by mass An aqueous dispersion comprising:

2. 2. The aqueous dispersion according to claim 1, wherein the component (a) is a hydrophobized fine titanium oxide particle obtained by subjecting hydrous silica-coated titanium oxide particles to a hydrophobization treatment.

3. 2. The aqueous dispersion according to claim 1, wherein the silicone in component (a) is selected from the group consisting of triethoxycaprylylsilane, hydrogen dimethicone, triethoxysilylethyl polydimethylsiloxyethyl dimethicone, and triethoxysilylethyl polydimethylsiloxyethylhexyl dimethicone.

4. 2. The aqueous dispersion according to claim 1, wherein the silicone in component (a) is hydrogen dimethicone.

5. 2. The aqueous dispersion according to claim 1, wherein the content of the component (b) in the aqueous dispersion is 7 to 15% by mass.

6. 2. The aqueous dispersion according to claim 1, wherein the component (c) is a component that is insoluble in the component (d).

7. 2. The aqueous dispersion according to claim 1, wherein the content of the component (d) in the aqueous dispersion is 28 to 82% by mass.

8. 2. The aqueous dispersion according to claim 1, wherein the mass ratio (c) / (b) of the content of the component (c) to the content of the component (b) is 0.2 to 0.

9.

9. 2. The aqueous dispersion according to claim 1, wherein the total content of the components (a), (b), (c) and (d) is 90% by mass or more based on the total amount of the aqueous dispersion.

10. 2. The aqueous dispersion according to claim 1, wherein component (c) is a polyglycerin-modified silicone having a chemical structure in which the silicone main chain is modified by block or graft type using polyglycerin.

11. 2. The aqueous dispersion according to claim 1, wherein component (c) is a polyglycerin-modified silicone having a silicone main chain with a branched silicone chain.

12. 2. The aqueous dispersion according to claim 1, wherein the HLB value of component (c) is 3 or more and less than 17.

13. A cosmetic preparation containing the aqueous dispersion according to any one of claims 1 to 12.

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