Manufacturing method for circuit connection structure, adhesive film for circuit connection, and circuit connection structure

Abstract

To provide a manufacturing method for a circuit connection structure, by which a circuit connection structure connected with sufficient adhesion strength and having excellent connection reliability is obtained while the connection resistance value between opposite electrodes is reduced.SOLUTION: A manufacturing method for a circuit connection structure includes the step of having an adhesive film 10 for circuit connection containing conductive particles 4 held between a first circuit member 21 including a first electrode 22 and a second circuit member 24 including a second electrode 25 and thermally crimping the first circuit member 21 and the second circuit member 24, thereby electrically connecting the first electrode 22 and the second electrode 25 to each other. The adhesive film 10 for the circuit connection includes a first adhesive layer 1 containing the conductive particle 4 and a first thermosetting resin component, and a second adhesive layer 2 containing a second thermosetting resin component. The second thermosetting resin component includes a cation polymerizable compound and a thermal cation polymerization initiator, and a cation stabilizer that reacts with a cation species generated by thermal decomposition of the thermal cation polymerization initiator.SELECTED DRAWING: Figure 3

Description

[Technical field]

[0001] The present disclosure relates to a method for producing a circuit connection structure, an adhesive film for circuit connection, and a circuit connection structure. [Background technology]

[0002] Conventionally, liquid crystal display panels, organic EL panels, etc. have been used as various display means for televisions, PC monitors, mobile phones, smartphones, etc. In such display devices, from the viewpoints of fine pitch, light weight and thinness, so-called COG (chip on glass) mounting is adopted in which a driving IC is mounted directly on the glass substrate of the display panel.

[0003] In a liquid crystal display panel in which the COG mounting method is adopted, for example, a semiconductor element such as a liquid crystal driving IC is connected on a transparent substrate (such as a glass substrate) having a plurality of transparent electrodes (such as ITO (indium tin oxide)). As an adhesive material for connecting the electrode terminals of the semiconductor element and the transparent electrodes, an anisotropically conductive circuit connection adhesive film in which conductive particles are dispersed in the adhesive is used. For example, when mounting a liquid crystal driving IC as a semiconductor element, the liquid crystal driving IC has a plurality of electrode terminals corresponding to the transparent electrodes on its mounting surface, and the liquid crystal driving IC is thermocompression-bonded onto the transparent substrate via the anisotropically conductive circuit connection adhesive film, whereby the electrode terminals and the transparent electrodes are connected to obtain a circuit connection structure.

[0004] In recent years, displays (flexible displays) having curved surfaces, such as POELD (Plasitic Organic Electro-Luminescence Diode) displays, have been proposed. In such flexible displays, flexible plastic substrates (polyimide substrates, etc.) are used as substrates instead of glass substrates, and various electronic components such as driving ICs are also mounted on the plastic substrates. As a method of such mounting, COP (chip on plastic) mounting using an adhesive film for circuit connection having anisotropic conductivity has been considered (for example, see Patent Document 1). [Prior art documents] [Patent documents]

[0005] [Patent Document 1] JP 2016-054288 A Summary of the Invention [Problem to be solved by the invention]

[0006] In current-driven OELDs, there is a demand for a lower connection resistance between opposing electrodes, while in the case of mounting using an adhesive film for circuit connection with anisotropic conductivity, there is also a demand for sufficient adhesive strength to be exhibited under short mounting conditions.

[0007] Known methods for reducing the connection resistance of a circuit connection structure include adjusting the particle hardness of the conductive particles and lowering the minimum melt viscosity of the adhesive film in order to improve the contact between the electrodes and the conductive particles. However, it is difficult to obtain a circuit connection structure in which the connection resistance value is unlikely to increase even after a reliability test by short-time mounting using only these methods.

[0008] Therefore, the main object of the present disclosure is to provide a manufacturing method for a circuit connection structure and an adhesive film for circuit connection that make it possible to obtain a circuit connection structure that is connected with sufficient adhesive strength and has excellent connection reliability while reducing the connection resistance value between opposing electrodes. [Means for solving the problem]

[0009] One aspect of the present disclosure relates to the following [1] to

[15] .

[0010] [1] A method for producing a circuit connection structure, comprising the steps of: interposing an adhesive film for circuit connection containing conductive particles between a first circuit member having a first electrode and a second circuit member having a second electrode; and thermocompression bonding the first circuit member and the second circuit member to electrically connect the first electrode and the second electrode to each other; the adhesive film for circuit connection has a first adhesive layer containing conductive particles and a first thermosetting resin component, and a second adhesive layer containing a second thermosetting resin component provided on the first adhesive layer, the second thermosetting resin component comprising a cationic polymerizable compound, a thermal cationic polymerization initiator, and a cationic stabilizer that reacts with cationic species generated by thermal decomposition of the thermal cationic polymerization initiator. [2] The method for producing a circuit connection structure described in [1], wherein the cation stabilizer is at least one compound selected from the group consisting of thiourea compounds, 4-alkylthiophenol compounds, and 4-hydroxyphenyl-dialkylsulfonium salts. [3] The method for producing a circuit connection structure described in [1] or [2], wherein the content of the cationic stabilizer in the second adhesive layer is 5 to 20 parts by mass per 100 parts by mass of the thermal cationic polymerization initiator. [4] The method for producing a circuit connection structure described in any one of [1] to [3], wherein the content of the cationic stabilizer in the second adhesive layer is 0.01 to 2.0 mass % based on the total mass of the second adhesive layer. [5] The method for producing a circuit connection structure according to any one of [1] to [4], wherein the cationically polymerizable compound is at least one compound selected from the group consisting of an oxetane compound and an alicyclic epoxy compound. [6] The method for producing a circuit connection structure described in any one of [1] to [5], wherein the first thermosetting resin component contains a cationic polymerizable compound and a thermal cationic polymerization initiator, the first adhesive layer further contains a cured product of a photocurable resin component, and the photocurable resin component contains a radical polymerizable compound and a photoradical polymerization initiator. [7] The method for producing a circuit connection structure according to any one of [1] to [6], wherein the first adhesive layer has a thickness of 5.0 μm or less. [8] An adhesive film for circuit connection comprising: a first adhesive layer containing conductive particles and a first thermosetting resin component; and a second adhesive layer containing a second thermosetting resin component provided on the first adhesive layer, wherein the second thermosetting resin component contains a cationic polymerizable compound, a thermal cationic polymerization initiator, and a cationic stabilizer that reacts with cationic species generated by thermal decomposition of the thermal cationic polymerization initiator. [9] The adhesive film for circuit connection described in [8], wherein the cationic stabilizer is at least one compound selected from the group consisting of thiourea compounds, 4-alkylthiophenol compounds, and 4-hydroxyphenyl-dialkylsulfonium salts.

[10] The adhesive film for circuit connection according to [8] or [9], wherein the content of the cationic stabilizer in the second adhesive layer is 5 to 20 parts by mass per 100 parts by mass of the thermal cationic polymerization initiator.

[11] The adhesive film for circuit connection according to any one of [8] to

[10] , wherein the content of the cationic stabilizer in the second adhesive layer is 0.01 to 2.0 mass % based on the total mass of the second adhesive layer.

[12] The adhesive film for circuit connection according to any one of [8] to

[11] , wherein the cationically polymerizable compound is at least one compound selected from the group consisting of oxetane compounds and alicyclic epoxy compounds.

[13] An adhesive film for circuit connection described in any of [8] to

[12] , wherein the first thermosetting resin component contains a cationic polymerizable compound and a thermal cationic polymerization initiator, the first adhesive layer further contains a cured product of a photocurable resin component, and the photocurable resin component contains a radical polymerizable compound and a photoradical polymerization initiator.

[14] The adhesive film for circuit connection according to any one of [8] to

[13] , wherein the first adhesive layer has a thickness of 5.0 μm or less.

[15] A circuit connection structure comprising: a first circuit member having a first electrode; a second circuit member having a second electrode; and a circuit connection portion disposed between the first circuit member and the second circuit member and electrically connecting the first electrode and the second electrode to each other, wherein the circuit connection portion comprises a cured product of the adhesive film for circuit connection according to any one of [8] to

[14] .

[0011] According to the method for producing a circuit connection structure described in [1] above, it is possible to obtain a circuit connection structure that is connected with sufficient adhesive strength and has excellent connection reliability while reducing the connection resistance value between opposing electrodes. The reason for this effect is believed to be that by using an adhesive film for circuit connection having a second adhesive layer containing a cationic stabilizer, the reaction initiation temperature of the cationic polymerization of the second adhesive layer can be increased, improving the expulsion of the resin during connection and reducing the connection gap (the distance between the connected opposing electrodes), which makes it possible to increase the contact area between the conductive particles and the electrodes. Effect of the Invention

[0012] According to the present disclosure, it is possible to provide a method for producing a circuit connection structure and an adhesive film for circuit connection that can obtain a circuit connection structure having excellent connection reliability, in which the connection is made with sufficient adhesive strength while reducing the connection resistance between opposing electrodes. The circuit connection structure obtained as described above can be one in which the connection resistance between opposing electrodes is unlikely to increase even after a reliability test under a high-temperature and high-humidity environment.

[0013] However, in recent years, with the increase in the number of pixels in displays, the area of ​​the electrodes of driver ICs has been reduced and the pitch has been narrowed. In such cases, it becomes difficult to ensure the insulation performance between adjacent electrodes while increasing the capture rate of conductive particles. In contrast, according to the manufacturing method of the circuit connection structure and the adhesive film for circuit connection of the present disclosure, the connection gap can be reduced to reduce the connection resistance between opposing electrodes, and therefore it is possible to fully respond to the reduction in the area of ​​the electrodes and the narrower pitch. [Brief description of the drawings]

[0014] [Figure 1] FIG. 1 is a schematic cross-sectional view showing one embodiment of an adhesive film for circuit connection. [Diagram 2] FIG. 2 is a schematic cross-sectional view showing one embodiment of a circuit connection structure. [Diagram 3] FIG. 3 is a schematic cross-sectional view showing one embodiment of a method for producing a circuit connection structure. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0015] Hereinafter, an embodiment of the present disclosure will be described in detail with reference to the drawings. In the following description, the same or corresponding parts are denoted by the same reference numerals, and duplicated descriptions will be omitted. Note that the present disclosure is not limited to the following embodiment.

[0016] In this specification, the numerical range indicated by "~" indicates a range including the numerical values ​​described before and after "~" as the minimum and maximum values, respectively. In the numerical ranges described in stages in this specification, the upper limit or lower limit of a certain numerical range may be replaced with the upper limit or lower limit of the numerical range of another stage. In addition, in the numerical ranges described in this specification, the upper limit or lower limit of the numerical range may be replaced with a value shown in the examples. In addition, the upper limit and lower limit values ​​described individually can be arbitrarily combined. In the expression of a numerical range "A to B", the numerical values ​​A and B at both ends are included in the numerical range as the lower limit and upper limit, respectively. In this specification, for example, the description "10 or more" means "10" and "a numerical value exceeding 10", and the same applies when the numerical values ​​are different. In addition, for example, the description "10 or less" means "10" and "a numerical value less than 10", and the same applies when the numerical values ​​are different. In addition, in this specification, "(meth)acrylate" means at least one of acrylate and the corresponding methacrylate. The same applies to other similar expressions such as "(meth)acryloyl" and "(meth)acrylic acid". In addition, "A or B" may include either A or B, or may include both. In addition, the materials exemplified below may be used alone or in combination of two or more types, unless otherwise specified. When a plurality of substances corresponding to each component are present in the composition, the content of each component in the composition means the total amount of the plurality of substances present in the composition, unless otherwise specified.

[0017] [Adhesive film for circuit connection] The adhesive film for circuit connection of this embodiment comprises a first adhesive layer containing conductive particles and a first thermosetting resin component, and a second adhesive layer containing a second thermosetting resin component provided on the first adhesive layer, the second thermosetting resin component containing a cationic polymerizable compound, a thermal cationic polymerization initiator, and a cationic stabilizer that reacts with a cationic species generated by thermal decomposition of the thermal cationic polymerization initiator. The first adhesive layer may further contain a photocurable resin component. The photocurable resin component may contain a radical polymerizable compound and a photoradical polymerization initiator.

[0018] Fig. 1 is a schematic cross-sectional view showing one embodiment of an adhesive film for circuit connection, and is a diagram showing a schematic longitudinal section of the adhesive film for circuit connection. The adhesive film for circuit connection 10 shown in Fig. 1 comprises a first adhesive layer 1 containing a plurality of conductive particles 4 and an adhesive component 3, and a second adhesive layer 2 provided on the first adhesive layer 1. In this specification, the term "longitudinal section" refers to a section (cross section in the thickness direction) perpendicular to the main surface (e.g., the adhesive film for circuit connection 10).

[0019] At least some of the conductive particles 4 may be arranged in the horizontal direction in a state in which adjacent conductive particles are spaced apart from each other in the longitudinal section of the adhesive film 10 for circuit connection. Here, "horizontal direction" means a direction parallel to the main surface of the adhesive film for circuit connection (left-right direction in FIG. 1). Note that in FIG. 1, some of the conductive particles 4 are exposed from the surface of the first adhesive layer 1 (for example, protruding toward the second adhesive layer 2), but the entire conductive particles 4 may be embedded in the first adhesive layer 1 so that the conductive particles 4 are not exposed from the surface of the first adhesive layer 1 (the conductive particles 4 may be dispersed in the first adhesive layer 1).

[0020] The adhesive film 10 for circuit connection is an adhesive film for circuit connection having anisotropic conductivity (anisotropic conductive adhesive film), and may be used for being interposed between a first circuit member having a first electrode and a second circuit member having a second electrode, and for electrically connecting the first electrode and the second electrode to each other by thermocompression bonding the first circuit member and the second circuit member. Note that "anisotropic conductivity" means that the film is conductive in the pressure direction and is insulating in the non-pressure direction.

[0021] Next, each component constituting the first adhesive layer 1 and the second adhesive layer 2 will be described.

[0022] <First adhesive layer> The first adhesive layer 1 may contain, for example, conductive particles 4 (hereinafter sometimes referred to as "component (A)"), a cured product of a photocurable resin component (hereinafter sometimes referred to as "component (B)"), and a thermosetting resin component (hereinafter sometimes referred to as "component (C)"). The cured product of component (B) may be a cured product obtained by completely curing component (B), or may be a cured product obtained by curing a portion of component (B). Component (C) is a component that can flow when connected, and is, for example, an uncured curable component (for example, a resin component). The components other than the conductive particles 4 constituting the first adhesive layer 1 are, for example, components that do not have electrical conductivity (for example, an insulating resin component).

[0023] [Component (A): Conductive particles] The component (A) is not particularly limited as long as it is a particle having electrical conductivity, and may be a metal particle composed of a metal such as Au, Ag, Pd, Ni, Cu, or solder, or a conductive carbon particle composed of conductive carbon. The component (A) may be a coated conductive particle having a core containing non-conductive glass, ceramic, plastic (polystyrene, etc.), and a coating layer containing the above metal or the above conductive carbon and coating the core. The component (A) may be one of various conductive particles used alone, or a combination of a plurality of conductive particles. Among these, the component (A) is preferably a coated conductive particle having a core containing plastic and a coating layer containing a metal or conductive carbon and coating the core.

[0024] When component (A) is a coated conductive particle, the cured product of the thermosetting resin component can be easily deformed by heating or applying pressure. This increases the contact area between the electrodes and component (A) when electrically connecting the electrodes, thereby further improving the conductivity between the electrodes.

[0025] The particle hardness of component (A) is 1,000 to 30,000 N / mm 2 3,000 to 200,000 N / mm 2The particle hardness is a value measured at a measurement temperature of 25° C. using a microcompression tester (probe tip shape: 50 μm×50 μm square).

[0026] The particle hardness of component (A) is 1,000 to 9,000 N / mm 2 3,000 to 9,000 N / mm 2 In this case, the connection resistance between the opposing electrodes of the circuit connection structure is unlikely to increase even in a high-temperature and high-humidity environment. From the viewpoint of reducing the connection resistance between the opposing electrodes of the circuit connection structure, the particle hardness of the component (A) may be 10,000 to 200,000 N / mm 2 10,000 to 30,0000N / mm 2 may be also possible.

[0027] The maximum particle size of the (A) component must be smaller than the minimum distance between the electrodes (the shortest distance between adjacent electrodes). The maximum particle size of the (A) component may be 1.0 μm or more, 2.0 μm or more, or 2.5 μm or more from the viewpoint of excellent dispersibility and conductivity. The maximum particle size of the (A) component may be 30.0 μm or less, 25.0 μm or less, 20.0 μm or less, 15.0 μm or less, 10.0 μm or less, or 5.0 μm or less from the viewpoint of excellent dispersibility and conductivity. In this specification, the particle size of any 300 pieces (pcs) of the (A) component in the first adhesive layer is measured by observation using a scanning electron microscope (SEM), and the largest value obtained is defined as the maximum particle size of the (A) component. Note that when the (A) component has protrusions or the like and is not spherical, the particle size of the (A) component is defined as the diameter of a circle circumscribing the conductive particle in the SEM image.

[0028] From the viewpoint of excellent dispersibility and electrical conductivity, the average particle size of the (A) component may be 1.0 μm or more, 2.0 μm or more, 2.5 μm or more, or 3.0 μm or more. From the viewpoint of excellent dispersibility and electrical conductivity, the average particle size of the (A) component may be 20.0 μm or less, 10.0 μm or less, 7.0 μm or less, or 5.0 μm or less. In this specification, the particle size of any 300 pieces (pcs) of the (A) component in the first adhesive layer is measured by observation using a scanning electron microscope (SEM), and the average value of the obtained particle sizes is defined as the average particle size.

[0029] It is preferred that the component (A) is uniformly dispersed in the first adhesive layer 1. From the viewpoint of obtaining a stable connection resistance, the particle density of the component (A) in the adhesive film for circuit connection 10 is 100 particles / mm 2 More than 1000 pieces / mm 2 More than 3000 pieces / mm 2 More than 5000 pieces / mm 2 More than 7000 pieces / mm 2 More than 10000 pieces / mm 2 or more than 12000 pieces / mm 2 From the viewpoint of improving the insulating properties between adjacent electrodes, the particle density of the component (A) in the adhesive film 10 for circuit connection may be 100,000 particles / mm 2 Below, 70000 pieces / mm 2 Below, 50000 pieces / mm 2 Below 30000 pieces / mm 2 or less than 20,000 pieces / mm 2 It may be the following:

[0030] The monodispersity of the (A) component in the circuit connection adhesive film 10 may be 90% or more. When the monodispersity of the (A) component is in this range, short circuit defects between adjacent circuits are unlikely to occur, and a circuit connection structure with sufficiently high connection reliability tends to be obtained. The monodispersity of the (A) component may be 92% or more, 94% or more, 96% or more, 97% or more, 98% or more, or 99% or more. The upper limit of the monodispersity is 100%. The monodispersity can be calculated, for example, by observing the circuit connection adhesive film 10 from the first adhesive layer side at a magnification of 200 times using a metal microscope, and measuring the number of the (A) component in the circuit connection adhesive film 10 according to the following formula. Monodispersion rate (%) = (2500 μm 2 Number of monodispersed conductive particles in / 2500μm 2 (number of conductive particles in) x 100

[0031] The content of the (A) component may be 1% by mass or more, 5% by mass or more, or 10% by mass or more based on the total mass of the first adhesive layer from the viewpoint of further improving the electrical conductivity. The content of the (A) component may be 60% by mass or less, 50% by mass or less, or 40% by mass or less based on the total mass of the first adhesive layer from the viewpoint of easily suppressing short circuits. When the content of the (A) component is within the above range, the effects of the present disclosure tend to be significantly exhibited. The content of the (A) component in the composition or composition layer (based on the total mass of the composition or composition layer) may be the same as the above range.

[0032] [Component (B): Photocurable resin component] The (B) component is not particularly limited as long as it is a resin component that is cured by light irradiation, but when the (C) component is a resin component having cationic curability, the (B) component may be a resin component having radical curability from the viewpoint of better connection resistance. The (B) component may contain, for example, a radical polymerizable compound (hereinafter sometimes referred to as "(B1) component") and a photoradical polymerization initiator (hereinafter sometimes referred to as "(B2) component").

[0033] Component (B1): radically polymerizable compound The component (B1) is a compound that is polymerized by radicals generated from the component (B2) upon irradiation with light (e.g., ultraviolet light). The component (B1) may be either a monomer or a polymer (or oligomer) obtained by polymerizing one or more types of monomers. The component (B1) may be used alone or in combination.

[0034] The (B1) component is a compound having a radical polymerizable group that reacts with a radical. Examples of the radical polymerizable group include a (meth)acryloyl group, a vinyl group, an allyl group, a styryl group, an alkenyl group, an alkenylene group, and a maleimide group. The number of radical polymerizable groups (the number of functional groups) possessed by the (B1) component may be 2 or more from the viewpoint of easily obtaining a desired melt viscosity after polymerization and being more excellent in connection reliability, and may be 10 or less, 6 or less, or 4 or less from the viewpoint of further improving the effect of reducing the connection resistance and suppressing the cure shrinkage during polymerization. In addition, in order to balance the crosslink density and the cure shrinkage, in addition to the compound having the number of radical polymerizable groups within the above range, a compound having the number of radical polymerizable groups outside the above range may be used.

[0035] The (B1) component contains a polyfunctional (two or more functional) (meth)acrylate from the viewpoint of suppressing the flow of the conductive particles. The polyfunctional (two or more functional) (meth)acrylate may be a bifunctional or trifunctional (meth)acrylate, and is preferably a bifunctional (meth)acrylate. The bifunctional (meth)acrylate may be a bifunctional aromatic (meth)acrylate.

[0036] Examples of polyfunctional (meth)acrylates include ethylene glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate, tetraethylene glycol di(meth)acrylate, polyethylene glycol di(meth)acrylate, propylene glycol di(meth)acrylate, dipropylene glycol di(meth)acrylate, tripropylene glycol di(meth)acrylate, tetrapropylene glycol di(meth)acrylate, polypropylene glycol di(meth)acrylate, ethoxylated polypropylene glycol di(meth)acrylate, 1,3-butane aliphatic (meth)acrylates such as diol di(meth)acrylate, 1,4-butanediol di(meth)acrylate, neopentyl glycol di(meth)acrylate, 3-methyl-1,5-pentanediol di(meth)acrylate, 1,6-hexanediol di(meth)acrylate, 2-butyl-2-ethyl-1,3-propanediol di(meth)acrylate, 1,9-nonanediol di(meth)acrylate, 1,10-decanediol di(meth)acrylate, glycerin di(meth)acrylate, tricyclodecane dimethanol (meth)acrylate, and ethoxylated 2-methyl-1,3-propanediol di(meth)acrylate;Aromatic (meth)acrylates such as ethoxylated bisphenol A di(meth)acrylate, propoxylated bisphenol A di(meth)acrylate, ethoxylated propoxylated bisphenol A di(meth)acrylate, ethoxylated bisphenol F di(meth)acrylate, propoxylated bisphenol F di(meth)acrylate, ethoxylated propoxylated bisphenol F di(meth)acrylate, ethoxylated fluorene di(meth)acrylate, propoxylated fluorene di(meth)acrylate, ethoxylated propoxylated fluorene di(meth)acrylate, trimethylolpropane tri(meth)acrylate, ethoxylated trimethylolpropane tri(meth)acrylate, propoxylated trimethylolpropane tri(meth)acrylate, ethoxylated propoxylated trimethylolpropane tri(meth)acrylate, pentaerythritol aliphatic (meth)acrylates such as pentaerythritol tri(meth)acrylate, ethoxylated pentaerythritol tri(meth)acrylate, propoxylated pentaerythritol tri(meth)acrylate, ethoxylated propoxylated pentaerythritol tri(meth)acrylate, pentaerythritol tetra(meth)acrylate, ethoxylated pentaerythritol tetra(meth)acrylate, propoxylated pentaerythritol tetra(meth)acrylate, ethoxylated propoxylated pentaerythritol tetra(meth)acrylate, ditrimethylolpropane tetraacrylate, and dipentaerythritol hexa(meth)acrylate; aromatic epoxy (meth)acrylates such as bisphenol-type epoxy (meth)acrylate, phenol novolac-type epoxy (meth)acrylate, and cresol novolac-type epoxy (meth)acrylate;

[0037] From the viewpoint of achieving both the effect of reducing the connection resistance and the suppression of particle flow, the content of the polyfunctional (difunctional or higher) (meth)acrylate may be, for example, 50 to 100 mass%, 70 to 100 mass%, or 90 to 100 mass%, or may be 100 mass%, based on the total mass of the (B1) component.

[0038] The (B1) component may further contain a monofunctional (meth)acrylate in addition to the polyfunctional (two or more functional) (meth)acrylate. Examples of the monofunctional (meth)acrylate include (meth)acrylic acid, methyl (meth)acrylate, ethyl (meth)acrylate, butyl (meth)acrylate, isobutyl (meth)acrylate, tert-butyl (meth)acrylate, butoxyethyl (meth)acrylate, isoamyl (meth)acrylate, hexyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, heptyl (meth)acrylate, octylheptyl (meth)acrylate, nonyl (meth)acrylate, Decyl (meth)acrylate, 2-hydroxyethyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 3-chloro-2-hydroxypropyl (meth)acrylate, 2-hydroxybutyl (meth)acrylate, methoxypolyethylene glycol (meth)acrylate, ethoxypolyethylene glycol (meth)acrylate, methoxypolypropylene glycol (meth)acrylate, ethoxypolypropylene glycol (meth)acrylate, mono(2-(meth)acryloyloxy) aliphatic (meth)acrylates such as diethyl succinate; benzyl (meth)acrylate, phenyl (meth)acrylate, o-biphenyl (meth)acrylate, 1-naphthyl (meth)acrylate, 2-naphthyl (meth)acrylate, phenoxyethyl (meth)acrylate, p-cumylphenoxyethyl (meth)acrylate, o-phenylphenoxyethyl (meth)acrylate, 1-naphthoxyethyl (meth)acrylate, 2-naphthyl (meth)acrylate, phenoxypolyether aromatic (meth)acrylates such as ethylene glycol (meth)acrylate, nonylphenoxy polyethylene glycol (meth)acrylate, phenoxy polypropylene glycol (meth)acrylate, 2-hydroxy-3-phenoxypropyl (meth)acrylate, 2-hydroxy-3-(o-phenylphenoxy)propyl (meth)acrylate, 2-hydroxy-3-(1-naphthoxy)propyl (meth)acrylate, and 2-hydroxy-3-(2-naphthoxy)propyl (meth)acrylate;Examples of such methacrylates include (meth)acrylates having an epoxy group such as glycidyl (meth)acrylate, (meth)acrylates having an alicyclic epoxy group such as 3,4-epoxycyclohexylmethyl (meth)acrylate, and (meth)acrylates having an oxetanyl group such as (3-ethyloxetan-3-yl)methyl (meth)acrylate.

[0039] The content of the monofunctional (meth)acrylate based on the total mass of the component (B1) may be, for example, 0 to 50 mass %, 0 to 30 mass %, or 0 to 10 mass %, or may be 0 mass %.

[0040] The cured product of the (B) component may have a polymerizable group that reacts with other than radicals. The polymerizable group that reacts with other than radicals may be, for example, a cationic polymerizable group that reacts with cations. Examples of the cationic polymerizable group include epoxy groups such as glycidyl groups, alicyclic epoxy groups such as epoxycyclohexylmethyl groups, and oxetanyl groups such as ethyloxetanylmethyl groups. The cured product of the (B) component having a polymerizable group that reacts with other than radicals can be introduced by using, as the (B) component, a (meth)acrylate having a polymerizable group that reacts with other than radicals, such as a (meth)acrylate having an epoxy group, a (meth)acrylate having an alicyclic epoxy group, or a (meth)acrylate having an oxetanyl group. The mass ratio of the (meth)acrylate having a polymerizable group that reacts by other than radicals to the total mass of the component (B1) (mass (feed amount) of the (meth)acrylate having a polymerizable group that reacts by other than radicals / total mass (feed amount) of the component (B1)) may be, for example, 0 to 0.7, 0 to 0.5, or 0 to 0.3 from the viewpoint of improving reliability.

[0041] The (B1) component may contain other radical polymerizable compounds in addition to polyfunctional (bifunctional or higher) and monofunctional (meth)acrylates. Examples of other radical polymerizable compounds include maleimide compounds, vinyl ether compounds, allyl compounds, styrene derivatives, acrylamide derivatives, and nadimide derivatives. The content of the other radical polymerizable compounds may be, for example, 0 to 40% by mass based on the total mass of the (B1) component.

[0042] Component (B2): Photoradical polymerization initiator The component (B2) is a photopolymerization initiator that generates radicals when irradiated with light having a wavelength in the range of 150 to 750 nm, preferably light having a wavelength in the range of 254 to 405 nm, and more preferably light having a wavelength of 365 nm (e.g., ultraviolet light). The component (B2) may be used alone or in combination.

[0043] The component (B2) is decomposed by light to generate free radicals. That is, the component (B2) is a compound that generates radicals by applying light energy from the outside. The component (B2) may be a compound having an oxime ester structure, a bisimidazole structure, an acridine structure, an α-aminoalkylphenone structure, an aminobenzophenone structure, an N-phenylglycine structure, an acylphosphine oxide structure, a benzyl dimethyl ketal structure, an α-hydroxyalkylphenone structure, or the like. The component (B2) may be used alone or in combination of two or more. The component (B2) may be a compound having at least one structure selected from the group consisting of an oxime ester structure, an α-aminoalkylphenone structure, and an acylphosphine oxide structure, from the viewpoint of easily obtaining a desired melt viscosity and from the viewpoint of being more effective in reducing the connection resistance.

[0044] Specific examples of compounds having an oxime ester structure include 1-phenyl-1,2-butanedione-2-(o-methoxycarbonyl)oxime, 1-phenyl-1,2-propanedione-2-(o-methoxycarbonyl)oxime, 1-phenyl-1,2-propanedione-2-(o-ethoxycarbonyl)oxime, 1-phenyl-1,2-propanedione-2-o-benzoyloxime, 1,3-diphenylpropanetrione-2-(o-ethoxycarbonyl)oxime, 1-phenyl-3-ethoxypropanetrione-2-(o-benzoyl)oxime, 1,2-octanedione, 1-[4-(phenylthio)phenyl-, 2-(o-benzoyloxime)], ethanone, 1-[9-ethyl-6-(2-methylbenzoyl)-9H-carbazol-3-yl]-, 1-(o-acetyloxime), and the like.

[0045] Specific examples of compounds having an α-aminoalkylphenone structure include 2-methyl-1-[4-(methylthio)phenyl]-2-morpholinopropan-1-one, 2-benzyl-2-dimethylamino-1-morpholinophenyl)-butanone-1, and the like.

[0046] Specific examples of compounds having an acylphosphine oxide structure include bis(2,6-dimethoxybenzoyl)-2,4,4-trimethyl-pentylphosphine oxide, bis(2,4,6-trimethylbenzoyl)-phenylphosphine oxide, and 2,4,6-trimethylbenzoyl-diphenylphosphine oxide.

[0047] The content of the (B2) component may be, for example, 0.1 to 10 parts by mass, 0.3 to 7 parts by mass, or 0.5 to 5 parts by mass per 100 parts by mass of the (B1) component from the viewpoint of suppressing the flow of the conductive particles.

[0048] The content of the cured product of the (B) component may be 1% by mass or more, 5% by mass or more, or 10% by mass or more based on the total mass of the first adhesive layer from the viewpoint of suppressing the flow of the conductive particles. The content of the cured product of the (B) component may be 50% by mass or less, 40% by mass or less, or 30% by mass or less based on the total mass of the first adhesive layer from the viewpoint of exhibiting low resistance in low-pressure mounting. When the content of the cured product of the (B) component is within the above range, the effect of the present disclosure tends to be significantly exhibited. The content of the (B) component in the composition or composition layer (based on the total mass of the composition or composition layer) may be the same as the above range.

[0049] [(C) component: thermosetting resin component] The (C) component is not particularly limited as long as it is a resin component that is cured by heat, but when the (B) component is a resin component having radical curing properties, the (C) component may be a resin component having cationic curing properties from the viewpoint of being superior in terms of connection resistance. The (C) component may contain, for example, a cationic polymerizable compound (hereinafter, sometimes referred to as "(C1) component") and a thermal cationic polymerization initiator (hereinafter, sometimes referred to as "(C2) component"). The first thermosetting resin component and the second thermosetting resin component refer to the thermosetting resin components contained in the first adhesive layer and the second adhesive layer, respectively, and the components (e.g., (C1) component, (C2) component, etc.) and the contents thereof contained in the first thermosetting resin component and the second thermosetting resin component may be the same or different from each other.

[0050] Component (C1): Cationic polymerizable compound The (C1) component is a compound that crosslinks by reacting with the (C2) component by heat. The (C1) component means a compound that does not have a radical polymerizable group that reacts with a radical, and the (C1) component is not included in the (B1) component. Examples of the (C1) component include compounds having a cyclic ether group, such as oxetane compounds and epoxy compounds. The (C1) component may be used alone or in combination. From the viewpoint of further improving the effect of reducing the connection resistance and achieving better connection reliability, the (C1) component may contain, for example, at least one selected from the group consisting of oxetane compounds and alicyclic epoxy compounds. From the viewpoint of easily obtaining a desired melt viscosity, the (C1) component preferably contains both at least one oxetane compound and at least one alicyclic epoxy compound.

[0051] The oxetane compound as the component (C1) can be used without any particular limitation as long as it has an oxetanyl group and does not have a radical polymerizable group. Examples of commercially available oxetane compounds include ETERNACOLL OXBP (trade name, 4,4'-bis[(3-ethyl-3-oxetanyl)methoxymethyl]biphenyl, manufactured by Ube Industries, Ltd.), OXSQ, OXT-121, OXT-221, OXT-101, and OXT-212 (trade name, manufactured by Toa Gosei Co., Ltd.). These may be used alone or in combination.

[0052] The alicyclic epoxy compound as the component (C1) can be used without any particular limitation as long as it has an alicyclic epoxy group (e.g., an epoxycyclohexyl group) and does not have a radical polymerizable group. Commercially available alicyclic epoxy compounds include, for example, EHPE3150, EHPE3150CE, Celloxide 8010, Celloxide 2021P, and Celloxide 2081 (trade name, manufactured by Daicel Corporation). These may be used alone or in combination.

[0053] Component (C2): Thermal cationic polymerization initiator The component (C2) is a thermal polymerization initiator that generates an acid or the like when heated to initiate polymerization. The component (C2) may be a salt compound composed of a cation and an anion. The component (C2) is, for example, BF 4 - , B.R. 4 - (R represents a phenyl group substituted with two or more fluorine atoms or two or more trifluoromethyl groups), PF 6 - , SbF 6 - , AsF 6 - and onium salts such as sulfonium salts, phosphonium salts, ammonium salts, diazonium salts, iodonium salts, anilinium salts, pyridinium salts, etc., each of which has an anion such as those mentioned above. These may be used alone or in combination of two or more.

[0054] From the viewpoint of storage stability, the component (C2) is, for example, an anion containing boron as a constituent element, i.e., BF 4 - or BR 4 - (R represents a phenyl group substituted with two or more fluorine atoms or two or more trifluoromethyl groups). The anion containing boron as a constituent element may be a salt compound having BR 4 - and more specifically, tetrakis(pentafluorophenyl)borate.

[0055] The onium salt as the component (C2) may be, for example, an anilinium salt, since it has resistance to substances that may cause inhibition of cationic curing. Examples of the anilinium salt compound include N,N-dialkylanilinium salts such as N,N-dimethylanilinium salts and N,N-diethylanilinium salts.

[0056] The component (C2) may be an anilinium salt having an anion containing boron as a constituent element. Commercially available products of such salt compounds include, for example, CXC-1821 (trade name, manufactured by King Industries).

[0057] From the viewpoint of ensuring the formability and curability of the first adhesive layer, the content of the (C2) component may be, for example, 0.1 to 20 parts by mass, 1 to 18 parts by mass, 3 to 15 parts by mass, or 5 to 12 parts by mass per 100 parts by mass of the (C1) component.

[0058] The content of the (C) component may be 5% by mass or more, 10% by mass or more, 15% by mass or more, or 20% by mass or more based on the total mass of the first adhesive layer, from the viewpoint of ensuring the curability of the first adhesive layer. The content of the (C) component may be 70% by mass or less, 60% by mass or less, 50% by mass or less, or 40% by mass or less based on the total mass of the first adhesive layer, from the viewpoint of ensuring the formability of the first adhesive layer. When the content of the (C) component is in the above range, the effect of the present disclosure tends to be significantly exhibited. The content of the (C) component in the composition or composition layer (based on the total mass of the composition or composition layer) may be the same as the above range.

[0059] [Other ingredients] The first adhesive layer may further contain other components in addition to the component (A), the cured product of the component (B), and the component (C). Examples of the other components include a thermoplastic resin (hereinafter sometimes referred to as "component (D)"), a coupling agent (hereinafter sometimes referred to as "component (E)"), and a filler (hereinafter sometimes referred to as "component (F)").

[0060] Examples of the (D) component include phenoxy resin, polyester resin, polyamide resin, polyurethane resin, polyester urethane resin, acrylic rubber, and epoxy resin (solid at 25°C). These may be used alone or in combination. The composition containing the (A), (B), and (C) components further contains the (D) component, so that the composition layer can be easily formed from the composition. Among these, the (D) component may be, for example, a phenoxy resin. The content of the (D) component may be 1% by mass or more, 5% by mass or more, or 10% by mass or more, based on the total mass of the first adhesive layer, and may be 70% by mass or less, 50% by mass or less, or 30% by mass or less. The content of the (D) component in the composition or composition layer (based on the total mass of the composition or composition layer) may be the same as the above range.

[0061] Examples of the (E) component include silane coupling agents having organic functional groups such as (meth)acryloyl groups, mercapto groups, amino groups, imidazole groups, and epoxy groups, silane compounds such as tetraalkoxysilanes, tetraalkoxytitanate derivatives, and polydialkyltitanate derivatives. These may be used alone or in combination. The first adhesive layer contains the (E) component, which can further improve the adhesiveness. The (E) component may be, for example, a silane coupling agent. The content of the (E) component may be 0.1 to 10% by mass based on the total mass of the first adhesive layer. The content of the (E) component in the composition or composition layer (based on the total mass of the composition or composition layer) may be the same as the above range.

[0062] Examples of the (F) component include non-conductive fillers (e.g., non-conductive particles). The (F) component may be either an inorganic filler or an organic filler. Examples of the inorganic filler include inorganic fine particles such as metal oxide fine particles, such as silica fine particles, alumina fine particles, silica-alumina fine particles, titania fine particles, and zirconia fine particles; and metal nitride fine particles. Examples of the organic filler include organic fine particles, such as silicone fine particles, methacrylate-butadiene-styrene fine particles, acrylic-silicone fine particles, polyamide fine particles, and polyimide fine particles. These may be used alone or in combination. The (F) component may be, for example, silica fine particles. The content of the (F) component may be 0.1 to 10% by mass based on the total mass of the first adhesive layer. The content of the (F) component in the composition or composition layer (based on the total mass of the composition or composition layer) may be the same as the above range.

[0063] [Other additives] The first adhesive layer may further contain other additives such as softeners, accelerators, anti-degradants, colorants, flame retardants, and thixotropic agents. The content of the other additives may be, for example, 0.1 to 10% by mass based on the total mass of the first adhesive layer. The content of the other additives in the composition or composition layer (based on the total mass of the composition or composition layer) may be the same as the above range.

[0064] The thickness d1 of the first adhesive layer may be, for example, 30.0 μm or less, 20.0 μm or less, 15.0 μm or less, 10.0 μm or less, 8.0 μm or less, 5.0 μm or less, 4.5 μm or less, 4.0 μm or less, 3.5 μm or less, 3.0 μm or less, or 2.5 μm or less. By having the thickness d1 of the first adhesive layer 1 be 30.0 μm or less, the resin content between the opposing circuits is reduced, and the increase in the connection resistance between the opposing circuits can be suppressed. This tendency is more pronounced when the thickness d1 of the first adhesive layer 1 is 5.0 μm or less. The thickness d1 of the first adhesive layer 1 may be, for example, 0.1 μm or more or 0.7 μm or more. 1, when a portion of the conductive particles 4 is exposed from the surface of the first adhesive layer 1 (for example, protruding toward the second adhesive layer 2), the distance from the surface 1a of the first adhesive layer 1 opposite the second adhesive layer 2 to the boundary S between the first adhesive layer 1 and the second adhesive layer 2 located in the space between adjacent conductive particles 4, 4 (the distance indicated by d1 in FIG. 1) is the thickness of the first adhesive layer 1, and the exposed portion of the conductive particle 4 is not included in the thickness of the first adhesive layer 1. The length of the exposed portion of the conductive particle 4 may be, for example, 0.1 μm or more and 5.0 μm or less.

[0065] The thickness d1 of the first adhesive layer 1 can be determined, for example, by the method described in the Examples. Specifically, the circuit connection adhesive film is sandwiched between two pieces of glass (thickness: about 1 mm), and a resin composition consisting of 100 g of bisphenol A type epoxy resin (product name: JER811, manufactured by Mitsubishi Chemical Corporation) and 10 g of a curing agent (product name: Epomount curing agent, manufactured by Refine Tech Co., Ltd.) is poured into the mold, and the cross section is polished using a polishing machine, and the thickness can be measured using a scanning electron microscope (SEM, product name: SE-8020, manufactured by Hitachi High-Tech Science Corporation). This operation may be performed multiple times, and the average value may be used as the thickness d1 of the first adhesive layer 1.

[0066] The ratio of the thickness of the first adhesive layer 1 to the average particle diameter of the conductive particles 4 (thickness of the first adhesive layer 1 / average particle diameter of the conductive particles 4) is 0.50 or more, and may be, for example, 0.55 or more or 0.60 or more. When the ratio is 0.50 or more, the resin content between the opposing circuits is reduced, and an increase in the connection resistance between the opposing circuits can be suppressed. The ratio may be, for example, 2.00 or less, 1.50 or less, 1.20 or less, or 1.00 or less.

[0067] <Second adhesive layer> The second adhesive layer 2 may be, for example, an insulating adhesive layer composed of a non-conductive component (insulating resin component). The second adhesive layer 2 contains, as a second thermosetting resin component, a cationic polymerizable compound, a thermal cationic polymerization initiator, and a cationic stabilizer that reacts with cationic species generated by thermal decomposition of the thermal cationic polymerization initiator.

[0068] The cationic polymerizable compound and the thermal cationic polymerization initiator contained in the second adhesive layer 2 may be the same as the components (C1) and (C2) used in the component (C) (i.e., the first thermosetting resin component) in the first adhesive layer 1. The cationic polymerizable compound and the thermal cationic polymerization initiator contained in the second thermosetting resin component may be the same as or different from those in the first thermosetting resin component.

[0069] The content of the second thermosetting resin component may be 5% by mass or more, 10% by mass or more, 15% by mass or more, or 20% by mass or more based on the total mass of the second adhesive layer from the viewpoint of maintaining reliability. The content of the second thermosetting resin component may be 80% by mass or less, 70% by mass or less, 60% by mass or less, or 50% by mass or less based on the total mass of the second adhesive layer from the viewpoint of preventing resin seepage problems in a reel, which is one embodiment of a supply form.

[0070] From the viewpoint of maintaining reliability, the content of the cationic polymerizable compound may be 5% by mass or more, 10% by mass or more, or 20% by mass or more, and may be 70% by mass or less, 60% by mass or less, or 50% by mass or less, based on the total mass of the second adhesive layer.

[0071] The content of the thermal cationic polymerization initiator may be, for example, 0.1 to 20 parts by mass, 1 to 18 parts by mass, 3 to 15 parts by mass, or 5 to 12 parts by mass relative to 100 parts by mass of the cationic polymerizable compound, from the viewpoint of ensuring the formability and curability of the second adhesive layer.

[0072] Examples of the cationic stabilizer (hereinafter sometimes referred to as "component (G)") that reacts with the cationic species generated by thermal decomposition of the thermal cationic polymerization initiator include thiourea compounds, 4-alkylthiophenol compounds, and 4-hydroxyphenyl-dialkylsulfonium salts. These may be used alone or in combination of two or more.

[0073] The thiourea compound includes ethylenethiourea, N,N'-diethylthiourea, N,N'-dibutylthiourea, and trimethylthiourea.

[0074] Examples of the 4-alkylthiophenol compound include 4-methylthiophenol, 4-ethylthiophenol, and 4-butylthiophenol.

[0075] Examples of 4-hydroxyphenyl-dialkylsulfonium salts include 4-hydroxyphenyl-dimethylsulfonium-methylsulfate, 4-hydroxyphenyl-diethylsulfonium-methylsulfate, and 4-hydroxyphenyl-dibutylsulfonium-methylsulfate.

[0076] The content of the component (G) may be 5 to 20 parts by mass, 5 to 15 parts by mass, or 5 to 10 parts by mass relative to 100 parts by mass of the thermal cationic polymerization initiator.

[0077] The content of the (G) component may be 0.01 mass% or more, 0.05 mass% or more, or 0.1 mass% or more, and may be 2.0 mass% or less, 1.0 mass% or less, or 0.5 mass% or less, based on the total mass of the second adhesive layer.

[0078] The second adhesive layer 2 may further contain other components and other additives than those in the first adhesive layer 1. Preferred aspects of the other components and other additives are the same as those of the first adhesive layer 1.

[0079] The content of the (D) component may be 1 mass% or more, 3 mass% or more, or 5 mass% or more, and may be 60 mass% or less, 40 mass% or less, or 20 mass% or less, based on the total mass of the second adhesive layer.

[0080] The content of the component (E) may be 0.1 to 10 mass % based on the total mass of the second adhesive layer.

[0081] The content of the (F) component may be 1 mass % or more, 10 mass % or more, or 30 mass % or more, and may be 90 mass % or less, 70 mass % or less, or 50 mass % or less, based on the total mass of the second adhesive layer.

[0082] The content of the other additives may be, for example, 0.1 to 10% by mass based on the total mass of the second adhesive layer.

[0083] The thickness d2 of the second adhesive layer 2 may be appropriately set according to the height of the electrodes of the circuit member to be bonded. The thickness d2 of the second adhesive layer 2 may be 5.0 μm or more or 7.0 μm or more, and may be 30.0 μm or less, 20.0 μm or less, 15.0 μm or less, or 13.0 μm or less, from the viewpoint of being able to sufficiently fill the space between the electrodes to seal the electrodes and obtain better connection reliability. In addition, when a part of the conductive particles 4 is exposed from the surface of the first adhesive layer 1 (for example, protruding to the second adhesive layer 2 side), the distance (distance shown as d2 in FIG. 1) from the surface 2a of the second adhesive layer 2 opposite to the first adhesive layer 1 side to the boundary S between the first adhesive layer 1 and the second adhesive layer 2 located in the space between the adjacent conductive particles 4, 4 is the thickness of the second adhesive layer 2.

[0084] The thickness d2 of the second adhesive layer 2 can be determined, for example, in the same manner as the method for measuring the thickness d1 of the first adhesive layer 1 described above.

[0085] The thickness of the adhesive film 10 for circuit connection (the total thickness of all layers constituting the adhesive film 10 for circuit connection; in FIG. 1, the total thickness d1 of the first adhesive layer 1 and the thickness d2 of the second adhesive layer 2) may be, for example, 5.0 μm or more or 8.0 μm or more, and may be 60.0 μm or less, 40.0 μm or less, 30.0 μm or less, or 20.0 μm or less.

[0086] From the viewpoint of the ability to capture conductive particles, the minimum melt viscosity of the adhesive film 10 for circuit connection may be 10 Pa·s or more, 30 Pa·s or more, 50 Pa·s or more, or 100 Pa·s or more. From the viewpoint of the connectivity between opposing electrodes, the minimum melt viscosity of the adhesive film 10 for circuit connection may be 2000 Pa·s or less, 1500 Pa·s or less, 1000 Pa·s or less, 500 Pa·s or less, 400 Pa·s or less, or 300 Pa·s or less. The minimum melt viscosity of the adhesive film can be determined, for example, by the following method. (Method for measuring minimum melt viscosity) Each adhesive film is laminated with a laminator to a thickness of 500 μm or more to obtain a laminate. The release-treated PET is peeled off from the obtained laminate and cut into a 10.0 mm × 10.0 mm sample to obtain a measurement sample. The minimum melt viscosity of the obtained measurement sample is measured using a viscoelasticity measuring device (product name: ARES-G2, manufactured by TA Instruments, heating rate: 10 ° C / min).

[0087] The adhesive film 10 for circuit connection may have anisotropic conductivity or may not have anisotropic conductivity. That is, the adhesive film for circuit connection may be an anisotropic conductive adhesive film or a non-anisotropic conductive (for example, isotropic conductive) adhesive film. The adhesive film 10 for circuit connection may be interposed between a first circuit member having a first electrode (the surface on which the first electrode is provided) and a second circuit member having a second electrode (the surface on which the second electrode is provided), and may be used to electrically connect the first electrode and the second electrode to each other (through conductive particles (or a molten and solidified product of conductive particles)) by thermocompression bonding the first circuit member and the second circuit member (heating a laminate including the first circuit member, the adhesive film 10 for circuit connection, and the second circuit member while pressing them in the thickness direction of the laminate).

[0088] The adhesive film 10 for circuit connection can reduce the connection resistance between opposing electrodes while providing a circuit connection structure with sufficient adhesive strength and excellent connection reliability.

[0089] Although the adhesive film for circuit connection of the present embodiment has been described above, the present disclosure is not limited to the above embodiment. The adhesive film for circuit connection may be composed of three or more layers, including two layers of a first adhesive layer and a second adhesive layer. In this case, the adhesive film for circuit connection may further include, for example, a third adhesive layer provided on the opposite side of the first adhesive layer from the second adhesive layer.

[0090] The third adhesive layer may contain at least the (C) component. The (C1) and (C2) components used in the (C) component (i.e., the third thermosetting resin component) in the third adhesive layer are similar to the (C1) and (C2) components used in the (C) component (i.e., the first thermosetting resin component) in the first adhesive layer, and therefore detailed description is omitted here. The third thermosetting resin component may be the same as or different from the first thermosetting resin component. The third thermosetting resin component may be the same as or different from the second thermosetting resin component.

[0091] The content of the (C) component may be 5% by mass or more, 10% by mass or more, 15% by mass or more, or 20% by mass or more based on the total mass of the third adhesive layer from the viewpoint of imparting good transferability and peel resistance. The content of the (C) component may be 70% by mass or less, 60% by mass or less, 50% by mass or less, or 40% by mass or less based on the total mass of the third adhesive layer from the viewpoint of imparting good half-cut properties and blocking resistance (suppression of resin bleeding from the reel).

[0092] The third adhesive layer may further contain other components and other additives than those in the first adhesive layer 1. Preferred aspects of the other components and other additives are the same as those in the first adhesive layer 1.

[0093] The content of the (D) component may be 10 mass% or more, 20 mass% or more, or 30 mass% or more, and may be 80 mass% or less, 70 mass% or less, or 60 mass% or less, based on the total mass of the third adhesive layer.

[0094] The content of the component (E) may be 0.1 to 10 mass % based on the total mass of the third adhesive layer.

[0095] The content of the (F) component may be 1 mass% or more, 3 mass% or more, or 5 mass% or more, and may be 50 mass% or less, 40 mass% or less, or 30 mass% or less, based on the total mass of the third adhesive layer.

[0096] The content of the other additives may be, for example, 0.1 to 10% by mass based on the total mass of the third adhesive layer.

[0097] The thickness of the third adhesive layer may be appropriately set depending on the height of the electrodes of the circuit member to be bonded. The thickness of the third adhesive layer may be 0.2 μm or more or 0.5 μm or more, and 5.0 μm or less or 2.5 μm or less, from the viewpoint of being able to sufficiently fill the space between the electrodes to seal the electrodes and obtain better connection reliability. The thickness of the third adhesive layer may be determined, for example, in the same manner as the method for measuring the thickness d1 of the first adhesive layer 1 described above.

[0098] When the adhesive film for circuit connection has a layer other than the first adhesive layer and the second adhesive layer (e.g., a third adhesive layer), the thickness of the adhesive film for circuit connection (the sum of the thicknesses of all layers constituting the adhesive film for circuit connection) may be within the range of possible thicknesses of the above-mentioned adhesive film for circuit connection 10.

[0099] <Method of manufacturing an adhesive film for circuit connection> A method for producing an adhesive film for circuit connection according to an embodiment may include, for example, a step (first step) of irradiating a composition layer made of a composition containing the (A) component, the (B) component, and the (C) component (first thermosetting resin component), and other components as necessary, with light to form a first adhesive layer, and a step (second step) of laminating a second adhesive layer containing the (C) component (second thermosetting resin component) and other components as necessary on the first adhesive layer. The production method may further include a step (third step) of laminating a third adhesive layer containing the (C) component (third thermosetting resin component) and other components as necessary on the layer opposite the second adhesive layer of the first adhesive layer. In this case, the second step may be performed first, or the third step may be performed first. When the third step is performed first, the third adhesive layer is laminated on the side opposite to the side of the first adhesive layer on which the second adhesive layer is to be laminated.

[0100] In the first step, for example, first, a composition containing the (A) component, the (B) component, and the (C) component, as well as other components added as necessary, is dissolved or dispersed in an organic solvent by stirring, mixing, kneading, etc., to prepare a varnish composition (a first adhesive composition in a varnish form). Thereafter, the varnish composition is applied to a substrate that has been subjected to a release treatment using a knife coater, a roll coater, an applicator, a comma coater, a die coater, etc., and then the organic solvent is volatilized by heating to form a composition layer made of the composition on the substrate. At this time, the thickness of the first adhesive layer (first adhesive film) finally obtained can be adjusted by adjusting the amount of the varnish composition applied. Next, the composition layer made of the composition is irradiated with light to harden the (B) component in the composition layer, and a first adhesive layer is formed on the substrate. The first adhesive layer can be called a first adhesive film.

[0101] The organic solvent used in the preparation of the varnish composition is not particularly limited as long as it has the property of dissolving or dispersing each component uniformly. Examples of such organic solvents include toluene, acetone, methyl ethyl ketone, methyl isobutyl ketone, ethyl acetate, propyl acetate, butyl acetate, etc. These organic solvents can be used alone or in combination of two or more. The stirring and mixing or kneading in the preparation of the varnish composition can be performed using, for example, a stirrer, a grinding machine, a three-roll mill, a ball mill, a bead mill, a homodisper, etc.

[0102] The substrate is not particularly limited as long as it has heat resistance that can withstand the heating conditions when volatilizing the organic solvent. Examples of such substrates include substrates (e.g., films) made of oriented polypropylene (OPP), polyethylene terephthalate (PET), polyethylene naphthalate, polyethylene isophthalate, polybutylene terephthalate, polyolefin, polyacetate, polycarbonate, polyphenylene sulfide, polyamide, polyimide, cellulose, ethylene-vinyl acetate copolymer, polyvinyl chloride, polyvinylidene chloride, synthetic rubber, liquid crystal polymer, and the like.

[0103] The heating conditions for volatilizing the organic solvent from the varnish composition applied to the substrate can be appropriately set according to the organic solvent used, etc. The heating conditions may be, for example, at 40 to 120° C. for 0.1 to 10 minutes.

[0104] A part of the solvent may remain in the first adhesive layer without being removed. The content of the solvent in the first adhesive layer may be, for example, 10 mass % or less based on the total mass of the first adhesive layer.

[0105] For the light irradiation in the curing step, it is preferable to use irradiation light having a wavelength in the range of 150 to 750 nm (for example, ultraviolet light). The light irradiation can be carried out using, for example, a low pressure mercury lamp, a medium pressure mercury lamp, a high pressure mercury lamp, an ultra-high pressure mercury lamp, a xenon lamp, a metal halide lamp, an LED light source, etc. The integrated light amount of the light irradiation can be appropriately set, but is, for example, 500 to 3000 mJ / cm. 2 It may be.

[0106] The second step is a step of laminating a second adhesive layer on the first adhesive layer. In the second step, for example, first, a second adhesive layer is formed on a substrate in the same manner as in the first step, except that (C) component such as (C1) component and (C2) component, (G) component, and other components added as necessary are used, and light irradiation is not performed, to obtain a second adhesive film. Next, the first adhesive film and the second adhesive film are bonded together to laminate the second adhesive layer on the first adhesive layer. In addition, in the second step, for example, a varnish composition (a varnish-like second adhesive composition) obtained using (C) component such as (C1) component and (C2) component, (G) component, and other components added as necessary is applied onto the first adhesive layer, and the organic solvent is volatilized, so that the second adhesive layer can also be laminated on the first adhesive layer.

[0107] Examples of the method for bonding the first adhesive film and the second adhesive film include hot pressing, roll lamination, vacuum lamination, etc. Lamination can be carried out under temperature conditions of, for example, 0 to 80°C.

[0108] A part of the solvent may remain in the second adhesive layer without being removed. The content of the solvent in the second adhesive layer may be, for example, 10 mass % or less based on the total mass of the second adhesive layer.

[0109] The third step is a step of laminating a third adhesive layer on the layer opposite the second adhesive layer of the first adhesive layer. In the third step, for example, first, a third adhesive layer is formed on a substrate in the same manner as in the second step to obtain a third adhesive film. Then, the third adhesive layer can be laminated on the layer opposite the second adhesive layer of the first adhesive layer by laminating the third adhesive film on the opposite side of the first adhesive film to the second adhesive film. In addition, in the third step, for example, a varnish composition (a varnish-like third adhesive composition) can be applied on the layer opposite the second adhesive layer of the first adhesive layer and the organic solvent can be volatilized to laminate the third adhesive layer on the first adhesive layer. The lamination method and conditions are the same as those in the second step.

[0110] A part of the solvent may remain in the third adhesive layer without being removed. The content of the solvent in the third adhesive layer may be, for example, 10 mass % or less based on the total mass of the third adhesive layer.

[0111] <Circuit connection structure and method for producing same> The circuit connection structure and the method for producing the same will be described below by taking as an example an embodiment in which the above-mentioned adhesive film for circuit connection 10 is used as the circuit connecting material.

[0112] Fig. 2 is a schematic cross-sectional view showing one embodiment of a circuit connection structure. As shown in Fig. 2, the circuit connection structure 100 includes a first circuit board 21 and a first circuit member 23 having a first electrode 22 formed on the main surface 21a of the first circuit board 21, a second circuit member 26 having a second electrode 25 formed on the main surface 24a of the second circuit board 24, and a circuit connection part 27 that includes a cured body of the circuit connection adhesive film 10, is disposed between the first circuit member 23 and the second circuit member 26, electrically connects the first electrode 22 and the second electrode 25 to each other via the conductive particles 4 (or a melted and solidified product of the conductive particles 4), and bonds the first circuit member 23 and the second circuit member 26.

[0113] The first circuit member 23 and the second circuit member 26 may be the same or different from each other. The first circuit member 23 and the second circuit member 26 may be a glass substrate or a plastic substrate on which electrodes are formed, a printed wiring board, a ceramic wiring board, a flexible wiring board, an IC chip, or the like. The first circuit board 21 and the second circuit board 24 may be formed of an inorganic material such as a semiconductor, glass, or ceramic, an organic material such as polyimide or polycarbonate, or a composite material such as glass / epoxy. Among these, since the circuit connection adhesive film 10A can be suitably used for COP mounting, the first circuit member 23 may be, for example, a plastic substrate made of an organic material such as polyimide, polycarbonate, polyethylene terephthalate, or cycloolefin polymer, and the second circuit board 24 may be, for example, an IC chip.

[0114] The first electrode 22 and the second electrode 25 may be electrodes containing metals such as gold, silver, tin, ruthenium, rhodium, palladium, osmium, iridium, platinum, copper, aluminum, molybdenum, titanium, and oxides such as indium tin oxide (ITO), indium zinc oxide (IZO), and indium gallium zinc oxide (IGZO). The first electrode 22 and the second electrode 25 may be electrodes formed by laminating two or more of these metals, oxides, and the like. An electrode formed by laminating two or more of these may have two or more layers, or three or more layers. When the first circuit member 23 is a plastic substrate, the first electrode 22 may be an electrode having a titanium layer on the outermost surface. The first electrode 22 and the second electrode 25 may be circuit electrodes or bump electrodes. At least one of the first electrode 22 and the second electrode 25 may be a bump electrode. The circuit connection structure shown in FIG. 2 is an embodiment in which the first electrode 22 is a circuit electrode and the second electrode 25 is a bump electrode.

[0115] The circuit connection portion 27 includes a cured body of the adhesive film 10 for circuit connection. The circuit connection portion 27 may be made of a cured body of the adhesive film 10 for circuit connection. The circuit connection portion 27 has, for example, a first cured body region 28 located on the first circuit member 23 side in the direction in which the first circuit member 23 and the second circuit member 26 face each other (hereinafter referred to as the "facing direction") and made of a cured body derived from the first adhesive layer other than the conductive particles 4, a second cured body region 29 located on the second circuit member 26 side in the facing direction and made of a cured body derived from the second adhesive layer, and conductive particles 4 interposed at least between the first electrode 22 and the second electrode 25 to electrically connect the first electrode 22 and the second electrode 25 to each other. As shown in FIG. 2, the circuit connection portion 27 does not have to have two distinct hardened body regions, the first hardened body region 28 and the second hardened body region 29, but may have a single hardened body region in which the hardened body derived from the first adhesive layer and the hardened body derived from the second adhesive layer are mixed.

[0116] Fig. 3 is a schematic cross-sectional view showing one embodiment of a method for producing a circuit connection structure. Fig. 3(a) and Fig. 3(b) are schematic cross-sectional views showing each step. As shown in Fig. 3, the method for producing a circuit connection structure 100 includes a step of interposing an adhesive film 10 for circuit connection between a first circuit member 23 having a first electrode 22 and a second circuit member 26 having a second electrode 25, and thermocompressing the first circuit member 23 and the second circuit member 26 to electrically connect the first electrode 22 and the second electrode 25 to each other.

[0117] Specifically, first, a first circuit member 23 including a first circuit board 21 and a first electrode 22 formed on a main surface 21a of the first circuit board 21, and a second circuit member 26 including a second circuit board 24 and a second electrode 25 formed on a main surface 24a of the second circuit board 24 are prepared.

[0118] Next, the first circuit member 23 and the second circuit member 26 are arranged so that the first electrode 22 and the second electrode 25 face each other, and the adhesive film for circuit connection 10 is arranged between the first circuit member 23 and the second circuit member 26. For example, as shown in FIG. 3(a), the adhesive film for circuit connection 10 is laminated on the first circuit member 23 so that the first adhesive layer 1 side faces the main surface 21a of the first circuit board 21. Next, the second circuit member 26 is arranged on the first circuit member 23 on which the adhesive film for circuit connection 10 is laminated so that the first electrode 22 on the first circuit board 21 and the second electrode 25 on the second circuit board 24 face each other.

[0119] Then, as shown in FIG. 3(b), the first circuit member 23, the circuit connection adhesive film 10A, and the second circuit member 26 are heated while the first circuit member 23 and the second circuit member 26 are pressed in the thickness direction to thermocompress the first circuit member 23 and the second circuit member 26 together. At this time, as shown by the arrow in FIG. 3(b), the second adhesive layer 2 contains a flowable uncured thermosetting resin component, so that it flows to fill the gaps between the second electrodes 25 and is cured by the heat of the thermocompression bonding. As a result, the first electrode 22 and the second electrode 25 are electrically connected to each other via the conductive particles 4, and the first circuit member 23 and the second circuit member 26 are bonded to each other, thereby obtaining the circuit connection structure 100 shown in FIG. 2.

[0120] In the manufacturing method of the circuit connection structure 100 of this embodiment, the first adhesive layer 1 can be said to be a layer in which a part of the first adhesive layer 1 is hardened by light irradiation, so that the conductive particles 4 are fixed in the first adhesive layer 1, and the first adhesive layer 1 hardly flows during thermocompression bonding, and the conductive particles are efficiently captured between the opposing electrodes, so that the connection resistance between the opposing first electrode 22 and second electrode 25 is reduced. In addition, by using a circuit connection adhesive film 10 having a second adhesive layer containing a cationic stabilizer, the resin removal property is improved and the connection gap (the distance between the connected opposing electrodes) (CG in FIG. 2) is reduced, so that the contact area between the conductive particles and the electrodes can be increased, and the connection resistance between the opposing first electrode 22 and second electrode 25 is further reduced. Furthermore, if the thickness of the first adhesive layer is 5.0 μm or less, the resin content between the opposing circuits is reduced, and the increase in the connection resistance between the opposing circuits can be further suppressed.

[0121] The heating temperature in thermocompression bonding can be set appropriately, and may be, for example, 50 to 250° C. The pressure is not particularly limited as long as it is within a range that does not damage the adherend, and in the case of COP mounting, for example, the area-equivalent pressure at the bump electrode may be 10 to 50 MPa, or may be 0.1 to 40 MPa. In addition, in the case of COG mounting, for example, the area-equivalent pressure at the bump electrode may be 10 to 100 MPa. The heating and pressurizing time may be in the range of 0.5 to 120 seconds.

[0122] From the viewpoint of ensuring good connection characteristics, the connection temperature when thermocompression bonding the first circuit member and the second circuit member may be 170 to 220°C, and may be 80% or more of the connection temperature 1 second after heating starts. Even in such a case, by using the adhesive film 10 for circuit connection, the connection gap CG can be made sufficiently small, and it is possible to achieve both reduced connection resistance and good connection reliability and adhesive strength. EXAMPLES

[0123] The present disclosure will be described in more detail below with reference to examples, although the present disclosure is not limited to these examples.

[0124] In the examples and comparative examples, the materials shown below were used as component (A), component (B1), component (B2), component (C1), component (C2), component (D), component (E), component (F), and component (G).

[0125] (A) Component: Conductive particles Conductive particle A-1: ​​Particles with an average particle size of 3.2 μm, with the surface of the plastic core plated with Ni and the outermost surface plated with Pd. Particle hardness: 10,000 to 18,000 N / mm 2 Conductive particle A-2: Particles with an average particle size of 3.2 μm, with the surface of the plastic core plated with Ni and the outermost surface plated with Pd. Particle hardness: 5,000 to 9,000 N / mm 2

[0126] (B) Component: Photocurable resin component Component (B1): radically polymerizable compound Radical polymerizable compound B1-1: VR-90 (bisphenol A type epoxy (meth)acrylate (bifunctional) (vinyl ester resin), manufactured by Resonac Co., Ltd.) Radical polymerizable compound B1-2: A-1000 (polyethylene glycol diacrylate (bifunctional), manufactured by Shin-Nakamura Chemical Co., Ltd.) Component (B2): Photoradical polymerization initiator Photoradical polymerization initiator B2-1: "Omnirad 907 (a compound having an α-aminoalkylphenone structure, manufactured by IGM Resins)"

[0127] (C) Component: Thermosetting resin component Component (C1): Cationic polymerizable compound Cationic polymerizable compound C1-1: ETERNACOLL OXBP (oxetane compound, manufactured by Ube Industries, Ltd.) Cationic polymerizable compound C1-2: EHPE3150 (alicyclic epoxy compound, manufactured by Daicel Corporation) Cationic polymerizable compound C1-3: Celloxide 2021P (alicyclic epoxy compound, manufactured by Daicel Corporation) Cationic polymerizable compound C1-4: jER1007 (epoxy compound, manufactured by Mitsubishi Chemical Corporation) Component (C2): Thermal cationic polymerization initiator Thermal cationic polymerization initiator C2-1: CXC-1821 (N-(p-methoxybenzyl)-N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate, manufactured by King Industries)

[0128] (D) Component: Thermoplastic resin Thermoplastic resin D-1: Phenototo FX-293 (phenoxy resin, manufactured by Nippon Steel Chemical & Material Co., Ltd.) Thermoplastic resin D-2: Phenototo YP-70 (phenoxy resin, manufactured by Nippon Steel Chemical & Material Co., Ltd.)

[0129] Component (E): Coupling agent Coupling agent E-1: SH-6040 (3-glycidoxypropyltrimethoxysilane, manufactured by Dow Corning Toray Co., Ltd.)

[0130] (F) Component: Filler Filler F-1: ADMAFINE SE2050 (silica particles, manufactured by ADMATECHS Co., Ltd.) Filler F-2: Aerosil R805 (silica fine particles, manufactured by Evonik Industries AG)

[0131] (G) Component: Cationic stabilizer Stabilizer G-1: 4-hydroxyphenyl-dimethylsulfonium-methylsulfate (manufactured by Sika Hamatite Co., Ltd.)

[0132] <Preparation of the first adhesive layer> (Adhesive layers P-1 and P-2) The materials shown in Table 1 were mixed into MEK in the composition ratios shown in Table 1 (the values ​​in Table 1 indicate the non-volatile content) to obtain a varnish composition (non-volatile content concentration: 50% by mass), which was then coated onto a release-treated PET (polyethylene terephthalate) film while applying a magnetic field, and the organic solvent and the like were dried with hot air at 70°C for 5 minutes to obtain a composition layer made of a composition containing each component. The composition layers were coated so that the thickness after drying would be 3.5 μm. Thereafter, the composition layers were irradiated with light (UV irradiation: metal halide lamp, accumulated light amount: 1500 to 2500 mJ / cm2) to obtain a composition layer made of a composition containing each component. 2 ) to prepare a first adhesive layer in which conductive particles are dispersed. The thickness of this layer was measured using a contact thickness meter.

[0133] In addition, when the thickness of the first adhesive layer is smaller than the thickness (diameter) of the conductive particles, the thickness of the conductive particles is reflected when the thickness of the layer is measured using a contact thickness meter, and the thickness of the area where the conductive particles are present is measured. Therefore, after producing a two-layer adhesive film in which the first adhesive layer and the second adhesive layer are laminated, the thickness of the first adhesive layer located in the space between adjacent conductive particles was measured using a scanning electron microscope by the following method. The results are shown in Table 1. [Measurement method] The adhesive film was sandwiched between two pieces of glass (thickness: approximately 1 mm) and a resin composition consisting of 100 g of bisphenol A type epoxy resin (product name: JER811, manufactured by Mitsubishi Chemical Corporation) and 10 g of a hardener (product name: Epomount Hardener, manufactured by Refine Tech Co., Ltd.) was poured into the mold. The cross section was then polished using a polishing machine, and the thickness of each layer was measured using a scanning electron microscope (SEM, product name: SE-8020, manufactured by Hitachi High-Tech Science Corporation).

[0134] The particle density of the first adhesive layer was measured and found to be approximately 18,000 particles / mm 2 It was.

[0135] [Table 1]

[0136] <Preparation of the second adhesive layer> A varnish composition (non-volatile content concentration: 60% by mass) was obtained by mixing the materials shown in Table 2 with MEK in the composition ratio shown in Table 2 (the numbers in Table 2 indicate the non-volatile content), and then the varnish was coated on a release-treated PET (polyethylene terephthalate) film and the organic solvent was dried with hot air at 70°C for 5 minutes to produce a second composition layer made of a composition containing each component. The composition layers were coated so that the thickness after drying was the thickness shown in Table 2. The thickness here was measured using a contact thickness meter.

[0137] [Table 2]

[0138] (Examples 1 to 4 and Comparative Examples 1 to 4) [Preparation of adhesive film] Using the first adhesive layer and second adhesive layer prepared above, adhesive films having the configurations shown in Table 3 were prepared. For example, in the adhesive film of Example 1, the first adhesive layer formed from composition P-1 was attached to the second adhesive layer formed from composition S-1 while applying a temperature of 50 to 60°C to obtain the adhesive film of Example 1. For the adhesive films of Examples 2 to 4 and Comparative Examples 1 to 4, adhesive films having the configurations shown in Table 3 were prepared in the same manner as in Example 1.

[0139] [Measurement of minimum melt viscosity] The adhesive film was laminated with a laminator to a thickness of 500 μm or more to obtain a laminate. The release-treated PET was peeled off from the obtained laminate and cut into a 10.0 mm × 10.0 mm measurement sample. The minimum melt viscosity of the obtained measurement sample was measured using a viscoelasticity measuring device (product name: ARES-G2, manufactured by TA Instruments, heating rate: 10 ° C / min).

[0140] [Fabrication of circuit connection structure] Using each of the adhesive films for circuit connection in Examples 1 to 4 and Comparative Examples 1 to 4, a circuit connection structure was produced according to the following procedure.

[0141] First, a plastic substrate with a Ti / Al / Ti circuit (thickness: 0.05 mm) was prepared as the first circuit member, and an IC chip with gold bumps (area of ​​bump electrodes: 840 μm 2 , space between bump electrodes (pitch): 24 μm, height of bump electrode: 8 μm) were prepared.

[0142] The adhesive film for circuit connection was cut to a width of 2.0 mm, and placed on the first circuit member so that the first adhesive layer and the first circuit member were in contact. Using a thermal temporary compression device (LD-06, manufactured by Ohashi Manufacturing Co., Ltd.) consisting of a stage made of a ceramic heater and a tool (8 mm x 50 mm), the adhesive film for circuit connection was heated at 70°C and 0.98 MPa (10 kgf / cm 2 ) for 2 seconds to attach the circuit connection adhesive film to the first circuit member, and then the release film on the side of the circuit connection adhesive film opposite the first circuit member was peeled off. Next, the circuit electrodes of the first circuit member and the bump electrodes of the second circuit member were aligned, and then a heat tool of 8 mm x 45 mm was used to heat and press the circuit connection structure for 5 seconds under conditions of a connection temperature of 180°C and an area-equivalent pressure of 20 MPa at the bump electrodes, with 50 μm-thick Teflon (registered trademark) interposed therebetween, to produce a circuit connection structure.

[0143] (Connection Gap Measurement) The entire circuit connection structure produced above was sealed with a casting resin consisting of 100 parts by mass of a bis-A type epoxy resin (product name: JER811, manufactured by Mitsubishi Chemical Corporation) and 10 parts by mass of a curing agent (product name: Epomount curing agent, manufactured by Refine Tech Co., Ltd.) to produce a casting sample. The casting sample was polished with a polishing machine (manufactured by Refine Tech Co., Ltd.) to produce a cross-sectional sample that allows confirmation of the cross section of the circuit connection structure. The produced cross-sectional sample was examined using a scanning electron microscope (SU8000, manufactured by Hitachi High-Tech Corporation) at a magnification of 10,000 times to measure the distance between the bump electrode and the circuit electrode.

[0144] (Evaluation of connection resistance: initial) The initial connection resistance (conduction resistance) of the produced circuit connection structure was measured by a four-terminal method. For the measurement, a constant current (1 mA) was applied between the circuit electrode of the first circuit member and the circuit electrode of the second circuit member (connection portion) of the circuit connection structure using a constant current power supply R-6145 manufactured by Advantest Corporation. The potential difference of the connection portion when the current was applied was measured using a digital multimeter (R-6557) manufactured by Advantest Corporation. The potential difference was measured at 14 random points, the average value was calculated, and the results were evaluated based on the following criteria. A: Less than 0.8Ω B: 0.8Ω or more and less than 1.0Ω C: 1.0Ω or more

[0145] (Evaluation of connection resistance: after reliability test) The produced circuit connection structure was stored for 64 hours in an environment of 110° C. and 85% RH. Thereafter, the average value of the potential difference of the connection was determined in the same manner as above, and evaluated based on the following criteria. A: Less than 0.8Ω B: 0.8Ω or more and less than 1.2Ω C: 1.2Ω or more

[0146] [Adhesive strength] A glass substrate (thickness: 0.5 mm) with SiN (silicon nitride) was prepared as the first circuit member, and an IC chip with gold bumps (area of ​​bump electrodes: 840 μm) was prepared as the second circuit member. 2 , space between bump electrodes (pitch): 24 μm, height of bump electrode: 8 μm) were prepared.

[0147] The adhesive film for circuit connection was cut to a width of 2.0 mm, and placed on the first circuit member so that the first adhesive layer and the first circuit member were in contact. Using a thermal temporary compression device (LD-06, manufactured by Ohashi Manufacturing Co., Ltd.) consisting of a stage made of a ceramic heater and a tool (8 mm x 50 mm), the adhesive film for circuit connection was heated at 70°C and 0.98 MPa (10 kgf / cm 2) for 2 seconds to attach the circuit connection adhesive film to the first circuit member, and then the release film on the side of the circuit connection adhesive film opposite the first circuit member was peeled off. Next, the circuit electrodes of the first circuit member and the bump electrodes of the second circuit member were aligned, and then a heat tool measuring 8 mm x 45 mm was used to heat and press the circuit connection structure for 5 seconds under conditions of a connection temperature of 180°C and an area-converted pressure of 20 MPa at the bump electrodes, with 50 μm-thick Teflon (registered trademark) interposed therebetween, to produce a circuit connection structure.

[0148] The shear strength of the fabricated circuit connection structures was measured using a shear adhesion tester (Nordson Advanced Technology, 4000Plus) when peeling the IC chip from the glass substrate (peel speed: 16 μm / s, temperature: 25°C), and evaluated based on the following criteria. A: Shear strength is 35MPa or more B: Shear strength is 30MPa or more and less than 35MPa C: Shear strength is less than 30MPa

[0149] [Table 3] [Explanation of symbols]

[0150] 1...first adhesive layer, 2...second adhesive layer, 3...adhesive component, 4...conductive particles, 10...adhesive film for circuit connection, 21...first circuit board, 22...first electrode (circuit electrode), 23...first circuit member, 24...second circuit board, 25...second electrode (bump electrode), 26...second circuit member, 27...circuit connection part, 100...circuit connection structure.

Claims

1. a step of interposing an adhesive film for circuit connection containing conductive particles between a first circuit member having a first electrode and a second circuit member having a second electrode, and thermocompressing the first circuit member and the second circuit member to electrically connect the first electrode and the second electrode to each other, the adhesive film for circuit connection has a first adhesive layer containing conductive particles and a first thermosetting resin component, and a second adhesive layer provided on the first adhesive layer and containing a second thermosetting resin component, The second thermosetting resin component comprises a cationic polymerizable compound, a thermal cationic polymerization initiator, and a cationic stabilizer that reacts with a cationic species generated by thermal decomposition of the thermal cationic polymerization initiator.

2. 2. The method for producing a circuit connection structure according to claim 1, wherein the cation stabilizer is at least one compound selected from the group consisting of a thiourea compound, a 4-alkylthiophenol compound, and a 4-hydroxyphenyl-dialkylsulfonium salt.

3. 2. The method for producing a circuit connection structure according to claim 1, wherein the content of the cationic stabilizer in the second adhesive layer is 5 to 20 parts by mass per 100 parts by mass of the thermal cationic polymerization initiator.

4. The method for producing a circuit connection structure according to claim 1, wherein the content of the cationic stabilizer in the second adhesive layer is 0.01 to 2.0 mass % based on the total mass of the second adhesive layer.

5. 2. The method for producing a circuit connection structure according to claim 1, wherein the cationically polymerizable compound is at least one compound selected from the group consisting of an oxetane compound and an alicyclic epoxy compound.

6. the first thermosetting resin component comprises a cationic polymerizable compound and a thermal cationic polymerization initiator; The first adhesive layer further contains a cured product of a photocurable resin component, The method for producing a circuit connection structure according to claim 1 , wherein the photocurable resin component contains a radically polymerizable compound and a photoradical polymerization initiator.

7. The method for producing a circuit connection structure according to claim 1 , wherein the first adhesive layer has a thickness of 5.0 μm or less.

8. A first adhesive layer containing conductive particles and a first thermosetting resin component, and a second adhesive layer provided on the first adhesive layer and containing a second thermosetting resin component, The second thermosetting resin component comprises a cationic polymerizable compound, a thermal cationic polymerization initiator, and a cationic stabilizer that reacts with a cationic species generated by thermal decomposition of the thermal cationic polymerization initiator.

9. 9. The adhesive film for circuit connection according to claim 8, wherein the cationic stabilizer is at least one compound selected from the group consisting of thiourea compounds, 4-alkylthiophenol compounds, and 4-hydroxyphenyl-dialkylsulfonium salts.

10. 9. The adhesive film for circuit connection according to claim 8, wherein the content of the cationic stabilizer in the second adhesive layer is 5 to 20 parts by mass per 100 parts by mass of the thermal cationic polymerization initiator.

11. The adhesive film for circuit connection according to claim 8, wherein the content of the cationic stabilizer in the second adhesive layer is 0.01 to 2.0 mass % based on the total mass of the second adhesive layer.

12. 9. The adhesive film for circuit connection according to claim 8, wherein the cationically polymerizable compound is at least one compound selected from the group consisting of oxetane compounds and alicyclic epoxy compounds.

13. the first thermosetting resin component comprises a cationic polymerizable compound and a thermal cationic polymerization initiator; The first adhesive layer further contains a cured product of a photocurable resin component, The adhesive film for circuit connection according to claim 8 , wherein the photocurable resin component comprises a radically polymerizable compound and a photoradical polymerization initiator.

14. 9. The adhesive film for circuit connection according to claim 8, wherein the first adhesive layer has a thickness of 5.0 μm or less.

15. a first circuit member having a first electrode; a second circuit member having a second electrode; a circuit connection portion disposed between the first circuit member and the second circuit member, the circuit connection portion electrically connecting the first electrode and the second electrode to each other; Equipped with The circuit connection portion comprises a cured product of the adhesive film for circuit connection according to any one of claims 8 to 14. Circuit connection structure.

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