Cosmetics

Abstract

Provided is a cosmetic that contains a component (A) and a component (B), spreads well, is not sticky, provides a soft coating, and gives a good feeling when used.　Component (A) is one or more selected from 1,1,1,3,5,5,5-heptamethyl-3-alkyl (C10-14) trisiloxanes, and component (B) is a silicone resin having a thermosoftening point of 50°C or higher and an average unit formula of RaSiO(4-a) / 2 (where R is the same or different monovalent optionally substituted hydrocarbon group, and a is a number from 1.2 to 2).

Description

[Technical field]

[0001] The present invention relates to a cosmetic that can be used as a skin cosmetic or a make-up cosmetic. Background technology

[0002] In recent years, the demand for cosmetics has become ever more diverse, and in response to this, the product forms have also become more diverse, not only in terms of item composition such as foundation, makeup base, sunscreen, lipstick, nail polish, and face powder, but also by further subdividing these, the form elements have been added such as liquid, powder, solid, emulsion, etc.

[0003] In particular, recent cosmetic products are required to have various physical and chemical properties, such as better water resistance and sweat resistance (sebum resistance) than ever before, as well as good usability when applied and abrasion resistance.

[0004] To satisfy the above requirements, the following have been proposed as technologies using silicone resins with film-forming ability: skin cosmetics as disclosed in JP-A-61-158910, additives for make-up cosmetics as disclosed in JP-A-02-42008, cosmetics as disclosed in JP-A-04-312511, and cosmetics as disclosed in WO2009 / 136486.

[0005] Furthermore, Japanese Patent Application Laid-Open No. 9-12431 proposes an invention for a cosmetic material containing a fluorine-containing silicone resin which is excellent in water resistance and sweat resistance and provides a soft coating. Summary of the Invention

[0006] The present invention aims to provide a cosmetic preparation which spreads well, is not sticky, gives a soft film and is excellent in feel when used.

[0007] The present invention provides a cosmetic preparation containing the following components (A) and (B): (A) one or more selected from 1,1,1,3,5,5,5-heptamethyl-3-alkyl(C10-14)trisiloxane (B) Average unit formula RaSiO (4-a) / 2(wherein R represents a monovalent substituted or unsubstituted hydrocarbon group, and a is a number of 1.2 to 2), Cone Resin

[0008] The cosmetic composition of the present invention spreads well and has a soft feel when applied to the skin, and is useful for preventing makeup from coming off due to sweat, etc. Furthermore, the cosmetic composition of the present invention has good usability properties such that it is not easily washed off even by washing with water, and has good stability over time. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0009] Component (A) is one or more selected from 1,1,1,3,5,5,5-heptamethyl-3-alkyl (C10-14) trisiloxanes, which may be in an oil form at room temperature.

[0010] Non-limiting examples of component (A) include (A-1) 1,1,1,3,5,5,5-heptamethyl-3-decyltrisiloxane, (A-2) 1,1,1,3,5,5,5-heptamethyl-3-dodecyltrisiloxane, and (A-3) 1,1,1,3,5,5,5-heptamethyl-3-tetradecyltrisiloxane. Each of the components (A-1), (A-2), and (A-3) can be used alone as component (A), but when component (A) is used as the sole component, it is preferable to use component (A-2).

[0011] As the component (A), a mixture of the components (A-1) and (A-2), a mixture of the components (A-1) and (A-3), a mixture of the components (A-2) and (A-3), or a mixture of the components (A-1), (A-2), and (A-3) can be used.

[0012] When component (A) is used as a mixture of components (A-1) and (A-2) or components (A-2) and (A-3), the content of component (A-2) in 100% by mass of the mixture is preferably 50% by mass or more, more preferably 60% by mass or more, and even more preferably 70% by mass or more.

[0013] When the (A) component is used as a mixture of the (A-1) component and the (A-3) component, the (A-1) component is preferably 20 to 80 mass%, more preferably 30 to 70 mass%, and even more preferably 40 to 60 mass%, based on 100 mass% of the total amount of the (A-1) and (A-3) components. In this case, the (A-3) component is preferably 80 to 20 mass%, more preferably 70 to 30 mass%, and even more preferably 60 to 40 mass%.

[0014] When the (A) component is used as a mixture of the (A-1), (A-2) and (A-3) components, the (A-1) component is preferably 5 to 80% by mass, more preferably 10 to 70% by mass, and even more preferably 20 to 60% by mass, out of a total of 100% by mass of the (A-1), (A-2) and (A-3) components. In this case, the (A-2) component is preferably 10 to 70% by mass, more preferably 20 to 60% by mass, and even more preferably 20 to 50% by mass. In this case, the (A-3) component is preferably 10 to 70% by mass, more preferably 20 to 60% by mass, and even more preferably 20 to 50% by mass.

[0015] The silicone resin of component (B) has the average unit formula RaSiO (4-a) / 2 (In the formula, R represents the same or different monovalent substituted or unsubstituted hydrocarbon group, and a is a number of 1.2 to 2.) and has a thermal softening point of 50°C or higher.

[0016] The monovalent substituted or unsubstituted hydrocarbon group of R in the above structural unit can be, for example, one having 1 to 12 carbon atoms, particularly 1 to 8 carbon atoms, excluding the substituent. Non-limiting examples of the substituted or unsubstituted monovalent hydrocarbon group of R include alkyl groups such as methyl, ethyl, propyl, and butyl; alkenyl groups such as vinyl and allyl; aryl groups such as phenyl and tolyl; cycloalkyl groups such as cyclohexyl and cyclooctyl; or groups in which the hydrogen atom bonded to the carbon atom of these groups is substituted with a halogen atom, a cyano group, an amino group, or the like, a cyanomethyl group, a γ-aminopropyl group, and an N-(β-aminoethyl)-γ-aminopropyl group. In view of ease of synthesis and water repellency, a methyl group, an ethyl group, and a phenyl group are preferred.

[0017] In the above average unit formula, if a is less than 1.2, the film formed on the skin after application becomes hard. When used as a cosmetic, this tends to affect the feel of the coating, such as tension or stickiness. On the other hand, when a exceeds 2 in the above average unit formula, the coating tends to become viscous, which may affect the feel of the coating, such as stickiness or greasiness. In either case, it is difficult to obtain sufficient coating durability.

[0018] Specifically, the silicone resin of component (B) is R 3 SiO 1 / 2 Units, R 2 SiO 2 / 2 Units, RSiO 3 / 2 Units and SiO 4 / 2 A silicone resin consisting of a combination of units is preferred. The combination of these four units results in an average unit formula RaSiO (4-a ) / 2 In the formula, a may be 1.2 to 2. From the viewpoint of obtaining sufficient coating durability, the component (B) R in silicone resin 2 SiO 2 / 2 The content of the unit in the structure is preferably 30 mol % or less.

[0019] The silicone resin of component (B) may be a mixture of multiple silicone resins that satisfy the above average unit formula. The use of such a mixture is preferred because it makes it easier to adjust the film strength, durability, and favorable feel of the resulting cosmetic.

[0020] When using a mixture of multiple silicone resins that satisfy the above average unit formula as the silicone resin of component (B), R 3 SiO 1 / 2 Units and RSiO 3 / 2 Silicone resin with R units as its main component 3 SiO 1 / 2 Units and SiO 4 / 2 Silicone resins containing the unit as the main component can be used in a ratio of 1 / 4-4 / 1.

[0021] If the silicone resin of component (B) has a thermal softening point below 50°C, the film formed after application of the cosmetic to the skin will feel sticky, resulting in poor usability. The thermal softening point can be measured based on the softening point measurement method (return ball method) of JIS K2207. The silicone resin of component (B) preferably has a thermal softening point of 60°C or higher, more preferably 70°C or higher.

[0022] The cosmetic preparation of the present invention preferably contains the components (A) and (B) in a total amount of 1 to 50 mass %, more preferably 3 to 30 mass %, and even more preferably 3 to 20 mass %.

[0023] With respect to the content of each component in the cosmetic of the present invention, where the total content of components (A) and (B) in the cosmetic is 100% by mass, the content of component (A) is preferably 50 to 95% by mass, and more preferably 60 to 90% by mass, and the content of component (B) is preferably 5 to 50% by mass, and more preferably 10 to 40% by mass.

[0024] In addition to the components (A) and (B), the cosmetic of the present invention may contain other components that are typically used in cosmetic preparations depending on the type of cosmetic preparation. For example, the cosmetic of the present invention may contain the following components selected as appropriate:

[0025] The cosmetic of the present invention may contain, as an oily component, but is not limited to, for example, solid paraffin, ceresin, beeswax, carnauba wax, Japan wax, candelilla wax, stearic acid, cetanol, cholesterol, microcrystalline wax, petrolatum, lanolin, partially hydrogenated oil, squalene, liquid paraffin, castor oil, diglyceride, triglyceride, higher fatty acid, higher alcohol, perfluoropolyether, perfluorodecalin, perfluorooctane, ester oil, octyldodecyl myristate, octyldodecyl oleate, neopentyl glycol dioctanoate, or combinations thereof.

[0026] The cosmetic composition of the present invention may contain, as an aqueous component, for example, glycerin, sorbitol, propylene glycol, 1,3-butylene glycol, polyethylene glycol, etc., but is not limited thereto. The aqueous dispersion medium may contain, for example, alcohol, carboxyvinyl polymers, cellulose derivatives, sodium alginate, ethanol, or combinations thereof.

[0027] The cosmetic composition of the present invention may contain, as a surfactant, one or a combination of two or more selected from the following group, but is not limited thereto.

[0028] anionic emulsifiers such as sodium alkylbenzenesulfonates, such as sodium hexylbenzenesulfonate, sodium octylbenzenesulfonate, sodium decylbenzenesulfonate, sodium dodecylbenzenesulfonate, sodium cetylbenzenesulfonate, sodium myristylbenzenesulfonate; sodium alkylnaphthylsulfonates, such as sodium butylnaphthylsulfonate; sodium polyoxyethylene monoalkylether sulfates, such as sodium polyoxyethylene octyl ether sulfate, sodium polyoxyethylene decyl ether sulfate, sodium polyoxyethylene icosyl ether sulfate; sodium polyoxyethylene mono(alkylphenyl)ether sulfates, such as sodium polyoxyethylene decylphenyl ether sulfate, or combinations thereof.

[0029] Cationic emulsifiers such as quaternary ammonium salts such as octyltrimethylammonium chloride, dodecyltrimethylammonium chloride, hexadecyltrimethylammonium chloride, tallow trimethylammonium chloride, coconut trimethylammonium chloride, octyldimethylbenzylammonium chloride, decyldimethylbenzylammonium chloride, dioctadecyldimethylammonium chloride, or combinations thereof.

[0030] Glycerol fatty acid esters such as glyceryl monolaurate, glyceryl monomyristate, glyceryl monostearate, glyceryl monooleate; polyglycerol fatty acid esters, sorbitan fatty acid esters, polyoxyethylene glycerol fatty acid esters, polyoxyethylene sorbitan fatty acid esters and polyoxyethylene fatty acid esters having similar fatty acid residues; nonionic emulsifiers such as polyoxyethylene alkyl ethers such as polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, or combinations thereof.

[0031] The cosmetic composition of the present invention further includes, as a powder, inorganic powders such as talc, kaolin, sericite, muscovite, synthetic mica, phlogopite, red mica, biotite, lithian mica, vermiculite, magnesium carbonate, calcium carbonate, diatomaceous earth, magnesium silicate, calcium silicate, aluminum silicate, barium silicate, barium sulfate, strontium silicate, metal tungstate, silica, hydroxyapatite, zeolite, boron nitride, ceramic powder, etc.; organic powders such as nylon powder, polyethylene powder, benzoguanamine powder, ethylene tetrafluoride powder, distyrenebenzene pinhole polymer powder, microcrystalline cellulose, silicone rubber, silicone resin powder; inorganic white pigments such as titanium oxide and zinc oxide; inorganic red pigments such as iron oxide (red oxide) and iron titanate; inorganic brown pigments such as γ-iron oxide; inorganic yellow pigments such as yellow iron oxide and ocher; inorganic black pigments such as black iron oxide and carbon black; mango violet, cobalt bicarbonate, Inorganic purple pigments such as oret, inorganic green pigments such as chromium oxide, chromium hydroxide, and cobalt titanate, inorganic blue pigments such as ultramarine and Prussian blue, pearl pigments such as titanium dioxide-coated mica, titanium dioxide-coated bismuth oxychloride, bismuth oxychloride, titanium dioxide-coated talc, fish scale foil, and colored titanium dioxide-coated mica, metal powder pigments such as aluminum powder and copper powder, Red No. 201, Red No. 202, Red No. 204, Red No. 205, Red No. 220, Red No. 226, and Red No. 228 organic pigments such as Red No. 3, Red No. 104, Red No. 106, Red No. 227, Red No. 203, Red No. 401, Red No. 505, Orange No. 205, Yellow No. 4, Yellow No. 5, Yellow No. 202, Yellow No. 203, Green No. 3 and Blue No. 1; organic pigments such as zirconium, barium or aluminum lakes; natural pigments such as chlorophyll, beta-carotene, or combinations thereof.

[0032] The cosmetic preparation of the present invention may contain, without limitation, other ingredients such as coloring agents such as organic pigments and organic dyes, preservatives, antioxidants, colorants, thickeners, pH adjusters, fragrances, UV absorbers, moisturizers, blood circulation promoters, cooling agents, antiperspirants, bactericides, and skin activators, as long as they do not impair the objectives and effects of the present invention.

[0033] The cosmetic of the present invention may also contain a desired amount of water depending on the type and formulation of the cosmetic.

[0034] The cosmetic of the present invention may be further modified depending on the type of cosmetic, and may include, but is not limited to, for example, squalane, liquid paraffin, isoparaffin, petrolatum, microcrystalline wax, ozokerite, ceresin, myristic acid, palmitic acid, stearic acid, oleic acid, isostearic acid, cetyl alcohol, stearyl alcohol, hexadecyl alcohol, oleyl alcohol, cetyl-2-ethylhexanoate, 2-ethylhexyl palmitate, 2-octyldodecyl myristate, 2-octyldodecyl gum ester, neopentyl glycol-2-ethylhexyl ether, glyceryl ester ... The composition may contain one or more selected from various hydrocarbons such as xanthate, isooctyl triglyceride, 2-octyldodecyl oleate, isopropyl myristate, isopropyl palmitate, isostearic triglyceride, coconut oil fatty acid triglyceride, olive oil, avocado oil, beeswax, myristyl myristate, mink oil, lanolin, higher fatty acids, oils and fats, esters, higher alcohols, waxes, silicone oils, and other oils, ultraviolet absorbers, antioxidants, preservatives, surfactants, moisturizers, fragrances, water, alcohol, thickeners, and the like.

[0035] The cosmetic of the present invention is preferably in any one of the following formulations: liquid, powder, solid, or emulsion.

[0036] The cosmetic of the present invention is preferably a skin cosmetic or a make-up cosmetic selected from a makeup base, a foundation, a sunscreen, a lipstick, an eyeliner, a mascara, and a skin cream.

[0037] The cosmetic of the present invention includes the following inventions.

[0038] (1) A cosmetic preparation containing the following components (A) and (B): (A) one or more selected from 1,1,1,3,5,5,5-heptamethyl-3-alkyl(C10-14)trisiloxanes; (B) Average unit formula RaSiO (4-a) / 2 (wherein R may be the same or different and represents a monovalent substituted or unsubstituted hydrocarbon group, and a is a number of 1.2 to 2), Silicone resin with a thermal softening point of 50°C or higher

[0039] (2) The cosmetic preparation according to (1), wherein the component (A) is one or more selected from the group consisting of (A-1) 1,1,1,3,5,5,5-heptamethyl-3-decyltrisiloxane, (A-2) 1,1,1,3,5,5,5-heptamethyl-3-dodecyltrisiloxane, and (A-3) 1,1,1,3,5,5,5-heptamethyl-3-tetradecyltrisiloxane.

[0040] (3) The cosmetic preparation according to (1), wherein the component (A) is one component selected from the group consisting of (A-1) 1,1,1,3,5,5,5-heptamethyl-3-decyltrisiloxane, (A-2) 1,1,1,3,5,5,5-heptamethyl-3-dodecyltrisiloxane, and (A-3) 1,1,1,3,5,5,5-heptamethyl-3-tetradecyltrisiloxane.

[0041] (4) The cosmetic preparation according to (1), wherein the component (A) is two components selected from the group consisting of (A-1) 1,1,1,3,5,5,5-heptamethyl-3-decyltrisiloxane, (A-2) 1,1,1,3,5,5,5-heptamethyl-3-dodecyltrisiloxane, and (A-3) 1,1,1,3,5,5,5-heptamethyl-3-tetradecyltrisiloxane, and the two components are either the component (A-1) and the component (A-2), the component (A-1) and the component (A-3), or the component (A-2) and the component (A-3).

[0042] (5) The cosmetic preparation according to (1), wherein the component (A) is composed of three components: (A-1) 1,1,1,3,5,5,5-heptamethyl-3-decyltrisiloxane, (A-2) 1,1,1,3,5,5,5-heptamethyl-3-dodecyltrisiloxane, and (A-3) 1,1,1,3,5,5,5-heptamethyl-3-tetradecyltrisiloxane.

[0043] (6) The cosmetic preparation according to (1), wherein the component (A) is two components selected from the group consisting of (A-1) 1,1,1,3,5,5,5-heptamethyl-3-decyltrisiloxane, (A-2) 1,1,1,3,5,5,5-heptamethyl-3-dodecyltrisiloxane, and (A-3) 1,1,1,3,5,5,5-heptamethyl-3-tetradecyltrisiloxane, wherein the two components are the component (A-1) and the component (A-2) or the component (A-2) and the component (A-3), and the content of the component (A-2) is 50 mass% or more.

[0044] (7) The cosmetic preparation according to (1), wherein the component (A) is two components selected from (A-1) 1,1,1,3,5,5,5-heptamethyl-3-decyltrisiloxane, (A-2) 1,1,1,3,5,5,5-heptamethyl-3-dodecyltrisiloxane, and (A-3) 1,1,1,3,5,5,5-heptamethyl-3-tetradecyltrisiloxane, wherein the two components are the component (A-1) and the component (A-2) or the component (A-2) and the component (A-3), and the content of the component (A-2) is 60 mass% or more.

[0045] (8) The cosmetic preparation according to (1), wherein the component (A) is two components selected from (A-1) 1,1,1,3,5,5,5-heptamethyl-3-decyltrisiloxane, (A-2) 1,1,1,3,5,5,5-heptamethyl-3-dodecyltrisiloxane, and (A-3) 1,1,1,3,5,5,5-heptamethyl-3-tetradecyltrisiloxane, wherein the mixture is a mixture of the component (A-1) and the component (A-2) or the component (A-2) and the component (A-3), and the content of the component (A-2) is 70 mass% or more.

[0046] (9) The cosmetic preparation according to (1), in which the component (A) is used as a mixture of the components (A-1) and (A-3), and the combined amount of the components (A-1) and (A-3) is 20 to 80 mass% and the amount of the component (A-3) is 80 to 20 mass%, relative to 100 mass% of the total amount of the components (A-1) and (A-3).

[0047] (10) The cosmetic preparation according to (1), in which the component (A) is used as a mixture of the components (A-1) and (A-3), and the combined amount of the components (A-1) and (A-3) is 30 to 70 mass% and the amount of the component (A-3) is 70 to 30 mass%, relative to 100 mass% of the total amount of the components (A-1) and (A-3).

[0048] (11) The cosmetic preparation according to (1), in which the component (A) is used as a mixture of the components (A-1) and (A-3), and the combined amount of the components (A-1) and (A-3) is 40 to 60 mass% and the amount of the component (A-3) is 60 to 40 mass%, relative to 100 mass% of the total amount of the components (A-1) and (A-3).

[0049] (12) The cosmetic preparation according to (1), in which the component (A) is used as a mixture of the components (A-1), (A-2), and (A-3), and in which the total of the components (A-1), (A-2), and (A-3) is 100% by mass, the component (A-1) accounts for 5 to 80% by mass, the component (A-2) accounts for 10 to 70% by mass, and the component (A-3) accounts for 10 to 70% by mass.

[0050] (13) The cosmetic preparation according to (1), in which the component (A) is used as a mixture of the components (A-1), (A-2), and (A-3), and in which the total of the components (A-1), (A-2), and (A-3) is 10 to 70 mass% of the component (A-1), 20 to 60 mass% of the component (A-2), and 20 to 60 mass% of the component (A-3).

[0051] (14) The cosmetic preparation according to (1), in which the component (A) is used as a mixture of the components (A-1), (A-2), and (A-3), and in which the total of the components (A-1), (A-2), and (A-3) is 100% by mass, the component (A-1) accounts for 20 to 60% by mass, the component (A-2) accounts for 20 to 50% by mass, and the component (A-3) accounts for 20 to 50% by mass.

[0052] (15) The silicone resin of component (B) is R 3 SiO 1 / 2 Units and RSiO 3 / 2 Silicone resin with unit as the main component and R 3 SiO 1 / 2 Units and SiO 4 / 2 A cosmetic material according to any one of (1) to (14) above, which is used as a mixture of silicone resins whose main component is the unit.

[0053] (16) The silicone resin of component (B) is R 3 SiO 1 / 2 Units and RSiO 3 / 2 Silicone resin with unit as the main component and R 3 SiO 1 / 2 Units and SiO 4 / 2 It is used as a mixture of silicone resins whose main component is the unit. The cosmetic preparation according to any one of (1) to (14), wherein the monovalent substituted or unsubstituted hydrocarbon group of R in the structural unit is selected from alkyl groups such as methyl, ethyl, propyl, and butyl; alkenyl groups such as vinyl and allyl; aryl groups such as phenyl and tolyl; cycloalkyl groups such as cyclohexyl and cyclooctyl; or groups in which the hydrogen atom bonded to the carbon atom of any of these groups has been substituted with a halogen atom, a cyano group, an amino group, or the like, a cyanomethyl group, a γ-aminopropyl group, and an N-(β-aminoethyl)-γ-aminopropyl group.

[0054] (17) The silicone resin of component (B) is R 3 SiO 1 / 2 Units and RSiO 3 / 2 Silicone resin with unit as the main component and R 3 SiO 1 / 2 Units and SiO 4 / 2 It is used as a mixture of silicone resins whose main component is the unit. The cosmetic preparation according to any one of (1) to (14), wherein the monovalent substituted or unsubstituted hydrocarbon group of R in the structural unit is selected from a methyl group, an ethyl group, or a phenyl group.

[0055] (18) The silicone resin of component (B) is R 3 SiO 1 / 2 Units, R 2 SiO 2 / 2 Units, RSiO 3 / 2 Units and SiO 4 / 2 The cosmetic preparation according to any one of (1) to (14), which is a silicone resin consisting of a combination of units.

[0056] (19) The silicone resin of component (B) is R 3 SiO 1 / 2 Units, R 2 SiO 2 / 2 Units, RSiO 3 / 2 Units and SiO 4 / 2 It is a silicone resin consisting of a combination of units, R 2 SiO 2 / 2 The cosmetic preparation according to any one of (1) to (14), wherein the constituent content of the unit is 30 mol % or less.

[0057] (20) A cosmetic preparation according to any one of (1) to (14), wherein the silicone resin of component (B) has a thermal softening point of 60°C or higher.

[0058] (21) A cosmetic preparation according to any one of (1) to (14), wherein the silicone resin of component (B) has a thermal softening point of 70°C or higher.

[0059] (22) The cosmetic preparation according to any one of (1) to (21), wherein the total content of the components (A) and (B) in the cosmetic preparation is 1 to 50 mass%.

[0060] (23) The cosmetic preparation according to any one of (1) to (21), wherein the total content of the components (A) and (B) in the cosmetic preparation is 3 to 30 mass%.

[0061] (24) The cosmetic preparation according to any one of (1) to (21), wherein the total content of the components (A) and (B) in the cosmetic preparation is 3 to 20 mass%.

[0062] (25) The cosmetic according to any one of (1) to (24), wherein the content of each component in the total content (100% by mass) of the components (A) and (B) in the cosmetic varies depending on the formulation of the cosmetic.

[0063] (26) The cosmetic preparation according to any one of (1) to (24), wherein the content of each of the components (A) and (B) in the cosmetic preparation is 50 to 95 mass% for component (A) and 5 to 50 mass% for component (B), based on 100 mass% of the combined content of components (A) and (B) in the cosmetic preparation.

[0064] (27) The cosmetic preparation according to any one of (1) to (24), wherein the content of each of the components (A) and (B) in the cosmetic preparation is 60 to 90 mass% for component (A) and 10 to 40 mass% for component (B), based on 100 mass% of the combined content of components (A) and (B) in the cosmetic preparation.

[0065] (28) A cosmetic preparation according to any one of (1) to (27), further comprising, in addition to components (A) and (B), an oil component selected from solid paraffin, ceresin, beeswax, carnauba wax, Japan wax, candelilla wax, stearic acid, cetanol, cholesterol, microcrystalline wax, petrolatum, lanolin, partially hydrogenated oil, squalene, liquid paraffin, castor oil, diglyceride, triglyceride, higher fatty acid, higher alcohol, perfluoropolyether, perfluorodecalin, perfluorooctane, ester oil, octyldodecyl myristate, octyldodecyl oleate, neopentyl glycol dioctanoate, or a combination thereof.

[0066] (29) In addition to components (A) and (B), the aqueous components include glycerin, sorbitol, propylene glycol, 1,3-butylene glycol, and polyethylene glycol. The cosmetic preparation according to any one of (1) to (28), comprising a component selected from the group consisting of a carboxyvinyl polymer, a cellulose derivative, sodium alginate, ethanol, and a combination thereof.

[0067] (30) A cosmetic preparation according to any one of (1) to (29), further comprising, in addition to the components (A) and (B), one or more surfactants selected from the following:

[0068] anionic emulsifiers such as sodium alkylbenzenesulfonates, such as sodium hexylbenzenesulfonate, sodium octylbenzenesulfonate, sodium decylbenzenesulfonate, sodium dodecylbenzenesulfonate, sodium cetylbenzenesulfonate, and sodium myristylbenzenesulfonate; sodium alkylnaphthylsulfonates, such as sodium butylnaphthylsulfonate; sodium polyoxyethylene monoalkylether sulfates, such as sodium polyoxyethylene octyl ether sulfate, sodium polyoxyethylene decyl ether sulfate, and sodium polyoxyethylene eicosyl ether sulfate; and sodium polyoxyethylene mono(alkylphenyl)ether sulfates, such as sodium polyoxyethylene decylphenyl ether sulfate.

[0069] Cationic emulsifiers such as quaternary ammonium salts such as octyltrimethylammonium chloride, dodecyltrimethylammonium chloride, hexadecyltrimethylammonium chloride, tallow trimethylammonium chloride, coconut oil trimethylammonium chloride, octyldimethylbenzylammonium chloride, decyldimethylbenzylammonium chloride, and dioctadecyldimethylammonium chloride.

[0070] Glycerol fatty acid esters such as glyceryl monolaurate, glyceryl monomyristate, glyceryl monostearate, and glyceryl monooleate; polyglycerol fatty acid esters, sorbitan fatty acid esters, polyoxyethylene glycerol fatty acid esters, polyoxyethylene sorbitan fatty acid esters, and polyoxyethylene fatty acid esters having similar fatty acid residues; nonionic emulsifiers such as polyoxyethylene alkyl ethers such as polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, and polyoxyethylene oleyl ether.

[0071] (31) In addition to components (A) and (B), Inorganic powders including talc, kaolin, sericite, muscovite, synthetic mica, phlogopite, red mica, biotite, lepidolite, vermiculite, magnesium carbonate, calcium carbonate, diatomaceous earth, magnesium silicate, calcium silicate, aluminum silicate, barium silicate, barium sulfate, strontium silicate, metal tungstates, silica, hydroxyapatite, zeolite, boron nitride, ceramic powders, Nylon powder, polyethylene powder, benzoguanamine powder, tetrafluoroethylene powder, distyrene benzene pinhole polymer powder, organic powders including microcrystalline cellulose, Silicone rubber, silicone resin powder, inorganic white pigments such as titanium oxide and zinc oxide, inorganic red pigments such as iron oxide (red ocher) and iron titanate, inorganic brown pigments such as gamma-iron oxide, inorganic yellow pigments including yellow iron oxide and ocher, Inorganic black pigments including black iron oxide and carbon black, Inorganic purple pigments including mango violet and cobalt violet, Inorganic green pigments including chromium oxide, chromium hydroxide, and cobalt titanate, Inorganic blue pigments including ultramarine and Prussian blue, Titanium dioxide coated mica, titanium dioxide coated bismuth oxychloride, bismuth oxychloride, titanium dioxide coated talc, fish scale foil, pearl pigments including colored titanium dioxide coated mica, Metal powder pigments including aluminum powder and copper powder, Organic pigments such as Red 201, Red 202, Red 204, Red 205, Red 220, Red 226, Red 228, Red 405, Orange 203, Orange 204, Yellow 205, Yellow 401 and Blue 404; organic pigments containing zirconium, barium or aluminium lakes such as Red 3, Red 104, Red 106, Red 227, Red 203, Red 401, Red 505, Orange 205, Yellow 4, Yellow 5, Yellow 202, Yellow 203, Green 3 and Blue 1; A cosmetic preparation according to any one of (1) to (30), which contains one or more natural pigments selected from the group consisting of chlorophyll and β-carotene.

[0072] (32) A cosmetic preparation according to any one of (1) to (31), further comprising, in addition to the components (A) and (B), one or more selected from an organic pigment, a coloring agent including an organic dye, a preservative, an antioxidant, a coloring agent, a thickener, a pH adjuster, a fragrance, an ultraviolet absorber, a moisturizer, a blood circulation promoter, a cooling agent, an antiperspirant, a germicide, a skin activator, and water.

[0073] (33) In addition to components (A) and (B), the following may be present: squalane, liquid paraffin, isoparaffin, petrolatum, microcrystalline wax, ozokerite, ceresin, myristic acid, palmitic acid, stearic acid, oleic acid, isostearic acid, cetyl alcohol, stearyl alcohol, hexadecyl alcohol, oleyl alcohol, cetyl-2-ethylhexanoate, 2-ethylhexyl palmitate, 2-octyldodecyl myristate, 2-octyldodecyl gum ester, and neopentyl glycol. The cosmetic preparation according to any one of (1) to (32), which contains one or more selected from the group consisting of various hydrocarbons including 2-ethylhexanate, isooctyl triglyceride, 2-octyldodecyl oleate, isopropyl myristate, isopropyl palmitate, isostearic triglyceride, coconut oil triglyceride, olive oil, avocado oil, beeswax, myristyl myristate, mink oil, and lanolin, higher fatty acids, oils and fats, esters, higher alcohols, waxes, and oils including silicone oil.

[0074] (34) The cosmetic preparation according to any one of (1) to (33), which is in any one of liquid, powder, solid, and emulsion forms.

[0075] (35) The cosmetic preparation according to any one of (1) to (33), which is a skin cosmetic preparation or a makeup cosmetic preparation selected from a makeup base, a foundation, a sunscreen, a lipstick, an eyeliner, a mascara, and a skin cream. EXAMPLES

[0076] The present invention will be described below with reference to examples, but the present invention is not limited to these.

[0077] The components used in the examples and comparative examples are as follows. In the following, "synthetic products" refers to products synthesized by the inventors.

[0078] (A)Ingredients 1,1,1,3,5,5,5-heptamethyl-3-dodecyltrisiloxane: synthetic product 1,1,1,3,5,5,5-heptamethyl-3-decyltrisiloxane: synthetic product 1,1,1,3,5,5,5-heptamethyl-3-tetradecyltrisiloxane: Synthetic product

[0079] (B) Ingredients Trimethylsiloxysilicate: Thermal softening point is 100°C or higher, a=1 in the average unit formula above. 5. SR1000, Momentive Performance Materials Polymethylsilsesquioxane: Thermal softening point 90°C, a in the above average unit formula = 1.7 5. SilForm Flexible Resin, Momentive Performance Materials

[0080] (Oily ingredients) 1,1,1,3,5,5,5-Heptamethyl-3-octyltrisiloxane: Silsoft 034, Momentive Performance Materials Polydimethylsiloxane with a viscosity of 5 cSt: Element14 PDMS 5-JC, Momentive Performance Materials Caprylic / Capric Triglyceride, PEG / PPG-20 / 15 Dimethicone: Harmonie Mesh emulsifier, Momentive Performance Materials Diphenyl Dimethicone: SilShine 150, Momentive Performance Materials

[0081] (Powder components) Silica: Harmonie Luxe 4 powder, Momentive Performance Materials Boron Nitride: CCS102-JA, Momentive Performance Materials Surface hydrophobic treated titanium oxide: SI01-2 CR-50 manufactured by Daito Kasei Kogyo Co., Ltd. Surface hydrophobic treated iron oxide (yellow): SI-2 Yellow LL-100P manufactured by Daito Kasei Kogyo Co., Ltd. Surface hydrophobic treated iron oxide (red): SI-2 Red R-516 manufactured by Daito Kasei Kogyo Co., Ltd. Surface hydrophobic treated iron oxide (black): Daito Kasei Kogyo Co., Ltd. SI-2 Black BL-100P

[0082] (aqueous component) Butylene glycol: Reagent Glycerin: Reagent Sodium chloride: Reagent

[0083] Examples 1 to 6, Comparative Examples 1 and 2 (BB Cream) Mixtures of each phase were prepared by stirring the ingredients for phase I, phase II, and phase III shown in Table 1 until uniform. Next, the mixture for phase II was added to the mixture for phase I and stirred until uniform, and then the mixture for phase III was added and stirred until uniform, obtaining BB creams for the examples and comparative examples.

[0084] The obtained makeup base cream was evaluated for spreadability on the skin, non-stickiness, soft texture, and makeup retention by the following methods. The results are shown in Table 1. Note that the values ​​for each component in Table 1 are in mass %, and the amount of water is adjusted to make the total 100 mass %.

[0085] (Spread on skin) An appropriate amount (about 1 g) of each of the cosmetics of the Examples and Comparative Examples was taken in the hand, applied to the face, and spread with the fingers to evaluate the spreadability on the skin. That is, 10 panel members evaluated the cosmetics on a 5-point scale (5 points: excellent, 4 points: slightly excellent, 3 points: equal, 2 points: slightly inferior, 1 point: inferior), with Comparative Example 1 being given 3 points, and the average scores are shown in Table 1.

[0086] (Sticky feeling) After application to the skin, the skin was evaluated for non-stickiness and refreshing feeling. That is, a panel of 10 members rated the product on a 5-point scale (5 points: excellent, 4 points: slightly excellent, 3 points: equal, 2 points: slightly inferior, 1 point: inferior), with Comparative Example 1 being given a score of 3 points. The average scores are shown in Table 1.

[0087] (Soft to the touch) After application to the skin and drying, it was evaluated that the skin had a soft feel without any tightness. That is, 10 panel members rated the product on a 5-point scale (5 points: excellent, 4 points: slightly excellent, 3 points: equal, 2 points: slightly inferior, 1 point: inferior), with Comparative Example 1 being given a score of 3, and the average scores are shown in Table 1.

[0088] (Makeup Holder) The makeup durability was evaluated 6 hours after application to the skin. That is, a panel of 10 members rated the product on a 5-point scale (5 points: excellent, 4 points: slightly excellent, 3 points: equal, 2 points: slightly inferior, 1 point: inferior), with Comparative Example 1 being given a score of 3. The average scores are shown in Table 1.

[0089] [Table 1]

[0090] The cosmetic preparation of the present invention, which uses component (A) and component (B) in combination, received excellent evaluations in all of the evaluations shown in Table 1.

[0091] When used as a skin cosmetic, the cosmetic of the present invention can provide a smooth feel without a sticky feeling, good water resistance due to excellent water repellency, etc., and when used as a make-up cosmetic, it can provide good even spreadability, good makeup retention due to excellent water repellency and water resistance, good appearance and a smooth application feel due to excellent luster and the colorability of the pigment, etc.

[0092] TIFF0007604717000002.tif114170

[0093] (Production method) The above components (1) to (7) and components (8) to (13) were mixed until homogeneous, and then the homogeneous mixture of components (1) to (7) and the homogeneous mixture of components (8) to (13) were mixed at 70°C for 30 minutes to obtain a homogeneous mixture of components (1) to (13). Next, components (14) through (16) are uniformly dissolved at 70°C, added to the uniform mixture of components (1) through (13), and mixed. The mixture is then homogenized in a homogenizer at 2,000 rpm for 5 minutes. After stirring, a liquid foundation was obtained.

[0094] (evaluation) The obtained liquid foundation was a uniformly dispersed liquid without lumps, was smooth and spread well when applied to the skin, and had a soft and smooth feel after drying.

[0095] TIFF0007604717000003.tif142170

[0096] (Production method) The above ingredients (1) to (3) were heated to 75°C while thoroughly stirring. Ingredients (4) to (12) were heated to 70°C while thoroughly stirring. The mixed ingredients (4) to (12) were added to the mixed ingredients (1) to (3), stirred for 2 minutes with a homogenizer (9500 rpm), and cooled to 40°C. The mixture of ingredients (13) to (15) that had been stirred until uniform was added to the mixed liquid of ingredients (1) to (12) and stirred, and then ingredient (16) was added and stirred. To this, ingredients (17) to (20) that had been stirred until uniform were added and stirred to obtain a skin cream.

[0097] (evaluation) The obtained skin cream was uniform, spread easily, and had a smooth feel after drying without any tightness or stickiness, and still felt moisturized even half a day after application. [Industrial Applicability]

[0098] The cosmetic of the present invention can be in any one of liquid, powder, solid, and emulsion forms, and can be used as a skin cosmetic or makeup cosmetic selected from a makeup base, foundation, sunscreen, lipstick, eyeliner, mascara, skin cream, and the like.

Claims

1. A skin cosmetic or makeup cosmetic comprising the following components (A) and (B): Component (A) is one or more selected from 1,1,1,3,5,5,5-heptamethyl-3-alkyl (C10-14) trisiloxanes, and includes at least either (A-1) 1,1,1,3,5,5,5-heptamethyl-3-decyltrisiloxane or (A-2) 1,1,1,3,5,5,5-heptamethyl-3-dodecyltrisiloxane. (B) Average unit formula RaSiO （４－ａ）／２ (wherein R is the same or different monovalent substituted or unsubstituted hydrocarbon group, and a is a number from 1.2 to 2),

2. 2. The cosmetic preparation according to claim 1, wherein the component (A) is any one of the components (A-1) and (A-2), the components (A-1) and (A-3), and the components (A-2) and (A-3) selected from the group consisting of (A-1) 1,1,1,3,5,5,5-heptamethyl-3-decyltrisiloxane, (A-2) 1,1,1,3,5,5,5-heptamethyl-3-dodecyltrisiloxane, and (A-3) 1,1,1,3,5,5,5-heptamethyl-3-tetradecyltrisiloxane.

3. 2. The cosmetic preparation according to claim 1, wherein component (A) is a mixture of three components: (A-1) 1,1,1,3,5,5,5-heptamethyl-3-decyltrisiloxane, (A-2) 1,1,1,3,5,5,5-heptamethyl-3-dodecyltrisiloxane, and (A-3) 1,1,1,3,5,5,5-heptamethyl-3-tetradecyltrisiloxane.

4. The silicone resin (B) is R ３ SiO １／２ Units and RSiO ３／２ Silicone resin with unit as the main component and R ３ SiO １／２ Units and SiO ４／２ 2. The cosmetic material according to claim 1, which is a mixture of silicone resins containing the unit as a main component.

5. The cosmetic preparation according to claim 1, comprising a total of 1 to 50 mass % of the components (A) and (B).

6. 2. The cosmetic according to claim 1, wherein the content of each of the components is 50 to 95 mass% for component (A) and 5 to 50 mass% for component (B) relative to 100 mass% total content of component (A) and component (B) in the cosmetic.

7. 7. The cosmetic according to any one of claims 1 to 6, which is a skin cosmetic or a make-up cosmetic selected from the group consisting of a makeup base, a foundation, a sunscreen, a lipstick, an eyeliner, a mascara, and a skin cream.

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