Hair cleansing composition

Abstract

To provide a hair detergent composition, which suppresses generation of coacervate, inhibits waves of hair before combed, reduces generation of waves caused by combing, and gives glossiness and a light finish to the hair.SOLUTION: Provided is a hair detergent composition, which is a composition of (A) a specific succinyl-arginine or a 0.1-5.0 wt.% of salt thereof, (B) 0.05-1.0 wt.% of a specific cationic polymer (at least either one of Polyquaternium-7 or Polyquaternium-10) and 0.2 wt% or less of Polyquaternium-10, (C) 5.0-16.0 wt.% of an anionic surface active agent, and (D) 0.5-3.0 wt.% of an amphoteric surface active agent and a ratio of the component (C) / the component (D), which is 4.0-30.0.SELECTED DRAWING: None

Description

[Technical field]

[0001] The present invention relates to a hair wash composition that suppresses the formation of coacervate, inhibits hair frizz before combing, reduces the occurrence of frizz due to combing, and provides a glossy, light finish. [Background technology]

[0002] In recent years, the popularity of natural hair has led to a decline in the rate of hair coloring and perming among young people. As a result, hair concerns have also changed, with fewer concerns about hair damage and more concerns about hair wavyness and difficulty in managing hair. In addition, as the number of black hairs increases, people are seeking to improve their hair's shine. In response to these concerns, styling shampoos that suppress hair manageability and wavyness have become popular among young people in recent years. However, hair shampoos alone may not be effective enough, and they may be used in combination with conditioners or leave-in care agents. As a technique for improving these problems, attempts have been made to correct wavy hair by blending cationic polymers, silicones, oils, sugars, etc. in hair cosmetics that are used by washing off, such as shampoos, conditioners, and treatments, to give hair hardness and weight. However, although these techniques impart hardness and weight to hair, they may not be able to sufficiently suppress wavyness, and natural hair, which causes less damage to hair, may feel heavy and sticky. Furthermore, with regard to improving frizz, for example, a hair cosmetic composition containing a combination of lecithin, an amphoteric surfactant, a film-forming polymer, and a cationic polymer (e.g., Patent Document 1) has been disclosed; however, when used on natural hair, the cosmetic composition still tends to feel heavy and sticky.

[0003] A technology called coacervate is used to improve the combability and foam smoothness during hair washing (Patent Document 2). Coacervate is a combination of a specific cationic polymer and a specific surfactant, which in a diluted state from hair washing to rinsing forms aggregates that become insoluble in water and precipitate, and adsorbs to the hair surface, improving the combability of hair from washing to rinsing and improving the foam smoothness (Patent Document 3). On the other hand, excessive adsorption and residue on hair due to excessive generation of coacervate during rinsing can cause hair to become wavy. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] JP 2004-203887 A [Patent Document 2] JP 2013-216639 A [Patent Document 3] Japanese Patent Application Publication No. 04-273811 [Patent Document 4] JP 2016-64994 A Summary of the Invention [Problem to be solved by the invention]

[0005] In order to solve these problems, a main object of the present invention is to provide a hair wash composition which suppresses the formation of coacervates, suppresses hair frizz before combing by using only a hair shampoo, reduces the occurrence of frizz due to combing, and provides a glossy, light finish. [Means for solving the problem]

[0006] Means for Solving the Problems The present inventors have conducted intensive research to solve the above-mentioned problems, and as a result have found that the above-mentioned problems can be solved by a hair wash composition containing an arginine derivative having a specific structure, a specific cationic polymer, and a specific composition of anionic surfactant and amphoteric surfactant, thereby completing the present invention.

[0007] That is, the present invention is as follows. (1) (A) 0.1 to 5.0% by weight of succinylarginine represented by the general formula (1) or a salt thereof [ka] (B) A specific cationic polymer (at least one of polyquaternium-7 and polyquaternium-10) is 0.05 to 1.0% by weight, and polyquaternium-10 is 0.2% by weight or less. (C) Anionic surfactant 5.0 to 16.0% by weight (D) Amphoteric surfactant 0.5 to 3.0% by weight And the ratio of component (C) to component (D) is 4.0 to 30.0 The hair cleansing composition has the following composition: (2) The hair wash composition according to (1), wherein the anionic surfactant as component (C) is at least one selected from the group consisting of alkyl sulfates, polyoxyethylene alkyl ether sulfates, α-olefin sulfonates, N-acylmethyl taurines, alkyl sulfosuccinates, and polyoxyethylene alkyl sulfosuccinates. (3) The hair wash composition according to (1) or (2), wherein the amphoteric surfactant as component (D) is at least one selected from the group consisting of amidoamine oxide type, amidopropylbetaine type, and sulfobetaine type. Effect of the Invention

[0008] According to the present invention, it is possible to provide a hair wash composition which contains a specific arginine derivative having excellent performance, contains a specific cationic polymer, and has a specific composition of anionic surfactant and amphoteric surfactant, thereby suppressing the generation of coacervate, and which, by using only a hair shampoo, suppresses hair frizz before combing and further reduces the occurrence of frizz due to combing, and leaves the hair with a glossy, light finish. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0009] Hereinafter, an embodiment of the present invention will be described. Component (A) is succinylarginine represented by general formula (1) or a salt thereof. [ka] As component (A), succinylarginine may be used alone or as a salt. As salts, metal salts having a potassium atom, a calcium atom, a sodium atom, a magnesium atom, or the like, and alkanolamines such as monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, and triisopropanolamine can be used. From the viewpoints of hue stability and low irritation, preferred metal salts are salts having a sodium atom, and preferred alkanolamine salts are triethanolamine salts.

[0010] As described in Patent Document 4, component (A) is a base that not only gives hair elasticity and volume, but also improves the feel of the hair surface. When component (A) is blended in the hair wash composition at 0.1 to 5.0% by weight, it gives hair shine, suppresses hair wavyness before combing, and reduces the occurrence of wavyness due to combing. A blend of 0.5 to 3.0% by weight is more preferred. If the blend is less than 0.1% by weight, the effect of the present invention may not be obtained, and if the blend exceeds 5.0% by weight, the finish may not be light and problems such as stiffness may occur.

[0011] Excessive adsorption and residue of coacervate on hair during rinsing may inhibit the effect of component (A) and may worsen the suppression of hair wavyness before combing. Therefore, the cationic polymer (B) is at least one of polyquaternium-7 and polyquaternium-10, which are less likely to leave coacervate on hair. More preferably, it is polyquaternium-7. By blending component (B) at 0.05 to 1.0% by weight, it is possible to improve the smoothness of hair during washing without reducing the effect of component (A). The blending amount is preferably 0.1 to 0.5% by weight. If it is less than 0.05% by weight, hair may become easily tangled and lightness may not be obtained at the time of finishing. If it is blended at more than 1.0% by weight, it may be adsorbed on hair and inhibit the effect of component (A). Furthermore, since polyquaternium-10 is more likely to cause residual coacervate than polyquaternium-7, it is preferable to blend it at 0.2% by weight or less, and it is not necessary to blend it at all.

[0012] The anionic surfactant (C) is blended in the hair wash composition mainly for the purpose of cleaning power. Examples of the anionic surfactant (C) include alkyl sulfates, polyoxyethylene alkyl ether sulfates, α-olefin sulfonates, N-acyl methyl taurines, alkyl sulfosuccinates, polyoxyethylene alkyl sulfosuccinates, alkyl sulfonates, internal olefin sulfonates, N-acyltaurines, acyl isethionates, α-sulfofatty acid methyl ester salts, etc., which have a strong acid group and are unlikely to leave a coacervate, and are preferably alkyl sulfates, polyoxyethylene alkyl ether sulfates, α-olefin sulfonates, N-acyl methyl taurines, alkyl sulfosuccinates, and polyoxyethylene alkyl sulfosuccinates. Specific examples of alkyl sulfates include lauryl sulfate, (coconut oil alkyl / babassu oil alkyl) sulfate, alkyl (C12,13) ​​sulfate, alkyl (C11-15) sulfate, alkyl (C11,13,15) sulfate, alkyl (C12-18) sulfate, alkyl (C12-14) sulfate, alkyl (C12-15) sulfate, alkyl (C12,14,16) sulfate, alkyl (C12-16) sulfate, oleyl sulfate, coco alkyl sulfate, stearyl sulfate, cetyl sulfate, cetearyl sulfate, myristyl sulfate, etc. Sodium lauryl sulfate is preferred. Specific examples of polyoxyethylene alkyl ether sulfates include laureth sulfate, laureth-2, -3, -5, -7, -8, -12, -40 sulfate, (C10-15) pareth sulfate, (C11-15) pareth-3 sulfate, (C11-15) pareth sulfate, (C11,13,15) pareth-1 sulfate, (C12-14) s-pareth-3 sulfate, (C12-14) pareth-3 sulfate, (C12-15) pareth-3 sulfate, (C12,13) ​​pareth-3 sulfate, (C12,13) ​​pareth sulfate, oleth sulfate, coceth sulfate, trideceth sulfate, myreth-3, -4 sulfate, etc. Preferably, sodium laureth sulfate is used. Specific examples of the α-olefin sulfonate include olefin (C14-16) sulfonate, olefin (C12-14) sulfonate, olefin (C14-18) sulfonate, etc. Preferred is sodium olefin (C14-16) sulfonate. Specific examples of N-acyl methyl taurine salts include cocoyl methyl taurine salt, oleoyl methyl taurine salt, caproyl methyl taurine salt, stearoyl methyl taurine salt, palmitoyl methyl taurine salt, myristoyl methyl taurine salt, lauroyl methyl taurine salt, etc. Preferred is sodium cocoyl methyl taurine. Specific examples of the alkyl sulfosuccinate include lauryl sulfosuccinate, diethylhexyl sulfosuccinate, dioctyl sulfosuccinate, and cetearyl sulfosuccinate. Specific examples of polyoxyethylene alkyl sulfosuccinates include laureth sulfosuccinate, s-pareth-2, -3, -5, -7, -9, -12 sulfosuccinate, pareth-1, -2, -4 sulfosuccinate, pareth-12, -4 sulfosuccinate, pareth-12, -4 sulfosuccinate, pareth-12, -4 sulfosuccinate, pareth-12, -4 sulfosuccinate, deceth-sulfosuccinate, etc. Preferred is laureth sulfosuccinate disodium. Examples of salts of anionic surfactants that can be used include metal salts having a sodium atom, a potassium atom, a calcium atom, a magnesium atom, or the like; alkanolamines such as monoethanolamine, diethanolamine, triethanolamine, monoisopropanolamine, diisopropanolamine, and triisopropanolamine; basic amino acids such as arginine, lysine, and histidine; amino acid salts such as sodium taurate; and ammonium. These anionic surfactants may be used alone or in combination of two or more kinds.

[0013] The component (C) is present in the hair wash composition in an amount of 5.0 to 16.0% by weight, so that the basic performance of a hair shampoo, such as cleansing ability, can be exhibited. The amount is more preferably 8.0 to 13.0% by weight. If the amount is less than 5.0% by weight, foaming may become poor. If the amount is more than 16.0% by weight, conditioning properties may decrease, and lightness may not be achieved when finished.

[0014] The amphoteric surfactant, which is component (D), has the effect of reducing the irritation caused by the anionic surfactant and improving foam quality, and is blended into the hair cleansing composition. Examples of the amphoteric surfactant that is component (D) include amphoteric surfactants of the amine oxide type, such as the amidoamine oxide type, amidopropyl betaine type, sulfobetaine type, imidazoline type, and alkyl betaine type. Preferred are amphoteric surfactants of the amidoamine oxide type, amidopropyl betaine type, and sulfobetaine type. Among these, amphoteric surfactants of the amidoamine oxide type are more preferred, as they are less likely to leave coacervate on the hair, and are excellent in mitigating the irritation caused by anionic surfactants and in improving foam quality. Specific examples of amphoteric surfactants of the amidoamine oxide type include lauramidopropylamine oxide (Softazoline (registered trademark) LAO-C manufactured by Kawaken Fine Chemical Co., Ltd., as a commercially available product), cocamidopropylamine oxide, wheat germ oil fatty acid amidopropylamine oxide, soyamidopropylamine oxide, myristamidopropylamine oxide, milk fat fatty acid amidopropylamine oxide, etc. Preferably, lauramidopropylamine oxide is used. Specific examples of the amine oxide type amphoteric surfactants include oleamine oxide, cocoamine oxide, dihydroxyethyl cocamine oxide, dihydroxyethyl lauramine oxide, stearamine oxide, decylamine oxide, decyltetradecylamine oxide, behenamine oxide, myristamine oxide, and lauramine oxide. Specific examples of amphoteric surfactants of the amidopropyl betaine type include cocamidopropyl betaine (commercially available products include Softazoline CPB and CPB-R manufactured by Kawaken Fine Chemicals Co., Ltd.), (capryl / capramido)propyl betaine, isostearamidopropyl betaine, undecylenamidopropyl betaine, oliveamidopropyl betaine, oleamidopropyl betaine, shea butter amidopropyl betaine, soyamidopropyl betaine, palm kernel fatty acid amidopropyl betaine (commercially available products include Softazoline PKPB manufactured by Kawaken Fine Chemicals Co., Ltd.), babassuamidopropyl betaine, myristamidopropyl betaine, meadowfoam amidopropyl betaine, lauramidopropyl betaine (commercially available products include Softazoline LPB and LPB-R manufactured by Kawaken Fine Chemicals Co., Ltd.), ricinoleic acid amidopropyl betaine, milk fat fatty acid amidopropyl betaine, and horse oil fatty acid amidopropyl betaine. Preferably, cocamidopropyl betaine is used. Specific examples of sulfobetaine-type amphoteric surfactants include lauryl hydroxysulfobetaine (lauryl hydroxysultaine), lauramidopropyl hydroxysultaine (commercially available products include Softazoline LSB and LSB-R manufactured by Kawaken Fine Chemicals Co., Ltd.), cocamidopropyl hydroxysultaine, erucamidopropyl hydroxysultaine, and methoxycinnamidopropyl hydroxysultaine. Preferably, lauryl hydroxysulfobetaine (lauryl hydroxysultaine) is used. Specific examples of imidazoline-type amphoteric surfactants include sodium cocoamphoacetate (commercially available products include Softazoline CH, CH-R, CL, and CL-R manufactured by Kawaken Fine Chemicals Co., Ltd.), sodium argan amphoacetate, sodium isostearoamphoacetate, sodium olive amphoacetate, sodium cacao butter amphoacetate, sodium caproamphoacetate, sodium sesame amphoacetate, sodium rice bran amphoacetate, sodium shea butter amphoacetate, sodium sweet almond amphoacetate, sodium palm amphoacetate, sodium babassu amphoacetate, and sodium peanut amphoacetate. a, sunflower seed sodium amphoacetate, grape seed sodium amphoacetate, mango sodium amphoacetate, cottonseed sodium amphoacetate, sodium lauroamphoacetate (available commercially available products include Softazoline LHL and LHL-SF manufactured by Kawaken Fine Chemicals Co., Ltd.), disodium cocoamphodiacetate, disodium soybean oil fatty acid amphodiacetate, disodium lauroamphodiacetate, sodium cocoamphopropionate (available commercially available products include Softazoline NS, SF, and SFD manufactured by Kawaken Fine Chemicals Co., Ltd.), and disodium cocoamphodipropionate. These amphoteric surfactants may be used alone or in combination of two or more. Furthermore, when effects such as transparency of the appearance of the hair wash composition, adjustment of the viscosity, and control of the amount of coacervate produced are required, it is preferable to use a desalted purified product of the amphoteric surfactant.

[0015] The amphoteric surfactant (D) is blended in the hair cleansing composition at 0.5 to 3.0% by weight, which reduces the irritation of the anionic surfactant and improves the foam quality. More preferably, it is blended at 1.0 to 2.0% by weight. If it is less than 0.5% by weight, this effect may be weakened, and if it exceeds 3.0% by weight, a large amount of coacervate with the cationic polymer may be generated, which may reduce the effect of the present invention. In addition, amphoteric surfactants of amidopropyl betaine type and sulfobetaine type may be more likely to cause coacervate residue on hair than amidoamine oxide type amphoteric surfactants, so that amphoteric surfactants of amidopropyl betaine type and sulfobetaine type are preferably blended at a total of 1.5% by weight or less, and may not be blended at all.

[0016] The effect of the present invention is achieved by making the ratio of component (C) / component (D) 4.0 to 30.0 by weight. More preferably, it is 5.0 to 20.0. If the ratio is less than 4.0, coacervate may be generated, inhibiting the effect of component (A), and the effect of the present invention may not be obtained. If it exceeds 30.0, the conditioning effect may decrease, hair may become easily tangled, stiffness may occur, and lightness at the end may not be obtained.

[0017] In addition, the hair cleansing composition of the present invention may contain other components than those described above, if necessary, within the qualitative and quantitative ranges that do not substantially impair the effects of the present invention. However, it may be necessary to control the amount of components added that may be adsorbed to the hair surface and inhibit the effects of component (A).

[0018] Non-ionic surfactants include, but are not limited to, PPG-2 cocamide (a commercially available product is Amizet (registered trademark) 1PC manufactured by Kawaken Fine Chemicals Co., Ltd.), cocamide MEA (a commercially available product is Amizole (registered trademark) CME manufactured by Kawaken Fine Chemicals Co., Ltd.), cocamide DEA (Amizole CDE-G manufactured by Kawaken Fine Chemicals Co., Ltd.), palm kernel oil fatty acid amide DEA (Amizole KD-1 manufactured by Kawaken Fine Chemicals Co., Ltd.), lauramide DEA (Amizole LDE-G manufactured by Kawaken Fine Chemicals Co., Ltd.), (lauramide / myristamide) DEA (Amizol LMDE-Y manufactured by Kawaken Fine Chemicals), Lauramide MIPA (Amizol PLME-A manufactured by Kawaken Fine Chemicals), PEG-3 Lauramide (Amizet 2L-Y manufactured by Kawaken Fine Chemicals), Lauryl / Myristyl Glycol Hydroxypropyl Ether (Viscosafe(R) LMPE manufactured by Kawaken Fine Chemicals), Cocamide Methyl MEA, 2-Ethylhexyl Glyceryl Ether, Glyceryl 2-Ethylhexanoate, Glyceryl Behenate / Eicosane Dioxide, Polyglyceryl Behenate / Eicosane Dioxide , alkyl glyceryl ether, alkyl glucosides, alkyl saccharides, ethylene oxide derivatives of alkylphenol formalin condensates, alkyl polyglucosides, alkylene glycol fatty acid esters, polyoxyethylene glyceryl isostearate, isodecyl glyceryl ether, polyethylene glycol ether of diester or triester of oleic acid and methyl glucose, glycerin alkyl ether, glycerin fatty acid ester, PEG-120 methyl glucose dioleate, ethylene glycol distearate, polyethylene glycol dipolyhydroxystearate, sucrose fatty acid esters, sorbitan sesquioleate, ceteareth-60 myristyl glycol, sorbitan monostearate, sorbitan fatty acid esters, sorbitol fatty acid esters, polyoxyethylene sorbitol tetraisostearate, tetraglycerin monolauryl ether, tetrapolyoxyalkylene ethylenediamine condensates, tri(capryl / capric)glyceryl, Pluronic (registered trademark) types, propylene glycol fatty acid esters, pentaerythritol fatty acid esters,Polyethylene glycol monooleate, polyethylene glycol type nonionic surfactant, polyethylene glycol fatty acid ester, polyoxyalkylene alkyl co-modified organopolysiloxane, polyoxyalkylene alkyl ethers, polyoxyalkylene alkylphenyl ether, polyoxyalkylene alkenyl ether, polyoxyalkylene ether, polyoxyalkylene esters, polyoxyalkylene glycol, polyoxyalkylene glycol fatty acid ester, polyoxyalkylene glycerin fatty acid ester, polyoxyalkylene dimethyl dimer diol ether, polyoxyalkylene sorbitan fatty acid ester, polyoxyalkylene sorbit fatty acid ester, polyoxyalkylene castor oil derivative, polyoxyalkylene hydrogenated castor oil derivative, polyoxyalkylene fatty acid amide, polyoxyalkylene fatty acid ester, polyoxyalkylene modified organopolysiloxane, polyoxyethylene POP alkyl ethers, polyoxyethylene alkylamine, polyoxyethylene alkyl allyl ether, polyoxyethylene alkyl ether ethers, polyoxyethylene alkyl thioethers, polyoxyethylene alkyl phenyl ethers, polyoxyethylene isostearyl ether, polyoxyethylene-octyldodecyl ether, polyoxyethylene glyceryl cocoate, polyoxyethylene-glycerin monoisostearate, polyoxyethylene glycerin fatty acid esters, polyoxyethylene cholestanol ether, polyoxyethylene cholesteryl ether, polyoxyethylene stanol ether, polyoxyethylene stearyl ether, polyoxyethylene sterol ether, polyoxyethylene cetostearyl hydroxymethylene ether, polyoxyethylene sorbitan monolaurate and other polyoxyethylene sorbitan monofatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene-sorbitol monolaurate, polyoxyethylene sorbitol fatty acid esters, polyoxyethylene sorbitol fatty acid esters, polyoxyethylene nonylphenyl ether, polyoxyethylene castor oil, polyoxyethylene phytostanol ether,Polyoxyethylene phytosteryl ether, polyoxyethylene phytosterol ether, polyoxyethylene propylene glycol fatty acid ester, polyoxyethylene polyoxypropylene butyl ethers, polyoxyethylene polyoxypropylene alkyl ethers, polyoxyethylene polyoxypropylene glycols, polyoxyethylene polyoxypropylene glyceryl ethers, polyoxyethylene methyl glucoside, polyoxyethylene PEG-glyceryl coconut oil fatty acid, polyoxyethylene lauryl ether, polyoxyethylene lanolin alcohol, polyoxyethylene lanolin derivatives, polyoxyethylene hydrogenated castor oil, polyoxyethylene hydrogenated castor oil fatty acid esters, polyoxyethylene hydrogenated castor oil derivatives, polyoxyethylene fatty acid esters, polyoxyethylene fatty acid diesters, polyoxysorbitol fatty acid esters, polyoxybutylene polyoxyethylene polyoxypropylene glyceryl ethers, polyoxypropylene alkyl ethers, polyoxypropylene diglyceryl ethers, polyoxypropylene monooctyl ether, polyglyceryl ether, polyglyceryl monoalkyl ether, polyglycerin alkyl ether, polyglycerin laurate, polyglycerin fatty acid ester, polysorbate, polypropylene glycol caprylyl ether, monoalkyl glyceryl ether, monoalkenyl glyceryl ether, ethylene glycol monooleate, monoglyceride derivatives, monoglycerin alkyl ether, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monolaurate, PEG-4 laurate, diethylene glycol laurate, propylene glycol laurate, hydrogenated castor oil derivatives, higher fatty acid sucrose esters, fatty acid oxybutylene, fatty acid glycol esters, fatty acid glycerin esters, fatty acid dioxybutylene, block polymers containing aliphatic alkyl groups, polyhydric alcohol-type nonionic surfactants, polyhydric alcohol fatty acid esters, sugar alcohol fatty acid esters, sugar ether-based, sugar ester-based, etc.

[0019] Other ingredients include, for example, (aminoethylaminopropylmethicone / dimethicone) copolymer, (divinyldimethicone / dimethicone) copolymer, (dimethicone / vinyldimethicone) crosspolymer, (meth)acrylic silicone graft copolymer, (meth)acrylic modified silicone, 1,1,1-triphenyl-3,3-dialkyl-3-alkenyldisiloxane, EO modified silicone, PEG / PPG-dimethicone, PEG-dimethicone, acrylic silicones, amidoalkyl modified polysiloxane, silicone with aminoalkyl side chains, , aminoethylaminopropylmethylsiloxane, aminoglycol modified polysiloxane, aminophenyl modified polysiloxane, aminopropyl dimethicone, aminopropyltrialkoxysilane, aminoethylaminopropylmethicone / dimethicone copolymer, aminopropylmethylsiloxane-dimethylsiloxane copolymer, aminopolyether modified silicone, amino modified silicone, amino modified silicone-polyether block copolymer, amodimethicone, alkyl modified silicone, alcohol modified silicone, alkoxy modified silicone , epoxy modified silicone, epoxy amino silane copolymer, polysiloxane with oxiranyl or oxetanyl group, carbinol modified polysiloxane, carboxy modified silicone, glyceryl modified silicone, diphenyl polysiloxane, dimethiconol, dimethicone, dimethicone copolyol, dimethicone copolymer, dimethylsiloxane-methyl (polyoxyethylene) siloxane copolymer, dimethylsiloxane copolymer, silanol terminated dimethylpolysiloxane, silicone elastomer, silicone quaternium-16 / glycine Doxydimethicone crosspolymer, silicone graft polymer, silicone phosphate triester, silicone wax, decyltrisiloxane carboxylic acid, trimethylsilylamodimethicone, trimethylsilyl terminated dimethylpolysiloxane, trimethylsiloxysilicate, silicone quaternium-2 panthenyl succinate, bis(alkoxy)PG amodimethicone, bis(PEG / PPG) dimethicone, biscetearyl amodimethicone, hydroxypropyl polysiloxane hydrolyzed wheat protein, phenyl trimethicone, fluorine modified silicone,Fluoroalkyl group-containing organopolysiloxane, betaine-modified silicone, polyamino-modified silicone, polyether-alkyl co-modified polysiloxane, polyether-modified silicone, polyoxyalkylene-alkyl co-modified silicone, polyoxyalkylene-modified silicone, silicone with polyoxyalkylene side chains, aminopolyether-modified silicone containing polyoxyalkylene structure, polyoxyethylene / polyoxypropylene copolymer-modified polysiloxane, polyglycidol-modified silicone, polyglycerin-alkyl co-modified polysiloxane xane, polyglycerin modified polysiloxane, polysilicone, methylhydrogenpolysiloxane, methylphenylpolysiloxane, meadowfoam oil fatty acid PEG-dimethicone, mercapto modified silicone, linoleamidopropyl PG-dimonium chloride phosphate dimethicone, crosslinked organopolysiloxane, crosslinked silicone POA copolymer, crosslinked polyether modified silicone, crosslinked polyglycerin modified silicone, highly polymerized amino modified silicone, highly polymerized dimethicone, highly polymerized dimethyl silicone, low polymerization dimethyl silicone, highly polymerized methyl Polysiloxane, highly polymerized methylpolysiloxane emulsion, silicone polymer with three-dimensional crosslinked structure, fatty acid modified silicone, quaternary ammonium group-containing silylated urethane polymer, quaternary cation modified silicone, long-chain alkyl modified acrylate silicone, linear aminopolyether modified silicone, linear aminopolyether modified polysiloxane, non-emulsifiable crosslinked type, partially crosslinked type organopolysiloxane polymer silicone and other silicones, glycerin, diglycerin and other glycerin derivatives, 1,3-butylene glycol, methylene glycol, glycerin, etc. Glycols such as choline, diethylene glycol, triethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, pentylene glycol, neopentyl glycol, hexylene glycol, caprylyl glycol, decylene glycol, lauryl glycol, and lauryl glycol hydroxypropyl ether, propanediol, 1,2-butanediol, 1,4-butanediol, 2,3-butanediol, 1,5-pentanediol, 1,2-pentanediol, isopentyldiol, hexanediol,Diols such as 1,2-hexanediol, 1,10-decanediol, ethylhexanediol, octanediol, butylethylpropanediol, methylpropanediol, 2-amino-2-hydroxymethyl-1,3-propanediol, etc.; sugars such as pentaerythritol, xylitol, fructose, sorbitol, mannitol, inositol, glucose, lactose, maltitol, sucrose, etc.; polyols such as sugar alcohols; hydroxyalkylated cyclodextrin, hydroxypropyl cellulose, acylated pullulan, Sugar derivatives such as stearoxyhydroxypropylmethylcellulose, allitol, talitol, and trehalose isostearate, trehalose, hyaluronic acid, acetylated hyaluronic acid, collagen, carboxymethylchitosan succinamide, PPG-2 arginine, sodium dilauroyl glutamate lysine, amidinoproline, mulberry milk, honey, pyrrolidone carboxylic acids, glucosamines, alanyl glutamine, glyceryl-N-(2-hydroxyethyl) carbamate, and moisturizing agents such as glucamines, PEG / PPG / polybutylene glycol Hair conditioners such as water-soluble moisturizing oils such as glycerin, diglucosyl gallic acid, glycylglycine, panthenol, cationized hydroxypropylcellulose, carnitine, proteoglycan, polyquaternium-67, -107, betaine, tripolyhydroxy fatty acid dipentaerythrityl, sericin, and a phosphorylcholine-like group-containing compound obtained by ring-opening an intermediate obtained by reacting a higher alcohol with 2-chloro-2-oxo-1,3,2-dioxaphosphorane in the presence of an organic base with dimethylalkylamine. agents, poly(styrenesulfonate) sodium salt, polyelectrolytes such as poly(diallyldimethylammonium chloride), (ammonium acryloyldimethyltaurate / beheneth methacrylate) crosspolymer, (PEG / decyltetradeceth / HDI) copolymer, xanthan gum, carboxymethylcellulose, sodium carboxymethylcellulose, polymethacryloyloxyethyl phosphorylcholine, quaternary ammonium group-containing silylated urethane polymer, (sodium acrylate / sodium acryloyldimethyltaurate) copolymer,Polymers such as (styrene / acrylates / methacrylic acid) copolymers, carboxyvinyl polymers, phosphorylcholine group-containing polymers, phosphate-crosslinked starch derivatives, hydroxypropyl starch phosphate, sodium polystyrene sulfonate, (methacryloylethyl dimethyl betaine / methacryloylethyl trimethyl ammonium chloride / methoxy polyethylene glycol methacrylate) copolymers, alkyl acrylate / alkyl methacrylate / polyoxyethylene copolymers, polymethoxy polyethylene glycol methacrylate, methacrylic copolymers, hydrogenated polyisobutene, 2-methacryloyloxyethyl phosphorylcholine / butyl methacrylate copolymers, polyuronic acid, 2-((meth)acryloyloxy)ethyl-2'-(trimethylammonio)ethyl phosphate polymers, lactones such as γ-docosalactone, gluconolactone, and erucalactone,

[0020] Cetyl 2-ethylhexanoate, di-2-heptylundecyl adipate, diglyceryl adipate mixed fatty acid ester, isostearyl isostearate, octyldodecyl isostearate, phytosteryl isostearate, propylene glycol isostearate, isodecyl benzoate, isotridecyl isononanoate, isononyl isononanoate, polyglyceryl eicosandioate / tetradecanedioate, cetyl octanoate, ethyl olivate, ethyl oleate, phytosteryl oleate, di-2-ethylhexyl succinate, diethyl succinate Hexyl, bis(diethylene glycol ethyl ether) succinate, diglyceryl diisostearate, propylene glycol dicaprylate, neopentyl glycol dicaprate, tripropylene glycol dineopentanoate, esters of dipentaerythritol and mixed fatty acids such as hydroxystearic acid / stearic acid / rosin acid, dilinoleic acid di(phytostearyl / isostearyl / cetyl / stearyl / behenyl), isocetyl stearate, stearyl stearate, hydrogenated castor oil stearate, diethyl sebacate, disebacate Ethyl, dextrin fatty acid ester, pentaerythrityl tetra 2-ethylhexanoate, pentaerythritol tetra 2-ethylhexanoate, tri (caprylic acid / capric acid) glyceryl, tri 2-ethylhexanoate glyceryl, triethylhexanoin, isodecyl neopentanoate, isopropyl palmitate, ethylhexyl palmitate, octyl palmitate, hydrogenated castor oil hydroxystearic acid, phytosteryl isostearate, isopropyl myristate, octyldodecyl myristate, myristyl myristate, diisostearyl malate Ester oils such as allyl, isopropyl lauroyl sarcosine, phytosteryl / behenyl / octyldodecyl / isostearyl lauroyl glutamate, di(cholesteryl / behenyl / octyldodecyl) lauroyl glutamate, diisostearyl lauroyl glutamate, dioctyldodeceth-2 lauroyl glutamate, disteareth-2 lauroyl glutamate, dihexyldecyl lauroyl glutamate, phytosteryl / decyltetradecyl myristoyl methyl-β-alanine, and other acyl amino acid esters, 18-methyleicosanoic acid,Branched fatty acids such as 14-methylpentadecanoic acid, 14-methylhexadecanoic acid, 15-methylhexadecanoic acid, 15-methylheptadecanoic acid, 16-methylheptadecanoic acid, 16-methyloctadecanoic acid, 17-methyloctadecanoic acid, and 17-methylnonadecanoic acid, as well as their ester oils, lanolin fatty acids and their salts and other lanolin extracts, sphingosine, natural ceramides or natural ceramides and their derivatives, camellia oil, macadamia nut oil, corn oil, olive oil, avocado oil, castor oil, safflower oil, jojoba oil, sunflower oil, na Natural oils such as seed oil, sesame oil, soybean oil, meadowfoam oil, lavender oil, eucalyptus oil, geranium oil, cypress oil, rose oil, carbanum oil, pepper oil, basil oil, palm rosa oil, pine needle oil, ylang-ylang oil, petitgrain oil, thyme oil, chamomile oil, acai palm fruit oil, argan oil, baobab oil, orange roughy oil, etc.; hydrogenated oils such as hydrogenated coconut oil, hydrogenated palm oil, hydrogenated castor oil, hydrogenated rapeseed oil, hydrogenated palm oil, hydrogenated jojoba oil, etc.; liquid paraffin, liquid isoparaffin, petrolatum, squalene, squalane, 2,2,4,6,6-pentamethylheptane, Hydrocarbon oils such as tannins and terpenes, aloe vera extract, scutellaria root extract, ginseng extract, persimmon tannin extract, canina rose extract, chamomile flower extract, virginiana extract, pear branch extract, centifolia rose extract, tea leaf extract, heartflower extract, witch hazel extract, tilia cordata extract, mulberry extract, cornflower extract, yuzu extract, Roman chamomile extract, royal jelly extract, Japanese pepper extract, cypress extract, hop extract, gentiana extract, taiso extract, kiwi extract, hawthorn extract, Extracts such as ginger extract, adzuki bean seed extract, althea extract, sage extract, fermented rice bran extract, milk thistle extract, white willow extract, grapefruit extract, amur extract, turmeric extract, ginseng extract, hibamata extract, beech bud extract, rice bran extract, camellia extract, peach kernel extract, sophora flavescens extract, chlorella extract, marjoram extract, yarrow extract, shell ginger leaf extract, broccoli extract, balsam extract, horse chestnut extract, licorice extract,Butcher's broom extract, Mimosa pudica extract, Inomoto's grass extract, Clary sage extract, Juniper berry extract, Honeysuckle extract, Lockjaw vine extract, Leaf mold extract, Saffron extract, Manuka extract, Job's tears seed extract, Soybean seed extract, Pomegranate flower extract, Yuzu fruit extract, Job's tears seed extract, Soybean seed extract, Pomegranate extract, Yuzu extract, Coffee tree extract, Himalayan snowbell extract, Plum extract, Bilberry extract, Tea extract, Extract from fermented fruits of grasses, Fermented soybean extract, Brown algae extract, Ageha Extract of thorny pear, wild rose extract, extract of fermented giant germ rice brown rice, extract of rose petals and pistils including placenta, extract of mangosteen extract, daisy extract, curry plant extract, ginkgo extract, ginger extract, calendula extract, quince seed extract, longan extract, apricot extract, pecan extract, sunshine cherry extract, cat's whiskers extract, black raspberry extract, Himalayan raspberry extract, walnut extract, Diarrhea indum extract, Phellodendron bark extract, Coptis japonica extract, Pueraria lobata extract, Lithospermum root extract, Peony extract extracts from natural products such as scutellaria extract, birch extract, sage extract, loquat extract, carrot extract, aloe extract, mallow extract, iris extract, grape extract, coix seed extract, loofah extract, lily extract, saffron extract, cnidium extract, ginger extract, Hypericum extract, rosemary extract, garlic extract, chili pepper extract, and Sanguinea oleifera extract; natural product extracts; proteins or hydrolysates thereof obtained from shells or pearls having nacre; and proteins obtained from silk. or its hydrolysates, protein-containing extracts obtained from the seeds of legumes, zinc pyrithione, trichlorocarbanilide, sulfur, dipotassium glycyrrhizinate, benzalkonium chloride and other antidandruff agents, glyoxylic acid, glyoxylic acid hydrate, glyoxylates, glyoxylamide and other antistatic agents, thickeners, viscosity adjusters, lower alcohols such as ethanol, naphthalenesulfonic acid and other surfactants, emulsifiers, opacifiers, phytic acid and other metal ion sequestering agents, ultraviolet absorbers, sulforaphane, nicotinamide, tannic acid, arginyl fucotosyl glucose,Antioxidants such as tocopheryl retinoate and polyphenols, preservatives, powdered ingredients, urethanes such as urethane resins, hydrophobically modified polyether urethanes and polyurethane gels, blood circulation promoters, local stimulants, hair follicle activators, hair nutrients, anti-androgenic agents, antiseborrheic agents, anti-aging agents, emollients, keratolytic agents, glycyrrhetinic acid, cholesterol, phytosterol, retinol, retinol acetate, retinol palmitate, menthol, alkoxysalicylic acid, salicylic acid, astaxanthin, N-benzoylglycylglycine, humic acid, fulvic acid, 1-indanylidene derivatives, allantoin, glycosaminoglycans, beeswax, candelilla wax, polyglutamic acids, nicotinic acids, phosphoserine, stigmasterol, oleanolic acid, trehangelin, tocopheryl phosphate, ascorbyl ether Skin conditioning agents such as thymol, flavanones, costunolide, dehydrocostus lactone, ascorbic acid-2-phosphate-6-fatty acid, whey, glycerophosphocholine, glucoheptonic acid, and glyceryl-1-octadecyl urethane; bactericides such as miconazole; preservatives; anti-inflammatory agents such as tranexamic acid; cooling agents; amino acids, vitamins such as tocopherol, ascorbic acid, and glucopyranosyl ascorbic acid; vitamin derivatives; herbal extracts; hair growth agents such as minoxidil, methylglyoxal, and isoliquiritigenin; pH adjusters such as citric acid, succinic acid, malic acid, lactic acid, tartaric acid, glycolic acid, glucuronic acid, and sodium hydroxide; deep sea water, pigments, dyes such as Gunjo, coloring materials, dyeing agents such as melanin precursors, and fragrances such as benzyl alcohol and geraniol.

[0021] The hair cleansing composition of the present invention can be used in products such as hair shampoos. EXAMPLES

[0022] The effects of the present invention will be described in more detail with reference to the following examples, but the present invention is not limited to these examples.

[0023] Production Example (Production of Succinylarginine Na Salt) In a 500 ml four-neck flask, 190 g of distilled water was added, and 53.8 g of arginine (Tokyo Chemical Industry Co., Ltd.) was added and stirred to completely dissolve. Succinic anhydride (30.9 g, 1 equivalent, Tokyo Chemical Industry Co., Ltd.) was added thereto. The temperature was raised to 50°C, and a 48 wt% aqueous solution of sodium hydroxide (Fujifilm Wako Pure Chemical Industries, Ltd.) (25.7 g, 1 equivalent) was added dropwise so that the pH was around 6, and the target product was obtained. The structure of the target product is 1 The results were confirmed by H-NMR (JEOL Ltd., JNM-ECZ400S). 1 H-NMR chemical shifts: 1.5–1.8 ppm (4H m), 2.3 ppm (4H m), 3.1 ppm (2H m), 4.1 ppm (1H m).

[0024] Test Method Hair cleansing compositions having the compositions shown in Tables 1 and 2 were prepared in a conventional manner to obtain the hair cleansing compositions described in Examples 1 to 11 and Comparative Examples 1 to 8. The numerical values ​​in the compositions indicate the weight percent of the pure content. The obtained hair cleansing compositions were evaluated as follows. The results are shown in Tables 1 and 2.

[0025] Evaluation method Coacervate confirmation test The turbidity (white balance) of the hair wash compositions in Tables 1 and 2 and those diluted 20-fold by weight with purified water was measured using a spectrophotometer (Spectrophotometer SE2000, Nippon Denshoku Industries Co., Ltd.) The presence or absence of coacervate formation was confirmed from the change in white balance upon dilution. <Coacervate confirmation criteria> 〇: Transparent (no change in white balance) ×: Cloudy (increased white balance) A mark "◯" indicates that no coacervate was formed, and a mark "×" indicates that a coacervate was formed.

[0026] Adjustment of wavy hair bundle for evaluation A hair bundle (Beaulax, hair strand 5, 100% black hair, root aligned) with a length of 30 cm and a width of 5 cm was washed with 3 g of a 10% by weight aqueous solution of sodium laureth sulfate (Kao, Emal (registered trademark) E-27C) and rinsed with hot water at 40°C. The hair bundle was towel-dried, combed with a ring comb, and naturally dried while hanging. The naturally dried hair bundle was sorted into four levels of wavy intensity, and the group with the strongest wavy intensity was selected as the hair bundle for evaluation and used as the wavy hair bundle for evaluation.

[0027] Method for evaluating the effect of suppressing frizz before combing The wavy hair bundle for evaluation was washed with 3 g of a 10 wt% aqueous solution of sodium laureth sulfate, and then rinsed with hot water at 40°C. The hair bundle was towel-dried, combed with a ring comb, and hung up in a temperature- and humidity-controlled room at room temperature of 25°C and humidity of 60%, and then an image was recorded as the state before treatment. After recording, 3 g of the hair cleansing composition of the examples and comparative examples of the present invention was applied to each hair bundle for evaluation again, washed, and rinsed with hot water at 40°C. Then, the wavy hair bundle for evaluation was towel-dried, and hung up in a temperature- and humidity-controlled room at room temperature of 25°C and humidity of 60%, and then an image was recorded as the state after treatment. Five trained evaluators compared the images recording the state of each hair bundle before treatment with the images recording the state of each hair bundle after treatment, and observed and evaluated the wavy suppression effect according to the following evaluation criteria, and the average of the total scores of the five people was calculated. The average value was judged based on the following score criteria. <Evaluation criteria for effect of suppressing wavy hair before combing> 5 points: No wavy hair 4 points: Some hair strands are slightly wavy 3 points: Some hair strands are wavy 2 points: The entire hair bundle is wavy 1 point: The entire hair bundle has large waves <Score criteria for effect of suppressing frizz before combing> ◎: Very good - 4.5 points or more ○: Excellent...3.0 points or more and less than 4.5 points △: Poor...1.5 points or more but less than 3.0 points ×: Very poor...less than 1.5 points

[0028] Evaluation method for the degree of waviness after combing (30 times, 300 times) After evaluating the effect of suppressing undulation before combing, the state of each hair bundle for evaluation when combed 30 times with a ring comb, and the state of the hair bundle for evaluation when combed 270 times (total 300 times) with a ring comb were recorded as images as the state after combing. Five trained evaluators compared the images recording the state of each hair bundle before combing with the images recording the state of each hair bundle after combing, and observed and evaluated the degree of undulation after combing 30 times and 300 times according to the following evaluation criteria, and calculated the average of the total scores of the five people. The average was judged based on the following score criteria. <Evaluation criteria for the degree of waviness after combing (30 times, 300 times)> 5 points: No wavy hair after combing 4 points: Some of the hair strands are slightly wavy after combing 3 points: Some of the hair strands are wavy after combing 2 points: The entire hair bundle is wavy after combing 1 point: The entire hair bundle is significantly wavy after combing <Score criteria for the degree of wavyness after combing (30 times, 300 times)> ◎: Very good - 4.5 points or more ○: Excellent...3.0 points or more and less than 4.5 points △: Poor...1.5 points or more but less than 3.0 points ×: Very poor...less than 1.5 points

[0029] How to evaluate the shine after 300 combings Five trained evaluators observed and evaluated the gloss of the evaluation wavy hair bundle after 300 combings according to the following evaluation criteria, and calculated the average of the total scores of the five evaluators. The average was judged based on the following score criteria. <Gloss evaluation criteria after 300 combings> 4 points: The hair bundle has a smooth and shiny surface. 3 points: The hair bundle is slightly messy but shiny 2 points: The hair bundle is slightly messy and lacks shine. 1 point: The hair bundle surface is very disordered and lacks shine. <Shine score criteria after 300 combings> ◎: Very good - 3.5 points or more ○: Excellent...3.0 points or more and less than 3.5 points △: Poor...2.0 points or more but less than 3.0 points ×: Very poor...less than 2.0 points

[0030] How to evaluate the lightness of the finish A hair bundle (Beaulux, Hair Strand 5, 100% black hair, root-aligned) with a length of 30 cm and a width of 5 cm was bleached. The bleached hair was left to stand for 24 hours in a constant temperature and humidity room at a room temperature of 25°C and a humidity of 60%, to prepare a hair bundle for evaluation. 3 g of the hair wash composition in Tables 1 and 2 was applied to the hair bundle for evaluation, washed, and rinsed with hot water at 40°C. The hair bundle was towel-dried and hand-blow-dried with hot air from a hair dryer, and a sensory evaluation test was conducted by eight expert panelists on the lightness of the finish according to the following evaluation criteria. The average of the total scores of the eight panelists was calculated. The average was judged based on the following score criteria. <Evaluation criteria for lightness of finish> 5: Very light 4: Slightly light 3: Neither 2: A little light 1: It's not lightweight <Lightness of finish score criteria> ◎: Very good - 4.0 points or more ○: Excellent...3.5 points or more and less than 4.0 points △: Poor...3.0 points or more but less than 3.5 points ×: Very poor...less than 3.0 points

[0031] Working Example [Table 1]

[0032] *1: Lipoflow (registered trademark) MN (Lion Specialty Chemicals), *2: Catinal (registered trademark) HC-200 (Toho Chemical Industry Co., Ltd.), *3: Emeral E-27C (Kao Corporation), *4: Emeral 327 (Kao Corporation), *5: Lipolan (registered trademark) LB-440 (Lion Specialty Chemicals), *6: NIKKOL (registered trademark) CMT-30 (Nikko Chemicals Co., Ltd.), *7: REWOPOL (registered trademark) SB FA 30 B (Evonik Japan Co., Ltd.), ※8: Softazoline LAO-C (Kawaken Fine Chemicals Co., Ltd.), ※9: Softazoline CPB (Kawaken Fine Chemicals Co., Ltd.), ※10: Amphitol (registered trademark) 20HD (Kao Corporation), ※11: Aminone (registered trademark) C-11S (Kao Corporation), ※12: Reagent (Fujifilm Wako Pure Chemical Industries, Ltd.)

[0033] Comparative Example [Table 2]

[0034] Evaluation Results Examples 1 to 11, which were prepared within the scope of the hair wash composition of the present invention, suppressed the generation of coacervate, were excellent in the effect of suppressing frizz before combing, reduced the occurrence of frizz after combing, and provided gloss after combing with a light finish. On the other hand, in Comparative Example 1 where the (A) component was outside the range, the occurrence of waves after 300 combings and the lightness of the finish were inferior. In Comparative Example 2 where the (A) component was less than the range, the effect of suppressing waves before combing, the occurrence of waves after combing, and the shine after combing were inferior. In Comparative Example 3 where the (B) component was outside the range, coacervate was generated, and the effect of suppressing waves before combing, the occurrence of waves after combing, and the shine after combing were inferior. In Comparative Example 4 where the (B) component was less than the range, the occurrence of waves after combing, the shine after combing, and the lightness of the finish were inferior. In Comparative Example 5 where the (C) component was outside the range and the (C) component / (D) component were outside the range, the occurrence of waves after combing, the shine after combing, and the lightness of the finish were inferior. In Comparative Example 6, where the (D) component was outside the range and the (C) component / (D) component was below the range, coacervate was generated, and the effect of suppressing wave before combing, the occurrence of wave after combing, and the shine after combing were poor. In Comparative Example 7, where the (D) component was below the range and the (C) component / (D) component was outside the range, the occurrence of wave after 300 combings, the shine after combing, and the lightness of the finish were poor. In Comparative Example 8, where the (B) component polyquaternium-10 was outside the range, coacervate was generated, and the occurrence of wave after combing, the shine after combing, and the lightness of the finish were poor. [Industrial Applicability]

[0035] The hair wash composition of the present invention suppresses the formation of coacervate, inhibits hair frizz before combing, and further reduces the occurrence of frizz due to combing, resulting in a glossy, light finish, thereby enhancing the commercial value of products such as hair shampoos.

Claims

1. (A) Formula (1) 【Chemistry 1】 or a salt thereof: 0.1 to 5.0% by weight (B) Polyquaternium-7: 0.05 to 1.0% by weight (C) Anionic surfactant: 5.0 to 16.0% by weight (D) Amphoteric surfactant: 0.5 to 3.0% by weight and the ratio of component (C) / component (D) is 4.0 to 30.

0. A hair wash composition having the composition:

2. 2. The hair wash composition according to claim 1, wherein the anionic surfactant as component (C) is at least one selected from the group consisting of alkyl sulfates, polyoxyethylene alkyl ether sulfates, α-olefin sulfonates, N-acyl methyl taurines, alkyl sulfosuccinates, and polyoxyethylene alkyl sulfosuccinates.

3. 3. The hair wash composition according to claim 1, wherein the amphoteric surfactant (D) is at least one selected from the group consisting of amidoamine oxide type, amidopropyl betaine type, and sulfobetaine type.

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