Container for receiving a cryofluid

Abstract

The invention relates to a container (1) for receiving a cryofluid, in particular cryogenic hydrogen, having an outer container (3) and an inner container (2) which is arranged therein in a spaced manner relative to the outer container via a support structure (13, 14), wherein the intermediate space (4) between the outer and inner container can be evacuated for the purpose of thermal insulation via an evacuation connection (5) which passes through the wall of the outer container (3), at least one thermal radiation-reflective thermal foil (6) is provided in the intermediate space (4), and at least one web (19, 20) is arranged between the inner face (18) of the outer container (3) and the outer face (17) of the foil (6).

Description

[0001] Container for holding a cryogenic fluid

[0002] The present invention relates to a container for holding a cryogenic fluid, in particular cryogenic hydrogen, having an outer container and an inner container arranged therein at a distance via a support structure, wherein the space between the outer and inner containers can be evacuated for the purpose of thermal insulation via an evacuation connection passing through the wall of the outer container, and wherein at least one heat radiation-reflecting film is located in the space.

[0003] To increase the energy content of energy sources that are gaseous under normal conditions, they are either compressed and stored in pressure vessels for transport and storage purposes, or cooled to low temperatures, thereby at least partially liquefying them into a cryogenic fluid and stored in thermally insulated containers. To power vehicles, for example, liquefied hydrogen or liquefied natural gas (LNG) are stored as high-energy-density cryogenic fluids for subsequent use in what are essentially conventional internal combustion engines or vehicle fuel cells.

[0004] To maintain the extremely low temperatures of such cryogenic fluids, e.g., in the range of -252 °C for liquid hydrogen or -161 °C for LNG, the space between the inner and outer containers is not only evacuated, but also at least one film made of heat-reflecting material, e.g., aluminum, is placed within it. If the film moves during the evacuation of the space and, as a result of the pressure drop, comes into contact with the inside of the outer container, gas pockets may remain there during the evacuation. The trapped gas escapes over time, disperses throughout the space, and thus impairs the vacuum quality required for thermal insulation.

[0005] EP 3 910 232 A1 discloses a container that leaves radial channels between blocks of thermal insulation material, which can be evacuated if necessary. However, the blocks must be relatively solid, making their insertion into the space significantly more difficult and requiring the blocks to be secured therein. Furthermore, the insulating effect of the solid blocks in conjunction with radial channels is poorer.

[0006] CN 111 396 741 A teaches the introduction of getters into the gap, which absorb gas particles to maintain the vacuum longer. However, the absorption properties of the getters are limited, so their effectiveness diminishes.

[0007] The invention aims to create an improved container for cryofluids that overcomes these problems.

[0008] This aim is achieved according to the invention with a container of the type mentioned in the introduction in that at least one web is arranged between the inside of the outer container and the outside of the film, wherein the at least one web starts from a location on the container remote from the evacuation connection and extends at least to the vicinity of the evacuation connection.

[0009] The web(s) in the area between the outer container and the film prevent the film from coming into contact with the inside of the outer container during evacuation. The path of at least one web guides any gas that would otherwise be trapped in the area of ​​the web along the web to the evacuation connection, where it is pumped out. As a result, a gradual deterioration of the vacuum over time due to the escape of gas from such gas pockets is prevented. In practical tests, the pressure increase in the space between the inner and outer containers over time, which occurs due to gas release, could be reduced by up to 570 times.

[0010] It is advantageous if the at least one web has at least one interruption in its length. Such an interruption can be provided, for example, at a manufacturing-related seam of the outer container in order to simplify the manufacture of the container. Alternatively or additionally, the at least one web can be interrupted at any desired point, e.g. at regular intervals or at points where gas inclusions are particularly likely for design reasons. Each interruption forms a passage point for any gas transverse to the longitudinal extent of the at least one web.

[0011] In a particularly advantageous embodiment of the invention, at least one pair of webs is provided, which form an evacuation channel between them. This gives the webs a dual function. On the one hand, they space the film from the inside of the outer container and prevent gas inclusions there. On the other hand, the evacuation channel between the webs brings a location on the container remote from the evacuation port into direct flow connection with the evacuation port, so that during evacuation, the space between them is suctioned from two sides.

[0012] Preferably, the webs of the web pair run approximately parallel to one another, and in particular, the mutual spacing of the webs of a pair corresponds approximately to the thickness of one web. This prevents the film from coming into contact with the outer container between the webs of a web pair during evacuation.

[0013] It is particularly advantageous if several pairs of webs are distributed around the inner circumference of the outer container. The more webs or pairs of webs, the better the degassing effect during evacuation. A good choice is, for example, 4-12, preferably 6-8 pairs of webs distributed around the inner circumference.

[0014] When using multiple pairs of webs, it is particularly advantageous if the evacuation channels of all pairs of webs are in fluid communication with one another at the remote location, preferably by spacing the pairs of webs apart from one another at the remote location. This ensures that this location is evacuated simultaneously via all evacuation channels.

[0015] In a first preferred variant, the web pairs can run from the said remote location to the evacuation connection and their evacuation channels can be in flow connection with the evacuation connection there, preferably by being spaced apart from one another there and from the latter. Alternatively, the webs of one of the web pairs can pass the evacuation connection and temporarily diverge in order to encircle the evacuation connection at a distance from one another. In the latter variant, the web pairs can in particular run from the said remote location to a location on the container opposite thereto and can be in flow connection with one another there, preferably by being spaced apart from one another at the said opposite location. All of these variants result in uniform suction of the space between the film and the inside of the outer container from two or more...three points , either from the location of the evacuation connection and from the said remote location or from the location of the evacuation connection and from two opposite ends of the container , for example its front ends .

[0016] Several webs can be connected to one another to form a grid or net and inserted into the space between the film and the outer container. Alternatively, the web(s) can be fixed to the outside of the film. It is particularly advantageous if the webs are connected to the inside of the outer container, preferably by spot welding or formed integrally with it. This facilitates manufacture and assembly. The film can, for example, be pushed onto the inner container as a tubular sleeve, and then the inner container, with the film pushed onto it, can be inserted into the outer container provided with the webs.

[0017] The webs can be made of any material, for example, vacuum-compatible plastics, or of the material of the outer container if they are formed from it, e.g., by stamping. In a particularly advantageous embodiment, the webs are formed by wires that are, for example, preferably spot-welded to the inside of the outer container. This allows for simple and cost-effective production.

[0018] If the webs or wires are welded to the inside of the outer container at specific points, i.e., at spaced-apart welding points, diffusion or passage paths for gas are created between the welding points, perpendicular to the longitudinal extension of the webs. Through these cross connections, gas inclusions next to the webs can be extracted into the evacuation channels formed by the webs.

[0019] Alternatively, the webs could also be gas-permeable in their transverse direction, for example by being made of porous material.

[0020] The heat-reflecting film can be made of any suitable material, e.g., any thin metal sheet, aluminum foil, etc. Preferably, the film is a multi-layer metal foil composite with a glass fiber fabric, scrim, or nonwoven between the metal foil layers. For example, the metal foil can be rolled up together with a suitable fabric, scrim, or nonwoven and then pushed onto the inner container.

[0021] The invention is explained in more detail below with reference to an embodiment shown in the accompanying drawings. In the drawings:

[0022] Fig. 1 shows the container of the invention in a schematic simplified longitudinal section;

[0023] Fig. 2 shows detail II of Fig. 1 enlarged;

[0024] Fig. 3 shows a section of detail II of Fig. 1 in cross section;

[0025] Fig. 4 shows a part of the outer container, the pairs of webs and the evacuation connection of the container of Fig. 1 in a perspective view; and

[0026] Fig. 5 shows an alternative variant of detail II of Fig. 1.

[0027] Fig. 1 shows a container 1 for holding a cryogenic fluid. The cryogenic fluid can, for example, be hydrogen, which is at least partially liquefied at temperatures of up to -252 °C and below and a pressure of up to 16 bar - or more, depending on the container design - or another cryogenic fluid that can be used in internal combustion engines or fuel cells, e.g. liquefied natural gas (LNG) with a temperature of up to -161 °C and below. The container 1 is mounted, for example, in the manner of a conventional fuel tank on the side of the chassis or frame of a commercial vehicle not shown here, e.g. a truck (lorry) or passenger car (car).

[0028] However, the cryogenic fluid can also be a refrigerant, for example, liquid nitrogen, which is used to operate the cooling system of refrigerated trucks, e.g., food transporters. Accordingly, the container 1 can also be used for storing such refrigerants on trucks or truck trailers.

[0029] To thermally insulate the cryogenic fluid from the outside environment, the container 1 has a double-walled construction, namely an inner container 2 and an outer container 3 surrounding it on all sides with a constant or varying distance A. The space 4 between the inner container 2 and the outer container 3 is evacuated via an evacuation connection 5 passing through the wall of the outer container 3. In the space 4, there is also (at least) one film 6, which reflects the heat radiation directed from the outer container 3 onto the inner container 2 back to the outer container 3 in order to keep the inner container 2 cool, as discussed in more detail later.

[0030] Since the cryogenic fluid in the inner container 2 is generally under pressure, (at least) the inner container 2 is designed as a pressure vessel made of metal or a pressure-resistant composite material, for example, steel, aluminum, or a composite material. The outer container 3 can also be made of metal, for example, but also of plastic, since it only has to withstand the ambient pressure compared to the vacuum in the intermediate space 4. Metals, especially stainless steels, have favorable vacuum properties.

[0031] The inner container 2 has a generally cylindrical shell 7, which is closed at each of its two ends by an outwardly convex cap 8. The term "generally cylindrical" refers to a cylinder with any base or cross-sectional area, whether circular, oval, rectangular, square, or square with rounded corners, or otherwise shaped. For maximum pressure resistance, the shell 7 and thus the inner container 2 have a circular cross-section.

[0032] The outer container 3 is largely adapted to the outer shape of the inner container 2, while maintaining the distance A to create the intermediate space 4. The outer container 3 is also composed, in particular, of a generally cylindrical shell 9 and two inwardly concave caps 10 closing the shell at the ends. It is understood that the distance A does not have to be the same on all sides of the inner container 2. The caps 8, 10 are welded to the respective shell 7, 9, for example, by means of circumferential weld seams 11, 12.

[0033] For the caps 8, 10, any type of dished end known in pressure vessel construction with outwardly convex curvature can be used, such as elliptical ends, dished ends, basket-arch ends, or the like. For the caps 8, 10, diffuser ends ("reverse-dished ends") can also be used, which have a central inwardly curved area surrounded by an outwardly curved edge area. Such diffuser ends are also subsumed here under the term "outwardly convex cap" because of their convex design, at least at the edges.

[0034] To establish the all-round distance A, the inner container 2 is supported on the outer container 3 via support structures 13, 14, which act, for example, on diametrically opposite sides of the inner container 2. In order to be able to absorb thermal changes in length of the inner container 2 in the direction of the diametrical line D between the first support structure 13 and the second support structure 14, the second support structure 14 is a loose bearing in the direction of the diametrical line D, i.e. allows movements of the cap 8 in the direction of the diametrical line D, whereas the first support structure 13 is a fixed bearing. Optionally, the first support structure 13 could also be such a loose bearing.

[0035] The support structures 13, 14 are shown only schematically in Fig. 1 and can be designed in any way known in the art.

[0036] Fig. 2 shows an exemplary embodiment of the film 6 in the intermediate space 4 between the inner container 2 and the outer container 3, in particular between the casing 7 of the inner container 2 and the casing 9 of the outer container 3. In the example shown, the film 6 is a multi-layer metal foil composite made up of three layers 15 of a metal foil, between or next to which there are three layers 16 of a glass fiber fabric, scrim or fleece. For example, a large-format metal foil is placed congruently on top of a large-format glass fiber fabric and rolled up in several layers, which results in a tubular sleeve that can be pushed onto the inner container 2 before it is mounted in the outer container 3.

[0037] If the intermediate space 4 is evacuated via the evacuation port 5 to create a vacuum in the intermediate space 4, it may happen that the flexible film 6, with its outer side 17, adheres to the inner side 18 of the outer container 3. Gases can become trapped in gas inclusions or gas pockets, from where they can, over time, diffuse out through the film 6 and into the intermediate space 4, thereby compromising the vacuum. The measures described below are designed to prevent this.

[0038] Between the inner side 18 of the outer container 3 and the outer side 17 of the film 6 there is arranged at least one web 19 or 20 which, for example, starts from a location 27 of the container 1 which is remote from the evacuation connection 5 and runs at least to the vicinity of the evacuation connection 5. In the example shown in Figs. 3 and 4, six pairs 21 - 26 of two webs 19, 20 each are distributed over the inner circumference of the outer container 3, which start from the location 27, spaced from one another there, and run to a location 28 of the outer container 3 opposite the location 27. The locations 27, 28 are arranged, for example, on the end faces of the container 1, i.e. diametrically opposite one another in the diametral D. Also at location 28 the web pairs 21 - 26 are spaced apart from each other.

[0039] The two webs 19, 20 of each web pair 21-26 run approximately parallel to one another at a mutual distance B, so that an evacuation channel 29 is formed between the webs 19, 20. Due to the mutual distance B of the web pairs 21-26 at the location 27 or 28, the evacuation channels 29 of all web pairs 21-26 are in flow communication with one another.

[0040] The webs 19, 20 of one of the web pairs 21-26, here web pair 21, pass the evacuation connection 5 on their way from location 27 to location 28 and temporarily diverge in order to surround the evacuation connection 5 between them at a distance C. The evacuation channel 29 of the web pair 21 is therefore in flow connection with the evacuation connection 5 and the evacuation connection 5 is also connected via the flow connections at locations 27 and 28 to the evacuation channels 29 of all the other web pairs 22-26. Alternatively, location 28 could directly be the location of the evacuation connection 5, i.e. all web pairs 21-26 end at their end opposite the remote location 27 around and at a distance from the evacuation connection 5.

[0041] Generally speaking, the evacuation connection 5 can be in flow communication with one or more nearby locations 28 or distant locations 27 via any number of webs 19, 20 or web pairs 21-26 extending from it.

[0042] In principle, however, one or more webs 19 or 20 can be arranged in any desired area between the inner side 18 of the outer container 3 and the outer side 17 of the film 6, in particular also at narrow points in the intermediate space, such as beads for the weld seams 11, 12, which lead to a reduced distance A there. Such narrow points can also arise at the butt joints or overlap points of the layers 15, 16 of a multi-layer film 6. There, too, the arrangement of one or more webs 19, 20 is useful in order to evacuate the intermediate space 4 without gas inclusions due to narrow points.

[0043] The functionality of the individual webs 19, 20 or web pairs 21-26 is shown in Fig. 3. Each web 19, 20 separates the film 6 from the outer container 3 during the evacuation of the intermediate space 4, so that a small, wedge-shaped evacuation channel 30, 31 is created on both sides of the web or web pair between the outer side 17 of the film 6, the inner side 18 of the outer container 3, and the side wall of the respective web 19, 20. Any gas pockets remaining between the film 6 and the outer container 3 are evacuated via these evacuation channels 30, 31. Between the webs 19, 20 of each web pair 21, 26 are the aforementioned evacuation channels 29, which form a kind of "main artery" for evacuating the intermediate space 4.

[0044] The webs 19, 20 can be made of any vacuum-compatible material, for example plastic, metal, glass fibers, etc. In the example shown, the webs 19, 20 are wires that are welded onto the inner side 18 of the outer container 3.

[0045] In particular, the webs or wires 19, 20 can also be welded on only point by point, as shown in Fig. 5. Between the welding points 32, gas flow paths 33 then arise in the transverse direction Q (Fig. 3) transverse to the longitudinal extent of the webs 19, 20. Any gas inclusions can diffuse into the evacuation channels 29 via these paths and be pumped out via these. The gas particles can thus "migrate" "beneath" the webs or wires 19, 20 in the transverse direction Q. A similar effect can be achieved if each web or wire 19, 20 has at least one interruption 34 in its respective course (Fig. 4), i.e. is completely open in the transverse direction Q. The gas particles can migrate at the interruption 34 in the transverse direction Q from one side of the web to the other. Such an interruption 34 is shorter, equal to or slightly longer than the web width or the wire diameter and can, for example,be arranged at regular intervals and / or at locations where gas inclusions are particularly likely for design reasons or where accelerated gas passage is desired, for example in the area around the evacuation connection 5 (Fig. 4) in order to facilitate evacuation.

[0046] Furthermore, an interruption 34 can be provided at a manufacturing-related seam of the outer container; e.g., the respective web or wire 19, 20 could extend to the edge of the bead of the cap 10 for the weld seam 11, be interrupted there, and continue to run on the jacket 9 after its interruption 34. The respective web or wire 19, 20 can thus be connected to their respective inner sides 18 in separate sections before the jacket 9 and cap 10 are assembled and welded to form the outer container 3.

[0047] It is understood that the web(s) 19, 20 may be connected not only to the inner side 18 of the outer container 3, but alternatively or additionally also to the outer side 17 of the film 6. One or more webs 19, 20 may also be connected to the inner side 18, others to the outer side 17.

[0048] The thickness of the webs 19, 20, or in the case of wires, their wire diameter, can approximately correspond to their mutual spacing B. The webs 19, 20 can also be formed integrally from the film 6 and / or the outer container 3. For example, the wall of the outer container 3 could be formed inwardly toward the webs 19, 20 by grooving or embossing. In an alternative embodiment, the webs 19, 20 could also simply be inserted between the film 6 and the outer container 3. Several such inserted webs 19, 20 can also be connected to form a type of grid or mesh that is inserted between the film 6 and the outer container 3.

[0049] The invention is not limited to the embodiments shown, but includes all variants, modifications and combinations thereof that fall within the scope of the appended claims.

Claims

Patent claims:

1. A container for holding a cryogenic fluid, in particular cryogenic hydrogen, with an outer container (3) and an inner container (2) arranged therein at a distance via a support structure (13, 14), wherein the intermediate space (4) between the outer and inner containers can be evacuated for the purpose of thermal insulation via an evacuation connection (5) passing through the wall of the outer container (3), and wherein at least one heat radiation-reflecting film (6) is located in the intermediate space (4), characterized in that at least one web (19, 20) is arranged between the inner side (18) of the outer container (3) and the outer side (17) of the film (6), wherein the at least one web (19, 20) starts from a location (27) of the container (1) remote from the evacuation connection (5) and extends at least to the vicinity of the evacuation connection (5).

2. Container according to claim 1, characterized in that the at least one web (19, 20) has at least one interruption (34) in its course.

3. Container according to claim 1 or 2, characterized in that at least one pair (21 - 26) of webs (19, 20) is provided, which form an evacuation channel (29) between one another.

4. Container according to claim 3, characterized in that the webs (19, 20) of the web pair (21 - 26) run approximately parallel to one another.

5. Container according to claim 4, characterized in that the mutual distance (B) of the webs (19, 20) of a pair (21 - 26) corresponds approximately to the thickness of one web (19, 20).

6. Container according to one of claims 3 to 5, characterized in that several pairs of webs (21 - 26) are distributed over the inner circumference of the outer container (3).

7. Container according to claim 6, characterized in that the evacuation channels (29) of all pairs of webs (21 - 26) at said remote location (27) are in flow communication with each other. tion, preferably in that the web pairs (21 - 26) are spaced apart from one another at said remote location (27).

8. Container according to claim 6 or 7, characterized in that the pairs of webs (21 - 26) from said remote location (27) extend to the evacuation connection (5) and their evacuation channels (29) are in flow connection with the evacuation connection (5) there, preferably by being spaced apart from one another and from the latter.

9. Container according to claim 6 or 7, characterized in that the webs (19, 20) of one of the web pairs (21) pass the evacuation connection (5) and diverge temporarily in order to encircle the evacuation connection (5) with a distance (C) between them.

10. Container according to claim 9, characterized in that the web pairs (21 - 26) extend from said remote location (27) to a location (28) of the container (1) opposite thereto and are in flow connection with one another there, preferably in that they are connected at said opposite location (28) are spaced apart from each other.

11. Container according to one of claims 1 to 10, characterized in that several webs (19, 20) are provided which are connected to one another to form a grid or net and are inserted between the inside (18) of the outer container (3) and the outside (17) of the film (6).

12. Container according to one of claims 1 to 10, characterized in that several webs (19, 20) are provided which are fixed on the outer side (17) of the film (6).

13. Container according to one of claims 1 to 10, characterized in that several webs (19, 20) are provided which are connected to the inner side (18) of the outer container (3), preferably welded or formed in one piece therewith.

14. Container according to one of claims 1 to 10, characterized in that a plurality of webs (19, 20) are provided which are welded to the inner side (18) of the outer container (3) at spaced-apart welding points (32).

15. Container according to one of claims 1 to 14, characterized in that several webs (19, 20) are provided which are gas-permeable in the transverse direction (Q).

16. Container according to one of claims 1 to 15, characterized in that several webs (19, 20) are provided which are formed by wires.

17. Container according to one of claims 1 to 16, characterized in that the foil (6) is a multi-layer metal foil composite with a glass fiber fabric, scrim or nonwoven (16) between the metal foil layers (15).

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