Skin cosmetic

Abstract

The present invention provides a skin cosmetic that, despite containing large amounts of powder, has excellent shelf life, spreads well when applied, provides a hydrating sensation, and prevents skin from becoming sticky after application.　The present invention relates to a skin cosmetic that contains components (A), (B), (C), and (D), where (A) is an oil-absorbing powder, 4 to 35 mass%; (B) is a crosslinked organopolysiloxane; (C) is an oil component in liquid form at 25°C, and (D) is a polyol. The total amount of powder including component (A) is 18 to 45 mass%.

Description

Skin cosmetics

[0001] The present invention relates to a skin cosmetic.

[0002] Conventionally, skin cosmetics intended to suppress stickiness caused by excess sebum have been investigated that incorporate a large amount of powder to provide a smooth feel while also providing a moisturizing sensation. For example, Patent Document 1 describes that a skin cosmetic containing water-absorbed porous powder, the surface of which is coated with a binder containing a crosslinked organopolysiloxane, provides a refreshing sensation while continuously suppressing stickiness caused by sebum, and can alleviate the discomfort of oily skin. (Patent Document 1) JP 2006-206545 A

[0003] The present invention relates to a skin cosmetic containing the following components (A), (B), (C), and (D): (A) 4 to 35 mass% of an oil-absorbing powder, (B) a crosslinked organopolysiloxane, (C) an oily component that is liquid at 25°C, and (D) a polyol, in which the total amount of powder including component (A) is 18 to 45 mass%. Detailed Description of the Invention

[0004] When conventional skin cosmetics contain a large amount of powder, it is difficult to ensure storage stability due to issues such as oil separation. There are also issues with the feel of the product when applied, such as spreadability and moisturizing sensation.

[0005] The present inventors have discovered that by using a combination of an oil-absorbing powder, a crosslinked organopolysiloxane, a liquid oily component, and a polyol, it is possible to obtain a skin cosmetic that, even when containing a large amount of powder, has excellent storage stability, spreads well upon application, has a moist feel when used, and yet suppresses stickiness on the skin after application.

[0006] The skin cosmetic of the present invention does not separate oil, has excellent storage stability, spreads easily upon application, does not become smudged on the skin after application, and provides a moist feel while suppressing stickiness after application and providing a smooth feel. Furthermore, for people who style their bangs so that they hang over their forehead, sweat and sebum on the forehead can sometimes cause the styled bangs to become messy, but by using the skin cosmetic of the present invention, such messiness of the bangs can also be suppressed.

[0007] Component (A) used in the present invention is an oil-absorbing powder. An oil-absorbing powder refers to a powder having an oil absorption capacity of 1 mL / g or more. From the viewpoint of improving storage stability, the oil-absorbing powder of component (A) preferably has an oil absorption capacity of 1 mL / g or more, more preferably 1.3 mL / g or more, even more preferably 1.5 mL / g or more, and preferably 4.5 mL / g or less, more preferably 4.3 mL / g or less, and even more preferably 4 mL / g or less. Furthermore, the oil absorption capacity of component (A) is preferably 1 to 4.5 mL / g, more preferably 1.3 to 4.3 mL / g, and even more preferably 1.5 to 4 mL / g.

[0008] In the present invention, oil absorption is measured with reference to the method for measuring oil absorption of pigments specified in JIS K5101-13-1:2004. Specifically, first, 1 g of powder was placed on a glass plate, and dimethylpolysiloxane (silicone 6cs) was added dropwise using a pipette. Each time, the powder and dimethylpolysiloxane were kneaded together using a spatula. This process was repeated, and the end point was determined when the paste of dimethylpolysiloxane and powder reached a smooth consistency. This paste was made to be one that could be spread without breaking or crumbling and that lightly adhered to the glass plate. The volume (mL) obtained by dividing the amount of dimethylpolysiloxane (g) at the end point by the specific gravity of dimethylpolysiloxane (0.925) was used as the oil absorption per 1 g of powder. While the JIS method uses refined linseed oil as the oil, the present invention used dimethylpolysiloxane, which is commonly used in cosmetics.

[0009] The oil-absorbing powder of component (A) is one that is commonly used in cosmetics and can be used without any particular limitation in terms of shape, such as spherical, plate-like, or needle-like, particle size, such as aerosol, fine particle, or pigment-grade, particle structure, such as porous or non-porous, etc. Examples of the oil-absorbing powder of component (A) include inorganic powders, and specific examples thereof include silica; metal silicates such as calcium silicate, magnesium silicate, strontium silicate, aluminum silicate, barium silicate, and magnesium aluminometasilicate; metal carbonates such as calcium carbonate and cobalt carbonate; metal tungstates such as calcium tungstate; metal oxides such as cobalt oxide and α-iron oxide; metal hydroxides such as hydrated iron oxide; and others such as silica gel and hydroxyapatite. Among these, from the viewpoints of improving storage stability, improving spreadability during application, reducing wrinkles on the skin after application, improving moisturized feeling on the skin after application, and improving smooth feeling on the skin after application, it is preferable to contain a spherical porous inorganic powder, and it is more preferable to contain spherical porous silica. As the silica, for example, commercially available products such as Sunsphere H-52 (manufactured by AGC Si-Tech Co., Ltd.; oil absorption 3.1 mL / g), Sunsphere H-51 (manufactured by AGC Si-Tech Co., Ltd.; oil absorption 1.6 mL / g), Sunsphere H-53 (manufactured by AGC Si-Tech Co., Ltd.; oil absorption 3.9 mL / g), Sunsphere H-122 (manufactured by AGC Si-Tech Co., Ltd.; oil absorption 1.65 mL / g), and Silica Microbead LB-1500 (manufactured by JGC Catalysts and Chemicals Co., Ltd.; oil absorption 2.30 mL / g) can be used.

[0010] Component (A) can be used alone or in combination of two or more, and the content thereof is 4% by mass or more, preferably 7% by mass or more, more preferably 10% by mass or more, even more preferably 11.5% by mass or more, and 35% by mass or less, preferably 33% by mass or less, more preferably 30% by mass or less, and even more preferably 17% by mass or less, based on the total composition, from the viewpoints of improving elongation during application, reducing twisting during application, and improving storage stability. The content of component (A) is 4 to 35% by mass, preferably 7 to 33% by mass, more preferably 10 to 30% by mass, and even more preferably 11.5 to 17% by mass.

[0011] The skin cosmetic of the present invention may further contain a powder other than component (A). Powders other than component (A) refer to powders having an oil absorption of less than 1 mL / g, and do not include the powder of component (A). Examples of powders other than component (A) include those commonly used in cosmetics, such as inorganic pigments such as talc, mica, sericite, kaolin, bentonite, alumina, nonporous silica, barium sulfate, cobalt blue, ultramarine, Prussian blue, manganese violet, titanium-coated mica, bismuth oxychloride, yellow iron oxide, red iron oxide, black iron oxide, magnesium oxide, zinc oxide, titanium oxide, zirconium oxide, and aluminum powder; organic pigments such as acrylic resin, polyester resin, fluororesin, polyethylene resin, polypropylene resin, Red No. 202, Red No. 204, Red No. 226, Yellow No. 401, and Blue No. 404; and biopolymers such as keratin powder, collagen powder, silk powder, cellulose powder, and chitosan powder. Among these, from the viewpoint of improving storage stability, it is preferable to contain one or more selected from talc, mica, nonporous silica, barium sulfate, and zinc oxide, more preferably one or more selected from nonporous silica, barium sulfate, and zinc oxide, and even more preferably one or more selected from nonporous silica and barium sulfate. These powders can be used alone or in combination of two or more.

[0012] In the present invention, the total amount of powder including component (A) is 18% by mass or more, preferably 20% by mass or more, more preferably 22% by mass or more, even more preferably 24% by mass or more, and 45% by mass or less, preferably 40% by mass or less, more preferably 38% by mass or less, and even more preferably 35% by mass or less, based on the viewpoints of improving spreadability during application, reducing creasing during application, improving storage stability, and improving the smooth feeling on the skin after application. Furthermore, the total amount of powder including component (A) is 18 to 45% by mass, preferably 20 to 40% by mass, more preferably 22 to 38% by mass, and even more preferably 24 to 35% by mass, based on the viewpoints of improving storage stability. Furthermore, the content of component (A) in the total powder is preferably 10% by mass or more, more preferably 15% by mass or more, even more preferably 20% by mass or more, even more preferably 26% by mass or more, and preferably 100% by mass or less, based on the viewpoints of improving storage stability. The content of component (A) in the total powder is preferably 10 to 100 mass%, more preferably 15 to 100 mass%, even more preferably 20 to 100 mass%, and even more preferably 26 to 100 mass%.

[0013] In the present invention, from the viewpoint of enabling stable production without causing water separation and improving storage stability, the oil absorption of the entire powder in 100 g of the skin cosmetic (the sum of the oil absorption (mL / g) of each powder x the blending ratio (%)) is preferably 30 mL or more, more preferably 35 mL or more, even more preferably 37 mL or more, even more preferably 38 mL or more, particularly preferably 38.5 mL or more, especially preferably 47.5 mL or more, preferably 130 mL or less, more preferably 100 mL or less, even more preferably 69 mL or less, even more preferably 68 mL or less, especially preferably 65 mL or less, especially preferably 62 mL or less. Furthermore, in the present invention, the oil absorption of the entire powder in 100 g of the skin cosmetic (the sum of the oil absorption (mL / g) of each powder x the blending ratio (%)) is preferably 30 to 130 mL, more preferably 35 to 100 mL, even more preferably 37 to 69 mL, still more preferably 38 to 68 mL, particularly preferably 38.5 to 65 mL, and especially preferably 47.5 to 62 mL.

[0014] Examples of the crosslinked organopolysiloxane of component (B) include crosslinked dimethylpolysiloxane and crosslinked alkylpolysiloxane. Note that crosslinked dimethylpolysiloxane is a polymer having a crosslinked structure in which the siloxane skeleton is three-dimensionally crosslinked, and crosslinked alkylpolysiloxane further has an alkyl group having 6 to 20 carbon atoms. Furthermore, the crosslinked organopolysiloxane of component (B) does not contain a polyoxyalkylene group in its structure.

[0015] Examples of crosslinked dimethylpolysiloxanes include (dimethicone / vinyl dimethicone) crosspolymers and (dimethicone / phenyl vinyl dimethicone) crosspolymers. From the viewpoint of improving storage stability, it is preferable to include one or more types selected from (dimethicone / vinyl dimethicone) crosspolymers and (dimethicone / phenyl vinyl dimethicone) crosspolymers, and it is more preferable to include (dimethicone / vinyl dimethicone) crosspolymers.

[0016] As the (dimethicone / vinyl dimethicone) crosspolymer, commercially available products such as KSG-15, which is a mixture with decamethylcyclopentasiloxane, and KSG-16, which is a mixture with low-viscosity dimethylpolysiloxane (both manufactured by Shin-Etsu Chemical Co., Ltd.), can be used. As the (dimethicone / phenylvinyl dimethicone) crosspolymer, commercially available products such as KSG-18, which is a mixture with methylphenylpolysiloxane (manufactured by Shin-Etsu Chemical Co., Ltd.), can be used.

[0017] Examples of crosslinked alkyl polysiloxanes include (vinyl dimethicone / lauryl dimethicone) crosspolymers, etc. Commercially available (vinyl dimethicone / lauryl dimethicone) crosspolymers include KSG-41, a mixture with liquid paraffin, KSG-42, a mixture with light isoparaffin, KSG-43, a mixture with glyceryl tri-2-ethylhexanoate, and KSG-44, a mixture with squalane (all manufactured by Shin-Etsu Chemical Co., Ltd.).

[0018] From the viewpoint of improving storage stability, component (B) preferably contains a crosslinked dimethylpolysiloxane, more preferably contains one or more selected from a (dimethicone / vinyl dimethicone) crosspolymer and a (dimethicone / phenyl vinyl dimethicone) crosspolymer, and even more preferably contains a (dimethicone / vinyl dimethicone) crosspolymer.

[0019] Component (B) can be used alone or in combination of two or more, and from the viewpoints of improving storage stability and improving the smooth feeling on the skin after application, the content is preferably 1% by mass or more of the total composition, more preferably 3% by mass or more, even more preferably 3.3% by mass or more, even more preferably 3.5% by mass or more, and preferably 15% by mass or less, more preferably 10% by mass or less, even more preferably 8.4% by mass or less, and even more preferably 8% by mass or less. The content of component (B) is preferably 1 to 15% by mass of the total composition, more preferably 3 to 10% by mass, even more preferably 3.3 to 8.4% by mass, and even more preferably 3.5 to 8% by mass.

[0020] Component (C) is an oily component that is liquid at 25°C. "Liquid" means that the viscosity at 25°C is 10,000 mPa s or less. The viscosity is measured using a Brookfield viscometer (VISCOMETER TVB-10, manufactured by Toki Sangyo Co., Ltd.) with a rotor No. 4 at 12 rpm for 1 minute. Examples of the oily component of component (C) include hydrocarbon oils, ester oils, ether oils, higher alcohols, silicone oils, and higher fatty acids.

[0021] More specifically, examples of hydrocarbon oils include squalane, liquid paraffin, liquid isoparaffin, light liquid isoparaffin, heavy liquid isoparaffin, etc. The hydrocarbon oil preferably contains one or more selected from squalane, liquid paraffin, liquid isoparaffin, and light liquid isoparaffin, more preferably contains one or more selected from squalane, liquid paraffin, and liquid isoparaffin, even more preferably contains one or more selected from squalane and liquid isoparaffin, and even more preferably contains liquid isoparaffin. Note that liquid isoparaffin is also called hydrogenated polyisobutene.

[0022] Examples of the ester oil include monoester oil, diester oil, triester oil, and tetraester oil. Examples of the monoester oil include monoesters of aliphatic or aromatic monocarboxylic or dicarboxylic acids having 2 to 24 carbon atoms, and specific examples thereof include cetyl 2-ethylhexanoate, cetyl octanoate, isononyl isononanoate, isotridecyl isononanoate, hexyl laurate, isopropyl myristate, octyldodecyl myristate, myristyl myristate, 2-hexyldecyl myristate, isopropyl palmitate, octyl palmitate, isocetyl stearate, isocetyl isostearate, octyl methoxycinnamate, and alkyl benzoates (C12 to C15). The monoester oil preferably contains one or more selected from isononyl isononanoate, isotridecyl isononanoate, and octyldodecyl myristate, more preferably contains one or more selected from isononyl isononanoate and isotridecyl isononanoate, and even more preferably contains isononyl isononanoate.

[0023] Examples of diester oils include diesters of dicarboxylic acids having 3 to 18 carbon atoms and difatty acid esters of polyhydric alcohols, and specific examples include propylene glycol dicaprylate, neopentyl glycol dicaprate, di-2-ethylhexyl succinate, diisopropyl sebacate, diisostearyl malate, etc. The diester oil preferably contains one or more selected from propylene glycol dicaprylate and neopentyl glycol dicaprate, and more preferably contains neopentyl glycol dicaprate.

[0024] Examples of triester oils include tri-fatty acid esters of trihydric or higher polyhydric alcohols, specifically, caprylic / capric triglyceride, glyceryl trioleate, glyceryl tri-2-ethylhexanoate, and vegetable oils such as olive oil, macadamia nut oil, meadowfoam oil, castor oil, safflower oil, sunflower oil, avocado oil, canola oil, apricot kernel oil, rice germ oil, and rice bran oil. The triester oil preferably contains one or more selected from caprylic / capric triglyceride, glyceryl tri-2-ethylhexanoate, and vegetable oils, more preferably caprylic / capric triglyceride and olive oil, and even more preferably caprylic / capric triglyceride.

[0025] Examples of tetraester oils include tetra-fatty acid esters of tetrahydric or higher polyhydric alcohols, and specific examples include pentaerythritol tetra(behenate / benzoate / ethylhexanoate), pentaerythritol tetraoctanoate, and pentaerythritol tetra-2-ethylhexanoate.

[0026] As the ester oil, from the viewpoint of improving storage stability and improving the moist feeling on the skin after application, it is preferable to include one or more types selected from monoester oil, diester oil, and triester oil, more preferably to include one or more types selected from monoester oil and diester oil, and even more preferably to include a diester oil.

[0027] The ether oil includes dialkyl ethers, specifically dihexyl ether, dicaprylyl ether, cetyl-1,3-dimethylbutyl ether, etc., and preferably contains cetyl-1,3-dimethylbutyl ether.

[0028] Examples of higher alcohols include isocetyl alcohol, isostearyl alcohol, 2-octyldodecanol, and oleyl alcohol.

[0029] Examples of silicone oils include volatile and non-volatile linear dimethylpolysiloxanes such as dimethylpolysiloxane (1 cs), dimethylpolysiloxane (1.5 cs), dimethylpolysiloxane (2 cs), and dimethylpolysiloxane (6 cs); branched siloxanes such as methyl trimethicone, tris(trimethylsilyl)methylsilane, and tetrakis(trimethylsilyl)silane; cyclic dimethylsiloxanes such as octamethylcyclotetrasiloxane, decamethylcyclopentasiloxane, and dodecamethylcyclohexasiloxane; and methylphenylpolysiloxanes such as diphenylsiloxyphenyl trimethicone. The silicone oil preferably contains one or more selected from linear dimethylpolysiloxanes and branched siloxanes, more preferably linear dimethylpolysiloxanes, even more preferably one or more selected from dimethylpolysiloxane (2cs) and dimethylpolysiloxane (6cs), and even more preferably dimethylpolysiloxane (6cs). Note that the silicone oil of component (C) does not include the crosslinked organopolysiloxane of component (B), the crosslinked dimethylpolysiloxane modified with polyoxyalkylene groups of component (F) described below, or the crosslinked alkylpolysiloxane modified with polyoxyalkylene groups.

[0030] Examples of higher fatty acids include oleic acid, isostearic acid, and undecylenic acid.

[0031] The oily component of component (C) preferably contains one or more oils selected from hydrocarbon oils, ester oils, ether oils, and silicone oils, and more preferably contains hydrocarbon oils and silicone oils, from the viewpoints of improving the moist feeling on the skin after application and improving storage stability.

[0032] Component (C) can be used alone or in combination of two or more, and from the viewpoints of improving the moist feeling on the skin after application and improving storage stability, the content is preferably 30% by mass or more of the total composition, more preferably 33% by mass or more, even more preferably 35% by mass or more, even more preferably 37.6% by mass or more, particularly preferably 45% by mass or more, preferably 60% by mass or less, more preferably 56.6% by mass or less, even more preferably 55% by mass or less, even more preferably 53% by mass or less, particularly preferably 52% by mass or less. The content of component (C) is preferably 30 to 60% by mass of the total composition, more preferably 33 to 56.6% by mass, even more preferably 35 to 55% by mass, even more preferably 37.6 to 53% by mass, particularly preferably 45 to 52% by mass.

[0033] In the present invention, the mass ratio of component (C) to the total powder amount [(C) / total powder amount] is preferably 0.1 or more, more preferably 0.5 or more, even more preferably 0.7 or more, even more preferably 0.8 or more, particularly preferably 0.9 or more, particularly preferably 1 or more, preferably 3.5 or less, more preferably 3 or less, even more preferably 2.7 or less, even more preferably 2.6 or less, particularly preferably 2.5 or less, particularly preferably 2.3 or less, from the viewpoints of improving storage stability and improving the smooth feeling on the skin after application. Furthermore, the mass ratio of component (C) to the total powder amount [(C) / total powder amount] is preferably 0.1 to 3.5, more preferably 0.5 to 3, even more preferably 0.7 to 2.7, even more preferably 0.8 to 2.6, particularly preferably 0.9 to 2.5, particularly preferably 1 to 2.3.

[0034] The polyol of component (D) is a compound having two or more hydroxyl groups in the molecule, and any of those commonly used in cosmetics may be used. Examples of dihydric alcohols include polyethylene glycol, propylene glycol, dipropylene glycol, tripropylene glycol, polypropylene glycol, 1,3-butylene glycol, 1,3-propanediol, and pentanediol. Examples of trihydric alcohols include glycerin and trimethylolpropane. Examples of tetrahydric alcohols include diglycerin and erythritol. Examples of pentahydric or higher polyhydric alcohols include polyglycerins such as triglycerin; and sugars and sugar alcohols such as glucose, maltose, maltose, sucrose, xylitol, sorbitol, maltitol, polyoxyethylene methyl glucoside, polyoxyethylene ethyl glucoside, and polyoxyethylene propylene glucoside. Of these, from the viewpoint of improving the moist feeling of the skin after application, it is preferable to contain one or more selected from dihydric alcohols and trihydric alcohols, more preferable to contain one or more selected from polyethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, and glycerin, and even more preferable to contain one or more selected from 1,3-butylene glycol and glycerin.

[0035] Component (D) can be used alone or in combination of two or more, and from the viewpoints of improving the moist feeling of skin after application, improving the smooth feeling of skin after application, and improving storage stability, the content is preferably 3% by mass or more, more preferably 5% by mass or more, even more preferably 6% by mass or more, even more preferably 7% by mass or more, particularly preferably 8% by mass or more, particularly preferably 9% by mass or more, preferably 30% by mass or less, more preferably 25% by mass or less, even more preferably 23% by mass or less, even more preferably 20% by mass or less, particularly preferably 16% by mass or less, particularly preferably 13% by mass or less. The content of component (D) is preferably 3 to 30% by mass, more preferably 5 to 25% by mass, even more preferably 6 to 23% by mass, even more preferably 7 to 20% by mass, particularly preferably 8 to 16% by mass, particularly preferably 9 to 13% by mass, based on the total composition.

[0036] The skin cosmetic of the present invention may further contain (E) water. From the viewpoints of improving spreadability during application, reducing creasing during application, and improving storage stability, the content of water as component (E) is preferably 1% by mass or more, more preferably 1.5% by mass or more, and even more preferably 2% by mass or more, and preferably 15% by mass or less, more preferably 13% by mass or less, and even more preferably 12% by mass or less, based on the total composition. Furthermore, the content of water as component (E) is preferably 1 to 15% by mass, more preferably 1.5 to 13% by mass, and even more preferably 2 to 12% by mass, based on the total composition.

[0037] The skin cosmetic of the present invention can further contain (F) a nonionic surfactant, which can improve stability. Examples of the nonionic surfactant of component (F) include crosslinked dimethylpolysiloxane modified with a polyoxyalkylene group, crosslinked alkylpolysiloxane modified with a polyoxyalkylene group, polyoxyethylene hydrogenated castor oil, sorbitan fatty acid ester, polyoxyethylene alkyl ether, polyoxyethylene fatty acid ester, polyoxyethylene alkanol ether, polyglycerin fatty acid ester, glycerin fatty acid ester, sucrose fatty acid ester, and alkyl glyceryl ether.

[0038] Examples of crosslinked dimethylpolysiloxanes modified with polyoxyalkylene groups include (dimethicone / (PEG-10 / 15)) crosspolymers. Commercially available (dimethicone / (PEG-10 / 15)) crosspolymers include KSG-210, a mixture with low-viscosity dimethylpolysiloxane, and KSG-240, a mixture with decamethylcyclopentasiloxane (both manufactured by Shin-Etsu Chemical Co., Ltd.).

[0039] Examples of crosslinked alkylpolysiloxanes modified with polyoxyalkylene groups include (PEG-15 / lauryl dimethicone) crosspolymer and (PEG-10 / lauryl dimethicone) crosspolymer. Commercially available (PEG-15 / lauryl dimethicone) crosspolymers include KSG-310, a mixture with liquid paraffin, KSG-320, a mixture with light isoparaffin, and KSG-330, a mixture with glyceryl tri-2-ethylhexanoate (all manufactured by Shin-Etsu Chemical Co., Ltd.). Commercially available mixtures of (PEG-15 / lauryl dimethicone) crosspolymer and (PEG-10 / lauryl dimethicone) crosspolymer include KSG-340, a mixture with squalane (manufactured by Shin-Etsu Chemical Co., Ltd.).

[0040] In terms of improving storage stability, the average number of moles of polyoxyethylene chains added constituting the polyoxyethylene hydrogenated castor oil is preferably 2 to 20, more preferably 3 to 15, even more preferably 4 to 10, even more preferably 4 to 8, and particularly preferably 5. Furthermore, in terms of improving storage stability, the polyoxyethylene hydrogenated castor oil preferably contains one or more selected from PEG-5 hydrogenated castor oil, PEG-10 hydrogenated castor oil, and PEG-20 hydrogenated castor oil, more preferably one or more selected from PEG-5 hydrogenated castor oil and PEG-10 hydrogenated castor oil, and even more preferably PEG-5 hydrogenated castor oil. As the PEG-5 hydrogenated castor oil, commercially available products such as Emalex HC-5K (manufactured by Nippon Emulsion Co., Ltd.) can be used.

[0041] In terms of improving storage stability, the fatty acid residue constituting the polyglycerol fatty acid ester preferably has 14 to 22 carbon atoms, more preferably 16 to 18 carbon atoms, and even more preferably 18 carbon atoms. Furthermore, in terms of improving storage stability, the average number of moles of glycerin added constituting the polyglycerol fatty acid ester is preferably 2 to 10, more preferably 2 to 6, even more preferably 2 to 4, and even more preferably 2. In terms of improving storage stability, the polyglycerol fatty acid ester preferably contains polyglyceryl-2 diisostearate. Commercially available polyglyceryl-2 diisostearate such as Cosmol 42V (manufactured by The Nisshin Oillio Group, Ltd.) can be used.

[0042] From the viewpoint of improving storage stability, the alkyl chain constituting the alkyl glyceryl ether preferably has 8 to 18 carbon atoms, more preferably 12 to 18, even more preferably 16 to 18, and even more preferably 18. The alkyl glyceryl ether preferably contains one or more selected from 2-ethylhexyl glyceryl ether, batyl alcohol, and isostearyl glyceryl ether, and more preferably contains isostearyl glyceryl ether. Commercially available isostearyl glyceryl ethers such as GE-IS(U) (manufactured by Kao Corporation) can be used.

[0043] Of these, from the viewpoint of improving storage stability, it is preferable to contain one or more selected from polyoxyalkylene group-modified crosslinked dimethylpolysiloxane, polyoxyethylene hydrogenated castor oil, polyglycerin fatty acid ester, and alkyl glyceryl ether, more preferable to contain one or more selected from polyoxyalkylene group-modified crosslinked dimethylpolysiloxane, polyoxyethylene hydrogenated castor oil, and polyglycerin fatty acid ester, even more preferable to contain polyoxyalkylene group-modified crosslinked dimethylpolysiloxane, and even more preferable to contain (dimethicone / (PEG-10 / 15)) crosspolymer.

[0044] Component (F) can be used alone or in combination of two or more, and from the viewpoint of improving storage stability, the content is preferably 0.1 mass% or more of the total composition, more preferably 0.2 mass% or more, even more preferably 0.48 mass% or more, even more preferably 0.5 mass% or more, particularly preferably 0.7 mass% or more, and preferably 5 mass% or less, more preferably 4 mass% or less, even more preferably 3.5 mass% or less, even more preferably 3 mass% or less, particularly preferably 2.4 mass% or less. The content of component (F) is preferably 0.1 to 5 mass% of the total composition, more preferably 0.2 to 4 mass%, even more preferably 0.48 to 3.5 mass%, even more preferably 0.5 to 3 mass%, particularly preferably 0.7 to 2.4 mass%.

[0045] The skin cosmetic of the present invention may further contain (G) a dextrin fatty acid ester, which can improve storage stability and spreadability during application. The dextrin fatty acid ester of component (G) is not limited as long as it is one commonly used in cosmetics, and an ester of a fatty acid having 8 to 24 carbon atoms and dextrin is preferred. Furthermore, the dextrin preferably has an average degree of polymerization of 3 to 150. Specific examples include dextrin palmitate, dextrin stearate, dextrin palmitate-stearate, dextrin oleate, dextrin isopalmitate, dextrin isostearate, dextrin myristate, and dextrin palmitate-2-ethylhexanoate. Among these, from the viewpoints of improving storage stability and improving spreadability during application, it is preferable to contain one or more selected from dextrin palmitate, dextrin myristate, and dextrin palmitate / 2-ethylhexanoate, and it is more preferable to contain dextrin palmitate.

[0046] Component (G) can be used alone or in combination of two or more, and from the viewpoints of improving storage stability and improving spreadability during application, the content is preferably 0.1% by mass or more, more preferably 0.2% by mass or more, even more preferably 0.5% by mass or more, still more preferably 0.8% by mass or more, and preferably 5% by mass or less, more preferably 4% by mass or less, even more preferably 3% by mass or less, and even more preferably 2% by mass or less, based on the total composition. The content of component (G) is preferably 0.1 to 5% by mass, more preferably 0.2 to 4% by mass, even more preferably 0.5 to 3% by mass, and even more preferably 0.8 to 2% by mass.

[0047] The skin cosmetic of the present invention may further contain an oil that is solid or semi-solid at 25°C, which can improve the moist feeling of skin after application. "Solid or semi-solid at 25°C" means that the viscosity at 25°C is greater than 10,000 mPa·s. The viscosity is measured in the same manner as for component (C). Examples of oils that are solid or semi-solid at 25°C include natural ceramides such as ceramide NG, ceramides such as N-(hexadecyloxyhydroxypropyl)-N-hydroxyethylhexadecanamide, sphingolipids such as sphingosines (including natural and synthetic products), sterols such as cholesterol and phytosterol, fatty acids having from 16 to 22 carbon atoms, alcohols having from 16 to 22 carbon atoms, and hydrocarbon oils such as petrolatum. N-(hexadecyloxyhydroxypropyl)-N-hydroxyethylhexadecanamide is a pseudo-ceramide and a ceramide functional component that complements the function of ceramide and can improve skin conditions (such as moisture content). The INCI name for N-(hexadecyloxyhydroxypropyl)-N-hydroxyethylhexadecanamide is Cetyl-PG Hydroxyethyl Palmitamide.

[0048] From the viewpoint of improving the moist feeling of the skin after application, the oil agent that is solid or semi-solid at 25°C preferably contains a sphingolipid, more preferably contains a ceramide, and even more preferably contains one or more selected from ceramide NG and N-(hexadecyloxyhydroxypropyl)-N-hydroxyethylhexadecanamide.

[0049] One or more types of oil agents that are solid or semi-solid at 25°C can be used, and from the viewpoint of improving the moist feeling of skin after application, the content is preferably 0.01% by mass or more, more preferably 0.05% by mass or more, even more preferably 0.1% by mass or more, and preferably 10% by mass or less, more preferably 5% by mass or less, and even more preferably 2% by mass or less, based on the total composition. Furthermore, the content of the oil agent that is solid or semi-solid at 25°C is preferably 0.01 to 10% by mass, more preferably 0.05 to 5% by mass, and even more preferably 0.1 to 2% by mass, based on the total composition.

[0050] In addition to the above-mentioned components, the skin cosmetic of the present invention may contain components commonly used in cosmetics, such as surfactants other than component (F), polymeric compounds, antioxidants, fragrances, preservatives, pH adjusters, sequestering agents, blood circulation promoters, cooling agents, antiperspirants, disinfectants, skin activators, moisturizers other than component (D), and cooling agents.

[0051] The skin cosmetic of the present invention can be produced by a conventional method, for example, by uniformly mixing an oily component containing components (B) and (C) with an aqueous phase component containing component (D), adding a powder component containing component (A), and stirring the mixture.

[0052] From the viewpoints of improving storage stability, improving spreadability during application, and reducing creasing on the skin after application, the skin cosmetic of the present invention preferably has a viscosity at 25°C of 100 Pa·s or more, more preferably 200 Pa·s or more, even more preferably 350 Pa·s or more, even more preferably 370 Pa·s or more, particularly preferably 390 Pa·s or more, preferably 4000 Pa·s or less, more preferably 3000 Pa·s or less, even more preferably 2500 Pa·s or less, even more preferably 2000 Pa·s or less, and particularly preferably 1800 Pa·s or less. The viscosity at 25° C. is preferably 100 to 4000 Pa s, more preferably 200 to 3000 Pa s, even more preferably 350 to 2500 Pa s, still more preferably 370 to 2000 Pa s, and particularly preferably 390 to 1800 Pa s. In the present invention, the viscosity is measured at 25° C. using a B-type viscometer with an elevator, at a rotation speed of 5 rpm, using rotor T-E when the viscosity is less than 2000 Pa s, or rotor T-F when the viscosity is 2000 Pa s or more.

[0053] The skin cosmetic of the present invention is preferably a water-in-oil emulsion cosmetic, and can be used as a skin cosmetic such as a skin care cosmetic, for example, an emulsion, a beauty serum, or a cream.

[0054] In addition to the above-described embodiments, the present invention also discloses the following embodiments.

[0055] <1> A skin cosmetic comprising the following components (A), (B), (C), and (D): (A) 4 to 35 mass% of an oil-absorbing powder, (B) a crosslinked organopolysiloxane, (C) an oily component that is liquid at 25°C, and (D) a polyol, wherein the total amount of powder including component (A) is 18 to 45 mass%.

[0056] <2> The skin cosmetic according to <1>, wherein the oil absorption of component (A) is preferably 1 to 4.5 mL / g, more preferably 1.3 to 4.3 mL / g, and even more preferably 1.5 to 4 mL / g. <3> The skin cosmetic according to <1> or <2>, wherein component (A) preferably contains an inorganic powder, more preferably a spherical porous inorganic powder, and even more preferably spherical porous silica. <4> The skin cosmetic according to any one of <1> to <3>, wherein the content of component (A) is preferably 7 to 33% by mass, more preferably 10 to 30% by mass, and even more preferably 11.5 to 17% by mass or less. <5> The skin cosmetic according to any one of <1> to <4>, further comprising a powder other than component (A) (a powder with an oil absorption of less than 1 mL / g). <6> The skin cosmetic according to any one of <1> to <5>, wherein the total amount of powder including component (A) is preferably 20 to 40% by mass, more preferably 22 to 38% by mass, and even more preferably 24 to 35% by mass. <7> The skin cosmetic according to any one of <1> to <6>, wherein the content of component (A) in the total powder is preferably 10 to 100% by mass, more preferably 15 to 100% by mass, even more preferably 20 to 100% by mass, and even more preferably 26 to 100% by mass. <8> The skin cosmetic according to any one of <1> to <7>, wherein component (B) is preferably one or more selected from crosslinked dimethylpolysiloxanes and crosslinked alkylpolysiloxanes, more preferably includes a crosslinked dimethylpolysiloxane, more preferably includes one or more selected from a (dimethicone / vinyldimethicone) crosspolymer and a (dimethicone / phenylvinyldimethicone) crosspolymer, and even more preferably includes a (dimethicone / vinyldimethicone) crosspolymer. <9> The skin cosmetic according to any one of <1> to <8>, wherein the content of component (B) is preferably 1 to 15% by mass, more preferably 3 to 10% by mass, even more preferably 3.3 to 8.4% by mass, and even more preferably 3.5 to 8% by mass. <10> The skin cosmetic preparation according to any one of <1> to <9>, wherein component (C) is at least one selected from hydrocarbon oils, ester oils, ether oils, higher alcohols, silicone oils, and higher fatty acids, preferably at least one selected from hydrocarbon oils, ester oils, ether oils, and silicone oils, and more preferably at least one selected from hydrocarbon oils and silicone oils.<11> The skin cosmetic according to any one of <1> to <10>, wherein the content of component (C) is preferably 30 to 60% by mass, more preferably 33 to 56.6% by mass, even more preferably 35 to 55% by mass, even more preferably 37.6 to 53% by mass, and particularly preferably 45 to 52% by mass. <12> The skin cosmetic according to any one of <1> to <11>, wherein the mass ratio of component (C) to the total powder amount [(C) / total powder amount] is preferably 0.1 to 3.5, more preferably 0.5 to 3, even more preferably 0.7 to 2.7, even more preferably 0.8 to 2.6, particularly preferably 0.9 to 2.5, and particularly preferably 1 to 2.3. <13> The skin cosmetic according to any one of <1> to <12>, wherein component (D) preferably comprises one or more selected from dihydric alcohols and trihydric alcohols, more preferably one or more selected from polyethylene glycol, propylene glycol, dipropylene glycol, 1,3-butylene glycol, and glycerin, and even more preferably one or more selected from 1,3-butylene glycol and glycerin. <14> The skin cosmetic according to any one of <1> to <13>, wherein the content of component (D) is preferably 3 to 30% by mass, more preferably 5 to 25% by mass, even more preferably 6 to 23% by mass, even more preferably 7 to 20% by mass, particularly preferably 8 to 16% by mass, and especially preferably 9 to 13% by mass. <15> The skin cosmetic according to any one of <1> to <14>, further comprising (E) water, the content of which is preferably 1 to 15% by mass, more preferably 1.5 to 13% by mass, and even more preferably 2 to 12% by mass. <16> The skin cosmetic according to any one of <1> to <15>, further comprising (F) a nonionic surfactant, the content of which is preferably 0.1 to 5% by mass, more preferably 0.2 to 4% by mass, even more preferably 0.48 to 3.5% by mass, even more preferably 0.5 to 3% by mass, and especially preferably 0.7 to 2.4% by mass.<17> (F) The nonionic surfactant is preferably at least one selected from the group consisting of crosslinked dimethylpolysiloxanes modified with polyoxyalkylene groups, crosslinked alkylpolysiloxanes modified with polyoxyalkylene groups, polyoxyethylene hydrogenated castor oil, sorbitan fatty acid esters, polyoxyethylene alkyl ethers, polyoxyethylene fatty acid esters, polyoxyethylene alkanol ethers, polyglycerin fatty acid esters, glycerin fatty acid esters, sucrose fatty acid esters, and alkylglyceryl ethers, and the crosslinked dimethylpolysiloxanes modified with polyoxyalkylene groups are preferably at least one selected from the group consisting of crosslinked alkylpolysiloxanes modified with polyoxyalkylene groups, polyoxyethylene hydrogenated castor oil, sorbitan fatty acid esters, polyoxyethylene alkyl ethers, polyoxyethylene fatty acid esters, polyoxyethylene alkanol ethers, polyglycerin fatty acid esters, glycerin fatty acid esters, sucrose fatty acid esters, and alkylglyceryl ethers. The skin cosmetic according to <16>, which preferably contains one or more selected from methylpolysiloxane, polyoxyethylene hydrogenated castor oil, polyglycerol fatty acid ester, and alkyl glyceryl ether, more preferably contains one or more selected from polyoxyalkylene group-modified crosslinked dimethylpolysiloxane, polyoxyethylene hydrogenated castor oil, and polyglycerol fatty acid ester, even more preferably contains polyoxyalkylene group-modified crosslinked dimethylpolysiloxane, and even more preferably contains (dimethicone / (PEG-10 / 15)) crosspolymer. <18> The skin cosmetic according to any one of <1> to <17>, which may further contain a dextrin fatty acid ester. <19> The skin cosmetic preparation according to any one of <1> to <18>, wherein the viscosity at 25°C is preferably 100 to 4000 Pa·s, more preferably 200 to 3000 Pa·s, even more preferably 350 to 2500 Pa·s, still more preferably 370 to 2000 Pa·s, and particularly preferably 390 to 1800 Pa·s.

[0057] <20> A skin cosmetic preparation containing the following components (A), (B), (C), (D), and (F): (A) 4 to 35% by mass of an oil-absorbing powder, (B) a crosslinked organopolysiloxane, (C) an oily component that is liquid at 25°C, (D) a polyol, and (F) a nonionic surfactant, wherein the total amount of powder including component (A) is 18 to 45% by mass. <21> A skin cosmetic preparation containing the following components (A), (B), (C), (D), and (F): (A) 4 to 35% by mass of an oil-absorbing powder, (B) a (dimethicone / vinyl dimethicone) crosspolymer, (C) an oily component that is liquid at 25°C, (D) a polyol, and (F) a (dimethicone / (PEG-10 / 15)) crosspolymer, wherein the total amount of powder including component (A) is 18 to 45% by mass.

[0058] Examples 1 to 14 and Comparative Examples 1 to 4 Skin cosmetics were produced with the compositions shown in Table 1, and the viscosity was measured and the storage stability, spreadability, lack of creasing, moist feeling (non-powdery feeling), and smooth feeling were evaluated. The results are also shown in Table 1.

[0059] (Production Method) An oily component containing components (B) and (C) and an aqueous phase component containing component (D) were uniformly mixed, followed by adding a powder component containing component (A) and stirring to obtain a skin cosmetic.

[0060] (Evaluation Method) (1) Viscosity (Pa s): The day after production, each skin cosmetic was measured at 25°C using a B-type viscometer with an elevator, with rotor TE for viscosity less than 2000 Pa s, and rotor TF for viscosity 2000 Pa s or more, at a rotation speed of 5 rpm.

[0061] (2) Storage stability: 30 g of each skin cosmetic was filled into a tube container (aluminum laminate tube, manufactured by Yoshino Kogyosho Co., Ltd., formulation outlet φ3 mm), and stored for one month in a thermostatic chamber at 40°C or -5°C with the tube container outlet facing downwards. After storage, each skin cosmetic was removed from the thermostatic chamber and left to stand for 5 hours in a thermostatic chamber at 25°C with the tube container outlet facing downwards. The skin cosmetic was then discharged from the tube outlet, and the appearance of the skin cosmetic was visually evaluated according to the following criteria: A: No change. B: Very slight oil separation was observed, to the extent that the surface of the skin cosmetic was wet. C: Slight oil separation was observed, but not enough to drip from the tube. D: Clear oil separation was observed, to the extent that it dripped from the tube.

[0062] (3) Spreadability: Three expert panelists applied each skin cosmetic to the skin (approximately 0.2 g on the back of the hand) and evaluated the spreadability using the following five-point scale. The results were shown as the total scores of the three expert panelists: 5: Very good spreadability; 4: Good spreadability; 3: Fairly good spreadability; 2: Poor spreadability; 1: Very poor spreadability.

[0063] (4) Freedom from creasing: Three expert panelists applied each skin cosmetic to the skin (approximately 0.2 g on the back of the hand), and then evaluated the freeness of the cosmetic on the following five-point scale. The results were shown as the total score of the three expert panelists: 5: No creasing at all. 4: Almost no creasing. 3: Some creasing. 2: Some creasing. 1: Significant creasing.

[0064] (5) Moisture (non-powdery): Three expert panelists applied each skin cosmetic to the skin (approximately 0.2 g on the back of the hand) and then evaluated the moisture (non-powdery) using the following five-point scale. The results are shown as the total scores of the three expert panelists. 5: Very good moisture (not powdery at all). 4: Good moisture (not powdery). 3: Fairly good moisture (slightly non-powdery). 2: Fairly poor moisture (powdery). 1: Poor moisture (very powdery).

[0065] (6) Smoothness: Three expert panelists applied each skin cosmetic to the skin (approximately 0.2 g on the back of the hand) and then evaluated the smoothness using the following five-point scale. The results are shown as the total points given by the three expert panelists: 5: Very good smoothness; 4: Good smoothness; 3: Fairly good smoothness; 2: Fairly poor smoothness; 1: Poor smoothness.

[0066]

[0067] *1: Porous silica (oil absorption: 3.1 mL / g); Sunsphere H-52 (manufactured by AGC Si-Tech Co., Ltd.), *2: Porous silica (oil absorption: 1.6 mL / g); Sunsphere H-51 (manufactured by AGC Si-Tech Co., Ltd.), *3: Porous silica (oil absorption: 3.9 mL / g); Sunsphere H-53 (manufactured by AGC Si-Tech Co., Ltd.), *4: Non-porous silica (oil absorption: 0.4 mL / g); Sunsphere NP30 (manufactured by AGC Si-Tech Co., Ltd.), *5: Barium sulfate (oil absorption: 0.7 mL / g); Plate-shaped barium sulfate H (manufactured by Sakai Chemical Industry Co., Ltd.), *6: Mixture of (dimethicone / vinyl dimethicone) crosspolymer and dimethicone; silicone KSG-16 (a mixture of 24% by mass of (dimethicone / vinyl dimethicone) crosspolymer and 76% by mass of dimethicone (6CS)) (manufactured by Shin-Etsu Chemical Co., Ltd.), *7: Dimethicone; silicone KF-96A-6CS (manufactured by Shin-Etsu Chemical Co., Ltd.), *8: Liquid isoparaffin; Pearleem EX (manufactured by NOF Corporation), *9: Glycerin; concentrated glycerin for cosmetics (manufactured by Kao Corporation), *10: 1,3-butylene glycol; 1,3-butylene glycol-P (manufactured by KH Neochem Co., Ltd.), *11: a mixture of (dimethicone / (PEG-10 / 15)) crosspolymer and dimethicone; silicone KSG-210 (a mixture of 24% by mass of (dimethicone / (PEG-10 / 15)) crosspolymer and 76% by mass of dimethicone (6CS)) (manufactured by Shin-Etsu Chemical Co., Ltd.)

[0068] Examples 15 to 19 Skin cosmetics having the compositions shown in Table 2 were prepared in the same manner as in Examples 1 to 14, and the viscosity was measured and the storage stability, spreadability, lack of creasing, moist feeling (non-powdery feeling), and smooth feeling were evaluated. The results are also shown in Table 2.

[0069]

[0070] * 12: PEG-5 hydrogenated castor oil; Emalex HC-5K (manufactured by Nippon Emulsion Co., Ltd.), * 13: Polyglyceryl-2 diisostearate; Cosmol 42V (manufactured by Nisshin Oillio Group Co., Ltd.), * 14: Isostearyl glyceryl; GE-IS (U) (manufactured by Kao Corporation), * 15: Dextrin palmitate; Leopearl KL2 (manufactured by Chiba Flour Milling Co., Ltd.)

[0071] Formulation Examples 1 to 3 All of the skin cosmetics shown in Table 3 exhibit no oil separation, have excellent storage stability, spread well upon application, do not crumble on the skin after application, and provide a moist feel while suppressing stickiness after application, resulting in a smooth feel. Furthermore, the viscosity at 25°C is 100 to 4000 Pa s.

[0072]

[0073] * 16: Zinc oxide (oil absorption: 0.4 mL / g); MICRO ZINC OXIDE MZ-504R3M (manufactured by Teika Corporation), * 17: Cetyl PG hydroxyethyl palmitamide; sphingolipid E ​​(manufactured by Kao Corporation), * 18: Ceramide NG; Ceramide TIC-001 (manufactured by Takasago International Corporation), * 19: Squalane; NIKKOL Sugar Squalane (manufactured by Nippon Surfactant Industry Co., Ltd.), * 20: Eucalyptus extract; Eucalyptus extract K (manufactured by Koei Kogyo Co., Ltd.)

[0074] Example 20, Comparative Examples 5-6: The skin cosmetics listed in Table 4 were prepared according to the methods described above, and the sebum absorption rate, unsaturated fatty acid absorption rate, and storage stability of the skin cosmetics were evaluated in the same manner as described above. The sebum absorption rate and unsaturated fatty acid absorption rate were calculated based on the relationship between the amount of sebum collected from skin without the skin cosmetic (unapplied) and the amount of sebum collected from skin with the skin cosmetic (applied). The results are also shown in Table 4. (Method for Evaluating Sebum Absorption Rate and Unsaturated Fatty Acid Absorption Rate) (1) After washing their face, one expert panelist allowed 15 minutes of acclimation and then applied 6 mg of the skin cosmetic to an area of ​​1.7 cm x 1.7 cm on their forehead. (2) The panelists rested for 90 minutes in an environmentally variable chamber at 20°C and 40% RH. (3) After 90 minutes, a piece of cigarette paper (manufactured by Rizla) was placed on the skin to which the skin cosmetic had been applied and pressed down for 10 seconds to collect sebum. The same procedure was also performed on the forehead skin to which no skin cosmetic was applied, and sebum was collected. (4) The sebum components adhering to the cigarette paper were extracted with methanol and quantified by LC-MS. Column: Acclaim 120 (C18 3 μm 120 Å 2.1 × 50 mm, Thermo Fisher Scientific) Column temperature: 45°C Mobile phase: A) 60% methanol containing 10 mM ammonium acetate B) chloroform / methanol (1 / 1, v / v) containing 10 mM ammonium acetate 10% B (0-1 min) → 10-60% B (1-1.1 min) → 60% B (1.1-6 min) → 60-95% B (6-6.1 min) → 95% B (6.1-11 min) → 95-10% B (11-11.1 min) → 10% B (11.1-15 min) (5) The sebum absorption rate of the skin cosmetic was evaluated using the following formula. Amount of sebum (unapplied): Amount of sebum collected from skin to which a skin cosmetic was not applied Amount of sebum (applied): Amount of sebum collected from skin to which a skin cosmetic was applied (Sebum absorption rate) = 100 - (amount of sebum (applied)) / (amount of sebum (unapplied)) x 100 The "unsaturated fatty acid absorption rate" was evaluated by calculating the "unsaturated fatty acid absorption rate" from the above formula using only the amount of unsaturated fatty acids in the amount of sebum collected by the above procedure.

[0075]

[0076] The same evaluation as in the evaluation of storage stability as described above was carried out, and it was found that Example 20 was stable after one month of storage at 40° C. and −5° C. On the other hand, both Comparative Examples 5 and 6 were unstable.

[0077] The skin cosmetics shown in Table 5 were produced according to the method described above, and the viscosity of the skin cosmetics was measured in the same manner as above. The storage stability, spreadability, lack of creasing, moist feeling (non-powdery feeling), and smooth feeling were evaluated according to the same methods and criteria as above. The results are also shown in Table 5.

[0078]

[0079] Examples 1 to 19 and 21 to 23, Comparative Examples 1 to 4 The skin cosmetics listed in Tables 1, 2, and 5 were evaluated for the ability of set bangs to stay in place using the following method. The results are shown in Tables 6 to 9. (Method for evaluating the ability of set bangs to stay in place) Three expert panelists applied approximately 0.2 g of each skin cosmetic to the forehead, and evaluated the ability of the set bangs to stay in place three hours later using the following five-point scale. The results are shown as the total score of the three expert panelists. 5: The bangs did not fall out of place. 4: The bangs hardly fell out of place. 3: The bangs were somewhat resistant to falling out of place. 2: The bangs were somewhat prone to falling out of place. 1: The bangs were prone to falling out of place.

[0080]

[0081]

[0082]

[0083]

Claims

1. The following components (A), (B), (C) and (D): (A) Oil-absorbing powder 4 to 35% by mass, (B) Crosslinked organopolysiloxane, (C) An oily component that is liquid at 25°C, (D) Polyol, and a skin cosmetic containing the total amount of powder containing component (A) being 18 to 45% by mass.

2. The skin cosmetic according to claim 1, wherein the mass ratio of component (C) to the total amount of powder [(C) / total amount of powder] is 0.1 to 3.

5.

3. The skin cosmetic according to claim 1 or 2, wherein the viscosity at 25°C is 100 to 4000 Pa·s.

4. The skin cosmetic according to any one of claims 1 to 3, wherein the content of component (D) is 3 to 30% by mass.

5. The skin cosmetic according to any one of claims 1 to 4, wherein the content of component (B) is 1 to 15% by mass.

6. The skin cosmetic according to any one of claims 1 to 5, wherein the content of component (C) is 30 to 60% by mass.

7. The skin cosmetic according to any one of claims 1 to 6, further containing (E) water and the water content being 1 to 15% by mass.

8. The skin cosmetic according to any one of claims 1 to 7, further containing (F) a nonionic surfactant.

9. The skin cosmetic according to any one of claims 1 to 8, wherein the oil absorption amount of the oil-absorbing powder of component (A) is 1 to 4.5 mL / g.

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