Cemented carbide and cutting tool

Abstract

Provided is cemented carbide comprising a first hard phase, a plurality of second hard phases, and a binder phase, wherein: the first hard phase comprises a plurality of tungsten carbide particles; the particle diameter D10 of the tungsten carbide particles is 0.40 μm or greater; the particle diameter D90 of the tungsten carbide particles is 2.00 μm or less; the second hard phase comprises at least one type of a first compound selected from the group consisting of TaNbC, TaNbN, TaNbCN, TiCN, TiNbC, TiNbN, and TiNbCN; the cemented carbide contains 0.30-1.60 vol% of the second hard phases; the average circularity of the second hard phases in the cross-section of the cemented carbide is 0.10-0.32; the standard deviation of the circularity is 0.094-0.130; the binder phase contains 50 mass% or greater of cobalt; and the cemented carbide contains 8.0-12.0 vol% of the binder phase.

Description

Cemented Carbide and Cutting Tools

[0001] The present disclosure relates to cemented carbides and cutting tools.

[0002] Conventionally, cemented carbide alloys have been used as materials for cutting tools, which include a first hard phase mainly composed of tungsten carbide (WC), a second hard phase mainly composed of a compound containing multiple metal elements including tungsten and one or more elements selected from carbon, nitrogen, oxygen, and boron, and a binder phase mainly composed of an iron group element.

[0003] International Publication No. 2017 / 191744

[0004] The cemented carbide of the present disclosure is a cemented carbide comprising a first hard phase, a plurality of second hard phases, and a binder phase, wherein the first hard phase comprises a plurality of tungsten carbide particles, wherein the tungsten carbide particles have a particle size D10 of 0.40 μm or more and a particle size D90 of 2.00 μm or less, the second hard phase comprises at least one first compound selected from the group consisting of TaNbC, TaNbN, TaNbCN, TiCN, TiNbC, TiNbN, and TiNbCN, the cemented carbide contains the second hard phase in an amount of 0.30 volume % or more and 1.60 volume % or less, the average circularity of the second hard phase in a cross section of the cemented carbide is 0.10 or more and 0.32 or less, and the standard deviation of the circularity is 0.094 or more and 0.130 or less, The binder phase contains 50 mass % or more of cobalt, and the cemented carbide contains 8.0 volume % or more and 12.0 volume % or less of the binder phase.

[0005] Fig. 1 is a diagram illustrating a typical configuration example of a cemented carbide according to embodiment 1. Fig. 2 is a schematic cross-sectional view of a cutting tool according to embodiment 2. Fig. 3 is a diagram illustrating an example of the cutting tool according to embodiment 2.

[0006] [Problem to be Solved by the Present Disclosure] When aluminum is machined with a cutting tool made of cemented carbide containing a second hard phase, tool damage caused by welding tends to increase, cutting resistance tends to increase, and tool life tends to decrease.

[0007] Therefore, an object of the present disclosure is to provide a cemented carbide alloy that, when used as a cutting tool material, enables the cutting tool to have a longer life even when machining aluminum, and a cutting tool including the same.

[0008] [Effects of the Present Disclosure] According to the present disclosure, it is possible to provide a cemented carbide alloy that, when used as a cutting tool material, enables the cutting tool to have a longer life even when machining aluminum, and a cutting tool including the cemented carbide alloy.

[0009] [Description of Embodiments of the Present Disclosure] First, embodiments of the present disclosure will be listed and described. (1) The cemented carbide of the present disclosure is a cemented carbide comprising a first hard phase, a plurality of second hard phases, and a binder phase, wherein the first hard phase comprises a plurality of tungsten carbide particles, the tungsten carbide particles have a particle size D10 of 0.40 μm or more, and a particle size D90 of 2.00 μm or less, the second hard phase comprises at least one first compound selected from the group consisting of TaNbC, TaNbN, TaNbCN, TiCN, TiNbC, TiNbN, and TiNbCN, the cemented carbide contains the second hard phase in an amount of 0.30 volume % or more and 1.60 volume % or less, and the average circularity of the second hard phase in a cross section of the cemented carbide is 0.10 or more and 0.32 or less, The standard deviation of the circularity is 0.094 or more and 0.130 or less, the binder phase contains 50 mass% or more of cobalt, and the cemented carbide contains 8.0 volume% or more and 12.0 volume% or less of the binder phase.

[0010] According to the present disclosure, it is possible to provide a cemented carbide that, when used as a material for cutting tools, enables the cutting tools to have a longer life even when machining aluminum.

[0011] (2) In the above (1), the cemented carbide may contain 0.08% by mass or more and 0.5% by mass or less of chromium.

[0012] Chromium is used as a grain growth inhibitor in the production of cemented carbide (Cr ３ C ２When the cemented carbide contains chromium in the above range, the hardness of the cemented carbide is improved, and the life of a cutting tool using the cemented carbide is further improved.

[0013] (3) In the above (1) or (2), the binder phase may contain one or both of iron and nickel.

[0014] This improves the toughness of the cemented carbide, and further improves the life of cutting tools using the cemented carbide.

[0015] (4) A cutting tool according to the present disclosure is a cutting tool including the cemented carbide according to any one of (1) to (3) above.

[0016] According to the present disclosure, it is possible to provide a cutting tool having a long life even when machining aluminum.

[0017] (5) In the above (4), the cutting tool may further include a substrate made of the cemented carbide and a coating provided on the substrate, thereby further improving the life of the cutting tool.

[0018] (6) In the above (4) or (5), a substrate made of the cemented carbide and a cutting edge member fixed to the substrate may be provided, which further improves the life of the cutting tool.

[0019] (7) In the above (6), the cutting edge member may be made of cubic boron nitride sintered body or diamond, which further improves the life of the cutting tool.

[0020] [Details of the Embodiments of the Present Disclosure] Specific examples of the cemented carbide and cutting tool of the present disclosure will be described below with reference to the drawings. In the drawings of the present disclosure, the same reference numerals represent the same or corresponding parts. Furthermore, dimensional relationships such as length, width, thickness, and depth have been appropriately changed for clarity and simplification of the drawings, and do not necessarily represent actual dimensional relationships.

[0021] In the present disclosure, the notation in the form of "A to B" means A or more and B or less, and when no unit is specified for A and a unit is specified only for B, the unit of A and the unit of B are the same.

[0022] In the present disclosure, when a compound or the like is represented by a chemical formula, unless the atomic ratio is particularly limited, it is intended to include any conventionally known atomic ratio, and should not necessarily be limited to only those within the stoichiometric range.

[0023] In the present disclosure, when one or more numerical values ​​are listed as the lower limit and the upper limit of a numerical range, the combination of any one numerical value listed as the lower limit and any one numerical value listed as the upper limit is also considered to be disclosed.

[0024] [Embodiment 1: Cemented Carbide] As shown in FIG. 1 , a cemented carbide 4 according to one embodiment of the present disclosure (hereinafter also referred to as "Embodiment 1") is a cemented carbide 4 comprising a first hard phase 1, a plurality of second hard phases 2, and a binder phase 3, wherein the first hard phase 1 comprises a plurality of tungsten carbide particles, wherein the tungsten carbide particles have a particle size D10 of 0.40 μm or more, and a particle size D90 of the tungsten carbide particles of 2.00 μm or less, wherein the second hard phase 2 comprises at least one first compound selected from the group consisting of TaNbC, TaNbN, TaNbCN, TiCN, TiNbC, TiNbN, and TiNbCN, and the cemented carbide 4 contains the second hard phase 2 in an amount of 0.30 vol% or more and 1.60 vol% or less, In a cross section of the cemented carbide 4, the average circularity of the second hard phase 2 is 0.10 or more and 0.32 or less, the standard deviation of the circularity is 0.094 or more and 0.130 or less, the binder phase 3 contains 50 mass% or more of cobalt, and the cemented carbide 4 contains 8.0 volume% or more and 12.0 volume% or less of the binder phase 3.

[0025] When used as a cutting tool material, the cemented carbide of embodiment 1 enables the cutting tool to have a long life even when machining aluminum. The reason for this is not clear, but is presumed to be as follows.

[0026] In the cemented carbide of embodiment 1, the average circularity of the second hard phase in the cross section of the cemented carbide is 0.10 to 0.32, and the standard deviation of the circularity is 0.094 to 0.130. This indicates that the cross section of the second hard phase is far from a perfect circle, and the perimeter of the second hard phase is longer than when the cross section of the second hard phase is a perfect circle. Therefore, the shape of the second hard phase is far from a perfect sphere (a perfect sphere), and the surface area of ​​the second hard phase is also larger than when the second hard phase is a perfect sphere. This improves the adhesion between the first hard phase, the second hard phase, and the binder phase. Therefore, a cutting tool using the cemented carbide of embodiment 1 as its material can suppress the expansion of tool damage caused by welding, even when machining aluminum, and can have a long tool life.

[0027] <Composition of Cemented Carbide> The cemented carbide of embodiment 1 is composed of a first hard phase, multiple second hard phases, and a binder phase. The cemented carbide may contain impurities as long as the effects of the present disclosure are not impaired. That is, the cemented carbide may be composed of a first hard phase, multiple second hard phases, a binder phase, and impurities. Examples of impurities include iron (Fe), molybdenum (Mo), calcium (Ca), silicon (Si), and sulfur (S). The impurity content of the cemented carbide (when there are two or more types of impurities, the total content of these impurities) may be 0% by mass or more and less than 0.1% by mass. The impurity content of the cemented carbide is measured by inductively coupled plasma emission spectroscopy (ICP optical emission spectroscopy). Shimadzu Corporation's "ICPS-8100" (trademark) can be used as the measuring device.

[0028] The content of the second hard phase in the cemented carbide of embodiment 1 is 0.30 vol% or more and 1.60 vol% or less. This improves the adhesion resistance, heat resistance, and wear resistance of the cemented carbide. The content of the second hard phase in the cemented carbide may be 0.40 vol% or more and 1.50 vol% or less, or 0.50 vol% or more and 1.40 vol% or less.

[0029] The cemented carbide of the first embodiment has a binder phase content of 8.0% by volume or more and 12.0% by volume or less, which improves the strength of the cemented carbide. The binder phase content of the cemented carbide may be 8.1% by volume or more and 11.9% by volume or less, or 8.2% by volume or more and 11.8% by volume or less.

[0030] The content of the first hard phase in the cemented carbide of the first embodiment is a value obtained by subtracting the volumes of the second hard phase and the binder phase from 100% by volume of the entire cemented carbide.

[0031] The methods for measuring the content of the first hard phase, the content of the second hard phase, and the content of the binder phase in a cemented carbide are as follows: (A1) A position of the cemented carbide is cut out to expose a cross section, which is then mirror-polished using a cross-section polisher (manufactured by JEOL Ltd.).

[0032] (B1) The processed surface of the cemented carbide is photographed using a scanning electron microscope (SEM) ("S-3400N" (trademark) manufactured by Hitachi High-Technologies Corporation) to obtain a backscattered electron image. Six backscattered electron images are prepared. The photographed areas of the six backscattered electron images are different. The photographed locations can be set arbitrarily. The observation conditions are a magnification of 5000x and an accelerating voltage of 10 kV.

[0033] (C1) The photographed area of ​​(B1) above is subjected to elemental analysis using an energy dispersive X-ray analyzer (SEM-EDX) attached to the SEM, to obtain an elemental mapping image.

[0034] (D1) The six backscattered electron images obtained in (B1) above are imported into a computer using image analysis software (ImageJ, version 1.51j8: https: / / imagej.nih.gov / ij / ), and binarized to obtain six binarized images. The binarization is performed under conditions preset in the image analysis software by clicking the "Make Binary" button on the computer screen after importing the images. In the binarized image, the first region consisting of the first hard phase and the second region consisting of the second and third hard phases can be distinguished by the shade of color. For example, in the binarized image, the first hard phase is shown as a black region, and the second and third hard phases are shown as white regions.

[0035] (E1) By superimposing the element mapping image obtained in (C1) above on the binarized image obtained in (D1) above, the regions where the first hard phase, the second hard phase, and the binder phase exist are identified on the binarized image. Specifically, the regions shown in black in the binarized image and where tungsten (W) and carbon (C) exist in the element mapping image correspond to the regions where the first hard phase exists. The regions shown in white in the binarized image and where titanium (Ti) or tantalum (Ta) exist in the element mapping image correspond to the regions where the second hard phase exists. The regions shown in white in the binarized image and where cobalt exists in the element mapping image correspond to the regions where the binder phase exists.

[0036] (F1) One rectangular measurement field of view of 25.3 μm × 17.6 μm is set in each of the six images after binarization. Using the image analysis software, the area percentages (area%) of the first hard phase, second hard phase, and binder phase are measured in each of the six measurement fields, with the area of ​​the entire measurement field being used as the denominator. In the present disclosure, the average area percentages (area%) of the first hard phase in the six measurement fields, the average area percentages (area%) of the second hard phase in the six measurement fields, and the average area percentages (area%) of the binder phase in the six measurement fields correspond to the content (volume%) of the first hard phase, the content (volume%) of the second hard phase, and the content (volume%) of the binder phase in the cemented carbide, respectively.

[0037] As long as measurements are made on the same sample, it has been confirmed that there is almost no variation in the measurement results even if the above measurement is performed multiple times by changing the selected location of the measurement field.

[0038] <First Hard Phase> <Composition> In the cemented carbide of the first embodiment, the first hard phase is composed of a plurality of tungsten carbide particles (hereinafter also referred to as "WC particles"). The tungsten carbide particles include not only "pure WC particles (including WC containing no impurity elements and WC with impurity elements contained below the detection limit)" but also "WC particles containing impurities therein, as long as the effects of the present disclosure are not impaired." Examples of impurities include iron (Fe), molybdenum (Mo), and sulfur (S).

[0039] <Particle size of tungsten carbide particles> The particle size D10 of the tungsten carbide particles is 0.40 μm or more, and the particle size D90 of the tungsten carbide particles is 2.00 μm or less. This provides the cemented carbide with high hardness, and improves the wear resistance of cutting tools containing the cemented carbide.

[0040] The tungsten carbide particles may have a D10 of 0.42 μm or more, or 0.44 μm or more, and a D90 of 1.98 μm or less, or 1.96 μm or less.

[0041] In the present disclosure, the D10 and D90 of tungsten carbide particles refer to the D10 (circle-equivalent diameter at which the cumulative number-based frequency is 10%) and D90 (circle-equivalent diameter at which the cumulative number-based frequency is 90%) of the equivalent circle diameters of the same area (Heywood diameters) of the tungsten carbide particles in the cross section of the cemented carbide, respectively.

[0042] In the present disclosure, the method for measuring D10 and D90 of tungsten carbide particles is as follows. (A2) Six images after binarization are obtained using the same method as the method for measuring the content of the first hard phase, etc., of cemented carbide. Furthermore, to remove noise, the "Despeckle" display on the computer screen is pressed once, and then the "Watershed" display is pressed. This allows the grain boundaries of the first hard phase (tungsten particles) to be identified on the binarized image using conditions preset in the image analysis software. Pressing "Analyze Particle" on the computer screen allows the area to be determined as 0.002 μm. ２ The equivalent diameter of a circle having the same area as the above tungsten carbide particles is measured.

[0043] (B2) In each of the six binarized images, a rectangular measurement field of 25.3 μm × 17.6 μm is set. Using the image analysis software, the area of ​​the six measurement fields is determined to be 0.002 μm. ２ Based on all of the above tungsten carbide particles, the equivalent diameters D10 and D90 of the circles with equal area of ​​the tungsten carbide particles are measured. In the present disclosure, the D10 and D90 measured above correspond to the D10 and D90 of the tungsten carbide particles.

[0044] Although the threshold value setting for the binarization process can be manually adjusted, this measurement method does not employ manual adjustment. In this measurement method, as described above, binarization is performed by pressing the "Make Binary" button. ２ The reason for measuring the equivalent circle diameter of the tungsten carbide particles is that the inventors have measured the area of ​​0.002 μm ２ This is because it has been confirmed that particles smaller than this size are often noise that is mistakenly detected as tungsten carbide particles in image analysis.

[0045] As long as measurements are made on the same sample, it has been confirmed that there is almost no variation in the measurement results even if the above measurement is performed multiple times by changing the selected location of the measurement field.

[0046] <Second Hard Phase> <Composition> In the first embodiment, the second hard phase comprises at least one first compound selected from the group consisting of TaNbC, TaNbN, TaNbCN, TiCN, TiNbC, TiNbN, and TiNbCN. This improves the adhesion resistance, heat resistance, and wear resistance of the cemented carbide. In the present disclosure, the ratio of the total number of Ta, Nb, and Ti atoms to the total number of C and N atoms of each of TaNbC, TaNbN, TaNbCN, TiCN, TiNbC, TiNbN, and TiNbCN is not limited to 1:1, and may include any conventionally known ratio as long as it does not impair the effects of the present disclosure.

[0047] The second hard phase may be made of one first compound selected from the group consisting of TaNbC, TaNbCN, TiCN, and TiNbCN.

[0048] The second hard phase may contain metal elements such as tungsten (W), chromium (Cr), and cobalt (Co) within a range that does not impair the effects of the present disclosure. The total content of W, Cr, and Co in the second hard phase may be 0 mass% or more and less than 0.1 mass%. The contents of W, Cr, and Co in the second hard phase are measured by ICP optical emission spectrometry.

[0049] The method for measuring the composition of the second hard phase is as follows: (A3) An arbitrary position of the cemented carbide is thinned using an ion slicer (apparatus: IB09060CIS (trademark) manufactured by JEOL Ltd.) to prepare a sample with a thickness of 30 to 100 nm. The acceleration voltage of the ion slicer is 6 kV for thinning and 2 kV for finish processing.

[0050] (B3) The sample is observed at 50,000x magnification using a scanning transmission electron microscope (STEM) (JFM-ARM300F (trademark) manufactured by JEOL Ltd.) to obtain a STEM-HAADF (HAADF: high-angle annular dark field) image. The imaging area for the STEM-HAADF image is set to the center of the sample, i.e., a position that does not include areas with properties clearly different from the bulk portion, such as near the surface of the cemented carbide (a position where the imaging area is entirely the bulk portion of the cemented carbide). The measurement condition is an acceleration voltage of 200 kV.

[0051] (C3) Next, elemental mapping analysis is performed on the STEM-HAADF image using EDX attached to the STEM to obtain an elemental mapping image. In the elemental mapping image, regions where tantalum (Ta) or titanium (Ti) and one or both of carbon (C) and nitrogen (N) exist are identified as the second hard phase, and the composition of the second hard phase is identified.

[0052] As long as measurements are made on the same sample, it has been confirmed that there is almost no variation in the measurement results even if the above measurement is performed multiple times by changing the selected location of the measurement field.

[0053] <Circularity and standard deviation of circularity of second hard phase> The cemented carbide of embodiment 1 includes a plurality of second hard phases. Each second hard phase is composed of one first compound particle or an aggregate of a plurality of first compound particles. When the second hard phase is composed of an aggregate of a plurality of first compound particles, the plurality of first compound particles may be composed of one type of first compound particle or two or more types of first compound particles.

[0054] In the cross section of the cemented carbide of embodiment 1, the average circularity of the second hard phase is 0.10 to 0.32, and the standard deviation of the circularity is 0.094 to 0.130. The average circularity of the second hard phase may be 0.15 to 0.31, or 0.17 to 0.30. The standard deviation of the circularity may be 0.100 to 0.127, or 0.110 to 0.124.

[0055] In the present disclosure, the average circularity of the second hard phase means the arithmetic average of the circularities of a plurality of second hard phases in the cross section of the cemented carbide. In the present disclosure, the circularity is the value obtained by dividing the circle-equivalent perimeter of the second hard phase in the cross section of the cemented carbide by the actual perimeter (actual perimeter) (circle-equivalent perimeter / actual perimeter). A smaller value of the circularity indicates that the shape of the second hard phase in the cross section of the cemented carbide is more different from a perfect circle.

[0056] In the present disclosure, the method for measuring the average circularity and standard deviation of the circularity of the second hard phase in the cross section of a cemented carbide is as follows: (A4) An arbitrary position of the cemented carbide is cut out to expose the cross section. The cross section is polished using a cross-section polisher. The polished surface of the cemented carbide is photographed using an SEM to obtain a backscattered electron image. The observation conditions are a magnification of 1000x and an accelerating voltage of 10 kV.

[0057] (B4) The photographed region of (A4) above is subjected to elemental analysis using an energy dispersive X-ray analyzer (SEM-EDX) attached to an SEM to obtain an element mapping image. By superimposing the backscattered electron image and the element mapping image, the second hard phase is identified on the backscattered electron image.

[0058] (C4) The backscattered electron image in which the second hard phase is identified is imported into a computer using image analysis software (Mountech Co., Ltd.'s "Mac-View Version.5" (trademark)), and the circularity of each second hard phase is measured under the following conditions: Acquisition mode: color difference Detection tolerance: 32, detection accuracy: 0.5 Scanning: density 10 x 1 time High cut: enabled

[110] Low cut: inverted

[150]

[0059] (D4) Identify three visual fields in which 30 or more second hard phases can be confirmed. Measure the average circularity and standard deviation of the circularity of the second hard phases based on all the second hard phases in the three visual fields. In the present disclosure, the average circularity and standard deviation of the circularity of the second hard phases measured above correspond to the average circularity and standard deviation of the circularity of the second hard phases in the cross section of the cemented carbide.

[0060] As long as measurements are made on the same sample, it has been confirmed that there is almost no variation in the measurement results even if the above measurement is performed multiple times by changing the selected location of the measurement field.

[0061] <Binder Phase> <Composition> In the cemented carbide of embodiment 1, the binder phase contains 50 mass% or more of cobalt. This allows the cemented carbide to have excellent toughness. The cobalt content of the binder phase may be 50 mass% or more and 100 mass% or less, 60 mass% or more and 90 mass% or less, or 70 mass% or more and 80 mass% or less.

[0062] The method for measuring the cobalt content of the binder phase is as follows. The region where the binder phase exists is identified in the element mapping image using the same methods as (A1) to (E1) of the method for measuring the content of the first hard phase, etc., of the cemented carbide described above. One rectangular measurement field of view of 24.9 μm × 18.8 μm is set in the element mapping image. The cobalt content is measured in the region where the binder phase exists in the measurement field of view. In the present disclosure, the average of the cobalt contents in the region where the binder phase exists in the six measurement fields of view corresponds to the cobalt content of the binder phase.

[0063] As long as measurements are made on the same sample, it has been confirmed that there is almost no variation in the measurement results even if the above measurement is performed multiple times by changing the selected location of the measurement field.

[0064] The binder phase may contain iron (Fe), nickel (Ni), etc., as long as the effects of the present disclosure are not impaired. The binder phase may contain cobalt and one or both of nickel and iron. The binder phase may consist of cobalt and one or both of nickel and iron.

[0065] <Chromium> The cemented carbide of embodiment 1 may contain 0.08% by mass or more and 0.5% by mass or less of chromium. The chromium content of the cemented carbide may be 0.10% by mass or more and 0.48% by mass or less, or 0.12% by mass or more and 0.46% by mass or less. The chromium content of the cemented carbide is measured by ICP atomic emission spectrometry.

[0066] <Manufacturing Method> The cemented carbide of the first embodiment can be manufactured through, for example, a preparation step, a mixing step, a molding step, a sintering step, and a cooling step.

[0067] <Preparation Step> In the preparation step, raw material powders are prepared. The raw material powders include WC powder, TaNbC powder, TaNbN powder, TaNbCN powder, TiCN powder, TiNbC powder, TiNbN powder, TiNbCN powder, NbC powder, Ta ２ O ５ Powder, TiO ２ Examples of the raw material powder include Co powder, Ni powder, and Fe powder. These raw material powders are appropriately selected based on the target composition of the cemented carbide. Chromium carbide (Cr ３ C ２ ) powder may be prepared.

[0068] The average particle size of the tungsten carbide (WC) powder is 1.0 μm or more and 1.8 μm or less.

[0069] TaNbC powder, TaNbN powder, TaNbCN powder, TiCN powder, TiNbC powder, TiNbN powder, TiNbCN powder, NbC powder, Ta ２ O ５ powder and TiO ２The powder has an average particle size of 1 μm to 2 μm, and is the raw material powder for the second hard phase.

[0070] The average particle size of the Co powder, Ni powder, and Fe powder may be 0.1 μm or more and 5 μm or less.

[0071] The average particle size of the raw material powder is determined by the Fischer method.

[0072] <Mixing step> In the mixing step, raw material powders are mixed in a predetermined ratio to obtain a mixed powder. The mixing ratio of each raw material powder is adjusted appropriately depending on the target cemented carbide composition. A bead mill is used for mixing. The mixing conditions are a bead diameter of 1 mm, a rotation speed of 2800 rpm, and a mixing time of 6 to 24 hours.

[0073] <Molding Step> In the molding step, the mixed powder is molded into a desired shape to obtain a molded body. The molding method and molding conditions are not particularly limited and may be any commonly used method and conditions.

[0074] <Sintering step> In the sintering step, the compact is first heated to 1450 to 1520°C and held for 120 minutes. The temperature rise rate at 1000°C or higher is 5°C / min. The pressure here may be vacuum or N ２ The mixture may be cooled to 1200°C at a temperature decreasing rate of -4.5 to -5.5°C / min to obtain a cemented carbide intermediate.

[0075] Next, the cemented carbide intermediate is subjected to HIP (Hot Isostatic Pressing). Specifically, the cemented carbide intermediate is subjected to a temperature of 1320°C and a pressure of 10 MPa for 60 minutes using Ar gas as a pressure medium. The cemented carbide intermediate is then slowly cooled to obtain the cemented carbide of embodiment 1. The temperature drop rate during slow cooling may be any general condition and is not particularly limited.

[0076] <Features of the Manufacturing Method of the Cemented Carbide of Embodiment 1> In the manufacturing method of the cemented carbide of Embodiment 1, by adopting the above-described mixing conditions, the raw material powder is easily crushed and sheared. Furthermore, the heating rate at 1000°C or higher is controlled to 5°C / min, the sintering temperature is set to 1450 to 1520°C, which is higher than a typical sintering temperature, and the heating rate is controlled to -4.5 to -5.5°C / min. Under these conditions, the shape of the second hard phase is more likely to deviate from a true sphere, and the cemented carbide of Embodiment 1 can be manufactured in which the average circularity of the second hard phase in the cross section of the cemented carbide is 0.10 to 0.32, and the standard deviation of the circularity is 0.094 to 0.130. This was discovered by the inventors as a result of extensive research.

[0077] [Embodiment 2: Cutting Tool] A cutting tool according to one embodiment of the present disclosure (hereinafter also referred to as "Embodiment 2") is a cutting tool comprising the cemented carbide of Embodiment 1. In the cutting tool of Embodiment 2, the cemented carbide of Embodiment 1 may constitute the entire tool or a part of the tool. Examples of cutting tools in which the cemented carbide of Embodiment 1 constitutes a part of the cutting tool include a cutting tool comprising an arbitrary substrate and a cutting edge member made of the cemented carbide of Embodiment 1 fixed to the substrate, and a cutting tool comprising a substrate made of the cemented carbide of Embodiment 1 and an arbitrary cutting edge member fixed to the substrate.

[0078] The cutting tool of the second embodiment can have a long tool life even when machining aluminum. The reason for this is not clear, but is presumed to be as follows.

[0079] When machining aluminum with a cutting tool made of a conventional cemented carbide containing a second hard phase, the tool damage caused by welding increases, cutting resistance increases, and the tool life tends to decrease. In the cemented carbide of embodiment 1, the adhesion between the first hard phase, the second hard phase, and the binder phase is improved. Therefore, the cutting tool of embodiment 2, which includes the cemented carbide of embodiment 1 as its material, can suppress the expansion of tool damage caused by welding even when machining aluminum, and can have a long tool life.

[0080] The type of cutting tool is not particularly limited. Examples of cutting tools include cutting tools, drills, end mills, indexable cutting inserts for milling, indexable cutting inserts for turning, metal saws, gear cutting tools, reamers, taps, etc. As shown in Figure 3, the cutting tool 10 of embodiment 2 can exhibit excellent effects, particularly in the case of end mills. The substrate 5 of the cutting tool 10 shown in Figure 2 is made of the cemented carbide of embodiment 1.

[0081] As shown in Figure 2, the cutting tool of the second embodiment may include a substrate 5 made of the cemented carbide of the first embodiment and a coating 6 provided on the substrate 5. The coating may be disposed so as to cover the entire surface of the substrate, or may be disposed so as to cover only a portion of the surface. When the coating is disposed so as to cover only a portion of the substrate, it may be disposed so as to cover the surface of at least a portion of the substrate that is involved in cutting. In the present disclosure, the portion of the substrate that is involved in cutting refers to a region of the substrate that is within 0.5 mm of the cutting edge.

[0082] The composition of the coating may be a compound consisting of one or more elements selected from the group consisting of metal elements of Groups 4, 5, and 6 of the periodic table, aluminum (Al), and silicon (Si), and one or more elements selected from the group consisting of carbon, nitrogen, oxygen, and boron. For example, TiCN, Al ２ O ３ , TiAlN, TiN, TiC, AlCrN, etc. The coating may also have a composition of cubic boron nitride (cBN), diamond-like carbon, or diamond. Diamond may be either single crystal diamond or polycrystalline diamond.

[0083] The coating may be a single layer or a multilayer, and the thickness of the coating may be 0.1 μm or more and 20 μm or less, or 0.5 μm or more and 15 μm or less.

[0084] The coating can be formed on the substrate by a vapor phase method such as chemical vapor deposition (CVD) or physical vapor deposition (PVD).

[0085] When the coating is formed by a CVD method, it is easy to obtain a coating that has excellent adhesion to the substrate. Examples of CVD methods include hot filament CVD. When the coating is formed by a PVD method, compressive residual stress is imparted to the coating, which makes it easy to increase its toughness.

[0086] The cutting tool of embodiment 2 may include a substrate made of the cemented carbide of embodiment 1 and a cutting edge member fixed to the substrate. The cutting edge member may be made of cubic boron nitride sintered body or diamond. The diamond may be a single crystal diamond or a polycrystalline diamond.

[0087] [Supplementary Note 1] A cutting tool according to the present disclosure includes a substrate made of the cemented carbide of embodiment 1 and a coating provided on the substrate, wherein the coating is made of diamond-like carbon.

[0088] The present embodiment will be described in more detail with reference to examples, although the present embodiment is not limited to these examples.

[0089] [Preparation of cemented carbide] The cemented carbide samples were prepared by the following procedure. <Preparation step> As raw material powders, WC powder, TaNbC powder (average particle size: 1 μm), TiCN powder (average particle size: 1 μm), NbC powder (average particle size: 1 μm), Ta ２ O ５ Powder (average particle size: 1 μm), TiO ２ Powder (average particle size: 1 μm), Cr ３ C ２ Powder (average particle size: 1 μm), Co powder (average particle size: 1 μm), Ni powder (average particle size: 1 μm), and Fe powder (average particle size: 1 μm) were prepared. WC powders were WC08 (average particle size: 0.8 μm), WC12 (average particle size: 1.2 μm), WC15 (average particle size: 1.5 μm), WC20 (average particle size: 2.0 μm), and WC06LV (average particle size: 0.6 μm) manufactured by A.L.M.T.C. Corporation, and were prepared so that the average particle sizes were as shown in parentheses. TaNbC powder was "TaNbC 67 / 33" manufactured by H.C. Starck, and was prepared so that the average particle size was 1 μm.

[0090] <Mixing step> The raw material powders were mixed in a bead mill or attritor in the proportions shown in Table 1 to obtain mixed powders. The mixing conditions for the "bead mill" were a bead diameter of 1 mm, a rotation speed of 2800 rpm, and a mixing time of 6 hours. The mixing conditions for the "attritor" were a rotation speed of 250 rpm, and a mixing time of 1 hour.

[0091]

[0092] <Molding Step> The mixed powder was pressed to obtain a round bar-shaped molded body.

[0093] <Sintering step> The compact was heated to the temperature shown in the "Holding" column of "Sintering" in Table 2, and held at that temperature for the time shown in the "Holding" column. The heating rate above 1000°C was as shown in the "Heating rate above 1000°C" column. The pressure during holding was vacuum (vac) or N ２ Under the conditions (flow rate 2 L / min, partial pressure 5 kPa, "N ２ (2L-5kPa)).

[0094] Next, the temperature was decreased to 1200°C at the temperature decreasing rate shown in the "Temperature decreasing rate" column of Table 2, to obtain a cemented carbide intermediate.

[0095] Next, the cemented carbide intermediate was subjected to HIP treatment. Specifically, the cemented carbide intermediate was subjected to a temperature of 1320°C and a pressure of 10 MPa for 60 minutes using Ar gas as a pressure medium. After that, the cemented carbide intermediate was slowly cooled to obtain each sample of cemented carbide.

[0096]

[0097] [Evaluation of Cemented Carbide] <Content of Second Hard Phase and Content of Binder Phase in Cemented Carbide> The content of the second hard phase and the content of the binder phase in the cemented carbide of each sample were measured. The specific measurement method is as described in Embodiment 1. The results are shown in the "Content" column of "Second Hard Phase" and the "Content" column of "Binder Phase" of "Cemented Carbide" in Table 3. In all samples, the components other than the second hard phase and binder phase were the first hard phase.

[0098] <D10 and D90 of particle diameters of tungsten carbide particles> For each sample of cemented carbide, the particle diameters D10 and D90 of the tungsten carbide particles were measured. The specific measurement method is as described in embodiment 1. The results are shown in the "D10" and "D90" columns of "First hard phase" under "Cemented carbide" in Table 3.

[0099] <Composition of second hard phase> The composition of the second hard phase was measured in each cemented carbide sample. The specific measurement method is as described in embodiment 1. The results are shown in the "Composition" column of "Second hard phase" in "Cemented carbide" in Table 3.

[0100] <Average circularity and standard deviation of circularity of second hard phase> In the cross section of the cemented carbide of each sample, the average circularity of the area of ​​the second hard phase and the standard deviation of the circularity of the second hard phase were measured. The specific measurement method is as described in embodiment 1. The results are shown in the "average" and "standard deviation" columns of "circularity" of "second hard phase" of "cemented carbide" in Table 3.

[0101] <Composition of binder phase> The composition of the binder phase and the cobalt content of the binder phase were measured for each cemented carbide sample. The specific measurement method is as described in embodiment 1. The results are shown in the "Composition" and "Co content" columns of "Binder phase" of "Cemented carbide" in Table 3.

[0102] <Chromium Content of Cemented Carbide> The chromium content of the cemented carbide of each sample was measured. The specific measurement method is as described in embodiment 1. The results are shown in the "Cr Content" column of "Cemented Carbide" in Table 3.

[0103]

[0104] [Preparation of Cutting Tool] A round bar made of cemented carbide for each sample was machined to prepare a substrate having an end mill shape (model number: ASM4100DL).

[0105] For samples with "DLC" in the "Type" column of "Coating" in Table 2, a diamond-like carbon coating was formed on a substrate by PVD. The specific coating method is as follows: The substrate was attached to a substrate holder in a coating apparatus. While argon gas was introduced into the coating apparatus at a flow rate of 5 cc / min, a triangular prism-shaped target made of sintered graphite ("IG-510" manufactured by Toyo Tanso Co., Ltd.) was evaporated and ionized by vacuum arc discharge (cathode current 120 A). A voltage of -100 V was applied to the substrate holder by a bias power supply, forming a 0.5 μm-thick diamond-like carbon coating on the substrate, thereby obtaining a cutting tool. The substrate heater was set to a temperature of 150°C at the start of coating, and the substrate heater was alternately turned on and off every 30 minutes during coating.

[0106] For the samples with "Diamond" in the "Type" column of "Coating" in Table 2, a polycrystalline diamond coating of 8 μm in thickness was formed on the substrate by the hot filament CVD method to obtain the cutting tool (end mill) of each sample. The film formation conditions in the hot filament CVD method were 700°C, 500 Pa, the gas used and its flow rate ratio H ２ / CH ４ = 100 / 1.

[0107] The end mills of each sample were used to machine the side surface of aluminum (ADC12). The machining conditions were a cutting speed Vc of 400 m / min, a table feed F of 6000 mm / min, a cutting depth (axial direction) ap of 10 mm, a cutting depth (radial direction) ae of 2 mm, and dry machining. The amount of wear was measured after 40 m of machining. The smaller the amount of wear, the longer the tool life is judged to be. The results are shown in the "Wear Amount" column of the "Cutting Test" in Table 3. "Chipping Occurred" in this column indicates that chipping occurred in the cutting tool before 40 m of machining, and machining was discontinued.

[0108] [Discussion] The cemented carbide alloys and cutting tools of Samples 1 to 20 correspond to Examples. The cemented carbide alloys and cutting tools of Samples 21 to 31 correspond to Comparative Examples. It was confirmed that the cutting tools of the Examples had a longer tool life than the cutting tools of the Comparative Examples. It was confirmed that the cutting tools of the Examples were capable of stable machining for long periods of time when used to machine aluminum. It is presumed that the cemented carbide alloy used as the material for the cutting tools of the Examples had improved adhesion between the first hard phase, second hard phase, and binder phase, and therefore, the expansion of tool damage caused by welding was suppressed even when machining aluminum.

[0109] Although the embodiments and examples of the present disclosure have been described above, it is intended from the beginning that the configurations of the above-described embodiments and examples may be appropriately combined or modified in various ways. The embodiments and examples disclosed herein are illustrative in all respects and should not be considered limiting. The scope of the present invention is defined by the claims, not by the above-described embodiments and examples, and is intended to include meanings equivalent to the claims and all modifications within the scope of the claims.

[0110] Reference Signs List 1 first hard phase, 2 second hard phase, 3 binder phase, 4 cemented carbide, 5 base material, 6 coating, 10 cutting tool.

Claims

1. A cemented carbide alloy comprising a first hard phase, a plurality of second hard phases, and a binder phase, wherein the first hard phase comprises a plurality of tungsten carbide particles, wherein the tungsten carbide particles have a particle size D10 of 0.40 μm or more and a particle size D90 of 2.00 μm or less, the second hard phase comprises at least one first compound selected from the group consisting of TaNbC, TaNbN, TaNbCN, TiCN, TiNbC, TiNbN, and TiNbCN, the cemented carbide contains the second hard phase in an amount of 0.30 volume % or more and 1.60 volume % or less, the average circularity of the second hard phase in a cross section of the cemented carbide is 0.10 or more and 0.32 or less, and the standard deviation of the circularity is 0.094 or more and 0.130 or less, The binder phase contains 50 mass % or more of cobalt, and the cemented carbide contains 8.0 volume % or more and 12.0 volume % or less of the binder phase.

2. The cemented carbide according to claim 1, wherein the cemented carbide contains 0.08% by mass or more and 0.5% by mass or less of chromium.

3. A cemented carbide according to claim 1 or claim 2, wherein the binder phase contains one or both of iron and nickel.

4. A cutting tool comprising the cemented carbide according to any one of claims 1 to 3.

5. The cutting tool according to claim 4, comprising a substrate made of the cemented carbide and a coating provided on the substrate.

6. A cutting tool according to claim 4, comprising a substrate made of the cemented carbide and a cutting edge member fixed to the substrate.

7. The cutting tool according to claim 6, wherein the cutting edge member is made of cubic boron nitride sintered body or diamond.

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