The invention discloses a production process of a luminous ceramic product, which belongs to the field of production processes of ceramic materials, and particularly relates to a production process of a luminous ceramic product. A manufacturing process comprises the steps of manufacturing a luminous glaze material, printing, burning, reshaping and the like. The luminous ceramic product disclosed by the invention is a high-technology environment-friendly product, has unique decorating and warning functions, can be widely applied to warning sign systems and emergency evacuation systems of various public utilities, and can be specifically applied to places such as stairs, passages, wall sides, door number plates, floors, decks, lifeboats, buoyant apparatuses, firefighting devices and the like. The luminous ceramic product has the advantages of super-long afterglow, high weather resistance, no influence of weather on the luminous time, acid resistance, alkali resistance, and no change in 100 years.