Method for solidifying arsenic by using copper slag

By adding arsenic-containing substances and sulfuric acid solution to copper slag, insoluble compounds are formed to solidify arsenic, solving the stability and economic problems of arsenic solidification in existing technologies, and realizing the resource utilization of copper slag and the stabilization of arsenic.

CN122076792APending Publication Date: 2026-05-26KUNMING UNIV OF SCI & TECH
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Patent Information

Application Number
CN202610291196.7
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2026-03-11
Publication Date
2026-05-26

AI Technical Summary

Technical Problem

Existing technologies for arsenic fixation suffer from low long-term stability, poor environmental adaptability, and poor economic efficiency. Furthermore, they are difficult to stabilize arsenic and utilize the products for resource recovery. Traditional cement-based solidified bodies are easily damaged, and the arsenic fixation efficiency of new iron-based materials fluctuates significantly with pH, ​​resulting in high costs and making large-scale promotion difficult.

Method used

Arsenic-containing substances are added to copper slag along with a sulfuric acid solution with a mass concentration of 10-25%. After stirring evenly, the mixture is cast into a mold. The reaction of Fe2+ and Fe3+ with arsenate ions forms an insoluble compound, which solidifies arsenic in the crystal lattice. The strength is generated by the chemical combination reaction between copper slag and sulfuric acid.

Benefits of technology

It achieves low-cost arsenic curing, and the material has rapid solidification, good stability and durability, realizes the comprehensive utilization of waste residue, and can effectively reduce the toxic leaching of arsenic.

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Abstract

The invention discloses a method for solidifying arsenic by using copper slag, which comprises the following steps: adding an arsenic-containing substance into the copper slag, uniformly mixing, adding a sulfuric acid solution with the mass concentration of 10-25%, uniformly stirring at normal temperature, molding, demolding, and curing to achieve the purpose of solidifying arsenic. According to the invention, the copper slag and the sulfuric acid solution are subjected to chemical bonding reaction to harden the material, so that strength is generated, the material is used as a pouring material, and the material has the characteristics of short setting time, good stability, good durability and the like, also has good cohesiveness, and realizes comprehensive utilization of industrial waste residues.
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