All-solid-state lithium battery interface buffer layer, preparation method and all-solid-state lithium battery

By setting up the interface buffer layer of lithium ion sieve adsorbent and polyethylene oxide in an all-solid-state lithium battery, the problem of solid electrolyte incompatible with the electrode is solved, the interface impedance is reduced, the battery's safety and cycle stability is improved, and the all-solid-state lithium battery can work normally at room temperature and exhibit high capacity and stable cycle performance.

CN114843614BActive Publication Date: 2025-03-18SHANGHAI INST OF SPACE POWER SOURCES
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Patent Information

Application Number
CN202210471971.9
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2022-04-29
Publication Date
2025-03-18
Estimated Expiration
2042-04-29

AI Technical Summary

Technical Problem

The solid electrolytes in existing all-solid-state lithium batteries are incompatible with the electrodes, resulting in large interface contact resistance, uneven current distribution and lithium dendrites.

Method used

An interface buffer layer is provided between the solid electrolyte and the electrode sheet of the all-solid lithium battery, including lithium ion sieve adsorbent and polyethylene oxide. The interface buffer layer is formed by H+/Li+ exchange reaction and hydrogen bonding of polyethylene oxide, reducing the interface impedance and improving the lithium ion transport capability.

Benefits of technology

By setting the interface buffer layer, the interface impedance is reduced, lithium dendrites are avoided, and the battery's safety and cycle stability are improved, so that all-solid-state lithium batteries can work normally at room temperature and show high capacity and stable cycle performance.

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Abstract

The present invention discloses an interface buffer layer of an all-solid-state lithium battery, a preparation method thereof and an all-solid-state lithium battery, wherein the interface buffer layer comprises a lithium ion sieve adsorbent and polyethylene oxide; the interface buffer layer is arranged between a solid electrolyte and a pole piece of the all-solid-state lithium battery. + / Li + The exchange reaction is carried out at a slower rate. After the exchange reaction occurs, H + It forms a bond with the polyethylene oxide in the buffer layer without causing any side reactions, thus ensuring the safety of the battery.
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