Microcapsule structure agricultural chemical based on protein amyloid aggregate

Abstract

The invention discloses a microcapsule structure agricultural chemical based on protein amyloid aggregate. The microcapsule structure agricultural chemical comprises an agricultural chemical, protein, a denaturing agent, plant essential oil, an emulsifier, a pH regulator and water. According to the invention, the denaturing agent is used for inducing protein to form amphiphilic protein amyloid aggregate, and the emulsifier is used for promoting the dissolution of the plant essential oil in water, so that the agricultural chemicals can be dissolved in the plant essential oil; the protein amyloid aggregate is aggregated and assembled on the surface of the plant essential oil through various non-covalent acting forces to form a stable agricultural chemical with a microcapsule structure, and the spreading, permeation and conduction of the agricultural chemical on plant leaves can be enhanced by spraying the agricultural chemical on the plant leaves; meanwhile, the protein amyloid aggregate gathers on the surface of the plant essential oil to form a film, so that the agricultural chemicals are stably adhered to the surface of the plant, the plant is resistant to rain wash, the utilization rate of the agricultural chemicals is increased, the environmental pollution is reduced, and the plant essential oil has a wide application prospect in agricultural production.

Description

Technical Field

[0001] The invention belongs to the technical field of new biological materials and microcapsule preparation, and in particular relates to a microcapsule structured agricultural chemical based on protein-based amyloid aggregates. Background Art

[0002] With the advancement of agricultural science and technology, the research and development of pesticide adjuvants has gradually become an important area for improving agricultural production efficiency and sustainability. In this regard, high-permeability pesticide adjuvants and pesticide adjuvants that can conduct against gravity are two innovative adjuvants with significant potential. Although traditional high-permeability pesticide adjuvants have advantages in improving the permeability of pesticides, they also have some defects. First, some high-permeability adjuvants will have rebound and droplet splashing problems when sprayed on plant leaves, which increases the complexity and uncertainty of their use. Secondly, excessive use of these adjuvants may cause the accumulation of agents in plants, posing potential risks to the environment and non-target organisms. At the same time, the production and application of such adjuvants usually require higher technical levels and equipment support, resulting in higher costs, which limits their application in some small-scale or economically poor agricultural production.

[0003] CN111802385A discloses a protein product that can fix a target object and remove it as needed. The protein product is prepared by using a protein, a modifier, and a target fixation agent to effectively increase the amount of pesticides and fertilizers fixed on the surface of plant leaves. However, the product has poor spreading, permeability, and conductivity on the fixed surface, and cannot dissolve non-water-soluble pesticide original drugs, resulting in limited application scenarios. Summary of the invention

[0004] In response to the problem that the above-mentioned protein products have poor permeability, adhesion and conductivity when interacting with fixed surfaces, the present invention provides a microcapsule structured agricultural chemical based on protein amyloid aggregates. The product has high permeability, high adhesion and high conductivity, and can exist stably under high temperature conditions. After spraying, it quickly adheres to the plant surface, thereby improving the utilization rate of pesticides and reducing environmental pollution.

[0005] The microcapsule structured agricultural chemicals based on protein amyloid aggregates provided by the present invention are made of the following raw materials in the following weight proportions:

[0006] Protein 0.05~50 parts

[0007]

[0008] Furthermore, it is preferred that the above-mentioned microcapsule structured agricultural chemicals based on protein amyloid aggregates are made of the following raw materials in the following weight proportions:

[0009]

[0010] Furthermore, it is more preferred that the above-mentioned microcapsule structured agricultural chemicals based on protein amyloid aggregates are made of the following raw materials in the following weight proportions:

[0011]

[0012] The above-mentioned protein is selected from animal-derived protein or plant-derived protein.

[0013] Furthermore, the animal-derived protein is at least one of the proteins contained in the following animals:

[0014] (1) Arthropoda, class Insecta, order Coleoptera: Pederidae, Coleoptera, Scarabaeoidea, Cerambycidae, Chrysomeliformes, Curculionoidea, Dermatophytidae, Cynomoroidea, Hydrocharoidea, Mud Beetles, Cerambycidae, Tiger Beetles, Curculionidae, Coccinellidae, Lampyridae, Cloth Beetles, Cryptolabridae, Thick-horned Coleoptera, and Ground Coleoptera;

[0015] (2) Arthropoda, Insecta, Hymenoptera: Ichneumonidae, Braconidae, Mylidae, Gall-bee Bees, Sphecidae, Vespidae, Formicidae, Apidae, Tenebrioidae, Sawfly, Woodfly, Parasitic Woodfly, Chrysopidae, Enameled Mylidae, Trichogrammatidae, Mylidae, Mylidae, Hammer-horned Mylidae, Marginal Mylidae, and Broad-bellied Mylidae;

[0016] (3) Arthropoda, Insecta, Lepidoptera: Microptera, Acanthidae, Xylotomidae, Superfamily Lycopodia, Rapeworms, Carpiomorpha, Limulidae, Torcula, Sciaenidae, Schizomysidae, Schizomysidae, Gnaphal ...;

[0017] (4) Arthropoda, Crustacea, Macacaridae: Phylum Arthropodidae, Macrophyllidae, Pseudophyllidae, Deep-sea Shrimp, Indian Shrimp, Broad Shrimp, Semi-toed Shrimp, Big-toed Shrimp, Toothed Shrimp, Proto-toed Shrimp, Pseudo-shrimp, Trogidae, Red Shrimp, Crown Shrimp, Lycopodidae, Microshrimp, Square Shrimp, Shrimp, Broad Shrimp, Parashrimp;

[0018] (5) Arthropoda, class Arachnida, order Araneae: Araneidae, Theridiidae, Theridiidae, Lycosauridae, Salticidae, Scorpionidae, Ixodidae, Acaridae, Tickidae, Red Spiders, Theridiidae, Theridiidae, Ocellidae, Theridiidae, Theridiidae, Theridiidae, Theridiidae, Theridiidae, Theridiidae, Theridiidae;

[0019] (6) Arthropoda, Arachnida, Scorpionidae: Pseudo-marsh scorpionidae, Pincer scorpionidae, Microscorpionidae, Pig scorpionidae, Marsh scorpionidae, True scorpionidae, Superstitious mountain scorpionidae, Bliss scorpionidae, Hairy scorpionidae, Fearful scorpionidae, Trapped scorpionidae, Semiscorpionidae, Scorpionidae, Heteroscorpionidae, Diploscorpionidae, Thin scorpionidae;

[0020] (7) Phylum Mollusca, Class Gastropod, Order Cephalopoda: Pseudo-spined Snails, Pseudo-spined Sea Snails, Adidae, Sternidae, Semeno-spined Snails ...

[0021] (8) Phylum Mollusca, Class Gastropod, Order Aplysia: Cylindrica, Aplysia, Hylostomidae, Hylostomidae, Hylostomidae, Hylostomidae, Hylostomidae, Hylostomidae, Hylostomidae, Hylostomidae;

[0022] (9) Phylum Mollusca, Class Gastropod, Order Nudibranch: Trionychidae, Trionychidae, Trionychidae, Trionychidae, Trionychidae, Trionychidae, Trionychidae, Trionychidae, Trionychidae, Trionychidae;

[0023] (10) Phylum Mollusca, Class Cephalopoda, Order Sepiidae: Sepiidae, Subfamily Heteropodinae, Subfamily Sakinocephalae, Subfamily Otocephalae;

[0024] (11) Phylum Mollusca, Class Cephalopoda, Order Octopus: Octopidae, Giant Octopidae, Corydalis, Cuttlefish, Argonautidae, Heptapodidae, Deep-sea Octopus, Brachycopedidae;

[0025] (12) Chordata: Acipenseridae, Hypophthalmichthys, Hypophthalmichthys, Neophthalmichthys, Osteoglossidae, Anguilla, Anguidae, Acanthodontidae, Cypriniformes, Gnaphalinae, Salmoniformes, Salmoninae, Herpidae, Salmoniformes, Ophiodontidae ... , Siluriformes, Siluridae, Silversides, Gnathophoridae, Silversides, Gnathophoridae, Gnathophoridae, Gadformes, Gadidae, Ophiopods, Ophiopods, Chrysopidae, Ophiopods, Ophiopods, Ophiopods, Ophiopods, Sphenodontidae, Syngnathidae, Syngnathidae, Syngnathidae, Perciformes, Wrasseniidae, Perciformes, Rockfish, Perciformes, Pomacanthidae, Perciformes, Cichlidae;

[0026] (13) Chordata, Amphibia, Apodidae: Jellyfish, Anemone, Lumbricidae, Leechidae, Snakes, Sea Cucumbers, Asteridae, Echinoidea, Snails, Mussels, Clams, Calycozoa;

[0027] (14) Chordata, class Amphibia, order Caudata: Cryptobranchidae, Ambystoma, Eusalidae, Hypoderma, Pulmonary Salamanders, Amphibia, Caviidae, Costidae, Eudontidae, Fat Salamanders, Blind-eyed Lumbricidae, and Megalostomidae;

[0028] (15) Chordata, Amphibia, Anura: Toads, Rhacophoridae, Hylacidae, Ceratopogonidae, Mylodactylidae, Microdactylidae;

[0029] (16) Phylum Chordata: Reptiles: Squamata, Testudinidae, Dermatochelydae, Testudinidae, Cheloniformes, Testudinidae, Testudinidae, Crocodilia, Alligators, Alligators, Alligators;

[0030] (17) Chordata: Psittaciformes, Cockatielidae, Psittaciformes, Lorikeetidae, Anseriformes, Anatidae, Anseriformes, Anseriformes, Sphenisciformes, Passeriformes, Passeriformes, Corvidae, Passeriformes, and Passeriformes;

[0031] (18) Chordata: Monotremes: Platypus, Echidna, Perissodactyla, Rhinoceros, Proboscidea;

[0032] (19) Chordata, Mammalia, Marsupials: Marmosets, Koalas, Bandicoots, Wombats, and Quetzalcoatlus;

[0033] (20) Chordata, class Mammalia, order Rodentia: Sciuridae, Cricetidae, Bamboo Rhynchomys, Dormouse, Myrmecophaga, Caviidae, Beaver, Flying Squirrel, Porcupine, Lemming, Gerbil, Capybara;

[0034] (21) Chordata, Mammalia, Chiroptera: Pteropus, Rhinolophus, Hippodrome, Myotis, Long-winged Bat, Brachypterygidae, Fruit Bat;

[0035] (22) Chordata, Mammalia, Carnivora: Felidae, Canidae, Ursidae, Mustelidae, Lutradae;

[0036] (23) Chordata, Mammalia, Primates: Hominidae, Gibbon, Loris, Tarsier, Lemuridae;

[0037] (24) Chordata, Mammalia, Artiodactyla: Camelidae, Suidae, Peccary, Giraffidae, Pronghorn, Cervidae, Musk Deer, Bovidae, Hippopotamidae;

[0038] (25) Phylum Chordae, Class Mammalia, Order Cetacea: Dolphins, Sperm Whales, Beaked Whales, Narwhals, Sharp-nosed Dolphins, Delphinidae, Porpoises, Baleen Whales, Gray Whales, Right Whales, Minke Whales, Beaked Whales, and Fin Whales.

[0039] Furthermore, the plant-derived protein is at least one of the following animal proteins:

[0040] (1) Ceratophyllum: Ceratophyllums: Ceratophyllums, ...

[0041] (2) True Mosses: Axis order, Axis family, Axis order, Hoary moss family, Axis order, Micro-moss family, Corrugated moss order, Corrugated moss family, Beaded moss order, Beaded moss family, True moss order, True moss family, True moss order, Lantern moss family, Shrimp moss order, Shrimp moss family, Tobacco moss order, Tobacco moss family, Brachycera order, Brachycera family, Opposite leaf order, Opposite leaf order, Anti-neon moss family, Gourd moss order, Big cap moss family, Gourd moss order, Gourd moss family, Purple calyx order, Purple calyx order, Purple calyx order, Purple calyx order, Purple calyx order, Purple calyx order, Stone crack moss Mosses, the order of the purple-calyx mosses, the order of the tiger-tail mosses, the order of the yellow-yellow mosses, the order of the oily mosses, the order of the oily mosses, the order of the white mosses, the order of the oily mosses, the order of the velvet-cap mosses, the order of the tree-lime mosses, the order of the tree-lime mosses, the order of the tree-lime mosses, the order of the straight-toothed mosses, the order of the wood-ling mosses, the order of the wood-ling mosses, the order of the ridge-capped mosses, the order of the juniper mosses, the order of the juniper mosses, the order of the water-lichen mosses, the order of the twisted-stem mosses, the order of the water-lichen mosses, the order of the water-lichen mosses, the order of the cold-lichen mosses, the order of the water-lichen mosses, the order of the beautiful-lichen mosses;

[0042] (3) Eubryophyta, Eubryophyta, Angiospermaceae, Angiospermaceae, Angiospermaceae, Angiospermaceae, Angiospermaceae;

[0043] (4) True mosses: Onagraceae, Bolognaaceae, Reverse hair mossaceae, Green mossaceae, Wetland mossaceae, Wannian mossaceae, Cryptocapsulariaceae, Silk mossaceae, Brocteraceae, Sphagaceae, Soft tooth mossaceae, Tower mossaceae, Gray mossaceae, Peacock mossaceae, Boat leaf mossaceae, Thin Luo mossaceae, White tooth mossaceae, Crepe mossaceae, Tilapia mossaceae, Golden hair mossaceae, Flat mossaceae, Straight mossaceae, Cotton mossaceae, False fine Luo mossaceae, Axillary mossaceae, Pteridaceae, Golden gray mossaceae, Hairy brocade mossaceae, Heterodontaceae, Weeping mossaceae, Heliconia mossaceae, Brocade mossaceae, Pseudo-thin Luo mossaceae, Sclerophyllaceae, Acanthaceae, Lepiophyllaceae, Thick handle mossaceae;

[0044] (5) Eubryophytes, Eubryophytes, and Hypobryophytes: Phyllostachys, Candleleafys, Microhylophytes, Botrychnophytes, Arboretum, Hypobryophytes, Thick Lithophytes, Echinopsaceae, and Light Mosses;

[0045] (6) True mosses: Black mosses, Black mosses, Black mosses, Black mosses, True mosses: Long mosses, Long mosses, Long mosses, True mosses: Golden mosses, Golden mosses, Golden mosses, True mosses: Sphagnum mosses, Sphagnum mosses, True mosses: Sphagnum mosses, True mosses: Sphagnum mosses, True mosses: Algae mosses, Algae mosses, True mosses: Tetradentata mosses, Tetradentata mosses, Tetradentata mosses;

[0046] (7) Chlorophyta, Chlorophyta: Bryophyceae, ...

[0047] (8) Chlorophyta, Chlorophyta, Acrophyceae, Acrophyceae, Gymnophyceae, Gymnophyceae, Gymnophyceae, Gymnophyceae, Dauerlys ...

[0048] (9) Marchantia: Bracteaceae, Microphylla, Microphylla, Nanximeiaceae, Forkleaf, Forkleaf, Greenleaf, Bandleaf, Bandleaf, Mossleaf, Bandleaf, Purpleleaf, Purpleleaf, Light-calyx, Ear-leaf, Light-calyx, Hair-ear, Light-calyx, Fine-scale, Light-calyx, Eye-calyx, Light-calyx, Flat-calyx, Hair-leaf, Hair-leaf, New-leaf;

[0049] (10) Phyllophyllous order: Acrocalyceae, Cryptocapsulariaceae, Erectleafaceae, Leptocarpaceae, Pocillopora, Eyelashaceae, Capsulariaceae, Macrocalyceae, Pseudo-macrocalyceae, Geocalyceae, Holocyceae, Fusariumaceae, Shearleafaceae, Longicyceae, Armoraceae, Leafmoss, Complexaceae, Fingerleafmoss, Toothcalyceae, Splitleafmoss, Beardmoss, Microcalyceae, Pseudocalyceae, Feathermoss, Pseudo-complexaceae, Scutellariaceae, Synophyllaceae, Diplocoleaceae, Tubemoss, Horizontalleafmoss, Velvetmoss;

[0050] (11) Phylum Ranunculaceae, Class Ranunculales: Verruco-crown family, Star-hole family, Snake family, Flowery family, Liverwort family, Dioscorea family, Light family, Single-month family, Money family, Leather-leaf family, Wesley family;

[0051] (12) Rhodophyta: Acrophyceae, Acrophyceae, Ignaec ...

[0052] (13) Rhodophyta, Rhodophyta, and Taxodium: Stem-spined algae, Gelatophyceae, Endophyceae, Taxodium, Myxocystis, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae;

[0053] (14) Vascular plants, class Equisetum: Alsophilales, Cyathophytes, family Cyathophytes, family Cyathophytes, family Equisetaceae, family Diplophyllaceae, family Diplophyllaceae, family Diplophyllaceae, family Hymenopterales, family Hymenopterales, family Hymenopterales, family Hymenopteraceae, family Osmanthaceae, family Pinaceae, family Sophora, family Sophora, family Sophora, family Cyperaceae, family Cyperaceae;

[0054] (15) Vascular plants, class Equisetaceae, order Polypodiaceae: Aspleniaceae, Aspleniaceae, Pterid ...

[0055] (16) Vascular plants: Acorusales, Acorus family; Palmaceae; Schisandraceae; Boraginaceae; Buxusales, Buxus family; Celastraceae; Ceratophyllum family; Ceratophyllum family; Chrysanthemum family; Commelinaceae; Commelinaceae; Commelinaceae; Commelinaceae; Commelinaceae; Cornaceae; Cornaceae; Hydrangeaceae; Cornaceae; Cyanophyllum family; Tassel family; Tassel family; Pentacarpaceae; Cucurbitaceae; Cucurbitaceae; Begoniaceae; Cucurbitaceae; Moracaceae; Cucurbitaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; The order Acanthaceae, the order Leguminosae, the order Polygala, the order Merantiaceae, the order Psoralea, the order Psoralea, the order Eucommia, the order Geraniales, the order Decapoda, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Vitis, the order Vitis; the order Vitis;

[0056] (17) Vascular plants: Alismataceae, Araceae, Araceae, Asteraceae, Asteraceae, Asteraceae, Asteraceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae;

[0057] (18) Vascular plants, Magnoliaceae, Apiaceae, Araliaceae, Pittosporaceae, and Coleopsaceae;

[0058] (19) Vascular plants, Magnoliaceae, Aquilegiaceae: Aquilegiaceae, Aquilegiaceae, Aquilegiaceae;

[0059] (20) Vascular plants, Magnoliaceae, Asparagales: Asparagaceae, Amaryllidaceae, Asphodelaceae, Curculigoaceae, Iridaceae, Orchidaceae;

[0060] (21) Vascular plants: Magnoliaceae, Asterales, Asteraceae, Campanulaceae, Menymaceae, Pentaphyllum, Stylophyllum;

[0061] (22) Vascular plants, Magnoliaceae, Cruciferae: Cruciferae, Glechomaea, Carica, Caricaceae, Moringaceae, Meliaceae, Echinopsaceae, Nasturtiumaceae;

[0062] (23) Vascular plants: Caryophyllaceae, Aizoaceae, Amaranthaceae, Uncariaceae, Basella, Cactaceae, Droseraceae, Petalopsis, Pinaceae, Cornaceae, Nepenthesaceae, Mirabilis, Allium, Phytolaccae, Pleurotus, Polygonaceae, Portulaceae, Glechomae, Salicaceae;

[0063] (24) Vascular plants: Ericaceae, Actinidiaceae, Impatiens, Alnus, Ixigera, Diospyros, Ericaceae, Leydigaceae, Cyperaceae, Pentaphyllum, Allium, Primulaceae, Sapotaceae, Costaceae, Styracaceae, Asteraceae, Theaceae;

[0064] (25) Vascular plants, Magnoliaceae, Fagales: Fagaceae, Betulaceae, Casuarinaceae, Fagaceae, Juglandaceae, Myricaceae;

[0065] (26)) Vascular plants, Magnoliaceae, Gentianales: Gentianaceae, Apocynaceae, Gelsemium, Gentianaceae, Loganaceae, Rubiaceae;

[0066] (27) Vascular plants, Magnoliaceae, Labiatae: Lamiaceae, Acanthaceae, Bignoniaceae, Vanillaceae, Gesneriaceae, Utriculariaceae, Matricariaceae, Ceratoniaceae, Aquilegiaceae, Oleaceae, Orobanchaceae, Paulowniaceae, Sesamaceae, Penicillaceae, Plantaginaceae, Scrophulariaceae, Verbenaceae, and Aglaonema;

[0067] (28) Vascular plants, Magnoliaceae, Liliales: Liliaceae, Colchicumaceae, Hostaceae, Veratrum, Smilaxaceae;

[0068] (29) Vascular plants: Malpurinae, Echinopsaceae, Echinopsaceae, Anshenaceae, Garciniaceae, Pomacantha, Stellariaceae, Corydalis, Euphorbiaceae, Hypericaceae, Glutinaceae, Linaceae, Tropaeolaceae, Cyperaceae, Passifloraceae, Arboraceae, Phyllanthaceae, Carexaceae, Drupaceae, Rhizophoraceae, Salicaceae, Violaceae;

[0069] (30) Vascular plants, Magnoliaceae, Malvaceae: Malvaceae, Malvaceae, Helianthaceae, Dipterocarpaceae, Thymelaeaceae;

[0070] (31) Vascular plants, Magnoliaceae, Myrtales: Myrtaceae, Combretaceae, Cryptomeriaceae, Lythraceae, Melastomataceae, Onagraceae;

[0071] (32) Vascular plants, Magnoliaceae, Pandanales: Pandanaceae, Stemonaceae, Mycorrhizae, and Featherleafaceae;

[0072] (33) Vascular plants: Magnoliaceae, Poaceae, Bromeliaceae, Cyperaceae, Cyperaceae, Cyperaceae, Juncaceae, Sphagaceae, Juncaceae, Typhaceae, and Cyperaceae;

[0073] (34) Vascular plants, Magnoliaceae, Proteales: Proteaceae, Nelumboceae, Platanaceae, and Ceropegiaceae;

[0074] (35) Vascular plants, Magnoliaceae, Ranunculales: Ranunculaceae, Berberidaceae, Astrophyllaceae, Akebiaceae, Menispermaceae, Papaveraceae;

[0075] (36) Vascular plants: Magnoliaceae, Rosaceae, Elaeagnaceae, Moraceae, Rhamnaceae, Rosaceae, Ulmaceae, Urticaceae;

[0076] (37) Vascular plants: Magnoliaceae, Santalum orders: Santalaceae, Cyperaceae, Cyperaceae, Cyperaceae, Loranthaceae, Aspergillus family, Citronaceae, Santalaceae, Cyperaceae, and Malvaceae;

[0077] (38) Vascular plants, Magnoliaceae, Sapindaceae: Sapindaceae, Anacardiaceae, Botrytis cinerea, Oleaceae, Meliaceae, Nitraria tanguticaceae, Rutaceae, Simsinaceae;

[0078] (39) Vascular plants: Magnoliaceae, Saxifragales: Saxifragaceae, Mycorrhizaceae, Cynomorium, Sansevieriaceae, Ribesaceae, Echinochloa, Hamamelidaceae, Myristicaceae, Paeoniaceae, Psoralea, Saxifragaceae;

[0079] (40) Vascular plants, Magnoliaceae, Solanales: Solanaceae, Convolvulaceae, Acanthaceae, Sphenopalmataceae;

[0080] (41) Vascular plants, Magnoliaceae, Zingiberales: Zingiberaceae, Cannaceae, Zingiberaceae, Orchidaceae, Marantaceae, Musaceae, Strelitziaceae;

[0081] (42) Vascular plants: Araucariaces, Araucariaceae, Araucariaces, Podocarpaceae, Cupressaceae, Cupressaceae, Cupressaceae, Taxaceae, Cycadales, Cycadaceae, Ephedales, Ephedraceae, Ginkgoales, Ginkgoaceae, Gnetaceae, Pinaceae, Pinaceae, and Machilaceae.

[0082] Furthermore, the above-mentioned protein is preferably any one or more of lysozyme, bovine serum albumin, human serum albumin, lactoferrin, whey albumin, insulin, α-lactalbumin, fibrinogen, β-lactoglobulin, Aβ peptide, prion protein, α-synuclein, cystatin C, huntingtin protein, immunoglobulin, ribonuclease A, cytochrome c, α-amylase, horseradish peroxidase, pepsin, myoglobin, collagen, keratin, hemoglobin, DNA polymerase, casein, soy protein, pea protein, zein, gliadin, gluten, oat protein, potato protein, hemp seed protein, walnut protein, rapeseed protein, hazelnut protein, quinoa protein, sunflower seed protein, pumpkin seed protein, black sesame protein, mushroom protein, red algae protein, legumin, barley protein, wheat protein, millet protein, gluten, kidney bean protein, casein, collagen, catalase, etc.

[0083] Furthermore, the above-mentioned denaturant is a reducing agent or an oxidizing agent, and the reducing agent is selected from any one or more of dithiothreitol, β-mercaptoethanol, tris(2-carboxyethyl)phosphine hydrochloride, cysteine, vitamin C, sodium borohydride, aluminum borohydride, reduced glutathione, etc., and the oxidizing agent is selected from at least one of trivalent cobalt salts, chlorates, potassium permanganate, persulfate, potassium dichromate, concentrated sulfuric acid, hydrochloric acid, nitric acid, hydrobromic acid, hydroiodic acid, perchloric acid, ozone, hydrogen peroxide, fluorine gas, chlorine gas, sodium bismuthate, periodic acid, sodium ferrate, lead dioxide, guanidine hydrochloride, urea, trifluoroethanol, hexafluoroisopropanol, trifluoroacetic acid, etc.

[0084] Furthermore, the plant essential oil is selected from any one or more of the following:

[0085] (1) Citrus fragrance: orange oil, lemon oil, grapefruit oil, lime oil, tangerine oil, grapefruit oil, blood orange oil, bitter orange oil, perfume orange oil, bergamot oil, lemon balm oil, bergamot oil, Malaysian orange oil, oil orange oil, lime leaf oil, lemongrass oil, fragrant lime oil, lemon lavender oil, peach oil, green lemon oil, teak oil, orange mint oil, citrus essential oil, lemon balm oil, Indian orange oil, sweet orange oil, mint lemon oil, golden lemon oil, spicy orange oil, green orange oil, chili orange oil, sweet orange oil, spicy citrus oil, bitter lime oil, tangerine oil, white Grape oil, wood orange oil, sugar orange oil, kumquat oil, tangerine oil, platycodon oil, grass orange oil, sweet lemon oil, lime oil, wild citrus oil, yellow orange oil, fruity oil, fresh orange oil, sunshine orange oil, snow orange oil, silver orange oil, fragrant green oil, Indian lemon oil, fragrant oil, green grapefruit oil, orange fragrance oil, sweet lime oil, fragrant fruit oil, tangerine oil, bubble orange oil, fig oil, honey tangerine oil, fragrant red orange oil, fresh lemon oil, white lemon oil, fragrant amber oil, golden lemon oil, blood orange essential oil, bergamot fragrance oil, golden pumpkin oil, amber orange oil, litsea cubeba essential oil, grapefruit essential oil, bitter orange essential oil;

[0086] (2) Floral fragrance: rose oil, lavender oil, jasmine oil, orange blossom oil, lily of the valley oil, lily oil, chamomile oil, peony oil, lily of the valley oil, carnation oil, violet oil, perfume lily oil, lavender essential oil, sunflower oil, cauliflower oil, clove oil, grapefruit flower oil, begonia oil, lilac oil, honeysuckle oil, bee flower oil, flower and grass oil, calendula oil, gardenia oil, iris oil, lilac oil, rosewood oil, okra oil, evening primrose oil, red rose oil, snowflake oil, white rose oil, violet leaf oil, lotus oil, poppy oil, blue lily oil, camphor flower oil, flower and fruit oil, honeysuckle oil, podocarpus oil, red tulip oil, Sweet alyssum oil, purple-leaf plum oil, verbena oil, white tulip oil, aromatic alkali oil, fragrant dendrobium oil, yellow rose oil, nectar oil, lily of the valley oil, gardenia oil, red carnation oil, rosemary oil, fragrant clove oil, flower and grass oil, okra flower oil, acacia oil, white lily of the valley oil, wildflower oil, vanilla flower oil, daylily oil, apple flower oil, mint flower oil, azalea oil, autumn rhyme flower oil, anemone oil, rose oil, thistle oil, crabapple flower oil, purple golden shea oil, pearl flower oil, golden camellia oil, white flower oil, laurel oil, ylang-ylang essential oil, rose essential oil, thyme essential oil, geranium essential oil, Damascus rose essential oil, hawthorn essential oil;

[0087] (3) Herbal incense: thyme oil, sage oil, shallot oil, basil oil, coriander oil, parsley oil, marjoram oil, geranium oil, mint oil, green garlic oil, Brazilian mint oil, basil oil, herbal oil, olive oil, spice grass oil, fragrant marjoram oil, juniper oil, licorice oil, herbal oil, fragrant wind oil, white lily oil, white chrysanthemum oil, wolfberry oil, fennel oil, laurel oil, fennel oil, garlic oil, perilla oil, thyme oil, coriander essential oil, shallot oil, lily oil, apricot oil, vanilla oil, insect oil Grass oil, sage oil, artichoke oil, wintergreen oil, fine leaf sesame oil, wolfberry oil, pepper oil, sweet artemisia oil, cinnamon oil, asafoetida oil, chive essential oil, purple root oil, mint oil, wild onion oil, gentian oil, yam oil, wormwood oil, aromatherapy oil, thistle oil, mint essential oil, chive flower oil, oregano oil, perfume grass oil, garlic essential oil, white artemisia oil, camphor leaf oil, mushroom oil, purslane oil, vanilla essential oil, verbena essential oil, myrtle essential oil, sandalwood essential oil, cedar essential oil, myrrh essential oil, eucalyptus essential oil;

[0088] (4) Camphor incense: camphor oil, white camphor oil, black camphor oil, red camphor oil, camphor essential oil, camphor fragrant oil, camphor flower oil, camphor leaf oil, camphor ketone oil, camphor fragrant oil, camphor emulsifiable concentrate, camphor extract oil, camphor grass oil, camphor wood oil, camphor essential oil, camphor alcohol oil, camphor ether oil, camphor ester oil, camphor wood oil, camphor extract oil, camphor fat oil, camphor fruit oil, camphor tree oil, camphor root oil, camphor liquid oil, camphor fruit oil, camphor fiber oil, camphor balm camphor oil, camphor oil, camphor oil, camphor essential oil, camphor smoke oil, camphor gum oil, camphor flower oil, camphor essential oil, camphor fragrant oil, camphor cell oil, camphor resin oil, camphor oil, camphor refined oil, camphor resin oil, camphor wood oil, camphor petroleum oil, camphor essential oil, camphor leaf oil, camphor liquid oil, camphor wood oil, camphor raw oil, camphor spice oil, camphor extract oil, camphor essential oil, camphor bark oil, camphor odor oil, camphor leaf extract oil;

[0089] (5) Resin incense: frankincense oil, myrrh oil, ambergris oil, frankincense tree oil, pine oil, resin essential oil, pine wood oil, cologne oil, resin extract oil, cedar oil, ancient prescription oil, frankincense gum oil, fragrant resin oil, agarwood oil, myrrh oil, balsam oil, fragrant wood oil, amber oil, ebony oil, fragrant sand oil, Brazilian incense oil, nutmeg oil, fragrant tree root oil, fragrant snow oil, Chinese torreya oil, pine essential oil, pine oil, cypress oil, resin oil, amber oil, resin tree oil, frankincense resin oil, white frankincense oil, black frankincense oil, smokeless incense oil, licorice oil, tree oil, gum oil, golden tree oil, frankincense essential oil, agarwood essential oil, white tree oil, Indian frankincense oil, agarwood oil, natural resin oil, vanilla resin oil, resin oil, natural incense oil, licorice resin oil, white tree oil, natural resin oil, resin extract oil, trunk oil;

[0090] (6) Woody fragrance: cedar oil, cypress oil, oak oil, mahogany oil, poplar oil, walnut oil, camphor oil, sandalwood essential oil, teak oil, olive oil, red pine oil, teak essential oil, vetiver oil, red beech oil, vanilla wood oil, white pine oil, tea tree essential oil.

[0091] Furthermore, the emulsifier is selected from at least one of polyvinyl alcohol, sodium carboxymethyl cellulose, fatty alcohol polyoxyethylene ether, alkylphenol polyoxyethylene polyoxypropylene ether, alkylamine polyoxyethylene ether, hydrogenated castor oil, fatty amide polyoxyethylene ether, Span-20, Span-80, soybean lecithin, beeswax, algin, gelatin, xanthan gum, guar gum, carrageenan, gum arabic, lactose, sodium dodecyl sulfate, sodium dodecylbenzene sulfonate, sodium bisulfate, sulfonated olive oil, sodium salt of fatty acids, sulfonated stearic acid, sulfonate, sulfonated ethylene oxide, dodecyltrimethylammonium chloride, alkylamine oxide, ammonium sulfate, ammonium bisulfate, alkylpyridine, titanate, and hexafluorophosphate.

[0092] Furthermore, the agricultural chemicals are selected from any one of pesticides, fertilizers, fertilizers, and biostimulants. The pesticides are selected from any one of insecticides, fungicides, herbicides, rodenticides, plant growth regulators, and biological pesticides; the fertilizers are selected from at least one of organic fertilizers, inorganic fertilizers, organic-inorganic compound fertilizers, and microbial fertilizers; the biostimulants are selected from at least one of microbial biostimulants, protein and amino acid biostimulants, humic acid and fulvic acid biostimulants, plant hormones and plant growth regulators, seaweed extract biostimulants, and sugar alcohol biostimulants.

[0093] The preparation method of the microcapsule structure agricultural chemicals based on protein amyloid aggregates of the present invention is: protein, denaturant, emulsifier, plant essential oil, agricultural chemicals and water are uniformly mixed to prepare the protein amyloid aggregate microcapsule structure agricultural chemicals; when in use, the prepared protein amyloid aggregate microcapsule structure agricultural chemicals are directly sprayed on the surface of crops or diluted with water and then sprayed on the surface of crops, and the specific dilution multiple is determined according to the use requirements of the agricultural chemicals.

[0094] The beneficial effects of the present invention are as follows:

[0095] 1. The preparation method of the microcapsule structured agricultural chemicals based on protein amyloid aggregates of the present invention is simple, the main components are protein and plant essential oil, it is non-toxic, less irritating, and friendly to the ecological environment.

[0096] 2. The microcapsule structured agricultural chemicals based on protein amyloid aggregates of the present invention can act on plant leaves by spraying to enhance the penetration and conduction of agricultural chemicals on the surface of crops; at the same time, the protein amyloid aggregates have adhesion, which allows the product to stably adhere to plant leaves, reduce droplet splashing, improve the utilization rate of agricultural chemicals, save costs and reduce environmental pollution, and has a high application prospect.

[0097] 3. The microcapsule structured agricultural chemicals of the present invention have good stability and can exist stably under continuous high temperature conditions. At the same time, various agricultural chemicals can exist stably for a long time after being combined.

[0098] 4. The microcapsule structured agricultural chemicals of the present invention are universal and can be stably adhered after forming a coating, which can give the agricultural chemicals the property of being resistant to rain erosion. The use effect is ideal and has broad application prospects in agricultural production. BRIEF DESCRIPTION OF THE DRAWINGS

[0099] Figure 1 This is a data diagram of the dynamic contact angle of the microcapsule structured agricultural chemicals based on protein-based amyloid aggregates on the crop surface in Example 1.

[0100] Figure 2This is a diagram showing the retention volume of the protein-amyloid aggregate-based microcapsule structured agricultural chemicals on the crop surface of Example 1.

[0101] Figure 3 This is a comparison of optical photographs of the protein-based amyloid aggregate microcapsule structured agricultural chemicals of Example 1 placed in an oven at 54° C. for 14 days.

[0102] Figure 4 This is a microscopic structure diagram of the microencapsulated agricultural chemicals based on protein-based amyloid aggregates of Example 1.

[0103] Figure 5 This is a laser confocal image of the transmission of the microcapsule structured agricultural chemicals based on protein amyloid aggregates in Example 1 inside crops.

[0104] Figure 6 This is a diagram showing the weed control effect of the protein-based amyloid aggregate microcapsule structured agricultural chemicals used in farmland experiments in Example 2. DETAILED DESCRIPTION

[0105] The present invention is further described in detail below in conjunction with the accompanying drawings and embodiments, but the protection scope of the present invention is not limited to these embodiments.

[0106] Example 1

[0107] In this embodiment, the microcapsule structure agricultural chemical based on protein amyloid aggregates is prepared by mixing 0.09g bovine serum albumin, 0.8g tri(2-carboxyethyl)phosphine hydrochloride, 1g Litsea cubeba essential oil, 1.1g hydrogenated castor oil, 0.8g buprofezin original drug, and 10g water. When used, 10mL of the obtained microcapsule structure agricultural chemical is directly added to 490mL water and mixed evenly, and then acted on the surface of the crop by spraying.

[0108] Example 2

[0109] In this embodiment, the microcapsule structure agricultural chemicals based on protein amyloid aggregates are prepared by uniformly mixing 10g bovine serum albumin, 15g dithiothreitol, 0.6g lavender essential oil, 0.7g gum arabic, 5g glyphosate, and 2500g water. When used, they are directly sprayed on the surface of crops.

[0110] Example 3

[0111] The protein-based amyloid aggregate microcapsule structure agricultural chemicals of this embodiment are prepared by mixing 0.11g bovine serum albumin, 1g β-mercaptoethanol, 1.2g tea tree essential oil, 1.3g hexafluorophosphate, 0.6g imidacloprid preparation, and 10g water. When used, 10mL of the obtained protein-based amyloid aggregate microcapsule structure agricultural chemicals are directly added to 490mL of water and mixed evenly, and then acted on the surface of crops by spraying.

[0112] Example 4

[0113] The protein-based amyloid aggregate microcapsule structure agricultural chemicals of this embodiment are prepared by mixing 0.15g bovine serum albumin, 1g cysteine, 1.3g peppermint essential oil, 1.4g sodium bisulfate, 0.8g urea, and 10g water. When used, 10mL of the obtained protein-based amyloid aggregate microcapsule structure agricultural chemicals are directly added to 490mL water and mixed evenly, and then acted on the surface of crops by spraying.

[0114] Example 5

[0115] The protein-based amyloid aggregate microcapsule structure agricultural chemicals of this embodiment are prepared by mixing 0.09g whey albumin, 0.9g reduced glutathione, 1g lemon essential oil, 1.1g ammonium sulfate, 0.9g buprofezin suspension, and 10g water. When used, 10mL of the obtained protein-based amyloid aggregate microcapsule structure agricultural chemicals are directly added to 490mL water and mixed evenly, and then acted on the surface of crops by spraying.

[0116] Example 6

[0117] The protein-based amyloid aggregate microcapsule structure agricultural chemical of this embodiment is prepared by mixing 0.12g soybean protein, 1.1g potassium chlorate, 1.2g orange flower essential oil, 1.3g polyvinyl alcohol, 1g flunidrone technical, and 10g water. When used, 10mL of the obtained protein-based amyloid aggregate microcapsule structure agricultural chemical is directly added to 490mL water and mixed evenly, and then sprayed on the surface of the crop.

[0118] Example 7

[0119] The protein-based amyloid aggregate microcapsule structure agricultural chemicals of this embodiment are prepared by mixing 0.15g of pepsin, 0.9g of potassium permanganate, 1.4g of chamomile essential oil, 1.5g of fatty alcohol polyoxyethylene ether, 0.9g of fluzosulfuron original drug, and 10g of water. When used, 10mL of the obtained protein-based amyloid aggregate microcapsule structure agricultural chemicals are directly added to 490mL of water and mixed evenly, and then acted on the surface of crops by spraying.

[0120] Example 8

[0121] The protein-based amyloid aggregate microcapsule structure agricultural chemicals of this embodiment are prepared by mixing 0.17g myoglobin, 1.2g ferrous sulfate, 1g rosemary essential oil, 1.1g dodecylamine polyoxyethylene ether, 1g isoproturon original drug, and 10g water. When used, 10mL of the obtained protein-based amyloid aggregate microcapsule structure agricultural chemicals are directly added to 490mL water and mixed evenly, and then acted on the surface of crops by spraying.

[0122] Example 9

[0123] The protein-based amyloid aggregate microcapsule structure agricultural chemicals of this embodiment are prepared by mixing 0.12g potato protein, 0.8g potassium dichromate, 1g chamomile essential oil, 1.1g carrageenan, 0.6g chlorothioxanthone technical drug, and 10g water. When used, 10mL of the obtained protein-based amyloid aggregate microcapsule structure agricultural chemicals are directly added to 490mL water and mixed evenly, and then acted on the surface of crops by spraying.

[0124] Example 10

[0125] The protein-based amyloid aggregate microcapsule structure agricultural chemicals of this embodiment are prepared by mixing 0.12g keratin, 1.1g potassium dichromate, 1.6g chamomile essential oil, 1.7g dodecyltrimethylammonium chloride, 0.9g difenoconazole original drug, and 10g water. When used, 10mL of the obtained protein-based amyloid aggregate microcapsule structure agricultural chemicals are directly added to 490mL water and mixed evenly, and then acted on the surface of crops by spraying.

[0126] Embodiment 11

[0127] The protein-based amyloid aggregate microcapsule structure agricultural chemicals of this embodiment are prepared by mixing 0.12g oat protein, 1.1g hydrobromic acid, 1.5g sandalwood essential oil, 1.6g fatty alcohol polyoxyethylene ether, 0.9g thiazin original drug, and 10g water. When used, 10mL of the obtained protein-based amyloid aggregate microcapsule structure agricultural chemicals are directly added to 490mL water and mixed evenly, and then acted on the surface of crops by spraying.

[0128] Example 12

[0129] The protein-based amyloid aggregate microcapsule structure agricultural chemicals of this embodiment are prepared by mixing 0.12g of zein, 1.1g of hydroiodic acid, 1.2g of ylang-ylang essential oil, 1.3g of xanthan gum, 0.9g of buprofezin original drug, and 10g of water. When used, 10mL of the obtained protein-based amyloid aggregate microcapsule structure agricultural chemicals are directly added to 490mL of water and mixed evenly, and then acted on the surface of crops by spraying.

[0130] Example 13

[0131] The protein-based amyloid aggregate microcapsule structure agricultural chemicals of this embodiment are prepared by uniformly mixing 0.12g pea protein, 0.8g perchloric acid, 1g ginger essential oil, 1.1g guar gum, 0.6g thiazin original drug, and 10g water. When used, 10mL of the obtained protein-based amyloid aggregate microcapsule structure agricultural chemicals is directly added to 490mL water and mixed evenly, and then sprayed on the surface of the crop.

[0132] Embodiment 14

[0133] The protein-based amyloid aggregate microcapsule structure agricultural chemicals of this embodiment are prepared by mixing 0.12g millet protein, 0.8g trifluoroethanol, 1g eucalyptus essential oil, 1.1g sodium diisooctyl succinate sulfonate, 0.6g chlorantraniliprole suspension, and 10g water. When used, 10mL of the obtained protein-based amyloid aggregate microcapsule structure agricultural chemicals are directly added to 490mL water and mixed evenly, and then acted on the surface of crops by spraying.

[0134] Embodiment 15

[0135] In this embodiment, the microcapsule structure agricultural chemical based on protein amyloid aggregates is prepared by mixing 0.09g bovine serum albumin, 0.8g tri(2-carboxyethyl)phosphine hydrochloride, 1g Litsea cubeba essential oil, 1.1g hydrogenated castor oil, 0.6g glyphosate preparation, and 10g water. When used, 10mL of the obtained microcapsule structure agricultural chemical is directly added to 490mL water and mixed evenly, and then acted on the surface of the crop by spraying.

[0136] Example 16

[0137] The microcapsule structure agricultural chemicals based on protein amyloid aggregates in this embodiment are prepared by mixing 45g soybean protein, 15g tri(2-carboxyethyl)phosphine hydrochloride, 15g ginger essential oil, 17g hydrogenated castor oil, 25g glyphosate preparation, and 100g water. When used, 100mL of the obtained microcapsule structure agricultural chemical mother solution is directly added to 100L water to dilute and mix evenly, and then act on the crop surface by spraying. The present invention can also use other pesticides, pesticide raw materials, fertilizers and other agricultural chemicals to replace the agricultural chemicals in the above examples 1 to 16, all of which are within the scope of protection of the present invention.

[0138] In order to demonstrate the beneficial effects of the present invention, the inventors conducted performance tests on the microcapsule structured agricultural chemicals based on protein amyloid aggregates prepared in the above Examples 1 and 2, respectively. The specific experiments are as follows:

[0139] 1. Verification of the penetration ability of agricultural chemicals based on protein-amyloid aggregate microcapsule structure

[0140] The lotus leaf was used as a plant leaf model, and the protein-based amyloid aggregate microcapsule structured agricultural chemicals of Example 1 were sucked into a 1 mL syringe. The contact angle change of the droplet on the lotus leaf surface was measured using an optical microscope contact angle measuring instrument. The dynamic contact angle change data of the protein-based amyloid aggregate microcapsule structured agricultural chemicals on the lotus leaf surface (see Figure 1 ).

[0141] 2. Verification of the immobilization ability of agricultural chemicals based on protein-amyloid aggregate microencapsulation structure

[0142] 0.8 g of thiamethoxam original drug was added to 10 g of water + 1 g of Litsea cubeba essential oil to obtain the water + essential oil + thiamethoxam group, 0.8 g of thiamethoxam original drug was added to 0.09 g of bovine serum albumin + 10 g of water + 1 g of Litsea cubeba essential oil to obtain the protein + essential oil + thiamethoxam group, and the microcapsule structure agricultural chemical based on protein amyloid aggregates in Example 1 was the protein amyloid + essential oil + thiamethoxam group. 0.2 mL of the prepared solution of each group was added to 9.8 mL of water to obtain 10 mL of liquid to be sprayed, and then 0.5 mL of the spraying liquid was taken each time and evenly sprayed on the surface of a 5 cm × 5 cm lotus leaf, and then immediately weighed with an analytical balance to compare the changes in mass before and after. Figure 1 The results show that the retention volume of the water + essential oil + thiazinone group on the lotus leaf surface is very low, followed by the protein + essential oil + thiazinone group, while the microcapsule structured agricultural chemicals based on protein amyloid aggregates in Example 1 of the present invention can retain a larger volume of liquid medicine on the lotus leaf surface, and the retention volume is 1.5 times that of other groups (see Figure 2 ).

[0143] 3. Storage stability verification of microencapsulated agricultural chemicals based on protein-amyloid aggregates

[0144] The microcapsule structured agricultural chemicals based on protein amyloid aggregates of Example 1 were placed in a constant temperature oven at 54°C and photographed at 1d, 7d and 14d (see Figure 3 The results show that the state of the microcapsule structured agricultural chemicals based on protein amyloid aggregates of Example 1 did not change within 14 days, and remained uniform and stable. This proves that the microcapsule structured agricultural chemicals based on protein amyloid aggregates of the present invention have good storage stability, which is conducive to storage and use in practical applications.

[0145] 4. Morphological analysis of microencapsulated agricultural chemicals based on protein-amyloid aggregates

[0146] After the microcapsule structure agricultural chemicals based on protein amyloid aggregates of Example 1 were freeze-dried, their morphology was observed by scanning electron microscopy. The results showed that the microcapsule structure agricultural chemicals based on protein amyloid aggregates of the present invention were microcapsule structures under scanning electron microscopy (see Figure 4 ).

[0147] 5. Delivery of agrochemicals in crops using protein-amyloid aggregate microcapsule structures

[0148] The thiamethoxam in the microcapsule structured agricultural chemicals based on protein amyloid aggregates of Example 1 was replaced with 7-hydroxycoumarin, and the broad bean seeds were soaked in the solution for 20 hours, and the fluorescence of the roots, stems and leaves was observed under a laser confocal microscope. The results showed that the microcapsule structured agricultural chemicals based on protein amyloid aggregates of the present invention can be conducted inside the plant (see Figure 5 ).

[0149] 6. Application effect of microencapsulated agricultural chemicals based on protein-amyloid aggregates in farmland experiments

[0150] The outdoor weed field was divided into three plots, each with a size of 3m×2m, and the following experiments were carried out respectively: the first group was sprayed with 2500mL water + essential oil group, i.e., a mixture of 2500g water + 0.6g lavender essential oil, without adding glyphosate; the second group was sprayed with 2500mL water + essential oil + protein + glyphosate group, i.e., a mixture of 2500g water + 0.6g lavender essential oil + 5g glyphosate; the third group was sprayed with 2500mL protein amyloid solution + essential oil + glyphosate solution group, i.e., the microcapsule structured agricultural chemicals based on protein amyloid aggregates in Example 2. Figure 6 The results show that the protein-based amyloid aggregate microcapsule structured agricultural chemicals of Example 2 can effectively remove weeds. Compared with the first and second groups, the weeds in the third group turned yellow and withered earlier.

Claims

1. A microcapsule structured agricultural chemical based on protein-based amyloid aggregates, characterized in that: It is made of the following raw materials in the following weight proportions: The denaturant is a reducing agent or an oxidizing agent.

2. The microcapsule structured agricultural chemical based on protein amyloid aggregates according to claim 1, characterized in that: It is made of the following raw materials in the following weight proportions:

3. The microcapsule structured agricultural chemical based on protein amyloid aggregates according to claim 1, characterized in that: It is made of the following raw materials in the following weight proportions:

4. The microcapsule structured agricultural chemical based on protein amyloid aggregates according to any one of claims 1 to 3, characterized in that: The protein is selected from animal-derived protein or plant-derived protein; The animal-derived protein is at least one of the proteins contained in the following animals: (1) Arthropoda, class Insecta, order Coleoptera: Pederidae, Coleoptera, Scarabaeoidea, Cerambycidae, Chrysomeliformes, Curculionoidea, Dermatophytidae, Cynomoroidea, Hydrocharoidea, Mud Beetles, Cerambycidae, Tiger Beetles, Curculionidae, Coccinellidae, Lampyridae, Cloth Beetles, Cryptolabridae, Thick-horned Coleoptera, and Ground Coleoptera; (2) Arthropoda, Insecta, Hymenoptera: Ichneumonidae, Braconidae, Mylidae, Gall-bee Bees, Sphecidae, Vespidae, Formicidae, Apidae, Tenebrioidae, Sawfly, Woodfly, Parasitic Woodfly, Chrysopidae, Enameled Mylidae, Trichogrammatidae, Mylidae, Mylidae, Hammer-horned Mylidae, Marginal Mylidae, and Broad-bellied Mylidae; (3) Arthropoda, Insecta, Lepidoptera: Microptera, Acanthidae, Xylotomidae, Superfamily Lycopodia, Rapeworms, Carpiomorpha, Limulidae, Torcula, Sciaenidae, Schizomysidae, Schizomysidae, Gnaphal ...; (4) Arthropoda, Crustacea, Macacaridae: Phylum Arthropodidae, Macrophyllidae, Pseudophyllidae, Deep-sea Shrimp, Indian Shrimp, Broad Shrimp, Semi-toed Shrimp, Big-toed Shrimp, Toothed Shrimp, Proto-toed Shrimp, Pseudo-shrimp, Trogidae, Red Shrimp, Crown Shrimp, Lycopodidae, Microshrimp, Square Shrimp, Shrimp, Broad Shrimp, Parashrimp; (5) Arthropoda, class Arachnida, order Araneae: Araneidae, Theridiidae, Theridiidae, Lycosauridae, Salticidae, Scorpionidae, Ixodidae, Acaridae, Tickidae, Red Spiders, Theridiidae, Theridiidae, Ocellidae, Theridiidae, Theridiidae, Theridiidae, Theridiidae, Theridiidae, Theridiidae, Theridiidae; (6) Arthropoda, Arachnida, Scorpionidae: Pseudo-marsh scorpionidae, Pincer scorpionidae, Microscorpionidae, Pig scorpionidae, Marsh scorpionidae, True scorpionidae, Superstitious mountain scorpionidae, Bliss scorpionidae, Hairy scorpionidae, Fearful scorpionidae, Trapped scorpionidae, Semiscorpionidae, Scorpionidae, Heteroscorpionidae, Diploscorpionidae, Thin scorpionidae; (7) Phylum Mollusca, Class Gastropod, Order Cephalopoda: Pseudo-spined Snails, Pseudo-spined Sea Snails, Adidae, Sternidae, Semeno-spined Snails ... (8) Phylum Mollusca, Class Gastropod, Order Aplysia: Cylindrica, Aplysia, Hylostomidae, Hylostomidae, Hylostomidae, Hylostomidae, Hylostomidae, Hylostomidae, Hylostomidae, Hylostomidae; (9) Phylum Mollusca, Class Gastropod, Order Nudibranch: Trionychidae, Trionychidae, Trionychidae, Trionychidae, Trionychidae, Trionychidae, Trionychidae, Trionychidae, Trionychidae, Trionychidae; (10) Phylum Mollusca, Class Cephalopoda, Order Sepiidae: Sepiidae, Subfamily Heteropodinae, Subfamily Sakinocephalae, Subfamily Otocephalae; (11) Phylum Mollusca, Class Cephalopoda, Order Octopus: Octopidae, Giant Octopidae, Coleoptera, Cuttlefish, Argonautidae, Heptapodidae, Deep-sea Octopus, Brachycoidea; (12) Chordata: Acipenseridae, Hypophthalmichthys, Hypophthalmichthys, Neophthalmichthys, Osteoglossidae, Anguilla, Anguidae, Acanthodontidae, Cypriniformes, Gnaphalinae, Salmoniformes, Salmoninae, Herpidae, Salmoniformes, Ophiodontidae ... , Siluriformes, Siluridae, Silversides, Gnathophoridae, Silversides, Gnathophoridae, Gnathophoridae, Gadformes, Gadidae, Ophiopods, Ophiopods, Chrysopidae, Ophiopods, Ophiopods, Ophiopods, Ophiopods, Sphenodontidae, Syngnathidae, Syngnathidae, Syngnathidae, Perciformes, Wrasseniidae, Perciformes, Rockfish, Perciformes, Pomacanthidae, Perciformes, Cichlidae; (13) Chordata, Amphibia, Apodidae: Jellyfish, Anemone, Lumbricidae, Leechidae, Snakes, Sea Cucumbers, Asteridae, Echinoidea, Snails, Mussels, Clams, Calycozoidae; (14) Chordata, class Amphibia, order Caudata: Cryptobranchidae, Ambystoma, Eusalidae, Hypoderma, Pulmonary Salamanders, Amphibia, Caviidae, Costidae, Eudontidae, Fat Salamanders, Blind-eyed Lumbricidae, and Megalostomidae; (15) Chordata, Amphibia, Anura: Toads, Rhacophoridae, Hylacidae, Ceratopogonidae, Mylodactylidae, Microdactylidae; (16) Phylum Chordata: Reptiles: Squamata, Testudinidae, Dermatochelydae, Testudinidae, Cheloniformes, Testudinidae, Testudinidae, Crocodilia, Alligators, Alligators, Alligators; (17) Chordata: Psittaciformes, Cockatielidae, Psittaciformes, Lorikeetidae, Anseriformes, Anatidae, Anseriformes, Anseriformes, Spheniscidae, Passeriformes, Passeriformes, Corvidae, Passeriformes, and Passeriformes; (18) Chordata: Monotremes: Platypus, Echidna, Perissodactyla, Rhinoceros, Proboscidea; (19) Chordata, Mammalia, Marsupials: Marmosets, Koalas, Bandicoots, Wombats, and Quetzalcoatlus; (20) Chordata, class Mammalia, order Rodentia: Sciuridae, Cricetidae, Bamboo Rhynchomys, Dormouse, Myrmecophaga, Caviidae, Beaver, Flying Squirrel, Porcupine, Lemming, Gerbil, Capybara; (21) Chordata, Mammalia, Chiroptera: Pteropus, Rhinolophus, Hippodrome, Myotis, Long-winged Bat, Brachypterygidae, Fruit Bat; (22) Chordata, Mammalia, Carnivora: Felidae, Canidae, Ursidae, Mustelidae, Lutradae; (23) Chordata, Mammalia, Primates: Hominidae, Gibbon, Loris, Tarsier, Lemuridae; (24) Chordata, Mammalia, Artiodactyla: Camelidae, Suidae, Peccary, Giraffidae, Pronghorn, Cervidae, Musk Deer, Bovidae, Hippopotamidae; (25) Phylum Chordae, Class Mammalia, Order Cetacea: freshwater dolphins, sperm whales, beaked whales, narwhals, sharp-nosed dolphins, dolphins, porpoises, baleen whales, gray whales, right whales, minke whales, beaked whales, fin whales; The plant-derived protein is at least one of the following animal proteins: (1) Ceratophyllum: Ceratophyllums: Ceratophyllums, ... (2) True Mosses: Axis, Axis, Hoary Mosses, Axis, Microstomaceae, Corrugated Mosses, Corrugated Mosses, Beaded Mosses, True Mosses, True Mosses, True Mosses, Lantern Mosses, Prawn Mosses, Prawn Mosses, Tobacco Mosses, Tobacco Mosses, Brachycera, Brachycera, Paraphylla, Paraphylla, Paraphylla, Antinymphae, Gourd Mosses, Big Cap Mosses, Gourd Mosses, Gourd Mosses, Purple Calyx Mosses, Purple Calyx Mosses, Purple Calyx Mosses, Purple Calyx Mosses, Stone Crevice Mosses Mosses, the order of the purple-calyx mosses, the order of the tiger-tail mosses, the order of the yellow-yellow mosses, the order of the oily mosses, the order of the oily mosses, the order of the white mosses, the order of the oily mosses, the order of the velvet-cap mosses, the order of the tree-lime mosses, the order of the tree-lime mosses, the order of the tree-lime mosses, the order of the straight-toothed mosses, the order of the wood-ling mosses, the order of the wood-ling mosses, the order of the ridge-capped mosses, the order of the juniper mosses, the order of the juniper mosses, the order of the water-lichen mosses, the order of the twisted-stem mosses, the order of the water-lichen mosses, the order of the water-lichen mosses, the order of the cold-lichen mosses, the order of the water-lichen mosses, the order of the beautiful-lichen mosses; (3) Eubryophyta, Eubryophyta, Angiospermaceae, Angiospermaceae, Angiospermaceae, Angiospermaceae, Angiospermaceae; (4) True mosses: Onagraceae, Bolognaaceae, Reverse hair mossaceae, Green mossaceae, Wetland mossaceae, Wannian mossaceae, Cryptocapsulariaceae, Silk mossaceae, Brocteraceae, Sphagaceae, Soft tooth mossaceae, Tower mossaceae, Gray mossaceae, Peacock mossaceae, Boat leaf mossaceae, Thin Luo mossaceae, White tooth mossaceae, Crepe mossaceae, Tilapia mossaceae, Golden hair mossaceae, Flat mossaceae, Straight mossaceae, Cotton mossaceae, False fine Luo mossaceae, Axillary mossaceae, Pteridaceae, Golden gray mossaceae, Hairy brocade mossaceae, Heterodontaceae, Weeping mossaceae, Heliconia mossaceae, Brocade mossaceae, Pseudo-thin Luo mossaceae, Sclerophyllaceae, Acanthaceae, Lepiophyllaceae, Thick handle mossaceae; (5) Eubryophytes, Eubryophytes, and Hypobryophytes: Phyllostachys, Candleleafys, Microhylophytes, Botrychnophytes, Arboretum, Hypobryophytes, Thick Lithophytes, Echinopsaceae, and Light Mosses; (6) True mosses: Black mosses, Black mosses, Black mosses, Black mosses, True mosses: Long mosses, Long mosses, Long mosses, True mosses: Golden mosses, Golden mosses, Golden mosses, True mosses: Sphagnum mosses, Sphagnum mosses, True mosses: Sphagnum mosses, True mosses: Sphagnum mosses, True mosses: Algae mosses, Algae mosses, True mosses: Tetradentata mosses, Tetradentata mosses, Tetradentata mosses; (7) Chlorophyta, Chlorophyta: Bryophyceae, ... (8) Chlorophyta, Chlorophyta, Acrophyceae, Acrophyceae, Gymnophyceae, Gymnophyceae, Gymnophyceae, Gymnophyceae, Dauerlys ... (9) Marchantia: Bracteaceae, Microphylla, Microphylla, Nanximeiaceae, Forkleaf, Forkleaf, Greenleaf, Bandleaf, Bandleaf, Mossleaf, Bandleaf, Purpleleaf, Purpleleaf, Light-calyx, Ear-leaf, Light-calyx, Hair-ear, Light-calyx, Fine-scale, Light-calyx, Eye-calyx, Light-calyx, Flat-calyx, Hair-leaf, Hair-leaf, New-leaf; (10) Phyllophyllous order: Acrocalyceae, Cryptocapsulariaceae, Erectleafaceae, Leptocarpaceae, Pocillopora, Eyelashaceae, Capsulariaceae, Macrocalyceae, Pseudo-macrocalyceae, Geocalyceae, Holocyceae, Fusariumaceae, Shearleafaceae, Longicyceae, Armoraceae, Leafmoss, Complexaceae, Fingerleafmoss, Toothcalyceae, Splitleafmoss, Beardmoss, Microcalyceae, Pseudocalyceae, Feathermoss, Pseudo-complexaceae, Scutellariaceae, Synophyllaceae, Diplocoleaceae, Tubemoss, Horizontalleafmoss, Velvetmoss; (11) Phylum Ranunculaceae, Class Ranunculales: Verruco-crown family, Star-hole family, Snake family, Flowery family, Liverwort family, Dioscorea family, Light family, Single-month family, Money family, Leather-leaf family, Wesley family; (12) Rhodophyta: Acrophyceae, Acrophyceae, Ignaec ... (13) Rhodophyta, Rhodophyta, and Taxodium: Stem-spined algae, Gelatophyceae, Endophyceae, Taxodium, Myxocystis, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae, Hyalariaceae; (14) Vascular plants, class Equisetum: Alsophilales, Cyathophytes, family Cyathophytes, family Cyathophytes, family Equisetaceae, family Diplophyllaceae, family Diplophyllaceae, family Diplophyllaceae, family Hymenopterales, family Hymenopterales, family Hymenopterales, family Hymenopteraceae, family Osmanthaceae, family Pinaceae, family Sophora, family Sophora, family Sophora, family Cyperaceae, family Cyperaceae; (15) Vascular plants, class Equisetaceae, order Polypodiaceae: Aspleniaceae, Aspleniaceae, Pterid ... (16) Vascular plants: Acorusales, Acorus family; Palmaceae; Schisandraceae; Boraginaceae; Buxusales, Buxus family; Celastraceae; Ceratophyllum family; Ceratophyllum family; Chrysanthemum family; Commelinaceae; Commelinaceae; Commelinaceae; Commelinaceae; Commelinaceae; Cornaceae; Cornaceae; Hydrangeaceae; Cornaceae; Cyanophyllum family; Tassel family; Tassel family; Pentacarpaceae; Cucurbitaceae; Cucurbitaceae; Begoniaceae; Cucurbitaceae; Moracaceae; Cucurbitaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; Dioscoreaceae; The order Acanthaceae, the order Leguminosae, the order Polygala, the order Merantiaceae, the order Psoralea, the order Psoralea, the order Eucommia, the order Geraniales, the order Decapoda, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Psoralea, the order Vitis, the order Vitis; the order Vitis; (17) Vascular plants: Alismataceae, Araceae, Araceae, Asteraceae, Asteraceae, Asteraceae, Asteraceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae, Aquaticaceae; (18) Vascular plants, Magnoliaceae, Apiaceae, Araliaceae, Pittosporaceae, and Coleopsaceae; (19) Vascular plants, Magnoliaceae, Aquilegiaceae: Aquilegiaceae, Aquilegiaceae, Aquilegiaceae; (20) Vascular plants, Magnoliaceae, Asparagales: Asparagaceae, Amaryllidaceae, Asphodelaceae, Curculigoaceae, Iridaceae, Orchidaceae; (21) Vascular plants: Magnoliaceae, Asterales, Asteraceae, Campanulaceae, Menymaceae, Pentaphyllum, Stylophyllum; (22) Vascular plants, Magnoliaceae, Cruciferae: Cruciferae, Glechomaea, Carica, Caricaceae, Moringaceae, Meliaceae, Echinopsaceae, Nasturtiumaceae; (23) Vascular plants: Caryophyllaceae, Aizoaceae, Amaranthaceae, Uncariaceae, Basella, Cactaceae, Droseraceae, Petalopsis, Pinaceae, Cornaceae, Nepenthesaceae, Mirabilis, Allium, Phytolaccae, Pleurotus, Polygonaceae, Portulaceae, Glechomae, Salicaceae; (24) Vascular plants: Ericaceae, Actinidiaceae, Impatiens, Alnus, Ixigera, Diospyros, Ericaceae, Leydigaceae, Cyperaceae, Pentaphyllum, Allium, Primulaceae, Sapotaceae, Costaceae, Styracaceae, Asteraceae, Theaceae; (25) Vascular plants, Magnoliaceae, Fagales: Fagaceae, Betulaceae, Casuarinaceae, Fagaceae, Juglandaceae, Myricaceae; (26)) Vascular plants, Magnoliaceae, Gentianales: Gentianaceae, Apocynaceae, Gelsemium, Gentianaceae, Loganaceae, Rubiaceae; (27) Vascular plants, Magnoliaceae, Labiatae: Lamiaceae, Acanthaceae, Bignoniaceae, Vanillaceae, Gesneriaceae, Utriculariaceae, Matricariaceae, Ceratoniaceae, Aquilegiaceae, Oleaceae, Orobanchaceae, Paulowniaceae, Sesamaceae, Penicillaceae, Plantaginaceae, Scrophulariaceae, Verbenaceae, and Aglaonema; (28) Vascular plants, Magnoliaceae, Liliales: Liliaceae, Colchicumaceae, Hostaceae, Veratrum, Smilaxaceae; (29) Vascular plants: Malpurinae, Echinopsaceae, Echinopsaceae, Anshenaceae, Garciniaceae, Pomacantha, Stellariaceae, Corydalis, Euphorbiaceae, Hypericaceae, Glutinaceae, Linaceae, Tropaeolaceae, Cyperaceae, Passifloraceae, Arboraceae, Phyllanthaceae, Carexaceae, Drupaceae, Rhizophoraceae, Salicaceae, Violaceae; (30) Vascular plants, Magnoliaceae, Malvaceae: Malvaceae, Malvaceae, Helianthaceae, Dipterocarpaceae, Thymelaeaceae; (31) Vascular plants, Magnoliaceae, Myrtales: Myrtaceae, Combretaceae, Cryptomeriaceae, Lythraceae, Melastomataceae, Onagraceae; (32) Vascular plants, Magnoliales, Pandanaceae: Pandanaceae, Stemonaceae, Mycorrhizae, and Featherleafaceae; (33) Vascular plants: Magnoliaceae, Poaceae, Bromeliaceae, Cyperaceae, Cyperaceae, Cyperaceae, Juncaceae, Sphagaceae, Juncaceae, Typhaceae, and Cyperaceae; (34) Vascular plants, Magnoliaceae, Proteales: Proteaceae, Nelumboceae, Platanaceae, and Ceropegiaceae; (35) Vascular plants, Magnoliaceae, Ranunculales: Ranunculaceae, Berberidaceae, Astrophyllaceae, Akebiaceae, Menispermaceae, Papaveraceae; (36) Vascular plants: Magnoliaceae, Rosaceae, Elaeagnaceae, Moraceae, Rhamnaceae, Rosaceae, Ulmaceae, Urticaceae; (37) Vascular plants: Magnoliaceae, Santalum orders: Santalaceae, Cyperaceae, Cyperaceae, Cyperaceae, Loranthaceae, Aspergillus family, Citronaceae, Santalaceae, Cyperaceae, and Malvaceae; (38) Vascular plants, Magnoliaceae, Sapindaceae: Sapindaceae, Anacardiaceae, Botrytis cinerea, Oleaceae, Meliaceae, Nitraria tanguticaceae, Rutaceae, Simsamariaceae; (39) Vascular plants: Magnoliaceae, Saxifragales: Saxifragaceae, Mycorrhizaceae, Cynomorium, Sansevieriaceae, Ribesaceae, Echinochloa, Hamamelidaceae, Myristicaceae, Paeoniaceae, Psoralea, Saxifragaceae; (40) Vascular plants, Magnoliaceae, Solanales: Solanaceae, Convolvulaceae, Acanthaceae, Sphenopalmataceae; (41) Vascular plants, Magnoliaceae, Zingiberales: Zingiberaceae, Cannaceae, Zingiberaceae, Orchidaceae, Marantaceae, Musaceae, Strelitziaceae; (42) Vascular plants: Araucariaces, Araucariaceae, Araucariaces, Podocarpaceae, Cupressaceae, Cupressaceae, Cupressaceae, Taxaceae, Cycadales, Cycadaceae, Ephedales, Ephedraceae, Ginkgoales, Ginkgoaceae, Gnetaceae, Pinaceae, Pinaceae, and Machilaceae.

5. The microcapsule structured agricultural chemical based on protein amyloid aggregates according to any one of claims 1 to 3, characterized in that: The protein is selected from any one or more of lysozyme, bovine serum albumin, human serum albumin, lactoferrin, whey albumin, insulin, α-lactalbumin, fibrinogen, β-lactoglobulin, Aβ peptide, prion protein, α-synuclein, cystatin C, huntingtin protein, immunoglobulin, ribonuclease A, cytochrome c, α-amylase, horseradish peroxidase, pepsin, myoglobin, collagen, keratin, hemoglobin, DNA polymerase, casein, soy protein, pea protein, zein, gliadin, gluten, oat protein, potato protein, hemp seed protein, walnut protein, rapeseed protein, hazelnut protein, quinoa protein, sunflower seed protein, pumpkin seed protein, black sesame protein, mushroom protein, red algae protein, legumin, barley protein, wheat protein, millet protein, gluten, kidney bean protein, casein, collagen, and catalase.

6. The microcapsule structured agricultural chemical based on protein amyloid aggregates according to any one of claims 1 to 3, characterized in that: The reducing agent is any one or more of dithiothreitol, β-mercaptoethanol, tris(2-carboxyethyl)phosphine hydrochloride, cysteine, vitamin C, sodium borohydride, aluminum borohydride, and reduced glutathione; the oxidizing agent is any one or more of trivalent cobalt salt, chlorate, potassium permanganate, persulfate, potassium dichromate, concentrated sulfuric acid, hydrochloric acid, nitric acid, hydrobromic acid, hydroiodic acid, perchloric acid, ozone, hydrogen peroxide, fluorine gas, chlorine gas, sodium bismuthate, periodic acid, sodium ferrate, lead dioxide, guanidine hydrochloride, urea, trifluoroethanol, hexafluoroisopropanol, and trifluoroacetic acid.

7. The microcapsule structured agricultural chemical based on protein amyloid aggregates according to any one of claims 1 to 3, characterized in that: The plant essential oil is selected from any one or more of the following: (1) Citrus fragrance: orange oil, lemon oil, grapefruit oil, lime oil, tangerine oil, grapefruit oil, blood orange oil, bitter orange oil, perfume orange oil, bergamot oil, lemon balm oil, bergamot oil, Malaysian orange oil, oil orange oil, lime leaf oil, lemongrass oil, fragrant lime oil, lemon lavender oil, peach oil, green lemon oil, teak oil, orange mint oil, citrus essential oil, lemon balm oil, Indian orange oil, sweet orange oil, mint lemon oil, golden lemon oil, spicy orange oil, green orange oil, chili orange oil, sweet orange oil, spicy citrus oil, bitter lime oil, tangerine oil, white Grape oil, wood orange oil, sugar orange oil, kumquat oil, tangerine oil, platycodon oil, grass orange oil, sweet lemon oil, lime oil, wild citrus oil, yellow orange oil, fruity oil, fresh orange oil, sunshine orange oil, snow orange oil, silver orange oil, fragrant green oil, Indian lemon oil, fragrant oil, green grapefruit oil, orange fragrance oil, sweet lime oil, fragrant fruit oil, tangerine oil, bubble orange oil, fig oil, honey tangerine oil, fragrant red orange oil, fresh lemon oil, white lemon oil, fragrant amber oil, golden lemon oil, blood orange essential oil, bergamot fragrance oil, golden pumpkin oil, amber orange oil, litsea cubeba essential oil, grapefruit essential oil, bitter orange essential oil; (2) Floral fragrance: rose oil, lavender oil, jasmine oil, orange blossom oil, lily of the valley oil, lily oil, chamomile oil, peony oil, lily of the valley oil, carnation oil, violet oil, perfume lily oil, lavender essential oil, sunflower oil, cauliflower oil, clove oil, grapefruit flower oil, begonia oil, lilac oil, honeysuckle oil, bee flower oil, flower and grass oil, calendula oil, gardenia oil, iris oil, lilac oil, rosewood oil, okra oil, evening primrose oil, red rose oil, snowflake oil, white rose oil, violet leaf oil, lotus oil, poppy oil, blue lily oil, camphor flower oil, flower and fruit oil, honeysuckle oil, podocarpus oil, red tulip oil, Sweet alyssum oil, purple-leaf plum oil, verbena oil, white tulip oil, aromatic alkali oil, fragrant dendrobium oil, yellow rose oil, nectar oil, lily of the valley oil, gardenia oil, red carnation oil, rosemary oil, fragrant clove oil, flower and grass oil, okra flower oil, acacia oil, white lily of the valley oil, wildflower oil, vanilla flower oil, daylily oil, apple flower oil, mint flower oil, azalea oil, autumn rhyme flower oil, anemone oil, rose oil, thistle oil, crabapple flower oil, purple golden shea oil, pearl flower oil, golden camellia oil, white flower oil, laurel oil, ylang-ylang essential oil, rose essential oil, thyme essential oil, geranium essential oil, Damascus rose essential oil, hawthorn essential oil; (3) Herbal incense: thyme oil, sage oil, shallot oil, basil oil, coriander oil, parsley oil, marjoram oil, geranium oil, mint oil, green garlic oil, Brazilian mint oil, basil oil, herbal oil, olive oil, spice grass oil, fragrant marjoram oil, juniper oil, licorice oil, herbal oil, fragrant wind oil, white lily oil, white chrysanthemum oil, wolfberry oil, fennel oil, laurel oil, fennel oil, garlic oil, perilla oil, thyme oil, coriander essential oil, shallot oil, lily oil, apricot oil, vanilla oil, insect oil Grass oil, sage oil, artichoke oil, wintergreen oil, fine leaf sesame oil, wolfberry oil, pepper oil, sweet artemisia oil, cinnamon oil, asafoetida oil, chive essential oil, purple root oil, mint oil, wild onion oil, gentian oil, yam oil, wormwood oil, aromatherapy oil, thistle oil, mint essential oil, chive flower oil, oregano oil, perfume grass oil, garlic essential oil, white artemisia oil, camphor leaf oil, mushroom oil, purslane oil, vanilla essential oil, verbena essential oil, myrtle essential oil, sandalwood essential oil, cedar essential oil, myrrh essential oil, eucalyptus essential oil; (4) Camphor incense: camphor oil, white camphor oil, black camphor oil, red camphor oil, camphor essential oil, camphor fragrant oil, camphor flower oil, camphor leaf oil, camphor ketone oil, camphor fragrant oil, camphor emulsifiable concentrate, camphor extract oil, camphor grass oil, camphor wood oil, camphor essential oil, camphor alcohol oil, camphor ether oil, camphor ester oil, camphor wood oil, camphor extract oil, camphor fat oil, camphor fruit oil, camphor tree oil, camphor root oil, camphor liquid oil, camphor fruit oil, camphor fiber oil, camphor balm camphor oil, camphor oil, camphor oil, camphor essential oil, camphor smoke oil, camphor gum oil, camphor flower oil, camphor essential oil, camphor fragrant oil, camphor cell oil, camphor resin oil, camphor oil, camphor refined oil, camphor resin oil, camphor wood oil, camphor petroleum oil, camphor essential oil, camphor leaf oil, camphor liquid oil, camphor wood oil, camphor raw oil, camphor spice oil, camphor extract oil, camphor essential oil, camphor bark oil, camphor odor oil, camphor leaf extract oil; (5) Resin incense: frankincense oil, myrrh oil, ambergris oil, frankincense tree oil, pine oil, resin essential oil, pine wood oil, cologne oil, resin extract oil, cedar oil, ancient prescription oil, frankincense gum oil, fragrant resin oil, agarwood oil, myrrh oil, balsam oil, fragrant wood oil, amber oil, ebony oil, fragrant sand oil, Brazilian incense oil, nutmeg oil, fragrant tree root oil, fragrant snow oil, Chinese torreya oil, pine essential oil, pine oil, cypress oil, resin oil, amber oil, resin tree oil, frankincense resin oil, white frankincense oil, black frankincense oil, smokeless incense oil, licorice oil, tree oil, gum oil, golden tree oil, frankincense essential oil, agarwood essential oil, white tree oil, Indian frankincense oil, agarwood oil, natural resin oil, vanilla resin oil, resin oil, natural incense oil, licorice resin oil, white tree oil, natural resin oil, resin extract oil, trunk oil; (6) Woody fragrance: cedar oil, cypress oil, oak oil, mahogany oil, poplar oil, walnut oil, camphor oil, sandalwood essential oil, teak oil, olive oil, red pine oil, teak fragrant oil, vetiver oil, red beech oil, vanilla wood oil, white pine oil, tea tree essential oil.

8. The microcapsule structured agricultural chemical based on protein amyloid aggregates according to any one of claims 1 to 3, characterized in that: The emulsifier is selected from at least one of polyvinyl alcohol, sodium carboxymethyl cellulose, fatty alcohol polyoxyethylene ether, alkylphenol polyoxyethylene polyoxypropylene ether, alkylamine polyoxyethylene ether, hydrogenated castor oil, fatty amide polyoxyethylene ether, Span-20, Span-80, soybean lecithin, beeswax, algin, gelatin, xanthan gum, guar gum, carrageenan, gum arabic, lactose, sodium dodecyl sulfate, sodium dodecylbenzene sulfonate, sodium bisulfate, sulfonated olive oil, sodium salt of fatty acids, sulfonated stearic acid, sodium sulfate, sulfonate, sulfonated ethylene oxide, dodecyltrimethylammonium chloride, alkylamine oxide, ammonium sulfate, ammonium bisulfate, alkylpyridine, titanate, and hexafluorophosphate.

9. The microcapsule structured agricultural chemical based on protein amyloid aggregates according to any one of claims 1 to 3, characterized in that: The agricultural chemical is any one of pesticides, fertilizers, fertilizers, and biostimulants.

10. The microcapsule structured agricultural chemical based on protein amyloid aggregates according to claim 9, characterized in that: The pesticide is selected from any one of insecticides, fungicides, herbicides, rodenticides, plant growth regulators, and biological pesticides; the fertilizer is selected from at least one of organic fertilizers, inorganic fertilizers, organic-inorganic compound fertilizers, and microbial fertilizers; the biostimulant is selected from at least one of microbial biostimulants, protein and amino acid biostimulants, humic acid and fulvic acid biostimulants, plant hormones and plant growth regulators, seaweed extract biostimulants, and sugar alcohol biostimulants.

11. The microcapsule structured agricultural chemical based on protein amyloid aggregates according to any one of claims 1 to 3, characterized in that: The protein, denaturant, emulsifier, plant essential oil, agricultural chemicals and water are evenly mixed to prepare the agricultural chemicals with protein-type amyloid aggregated microcapsule structure; when in use, the agricultural chemicals with protein-type amyloid aggregated microcapsule structure are directly sprayed on the surface of crops or diluted with water and then sprayed on the surface of crops, and the specific dilution multiple is determined according to the use requirements of the agricultural chemicals.

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