Process and device for recovering zinc from hexafluorobutadiene waste liquid

Abstract

The invention belongs to the technical field of fluorine chemical industry, and particularly relates to a process and a device for recovering zinc from hexafluorobutadiene waste liquid. The process for recovering zinc from the hexafluorobutadiene waste liquid comprises the following steps: pretreating the hexafluorobutadiene waste liquid; adding sodium carbonate into the pretreated waste liquid, adjusting the pH value, carrying out a stirring reaction to generate a precipitate, carrying out muddy water washing on filter-pressed filtrate, and drying to obtain a dry zinc carbonate material; adding a zinc carbonate dry material into an electroplating solution preparation kettle containing a zinc sulfate solution, stirring and reacting to obtain the zinc sulfate solution, and pumping the zinc sulfate solution into an electrogalvanizing solution storage tank for later use; and the prepared zinc sulfate solution is pumped into an electroplating bath, and zinc is recycled through electroplating. According to the process for recovering zinc from the hexafluorobutadiene waste liquid, provided by the invention, a production closed loop of a hexafluorobutadiene process is realized, the economic benefit is improved, and environment-friendly production is realized. The invention further provides a device for recovering zinc from the hexafluorobutadiene waste liquid, and the device is simple in structure, high in cyclic utilization rate and high in recovery rate.

Description

Technical Field

[0001] The invention belongs to the technical field of fluorine chemical industry, and specifically relates to a process and a device for recovering zinc from hexafluorobutadiene waste liquid. Background Art

[0002] Hexafluorobutadiene is a new type of fluorine-containing green electronic etching gas with the advantages of fast etching rate, high aspect ratio and high selectivity. It can achieve nearly vertical etching processing, making it possible to manufacture small-volume, large-capacity 3D NAND flash memory. At the same time, hexafluorobutadiene is environmentally friendly and is currently the only fluorine-containing electronic etching gas that has both excellent etching performance and environmental protection performance. Hexafluorobutadiene has better performance than other etching gases, such as nitrogen trifluoride, but its high cost has hindered its market development. Therefore, the cost reduction of hexafluorobutadiene is a topic of concern in the industry.

[0003] CN112499668A discloses a method and device for treating waste liquid containing water-soluble alcohol, zinc chloride and zinc powder, wherein the waste liquid containing water-soluble alcohol, zinc chloride and zinc powder is obtained in the process of preparing hexafluoro-1,3-butadiene by reacting tetrachlorohexafluorobutane and zinc powder, wherein water-soluble alcohol is often used as a solvent to promote the reaction in the preparation process, and the above waste liquid is obtained after the reaction is completed. The treatment process is to first pre-treat and then react with hydrochloric acid to convert zinc powder into a zinc chloride aqueous solution, then evaporate all the zinc chloride through a thin film evaporator, and then effectively separate the waste liquid from the soluble salt and dispose of it. In this method, first pre-treat and then react with hydrochloric acid to mainly convert zinc powder into a zinc chloride aqueous solution. Since zinc powder is relatively active, it reacts violently with hydrochloric acid and produces hydrogen, which is flammable and explosive, bringing new risks. In addition, the water-soluble alcohol used as a solvent is directly used as a waste liquid, which produces more hazardous waste and increases the treatment cost. Summary of the invention

[0004] The technical problem to be solved by the present invention is to overcome the above-mentioned defects of the prior art, provide a process for recovering zinc from hexafluorobutadiene waste liquid, realize the production closed loop of the hexafluorobutadiene process, improve the economic benefits, and realize environmentally friendly production. The present invention also provides a device for recovering zinc from hexafluorobutadiene waste liquid, which has a simple structure, high recycling rate and high recovery rate.

[0005] The process for recovering zinc from hexafluorobutadiene waste liquid of the present invention comprises the following steps: (1) Pre-treating hexafluorobutadiene waste liquid; (2) adding sodium carbonate to the pretreated waste liquid, adjusting the pH to 6-7, stirring the reaction, generating sedimentation, washing the filter mud after filter pressing, and drying to obtain zinc carbonate dry material; (3) Adding dry zinc carbonate to the electroplating solution preparation kettle containing zinc sulfate solution, stirring and reacting to make the zinc ion concentration reach 40-55 g / L, and obtaining zinc sulfate solution, which is pumped into the electroplating zinc solution storage tank for standby use; (4) Pour the prepared zinc sulfate solution into the electroplating tank, set the voltage to 3.1~3.4V, and the current density to 600A / dm 2 , pH = 2, temperature 40 ~ 45 ° C, start electroplating to recover zinc, the cathode of the electroplating tank is nickel-plated, and the zinc sulfate solution containing sulfuric acid overflowing from the anode area is returned to the electroplating solution preparation kettle in step (3) to replenish zinc and then pumped into the electroplating zinc solution storage tank again, and finally enters the electroplating tank for cyclic electroplating.

[0006] The pretreatment step of step (1) comprises: distilling the hexafluorobutadiene waste liquid at 75-85° C., removing the light components at normal pressure, injecting the waste liquid into a reaction kettle after removing the light components, stirring at 40-100 rpm, and maintaining room temperature.

[0007] The light components removed include hexafluorobutadiene, hexafluorocyclobutene, pentafluoropropylene and ethanol.

[0008] Step (2) Stir the reaction for 2 to 3 hours.

[0009] The filter mud after the filter pressing in step (2) is washed with water at a solid-liquid ratio of 1:5, the washing time is 2-2.5 hours, and the drying temperature is 80-100° C. The moisture content of the obtained zinc carbonate dry material is below 2.5wt%.

[0010] The zinc ion concentration of the zinc sulfate solution in the electroplating solution preparation kettle containing the zinc sulfate solution in step (3) is 30-35 g / L; the reaction is stirred for 1.5-2.5 hours.

[0011] A device for recovering zinc from hexafluorobutadiene waste liquid comprises a distillation tower A, a reactor, a filter press A, a water washing kettle, a filter press B, a dryer, an electroplating liquid storage tank, and an electroplating tank. The top of the distillation tower A is connected to an adsorption tower, the bottom of the distillation tower A is connected to the reactor, the reactor is connected to the filter press A, the filter press A is connected to the water washing kettle, the water washing kettle is connected to the filter press B, the filter press B is connected to the dryer, the dryer is connected to a zinc sulfate preparation kettle, the zinc sulfate preparation kettle is connected to the electroplating liquid storage tank, and the electroplating liquid storage tank is connected to the electroplating tank.

[0012] A delivery pump a is provided between the bottom of the distillation tower A and the reactor, a delivery pump b is provided between the reactor and the filter press A, and a delivery pump c is provided between the water washing kettle and the filter press B.

[0013] The filter press A is connected to the distillation tower B. The top of the distillation tower B is provided with a condenser, and the condenser is connected to the ethanol solution storage tank.

[0014] A return pipeline is arranged between the electroplating tank and the zinc sulfate preparation kettle.

[0015] Specifically, the process for recovering zinc from hexafluorobutadiene waste liquid comprises the following steps: (1) Pretreatment of hexafluorobutadiene waste liquid: distill the hexafluorobutadiene waste liquid at 75-85°C, remove the light substances (hexafluorobutadiene, hexafluorocyclobutene, pentafluoropropylene, ethanol) at normal pressure, and then inject it into a reactor after removing the light substances. Start stirring at 40-100 rpm and maintain room temperature.

[0016] (2) Sodium carbonate is added to the pretreated waste liquid to adjust the pH to 6-7. After stirring for 2-3 hours, the stirring is stopped to generate sediment. The valve at the bottom of the reactor is opened to pump the material into the filter press A for filtration separation. The filter mud after filtration is transported to the washing reactor through an auger and washed for 2-2.5 hours at a solid-liquid ratio of 1:5. After washing, the washed material is pumped into the filter press B for filtration separation. The filter mud is dried at a drying temperature of 80-100°C until the water content is below 2.5wt% to obtain zinc carbonate dry material.

[0017] (3) Open the zinc sulfate preparation kettle, add the low-concentration (zinc ion concentration 30-35 g / L) zinc sulfate solution overflowing from the electroplating tank, add zinc carbonate dry material to prepare a zinc sulfate solution with a concentration of 40-55 g / L, and stir to react for 1.5-2.5 hours. After stirring, re-measure the zinc ion concentration. If the concentration is not up to standard, continue to add low-concentration zinc sulfate solution or zinc carbonate dry material to adjust the concentration until the concentration is up to standard. If the concentration is up to standard, pump the material into the electroplating solution storage tank to obtain zinc sulfate solution, which is then pumped into the electro-galvanizing solution storage tank for standby use.

[0018] (4) Pour the prepared zinc sulfate solution into the electroplating tank, set the voltage to 3.1~3.4V, and the current density to 600A / dm 2 , pH=2, temperature 40~45℃, start electroplating to recover zinc, nickel plating at the cathode of the electroplating tank, the zinc sulfate solution containing sulfuric acid overflowing from the anode area returns to the electroplating solution preparation kettle in step (3) to replenish zinc and then enters the electroplating zinc solution storage tank again, and then enters the electroplating tank for cyclic electroplating. The cathode consumes hydroxide, leaving hydrogen ions. After the cathode consumes zinc ions, it combines with the remaining sulfate ions to form sulfuric acid. There is a permeable membrane in the cathode area of ​​the reformed electrolytic cell, which continuously replenishes new electroplating solution. The low-concentration electroplating solution continuously seeps out and overflows through the overflow port of the electroplating tank. The overflow liquid is a low-concentration zinc sulfate solution containing sulfuric acid.

[0019] The hexafluorobutadiene waste liquid described in the present invention is obtained by the following hexafluorobutadiene process route: using chlorotrifluoroethylene as a raw material, generating an ortho-dihalide intermediate 3,4-dichlorohexafluoro-1-butene through a high-temperature addition reaction, and successively obtaining an intermediate (3,4-dichlorohexafluoro-1-butene) with a purity of more than 99% through the process steps of recovering unreacted raw materials, multi-stage distillation separation, etc., and the prepared intermediate (3,4-dichlorohexafluoro-1-butene) undergoes a dehalogenation reaction with zinc powder in a reactor under the condition of using ethanol as a solvent, removing two chlorine atoms and forming a double bond, thereby producing hexafluorobutadiene, and the generated hexafluorobutadiene gas escapes and is collected and purified and separated to obtain the finished hexafluorobutadiene. The liquid remaining after the reaction in the reactor is diluted and dissolved with water and then released, which is the hexafluorobutadiene waste liquid to be treated in the present invention, mainly containing ethanol, zinc chloride, water and a small amount of organic matter (hexafluorobutadiene, hexafluorocyclobutene, pentafluoropropylene, etc.).

[0020] For the above-mentioned zinc-containing waste liquid, the common practice in the industry is to directly outsource the treatment as waste liquid, or to separate the organic matter by distillation, and then collect the distilled ethanol to recover and recycle it as a solvent, and the remaining zinc chloride aqueous solution is outsourced as waste liquid for resource recycling by a third-party enterprise. As a waste liquid outsourcing treatment, it is necessary to spend an additional part of the cost, which increases the production cost of hexafluorobutadiene. The waste liquid of the present invention is first heated to separate the low-boiling impurities from the solution, and the treated solution is added with sodium carbonate to convert zinc into zinc carbonate and precipitate it from the waste liquid. The zinc carbonate is purified and then acidified and electroplated to recover the zinc plate for sale. After distillation, the filtrate is separated from the ethanol solution and the sodium chloride salt, and the recovered ethanol solution is returned to the system for reuse, and the sodium chloride waste salt is entrusted to a hazardous waste unit for treatment.

[0021] Compared with the prior art, the present invention has the following beneficial effects: (1) The process for recovering zinc from hexafluorobutadiene waste liquid of the present invention has a high zinc content and the recovered ethanol can be recycled, thereby reducing the production cost of hexafluorobutadiene, reducing investment, increasing profits and being environmentally friendly.

[0022] (2) The device for recovering zinc from hexafluorobutadiene waste liquid of the present invention has a simple structure, a closed-loop production system, and a high recycling rate. BRIEF DESCRIPTION OF THE DRAWINGS

[0023] Figure 1 The present invention is a schematic diagram of a device for recovering zinc from hexafluorobutadiene waste liquid.

[0024] In the figure: 1. distillation tower A; 2. adsorption tower; 3. reaction kettle; 4. filter press A; 5. distillation tower B; 6. condenser; 7. ethanol solution storage tank; 8. delivery pump a; 9. delivery pump b; 10. water washing kettle; 11. delivery pump c; 12. filter press B; 13. dryer; 14. zinc sulfate preparation kettle; 15. electroplating solution storage tank; 16. electroplating tank. DETAILED DESCRIPTION

[0025] The present invention will be further described below in conjunction with specific embodiments.

[0026] The raw materials and additives used in the following examples are all commercially available products.

[0027] The device for recovering zinc from hexafluorobutadiene waste liquid comprises a distillation tower A1, a reactor 3, a filter press A4, a water washing kettle 10, a filter press B12, a dryer 13, a plating solution storage tank 15, and an electroplating tank 16. The top of the distillation tower A1 is connected to the adsorption tower 2, the bottom of the distillation tower A1 is connected to the reactor 3, the reactor 3 is connected to the filter press A4, the filter press A4 is connected to the water washing kettle 10, the water washing kettle 10 is connected to the filter press B12, the filter press B12 is connected to the dryer 13, the dryer 13 is connected to the zinc sulfate preparation kettle 14, the zinc sulfate preparation kettle 14 is connected to the plating solution storage tank 15, and the plating solution storage tank 15 is connected to the electroplating tank 16.

[0028] A delivery pump a8 is provided between the bottom of the distillation tower A1 and the reactor 3, a delivery pump b9 is provided between the reactor 3 and the filter press A4, and a delivery pump c11 is provided between the water washing tank 10 and the filter press B12.

[0029] The filter press A4 is connected to a distillation tower B5 , a condenser 6 is provided on the top of the distillation tower B5 , and the condenser 6 is connected to an ethanol solution storage tank 7 .

[0030] A return pipeline is provided between the electroplating tank 16 and the zinc sulfate preparation kettle 14 .

[0031] The adsorption tower 2 at the top of the distillation tower A1 of the above device is a tail gas adsorber, which is equipped with activated carbon. The low-boiling organic impurities distilled are adsorbed by the activated carbon and then discharged. In production, it is the tail gas system of the hexafluorobutadiene production device. The distillation tower B5 is used to distill and recover ethanol in the solution. According to the different boiling points of ethanol and water, the ethanol collected by condensation from the distillation tower B5 is recycled and reused in the production of hexafluorobutadiene, and the solution after the ethanol is recovered is used for zinc recovery.

[0032] The components (by mass) in the hexafluorobutadiene waste liquid in the following examples are: 35% ethanol, 34% water, 30% zinc chloride, 0.5% hexafluorobutadiene, 0.2% hexafluorocyclobutene, and 0.3% pentafluoropropylene.

[0033] The following examples were carried out using the above-mentioned apparatus.

[0034] Example 1 The process for recovering zinc from hexafluorobutadiene waste liquid comprises the following steps: (1) Pretreatment of hexafluorobutadiene waste liquid: distill the hexafluorobutadiene waste liquid at 80°C, remove the light fraction at normal pressure, and then inject it into a reactor after removing the light fraction. Turn on the stirring at 70 rpm and maintain room temperature.

[0035] (2) Sodium carbonate was added to the pretreated waste liquid to adjust the pH to 6. After stirring for 2 hours, the stirring was stopped to generate sediment. The valve at the bottom of the reactor was opened to pump the material into the filter press A for filtration separation. The filter mud after filtration was transported to the washing reactor through an auger and washed for 2 hours at a solid-liquid ratio of 1:5. After washing, the washed material was pumped into the filter press B for filtration separation. The filter mud was dried at a drying temperature of 90°C until the water content was below 2.5wt% to obtain zinc carbonate dry material.

[0036] (3) Open the zinc sulfate preparation kettle, add the low-concentration (zinc ion concentration measured by atomic absorption method is 30 g / L) zinc sulfate solution overflowing from the electroplating tank, control the pH to 2, add dry zinc carbonate, stir and react for 2 hours, and measure the zinc ion concentration to be 45 g / L. Pour it into the electroplating zinc solution storage tank for later use.

[0037] (4) Pour the prepared zinc sulfate solution (zinc ion concentration 45g / L) into the electroplating tank, set the voltage to 3.2V and the current density to 600A / dm 2 , pH = 2, temperature 45 ° C, start electroplating to recover zinc (the zinc recovery rate is 93.2%, calculated based on the total amount of zinc powder put into the reaction during the C4F6 production process), nickel is plated at the cathode of the electroplating tank, and the zinc sulfate solution containing sulfuric acid overflowing from the anode area is returned to the electroplating solution preparation kettle in step (3) to replenish zinc and then pumped into the electroplating zinc solution storage tank again, and then enters the electroplating tank for cyclic electroplating.

[0038] Example 2 The process for recovering zinc from hexafluorobutadiene waste liquid comprises the following steps: (1) Pretreatment of hexafluorobutadiene waste liquid: distill the hexafluorobutadiene waste liquid at 75°C, remove the light fraction at normal pressure, and then inject it into a reactor after removing the light fraction. Turn on stirring at 100 rpm and maintain room temperature.

[0039] (2) Sodium carbonate was added to the pretreated waste liquid to adjust the pH to 7. After stirring for 3 hours, the stirring was stopped to generate sediment. The valve at the bottom of the reactor was opened to pump the material into the filter press A for filtration separation. The filter mud after filtration was transported to the washing reactor through an auger and washed for 2.5 hours at a solid-liquid ratio of 1:5. After the washing was completed, the washed material was pumped into the filter press B for filtration separation. The filter mud was dried at a drying temperature of 100°C until the water content was below 2.5wt% to obtain zinc carbonate dry material.

[0040] (3) Open the zinc sulfate preparation kettle, add the low-concentration (zinc ion concentration measured by atomic absorption method is 30.5 g / L) zinc sulfate solution overflowing from the electroplating tank, control the pH to 2, add dry zinc carbonate, stir and react for 1.5 hours, and measure the zinc ion concentration to be 40 g / L. Pour it into the electroplating zinc solution storage tank for later use.

[0041] (4) Pour the prepared zinc sulfate solution (zinc ion concentration 40g / L) into the electroplating tank, set the voltage to 3.1V and the current density to 600A / dm 2 , pH = 2, temperature 40 ° C, start electroplating to recover zinc (the zinc recovery rate is 90.6%, calculated based on the total amount of zinc powder put into the reaction during the C4F6 production process), nickel is plated at the cathode of the electroplating tank, and the zinc sulfate solution containing sulfuric acid overflowing from the anode area is returned to the electroplating solution preparation kettle in step (3) to replenish zinc and then pumped into the electroplating zinc solution storage tank again, and then enters the electroplating tank for cyclic electroplating.

[0042] Example 3 The process for recovering zinc from hexafluorobutadiene waste liquid comprises the following steps: (1) Pretreatment of hexafluorobutadiene waste liquid: distill the hexafluorobutadiene waste liquid at 85°C, remove the light fraction at normal pressure, and then inject it into a reactor after removing the light fraction. Turn on the stirring at 40 rpm and maintain room temperature.

[0043] (2) Sodium carbonate was added to the pretreated waste liquid to adjust the pH to 6. After stirring for 2 hours, the stirring was stopped to generate sediment. The valve at the bottom of the reactor was opened to pump the material into the filter press A for filtration separation. The filter mud after filtration was transported to the washing reactor through an auger and washed for 2 hours at a solid-liquid ratio of 1:5. After washing, the washed material was pumped into the filter press B for filtration separation. The filter mud was dried at 80°C until the water content was below 2.5wt% to obtain zinc carbonate dry material.

[0044] (3) Open the zinc sulfate preparation kettle, add the low-concentration (zinc ion concentration measured by atomic absorption method is 35 g / L) zinc sulfate solution overflowing from the electroplating tank, control the pH to 2, add dry zinc carbonate, stir and react for 2.5 hours, and measure the zinc ion concentration to be 55 g / L. Pour it into the electroplating zinc solution storage tank for later use.

[0045] (4) Pour the prepared zinc sulfate solution (zinc ion concentration 55g / L) into the electroplating tank, set the voltage to 3.4V and the current density to 600A / dm 2 , pH = 2, temperature 45 ° C, start electroplating to recover zinc (the zinc recovery rate is 95.4%, calculated based on the total amount of zinc powder put into the reaction during the C4F6 production process), nickel is plated at the cathode of the electroplating tank, and the zinc sulfate solution containing sulfuric acid overflowing from the anode area is returned to the electroplating solution preparation kettle in step (3) to replenish zinc and then pumped into the electroplating zinc solution storage tank again, and then enters the electroplating tank for cyclic electroplating.

Claims

1. A process for recovering zinc from hexafluorobutadiene waste liquid, characterized in that: The following steps are involved: (1) Pre-treating hexafluorobutadiene waste liquid; (2) adding sodium carbonate to the pretreated waste liquid, adjusting the pH to 6-7, stirring the reaction, generating sedimentation, washing the filter mud after filter pressing, and drying to obtain zinc carbonate dry material; (3) Adding dry zinc carbonate to the electroplating solution preparation kettle containing zinc sulfate solution, stirring and reacting to make the zinc ion concentration reach 40-55 g / L, and obtaining zinc sulfate solution, which is pumped into the electroplating zinc solution storage tank for standby use; (4) Pour the prepared zinc sulfate solution into the electroplating tank, set the voltage to 3.1~3.4V, and the current density to 600A / dm 2 , pH = 2, temperature 40 ~ 45 ° C, start electroplating to recover zinc, the cathode of the electroplating tank is nickel-plated, and the zinc sulfate solution containing sulfuric acid overflowing from the anode area is returned to the electroplating solution preparation kettle in step (3) to replenish zinc and then pumped into the electroplating zinc solution storage tank again, and finally enters the electroplating tank for cyclic electroplating.

2. The process for recovering zinc from hexafluorobutadiene waste liquid according to claim 1, characterized in that: The pretreatment step of step (1) comprises: distilling the hexafluorobutadiene waste liquid at 75-85° C., removing the light components at normal pressure, injecting the waste liquid into a reaction kettle after removing the light components, stirring at 40-100 rpm, and maintaining room temperature.

3. The process for recovering zinc from hexafluorobutadiene waste liquid according to claim 2, characterized in that: The light components removed include hexafluorobutadiene, hexafluorocyclobutene, pentafluoropropylene and ethanol.

4. The process for recovering zinc from hexafluorobutadiene waste liquid according to claim 1, characterized in that: Step (2) Stir the reaction for 2 to 3 hours.

5. The process for recovering zinc from hexafluorobutadiene waste liquid according to claim 1, characterized in that: The filter mud after the filter pressing in step (2) is washed with water at a solid-liquid ratio of 1:5, the washing time is 2-2.5 hours, and the drying temperature is 80-100° C. The moisture content of the obtained zinc carbonate dry material is below 2.5wt%.

6. The process for recovering zinc from hexafluorobutadiene waste liquid according to claim 1, characterized in that: The zinc ion concentration of the zinc sulfate solution in the electroplating solution preparation kettle containing the zinc sulfate solution in step (3) is 30-35 g / L; the reaction is stirred for 1.5-2.5 hours.

7. A device for recovering zinc from hexafluorobutadiene waste liquid according to any one of claims 1 to 6, characterized in that: The invention comprises a distillation tower A (1), a reaction kettle (3), a filter press A (4), a water washing kettle (10), a filter press B (12), a dryer (13), a plating solution storage tank (15), and an electroplating tank (16). The top of the distillation tower A (1) is connected to the adsorption tower (2), the bottom of the distillation tower A (1) is connected to the reaction kettle (3), the reaction kettle (3) is connected to the filter press A (4), the filter press A (4) is connected to the water washing kettle (10), the water washing kettle (10) is connected to the filter press B (12), the filter press B (12) is connected to the dryer (13), the dryer (13) is connected to the zinc sulfate preparation kettle (14), the zinc sulfate preparation kettle (14) is connected to the plating solution storage tank (15), and the plating solution storage tank (15) is connected to the electroplating tank (16).

8. The device for recovering zinc from hexafluorobutadiene waste liquid according to claim 7, characterized in that: A delivery pump a (8) is provided between the bottom of the distillation tower A (1) and the reaction kettle (3), a delivery pump b (9) is provided between the reaction kettle (3) and the filter press A (4), and a delivery pump c (11) is provided between the washing kettle (10) and the filter press B (12).

9. The device for recovering zinc from hexafluorobutadiene waste liquid according to claim 7, characterized in that: The filter press A (4) is connected to a distillation tower B (5), a condenser (6) is provided at the top of the distillation tower B (5), and the condenser (6) is connected to an ethanol solution storage tank (7).

10. The device for recovering zinc from hexafluorobutadiene waste liquid according to claim 7, characterized in that: A return pipeline is provided between the electroplating tank (16) and the zinc sulfate preparation kettle (14).

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