Preparation method and application of conductive corrosion-resistant conversion coating of magnesium alloy

Abstract

The invention discloses a preparation method and application of a magnesium alloy conductive corrosion-resistant conversion coating, and relates to the field of surface treatment. The preparation method comprises the following steps: combining cerium salt and vanadate, adding a complexing agent and an auxiliary film-forming agent to prepare a conversion treatment solution, and soaking a magnesium alloy subjected to polishing and oil removal pretreatment in the conversion treatment solution to prepare the conductive corrosion-resistant coating of the magnesium alloy. According to the preparation method, sodium tetraborate is selected as an auxiliary film-forming agent, the conversion liquid can react at neutral normal temperature by regulating and controlling the reaction time, the concentration of the auxiliary film-forming agent and the ratio of cerium salt to vanadate, and the conductive corrosion-resistant conversion coating is prepared. The preparation method of the conversion coating has the characteristics of simple operation environment, convenience in operation and the like, and the conversion coating prepared by the method has good adhesive force and excellent corrosion resistance, and can retain the excellent conductivity of a matrix. The method is simple in preparation process, low in cost and more suitable for industrial production.

Description

Technical Field

[0001] The invention relates to a preparation method and application of a magnesium alloy conductive corrosion-resistant conversion coating, belonging to the technical field of surface treatment. Background Art

[0002] As an engineering material, magnesium alloy has the advantages of easy processing and recycling, low density, good electromagnetic shielding performance, strong electrical and thermal conductivity, etc. It is widely used in aerospace, military defense, biomedicine, transportation, 3C digital and other fields. However, since the electrode potential of magnesium alloy is -2.731V, the electrochemical activity is extremely active, and it is very easy to generate a loose and porous oxide film in the atmospheric environment, and the micro-galvanic couple formed with the intermetallic compounds on the surface will accelerate its corrosion process. These surface characteristics lead to poor corrosion resistance of magnesium alloy, which limits its application. Therefore, in order to meet the needs of short-term storage of magnesium alloy parts after processing and subsequent processing in production, it is urgent to develop a surface corrosion resistance treatment method with good corrosion resistance and electrical conductivity.

[0003] As an important corrosion protection method, surface modification technology can form a functional barrier layer on the surface of the substrate that isolates corrosive media, thereby improving the corrosion resistance of magnesium alloys and extending their service life. Surface modification technologies for magnesium alloys mainly include chemical conversion films, anodized layers, diffusion coatings, electroplating / chemical plating layers, vapor deposition layers, and organic coatings. Among them, chemical conversion films are widely used as a process that is simple to operate, economical and efficient, does not require special equipment, and is suitable for complex structures and large-sized workpieces.

[0004] At present, many chemical conversion coatings have been developed for magnesium alloy systems, such as chromate system, phosphate system, titanium / molybdenum system, stannate system, rare earth system, molybdate system, vanadate system, etc. The traditional chromate passivation film is mainly composed of chromic anhydride and potassium dichromate, which has excellent corrosion resistance and adhesion, but its use is restricted because hexavalent chromium is harmful to the environment and human body. Although other technologies have overcome the Cr 6+ However, they have different disadvantages. For example, the chemical conversion liquid of the phosphate system is consumed very quickly, the production cost is high, and the wastewater treatment is complicated. Although the stannate system has a low production cost and little pollution, it has the disadvantages of thin film layer and poor corrosion resistance.

[0005] Rare earth conversion film is a hot research field in magnesium alloy surface treatment technology in recent years. It has attracted extensive attention and developed rapidly because of its non-toxic and pollution-free nature. Cerium conversion film is currently the most studied type of rare earth conversion film. For example, CN101469421B discloses a magnesium alloy chemical conversion film film-forming solution composed of high cerium sulfate, sulfuric acid, phytic acid, corrosion inhibitor and buffer. After being treated with the film-forming solution, the conversion film has good adhesion, good corrosion resistance and wear resistance, good paint film adhesion and low resistance. CN108018544A discloses a magnesium alloy rare earth conversion film treating agent, which includes 0.5-60 parts of acid solution, 0.5-80 parts of rare earth salt, 0.5-20 parts of vanadate, 0.5-20 parts of buffer salt, and 0.05-1 parts of dispersant. The appearance and salt spray resistance of the magnesium alloy treated by the treating agent can reach the performance and appearance requirements of the phosphorus-free chromium conversion film in the current industrial production.

[0006] Although the cerium conversion film in the above patent can better meet the requirements of conductivity, corrosion resistance and green environmental protection, the preparation of the conversion film needs to be carried out under acidic conditions and / or high temperature conditions, which will result in the operator having to wear safety gloves or other protective tools during its preparation, and the corrosion resistance of the prepared conversion film cannot fully meet the temperature and pH requirements for short-term storage.

[0007] Therefore, there is an urgent need to explore a method that is simple in process, low in cost and environmentally friendly to solve the above technical problems and make it more suitable for industrial production. Summary of the invention

[0008] In view of the above-mentioned problems, the purpose of the present invention is to provide a magnesium alloy conductive corrosion-resistant conversion coating and a preparation method and application thereof, so as to solve the problems of high temperature and harsh reaction conditions during the formation of the conversion film in the prior art, and to achieve the preparation of a magnesium alloy corrosion-resistant conversion film with high corrosion resistance and conductivity under normal temperature and neutral conditions.

[0009] In view of the above problems, the present invention first provides a magnesium alloy conductive corrosion-resistant conversion coating treatment solution, whose components include cerium salt, vanadate, complexing agent and auxiliary film-forming agent, the auxiliary film-forming agent is borate, and the pH of the treatment solution is 6.5-8.5.

[0010] In one embodiment of the present invention, the mass ratio of the cerium salt to the vanadate is 1:1.5-2.5.

[0011] In one embodiment of the present invention, the cerium salt includes at least one of cerium oxide, cerium chloride and cerium nitrate, preferably cerium nitrate.

[0012] In one embodiment of the present invention, the concentration of the cerium salt in the treatment solution is 3.0-5.0 g / L.

[0013] In one embodiment of the present invention, the vanadate comprises sodium metavanadate and / or ammonium metavanadate, preferably sodium metavanadate.

[0014] In one embodiment of the present invention, the concentration of vanadate in the treatment solution is 5.5-8.5 g / L.

[0015] In one embodiment of the present invention, the complexing agent includes at least one of ethylenediaminetetraacetic acid, disodium ethylenediaminetetraacetate, tetrasodium ethylenediaminetetraacetate, and potassium sodium tartrate.

[0016] In one embodiment of the present invention, in the treatment solution, the concentration of the complexing agent is 10-15 g / L.

[0017] In one embodiment of the present invention, the borate is sodium tetraborate, and in the treatment solution, the concentration of the sodium tetraborate is 4-6 g / L.

[0018] The present invention also provides a method for preparing a magnesium alloy conductive corrosion-resistant conversion coating, comprising the following steps:

[0019] (1) Magnesium alloy pretreatment: After mechanical grinding of the magnesium alloy substrate, it is placed in a solvent for degreasing and deoiling;

[0020] (2) Preparation of conversion coating treatment liquid: cerium salt, vanadate, complexing agent, auxiliary film-forming agent and deionized water are mixed and stirred, and the pH is adjusted to 6.5-8.5 with acid and then allowed to stand to obtain a treatment liquid;

[0021] (3) Preparation of conversion coating: The magnesium alloy substrate pretreated in step (1) is immersed in a treatment solution by soaking, and then dried at room temperature to obtain a magnesium alloy conductive corrosion-resistant conversion coating.

[0022] In one embodiment of the present invention, in step (1), the magnesium alloy substrate is AZ91D magnesium alloy, and the mechanical polishing is polishing with sandpaper.

[0023] In one embodiment of the present invention, in step (1), the solvent is an organic solvent, including acetone or anhydrous ethanol, to ensure that the cleanliness of the surface of the magnesium alloy substrate after pretreatment reaches Sa3 level.

[0024] In one embodiment of the present invention, in step (2), the acid includes at least one of common acids such as hydrochloric acid, nitric acid, oxalic acid, etc., and the standing time is 15-25 minutes.

[0025] In one embodiment of the present invention, in step (2), in the treatment solution, the concentration of cerium salt is 4.0 g / L, the concentration of vanadate is 7.5 g / L, the concentration of complexing agent is 13.5 g / L, and the concentration of borate is 6 g / L.

[0026] In one embodiment of the present invention, in step (3), the soaking temperature is 21-25° C., and the soaking time is 10 to 50 minutes, preferably 20 to 40 minutes.

[0027] In one embodiment of the present invention, in step (3), the drying temperature is 30° C. and the drying time is 10-20 min.

[0028] The present invention also provides a magnesium alloy conductive corrosion-resistant coating prepared according to the above method.

[0029] The invention also discloses an application of the magnesium alloy conductive corrosion-resistant coating in the processing of magnesium alloy parts.

[0030] Beneficial effects of the present invention:

[0031] (1) The present invention prepares a magnesium alloy conductive corrosion-resistant conversion coating and a preparation method thereof. Compared with the prior art, the coating of the present invention has a distinct structure and more controllable specifications, which not only improves the corrosion resistance of the coating, but also has better conductivity.

[0032] (2) The present invention selects cerium salt as the main salt and combines it with vanadate to form a conversion treatment liquid. The cerium salt and vanadate have low corrosion to the magnesium alloy matrix, simple operation, good stability of the prepared conversion liquid, and easy maintenance. The addition of vanadate can not only serve as a pore filler to fill the pores, but also as an oxidant and passivating agent to increase the film generation rate and density.

[0033] (3) By adding sodium tetraborate to the treatment solution containing cerium salt and vanadate, the treatment solution can generate conductive contact spots on the surface of the magnesium alloy under neutral conditions, thereby retaining the original conductive properties of the magnesium alloy. The conversion coating can better bond with the substrate due to its good adhesion to prevent falling off.

[0034] (4) By adjusting the mass ratio of cerium salt to vanadate to 1:1.5-2.5 and the concentration of sodium tetraborate to 4-6 g / L, the conversion coating can be prepared under neutral conditions and room temperature conditions, while ensuring that the prepared conversion coating has good corrosion resistance and conductivity. When the concentration of cerium salt is 4.0 g / L, the concentration of vanadate is 7.5 g / L, the concentration of sodium tetraborate is 6 g / L, and the reaction time is 30 min, the performance of the prepared conversion coating is the best.

[0035] (5) The preparation process of the present invention is simple, the inorganic materials used are pollution-free, environmentally friendly, and low-cost, making it more suitable for industrial production. The conversion coating of the present invention can be prepared under neutral and room temperature conditions. In the actual production process, operators do not need to wear high-temperature and corrosion-resistant gloves to operate, which not only saves resources and reduces costs, but also greatly improves the safety of operation. BRIEF DESCRIPTION OF THE DRAWINGS

[0036] Figure 1 A flow chart of a method for preparing a conductive, corrosion-resistant conversion coating of a magnesium alloy provided in an embodiment of the present invention.

[0037] Figure 2 Surface morphology of the magnesium alloy conductive corrosion-resistant conversion coatings prepared in the control example, comparative example 1 and embodiments 1 to 5.

[0038] Figure 3 The Tafel curves of the magnesium alloy conductive corrosion-resistant conversion coatings prepared in the control example, comparative example 1 and examples 1 to 5 are shown.

[0039] Figure 4 The electrical conductivity diagrams of magnesium alloy conductive corrosion-resistant conversion coatings prepared in the control example, comparative example 1 and embodiments 1 to 5 are shown.

[0040] Figure 5 Surface morphology of the conductive corrosion-resistant conversion coatings of magnesium alloys prepared in the control example, example 3 and examples 6 to 9.

[0041] Figure 6 Tafel curves of magnesium alloy conductive corrosion-resistant conversion coatings prepared in the control example, example 3, and examples 6 to 9.

[0042] Figure 7 The conductivity diagram of the magnesium alloy conductive corrosion-resistant conversion coating prepared in the control example, example 3 and examples 6 to 9.

[0043] Figure 8 Tafel curves of magnesium alloy conductive corrosion-resistant conversion coatings prepared in the control example, examples 1, 3, 5, 6, 9 and examples 10 to 13.

[0044] Fig. 9 The electrical conductivity diagrams of magnesium alloy conductive corrosion-resistant conversion coatings prepared in the control example, examples 1, 3, 5, 6, 9 and examples 10 to 13 are shown. DETAILED DESCRIPTION

[0045] In order to make the above-mentioned objects, features and advantages of the present invention more obvious and easy to understand, the specific implementation methods of the present invention are described in detail below in conjunction with the accompanying drawings.

[0046] In the following description, many specific details are elaborated to facilitate a full understanding of the present invention, but the present invention can also be implemented in other ways different from those described herein, and those skilled in the art can make similar generalizations without violating the connotation of the present invention. Therefore, the present invention is not limited to the specific embodiments disclosed below.

[0047] Secondly, the term "one embodiment" or "embodiment" as used herein refers to a specific feature, structure, or characteristic that may be included in at least one implementation of the present invention. The term "in one embodiment" that appears in different places in this specification does not necessarily refer to the same embodiment, nor does it refer to a separate or selective embodiment that is mutually exclusive with other embodiments.

[0048] Test method:

[0049] In the present invention, a CHI750E electrochemical workstation (EIS, Shanghai Chenhua Instrument Co., Ltd.) was used to study the corrosion resistance of the conductive corrosion-resistant conversion coating. The electrochemical test adopted a traditional three-electrode system, in which the sample to be tested was the working electrode, the saturated calomel electrode was the reference electrode, and the platinum electrode was the counter electrode. The frequency range of the electrochemical workstation was adjusted to 10 -2 Hz to 10 5 Hz, and the wavelength of the sinusoidal AC disturbance is adjusted to 10mA.

[0050] In the present invention, the conductivity is studied by a four-probe tester (SPM, Suzhou Jingge Electronics Co., Ltd.). During the conductivity test (the measured data is the conductivity of the coating and the substrate as a whole), in order to ensure that more accurate data is obtained, 5 test points are randomly selected for each sample, and the conductivity of the sample is the average value of the data.

[0051] Combine the following Figure 1 The present invention is further described with reference to the process in the accompanying drawings, but the present invention is not limited thereto.

[0052] Example 1

[0053] A magnesium alloy conductive corrosion-resistant conversion coating treatment liquid comprises cerium nitrate, sodium metavanadate, disodium ethylenediaminetetraacetate, sodium tetraborate and water, wherein the concentration of cerium nitrate is 4.0 g / L, the concentration of sodium metavanadate is 7.5 g / L, the concentration of disodium ethylenediaminetetraacetate is 13.5 g / L, and the concentration of sodium tetraborate is 2 g / L.

[0054] A method for preparing a magnesium alloy conductive corrosion-resistant conversion coating comprises the following steps:

[0055] (1) Magnesium alloy pretreatment: The surface of the substrate AZ91D magnesium alloy was polished with sandpaper and ultrasonically cleaned with acetone or anhydrous ethanol for 5 min to remove grease and debris on the surface of the sample to ensure that the surface cleanliness of the substrate reached Sa3 level;

[0056] (2) Preparation of conversion coating treatment liquid: cerium salt, vanadate, complexing agent, auxiliary film-forming agent and deionized water are mixed and stirred, and the pH is adjusted to 7.0 with acid and then allowed to stand for 20 minutes to obtain a treatment liquid;

[0057] (3) Preparation of conversion coating: The magnesium alloy substrate pretreated in step (1) is immersed in the treatment solution by immersion, and after immersion at room temperature (21-25°C) for 30 minutes, it is dried in a drying oven at 30°C for 20 minutes to obtain a magnesium alloy conductive corrosion-resistant conversion coating.

[0058] Example 2

[0059] The difference between Example 2 and Example 1 is that the concentration of sodium tetraborate is 4 g / L.

[0060] Example 3

[0061] The difference between Example 3 and Example 1 is that the concentration of sodium tetraborate is 6 g / L.

[0062] Example 4

[0063] The difference between Example 4 and Example 1 is that the concentration of sodium tetraborate is 8 g / L.

[0064] Example 5

[0065] The difference between Example 5 and Example 1 is that the concentration of sodium tetraborate is 10 g / L.

[0066] Comparison Example

[0067] Untreated AZ91D magnesium alloy substrate.

[0068] Comparative Example 1

[0069] The difference between Comparative Example 1 and Example 1 is that sodium tetraborate is not added.

[0070] The concentration of sodium tetraborate is related to the pH value of the conversion solution. In order to enable the conductive corrosion-resistant conversion coating to react under neutral conditions, the reaction time was fixed at 30 minutes, and the conductive corrosion-resistant conversion coating was prepared with 5 gradients of sodium tetraborate concentration ranging from 2g / L to 10g / L. The conductive corrosion-resistant conversion coating prepared in the example was subjected to coating electrochemical test and conductivity test. The results are shown in Table 1 and Figures 2 to 4 shown.

[0071] Table 1 Comparison of the performance of magnesium alloy conductive corrosion resistant coatings in control example, comparative example 1 and examples 1 to 5

[0072]

[0073] from Figure 2 It can be seen from Table 1 that by adding sodium tetraborate to the conversion treatment solution, the conversion treatment solution can generate conductive contact spots under neutral conditions, retaining the original conductive properties of the magnesium alloy. Figures 3-4 It can be found that when the concentration of sodium tetraborate in Example 3 is 6 g / L, J corr The smallest, the best corrosion resistance, and the electrical conductivity compared to the matrix only decreased by 10.56%, basically retaining the conductive properties of magnesium alloy.

[0074] Example 6

[0075] The difference between Example 6 and Example 3 is that in step (3), the soaking time is 10 minutes.

[0076] Example 7

[0077] The difference between Example 7 and Example 3 is that in step (3), the soaking time is 20 minutes.

[0078] Example 8

[0079] The difference between Example 8 and Example 3 is that in step (3), the soaking time is 40 minutes.

[0080] Example 9

[0081] The difference between Example 9 and Example 3 is that in step (3), the soaking time is 50 minutes.

[0082] In the process of forming the conversion coating, not only the concentration of sodium tetraborate affects the performance of the final conversion coating, but also the immersion time. In Examples 6 to 9, the concentration of sodium tetraborate was fixed at 6 g / L, and 5 gradients were taken in the immersion time of 10 min to 50 min to prepare the conductive corrosion-resistant conversion coating. The conductive corrosion-resistant conversion coating prepared in the examples was subjected to coating electrochemical test and conductivity test. The results are shown in Table 2:

[0083] Table 2 Comparison of coating properties

[0084]

[0085] By changing the immersion time, the sample with the best corrosion resistance and conductivity was found. It can be found from Table 2 that when the reaction time is 30 min, J corr The smallest corrosion resistance is the best.

[0086] Example 10

[0087] The difference between Example 10 and Example 1 is that in step (3), the soaking time is 10 minutes.

[0088] Embodiment 11

[0089] The difference between Example 11 and Example 1 is that in step (3), the soaking time is 50 minutes.

[0090] Example 12

[0091] The difference between Example 12 and Example 5 is that in step (3), the soaking time is 10 minutes.

[0092] Embodiment 13

[0093] The difference between Example 13 and Example 5 is that in step (3), the soaking time is 50 minutes.

[0094] Considering that the concentration of sodium tetraborate and the reaction time affect each other on the performance of the conductive corrosion-resistant conversion coating, a comprehensive test was conducted with three gradients of sodium tetraborate concentration and reaction time. The conductive corrosion-resistant conversion coating prepared in the example was subjected to coating electrochemical test and conductivity test. The results are shown in Table 3:

[0095] Table 3 Comparison of coating properties

[0096]

[0097] It can be found from Table 3 that when the sodium tetraborate concentration is 6 g / L and the reaction time is 30 min, J corr The minimum corrosion resistance is the best, and the electrical conductivity of the magnesium alloy is basically retained.

[0098] Embodiment 14

[0099] The difference between Example 14 and Example 3 is that the concentration of sodium metavanadate is adjusted so that the mass ratio of cerium nitrate to sodium metavanadate is 1:1.

[0100] Embodiment 15

[0101] The difference between Example 15 and Example 3 is that the concentration of the complexing agent used is 15 g / L.

[0102] Example 16

[0103] The difference between Example 16 and Example 3 is that the concentration of the complexing agent used is 10 g / L.

[0104] Comparative Example 2

[0105] The difference between Comparative Example 2 and Example 3 is that the concentration of sodium metavanadate is adjusted so that the mass ratio of cerium nitrate to sodium metavanadate is 2:1.

[0106] Comparative Example 3

[0107] The difference between Comparative Example 3 and Example 3 is that the auxiliary film-forming agent used is 6 g / L of stearic acid.

[0108] Comparative Example 4

[0109] The difference between Comparative Example 4 and Example 3 is that the auxiliary film-forming agent used is 6 g / L of sodium dodecylbenzene sulfonate.

[0110] Table 4 Coating performance comparison

[0111]

[0112] Compared with Example 3, Example 14 and Comparative Example 2 found that when the mass ratio of cerium nitrate to sodium metavanadate was 1:1.875, that is, when the concentration of cerium nitrate was 4.0 g / L and the concentration of sodium metavanadate was 7.5 g / L, the corrosion resistance was the best. According to Examples 15 and 16 compared with Example 3, it was found that the concentration of the complexing agent had limited effect on its corrosion resistance when it was 10-15 g / L. According to Comparative Examples 3 and 4 compared with Example 3, it was found that when the auxiliary film-forming agent was sodium tetraborate, the corrosion resistance and conductivity were the best.

[0113] From the above results, it can be seen that after the surface of AZ91D magnesium alloy is modified by the method of the present invention, the corrosion resistance of the obtained coating is greatly improved, and the good electrical conductivity is basically retained, indicating that the present invention successfully prepares the conductive corrosion-resistant conversion coating of magnesium alloy.

[0114] The embodiments provided above are not intended to limit the scope of the present invention, and the steps described are not intended to limit the execution order thereof. Those skilled in the art may make obvious improvements to the present invention in combination with existing common knowledge, which also fall within the scope of protection defined by the claims of the present invention.

Claims

1. A magnesium alloy conductive corrosion-resistant conversion coating treatment solution, characterized in that: The components include cerium salt, vanadate, complexing agent and auxiliary film-forming agent, wherein the auxiliary film-forming agent is borate, and the pH value of the treatment liquid is 6.5-8.

5.

2. The treatment liquid according to claim 1, characterized in that The mass ratio of the cerium salt to the vanadate is 1:1.5-2.

5.

3. The treatment liquid according to claim 1 or 2, characterized in that: The cerium salt includes at least one of cerium oxide, cerium chloride, and cerium nitrate; the vanadate includes sodium metavanadate and / or ammonium metavanadate; and the complexing agent includes at least one of ethylenediaminetetraacetic acid, disodium ethylenediaminetetraacetate, tetrasodium ethylenediaminetetraacetate, and potassium sodium tartrate.

4. The treatment liquid according to claim 1, characterized in that In the treatment solution, the concentration of the cerium salt is 3.0-5.0 g / L, the concentration of the vanadate is 5.5-8.5 g / L, and the concentration of the complexing agent is 10-15 g / L.

5. The treatment liquid according to claim 1, characterized in that The borate is sodium tetraborate. In the treatment solution, the concentration of the sodium tetraborate is 4-6 g / L.

6. A method for preparing a magnesium alloy conductive corrosion-resistant conversion coating, characterized in that: The following steps are involved: (1) Magnesium alloy pretreatment: After mechanical grinding of the magnesium alloy substrate, it is placed in a solvent for degreasing and deoiling; (2) Preparation of the conversion coating treatment liquid: cerium salt, vanadate, complexing agent, auxiliary film-forming agent and deionized water are mixed and stirred, and the pH is adjusted to 6.5-8.5 with acid and then allowed to stand to obtain the magnesium alloy conductive corrosion-resistant conversion coating treatment liquid according to any one of claims 1 to 5; (3) Preparation of conversion coating: The magnesium alloy substrate pretreated in step (1) is immersed in the treatment solution of step (2) by soaking, and then dried at room temperature to obtain a magnesium alloy conductive corrosion-resistant conversion coating.

7. The preparation method according to claim 6, characterized in that: In step (1), the magnesium alloy substrate is AZ91D magnesium alloy, the mechanical polishing is polishing with sandpaper, the solvent is an organic solvent, including acetone or anhydrous ethanol, and after degreasing and deoiling, the cleanliness of the surface of the magnesium alloy substrate is ensured to reach Sa3 level.

8. The preparation method according to claim 6, characterized in that: In step (2), the acid includes at least one of common acids such as hydrochloric acid, nitric acid, oxalic acid, etc., and the standing time is 15-25 minutes.

9. The preparation method according to claim 6, characterized in that: In step (3), the soaking temperature is 21-25°C, the soaking time is 10-50 minutes, the drying temperature is 30°C, and the drying time is 10-20 minutes.

10. A magnesium alloy conductive corrosion-resistant coating prepared according to the method of any one of claims 6 to 9.

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