Purifier for hydrogen sulfide gas
By designing a multi-stage purification hydrogen sulfide gas purifier, using the combination technology of absorbing liquid, electrocatalytic regenerator and atomizing nozzle, the problem of poor purification effect of hydrogen sulfide gas in the prior art is solved, and an efficient multi-stage purification effect is achieved.
Patent Information
- Application Number
- CN202421021545.6
- Authority / Receiving Office
- CN · China
- Patent Type
- Utility models(China)
- Current Assignee / Owner
- Filing Date
- 2024-05-10
- Publication Date
- 2025-03-21
- Estimated Expiration
- 2034-05-10
AI Technical Summary
The existing hydrogen sulfide gas purifiers fail to effectively purify various substances in the hydrogen sulfide gas, resulting in poor purification effect.
A purifier including an adsorption chamber, a separation chamber and a dust reduction chamber are designed, and the hydrogen sulfide gas is purified by multi-stage use of the absorbent liquid in the storage box and an electrocatalytic regenerator, and the copper sulfate solution is sprayed into the dust reduction chamber through an atomization spray head for secondary purification.
Multi-stage purification of hydrogen sulfide gas is achieved, the purification effect is improved, the safe emission of gas is ensured, and the practicality of the purifier is improved.
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Figure CN222641661U_ABST
Abstract
Description
Technical Field
[0001] The utility model relates to the technical field of hydrogen sulfide, in particular to a purifier for hydrogen sulfide gas. Background Art
[0002] Hydrogen sulfide is an inorganic compound with the chemical formula H2S and a molecular weight of 34.076. It is a flammable acidic gas under standard conditions. It is colorless and has the smell of rotten eggs at low concentrations. It has the smell of sulfur at extremely low concentrations and is highly toxic. Its aqueous solution is hydrosulfuric acid, which is weaker in acidity, weaker than carbonic acid, but stronger than boric acid. It is soluble in water and easily soluble in alcohols, petroleum solvents and crude oil.
[0003] After searching, it is proposed in a hydrogen sulfide gas detection alarm system with patent publication number CN218546699U that "the utility model relates to the field of hydrogen sulfide detection technology. The hydrogen sulfide gas detection alarm system is equipped with two hydrogen sulfide detectors. The first hydrogen sulfide detector is mainly used to detect hydrogen sulfide in the sampled gas, and then the sampled gas will be purified through the water tank and the air filter box so that the discharged gas will not pollute the atmosphere. The second hydrogen sulfide detector detects the exhaust gas. Once the exhaust gas hydrogen sulfide exceeds the standard, an alarm will be sounded to notify the staff to replace the filter liquid and filter element in the water tank to prevent air pollution."
[0004] However, the above scheme still has certain shortcomings in actual use. In this scheme, only a water tank and an air filter box are used to purify the hydrogen sulfide gas, and each substance in the hydrogen sulfide gas is not purified, resulting in a significant reduction in the purification effect of the hydrogen sulfide gas. Utility Model Content
[0005] The utility model provides a purifier for hydrogen sulfide gas to solve the problems in the background technology.
[0006] To achieve the above-mentioned purpose, the utility model provides the following technical solutions: a purifier for hydrogen sulfide gas, comprising a purification box, the interior of which is divided into an adsorption chamber, a separation chamber and a dust reduction chamber by two partitions;
[0007] The inner wall of the adsorption chamber is movably connected with an adsorption net through a socket, a connecting pipe is fixedly installed at the bottom of the inner wall of the adsorption chamber, and a storage box is movably connected with the bottom of the purification box, and the interior of the storage box is injected with absorption liquid;
[0008] A gas-liquid separation layer is fixedly installed on the inner wall of the separation chamber, an electrocatalytic regenerator is fixedly installed on the bottom end of the gas-liquid separation layer, an extraction pump is fixedly installed on the bottom end of the electrocatalytic regenerator, and the extraction pump is connected to the inside of the storage box;
[0009] A mounting recess is provided at the bottom of the dust reduction chamber, and a waste residue box is movably connected to the mounting recess through a rotating pin. A water storage tank is fixedly installed on the top of the purification box, and copper sulfate solution is injected into the water storage tank. A diversion pipe is fixedly installed on the bottom end of the water storage tank through a water pump, and the water outlet end of the diversion pipe is located inside the purification box and fixedly installed with an atomizing nozzle.
[0010] Furthermore, the top of the purification box is fixedly connected with an air inlet pipe through an air pump, and a front plate is fixedly installed on the front side of the purification box.
[0011] Furthermore, an exhaust fan is fixedly installed inside the front plate, and a dustproof net is arranged on the outer side of the exhaust fan.
[0012] Furthermore, the bottom end of the connecting pipe extends below the liquid level of the storage box, and the bottom of the inner wall of the separation chamber is connected to the storage box.
[0013] Furthermore, a baffle is fixedly mounted on the inner wall of the dust reduction chamber, and the electrocatalytic regenerator is located in a cavity formed between the baffle and the dust reduction chamber.
[0014] Compared with the prior art, the utility model provides a purifier for hydrogen sulfide gas, which has the following beneficial effects:
[0015] 1. The hydrogen sulfide gas purifier is provided with a storage box, an electrocatalytic regenerator and a gas-liquid separation layer, and uses the absorption liquid in the storage box to react with the hydrogen sulfide gas, thereby absorbing the hydrogen sulfide and stabilizing it into a mixed liquid, and then cooperates with an extraction pump to pump the mixed liquid into the electrocatalytic regenerator for electrocatalytic regeneration reaction, so that the hydrogen sulfide in the mixed liquid is oxidized into sulfate, and finally the gas-liquid separation layer can separate the mixed liquid into gas and liquid, so that the separated electrocatalytic mixed liquid falls into the storage box again to achieve recycling and reuse, so that the hydrogen sulfide gas is purified in multiple stages.
[0016] 2. The hydrogen sulfide gas purifier is provided with a waste residue box, a water storage tank and an atomizing nozzle. The copper sulfate solution in the water storage tank can be sprayed in the dust reduction chamber in the form of mist by the atomizing nozzle, so that the copper sulfate solution will form copper sulfide which is insoluble in general strong acid when reacting with the hydrogen sulfide gas after preliminary purification, and finally fall into the waste residue box and wait for recovery by the staff, so that the hydrogen sulfide gas is secondary purified, thereby further improving the practicality of the purifier. BRIEF DESCRIPTION OF THE DRAWINGS
[0017] Figure 1 It is a schematic diagram of the structure of the utility model;
[0018] Figure 2 It is a schematic diagram of the structure of the utility model;
[0019] Figure 3 for Figure 1 A magnified view of the structure at center;
[0020] Figure 4 for Figure 1 Enlarged view of the structure at point B in the middle.
[0021] In the figure: 1. purification box; 2. air inlet pipe; 3. adsorption chamber; 301. socket; 302. adsorption net; 303. connecting pipe; 304. storage box; 305. extraction pump; 306. electrocatalytic regenerator; 4. separation chamber; 5. dust reduction chamber; 501. baffle; 502. installation notch; 503. rotating pin; 504. waste residue box; 505. water storage tank; 506. diverter pipe; 507. atomizing nozzle; 6. front plate; 601. outlet fan; 602. dust net; 7. gas-liquid separation layer. DETAILED DESCRIPTION
[0022] The following will be combined with the drawings in the embodiments of the utility model to clearly and completely describe the technical solutions in the embodiments of the utility model. Obviously, the described embodiments are only part of the embodiments of the utility model, not all of the embodiments. Based on the embodiments in the utility model, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the utility model.
[0023] See also Figure 1-4 The utility model discloses a purifier for hydrogen sulfide gas, including a purification box 1, the top of which is fixedly connected to an air inlet pipe 2 through an air pump, a front plate 6 is fixedly installed on the front side of the purification box 1, and the interior of the purification box 1 is divided into an adsorption chamber 3, a separation chamber 4 and a dust reduction chamber 5 by two partitions.
[0024] The inner wall of the adsorption chamber 3 is movably connected with an adsorption net 302 through a socket 301, a connecting pipe 303 is fixedly installed at the bottom of the inner wall of the adsorption chamber 3, and a storage box 304 is movably connected to the bottom of the purification box 1, and the storage box 304 is injected with absorption liquid.
[0025] A gas-liquid separation layer 7 is fixedly installed on the inner wall of the separation chamber 4 , an electrocatalytic regenerator 306 is fixedly installed on the bottom end of the gas-liquid separation layer 7 , an extraction pump 305 is fixedly installed on the bottom end of the electrocatalytic regenerator 306 , and the extraction pump 305 is connected to the interior of the storage box 304 .
[0026] By setting up a storage box 304, an electrocatalytic regenerator 306 and a gas-liquid separation layer 7, the absorption liquid in the storage box 304 is used to react with the hydrogen sulfide gas, thereby absorbing the hydrogen sulfide and stabilizing it into a mixed liquid, and then the extraction pump 305 is used to pump the mixed liquid into the electrocatalytic regenerator 306 for electrocatalytic regeneration reaction, so that the hydrogen sulfide in the mixed liquid is oxidized into sulfate, and finally the gas-liquid separation layer 7 can separate the mixed liquid into gas and liquid, so that the separated electrocatalyzed mixed liquid falls into the storage box 304 again, thereby realizing recycling and repeated utilization, so that the hydrogen sulfide gas undergoes multi-stage purification.
[0027] The reaction principle of the absorption liquid in the storage box 304, the electrocatalytic regenerator 306 and the gas-liquid separation layer 7 has been described in detail in a hydrogen sulfide gas purification system of patent publication number CN218741204U, and will not be further elaborated here.
[0028] A mounting recess 502 is provided at the bottom of the dust reduction chamber 5, and a waste residue box 504 is movably connected to the mounting recess 502 through a rotating pin 503. A water tank 505 is fixedly installed at the top of the purification box 1, and a copper sulfate solution is injected into the water tank 505. A shunt pipe 506 is fixedly installed at the bottom of the water tank 505 through a water pump. The water outlet end of the shunt pipe 506 is located inside the purification box 1 and is fixedly installed with an atomizing nozzle 507.
[0029] The reaction principle of copper sulfate solution has been described in detail in a hydrogen sulfide absorption device with patent publication number CN202321099028.6, and will not be further elaborated here.
[0030] By setting up a waste residue box 504, a water storage tank 505 and an atomizing nozzle 507, the copper sulfate solution in the water storage tank 505 can be sprayed in the dust reduction chamber 5 in the form of mist using the atomizing nozzle 507, so that the copper sulfate solution will form copper sulfide that is insoluble in general strong acids when reacting with the hydrogen sulfide gas that has been initially purified, and finally fall into the waste residue box 504 and wait for recovery by the staff, so that the hydrogen sulfide gas is subjected to secondary purification, thereby further improving the practicality of the purifier.
[0031] Specifically, an exhaust fan 601 is fixedly installed inside the front plate 6 , and a dustproof net 602 is arranged on the outer side of the exhaust fan 601 .
[0032] In this embodiment, the gas after the purification operation is finally discharged from the purification box 1 under the drive of the outlet fan 601, and the outlet fan 601 can be dust-proofed by using the dust-proof net 602.
[0033] Specifically, the bottom end of the connecting pipe 303 extends below the liquid level of the storage box 304 , and the bottom of the inner wall of the separation chamber 4 is connected to the storage box 304 .
[0034] In this embodiment, hydrogen sulfide gas is introduced into the storage box 304 below the liquid level through the connecting pipe 303, and the mixed liquid after separation and electrocatalysis falls into the storage box 304 again to achieve recycling and reuse.
[0035] Specifically, a baffle 501 is fixedly installed on the inner wall of the dust reduction chamber 5 , and the electrocatalytic regenerator 306 is located in a cavity formed between the baffle 501 and the dust reduction chamber 5 .
[0036] In this embodiment, the baffle 501 can be used to protect the electrocatalytic regenerator 306 , thereby preventing the copper sulfate solution from contacting the electrocatalytic regenerator 306 and causing damage to the electrocatalytic regenerator 306 .
[0037] When in use, the hydrogen sulfide gas is first introduced into the adsorption chamber 3 through the air inlet pipe 2, and the hydrogen sulfide gas is forced to pass through multiple adsorption nets 302, so that the adsorption nets 302 filter and adsorb impurities in the hydrogen sulfide gas, and then the hydrogen sulfide gas is introduced into the storage box 304 below the liquid level through the connecting pipe 303, and the storage box 304 is injected with an absorption liquid containing sodium hydroxide, sodium chloride and oxygen-rich ion water, which will react with the hydrogen sulfide gas, and then the extraction pump 305 is started, so that the extraction pump 305 draws the mixed liquid formed by the reaction of the absorption liquid and hydrogen sulfide in the storage box 304 into the electrocatalytic regenerator 306, so that the electrocatalytic regenerator 306 performs an electrocatalytic regeneration reaction on the mixed liquid, and promotes the hydrogen sulfide in the mixed liquid to oxidize into sulfate, and then these substances enter the gas-liquid separation layer 7 for gas-liquid separation, and the purified gas will enter the dust reduction chamber 5, and the mixed liquid after separation of electrocatalysis will fall into the storage box 304 again to achieve recycling and reuse;
[0038] Then, the water tank 505 is opened, and the water tank 505 is prompted to inject the copper sulfate solution into the interior of the atomizing nozzle 507 through the shunt pipe 506 through the water pump arranged at the bottom thereof. Then, the atomizing nozzle 507 can spray the copper sulfate solution in the water tank 505 into the dust reduction chamber 5 in the form of mist, so that the copper sulfate solution will form copper sulfide which is insoluble in general strong acid when reacting with the preliminarily purified hydrogen sulfide gas, and finally fall into the waste residue box 504 and wait for the staff to recycle it;
[0039] When the waste box 504 needs to be disassembled, the rotating pin 503 needs to be rotated in advance so that the rotating pin 503 and the waste box 504 are released from the overlapping state, so that the splicing state between the waste box 504 and the installation recess 502 is released. Then the staff can remove the waste box 504 from the opening of the installation recess 502 and recycle the waste inside the waste box 504.
[0040] The gas after the above purification operation is finally discharged from the purification box 1 under the drive of the outlet fan 601.
[0041] In summary, the hydrogen sulfide gas purifier is provided with a storage box 304, an electrocatalytic regenerator 306 and a gas-liquid separation layer 7, and uses the absorption liquid in the storage box 304 to react with the hydrogen sulfide gas, thereby absorbing hydrogen sulfide and stabilizing it into a mixed liquid, and then cooperates with the extraction pump 305 to pump the mixed liquid into the electrocatalytic regenerator 306 for electrocatalytic regeneration reaction, so that the hydrogen sulfide in the mixed liquid is oxidized into sulfate, and finally the gas-liquid separation layer 7 can perform gas-liquid separation on the mixed liquid, so that the separated electrocatalytic mixed liquid falls into the storage box 304 again, thereby Realize recycling and reuse, so that the hydrogen sulfide gas undergoes multi-stage purification; by setting up a waste slag box 504, a water tank 505 and an atomizing nozzle 507, the copper sulfate solution in the water tank 505 can be sprayed in the dust reduction chamber 5 in the form of mist using the atomizing nozzle 507, so that the copper sulfate solution will form copper sulfide that is insoluble in general strong acid when reacting with the hydrogen sulfide gas after preliminary purification, and finally fall into the waste slag box 504 and wait for the staff to recycle it, so that the hydrogen sulfide gas is purified at the second level, thereby further improving the practicality of the purifier.
[0042] Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and variations may be made to the embodiments without departing from the principles and spirit of the present invention, and that the scope of the present invention is defined by the appended claims and their equivalents.
Claims
1. A purifier for hydrogen sulfide gas, comprising a purification box (1), characterized in that: The interior of the purification box (1) is divided into an adsorption chamber (3), a separation chamber (4) and a dust reduction chamber (5) by two partitions; The inner wall of the adsorption chamber (3) is movably connected to an adsorption net (302) via a plug socket (301); a connecting pipe (303) is fixedly installed at the bottom of the inner wall of the adsorption chamber (3); a storage box (304) is movably connected to the bottom of the purification box (1); and an absorption liquid is injected into the storage box (304); A gas-liquid separation layer (7) is fixedly mounted on the inner wall of the separation chamber (4), an electrocatalytic regenerator (306) is fixedly mounted on the bottom end of the gas-liquid separation layer (7), an extraction pump (305) is fixedly mounted on the bottom end of the electrocatalytic regenerator (306), and the extraction pump (305) is connected to the interior of the storage box (304); The bottom of the dust reduction chamber (5) is provided with an installation recess (502), and the installation recess (502) is movably connected to a waste residue box (504) via a rotating pin (503). A water storage tank (505) is fixedly installed on the top of the purification box (1), and a copper sulfate solution is injected into the interior of the water storage tank (505). A shunt pipe (506) is fixedly installed at the bottom of the water storage tank (505) via a water pump. The water outlet end of the shunt pipe (506) is located inside the purification box (1) and is fixedly installed with an atomizing nozzle (507).
2. A hydrogen sulfide gas purifier according to claim 1, characterized in that: The top of the purification box (1) is fixedly connected to an air inlet pipe (2) via an air pump, and a front plate (6) is fixedly installed on the front side of the purification box (1).
3. A hydrogen sulfide gas purifier according to claim 2, characterized in that: An exhaust fan (601) is fixedly installed inside the front plate (6), and a dustproof net (602) is arranged on the outside of the exhaust fan (601).
4. A purifier for hydrogen sulfide gas according to claim 1, characterized in that: The bottom end of the connecting pipe (303) extends below the liquid level of the storage box (304), and the bottom of the inner wall of the separation chamber (4) is connected to the storage box (304).
5. A hydrogen sulfide gas purifier according to claim 1, characterized in that: A baffle (501) is fixedly mounted on the inner wall of the dust reduction chamber (5), and the electrocatalytic regenerator (306) is located in a cavity formed between the baffle (501) and the dust reduction chamber (5).
Citation Information
Patent Citations
Hydrogen sulfide gas detection alarm system
CN218546699U
Hydrogen sulfide gas purification system
CN218741204U
Hydrogen sulfide absorption device
CN220090972U