Method and equipment for recycling polystyrene-based materials containing organic halogen flame retardants into styrene and other valuables and / or energy

Abstract

A method and equipment for recycling polystyrene-based materials are provided. [Solution] A method for recycling a polystyrenic material containing an organic halogen flame retardant, comprising: (i) dissolving the polystyrenic material in a high-boiling point non-polar organic reaction solvent; (ii) heating the polystyrene contained in the reaction solvent to a temperature that releases a halogen from the flame retardant; (iii) contacting the released halogen with a base to form a halogen residue; (iv) removing the halogen residue; (v) pyrolyzing the polystyrene contained in the reaction solvent at a temperature that depolymerizes the polystyrene; and (vi) distilling the depolymerized mixture into at least a styrene fraction. The method and equipment therefor.

Description

[Technical field]

[0001] The present invention relates to a method and plant for recycling polystyrenic materials containing organohalogen flame retardants into styrene and other values ​​and / or energy. [Background technology]

[0002] Polystyrenic materials are polystyrene, expanded polystyrene (EPS), extruded polystyrene (XPS), e.g. those used and / or in combination in packaging foils and containers, styrene-butadiene rubber (SBR), and acrylonitrile-butadiene-styrene (ABS). These materials may come from renovation construction elements, which include (expanded) polystyrene cores and polyolefin foils, or from electrical and electronic fittings, which today have short product life cycles.

[0003] These polystyrene-based materials contain flame retardants that are activated under ignition conditions, e.g., under fire or heat, and are intended to prevent or slow the ignition or spread of fire. When polystyrene containing flame retardants is recycled, the flame retardants must be removed in such a way that they do not enter the environment. This is especially so with regard to organic halogen flame retardants, examples of which are organic bromine flame retardants (organobrominated flame retardants), such as hexabromocyclododecane (HBCD), tetrabromobisphenol A (2,3-dibromopropyl) ether (BDDP or FR-720), tris(tribromophenoxy)triazine (FR-245), tetrabromobisphenol-A-bis(2,3-dibromo-2-methylpropyl ether, 1,1'-(isopropylidene)bis[3,5-dibromo-4-(2,3-dibromo-2-methylpropoxy)benzene] (TBBPA-DBMPE or AP 1300). SF), block copolymer of polystyrene and brominated polybutadiene (FR-122P), organochlorine flame retardants such as tris(1-chloro-2-propyl)phosphate (TCPP) and polyvinyl chloride (PVC), and organofluorine flame retardants such as tetradecafluorohexane (TDFH). Expanded polystyrene-based materials contain Freon, which is used as a blowing agent. It is an organofluorinated compound, such as hydrochlorofluorocarbons (HCFCs, e.g. R-22, R-12, and R134a).

[0004] From the prior art, several methods are known for removing bromine from styrene polymers containing brominated flame retardants. Grause et al., Degradation and Stability, 112, 86-93, 2015, used a solution of NaOH in ethylene glycol to remove decabromodiphenylethane (DBPE) from high impact polystyrene. The debromination ratio was 42% at 190°C. This ratio was reduced by mechanical treatment using a ball mill reactor to about 0.02 wt%. Ukisu, Chemosphere, 179, 179-184, 2017, investigated the catalytic debromination of HBCD using a silica-supported palladium catalyst in a 2-propanol / methanol solution containing dissolved NaOH at 35°C. The yield of the reaction product was 92% with respect to the bromine-free material. Evangelopoulos et al., Waste Management, 94, 165-171, 2019, investigated the removal of tetrabromobisphenol (TBBPA) from brominated plastics, modem Wi-Fi plastics, and printed circuit boards using solvent extraction with isopropanol or toluene followed by pyrolysis. The extent of removal of the brominated compounds was reported to be relatively low. Wang et al., J. Hazardous Materials, 205-206, 156-163, (2012), investigated the debromination of ABS containing TBBPA. Water, methanol, isopropanol, and acetone were used under supercritical conditions (400 °C, 9-19 MPa). Water showed the highest debromination efficiency (97.6%). An alkali was added to supercritical isopropanol, and a salt was formed that dissolved in the supercritical alcohol and precipitated under ambient conditions. The use of NaOH and KOH resulted in a bromine yield of about 5 wt% in the treated article. Dement´ev et al., J. Anal. Appl. Pyrolysis, 142, pp. 1-10, 2019, investigated the thermal depolymerization of polystyrene in highly aromatic hydrocarbons. At 500°C, the styrene yield was 84.4% at a polymer conversion of 93.8%. Summary of the Invention [Problem to be solved by the invention]

[0005] The present invention has as its object the recycling of polystyrenic materials, providing high purity styrene that can be used as virgin or added styrene monomer and other articles that are useful for sale or for reuse in the process, while producing minimal by-products and without the formation of halogenated hydrocarbons, such as PCBs and PBBs. Moreover, the dehalogenation process is carried out under mild conditions (mild temperatures and atmospheric pressure), in a basic organic environment, without catalysts and in conventional reaction vessels. The present invention therefore aims to provide a method and an apparatus for carrying out the method, in which all reactions are carried out in the liquid phase, preferably or mainly with the solvent that is released during the carrying out of the method, which is the compound resulting from the method according to the invention. The materials used and the reaction conditions applied are such that it is not necessary to operate the compression part of the apparatus, in particular on-site, under ATEX conditions, since no explosive atmosphere is generated. Also, with regard to the transport of materials and intermediate products (e.g. compressed polystyrene), they fall under the lowest classification of ADR (Accord europeen relative au transport international des marchandises Dangereouses par Route).

[0006] It should be understood that the present invention can recycle a variety of different polystyrenic materials, such as packaging, e.g. yoghurt cups or bowls, and / or building materials. In particular with respect to expanded, foamed and extruded materials, the compression is not thermal and / or chemical compression. Thus, the method according to the present invention can be used with mechanically and / or thermally and / or chemically compressed materials. [Means for solving the problem]

[0007] In accordance with this object, the present invention provides a method for recycling polystyrenic materials containing organohalogen flame retardants, the method comprising the steps of: (i) dissolving a polystyrene-based material in a high boiling point non-polar organic reaction solvent; (ii) heating the polystyrene contained in a reaction solvent to a temperature that causes the release of halogen compounds from the flame retardant; (iii) contacting the released halogen compound with a base to form a halogen residue; (iv) removing halogen residues; (v) pyrolyzing the polystyrene contained in the reaction solvent at a temperature that depolymerizes the polystyrene; and (vi) distilling the depolymerized mixture into at least a styrene fraction. [Brief description of the drawings]

[0008] [Figure 1] FIG. 1 is a diagram of the basic process and equipment of the present invention, including a removal step or unit for removing flame retardants from polystyrenic materials, a pyrolysis step or unit, and a distillation step or unit for providing styrene by distillation. [Diagram 2] FIG. 2 is a diagram of a method and installation of the present invention which, in addition to the method and installation of FIG. 1, includes a compression step or unit for compressing the expanded polystyrene, and a step or unit for replacing the compression solvent with reaction solvent, both of which are preferably recycled. [Diagram 3] FIG. 3 is a process flow diagram showing the compression unit in more detail. [Figure 4] FIG. 4 is a process flow diagram of an alternative compression unit. [Diagram 5] FIG. 5 is a process flow diagram of further details of an apparatus of the invention for carrying out the method of the invention. [Figure 6] FIG. 6 is further detail of a unit for replacing at least a portion of the compressed solvent by the reaction solvent. [Figure 7]FIG. 7 is further detail of a unit for purifying compressed solvent. [Figure 8] FIG. 8 shows further details of the heating or dehalogenation unit. [Figure 9] FIG. 9 provides further details of the pyrolysis. [Figure 10] FIG. 10 shows further details of the cooling unit for reducing the solvent temperature after pyrolysis. [Figure 11] FIG. 11 is further detail of the distillation unit for providing distillation fractions for styrene, and compression and reaction solvents. [Figure 12] FIG. 12 shows a stripping unit (stripper unit) for purifying compressed solvent. [Figure 13] FIG. 13 is a side view of a molten bed reactor used in the method and system of the present invention. [Figure 13A] FIG. 13A is a cross section taken along line AA' in FIG. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0009] The process of the invention comprises the dissolution of polystyrene containing an organic halogen flame retardant and possible foreign plastics in a high-boiling reaction solvent, from which the halogens present in the flame retardant compounds are released as halogen compounds. The halogen compounds are captured by a base and removed as halogen residues. The dehalogenated polystyrene present in the reaction solvent is then pyrolyzed and depolymerized to at least styrene. The styrene contains a minimum amount of residual organic halogen flame retardant and any halogen compounds and is suitable for use as virgin monomer or additional styrene monomer. The use of a high-boiling reaction solvent in all process steps allows operation under non-ATEX conditions, especially on-site, during compaction, and allows handling and routing of products and intermediate products under the lowest ADR conditions. In one embodiment of the invention, the halogen compounds released from the flame retardant may be recovered from the reaction solvent and separated from the solvent by contacting with a base, thereby forming halogen residues, for example halogen salts and / or halogen-containing gases. Under these circumstances, practically any base capable of forming such halogen salts may be used. In a preferred embodiment, a base is added to the reaction solvent, whereby the halogen compounds released in step (ii) are contacted with the base in step (iii), whereby halogen residues are formed in the reaction solvent. Preferably, the halogen residues are halogen salts and / or halogen-containing gases. For example, the halogen-containing gas can be hydrogen bromide. This means that the base is present in the reaction solvent during the heating step when the halogen compounds are released from the flame retardant or organic halogen containing freon. The released halogen compounds are then captured and converted into halogen residues, for example into halogen salts and / or halogen-containing gases, which can be easily removed from the reaction solvent as a solid and / or as a gas. Thus, no halogen compounds in the form of corrosive substances, for example those in the form of halogen acids, are present in the reaction solvent or are present in the reaction solvent only for a short time, and therefore there is no need to use corrosion-resistant materials for the equipment.Furthermore, under the heating conditions of step (ii) and during the subsequent pyrolysis step (v), no halogen compounds are present, thus avoiding any side reactions of halogen compounds with the solvent or the depolymerization products.

[0010] Particularly preferably, the base added to the non-polar organic reaction solvent is dissolved therein, so that the reaction with the halogen proceeds optimally in the liquid phase, which facilitates the removal of halogen residues, such as halogen salts and / or halogen-containing gases. Furthermore, this avoids any side streams, such as water and polar (organic) solvents containing the base. Thus, the base used to form the halogen salt in the reaction solvent is selected from the group comprising sodium diamine, potassium tert-butoxide (KotBu), sodium bis(trimethylsilyl)amide, and P(CH3NCH2CH2)3N. These selected bases are soluble in the reaction solvent. Small amounts of volatiles formed may be removed or neutralized.

[0011] For example, the base may be provided to the reaction solvent using a liquid-liquid interface, the advantage of which is that polystyrene-based materials have a relatively high solubility in polar solvents and benefit from non-polar solvents.

[0012] Essentially, a variety of different polystyrenic materials may be used, such as polystyrene, high impact polystyrene (HIPS), expanded polystyrene (EPS), extruded polystyrene (XPS), styrene-butadiene rubber (SBR), and acrylonitrile-butadiene-styrene (ABS). Some of these materials contain additional monomers (or polymers) that do not adversely affect the performance of the process. This is true for polystyrenic materials that contain up to about 10% by weight of foreign polymers, such as polyethylene, polypropylene, and / or polyvinyl chloride. Examples used are Piocelan polypropylene composite polystyrenic foams and polyethylene composite polystyrene foams. Again, these foreign polymers do not inhibit the process and will end up in the remaining product stream.

[0013] The dehalogenation of the flame retardant in step (ii) is generally carried out by heating the reaction solvent containing the polystyrene to a temperature in the range of about 150° C. to about 350° C., preferably about 180° C. to about 300° C. The pressures corresponding to these temperatures are various values ​​in the range of about 1 bar to about 20 bar, preferably about 1 bar to about 15 bar, for example 1 to 12 bar.

[0014] The dehalogenation reaction is initiated at elevated temperature, and the higher the temperature, the shorter the time for completion of the reaction. The reaction time for dehalogenation is generally 2-120 minutes, while the halogenation is usually substantially complete in 5-70 minutes, e.g., 10-60 minutes.

[0015] The method of the present invention is particularly intended for the recycling of expanded, foamed or extruded polystyrene or mixtures of polystyrene and expanded, foamed or extruded polystyrene, and their associated polystyrenic materials. However, due to the relatively low density of expanded polystyrene, their application to the basic method of the present invention is relatively low in practicality. Therefore, the present invention, in a generally preferred embodiment, provides an additional pre-step in the method, in which the expanded polystyrene is compressed and its density is substantially increased. Furthermore, the compressed polystyrene is converted into a semi-solid form of a rigid material or a two-phase system, depending on the type and amount of compression solvent used. However, they are easily handled and relatively less sticky or non-sticky. However, in order to compress the expanded polystyrene properly or optimally, it is necessary to use a solvent or solvent mixture whose properties are different from the reaction solvent. Thus, the present invention provides a pre-step, which is the step of compressing the expanded polystyrene in a compression solvent. This compression solvent causes the expanded polystyrene to form a semi-solid material or a two-phase system including a semi-solid (dough-like) phase of polystyrene. The compressed form rigid polystyrene is separated from the liquid phase by any suitable technique.

[0016] The two-phase system or the compressed polystyrene may be subjected to a heating step for dehalogenation. However, it is preferred to add reaction solvent or to at least partially replace the compression solvent with reaction solvent, and after this replacement the compressed polystyrene proceeds to step (i) of the process of the invention.

[0017] It should be noted at this point that the compression pre-step does not have to take place immediately in time and / or place relative to step (i) or step (ii) of the method of the invention. It is equally possible to carry out the pre-step earlier in time and / or even at a different location, while retaining all the advantages of the invention, especially when the availability and / or presence of recycled polystyrene material is less than the process speed. The recycled expanded polystyrene is then advantageously compressed at one or more remote locations and transported to a central processing location, where compressed polystyrene from different locations, different types and / or different sources is processed. All transport and processing proceeds under typical and conventional conditions, since it is not necessary to work under ATEX conditions and the two-phase system and compressed polystyrene are materials that fall under the lowest ADR classification.

[0018] One of the important findings of the present invention is that the pyrolysis mixture obtained after pyrolysis in step (v) contains aromatic and / or aliphatic fractions that can be obtained by distillation in step (vi) and has the properties of compressing the expanded polystyrene present in the polystyrenic material and / or the properties of the reaction solvents, which are the solvents and distillation fractions unique to the process.

[0019] Regarding compression, since the distillate fractions have high boiling points, the process involving compression is carried out at a temperature at least 10°C below the flash point, so that the process is not carried out under ATEX conditions. If only the aromatic fraction is used for compression, compression results in the formation of a polystyrene solution with the viscosity of a syrup. If a mixture of aromatic and aliphatic fractions is used, the mixed compression results in the formation of a two-phase system with the viscosity of a paste or a hard product with a Camembert cheese-like viscosity. The more aliphatic fraction is used, the harder the viscosity and the increased polymer density. The process of the invention therefore at least partially applies as compression solvent a mixture of an aliphatic solvent with an aromatic compression solvent, for example a mixture with a high-boiling distillation fraction obtainable in step (vi), preferably a styrene dimer fraction boiling at about 280° C. to about 320° C., or at about 150° C. to about 270° C., for example at about 180° C. to about 250° C., at an absolute pressure of about 5 to 30 mbar, preferably at an absolute pressure of 10 to 30 mbar. Alternatively, the dimer fraction may have a C16 or less and have a boiling point of about 290° C. to 305° C. In other words, the process of the present invention utilizes at least a portion of the mixture between aliphatic compounds and aromatic compounds, for example the high boiling distillation fraction obtainable in step (vi), preferably a mixture with a styrene dimer fraction boiling at about 280°C to about 320°C, or boiling at about 150°C to about 270°C, for example boiling at about 180°C to about 250°C, at an absolute pressure of about 5 to 30 mbar, preferably at an absolute pressure of 10 to 30 mbar. Alternatively, the dimer fraction may have C16 or less and have a boiling point of about 290°C to 305°C. The aromatic compression solvent and the aliphatic compression solvent are preferably fractions obtainable in the distillation of step (vi).

[0020] The volume ratio of aromatic and aliphatic solvents is selected depending on the composition of the (expanded, foamed or extruded) polystyrene-based material. Some flame retardants, such as HBCD, are only slightly soluble in aliphatic solvents and well soluble in aromatic solvents, while any polyethylene and / or polypropylene present is relatively well soluble in aliphatic solvents. The volume ratio of aromatic and aliphatic compression solvents is therefore selected depending on the type of polystyrene material to be recycled and in relation to the viscosity of the compressed mass. For example, above 20% aromatic solvent results in a hard form of the compressed mass. The volume ratio may therefore be in the range of about 30:70 (paste viscosity), preferably about 20:80, more preferably about 10:90 (hard viscosity).

[0021] Another important finding of the present invention is that the pyrolysis mixture obtained after the pyrolysis of step (ii) contains a fraction having the property of dissolving the dehalogenated polystyrene and having such a high boiling point that both the dehalogenation of step (ii) and the pyrolysis of step (v) can be carried out under liquid conditions. This reaction solvent is also a unique product of the system, the decomposition of which produces styrene and styrene oligomers, which can be used. Thus, the process of the present invention applies, at least in part, a high-boiling non-polar organic reaction solvent having a vapor pressure of less than about 15 bar, preferably less than about 10 bar, at a temperature in the range of about 250°C to about 450°C. This reaction solvent is preferably a high-boiling distillation fraction obtainable in step (vi), preferably a styrene trimer fraction having a boiling point of about 380°C to about 420°C. Alternatively, the trimer fraction may contain C24 or less and has a boiling point of 400°C.

[0022] Due to the differences in composition and properties of the compression solvent and the reaction solvent, the compression solvent is preferably at least partially replaced by the reaction solvent prior to the dehalogenation step (ii), and the compression solvent is preferably recycled to the compression step.

[0023] When the reaction of the released halogen compounds with the base in step (ii) is preferably carried out in the reaction solvent, and the release of halogen is significant, preferably the removal of halogen residues, preferably the removal of halogen salts and / or halogen-containing gases, is carried out in the reaction solvent and / or downstream from the reaction solvent by solid-liquid separation, for example by filtration, centrifugation, (hydro)cyclone separation, with a residue / salt particle size of less than 20 μm, preferably less than 20 μm, for example less than 1 μm or less than 0.4 μm. Such residue / salt removal has the additional advantage, namely that any sand or other granular material present in the recycled styrenic material is removed, which benefits the processing operation and reduces the risk of ground damage due to friction.

[0024] For practical and sufficient removal of any organohalogen flame retardant, the base is preferably present in excess, preferably in slight excess, such that the molar ratio of base to organohalogen flame retardant is from about 1.1 to about 3, e.g., from about 1.5 to about 2.6, or from 1.1 to 1.5.

[0025] As mentioned above, the pyrolysis step (v) is carried out under more severe conditions than the dehalogenation step (ii). In practice, the pyrolysis of step (v) is carried out at atmospheric pressure, at a temperature of about 400° C. to about 550° C., preferably at a temperature of about 480° C. to about 520° C., more preferably at a temperature of about 500° C. to about 520° C., or at a relatively high pressure and a correspondingly relatively low temperature. Preferably, the pressure is about 1 bar to 3 bar.

[0026] The pyrolysis step (v) may be carried out in a molten bed reactor and / or a tube reactor and / or a fluidized bed reactor, which is a conventional and simple design and applicable reactor since the pyrolysis is carried out under liquid conditions due to the use of a high boiling point reaction solvent, which is optimal in terms of heat transfer and pyrolysis to solid substances, such as to soot, is substantially avoided.

[0027] Optimally running the method of the present invention provides beneficial results, namely, a removal of at least 90%, preferably at least 95%, more preferably at least 99% of the organohalogen flame retardant present in the polystyrenic material, such that the styrenic product contains less than 15 ppm, preferably less than 10 ppm, for example less than 5 ppm of flame retardant.

[0028] Another aspect of the invention relates to an apparatus for recycling polystyrenic materials containing organohalogen flame retardants, as defined and discussed in this disclosure.

[0029] Such facilities include: a dissolving unit (a) for dissolving the polystyrenic material in a high-boiling non-polar organic reaction solvent or in a mixture with a high-boiling aliphatic reaction solvent; a heating unit (b) for heating the polystyrene contained in the reaction solvent to a temperature for releasing the halogen compounds from the flame retardant; · a contacting unit (c) for contacting the released halogen compounds with a base to form halogen residues; · a halogen residue removal unit (d) for removing halogen residues from the reaction solvent; a pyrolysis unit (e) for pyrolyzing the polystyrene in the reaction solvent at a temperature for depolymerizing the polystyrene; and A distillation unit (f) for distilling the depolymerized mixture to at least a styrene fraction.

[0030] As discussed above, the installation is suitable for compressing the expanded polystyrene and additionally comprises a compression unit for compressing the expanded polystyrene in a compression solvent and preferably for replacing the compression solvent by the reaction solvent.

[0031] Advantageously, the reaction solvent used for dehalogenation and pyrolysis is also at least partially produced when carrying out the method of the invention. For that purpose, the installation has a distillation unit (f) which distills the depolymerization mixture into a styrene trimer fraction which is recycled and at least partially used as reaction solvent. For the same reason, the distillation unit (f) distills the depolymerization mixture into a styrene dimer fraction which is recycled and at least partially used as compression solvent for the expanded polystyrene.

[0032] In a preferred embodiment, the halogen residual is a halogen salt and / or a halogen-containing gas.

[0033] As discussed above, pyrolysis is carried out under liquid conditions due to the use of high boiling point solvents. This allows the use of molten bed reactors and / or tube reactors and / or fluidized bed reactors. This is a conventional and simple design and applicable reactor (reactor), since this liquid state pyrolysis is optimal in terms of heat transfer and pyrolysis into solid materials, such as soot, is substantially avoided. Thus, pyrolysis unit (e) comprises molten bed reactors and / or tube reactors and / or fluidized bed reactors. Additional advantages of using molten bed reactors and / or tube reactors and / or fluidized bed reactors are discussed below.

[0034] The method and equipment of the present invention are suitable for recycling a variety of different polystyrenic materials containing many different flame retardants. Examples of polystyrenic materials are polystyrene, expanded polystyrene (EPS), extruded polystyrene (XPS), such as those used in packaging foils and containers, styrene-butadiene rubber (SBR), and acrylonitrile-butadiene-styrene (ABS). Examples of organohalogen flame retardants are organobromine flame retardants, such as hexabromocyclododecane (HBCD), tetrabromobisphenol A (2,3-dibromopropyl) ether (BDDP or FR-720), tris(tribromophenoxy)triazine (FR-245), tetrabromobisphenol-A-bis(2,3-dibromo-2-methylpropyl ether, 1,1'-(isopropylidene)bis[3,5-dibromo-4-(2,3-dibromo-2-methylpropoxy)benzene] (TBBPA-DBMPE or AP 1300 SF), block copolymer of polystyrene and brominated polybutadiene (FR-122P), organochlorine flame retardants, such as tris(1-chloro-2-propyl)phosphate (TCPP) and polyvinyl chloride (PVC), and organofluorine flame retardants. The expanded polystyrene-based material may contain fluorinated organic compounds, such as hydrochlorofluorocarbons (HCFCs, e.g., R-22, R-12, and R134a).

[0035] <Details of the Invention> The mentioned and other features and advantages of the method and installation of the invention will become apparent from the following description, which is to be considered as being provided for information purposes only and without limiting the invention in any way, and in this regard, reference is made to the attached drawings, in which:

[0036] Example 1: Compression of expanded polystyrene 25 grams of expanded polystyrene are added to 50 grams of compressed solvent. The compression solvent contains about 20% by weight of an aromatic hydrocarbon having a boiling point of about 300° C. and about 80% by weight of an aliphatic hydrocarbon having a boiling point of 310° C. Compression was carried out at about 60-70° C. After dissolution in the compression solvent, a stable product is formed in a relatively hard form. This highly filled polystyrene product has a solids content of about 60%.

[0037] Example 2: Compression of expanded polystyrene-based materials containing polyethylene and / or polypropylene An expanded polystyrene article containing 24.75 grams of expanded polystyrene (95%) and 1.25 grams of expanded polyethylene (5%) is added to 50 grams of compressed solvent containing about 20% by weight of an aromatic hydrocarbon having a boiling point of about 300° C. and 80% by weight of an aliphatic hydrocarbon having a boiling point of about 300° C. The compression temperature is about 85° C.

[0038] Expanded polyethylene compresses like expanded polystyrene, but produces a waxy, homogeneous end product. The solids content is about 66%. Expanded polystyrene contains only small concentrations of expanded polyethylene, so expanded polyethylene can be processed similarly to expanded polystyrene.

[0039] Example 3: Compression of expanded polystyrene-based materials containing polyethylene and / or polypropylene 4.3 grams of expanded polystyrene-based material, containing about 60% by weight polystyrene, 35% by weight expanded polypropylene, and 5% by weight expanded polyethylene, are added to 65 ml of a compressed solvent mixture, which contains 40% by volume of an aromatic hydrocarbon (Solvesso 150 ND) with a boiling point in the range of about 290-305°C, and 60% by volume of an aliphatic hydrocarbon (Valsol 60) with a boiling point of about 187-216°C. The density of the resulting compressed solvent solution is 67 gr / l. Compression is carried out at a temperature of 130°C.

[0040] Expanded polyethylene and expanded polypropylene deform in a similar manner to expanded polystyrene. However, a gel-like end product is obtained. Expanded polystyrene with some extraneous polyethylene and / or polypropylene can therefore be compressed, but at relatively high compression temperatures.

[0041] Due to the jelly-like consistency of the final product, a one-pass-remove concept (according to FIG. 4) can be applied, where the mixture after being saturated with deformed expanded polystyrene, expanded polypropylene, and some expanded polyethylene can be stored as briquettes until further processing.

[0042] Example 4: Dehalogenation of Polystyrene Polystyrene containing 1 wt. % flame retardant was dissolved in Solvesso 150 ND (boiling point: 183°C-194°C, ExxonMobil Chemical Series) as aromatic reaction solvent. Base was added to the reaction solvent at a given molar ratio of organic halogen to base. Debromination was carried out at a given temperature. Conversion over about 60 minutes at a given temperature was calculated as 1-(mass recovered oil * [Br] in oil) / mass Br added to reactor).

[0043] [Table 1]

[0044] Example 5: Dehalogenation of polystyrene by trimer fractionation Polystyrene containing HBCD flame retardant was dissolved in styrene trimer fraction used as aromatic solvent. NaNH 2 The base was added to the reaction medium at a molar ratio of 2.6 of the given organic halogen to base. The debromination was carried out at 250° C. The conversion after 60 min at reaction temperature was calculated as 1-(mass oil recovered*[Br] in oil) / mass Br added to reactor) and was approximately 99%.

[0045] Example 6: Dehalogenation of expanded polystyrene by trimer fractionation Expanded polystyrene containing 0.71 wt.% HBCD was subjected to dehalogenation using a mixture of styrene dimers and trimers (obtained by pyrolysis of polystyrene beads dissolved in Solvesso 150 ND at 350°C and removal of styrene monomer by fractional distillation at 100°C and 100 mbar) as compressed solvent. The reactor charge was 10 wt.% EPS, which corresponds to a charge of 0.1 wt.% flame retardant. NaNH 2 was used as the base, and the base / Br ratio was 2.6. The reaction temperature was 250° C. and the reaction time was 60 min. The dehalogenation conversion was 98% for the EPS(HBCD) sample.

[0046] Example 7: Pyrolysis of compressed polystyrene The compressed polystyrene obtained in Example 5 was subjected to pyrolysis, in particular for the production of styrene by depolymerization of polystyrene. The liquid mixture of polystyrene and styrene trimers (obtained after distillation of the dimer / trimer mixture of Example 6 at 250°C and 20 mbar absolute pressure) was fed to a pyrolysis reactor and subjected to pyrolysis at atmospheric pressure at a temperature of 500°C for about 5-10 minutes. The pyrolyzed oily liquid obtained was cooled to a temperature of about 160°C by quenching with cooled reaction solvent. After removal of any solids, such as charcoal and soot, the cooled liquid mixture was subjected to a stripping operation to obtain a styrene product stream, of which styrene is the main constituent as the top distillate. Further obtained are a middle distillate fraction and a bottom fraction.

[0047] The styrene product stream was subjected to a four stage distillation unit to distill off an aliphatic fraction that can be used as an aliphatic solvent, a light aromatic fraction, and a heavy end as a bottom fraction. The top fraction is styrene, boils at about 145°C, has a purity of at least 98% and contains less than 7 ppm of flame retardants.

[0048] The middle distillation fraction is further distilled to provide light naphtha and a fraction boiling at about 280-320°C which is a dimer fraction used as a compression solvent. The bottom distillation fraction boils at about 380-420°C which is a trimer fraction used as a reaction solvent.

[0049] Details of the method and apparatus of the present invention FIG. 1 shows an overall process flow diagram of the method and equipment 1 of the present invention. Equipment 1 includes a dissolution unit 4 to which a polystyrene-based material 5 containing an organic halogen flame retardant is added for dissolution or dispersion in the added reaction solvent 6. A mixture 7 containing polystyrene in the reaction solvent 6 is added to a heating unit 8. In the heating unit 8, the polystyrene present in the reaction solvent 6 is heated to a temperature for a sufficient time to release halogen compounds from the flame retardant. The heating temperature is preferably about 180° C. to about 300° C., for example 250° C., for about 10 to 120 minutes, preferably about 45 to about 90 minutes, for example 60 minutes.

[0050] The released halogen compounds are converted to halogen residues, for example halogen salts and / or halogen-containing gases, and a base 21 is added. The halogen residues, for example halogen salts, are removed using a hydrocyclone or by filtration. The polystyrene 9, which has been freed of halogen and is contained in the reaction solvent, is added to a pyrolysis unit 10, in which the polystyrene 9 is pyrolyzed and depolymerized to styrene 13, valuable products 14, and pyrolysis solids, for example soot 15. The pyrolysis is carried out at about 400°C to about 600°C, or about 425°C to about 550°C, for example 450 to about 500°C.

[0051] The pyrolysis mixture 11 in reaction solvent is added to a distillation unit 12 where styrene 13 and valuable products 14 are distilled off. Other distillation liquids and gases may be used to generate energy. Pyrolysis solids 15 are removed.

[0052] Figure 2 shows another overall process flow diagram of the method and installation 2 of the invention. Compared to the installation 1 of Figure 1, the installation 2 additionally comprises a compression unit 17, in which the expanded polystyrene-based material 22 is compressed with a compressed solvent 16. The mixture of compressed polystyrene 18 contained in the compressed solvent 16 is added to a separation unit 19, in which the compressed solvent is at least partially replaced by the reaction solvent 6. The replaced compressed solvent 19 is recycled to the compression unit 17. The reaction solvent 6 added to the separation unit 19 can be fresh reaction solvent 6 and / or recycled (recycled) reaction solvent 20 obtained as valuable product 14 in the distillation unit 12.

[0053] The mixture of compressed polystyrene and compressed solvent may be in the form of a two-phase system, having a semi-solid polystyrene phase and a liquid phase, or may have a single semi-solid phase, which can be transported by conventional means, for example by pumping. The type of compressed form depends on the amount of compressed solvent added and the type of expanded polystyrene-based material, and is as desired or necessary. If this material also contains polyethylene and / or polypropylene, another valuable distillation product 14 contains an aliphatic solvent, and the mixture of the reaction of the aliphatic solvent with the compressed solvent improves the dissolution of the flame retardant contained in the polystyrene-based material.

[0054] Figure 3 shows in more detail the compression unit 17 according to the invention. Expanded polystyrene 22 is added to a storage hopper 24 and transported by a conveyor screw 25 to a compression mill 26. Here, the expanded polystyrene is compressed with compressed fluid 16, provided by a sprayer unit 28, which is collided with the expanded polystyrene by a rotating compression arm 27. The compressed polystyrene 18 formed is transported via a pump 31 and a cooling unit 32 to a storage tank 33. The tank 33 contains a two-phase system with a phase of semi-solid compressed polystyrene 18 and a phase of liquid compressed fluid. The excess of compressed fluid 16 may be recycled via a pump 34 to a compressed fluid tank 37, which also receives a supply of new (unused) compressed fluid from a reservoir 35 via a pump 36.

[0055] The compressed polystyrene 18 collected in tank 33 may be added directly to heating unit 17 or may first be transported from a remote location to a central facility 1-3.

[0056] FIG. 4 shows in more detail another compression unit 17 of the invention (the same reference numbers indicate the same components of the compression unit 17 described in FIG. 3). Unlike the compression unit 17 of FIG. 3, here the compression unit operates under the one-pass-removal principle, whereby this compression unit 17 is adapted to compress expanded, foamed or extruded polystyrene containing a high content of polyethylene and / or polypropylene, for example in an amount of about 5 to about 10% by weight. This means that the compressed polystyrene 18 is transported by an extrusion conveyor onto a porous conveyor belt 44 and is spray-cooled with a cooling liquid 39, which is supplied by a pump 41 and collected in a dipping tray 40. The compressed polystyrene briquettes 43 are collected in a bin 42. The compressed solvent 16 leaving the compression unit 17 together with the briquettes 43 is supplemented and supplied by a tank 35 and a heater 29 and a pump 30.

[0057] Figure 5 shows a non-limiting example process flow diagram of another facility 3 of the present invention for recycling polystyrenic material 5 into styrene 13 and trimer fraction 52, aliphatic solvent 50, light aromatics 54, and light naphtha 55. Also produced is a dimer fraction 53 for use as a compression solvent in processing expanded polystyrene. The major unit operations are discussed and detailed in Figures 6-13.

[0058] The installation 3 includes a compression unit 17 for compression of the expanded polystyrene material 22 in a compression solvent 16, as described with reference to Figures 3 and 4. The volume ratio of the compression solvent 16 to the expanded polystyrene 22 is about 1:1. The compressed polystyrene 18 is fed to a dissolution unit 4 having a mixing tank 56, where it is dissolved in the reaction solvent 20 and / or trimer fraction 52, which are fed (optionally in a mixture with an aliphatic solvent 50).

[0059] The dissolved polystyrene 7 is filtered and enters the separation unit 19, including the solvent recovery section 45, for separating the compressed solvent 16. The polystyrene contained in the reaction solvent 6 is transported into the heating unit 8 for dehalogenation of the flame retardant. The released halogen compounds react with the base 21 present in the reaction solvent and / or added in the form of a mixture with the aliphatic / aromatic solvent mixture from the tank 71 via the pump 75, and the halogen residues formed, e.g. halogen salts, are filtered off. The polystyrene 9, freed of halogen and present in the reaction solvent 6, is in the form of a mixture 83 and is subjected to pyrolysis in the pyrolysis unit 10 at a temperature of about 510° C. The pyrolysis mixture is cooled in the quench unit 46 with the cooled reaction solvent, i.e. in the trimer fraction 52.

[0060] After removal of soot and charcoal by filtration, the filtered pyrolysis mixture 11 is subjected to distillation sections 48 and 48 in distillation unit 12 to provide pure styrene 13, a dimer fraction 53 used as compression solvent 16, a trimer fraction used as reaction solvent 6, an aliphatic solvent 50 used in blending with compression solvent 16, and light aromatics 54 used in blending with reaction solvent 6. Other product streams may be used for energy production and / or for heating and / or as feedstock for cracking into additional aromatic compounds.

[0061] 6 shows separation unit 19 in more detail. A liquid mixture 58 of about 1 part polystyrene, about 1 part compressed solvent 16, and about 2 parts reaction solvent 6 enters a flash drum 63 which is heated by heater 60 and equipped with a vacuum pump 62 for flashing the mixture 58. The low boiling point compressed solvent 16 leaves the flash drum across the top and is conveyed to solvent recovery section 45. A liquid mixture 59 of about 2 parts relatively high boiling point reaction solvent 6 and about 1 part dissolved polystyrene reaches the bottom and is sent to heating section 8. The temperature of the mixture is regulated by reboiler 61, thereby maintaining the polystyrene in a liquid state.

[0062] 7 shows the compressed solvent recovery section 45 in more detail. Compressed solvent 16 added via pump 64 is stripped by stripper 65 and pumped to storage tank 68 after cooling in condensate 66. The stripped light fraction 72 is cooled in condensate 69 and pumped to storage tank 71 via pump 70. The stripper may operate below atmospheric pressure by connection of vacuum line 73 connected to vacuum pump 62. If desired, the compressed solvent may be mixed with the added light aromatics 54.

[0063] FIG. 8 shows in more detail a heating unit 8 for the dehalogenation of polystyrene. The heating unit 8 comprises a reactor 74, for example a plug flow reactor 74. A mixture 59 of polystyrene dissolved in a reaction solvent 6 (i.e. here the trimer fraction which may contain some compressed solvent 16) enters the reactor 74 and is mixed with a base 21 fed through a pump 76 and a heater 77. The reaction solvent 6 may contain some compressed solvent 16. The reactor 74 is operated at a dehalogenation temperature of about 250° C. and at an overpressure of about 5 to about 15 bar, preferably about 5 to about 12 bar. The residence time depends on the type and concentration of the organohalogen flame retardant in the mixture 59. In general, the residence time is about 2 minutes to 60 minutes. The halogen compounds released by the flame retardant are captured by the base 21 and halogen residues, for example halogen salts and / or halogen-containing gases, are formed in the reaction solvent. Any gaseous reaction products formed, such as ammonia, may exit reactor 74 via gas bleed 80. Polystyrene, halogen residuals, such as halogen salts and / or halogen-containing gases, reaction solvent, and any remaining reactants, such as base 21, and other reaction products, are filtered in filtration train 81, which filters mixture 79 at about 100 μm, about 40 μm or 20 μm, and 1 μm or 0.4 μm. Solids that are filtered out are collected in sludge tank 82 and may be purified. Filtered liquid 83 enters pyrolysis unit 10.

[0064] Figure 9 shows the pyrolysis unit 10 in more detail. A pyrolysis reactor 84 is equipped with a heater 85 for heating the liquid mixture 83 at about 480°C to about 520°C, preferably 500°C to about 520°C, at a pressure of about 1 bar to about 3 bar, and / or for vaporization and reaction into a pyrolysis mixture 11 comprising depolymerized polystyrene into at least styrene and other depolymerized fractions, such as dimer and trimer fractions, and reactive fractions, such as aliphatic fraction 50 and aromatic fraction 54. A preferred embodiment of the pyrolysis reaction 84 is shown in Figure 13 below.

[0065] Figure 10 shows the quench section 46 in more detail. It comprises a quencher 86, into which the mixture 11 and / or the reaction solvent, which is recycled after cooling, is sprayed, and a cooler 87 and a spray pump 88. It is based on the idea of ​​the invention, namely that cooling is achieved without the use of exogenous solvent, by using the reaction solvent in the form of the trimer fraction originating from the process. By cooling, the temperature of the mixture 11 is significantly reduced to a temperature at which secondary reactions are substantially avoided or stopped. After quenching, the mixture passes through a filter 89 to remove any remaining or newly formed solids, such as soot and charcoal.

[0066] FIG. 11 shows the crude stripper unit 47 of the distillation unit 12 in more detail. The crude stripper unit 90 distills the pyrolysis mixture 11, preferably under reduced pressure, into a top fraction 91, a middle fraction 92 and a bottom fraction 93. The operation is such that the production of the top fraction 91 is maximized, since it contains mainly styrene 13. The top fraction 91 obtained at the top after the upstream is cooled in a condenser 94, partially recycled and partially cooled in a cooler 95 to provide a cooled top fraction 91. The middle fraction 92 is cooled in a cooler 96 and further processed in the light ends stripper unit 48. The bottom fraction 93 is heated in a reboiler 97, partially recycled and partially cooled in a cooler 98. This bottom fraction 93 can be recycled to the dissolution unit 4 as a trimer fraction 52 or stored in a storage tank 99 and used for energy production.

[0067] 12 shows the light ends stripper unit 48 in more detail, where the intermediate fraction 92 is removed in a stripper 100 to distill off the light naphtha 55 at the top via a condenser 102 and a cooler 101, whereby at the bottom the dimer fraction 53 is distilled off via a reboiler 103 and a cooler 104, which has a specification and / or a flash point that may be used as the compressed solvent 16 and allows the equipment to operate safely.

[0068] Returning to Figure 5, there is shown that the overhead fraction 91 is distilled in distillation column 105, of which the top fraction provides aliphatic solvent 50. The bottom fraction 106 is distilled in distillation column 107, of which bottom fraction 108 is recycled to distillation column 105. The overhead fraction 109 is distilled in distillation column 110, of which the bottom fraction 108 is recycled to distillation column 105. The top fraction 109 is distilled in distillation column 110, of which the light aromatics are provided as overhead fraction 111. The bottom fraction 112 is applied to styrene distillation column 113, of which the high purity styrene 13 is provided, and of which the heavy ends 51 are provided as bottom fraction.

[0069] Finally, Figures 13 and 13A show in more detail an embodiment of the reactor 84 in the form of a molten bed reactor 114. The reactor 114 has a reactor housing 119 with a heat exchanger 115 dividing the housing 119 into a bottom part 116 and a top part 117. The bottom part 116 and the top part 117 are connected by a number of heating pipes 118, which extend over the height of the heat exchanger 115 and are regularly divided over the surface of the heat exchanger. The inlet 120 of the reactor 114 is connected to a downpipe 122 which extends coaxially through the heating exchanger 115. Preferably, the surface area of ​​the downpipe 122 is substantially equal to the total surface area of ​​the heating pipes 118. The downpipe 122 opens into the bottom part 116. The top part 117 is connected to an outlet 121. The downpipe 122 may be equipped with a propeller means 123 for controlling the flow of the mixture 83 through the heat exchanger depending on the required degree of pyrolysis. The heat exchanger 115 is equipped with a top inlet 124 and a bottom outlet 125 for a heating medium 126, which is in countercurrent contact with the mixture in the heating pipe. In this way, the liquid mixture 11 and / or 83 passes through the molten bed reactor 114 via the inlet 120 while being pyrolyzed and leaves the reactor 144 as the pyrolyzed mixture 11 via the outlet 121.

[0070] Finally, it should be mentioned that the present invention also extends to the removal of halogens from organic compounds other than flame retardants. The concept of the present invention can also be used with other suitable organic molecules, such as in mixtures of other organic molecules, such as PVC, for example polymers in pyrolysis mixtures. This is due to the non-polar solvents containing strong bases and generating halogen residues at high temperatures, such as halogen salts and / or halogen-containing gases, which can be easily separated.

Claims

1. 1. A method for recycling polystyrenic materials containing organic halogen flame retardants, comprising the steps of: (i) dissolving the polystyrenic material in a high boiling point non-polar organic reaction solvent; (ii) heating the polystyrene contained in the reaction solvent to a temperature that releases halogen from the flame retardant; (iii) contacting the released halogen with a base to form a halogen residual; (iv) removing said halogen residues; (v) pyrolyzing the polystyrene contained in the reaction solvent at a temperature that depolymerizes the polystyrene; and (vi) distilling the depolymerized mixture into at least a styrene fraction; A method comprising:

2. 2. The method of claim 1, wherein the base is added to the reaction solvent whereby the halogen released in step (ii) contacts the base in step (iii), whereby the halogen residue is formed in the reaction solvent.

3. 3. The method according to claim 1 or 2, wherein the halogen residues are halogen salts and / or gases containing the halogen.

4. 4. The method of claim 3, wherein the base used to form the halogen salt in the reaction solvent is selected from the group consisting of sodium diamine, potassium tert-butoxide, sodium bis(trimethylsilyl)amide, and P(CHNCHCH)N.

5. 3. The method of claim 1 or 2, wherein the polystyrenic material may contain up to about 10% by weight of foreign polymers, such as polyethylene, polypropylene, and / or polyvinyl chloride.

6. 3. The process according to claim 1 or 2, wherein in step (ii), the reaction medium containing the polystyrene is heated to a temperature in the range of about 150°C to about 350°C, preferably about 180°C to about 300°C.

7. 3. The method according to claim 1 or 2, wherein the polystyrene to be recycled is expanded polystyrene, the method comprising a step of compressing the expanded polystyrene in a compression solvent, after which, preferably, the compression solvent is at least partially replaced by the reaction solvent, and preferably, the compression solvent is an aromatic compression solvent, for example a high-boiling distillation fraction obtainable in step (vi), preferably a styrene dimer fraction boiling at about 280° C. to about 320° C. or about 180° C. to about 250° C. and at a pressure of about 5 to 30 mbar absolute, preferably at a pressure of 10 to 30 mbar absolute.

8. 8. The method according to claim 7, wherein the compressed solvent is a mixture of the aromatic compressed solvent and the aliphatic compressed solvent, preferably a fraction obtainable by distillation of step (vi), and preferably the volume ratio of the aromatic compressed solvent to the aliphatic compressed solvent is in the range of about 30:70, preferably about 20:80, more preferably about 10:

90.

9. 3. The process according to claim 1 or 2, wherein the high boiling non-polar organic reaction solvent has a vapour pressure of less than about 15 bar, preferably less than about 10 bar, at a temperature in the range of from about 250° C. to about 450° C., and preferably the reaction solvent is a high boiling distillation fraction obtainable in step (vi), preferably a styrene trimer fraction boiling at from about 380° C. to about 420° C.

10. 8. The method of claim 7, wherein the displaced compressed solvent is at least partially recycled to the compressing step.

11. 3. The method according to claim 1 or 2, wherein in step (iv), the halogen residues are removed from the reaction solvent by filtration, centrifugation, cyclone separation, with a residual particle size of less than about 20 μm, preferably less than about 20 μm, for example less than 1 μm, or less than 0.4 μm.

12. The method of claim 1 or 2, wherein the molar ratio of base to the organohalogen flame retardant is from about 1 to about 3, such as from about 1.5 to about 2.

6.

13. 3. The process according to claim 1 or 2, wherein the pyrolysis of step (v) is carried out at atmospheric pressure, at a temperature of about 400°C to about 550°C, preferably about 480°C to about 520°C, more preferably about 500°C to about 520°C, or at higher pressures and corresponding temperatures, preferably at a pressure of about 1 bar to 3 bar, preferably said pyrolysis step (v) is carried out in a molten bed reactor and / or a tubular reactor and / or a fluidized bed reactor.

14. 3. The method according to claim 1 or 2, wherein the removal of organohalogen flame retardants present in the polystyrenic material is at least 90%, preferably at least 95%, more preferably at least 99%.

15. For example, as described in claim 1 or 2, a facility for recycling polystyrene-based materials containing organic halogen flame retardants, comprising: a dissolving unit (a) for dissolving said polystyrenic material in a high-boiling non-polar organic reaction solvent or in a mixture with a high-boiling aliphatic reaction solvent; a heating unit (b) for heating the polystyrene contained in the reaction solvent to a temperature that causes the halogen to be released from the flame retardant; a contacting unit (c) for contacting the released halogen with a base to form a halogen residue; a halogen residue removal unit (d) for removing said halogen residues from said reaction solvent; a pyrolysis unit (e) for pyrolyzing the polystyrene in the reaction solvent at a temperature to depolymerize the polystyrene; and a distillation unit (f) for distilling the depolymerized mixture into at least a styrene fraction; Facilities having:

16. 16. The facility of claim 15, wherein the halogen residuals are halogen salts and / or gases containing the halogens.

17. 16. The installation according to claim 15, comprising a compression unit for compressing expanded polystyrene in a compression solvent and for replacing said compression solvent with said reaction solvent.

18. 16. The installation according to claim 15, wherein the distillation unit (f) distills the depolymerized mixture into a styrene trimer fraction, which is recycled and at least partially used as a reaction solvent, and / or the distillation unit (f) distills the depolymerized mixture into a styrene dimer fraction, which is recycled and at least partially used as a compression solvent for the expanded polystyrene.

19. 16. The installation according to claim 15, wherein the pyrolysis unit (e) comprises a molten bed reactor and / or a tube reactor and / or a fluidized bed reactor.

20. The organic halogen flame retardant is an organic bromine flame retardant, an organic chlorine flame retardant, or an organic fluorine flame retardant, such as hexabromocyclododecane (HBCD), tetrabromobisphenol A (2,3-dibromopropyl) ether (BDDP or FR-720), tris(tribromophenoxy)triazine (FR-245), tetrabromobisphenol-A-bis(2,3-dibromo-2-methylpropyl ether), 1,1'-(iso ...

3. The method according to claim 1 or 2, wherein the organic fluorine compound is selected from the group consisting of 3,5-dibromo-4-(2,3-dibromo-2-methylpropyl)benzene (TBBPA-DBMPE or AP1300SF), tris(1-chloro-2-propyl)phosphate (TCPP), tetradecafluorohexane (TDFH), and the organic fluorine compound may include hydrochlorofluorocarbons (HCFCs, e.g., R-22, R-12, and R134a).

21. 3. The method of claim 1 or 2, wherein the polystyrenic material comprises polystyrene, expanded polystyrene (EPS), extruded polystyrene (XPS), such as those used in packaging foils and containers, styrene-butadiene rubber (SBR), acrylonitrile-butadiene-styrene (ABS).

Images