Production apparatus and production method

Abstract

To provide an apparatus and method for producing a reaction product that can suppress clogging to improve productivity.SOLUTION: The production apparatus includes a plurality of nozzles for ejecting a liquid material, a plurality of pumps for sending the liquid material to the respective nozzles, and a recovery unit for recovering a reaction product produced by reaction between the liquid materials ejected from the respective nozzles. Each of the nozzles is configured to eject the liquid material toward one reaction space in an outer space of the nozzle.SELECTED DRAWING: Figure 1

Description

[Technical field]

[0001] The present invention relates to a generating device and a generating method. [Background technology]

[0002] In recent years, metal-organic frameworks (MOFs) have been used as adsorbents. ) has been attracting attention. Organometallic complexes are used in the fields of metal-organic frameworks, metal-organic frameworks, and porous structures. Porous Coordination Polymer (PCP) is a polymer made of metal salts and organic compounds. The organic metal complex is a porous material that can be produced using the raw materials metal ions. and organic ligands, and has a highly regular lattice spacing of nanometer order. It has a lattice structure and is known to have functions such as storage, separation, and catalytic reactions of substances. Examples of organometallic complexes include activated carbon, which is a graphite-based carbon material, and silicon and aluminum. Compared with other conventionally known porous materials such as zeolites, which are mainly composed of aluminum, The volume is very large, and the chemical environment within the pores can be designed to provide specific substance adsorption properties.

[0003] In addition to the solvothermal method and autoclave method, there are also other methods for generating organometallic complexes. The microreactor method has been studied. A microchannel with an inner diameter of several tens of nanometers to several millimeters is formed on a glass substrate. By flowing two reacting fluids and causing a chemical reaction at the interface region where the two reacting fluids meet, The method is a method for producing a reaction product. The microchannels are arranged in multiple stages, and each microchannel is connected to the middle of each microchannel. The microchannels merge vertically to form a merged channel, and the vertical direction of this merged channel In between, a continuous reaction interface is formed where the reaction fluids from each microchannel come into contact. A microreactor having a microchannel structure is disclosed in Patent Document 1. The microreactor installed on the reactor allows for the simultaneous separation and extraction of reaction products and catalysts used in the reaction. This can improve the reaction efficiency. [Prior art documents] [Patent documents]

[0004] [Patent Document 1] JP 2004-181298 A Summary of the Invention [Problem to be solved by the invention]

[0005] However, in the microreactor described in Patent Document 1, the reaction pathway is Because of the relatively small diameter, clogging of the reaction pathway by reaction products may occur. It is believed that if clogging occurs in the reaction pathway, the productivity of the reaction product will decrease. This problem is not limited to the generation of organometallic complexes, but also applies to the generation of liquids. It is generally generated when reaction products are produced by reactions between biological materials. It is possible.

[0006] Therefore, the present invention provides a reaction product that can suppress the occurrence of clogging and improve productivity. The object is to provide an object generating device and an object generating method. [Means for solving the problem]

[0007] A generating device according to one aspect of the present disclosure includes a plurality of nozzles for ejecting a liquid material, each of which includes: The liquid material is injected from multiple pumps into the nozzles, and the liquid material is then sprayed simultaneously. and a recovery section for recovering the reaction product produced by the reaction of the two nozzles. The liquid material is injected toward one reaction space in the space outside the reaction space.

[0008] A method for producing a reaction product according to an embodiment of the present disclosure includes spraying each of a plurality of liquid materials. Injecting each liquid material toward one reaction space in the space outside the nozzle and generating a reaction product by reacting the respective ejected liquid materials with each other. and recovering the product. Effect of the Invention

[0009] According to the present invention, a reaction product capable of suppressing the occurrence of clogging and improving productivity is obtained. An apparatus and method for generating [Brief description of the drawings]

[0010] [Figure 1] FIG. 1 is a front view showing a schematic configuration of a generation device 100 according to an embodiment of the present disclosure. [Diagram 2] FIG. 2 is a perspective view of a support member 170 on which the material supply unit 110 and the air injection unit 140 of the production device 100 according to the present embodiment are provided. [Diagram 3] FIG. 2 is a front view of a support member 170 on which the material supply unit 110 and the air injection unit 140 of the production apparatus 100 according to the present embodiment are provided. [Figure 4] 1A and 1B are bottom views of a support member 170 on which the material supply unit 110 and the air injection unit 140 of the production apparatus 100 according to this embodiment are provided. [Diagram 5] 1 is a schematic cross-sectional view of the vicinity of an air injection unit 140, a first material supply unit 110a, and a second material supply unit 110b. [Figure 6] 1 is a schematic cross-sectional view of the vicinity of an air injection unit 140, a first material supply unit 110a, and a second material supply unit 110b. [Figure 7] FIG. 13 is an enlarged top view showing a part of a material supplying section 110A of a modified example. [Figure 8] FIG. 13 is an enlarged top view showing a part of a material supplying section 110B of a modified example. [Figure 9] FIG. 13 is an enlarged top view showing a part of a material supplying section 110C of a modified example. [Figure 10] FIG. 13 is a top view of a support member 170G of a generating device according to another embodiment. [Figure 11] FIG. 11 is a cross-sectional view of a support member 170G of a generating device according to another embodiment. [Figure 12] 1 is a flow chart of a method for producing a reaction product according to an embodiment of the present disclosure. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0011] Hereinafter, the present embodiment will be described with reference to the accompanying drawings. Therefore, the same reference numerals are used to refer to the same components in each drawing as much as possible to avoid duplication. In addition, each drawing may show an X-axis, a Y-axis, and a Z-axis. The X-axis and Z-axis form a right-handed three-dimensional Cartesian coordinate system. Hereinafter, the arrow direction of the X-axis is referred to as the +X direction The direction opposite to the arrow is called the -X direction. The same applies to the other axes. The -Z direction is sometimes called the "upper" or "upper" direction, and the -Z direction is sometimes called the "lower" or "lower" direction. In addition, the planes perpendicular to the X-axis, Y-axis, and Z-axis are called YZ planes, ZX planes, and XY planes. However, these directions are used for convenience to explain the relative positional relationship. Therefore, these directions do not define absolute positional relationships.

[0012] (Reaction product generating device) Hereinafter, a reaction product generating apparatus 100 according to an embodiment of the present disclosure will be described. In the following, a reaction product generating apparatus 100 is used to react a metal salt with an organic compound. As a result, the reaction product is an organometallic complex (Metal-Organic Framework (MOF)) An example of generating the following will be described.

[0013] FIG. 1 is a front view showing a schematic configuration of a generating device 100 according to an embodiment of the present disclosure. As shown in FIG. 1, the generator 100 includes a plurality of nozzles 112, a plurality of pumps 120, and , and a recovery section 130.

[0014] Each of the plurality of nozzles 112 is configured to eject a liquid material 152, which will be described below. The plurality of nozzles 112 includes a first nozzle 112a and a second nozzle 112b. The first nozzle 112a ejects the first liquid material 152a. The second nozzle 112b ejects the second liquid material 152b. The first nozzle 112a and the second nozzle 112b are arranged on the outer side of the nozzle. One reaction space in the space (outside the first nozzle 112a and outside the second nozzle 112b) The liquid materials 152a and 152b are configured to be ejected toward M1, respectively. In the generating device 100 according to this embodiment, the multiple nozzles 112 The material supply unit 110 is a part of the material supply unit 110. The material supply unit 110 includes a first material supply unit 110a and a second material supply unit 110b. supply unit 110b, the first nozzle 112a being part of the first material supply unit 110a, The second nozzle 112b is a part of the second material supply unit 110b. The reaction space M1 is filled with a first liquid material 152a supplied from a first nozzle 112a and a second liquid material 152b supplied from a second nozzle 112b. The second liquid material 152b supplied from the nozzle 112b joins the first liquid material 152a. The space includes a central axis of a flow path in the first nozzle 112a and a central axis of a flow path in the second nozzle 112b. This is the area that includes the intersection with the central axis of the flow channel.

[0015] The plurality of pumps 120 includes a first pump 120a and a second pump 120b. The pump 120a is connected to a first liquid material storage section 150a via a first supply pipe 160a. The first pump 120a pumps the first liquid material 1 stored in the first liquid material storage section 150a. The second pump 120b pumps the second liquid material 52a to the first material supply unit 110a. The second pump 120b is connected to the second section 150b via a second supply pipe 160b. The second liquid material 152b stored in the liquid material storage section 150b is supplied to the second material supply section 110b. As a result, the first pump 120a pumps the first liquid material 15 to the first nozzle 112a. The second pump 120b pumps the second liquid material 152b to the second nozzle 112b. send out.

[0016] As the first pump 120a and the second pump 120b, a non-pulsating (non-pulsating flow) pump is used. A non-pulsating pump may be used as the first pump 120a and the second pump 120b. This allows the first liquid material 152a and the second liquid material 152b to be supplied at a constant flow rate. Therefore, the first liquid material 152a and the second liquid material 152b can be mixed with each other without being overly mixed. It is possible to react without any delay. For example, a mono pump is used as a non-pulsating pump. Alternatively, a pump with pulsation may be improved to have no pulsation. In addition, the first pump 120a and the second pump 120b may be the same or different. For example, a pump with pulsation can be used. A jar pump or a gear pump can also be used.

[0017] The recovery unit 130 is configured to recover each of the nozzles 112 (the first nozzle 112a and the second nozzle 112 b) between the liquid materials (the first liquid material 152a and the second liquid material 152b) supplied from The reaction product 190 produced by the reaction is collected.

[0018] The generating device 100 according to this embodiment may include an air injection unit 140. The unit 140 injects air toward the reaction space M1 to inject the reaction product generated in the reaction space M1. The product 190 is blown toward the collection section 130. In this case, the air injection unit 140 is configured to inject air vertically downward (i.e., in the -Z direction). 1, the reaction space includes an air injection nozzle 142 configured to M1 is the injection opening 118a of the first nozzle 112a of the first material supply unit 110a and the injection opening 118b of the second material supply unit 110b. The air jet is disposed outside the jet opening 118b of the second nozzle 112b of the feed supply unit 110b. The air injection nozzle 142, which is the part 140, injects air in the direction (-Z direction). 3. It is located downstream of the injection nozzle 142.

[0019] In the production apparatus 100 according to this embodiment, a first material supply including a first nozzle 112a a second material supply unit 110b including a second nozzle 112b, and an air injection unit 140 The generating device 100 according to the present embodiment also includes the following components: The heating unit 180 (see FIG. 3) is included. The heating unit 180 will be described later.

[0020] 2 to 4, the nozzle 112 and the air injection unit 140 of the generating device 100 are 2, 3, and 4 are perspective views of the support member 170. 1 is a front view seen from the +Y direction, and a bottom view seen from the -Z direction.

[0021] The support member 170 includes a first material supply unit 110a, a second material supply unit 110b, and an air jet. 2, the outer shape of the support 140 is a rectangular parallelepiped. As shown in FIG. 4, the support member 170 has a side surface (YZ surface) in the +X direction and a side surface (YZ surface) in the -X direction. The first material supply unit 110a is provided on the side surface (YZ surface) of the substrate 100 and the upper surface (XY surface) in the +Z direction of the substrate 100. The supply unit 110b and the installation units 172a, 172b, and 17 The installation portion 172a and the installation portion 172b are provided in the Z direction. The first material supplying portion 11 is provided at the same height and facing each other in the X direction. 0a indicates that the ejection opening 118a of the first nozzle 112a faces the -X direction with respect to the installation portion 172a. The second material supply unit 110b is disposed so as to face the second material supply unit 110b with respect to the installation unit 172b. The nozzle 112b is arranged so that the ejection opening 118b faces the +X direction. The first nozzle 112a of the material supply unit 110a and the second nozzle 11 2b are arranged to face each other in the X direction. More specifically, the first material supply The first nozzle 112a of the material supply unit 110a and the second nozzle 112b of the material supply unit 110b The center of the opening 118a (the center in a cross section perpendicular to the X direction) and the center of the opening 118b The opening 118a is arranged so that the line connecting the openings 118a and 118b is parallel to the X direction. The case where the straight line connecting the center of the opening 118b and the center of the opening 118b is parallel to the X direction is However, the present invention is not limited to this. For example, the central axis (opening) of the flow path of the first material supply unit 110a may be the axis perpendicular to the opening 118a) and the central axis of the flow passage of the second material supply unit 110b (the axis perpendicular to the opening 118a) The axis perpendicular to the first material supply may be inclined with respect to the X direction. The central axis of the first material supply unit 110a and the central axis of the second material supply unit 110b are aligned along the X-axis (the axis extending in the X-direction). It may be tilted by ±10° relative to the

[0022] In addition, a mixing gap 174 is provided on the lower surface side of the support member 170 in the -Z direction. The space 174 is provided with a first material 152a supplied from the first material supply unit 110a and a second material supply unit 152b. The mixing space 174 reacts with the second material 152b supplied from the supply unit 110b. is provided so as to open downward (in the -Z direction) of the support member 170. In this way, the upper surface (+Z surface) of the mixing space 174 is a cross-sectional view (a cross-section perpendicular to the Y direction (X The mixing space 174 has a generally semicircular shape that is convex upward in the +Z direction. The inner surface of the mixing chamber has a semi-spherical surface that is convex upward. The opening 174a of the joining space 174 is circular.

[0023] FIG. 5 shows a schematic diagram of the reaction that proceeds inside the support member 170. In this way, the first material fed from the first nozzle 112a of the first material supply unit 110a in the −X direction is The liquid material 152a is fed in the +X direction from the second nozzle 112b of the second material supply unit 110b. The second liquid material 152b is mixed with the first liquid material 152b in the mixing space 174 of the support member 170. The first liquid material 152a and the second liquid material 152b collide in a reaction space M1 including a joining point. In this embodiment, the first liquid material 152a contains a metal salt, and the second liquid material 15 The first liquid material 152a and the second liquid material 152b include an organic compound. As a result, the metal salt in the first liquid material 152a and the organic compound in the second liquid material 152b are mixed. The reaction is carried out to generate a substance that will become the core of the organometallic complex as a reaction product. At this time, in the generating device 100, the air injection unit 140 injects the air into the mixing space 174. Air is injected into the reaction space M1 in the -Z direction. The substance that becomes the core of the organometallic complex generated by the collision with the second liquid material 152b is in the -Z direction. The core material of the organometallic complex is blown away in the direction of the opening 174a of the mixing space 174. The reaction product is discharged from the support member 170 in the -Z direction to the outside. The substance that becomes the core of the organometallic complex is collected by the collection unit 13 provided in the −Z direction of the support member 170. It is retrieved by 0.

[0024] The following describes the effects of the generating device 100 according to this embodiment.

[0025] Conventionally, various methods have been used to generate reaction products. For example, In the case where a metal salt is reacted with an organic compound to produce an organometallic complex as a product, For example, the solvothermal method and the autoclave method have been used. Liquid materials containing metal salts and liquid materials containing organic compounds were mixed using the autoclave method and the autoclave method. A batch synthesis method in which the and are reacted in a vessel heated and pressurized to a specified temperature and pressure. Organometallic complexes can be formed.

[0026] In addition, methods for generating organometallic complexes include the solvothermal method and the autoclave method. In the past, microreactor methods have been considered. A microchannel having an inner diameter of several tens of nanometers to several millimeters is formed on a ceramic substrate. Two reactant fluids are then passed through the interface, where a chemical reaction occurs. The microreactor method is a method for producing a reaction product by However, it is possible to produce nano-level organometallic complexes with uniform molecular diameters. Due to the reactor structure, which is characterized by its small diameter (e.g. 60 μm), Blockages may occur in the

[0027] In the generation device 100 according to this embodiment, the plurality of nozzles 112a and 112b Each of them sprays liquid material toward one reaction space M1 in the outer space. In such a configuration, the reaction products generated by the collision of the liquid materials are It is generated in the large space outside each nozzle, not inside, which can lead to clogging. Never.

[0028] In addition, in the microreactor method, for example, clogging occurs in the reaction path. It is considered that the productivity of the reaction product may decrease when the reaction mixture is heated. In the case of 100, the occurrence of clogging can be suppressed, and as a result, the productivity of the reaction product can be increased. It can also be improved.

[0029] In the production device 100 according to this embodiment, the first pump 120a and the second pump The first liquid material 152a and the second liquid material 152b are continuously dispensed by the tap 120b. Since the reaction product can be continuously produced, the reaction product can be continuously produced. In the Bose-thermal and autoclave processes, a relatively large amount of reaction product can be produced at one time. However, because it is a batch type, continuous production is not possible. The apparatus 100, with the above-mentioned configuration, is capable of continuously producing the pulp and paper while improving productivity compared to the conventional method. This becomes possible.

[0030] Furthermore, the generating device 100 according to this embodiment is provided with an air injection unit 140. In the generation device 100 according to this embodiment, the reaction is performed by the air injection unit 140. Air is sprayed toward the space M1, which produces reaction products of a more uniform size. The reaction can be carried out by batch methods such as the solvothermal method and the autoclave method. In this case, the reaction product is generated by the collision of the liquid material 152a and the liquid material 152b. The core substances of an organometallic complex may further bond together to become larger. However, in the production device 100 according to this embodiment, a reaction that produces a reaction product is carried out. By injecting air into the reaction space M1, adhesion of reaction products to each other is suppressed. This allows the reaction products to be more uniform in size. It is also possible to suppress variation in the size of the reaction products produced.

[0031] In the generating apparatus 100 according to this embodiment, the first nozzle 1 of the first material supply unit 110a The nozzle 12a is configured to eject the first liquid material 152a at a first flow rate, which is a constant flow rate. Similarly, the second nozzle 112 of the second material supply unit 110b may be configured. b is a second pump 1 so as to inject the second liquid material 152b at a second flow rate which is a constant flow rate. 50b may be configured. The first flow rate and the second flow rate may be, for example, predetermined flow rates. At this time, the first liquid material 152a and the second liquid material 152b are supplied at a constant flow rate. Therefore, it is possible to react with each other without excess or deficiency. For example, the flow rate is 200 ml / 5 min (40 ml per minute). In this case, the flow rate does not have to be constant. For example, the flow rate may be dynamically changed. .

[0032] In this embodiment, the first liquid material 152a is sprayed from the first nozzle 112a. The injection pressure and the injection pressure at which the second liquid material 152b is injected from the second nozzle 112b are both This is set to be larger than the pressure at which air is injected from the air injection unit 140. As a result, the first liquid material 152a and the second liquid material 152b collide with each other and react with each other. This can prevent the air from being blown away by the air injected by the air injection unit 140. The ejection pressure of the first liquid material 152a and the ejection pressure of the second liquid material 152b can be adjusted. The injection pressure is controlled by the first pump 150a and the second pump 152b, respectively. This is also fine.

[0033] In the generating apparatus 100 according to this embodiment, the first nozzle 1 of the first material supply unit 110a The injection opening 118a of the second nozzle 112b of the second material supply unit 110b is The distance between the opening 118b and the opening 118c is 0.05 mm or more and 1.0 mm or less (distance D1 shown in FIG. 6). 6 shows the air injection unit 140, the first material supply unit 110a, and the 1 is a schematic cross-sectional view for explaining the relationship between the first material supply unit 110b and the second material supply unit 110b. On a straight line connecting the central axis of the flow channel in nozzle 112a and the central axis of the flow channel in nozzle 112b 6, the distance between the injection opening 118a and the injection opening 118b. As shown, the distance D1 is the distance between the center of the ejection opening 118a and the center of the ejection opening 118b. The ejection opening 118a and the ejection opening 118b are, for example, circular. The center of the injection opening 118a is the center of a circle of a cross section perpendicular to the X direction of the injection opening 118a. The center of the injection opening 118b is the center of a circle of a cross section perpendicular to the X direction of the injection opening 118b. It is.

[0034] When the distance D1 between the ejection opening 118a and the ejection opening 118b is less than 0.05 mm The liquid material 152a and / or the liquid material 152b to be ejected, or the liquid material 152a and the liquid The reaction product generated by the reaction with the substrate material 152b is scattered and is injected into the injection opening 118a and and / or the injection opening 118b, and the first nozzle 112a and / or the second nozzle 11 2b may become clogged. By setting the thickness to 0.05 mm or more, the scattered liquid materials 152a and 152b and the reaction products can be prevented from being scattered. The nozzles (the first nozzle 112a and the second nozzle 112b) are prevented from being clogged due to the composition or the like. In addition, the distance between the first material supply unit 110a and the second material supply unit 110b can be reduced. By setting the distance to 1.0 mm or less, the first liquid material 152a and the second liquid material 152b Therefore, the productivity of the reaction product can be improved. This can be done.

[0035] In the generation device 100 according to this embodiment, the air injection nozzle of the air injection unit 140 The injection opening 148 of the nozzle 142 is the injection opening of the first nozzle 112a of the first material supply unit 110a. The mouth portion 118a and the injection opening portion 118b of the second nozzle 112b of the second material supply portion 110b The distance (D2 in Fig. 6) from the line (L1 in Fig. 6) connecting the The distance may be greater than or equal to 10.0 mm.

[0036] In this embodiment, the liquid materials 152 (first liquid The reaction product ( For example, the number of nuclei of the organometallic complex is reduced, and then the nuclei are blown away by a jet of air as described above. By configuring in this way, further crystal growth and adhesion to each other can be suppressed. This allows the generation of reaction products of relatively uniform size. When the need to reduce the number is relatively small, the space where the liquid materials 152 join together is very small. It doesn't have to be space.

[0037] In the generating device 100 according to this embodiment, the air injection unit 140 is The injection opening 118a of the first nozzle 112a of the supply unit 110a and the injection opening 118b of the second nozzle 112a of the supply unit 110b are With respect to the straight line (straight line L1 shown in FIG. 6) connecting the injection opening 118b of the second nozzle 112b The air ejection unit 140 is disposed in the -Z direction. Therefore, in FIG. 6, the angle θa between the injection direction of the injection opening 148 and the straight line L1 is 90°. However, the arrangement of the air injection unit 140 is not limited to this. , the injection opening 118a of the first nozzle 112a of the first material supply unit 110a, and the injection opening 118b of the second material supply unit The air gap with respect to a straight line L1 connecting the injection opening 118b of the second nozzle 112b of the first nozzle 110b The angle θa of the gas ejection direction may be greater than or equal to 45° and less than or equal to 135°.

[0038] Furthermore, in the generating apparatus 100 according to this embodiment, the first material supply unit 110a The injection opening 118a of the nozzle 112a and the second nozzle 112b of the second material supply unit 110b The diameter of the injection opening 118b may be, for example, not less than 0.1 mm and not more than 1.0 mm. In addition, the first nozzle 112a of the first material supply unit 110a and the second nozzle 112b of the second material supply unit 110b The ejection pressure of the first liquid material 152a and the ejection pressure of the second liquid material 152b from the nozzle 112b are For example, it may be 0.05 MPa or more and 1.00 MPa.

[0039] The distances between the components and the arrangement angles described above are merely examples, and other sizes may also be used. In addition, the liquid material used, the environment in which it is used, and the particle size of the reaction product that is generated can be easily determined. For example, the injection pressure of the air injection unit 140 can be changed depending on the reaction product. The particle size may be changed according to the target particle size of the product and the target variation of the particle size. good.

[0040] In the generating device 100 according to this embodiment, as described above, the heating unit 180 is further provided. As shown in FIG. 3, the heating unit 180 may be a heating coil. For example, a coil-shaped heating unit 180 provided around the first material supply unit 110a may be used. a, a coil-shaped heating unit 180b provided around the second material supply unit 110b, and an air jet. and a coil-shaped heating section 180c provided around the radiating section 140.

[0041] For example, the first liquid material 1 sprayed from the first nozzle 112a of the first material supply unit 110a 52a and the second liquid material 1 sprayed from the second nozzle 112b of the second material supply unit 110b. 52b are reaction spaces after being heated by the heating units 180a and 180b, respectively. The air injected from the air injection unit 140 may be injected toward the heating unit M1. After being heated by 180c, it may be injected toward the reaction space M1.

[0042] As illustrated in FIG. 3, the heating unit 180 includes a first material supply unit 110a, a second material supply unit 110b, and a The air injection unit 10b and the air injection unit 140 may be provided separately, but is not limited to this. Alternatively, the heating unit 180 may be the air injection unit 140, the first material supply unit 110a, and The heating unit 110b may be provided for two or all of the first material supply unit 110a and the second material supply unit 110b. 80 may be provided to heat the entire support member 170, or each fluid may be supported by For example, the first supply pipe 160a and the second supply pipe 160b are heated before being supplied to the support member 170. The heating unit 180 may be configured, for example, using an electric heating wire or the like. The liquid material 152 sprayed by the material supply unit 110 and the air spray unit 140 may be used. The extent to which the injected air is heated depends on, for example, the reacting materials and production volume. It may be set appropriately depending on the situation.

[0043] The air injection unit 140, the first material supply unit 110a, the first nozzle 112a, and the second nozzle 1 12b) is not particularly limited, and any conventionally known nozzle can be used. The nozzles used in the air injection unit 140, the first nozzle 112a, and the second nozzle 112b As the nozzle, for example, a straight nozzle or a conical nozzle can be used.

[0044] The injection nozzle 142 of the air injection unit 140 is configured to have a shape of the injected air (perpendicular to the injection direction). The cross-sectional shape (in Fig. 1, the cross-sectional shape parallel to the XY plane) is rectangular. Such a nozzle may be called a slit-type air nozzle, etc. In addition, the shape of the ejected air (on the XY plane) of the ejection nozzle 142 of the air ejection unit 140 is The nozzle may have a circular shape in a parallel cross section. The air flows in a cylindrical or conical shape. The size and injection pressure can be appropriately set based on the reaction products to be generated, the reaction rate, etc. do.

[0045] (Modification) 7 to 9, a modified example of the reaction product generating device of this embodiment will be described. The reaction product generating apparatus 100 described above has two nozzles 112 (first nozzle 112a and and the second nozzle 112b (i.e., two material supply units 110 (first material supply unit 110a and The embodiment has been described with reference to an example in which the nozzles 112 are provided with the first material supply unit 110b) and the second material supply unit 110c). For example, when a reaction product is produced using three or more liquid materials, More than one nozzle 112 may be provided, and more than two material supply units 110 may be provided. good.

[0046] FIG. 7 is an enlarged top view diagrammatically illustrating the reaction space M1 and its surroundings of the material supply unit 110A of the modified example. 7 is a top view of the material supply unit 110A of the modified example as viewed from the +Z direction. As shown in FIG. 7, the material supply unit 110A includes three material supply units 11 The material supply unit 110a1, the material supply unit 110a2, and the material supply unit 110a3 are provided. A is used when three kinds of liquid materials 152 are reacted. As shown in FIG. The material supply unit 110A includes the material supply unit 110a1, the material supply unit 110a2, and the material supply unit 1 10a3 are arranged to form an angle of 120° with each other. The material supply unit 110a1, the material supply unit 110a2, and the material supply unit 110a3 are a reaction space. They are arranged at equal intervals in the circumferential direction of a circle centered around M1. The supply unit 110a1, the material supply unit 110a2, and the material supply unit 110a3 are thus By being evenly distributed, the supporting member 170 equipped with the material supplying unit 110A has three types The liquid materials can be collided and reacted with each other under the same conditions.

[0047] When three kinds of liquid materials are reacted, for example, the two material supply systems described with reference to FIG. In the same configuration as the generating device 100 according to this embodiment, which includes the units 110a and 110b, A solution obtained by combining two kinds of liquid materials is sprayed from the first nozzle 112a, and the remaining solution is sprayed from the second nozzle 112b. It is also possible to eject the two from the nozzle 112b and cause the reaction. Before the solution made by combining the liquid materials is collided with the remaining solution, the first nozzle is The solid product produced by the reaction between the two solutions grows inside the first nozzle 112a. This causes a problem that the solution in the first nozzle 112a becomes suspended and causes clogging. In contrast, as in the material supply unit 110A of the modified example, three kinds of liquid materials are reacted. When the three material supply units 110a1, 110a2, and 110a3 are used, This eliminates the need to synthesize two types of solutions in advance, and prevents clogging inside the material supply unit 110. Therefore, the productivity of the reaction product using the three solutions can be improved. can be done.

[0048] In the same manner as the material supply unit 110A shown in FIG. 7, when four or more kinds of liquid materials are used for reaction, Even in this case, the angle between the material supply units 110 is adjusted according to the number of the material supply units 110. For example, the distance may be calculated by dividing the distance by 360° by the number of nozzles (the number of material supply units 110). Alternatively, the material supply units 110 may be equally spaced apart from each other so as to form an angle therebetween.

[0049] FIG. 8 is a top view, seen from the +Z direction, of a material supply unit 110B according to another modified example. The material supply unit 110B is used when reacting four types of liquid materials 152. As shown in FIG. 8, the material supply unit 110B includes four material supply units 110b1, 110b2, a material supply unit 110b3, and a material supply unit 110b4. 0b1, material supply unit 110b2, material supply unit 110b3, and material supply unit 110b4 are For example, they are equally spaced at 90° angles to each other.

[0050] FIG. 9 is a schematic diagram showing a material supply unit 110C according to still another modified example. The liquid material 152 is used to react with six kinds of liquid materials 152. The material supply unit 110C includes six material supply units 110c1, 110c2, and 110c3, material supply unit 110c4, material supply unit 110c5, and material supply unit 110c6 The material supply unit 110c1, the material supply unit 110c2, the material supply unit 110c3, The material supply unit 110c4, the material supply unit 110c5, and the material supply unit 110c6 are, for example, six They are evenly spaced to form an angle of 0°.

[0051] As another modification, for example, when five kinds of liquid materials 152 are reacted, Five material feeds are placed at an angle of 72°, calculated by dividing the angle by the number of nozzles (5). The sections 110 may be equally spaced.

[0052] Even when reacting three or more kinds of liquid materials, the air injection unit 140 By injecting air in the -Z direction toward the reaction space M1, two types of liquid materials were used. As with the case of using two types of liquids, it is possible to control the particle size of the reaction product and improve productivity. When using a plastic material, as described above, the cross-sectional shape of the injected air flow is rectangular or A circular air injection unit 140 may be used. Also, three or more material supply units 110 may be used. In this case, the air injection part 140 (i.e., the injected air) has a circular cross-sectional shape. It is preferable to use an air jet 140 having a cylindrical (or conical) shape. By using the air injection unit 140 having a circular cross-sectional shape, the cross-sectional shape of the injected air flow can be, for example, The reaction space M1 is supplied with the liquid so that the center of the circle is near the center of the reaction space M1. By injecting air into the liquid material 152 supplied from each material supply unit 110, It is possible to inject air at a relatively uniform injection pressure against the liquid material 152 being injected. This allows the reaction between the liquid materials 152 to proceed relatively uniformly.

[0053] 10 and 11, a plurality of nozzles 112 and material supply units 110 are provided. An example of a possible generating device will be described. FIG. 10 shows the supporting structure of the generating device according to another embodiment of this case. FIG. 11 is a schematic top view of the support member 170G as viewed from the +Z direction (top view parallel to the XY plane); FIG. 11 is a cross-sectional view of the support member 170G as viewed from the +Y direction (a cross-sectional view parallel to the XZ plane). .

[0054] As shown in FIG. 10, the support member 170G has six nozzle mounting portions 172g1, 17 2g2, 172g3, 172g4, 172g5, and 172g6 (hereinafter, the six The nozzle mounting portions are collectively referred to as nozzle mounting portions 172g. , 172g2, 172g3, 172g4, 172g5, and 172g6, respectively. Material supply units 110g1, 110g2, 110g3, 110g4, 110g5, and 110 The nozzle g6 is disposed in the support member 170G. The outer shape of the support member 170G is cylindrical. 10, the outer shape of the support member 170G is circular in top view, and as shown in FIG. As shown, the outer shape of the support member 170G is rectangular (e.g., long) in a cross section parallel to the XZ plane. (rectangular).

[0055] In the support member 170G, material supply units 110g1, 110g2, 110g3, and 11 In the case shown in FIG. In this case, all six nozzle installation parts 172g1, 172g2, 172g3, 172g Six material feeders 110g1, 110g2, 110g4, 172g5, and 172g6 3, 110g4, 110g5, and 110g6 are arranged, and six types of liquid The reaction by the substrate material 152 is allowed to proceed. 2g1, 172g2, 172g3, 172g4, 172g5, and 172g6 are all The material supply units 110g1, 110g2, 110g3, and 110g4 are all the same size and shape. 0g4, 110g5, and 110g6 are also the same size and shape.

[0056] For example, in the case where a reaction is caused to proceed using two kinds of liquid materials 152 as described with reference to FIG. In this case, six nozzle installation parts 172g1, 172g2, 172g3, 172g4, 172 Of the two, 172g5 and 172g6, only the nozzle installation parts 172g1 and 172g4 are The material supply units 110g1 and 110g4 can be installed and used. , unused nozzle mounting parts 172g2, 172g3, 172g5, and 172g6 Therefore, by blocking the area, it is possible to prevent the splashing of liquid materials and the adhesion of reaction products. This is preferable because it can suppress the

[0057] In addition, in the case of reacting three kinds of liquid materials 152 described with reference to FIG. Three material supply units 11 are provided for the three nozzle installation units 172g1, 172g3, and 172g5. By installing 0g1, 110g3, and 110g5, three types of liquid materials were It can be used as a generator for generating reaction products by reacting. The uncovered nozzle installation parts 172g2, 172g4, and 172g6 are covered. It is preferable to keep

[0058] As described with reference to FIGS. 7 to 9, three or more types of liquid materials are collided and reacted with each other. In this case, the number of nozzles 112 in the material supply unit 110 is increased. The support member 170 is processed in combination with the support member 170 shown in FIGS. 70G, the nozzle installation portion 172g is of the same size and shape, and the material supply portion 110 By making the size and shape of the material supplying unit 110 the same, the material supplying unit 110 can be unitized. Then, the nozzle 112 of the material supply unit 110 is set according to the type of liquid material 152 to be reacted. It can be inserted into the nozzle installation portion 172g for use, making it a versatile support member. In this case, the overall outer shape of the support member 170G can be made as shown in FIG. By making the shape cylindrical, the liquid materials 152 are allowed to join together in the reaction space M1. Each nozzle installation part 172g and each nozzle of the material supply part 110g are 112 can be arranged symmetrically.

[0059] The support member 170G described with reference to FIGS. 10 and 11 has six nozzle mounting portions 172. g, in the case where two, three, or six kinds of liquid materials 152 are reacted, However, as another modification, for example, the center point near the reaction space M1 may be set as the center. By providing eight nozzle mounting sections spaced at 45° angles from each other, , 2, 4, or 8 types of liquid material 152 are mixed and reacted. The number of nozzle installation parts 172 is not limited to six or eight, and can be any number with respect to the support member 170. The nozzle installation portion 172 is appropriately provided according to the number of liquid materials that may be simultaneously ejected. Of the nozzle installation parts 172 provided, depending on the number of liquid materials to be reacted, The nozzle 112 of the material supply unit 110 is disposed in the nozzle installation unit 172, and the reaction product is generated. It may also be used in.

[0060] (Method of Producing Reaction Products) With reference to FIG. 12, a method for producing a reaction product according to an embodiment of the present disclosure will be described. FIG. 12 is a flow chart of a method for producing a reaction product according to an embodiment of the present disclosure.

[0061] First, a reaction space is formed in the space outside the nozzle that sprays each of the multiple liquid materials. Each liquid material is sprayed toward the target object (S1202).

[0062] Next, the sprayed liquid materials react with each other to generate reaction products (S12 04).

[0063] Next, the generated reaction products are collected (S1206).

[0064] As a result of the above, a reaction product is produced.

[0065] The reaction product generating apparatus and the reaction product generating method according to the present embodiment are used to generate an organometallic complex. In the case of generating the above, for example, the nucleus of the organometallic complex recovered in the recovery section 130 is The core material of the organometallic complex is collected from the suspension containing the material using a centrifuge or other device, and then dried. After drying and activation, crystals of the organometallic complex can be obtained. The reaction product generating apparatus and the reaction product generating method according to the present embodiment include a method for generating a reaction product by using a plurality of liquid materials. In particular, it can be used to produce a variety of reaction products produced by reacting It can also be used in the production of organometallic complexes produced by the reaction of organic compounds with metal salts. The reaction product generating device and the reaction product generating method according to the present embodiment can be used. The organometallic complexes that can be produced include ZIFs, HKUSTs, ELMs, and SIFs. SIX, JAST, and CPL. The organometallic complex produced by the reaction product producing apparatus and the reaction product producing method is applied to, for example, a nonwoven fabric. It can be used as a filter to selectively separate the target substance by adhering it.

[0066] The above-described embodiment is intended to facilitate understanding of the present invention and does not limit the present invention. The elements of the embodiment and their arrangements, materials, conditions, etc. The shape and size are not limited to those shown in the examples and can be changed as appropriate. In addition, configurations shown in different embodiments may be partially substituted or combined. It is Noh. [Explanation of symbols]

[0067] 100... generating device, 110... material supply unit, 112... nozzle, 118a, 118b... injection opening A nozzle portion, 120... a pump, 130... a collection portion, 140... an air injection portion, 150a... a first liquid material Storage section, 150b... second liquid material storage section, 152... liquid material, 170... support member, 174 ...mixing space, 174a...opening, 180...heating mechanism, 190...reaction product, M1...reaction space between

Claims

1. A plurality of nozzles for ejecting liquid material; a plurality of pumps for pumping liquid material to each of said nozzles; The reaction products generated by the reaction between the liquid materials sprayed from each of the nozzles are circulated. A recovery section for collecting the wastewater, Each of the nozzles sprays liquid material toward one reaction space in the outer space.

36. A generating device configured to emit a beam of light.

2. By injecting air into the reaction space, the reaction product generated in the reaction space is The generator of claim 1 , further comprising an air jet for blowing air towards the collection section.

3. The generating device according to claim 2 , wherein the air injection unit injects air vertically downward.

4. The plurality of nozzles include a first nozzle for spraying a first liquid material including a metal salt, and a second nozzle for spraying an organic compound. A second nozzle for ejecting a second liquid material including The reaction product is an organometallic complex produced by the reaction of the metal salt with the organic compound. The generating device of claim 1 ,

5. 10. The method of claim 1, wherein each of the nozzles ejects the liquid material at a constant flow rate. equipment.

6. The plurality of nozzles includes a first nozzle and a second nozzle, The distance between the injection opening of the first nozzle and the injection opening of the second nozzle is 0.05 mm.

2. The generator of claim 1 , wherein the first and second electrodes are spaced apart from each other by a distance of at least 1.0 mm and no more than 1.0 mm.

7. 2. The method according to claim 1, wherein the liquid material is heated before being sprayed toward the reaction space. generator.

8. A nozzle is provided to inject each of the liquid materials into a reaction space outside the nozzle. and ejecting each of the liquid materials. generating a reaction product by reacting the ejected liquid materials with each other; and recovering the reaction product.

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