Four-fluid bipolar plate for fuel cell

Abstract

To provide a bipolar plate that provides improved delivery of humidified reactants and better removal of produced water.SOLUTION: A bipolar plate 100 for a fuel cell includes a non-porous subplate 102 and a porous subplate 104. The non-porous subplate 102 includes a water management surface 122, a reactant surface on the opposite side, and an internal coolant passage between the two surfaces. The porous subplate 104 includes a reactant surface and a water management surface on the opposite side. The reactant surface includes a first reactant flow field. The water management surface is fluidically connected to the water management surface of the non-porous subplate.SELECTED DRAWING: Figure 3

Description

[Technical field]

[0001] CROSS-REFERENCE TO RELATED APPLICATIONS This application references and claims priority to and the benefit of U.S. patent application Ser. No. 17 / 344,377, entitled "FOUR-FLUID BIPOLAR PLATE FOR FUEL CELL," filed June 10, 2021, which is incorporated by reference in its entirety herein. [Background technology]

[0002] The present disclosure relates generally to fuel cell bipolar plates, and more specifically to a bipolar plate structure that provides improved delivery of humidified reactants and better removal of product water.

[0003] In a proton exchange membrane (PEM) fuel cell, hydrogen fuel is supplied to the negative electrode (anode), where it undergoes the oxidation reaction H2→2H + +2e - It is catalytically dissociated into a proton and an electron by the proton (H + ) passes through the membrane electrolyte to the positive electrode (cathode), while electrons (e - ) is conducted through an external path, generating a current between the anode and the cathode through an external load. At the cathode, the reduction reaction: O2 + 4e - +4H + Protons and electrons recombine in the presence of oxygen to form water, according to →2H2O. The by-products of the PEM fuel cell reaction are water and heat, which necessitates cooling the fuel cell to maintain an acceptable internal temperature.

[0004] A single fuel cell includes a membrane electrode assembly (MEA) that contains a membrane electrolyte sandwiched between a pair of electrodes (anode and cathode), and adjacent to each electrode on the opposite side from the membrane electrolyte, a conductive plate that defines a reactant gas flow field. A typical flow field plate directs the reactant gases through gas diffusion layers and microporous layers to their respective electrodes. In some designs, the flow field plate can also carry the water by-product out of the cell.

[0005] To increase the electrical output of an electrochemical conversion assembly or fuel cell, multiple fuel cells are typically arranged and connected in series in a stack. In this arrangement, two adjacent cell units can share a common polar plate, which serves as the anode and cathode of the two adjacent cell units connected in series. Such a polar plate is commonly referred to as a "bipolar plate." Summary of the Invention [Means for solving the problem]

[0006] In one embodiment, a bipolar plate for a fuel cell includes a non-porous subplate including at least one water management surface and an internal coolant passage. The bipolar plate further includes a porous subplate including a reactant surface and an opposing water management surface. The reactant surface of the porous subplate includes a first reactant flow field, and the water management surface is fluidly connected to the water management surface of the non-porous subplate.

[0007] In another embodiment, a bipolar plate for a fuel cell includes an oxidant flow field, a fuel reactant flow field, dedicated coolant passages, and a water management flow field.

[0008] In yet another embodiment, a bipolar plate for a fuel cell includes a non-porous subplate having a water management side and a reactant side. The reactant side includes a first reactant flow field. The bipolar plate further includes a porous subplate having a reactant side and an opposing water management side. The reactant side includes a second reactant flow field. The water management side of the porous subplate is fluidly connected to the water management side of the non-porous subplate.

[0009] The features described herein can be better understood with reference to the drawings described below. The drawings are not necessarily to scale, emphasis instead being placed upon illustrating the principles of the invention. In the drawings, like numbers are used to refer to like parts throughout the various views. [Brief description of the drawings]

[0010] [Figure 1] FIG. 1 shows a schematic cross-sectional exploded view of a typical fuel cell. [Diagram 2] FIG. 2 shows a schematic cross-section of a typical fuel cell power plant. [Diagram 3] FIG. 3 shows an exploded perspective view of the anode side of a bipolar plate according to one embodiment of the present invention. [Figure 4] FIG. 4 shows an exploded perspective view of the cathode side of the bipolar plate shown in FIG. [Diagram 5] FIG. 5 shows a further exploded view of the bipolar plate shown in FIG. [Figure 6] FIG. 6 shows a further exploded view of the bipolar plate shown in FIG. [Figure 7] FIG. 7 shows a perspective cross-sectional view of the cathode side of the bipolar plate shown in FIG. [Figure 8] FIG. 8 shows an enlarged cross-sectional view of the bipolar plate shown in FIG. [Figure 9] FIG. 9 shows another perspective cross-sectional view of the cathode side of the bipolar plate shown in FIG. [Figure 10] FIG. 10 shows an enlarged cross-sectional view of the bipolar plate shown in FIG. [Figure 11] FIG. 11 shows a cross-sectional view of a fuel cell having a bipolar plate according to a first embodiment of the present invention. [Figure 12] FIG. 12 shows a cross-sectional view of a stack of fuel cells having bipolar plates according to a first embodiment of the invention. [Figure 13] FIG. 13 shows a schematic cross-sectional view of a fuel cell power plant according to one embodiment of the present invention. [Figure 14] FIG. 14 shows a cross-sectional view of a fuel cell having a bipolar plate according to a second embodiment of the present invention. [Figure 15] FIG. 15 shows a cross-sectional view of a fuel cell having a bipolar plate according to a third embodiment of the present invention. [Figure 16] FIG. 16 shows a cross-sectional view of a fuel cell having a bipolar plate according to a fourth embodiment of the present invention. [Figure 17] FIG. 17 shows a cross-sectional view of a fuel cell having a bipolar plate according to a fifth embodiment of the present invention. [Figure 18] FIG. 18 shows a cross-sectional view of a fuel cell having a bipolar plate according to a sixth embodiment of the present invention. [Figure 19] FIG. 19 shows a cross-sectional view of a fuel cell having a bipolar plate according to a seventh embodiment of the present invention. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0011] 1 shows a typical polymer electrolyte membrane (PEM) fuel cell 10, which generally includes a negative electrode (anode) 12 and a positive electrode (cathode) 14 separated by an ionomer membrane 16. An anode catalyst layer 18 a and the cathode catalyst layer 18 c A catalyst layer 18 is formed on each side of a generally planar membrane to convert hydrogen and oxygen reactant gases into electricity and water. This assembly is commonly referred to as a membrane electrode assembly (MEA) 20. a , 18 c can be the same for the anode 12 and the cathode 14, but typically they are different. For example, the anode catalyst layer 18a may have the function of splitting hydrogen atoms into hydrogen ions and electrons, while the cathode catalyst layer 18 c may have the function of reacting oxygen gas with electrons to form water.

[0012] The reactants (i.e., hydrogen and air) are directed to the MEA 20 by a flow field plate 22 that typically contains reactant flow channels (shown in dashed lines). The flow field plate 22 is shown as a bipolar plate and contains reactant flow channels for both fuel and oxidant. The reactants are transported from the channels to a gas diffusion layer (GDL) 24 adjacent to the flow field plate 22. a ,twenty four c and then through the GDL and each catalyst layer 18 a , 18 c Microporous layer (MPL) 26 located between a , 26 c The GDL may have several functions, such as diffusing the reactant gas stream to the catalyst layer, transporting the liquid and vapor water by-product from the catalyst layer to the cathode gas channel (which is carried by the gas stream), collecting the electric current generated from the electrochemical reaction, and imparting mechanical strength to support and protect the catalyst-coated membrane. The GDL is typically a highly porous (e.g., 60%-90%) carbon fiber nonwoven paper or woven carbon fiber fabric, approximately 0.25-0.35 mm thick, with pore sizes on the order of hundreds of microns, and may be treated with a variety of proprietary substances to improve performance. The MPL functions to minimize the contact resistance between the GDL and the catalyst layer, helping to improve water transport. The MPL typically consists of a thin layer of carbon powder and PTFE particles coated on the GDL, with pore sizes on the order of one micron. Some fuel cells are assembled to produce a membrane electrode assembly (MEA), microporous layer (MPL), and gas diffusion layer (GDL) into a unitary assembly, known as a unitized electrode assembly (UEA).

[0013] FIG. 2 illustrates a typical fuel cell power plant 30 that employs a stack of fuel cells 10 as described in FIG. 1. Fuel, such as hydrogen (H2), is supplied to fuel inlet 32, flows through the anode flow field plate, and is distributed to the anode catalyst layer. Unconsumed fuel exits fuel outlet 34 and returns to fuel inlet 32 ​​through a recycle pump (not shown), where it may be periodically purged to the ambient environment. An oxidant, such as air, is supplied to air inlet 36 by a blower (not shown), flows through the cathode flow field plate, and is distributed to the cathode catalyst layer. Excess process air, humidified by water by-product, exits air outlet 38 and may pass through a radiator and / or condenser (not shown) before being exhausted to the environment.

[0014] The power plant 30 may further include a coolant loop 40 for removing heat from the fuel cells. In many automotive applications, the coolant is a mixture of water and ethylene glycol to prevent the coolant from freezing in cold climates. A pump 42 supplies the coolant to a coolant inlet 44 where it is directed through cooling plates or the like (not shown, but typically located between the fuel cells 10) and distributed over the surfaces of the plates. The fuel cells 10 transfer sensible heat to the circulating coolant, so the coolant becomes warm but does not undergo a phase change. Upon leaving the stack at a coolant outlet 46, the coolant passes through a heat exchanger 48 where sensible heat is removed before being circulated back to the inlet 44. In one example, the heat exchanger 48 is a radiator. A flow control valve or orifice 50 may be used to regulate the flow of the coolant.

[0015] As shown in FIG. 1, the reactant flow field plate 20 is a bipolar plate. Many bipolar plate designs use solid materials, and a few designs use porous materials on both the anode and cathode sides. Each design has its own advantages and disadvantages. Solid bipolar plates, as the name suggests, are excellent at keeping reactant gases separated because they are impermeable to hydrogen fuel. Additionally, solid bipolar plates in a stack are relatively easy to seal due to their impermeable nature. Thus, the power plant stack can be pressurized, which improves cell performance and reduces cell degradation. Another advantage of solid bipolar plates is that their impermeable nature allows the use of antifreeze type coolants, such as a water / ethylene glycol mixture (WEG), in the stack. This antifreeze type coolant is highly beneficial for batteries that operate in low temperature environments, such as automotive applications. However, care must be taken to isolate the WEG from the MEA, as the WEG will foul the membrane electrodes.

[0016] Solid bipolar plates may be manufactured from metals such as stainless steel or titanium. Metal plates can be formed into the shape of the flow field by traditional mass production methods such as stamping, making them potentially cheaper to mass produce. Solid bipolar plates may also be manufactured from non-porous carbon or from polymer (composite) materials. Solid carbon or composite plates can be mass produced, such as by molding, and typically can be held to tighter dimensional tolerances than metal molded plates. However, solid carbon or composite plates are more expensive to manufacture than metal plates.

[0017] While solid bipolar plates are useful and can be advantageous in certain applications, they do have drawbacks. One drawback of metal plates is that they are prone to corrosion due to the presence of air and water at very high electrochemical potentials. The corrosion layer is non-conductive, and as the plates corrode, fuel cell performance decreases. Coatings have been developed and applied to the plates to mitigate corrosion, but this technology also has operational limitations.

[0018] The automotive industry in particular may be targeting a fuel cell operating life of 5,000 hours. Some coatings on metal plates are said to have achieved this objective. However, the heavy vehicle industry may require an operating life of 30,000 hours. No current automotive coating or construction comes close to that limit. Therefore, the heavy vehicle industry needs to develop fuel cells with a much longer operating limit, possibly even as long as 30,000 hours.

[0019] Another disadvantage of solid plates is that they have no inherent water management capabilities. In the operation of a PEM fuel cell, it is important to maintain a proper water balance between the rate at which water is produced at the cathode electrode (including water resulting from proton drag through the PEM electrolyte) and the rate at which water is removed from the cathode or supplied to the anode electrode. In the case of a PEM fuel cell, if insufficient water is returned to the anode electrode, the adjacent portion of the PEM electrolyte will dry out, thereby slowing the rate of hydrogen ion transport through the PEM, causing return fluid crossover, and localized overheating. Similarly, if insufficient water is removed from the cathode, the cathode electrode may become flooded, effectively limiting the supply of oxidant to the cathode and reducing the current. Furthermore, if too much water is removed from the cathode, the PEM may dry out, limiting the ability of hydrogen ions to pass through the PEM and reducing cell performance. Typically, solid plates require external water management measures, such as an external humidifier, to prevent the MEA from drying out or cracking.

[0020] Porous bipolar plates, also called water transport plates, are porous separator plates used on both the cathode and anode sides of the electrodes in fuel cells. Porous bipolar plates have tightly controlled pore sizes to create a bubble barrier that allows liquid movement through the pores into the liquid water cavities but prevents reactant gas movement during fuel cell operation. Liquid movement allows for membrane hydration and allows for the removal of product water on the cathode side resulting from the electrochemical reactions in the fuel cell. Preventing reactant gas movement prevents fuel and oxidant gases from leaking into the liquid water cavities.

[0021] The porous plate keeps the membrane electrode assembly hydrated by wicking up excess water in the flow field channels and transferring it to areas that are losing water through evaporation, providing an excellent moisture balance. The porous bipolar plate is exposed to a water flow field to maintain the desired operation of the fuel cell. In localized areas of the cell where reactant gases flow from low to high temperature areas, water evaporates from the porous plate and the gas stream is saturated with water vapor; in areas where reactant gases flow from high to low temperature areas, the porous plate can wick up product water formed in the electrochemical reaction and liquid water condensed from the cooling gas stream. As a result, one advantage of fuel cell systems with porous bipolar plates is that they are very durable. Another advantage is that systems with porous bipolar plates do not require the use of external humidifiers, thus reducing weight and complexity.

[0022] Typically, a pump-driven circulating water loop can be used to provide cooling for the cells as well as the driving force for moving water through the pores of the water transport plate and removing product water.

[0023] Although porous bipolar plates have advantages, they also have disadvantages. For example, it can be difficult to manufacture plates with specific pore sizes, making them costly to mass produce. Another disadvantage is that porous plates are difficult to seal, which can lead to reliability issues in pressurized systems. Another major disadvantage is that fuel cells using porous bipolar plates cannot use antifreeze-type coolants, such as WEG, in the water cooling loop to avoid the coolant being absorbed into the pores and contaminating the MEA.

[0024] The inventive embodiments of the present disclosure solve many of the aforementioned problems with bipolar plates by using a four-fluid plate structure that provides a fuel reactant flow field, an oxidant flow field, a water management flow field, and dedicated coolant passages for an antifreeze type coolant. The embodiments include both non-porous and porous plate portions, judiciously selected to capture the best aspects of both designs while reducing or eliminating the associated disadvantages. Four-fluid bipolar plates can be easily manufactured and reduce costs.

[0025] 3 and 4, a bipolar plate 100 for a fuel cell includes a non-porous subplate 102 and a porous subplate 104. In one embodiment of the invention, the non-porous subplate 102 includes a reactant face 106 (shown in FIG. 3) and an opposing water management face 108 (shown in FIG. 4). As shown, the reactant face 106 delivers hydrogen to the anode side of the MEA via a fuel flow field. Non-limiting examples of flow fields include cavities, porous substrates, or, as shown in the illustrated embodiment, fuel flow field channels 110. The non-porous subplate 102 further includes internal coolant passages 112 that separate an antifreeze type coolant, such as WEG, from other components in the fuel cell (FIGS. 8 and 11). Other typical features of the non-porous subplate 102 may include internal manifolds 114 for fuel supply 114a and fuel return 114b, oxidant supply 114c and oxidant return 114d, water management supply 114e and water management return 114f, and WEG coolant supply 114g and WEG coolant return 114h. Sealing means 116 allow multiple fuel cells to be sealed and operated under pressure.

[0026] 4 shows the opposite side of the bipolar plate 100. The water management surface 108 of the non-porous subplate 102 includes a water flow field, non-limiting examples of which include a cavity, a porous substrate, or, as shown in the illustrated embodiment, water channels 118 that form part of an external circulating water management loop 150 (FIG. 13) and allow for proper water management of the cathode flow field, as described in more detail below. Water enters the plate channels through the water management supply manifold 114e and exits through a water management return manifold 114f.

[0027] The porous subplate 104 includes a reactant face 120 and an opposing water management face 122. The reactant face 120 delivers oxidant (e.g., air) to the cathode side of the MEA via an oxidant flow field. Non-limiting examples of flow fields include cavities, porous substrates, or, as shown in the illustrated embodiment, in this embodiment, oxidant flow field channels 124. In this embodiment, the water management face 122 (FIG. 3) is featureless (e.g., flat), but plays an important role in maintaining optimal cell performance and durability.

[0028] The porous subplate 104 may be made from graphite or other carbon-based materials, or from metals such as titanium or stainless steel. Features such as channels may be formed by hydroforming, casting, thermoforming, 3D printing / additive manufacturing, or milling / machining.

[0029] As previously mentioned, the pores in the porous subplate 104 are sized to form a bubble barrier during fuel cell operation. The pore size is determined by the particular fuel cell operating conditions and pressure. For graphite or other carbon-based materials, the pores may be formed in the plate by known methods. For example, U.S. Patent No. 6,197,442 details a manufacturing process in which graphite powder, reinforcing fibers, cellulosic fibers, and thermosetting resin are mixed with a liquid to form a slurry, which is showered onto a screen to form a planar sheet, which is dried to form a paper. Such paper is cut to the desired size and laid up. The layup is laminated under pressure and heat, carbonized, and graphitized to form a water transport plate for later machining as required. The finished porous plate exhibits excellent physical properties in terms of bubble pressure, water permeability, median pore size, porosity, in-plane resistivity, and compressive yield strength. For metallic porous plates, the pores may be formed by, for example, a punch press or laser drilling.

[0030] 5 and 6 show further exploded views of the non-porous sub-plate 102 according to a first embodiment of the invention. The non-porous sub-plate 102 may be formed from two half-plates 102A and 102B that are easily manufactured and joined together. For example, the half-plates may be manufactured from a metal such as stainless steel or titanium, the flow channels and other features may be formed by metal stamping or the like, and the two half-plates may be joined together by welding.

[0031] Other non-limiting examples of joining methods include, for example, laser welding, brazing, thermoplastic bonding, or adhesives. Half-plate 102A in the illustrated embodiment includes fuel flow field channels 110 on the reactant-facing side (FIG. 5) and WEG coolant half-channels 126A on the opposite side (FIG. 6). Half-plate 102B includes water channels 118 on the water management side 108 (FIG. 6) and WEG coolant half-channels 126B on the opposite side (FIG. 5).

[0032] Further details can be found with reference to Figures 7 and 8, where Figure 7 shows a cross-sectional view of the cathode side of the bipolar plate 100 along approximately the location shown in Figure 4, and Figure 8 shows an enlarged view of the plate shown in Figure 7. With reference to Figure 8, the non-porous sub-plate 102 and the porous sub-plate 104 are shown in more detail. The half-plates 102A, 102B are shown separated (e.g., before bonding) for clarity. Each half-plate may include a row of raised surfaces 128 and valleys 130, 132 therebetween, which may define fluid flow channels in the outer surface of the non-porous plate. The raised surfaces 128 on one side of the plate define recesses 134 on the opposite side of the same plate. The recesses may define an internal cavity 136 when the two half-plates 102A, 102B are bonded together. In one example, valleys 130 on half-plate 102B define the water management channels 118, valleys 132 on half-plate 102A define the fuel flow field channels 110, and internal cavities 136 define internal antifreeze coolant passages.

[0033] The reactant face 120 of the porous subplate 104 includes oxidant flow field channels 124 for supplying air to the MEA. In one example, the channels 124 are transverse to the fuel flow field channels 110. The water management face 122 of the porous subplate 104 is positioned against a flat raised surface 128 of the half-plate 102B. In this manner, as demineralized (DI) water is circulated through the water channels 118, the pores in the porous subplate 104 are in fluid communication with the DI water, causing the subplate 104 to become and remain fully saturated with liquid.

[0034] The desired porosity in the porous subplate 104 may be achieved by any suitable method known in the fuel cell arts. For example, the porous subplate 104 may be fabricated as a water transport plate (WTP), may be net-shape molded from a slurry having the appropriate particle size, or may be laser drilled to achieve the desired pore size.

[0035] Figure 9 shows another cross-sectional view of the bipolar plate 100, a portion of which is shown enlarged in Figure 10 to illustrate one possible construction. Looking at Figure 10, the cross-sectional view includes half-plate 102A, half-plate 102B, and porous sub-plate 104. As with Figure 8, half-plates 102A and 102B are shown somewhat separated for clarity. Also shown is the recess 134 in half-plate 102A, which forms the WEG coolant half-channel 126A.

[0036] The porous subplate 104 may be sealed to the non-porous subplate 102 by conventional means to prevent gas or water leakage. For example, the sealing means 116 may include adhesive, nesting, an interference fit, or a groove for receiving a molded compression seal, gasket, or O-ring. In one example, the porous subplate 104 may be nested in a recess 138 formed in the water management surface 108 of the non-porous subplate 102. The recess 138 spans the entire plane of the porous subplate 104, effectively trapping it and ensuring proper alignment during assembly. In some examples, the recess 138 may reduce the overall thickness of the bipolar plate 100, since the porous subplate 104 is substantially embedded in the thickness of the other plates, with only a minimal increase in the overall thickness dimension.

[0037] FIG. 11 shows a cross-sectional view of a proton exchange membrane (PEM) fuel cell 140 with a bipolar plate 100 according to a first embodiment of the present invention, FIG. 12 shows a stack of such fuel cells, and FIG. 13 shows a cross-sectional view of a fuel cell power plant 144 with the disclosed bipolar plate 100. In the illustrated example, the oxidant flow field channels 124 are shown parallel to the fuel flow field channels 110, but this is for illustrative purposes only and is the same for the other embodiments. The fuel cell 140 includes a bipolar plate 100 between upper and lower unitized electrode assemblies 28 (UEA). The bipolar plate 100 contacts each UEA 28.

[0038] During operation, hydrogen is introduced at inlet 114a and reaches the anode side of the UEA 28 by flowing through the fuel flow field channels 110 in the non-porous subplate 102. Air is introduced at inlet 114c and reaches the cathode side of the UEA 28 by flowing through the oxidant flow field channels 124 in the porous subplate 104. A water pump 146 circulates water through a demineralizer 148 in a water management loop 150. Demineralized water, or deionized (DI) water, passes through a water management supply 114e and enters the stack 144 through channels 118 formed by the non-porous subplate 102 and the porous subplate 104. The pores of the porous subplate 104 fill with water and the subplate acts as a sponge, retaining water and keeping the UEA 28 hydrated. The porous subplate 104 can transport the liquid directly to the UEA 28 or it can evaporate the water and transfer the water vapor to the UEA via the airflow. The porous subplate 104 can also remove product water formed by the reaction at the cathode from the UEA 28. Product water in liquid form can also be pumped directly into the pores of the porous subplate 104 by maintaining a lower pressure in the water management loop 150 than the reactant pressure. If the product water is in the form of steam, it can be condensed on the porous subplate where it is absorbed and returned to the circulating water loop.

[0039] Thermal management is primarily controlled by a dedicated, isolated coolant loop 152. A coolant pump 154 ​​drives coolant through the stack 144 via coolant supply 114g and out of the stack 144 via coolant return 114h. Meanwhile, in some configurations, the coolant is distributed across the surface of the cells 140. In the illustrated embodiment, the coolant flows through an internal passage 112 formed by joining half-plates 102A and 102B (FIG. 10). Upon leaving the stack at coolant return 114h, the coolant passes through a heat exchanger 156 where sensible heat is rejected before being circulated back to the supply 114g. In one example, the heat exchanger 156 is a radiator. A flow control valve or orifice 158 can be used to regulate the flow of the coolant.

[0040] The impermeability of the non-porous subplate 102 eliminates the need for separate coolant tubes and allows the coolant passages to be located internally in the subplate 102, saving space compared to some designs that add a separate cooling plate. As previously mentioned, this design allows the use of antifreeze type coolants such as a water / ethylene glycol mixture (WEG), which is beneficial for fuel cells operating in low temperature environments.

[0041] In the illustrated embodiment, the coolant flows through internal passages formed by joining the half-plates 102A and 102B. However, other means of distributing the coolant are contemplated within the scope of the present invention. For example, the internal coolant passages can be defined by cavities that include a porous matrix that distributes the coolant.

[0042] While under most circumstances an external humidifier is not necessary in the disclosed embodiments, there are scenarios in which adding an external humidifier would be beneficial to the system. For example, if the bipolar plate 100 only uses passive water management, especially when operated in a hot, dry environment, water could evaporate from the porous subplate faster than the fuel cell could create product water. In such circumstances, it may be advantageous to add an external humidifier 159 (FIG. 13) to the system rather than incorporating active cooling as detailed in other embodiments herein.

[0043] In the illustrated embodiment, there is no porous media in the anode channel 110. In some operating conditions, such as the presence of localized cold regions, moisture may condense and water may accumulate in the anode channel. The water must be periodically removed to prevent degradation of the anode electrode performance. Prior art solutions to this problem include attempting to blow the water away, which requires extra operating steps and consumes parasitic power. In one embodiment, as shown in Figures 11 and 12, one or more small drain holes 142 can be drilled from the bottom of the hydrogen channel to communicate with the DI water cavity 118. The drain holes 142 can be sized as a bubble barrier to transport excess water from the fuel channel 110 to the water channel 118 without allowing the reactant gases to escape. The pressure of the DI water loop can be maintained lower than the pressure of the anode and cathode. In this way, the pressure differential will drive the water accumulation through the drain holes 142 and into the cavity 118 where the water is returned to the DI water loop.

[0044] As mentioned above, under typical operating conditions, the thermal management of a fuel cell power plant is primarily controlled by the antifreeze coolant loop 152, with sensible heat being transferred to the circulating coolant passing through the coolant flow field. To a lesser extent, some of the cell cooling may also be provided by evaporative cooling as product water in the pores evaporates, although evaporative cooling is not typically considered as a control parameter in a sensible coolant flow system.

[0045] Evaporative cooling utilizes the heat of vaporization to improve cooling effectiveness per volume of water by up to 100 to 1 compared to sensible coolant flow methods. The inventors of the present disclosure have determined that under certain conditions enhanced cooling can be achieved through evaporation. Thus, in one aspect of the present invention, independent operation of the water management loop and the coolant loop can be utilized to operate in a thermal boost mode or a water recovery / accumulation mode.

[0046] In thermal boost mode, additional cooling is needed for a finite duration, such as when the stack is demanding a lot of power. In fuel cell vehicles (especially trucks), thermal boost mode can be useful when climbing steep hills or long roadways, when operating at high power on hot days, or in any other scenario where the radiator is not large enough to adequately handle the cooling demands. In thermal boost mode, the thermal management method shifts from sensible cooling to evaporative cooling, providing more cooling capacity. Evaporative cooling can account for a large portion of the total cooling function in thermal boost mode, and in some design scenarios can account for more than 90%.

[0047] During operation, if additional cooling is needed or calculated to be needed, in a first step, the coolant flow rate (i.e., WEG) is decreased, which reduces the sensible cooling capacity. As a result, the temperature of the stack begins to increase, which increases the rate of water evaporation from the pores, and significant evaporative cooling is achieved. Then, in a second step, the temperature of the fuel cell is increased or maintained to increase the degree of evaporative cooling. To compensate for the increased water evaporation and prevent the pores from drying out and losing the bubble barrier, in a third step, the water flow rate through the water management flow field can be increased. In one example, the increased water flow rate is achieved by providing a pump-driven circulating water management loop in fluid communication with the water management flow field and increasing the water flow rate through the pump.

[0048] The disclosed evaporative cooling scheme provides a better short term thermal management control strategy due to its greater ability to handle large short term heat demands: the coolant flow rate can be adjusted to a lower value to achieve the appropriate level of evaporative cooling and desired stack temperature.

[0049] The disclosed thermal boost mode depletes the amount of water in the water management loop beyond what can be simultaneously replenished by the formation of product water. Thus, the thermal boost mode is intended to be relatively short term. However, in another aspect of the invention, the independent operation of the water management loop and the coolant loop may be utilized to operate a water recovery / accumulation mode. In the water recovery / accumulation mode, the coolant flow rate (i.e., WEG) is increased above normal rates, evaporative cooling is reduced, and excess water is produced in the cell by condensation. The excess product water can be collected and held for use in a future thermal boost mode.

[0050] In one embodiment, the water recovery / accumulation mode may also be operated during portions of the cycle where the stack is not needed and the airflow through the radiator provides sufficient cooling, such as when the vehicle is traveling on level ground. In a first step, when additional product water is needed or calculated to be needed, the coolant flow rate (i.e., WEG) in the coolant loop is increased to increase sensible cooling. As a result, the stack temperature is reduced and the amount of product water that evaporates from the pores is reduced, forming condensed water instead. In a second step, the temperature of the fuel cell is reduced, but maintained, to condense the excess product water. To compensate for the reduced water evaporation and prevent self-cladding, in a third step, the water flow rate through the water management flow field may be reduced. In one example, the reduction in water flow rate may be achieved by providing a pump-driven circulating water management loop in fluid communication with the water management flow field and using the pump to reduce the water flow rate.

[0051] In another embodiment, the fuel cell controller may receive sensor or environmental inputs to determine whether and to what extent a thermal boost mode or a water recovery / accumulation mode is warranted. Non-limiting examples of sensor inputs may include air flow rate, cathode exhaust temperature, cathode exhaust pressure, total water storage capacity, water inventory, water temperature, ambient temperature, coolant return temperature, and water loop outlet pressure. The controller may command coolant pump and / or water pump flow rate settings depending on the sensor input values.

[0052] The fuel cell controller may also receive inputs from external environmental factors. Non-limiting examples include payload timing, vehicle route, GPS coordinates, road grade, weather forecast, time of day, and driver behavior. In one example, the controller may receive GPS route data indicating a steep or extended roadway grade is approaching. The controller may command the stack well in advance to operate a water recovery / accumulation mode, which can collect product water and hold it in a water reservoir. Then, when the vehicle encounters a grade, the controller may command the stack to operate a thermal boost mode.

[0053] The thermal boost and water recovery / storage modes of operation are not limited to the disclosed hybrid bipolar plates. The inventors envision that the disclosed method of operation may be possible and beneficial in any four-fluid fuel cell power plant where an antifreeze type coolant loop is operated independently of the water management loop, such as that disclosed in U.S. Patent No. 7,135,247. The '247 patent discloses separate individual cooling plates aligned between every other fuel cell.

[0054] The disclosed thermal boost and water recovery / storage modes offer several benefits and advantages over prior art three-fluid stacks. One benefit is that the thermal boost mode reduces parasitic power because at high power output the radiator and fan are actually tuned down instead of increased. In prior art stacks, running the radiator and fan harder reduces efficiency. Conversely, tuning down the radiator increases efficiency.

[0055] Another advantage of the disclosed thermal boost mode is that the size of the radiator may be reduced due to alternative cooling means that can be achieved within the fuel cell. Prior art three-fluid designs use much larger radiators that are more expensive and add weight to the vehicle, reducing performance. This is especially true for fuel cell trucks.

[0056] FIG. 14 shows a cross-sectional view of a fuel cell 240 with a four-fluid bipolar plate 200 according to a second embodiment of the invention. The half-plate 102A may be of the same structure as shown in FIG. 11, but the half-plate 102B is replaced by a simple flat plate 202B. The flat plate may be made of the same material as the half-plate 102A. The porous sub-plate 204 in this embodiment includes oxidant flow field channels 224 on a first side of the plate and DI water channels 218 on the opposite second side. In this structure, the non-porous sub-plate 102 does not have water channels. One advantage of this embodiment is the low profile, which reduces the height and weight of the stack. The size of the WEG coolant passages 212 is also reduced by half, but this can be compensated for by increasing the coolant flow rate.

[0057] FIG. 15 shows a cross-sectional view of a fuel cell 340 with a four-fluid bipolar plate 300 according to a third embodiment of the invention. In this embodiment, DI water does not circulate throughout the stack, but only circulates within the cell 340. The half-plate 102A may be of the same structure as shown in FIG. 11, but the half-plate 102B is replaced by a simple flat plate 302B, which may be made of the same material as the half-plate 102A. The sub-plate 304, which may be constructed as a water transport plate, acts as a porous substrate for DI water, and is in effect a DI water "sponge": it collects product water and humidification water from the air and circulates it back to the inlet of the cell reactant channel 324 to moisten the UEA 28. Intra-cell circulation occurs by pore wicking, such that as water in the pores evaporates at the inlet of the reactant channel, new water is wicked up from further downstream of the channel 324, where the pores are still saturated. This cycle continues passively, with evaporation occurring at the inlet of the channel and condensation at the outlet of the channel. This embodiment offers the advantages of passive water management, being less complex, saving the cost of external pumps and piping, and consuming no parasitic power.

[0058] FIG. 16 shows a cross-sectional view of a fuel cell 440 having a four-fluid bipolar plate 400 according to a fourth embodiment of the present invention. In this embodiment, the configuration is essentially the same as that shown in FIG. 11, except that an additional separator plate 460 divides the internal WEG coolant passages into two separate channels (shown as WEG1, WEG2). The separate channels can be used to even out the heat distribution across the cell, i.e., to add more cooling capacity where needed. In one example, the two separate channels can carry coolants of different composition or completely different fluids.

[0059] FIG. 17 shows a cross-sectional view of a fuel cell 540 having a four-fluid bipolar plate 500 according to a fifth embodiment of the invention. In this embodiment, the cathode side structure and WEG internal coolant passages are essentially the same as those shown in FIG. 9, but the anode side uses a porous subplate 562 to supply hydrogen to the UEA 28. The non-porous subplate 102 is unchanged, but instead of the valleys 132 of the subplate 102A defining the fuel reactant channels (FIG. 8), in this embodiment they define water channels 518 to maintain hydration of the porous anode subplate 562. As with the cathode side, the porous anode subplate 562 includes fuel flow field channels 510 adjacent to the UEA 28.

[0060] FIG. 18 shows a cross-sectional view of a fuel cell 640 having a bipolar plate 600 according to a sixth embodiment of the invention. This embodiment is a three-fluid system since it does not include internal coolant passages for the WEG coolant. The bipolar plate includes a non-porous sub-plate 602 and a porous sub-plate 104. The porous sub-plate is essentially the same as that shown in FIG. 11. The non-porous sub-plate 602 differs from the previous embodiment in that it includes a single plate and does not have a flat plate welded or otherwise joined to it. Thus, the sub-plate 602 includes a water management surface that defines water channels 618 and an opposing reactant surface that defines fuel flow field channels 610.

[0061] FIG. 19 shows a cross-sectional view of a fuel cell 740 having a four-fluid bipolar plate 700 according to a seventh embodiment of the present invention. In this embodiment, the bipolar plate 700 includes a porous subplate 704 on the cathode side and a hybrid subplate 766 on the anode side. The subplate 704 is essentially the same as the subplate 204 (FIG. 14) with an oxidant flow field 724 on one side and a water flow field 718 on the opposite side. The hybrid subplate 766 includes a porous portion and a non-porous portion. The non-porous portion defines an internal coolant passage 712 that isolates the coolant from exposure to other cell components. The coolant may be an antifreeze type coolant such as WEG. The porous portion defines a plurality of pores 768 that fluidly connect the fuel reactant flow field 710 to the water flow field 718. The pores 768 are sized as a bubble barrier to transport excess water from the fuel flow field 710 to the water flow field 718 without allowing hydrogen gas to escape into the water cavities.

[0062] In one example, the sub-plate 766 may include a half-plate 766A (similar to 102A in FIG. 8 ) joined to a half-plate 766B (similar to 202B in FIG. 14 ) to form the internal coolant passages 712. The flat plate 766B may be formed from the same material as the half-plate 766A. The half-plates 766A, 766B may be joined by any of the previously mentioned techniques, such as welding, laser welding, brazing, thermoplastic bonding, or adhesives. After joining, the holes 768 may be formed by any suitable technique, such as laser drilling.

[0063] Further embodiments may be realized by swapping the fuel and oxidant reactants. For example, in the previous embodiment, air was described as flowing through the channels of the porous subplate 104 and hydrogen was described as flowing through the channels of the non-porous subplate 102. It is also considered within the scope of the present invention to swap the positions, i.e., hydrogen flows through the channels of the porous subplate 104 and air flows through the channels of the non-porous subplate 102.

[0064] One of the improvements of the disclosed fuel cell system is the prevention of galvanic corrosion on the non-porous metal subplate. Galvanic corrosion can occur at the interface 164 (FIGS. 11 and 13) between the porous carbon subplate and the metal subplate due to their potential difference. When the metal begins to oxidize, the cell begins to degrade because the oxide layer becomes non-conductive. Prior art solutions to this problem (when the system includes non-porous carbon) include applying a coating to the metal plate to prevent corrosion. While the disclosed fuel cell system can still benefit from a coating, the system may not need to utilize a coating because the demineralized / deionized water loop sweeps the interface 164 between the metal and carbon, removing any corrosion products that may normally build up and make the interface non-conductive. In fact, the water circulating at the interface prevents oxide buildup.

[0065] A sample of the method described herein is as follows:

[0066] (1) A method for preventing corrosion of a carbon / metal interface in a fuel cell, the method comprising the steps of:

[0067] providing a bipolar plate including a metallic subplate and a porous subplate, the metallic subplate having at least one water management surface, the porous subplate having a water management surface opposite a reactant surface, the water management surface of the porous subplate adjacent the water management surface of the metallic subplate to form an interface;

[0068] providing a unitized electrode assembly adjacent to the bipolar plate;

[0069] flowing fuel and oxidant reactants from a reactant flow field on the bipolar plate to the unitized electrode assembly to initiate an electrochemical reaction;

[0070] flowing water through the water management loop and onto the water management surface of the metallic subplate and the porous subplate to sweep away corrosion products formed at the interface; and

[0071] Deionizing and desalting the water flowing through the water management loop.

[0072] (2) A method for preventing corrosion at the carbon / metal interface in the fuel cell described in (1) above, further comprising the steps of forming internal coolant passages in the bipolar plate and flowing an antifreeze-type coolant through the internal coolant passages.

[0073] (10) A method for operating a four-fluid fuel cell in a thermal boost mode, comprising the steps of:

[0074] providing a four-fluid fuel cell including an oxidant flow-field, a fuel reactant flow-field, a water management flow-field, and an independent circulating coolant loop operable to remove sensible heat, the coolant loop in fluid communication with the coolant flow-field;

[0075] reducing the flow rate of coolant in the coolant loop to reduce sensible cooling capacity; and

[0076] Maintaining or increasing the temperature of the fuel cell to increase evaporative cooling.

[0077] (11) A method of operating a four-fluid fuel cell as described in (10) above, wherein the coolant is an antifreeze type coolant.

[0078] (12) A method of operating a four-fluid fuel cell as described in (10) above, wherein at least one of the oxidant flow field and the fuel reactant flow field comprises a plurality of pores fluidly connected to a water management flow field, the pores being configured as bubble barriers.

[0079] (13) A method of operating a four-fluid fuel cell as described in (10) above, wherein the step of providing the four-fluid fuel cell includes providing a hybrid bipolar plate including an oxidant flow field, a fuel reactant flow field, internal coolant passages, and a water management flow field.

[0080] (14) A method of operating a four-fluid fuel cell as described in (10) above, further comprising the step of increasing the flow rate of water through the water management flow field to compensate for increased evaporation.

[0081] (15) A method of operating a four-fluid fuel cell as described in (14) above, wherein the step of providing the four-fluid fuel cell further comprises providing a circulating water management loop in fluid communication with the water management flow field.

[0082] (20) A method for accumulating and retaining product water in a four-fluid fuel cell, comprising the steps of:

[0083] providing a four-fluid fuel cell including an oxidant flow-field, a fuel reactant flow-field, a water management flow-field, and an independent circulating coolant loop operable to remove sensible heat, the coolant loop in fluid communication with the coolant flow-field;

[0084] increasing the flow rate of coolant in the coolant loop to increase sensible cooling capacity; and

[0085] Maintaining or decreasing the temperature to condense excess product water.

[0086] (21) A method for accumulating and retaining product water in a four-fluid fuel cell as described in (20) above, further comprising the step of providing a water tank for storing excess product water, the water tank being in fluid communication with the water management loop.

[0087] (22) A method for accumulating and retaining product water in a four-fluid fuel cell as described in (20) above, further comprising the step of reducing the flow rate of water through the water management flow field to accumulate excess product water and compensate for reduced evaporation.

[0088] (23) A method for accumulating and retaining product water in a four-fluid fuel cell as described in (22) above, wherein the step of providing a four-fluid fuel cell further includes providing a circulating water management loop in fluid communication with the water management flow field.

[0089] (24) A method as described in any of (10) or (20) above, wherein the controller commands flow settings of the coolant pump and the water pump in response to sensor data including at least one of air flow, cathode exhaust temperature, cathode exhaust pressure, total water capacity, water inventory, water temperature, ambient temperature, coolant return temperature, and water loop outlet pressure.

[0090] (25) A method according to any of (10) or (20) above, wherein the controller commands flow settings of the coolant pump and the water pump in response to environmental factors, the environmental factors including at least one of payload timing, vehicle route, GPS coordinates, road gradient, weather forecast, time of day, and driver behavior.

Claims

1. below:

1. A non-porous subplate, the non-porous subplate including a first water management surface and a second water management surface opposite the first water management surface, the non-porous subplate having: a fuel supply internal manifold through-passage and a fuel return internal manifold through-passage; oxidant supply and return internal manifold passages; Water management supply internal manifold penetrations and water management return internal manifold penetrations; coolant supply and return internal manifold through-passages; and an internal coolant passage in fluid communication with the coolant supply internal manifold throughpassage at one end and in fluid communication with the coolant return internal manifold throughpassage at the other end, the internal coolant passage extending across an area between the fuel supply and fuel return internal manifold throughpassages and the oxidant supply and oxidant return internal manifold throughpassages; a non-porous subplate defining a first porous subplate including a reactant side and an opposing water management side, the reactant side including a first reactant flow field in fluid communication with one of the fuel supply internal manifold throughways and the oxidant supply internal manifold throughways, the water management side in fluid communication with the first water management side of the non-porous subplate; and a second porous subplate including a reactant face and an opposing water management face, the reactant face including a second reactant flow field in fluid communication with the other of the fuel supply internal manifold throughways and the oxidant supply internal manifold throughways, the water management face in fluid communication with the second water management face of the non-porous subplate; 13. A bipolar plate for a fuel cell comprising:

2. 2. The bipolar plate of claim 1, wherein at least one of the first and second porous subplates forms a nested seal within a recessed perimeter of the non-porous subplate.

3. The bipolar plate of claim 1 , wherein at least one face of the non-porous subplate defines a water management flow field.

4. The bipolar plate of claim 3 , wherein the water management flow field comprises water flow field channels.

5. The bipolar plate of claim 1 , wherein the non-porous sub-plate comprises a first half-plate bonded to a second half-plate.

6. The bipolar plate of claim 5 , wherein the interior coolant passages are defined by the first and second half-plates joined together.

7. The bipolar plate of claim 1 , wherein said interior coolant passages are compatible with antifreeze type coolants.

8. 2. The bipolar plate of claim 1, wherein at least one of the first and second porous subplates includes a bubble barrier pore structure adapted to allow transport of a liquid through the pore structure and prevent transport of a reactant gas through the pore structure.

9. 9. The bipolar plate of claim 8, wherein both the first and second porous subplates include a bubble barrier pore structure that allows transport of liquid through the pore structure and prevents transport of reactant gases through the pore structure.

10. 1. A non-porous subplate for a fuel cell bipolar plate assembly, comprising: a first water management surface and a second water management surface opposite the first water management surface; The non-porous subplate comprises: a fuel supply internal manifold through-passage and a fuel return internal manifold through-passage; oxidant supply and return internal manifold passages; Water management supply internal manifold penetrations and water management return internal manifold penetrations; coolant supply and return internal manifold through-passages; and an internal coolant passage in fluid communication with the coolant supply internal manifold throughpassage at one end and in fluid communication with the coolant return internal manifold throughpassage at the other end, the internal coolant passage extending across an area between the fuel supply and fuel return internal manifold throughpassages and the oxidant supply and oxidant return internal manifold throughpassages; A non-porous subplate defining a

11. The non-porous subplate of claim 10 , wherein the first water management surface includes a first recessed perimeter adapted to receive a first porous subplate.

12. The non-porous subplate of claim 11 , wherein the first recessed perimeter is further adapted to provide a nested seal with the first porous subplate.

13. The non-porous subplate of claim 11 , wherein the second water management surface includes a second recessed perimeter adapted to receive a second porous subplate.

14. The non-porous subplate of claim 13 , wherein the second recessed perimeter is further adapted to provide a nested seal with the second porous subplate.

15. The non-porous subplate of claim 10 further comprising a first half-plate joined to a second half-plate thereby defining an internal coolant passage.

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