Activation of self-passivating metals using reagent coatings for low temperature nitrocarburization in the presence of oxygen-containing gas

A method using pyrolysis products of nitrogen and carbon reagents in an oxygen-containing atmosphere activates and hardens self-passivating metals like stainless steel, addressing the Beilby layer issue and enabling effective case formation on complex shapes without pre-treatment, with enhanced properties and simplified industrial application.

US20260002244A1Pending Publication Date: 2026-01-01CASE WESTERN RESERVE UNIV +1
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Patent Information

Application Number
US19/317437
Authority / Receiving Office
US · United States
Patent Type
Applications(United States)
Current Assignee / Owner
Priority Date
2021-04-28
Filing Date
2025-09-03
Publication Date
2026-01-01

AI Technical Summary

Technical Problem

Conventional low-temperature surface hardening methods for self-passivating metals like stainless steel, such as carburization, nitriding, and nitrocarburization, are ineffective on complex-shaped workpieces due to the presence of a Beilby layer, and require pre-treatment to remove this layer, while self-activating technologies fail to penetrate it effectively.

Method used

A method involving exposure to pyrolysis products of nonpolymeric reagents containing nitrogen and carbon in an oxygen-containing atmosphere at low temperatures, which activates and hardens the metal surface without the need for pre-treatment, allowing case formation even on complex shapes.

Benefits of technology

Enables effective case formation with enhanced properties like hardness, corrosion resistance, and abrasion resistance on self-passivating metals, including stainless steel, without the need for pre-treatment, and can be conducted in ambient air, reducing costs and simplifying industrial processes.

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Abstract

A method for low-temperature interstitial case formation on a self-passivating metal workpiece includes exposing the workpiece in a heated gaseous environment comprising oxygen to pyrolysis products of a nonpolymeric reagent comprising nitrogen and carbon.
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