Solid laundry composition

A solid laundry detergent composition with a pH of 6.5 to 9, using a low pH spray-dried detergent particle and a fabric softening agent, addresses the issues of fabric dye fading and skin irritation, achieving effective cleaning and fabric care in shorter wash cycles.

WO2025045955A1PCT designated stage expired Publication Date: 2025-03-06UNILEVER IP HLDG BV +2
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Patent Information

Application Number
PCT/EP2024/074092
Authority / Receiving Office
WO · WO
Patent Type
Applications
Current Assignee / Owner
Priority Date
2023-08-30
Filing Date
2024-08-28
Publication Date
2025-03-06

AI Technical Summary

Technical Problem

Existing solid laundry detergent compositions with high pH profiles cause fabric dye fading and skin irritation, and they often require longer wash cycles, leading to fabric damage and stiffness.

Method used

A solid laundry detergent composition with a pH ranging from 6.5 to 9, incorporating a low pH spray-dried detergent particle and a fabric softening agent, which maintains cleaning performance in shorter wash cycles while providing fabric care benefits such as color retention and softness.

Benefits of technology

The composition achieves good stain removal performance in shorter wash cycles, delivers improved fabric care by retaining color and providing softness, and maintains powder and storage properties without caking.

✦ Generated by Eureka AI based on patent content.

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Abstract

The present invention relates to the solid laundry detergent composition. The invention particularly relates to solid free flowing particulate laundry detergent composition having a low pH profile. It is therefore desired to provide a solid free flowing laundry detergent composition which has a pH ranging from 6.5 to 9 and which delivers good fabric care performance. The present invention addresses this need by incorporating a combination of a specific low pH spray dried detergent particle and a fabric softening agent in a solid detergent composition.
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Description

[0001]P0000411EP CPL 1 SOLID LAUNDRY COMPOSITION Field of the Invention The present invention relates to a solid laundry detergent composition. The invention 5 particularly relates to a solid, free flowing, particulate laundry detergent composition having a low pH profile. Background of the Invention Solid laundry detergent composition typically has an alkaline pH. This alkaline pH profile 10 ensures good cleaning performance by saponification of grease and cleaning by the mechanism of swelling the fibers of fabric. However, the alkaline pH range may cause fading of some fabric dyes over multiple laundry cycles. In addition to fading of fabric colour, the alkaline detergent composition are likely to irritate the 15 skin when traces of the composition remain on the clothing after rinse. Other concerns which additionally need to be addressed while formulating the solid laundry detergent composition with high pH profile include improving the fabric care benefits, fabric appearance performance and / or fabric shape retention performance. 20 It is known to address these concerns of detergent composition with high pH profile, by lowering the pH of the composition which offer the advantage of being less harsh to skin and reduces color fading. It is known in the art to formulate the solid detergent composition at a lower pH and then to balance the formulation with specific ingredients to provide good cleaning performance. 25 One such document is EP 3301158 A1 (P&G, 2018) which discloses a solid free flowing particulate laundry detergent composition having a pH ranging from 6.5 to 8 and where the composition includes alkoxylated polyalkyleneimine and a base detergent particle having 1 wt.% to 10 wt.% organic acid and an anionic surfactant. 30 One concern with solid laundry detergent composition having a low pH base detergent particle comprising an organic acid, is the deliquescent nature of organic acid particularly citric acid. The deliquescent nature of citric acid particularly when added in an amount ranging from 1 wt.% to 10 wt.% was found to be detrimental to the physical stability of the product containing the citric acid, particularly in hot and humid conditions which are common in most parts of the world. 35 By deliquescent it is meant that citric acid forms a hydrate from moisture and then proceeds to P0000411EP CPL 2 dissolve in its own water of hydration. In granular detergent composition, presence of citric acid may result in lumpy, cakey, and poor flowability of the composition. Consumer studies indicate that when the pH of the composition is lowered, consumers tend to 5 wash the fabric over longer wash cycles to achieve the desired cleaning performance. The longer wash cycles tend to hasten the fabric damage. Low pH compositions with a reduction in the pH improves the fabric care benefits which is seen in the better color retention seen in fabrics washed with the composition. The composition may10 still render the fabric stiff after the wash cycle due to the longer wash cycles. Consumers correlate the fabric care benefits with the softness of the fabrics felt after the laundering process. When the fabrics have a certain amount of stiffness after the wash, the laundry detergent composition is perceived to be harsh on the fabrics. To overcome this 15 problem, it is known to add fabric conditioners which contain cationic ingredients. However, today’s consumer desire for a single composition which provides both fabric cleaning performance and the fabric care benefits. Thus, it is desired to provide a laundry detergent composition which provides good softness sensorials along with cleaning performance and fabric care benefits which includes color retention and fabric softness. 20 It is therefore desired to provide a solid free flowing laundry detergent composition which has a pH ranging from 6.5 to 9 and which provides good stain removal performance in shorter wash cycles and thereby delivers good fabric care performance. 25 It is also desired to provide a low pH solid laundry composition which provides good powder properties and storage properties over long periods without caking. Another requirement is to provide a solid laundry detergent composition which is biodegradable, and which exhibits improved cleaning performance. 30 Summary of the Invention The present invention addresses this need by incorporating a combination of a specific low pH spray dried detergent particle and a specific fabric softening agent in a solid detergent composition to provide desired softness benefits while maintain cleaning performance in shorter 35 wash cycles and which delivers good fabric care performance. The specific low pH spray dried P0000411EP CPL 3 detergent particle comprises (i) organic carboxylic acid, or (ii) a salt of organic carboxylic acid selected from the group consisting of (a) organic carboxylic acid salt of alkaline earth metal; (b) organic carboxylic acid salt of aluminium, (c) an aluminium complex of organic carboxylic acid, (d) organic carboxylic acid salt of alkali metal and mixtures thereof. 5 The present inventors have found that the solid detergent composition according to the first aspect preferably having a pH ranging from 6.5 to 9, more preferably from 7 to 9, and the fabric softening agent achieves the desired fabric softeness while maintaining good cleaning performance, in shorter wash cycles and delivers good fabric care performance. The low pH 10 solid laundry composition provides good powder properties and storage properties over long periods without caking. The composition also has good anti-redeposition benefits, has good dissolution profile, and good foam performance. According to a first aspect of the present invention disclosed is a solid laundry composition15 comprising: (i) a spray dried detergent particle comprising (i) an organic carboxylic acid, or (ii) a salt of organic carboxylic acid selected from the group consisting of (a) organic carboxylic acid salt of alkaline earth metal; (b) organic carboxylic acid salt of aluminium, (c) an aluminium complex of organic carboxylic acid, (d) organic carboxylic acid salt of alkali 20 metal and mixtures thereof; where the spray dried detergent particle has an equilibrium pH of 4 or more when measured at 1 wt.% dilution in deionized water at 25°C and, (ii) a fabric softening agent selected from the group consisting of (i) cellulase enzyme (ii) fabric softening clay and chelating agent (iii) fabric softening clay and cationic polymer (iv) cationic polymer and chelating agent; and mixtures thereof; wherein the spray-dried25 detergent particle comprises from 0 wt.% to 4 wt.% sodium carbonate. Preferably the solid laundry composition has an equilibrium pH ranging from 6 to 9 when measured at 1 wt.% dilution in deionized water at 25°C. 30 Detailed Description of the Invention According to a first aspect of the invention, the solid detergent composition includes a low pH spray-dried detergent particle and a fabric softening agent. Spray-dried detergent particle P0000411EP CPL 4 According to the first aspect of the present invention the solid laundry composition includes a low pH spray-dried detergent particle which has an organic carboxylic acid, or a salt of organic carboxylic acid selected from (a) organic carboxylic acid salt of aluminium, (b) organic carboxylic acid salt of alkaline earth metal, (c) an aluminium complex of organic carboxylic acid, 5 (d) organic carboxylic acid salt of alkali metal and mixtures thereof. The spray dried detergent particle preferably has a pH of 4 or more, more preferably a pH ranging from 4 to 8.5, still preferably 6 to 8.5, more preferably above 7, still preferably from 7 to 8.5 when measured using a 1 wt.% solution with distilled water at 25°C. The spray-dried 10 detergent particle is generally referred to as base powder. This base powder is mixed with other post dosed ingredients to form the fully formulated solid laundry detergent composition according to the present invention. Preferably the spray-dried detergent particle has a bulk density of less than 550g / L. Preferably 15 the spray-dried detergent particle has a weight average particle size ranging from 300 micrometres to 600 micrometres. Preferably, the solid laundry composition according to the present invention includes comprises from 20 wt.% to 90 wt.% spray-dried detergent particle, still preferably from 20 wt.% to 80 wt.% 20 spray-dried detergent particle, more preferably from 20 wt.% to 60 wt.% spray-dried detergent particle. Preferably the solid laundry composition comprises at least 30 wt.%, at least 35 wt.%, still preferably at least 40 wt.%, still preferably at least 45 wt.%, most preferably at least 50 wt.% of spray-dried detergent particle, but typically not more than 75 wt.%, still preferably not more than 70 wt.%, still further preferably not more than 68 wt.%, still more preferably not more than 25 65 wt.% and most preferably not more than 60 wt.%, spray-dried detergent particle based on the weight of the solid laundry detergent composition. The spray-dried detergent particle comprises 0 wt.% to 8 wt.% alkali metal salt of carbonate, preferably 0 wt.% to 4 wt.% alkali metal salt of carbonate, preferably 0 wt.% to 2 wt.% alkali 30 metal salt of carbonate, still preferably 0 wt.% alkali metal salt of carbonate. Preferably where the alkali metal salt of carbonate is sodium carbonate. The spray-dried detergent particle comprises 0 wt.% to 8 wt.% alkali metal salt of silicate, more preferably 0 wt.% to 4 wt.% alkali metal salt of silicate, still preferably 0 wt.% alkali metal salt of35 silicate. Preferably where the alkali metal salt of silicate is sodium silicate. P0000411EP CPL 5 Organic carboxylic acid: Preferably the spray-dried detergent particle has an organic carboxylic acid. Preferably the organic carboxylic acid is a monomeric organic carboxylic acid, still preferably a monomeric organic polycarboxylic acid. Suitable examples of the organic carboxylic acid include but is not 5 limited to formic acid, acetic acid, propionic acid, butyric acid, acrylic acid, methacrylic acid, chloroacetic acid, citric acid, lactic acid, glyoxylic acid, acetoacetic acid, oxalic acid, malonic acid, adipic acid, phenylacetic acid, benzoic acid, salicylic acid, glycine, alanine, valine, aspartic acid, glutamic acid, lysine, phenylalanine, nicotinic acid, picolinic acid, fumaric acid, benzoic acid, succinic acid and glycolic acid. Preferably, the organic carboxylic acid is selected from the 10 group citric acid, malic acid, succinic acid, lactic acid, glycolic acid, fumaric acid, tartaric acid, formic acid, and mixtures thereof. More preferably, the organic carboxylic acid is citric acid, lactic acid, and tartaric acid. Most preferably organic carboxylic acid is citric acid. The organic acid may be at least partially coated, or even completely coated, by a water-dispersible material. Water-dispersible material also typically includes water-soluble material. A suitable15 water-dispersible material is wax. A suitable water-soluble material is citrate. Preferably the spray-dried detergent particle includes a mixture of organic carboxylic acid and silica. Preferably the silica is present in an amount ranging from 0.2 wt.% to 5 wt.%, still preferably from 0.2 wt.% to 3.5 wt.%, further preferably from 0.2 wt.% to 3 wt.%, still more 20 preferably 0.5 wt.% to 2.5 wt.% in the spray-dried detergent particle. The silica may be either performed or generated in-situ. Salt of organic carboxylic acid Preferably the salt of organic carboxylic acid is a salt of monomeric organic carboxylic acid, still 25 preferably a monomeric organic polycarboxylic acid. The organic carboxylic acid includes those mentioned hereinabove. Organic carboxylic acid salt of an alkaline earth metal: Preferably the organic carboxylic acid salt is an organic carboxylic acid salt of an alkaline earth metal. Preferably the organic 30 carboxylic acid salt of alkaline earth metal includes one or more of alkaline earth metal salt of organic carboxylic acid, di-alkaline earth metal salt of organic carboxylic acid, tri alkaline earth metal salt of organic carboxylic acid or mixtures thereof. Preferably the alkaline earth metal is magnesium. Preferably the organic carboxylic acid salt of alkaline earth metal is a citric acid salt of magnesium, preferably comprising one or more of magnesium citrate, magnesium dicitrate,35 magnesium tricitrate and mixtures thereof. P0000411EP CPL 6 Preferably in addition to the organic carboxylic acid salt of alkaline earth metal, the spray-dried particle may additionally include any one of the ingredient selected from the group consisting of hydroxide of alkaline earth metal, silicate salt of alkaline earth metal, disilicate salt of alkaline earth metal, silica, or mixtures thereof. Preferably the silicate salt of the alkaline earth metal 5 and / or the disilicate salt of the alkaline earth metal is in amorphous form. Most preferably the organic carboxylic acid is citric acid. Preferably the amount of organic carboxylic acid salt of alkaline earth metal in the spray-dried detergent particle ranges from 0.2 wt.% to 6 wt.%. Preferably the amount of organic carboxylic 10 acid salt of alkaline earth metal in the spray-dried detergent particle is not less than 0.25 wt.%, still preferably not less than 1 wt.%, more preferably not less than 1.5 wt.%, still more preferably not less than 2 wt.%, but typically not more than 5 wt.%, preferably not more than 4 wt.% or still preferably not more than 3 wt.% 15 Preferably the spray-dried detergent particle includes: (i) from 3 wt.% to 50 wt.% detersive surfactant; preferably anionic detersive surfactant; (ii) from 0.2 wt.% to 6 wt.% organic carboxylic acid salt of alkaline earth metal; (iii) preferably from 2 wt.% to 20 wt.% organic carboxylic acid salt of alkali metal; (iv) preferably from 0 wt.% to 4 wt.% silicate and / or disilicate salt of alkaline earth metal; (v) preferably from 0 wt.% to 2 wt.% alkaline earth metal salt, 20 preferably hydroxide of alkaline earth metal; (vi) preferably 25 wt.% to 88 wt.% filler; and, (vii) preferably from 1 wt.% to 3.5 wt.% moisture content. Preferably the spray-dried detergent particle includes a mixture of organic carboxylic acid salt of alkaline earth metal and organic carboxylic acid salt of alkali metal. Preferably the 25 amount of the acid salt of alkali metal in the spray-dried detergent particle is not less than 2.5 wt.%, still preferably not less than 3.5 wt.%, more preferably not less than 5, still more preferably not less than 5.5 wt.%, furthermore preferably not less than 8 wt.%, but typically not more than 18 wt.%, preferably not more than 15 wt.% or still preferably not more than 12 wt.%, more preferably not more than 10 wt.%. 30 Preferably the amount of detersive surfactant in the spray-dried detergent particle is not less than 3 wt.%, still preferably not less than 5 wt.%, more preferably not less than 8 wt.%, still more preferably not less than 10 wt.%, but typically not more than 40 wt.%, preferably not more than 35 wt.% or still preferably not more than 30 wt.%. P0000411EP CPL 7 Preferably the amount of silicate salt and / or disilicate salt of alkaline earth metal in the spray- dried detergent particle is not less than 0.1 wt.%, still preferably not less than 0.2 wt.%, more preferably not less than 0.25 wt.%, still more preferably not less than 0.3 wt.%, but typically not more than 3.8 wt.%, preferably not more than 3 wt.% or still preferably not more than 2.5 wt.%. 5 Preferably the amount of alkaline earth metal salt, more preferably the hydroxide of alkaline earth metal salt in the spray-dried detergent particle is not less than 0.1 wt.%, still preferably not less than 0.2 wt.%, more preferably not less than 0.25 wt.%, still more preferably not less than 0.3 wt.%, but typically not more than 1.8 wt.%, preferably not more than 1.7 wt.% or still10 preferably not more than 1.65 wt.%. Organic carboxylic acid salt of aluminium: Preferably the organic carboxylic acid salt is an organic carboxylic acid salt of aluminium. Preferably the organic carboxylic acid salt of aluminium is aluminium citrate and preferably the aluminium citrate includes one or more of15 aluminium mono-citrate, aluminium dicitrate, aluminium tricitrate and mixtures thereof. Preferably, the organic carboxylic acid is selected from the group citric acid, malic acid, succinic acid, lactic acid, glycolic acid, fumaric acid, tartaric acid, formic acid, and mixtures thereof. More preferably, the organic carboxylic acid is citric acid, lactic acid, and tartaric acid. Most preferably20 organic carboxylic acid is citric acid. Preferably in addition to the organic carboxylic acid salt of aluminum, the spray-dried particle may additionally include any one of the ingredient selected from the group consisting of alkali metal aluminosilicate, alkali metal silicate, aluminium hydroxide, alkali metal salt of organic 25 carboxylic acid, silica, or mixtures thereof. Most preferably the organic carboxylic acid is citric acid. Preferably the amount of organic carboxylic acid salt of aluminum in the spray-dried detergent particle ranges from 0.4 wt.% to 10 wt.%. Preferably the amount of organic carboxylic acid salt 30 of salt of aluminum in the spray-dried detergent particle is not less than 0.45 wt.%, still preferably not less than 0.5 wt.%, still preferably not less than 0.6 wt.%, more preferably not less than 0.8 wt.%, still more preferably not less than 1 wt.%, but typically not more than 9.5 wt.%, preferably not more than 8 wt.% or still preferably not more than 7.5 wt.%, further preferably not more than 7 wt.%, most preferably not more than 6.5 wt.%. 35 P0000411EP CPL 8 Preferably the spray-dried detergent particle includes: (i) from 3 wt.% to 50 wt.% detersive surfactant; preferably anionic detersive surfactant; (ii) from 0.5 wt.% to 10 wt.% of one or more of organic carboxylic acid salt of aluminium, an aluminium complex of organic carboxylic acid or mixtures thereof; (iii) preferably from 2 wt.% to 12 wt.% organic carboxylic acid salt of alkali 5 metal; (iv) preferably from 0.75 wt.% to 3.5 wt.% silica; (v) preferably from 0 wt.% to 2 wt.% silicate salt of alkali metal; (vi) preferably from 0 wt.% to 1 wt.% aluminium hydroxide; (vii) preferably 25 wt.% to 88 wt.% filler; and, (viii) preferably from 1 wt.% to 3.5 wt.% moisture content. 10 Preferably the spray-dried detergent particle includes: (i) from 3 wt.% to 50 wt.% detersive surfactant; preferably anionic detersive surfactant; (ii) from 0.4 wt.% to 10 wt.% of one or more of organic carboxylic acid salt of aluminium, an aluminium complex of organic carboxylic acid or mixtures thereof; (iii) preferably from 0 wt.% to 12 wt.% organic carboxylic acid salt of alkali metal; (iv) preferably from 0 wt.% to 2 wt.% silicate salt of alkali metal; (v) preferably from 0 15 wt.% to 2 wt.% aluminium hydroxide; (vii) preferably 25 wt.% to 88 wt.% filler; and, (viii) preferably from 1 wt.% to 3.5 wt.% moisture content. Preferably the amount of silicate salt of alkali metal in the spray dried detergent particle is not less than 0.1 wt.%, still preferably not less than 0.2 wt.%, more preferably not less than 0.25 20 wt.%, still more preferably not less than 0.3 wt.%, but typically not more than 2 wt.%, preferably not more than 1.5 wt.% or still preferably not more than 1 wt.%. Preferably the spray dried detergent particle does not include alkali metal salt of silicate. Preferably the amount of aluminium hydroxide in the spray dried detergent particle is not less 25 than 0.01 wt.%, still preferably not less than 0.04 wt.%, more preferably not less than 0.06 wt.%, still more preferably not less than 1 wt.%, but typically not more than 0.8 wt.%, preferably not more than 0.7 wt.% or still preferably not more than 0.6 wt.%. Preferably the spray-dried detergent particle includes a mixture of organic carboxylic acid of 30 aluminum and organic carboxylic acid salt of alkali metal. The amount of organic carboxylic acid of alkali metal in the spray dried detergent particle is not less than 2.5 wt.%, still preferably not less than 3 wt.%, more preferably not less than 3.2, still more preferably not less than 3.5 wt.%, but typically not more than 11.5 wt.%, preferably not more than 11 wt.% or still preferably not more than 10.5 wt.%, more preferably not more than 10.3 wt.%, still more preferably not more35 than 10 wt.%. P0000411EP CPL 9 Preferably the amount of one or more of the organic carboxylic acid salts of aluminium, aluminium complex of organic carboxylic acid or mixtures thereof in the spray dried detergent particle is not less than 0.45 wt.%, still preferably not less than 1 wt.%, more preferably not less 5 than 1.5 wt.%, still more preferably not less than 2 wt.%, but typically not more than 9.5 wt.%, preferably not more than 9 wt.% or still preferably not more than 8.5 wt.%. Aluminium complex of organic carboxylic acid: Preferably the organic carboxylic acid salt is an aluminium complex of organic carboxylic acid. 10 Preferably in addition to the aluminium complex of organic carboxylic acid, the spray-dried particle may additionally include any one of the ingredient selected from the group consisting of organic carboxylic acid salt of aluminium, alkali metal aluminosilicate, alkali metal silicate, aluminium hydroxide, alkali metal salt of organic carboxylic acid, silica, or mixtures thereof.15 Most preferably the organic carboxylic acid is citric acid. Preferably the amount of aluminium complex of organic carboxylic acid in the spray-dried detergent particle ranges from 0.4 wt.% to 10 wt.%. Preferably the amount of aluminium complex of organic carboxylic acid in the spray-dried detergent particle is not less than 0.45 20 wt.%, still preferably not less than 0.5 wt.%, still preferably not less than 0.6 wt.%, more preferably not less than 0.8 wt.%, still more preferably not less than 1 wt.%, but typically not more than 9.5 wt.%, preferably not more than 8 wt.% or still preferably not more than 7.5 wt.%, further preferably not more than 7 wt.%, most preferably not more than 6.5 wt.%. 25 Preferably the spray-dried detergent particle includes: (i) from 3 wt.% to 50 wt.% detersive surfactant; preferably anionic detersive surfactant; (ii) from 0.5 wt.% to 10 wt.% of one or more of organic carboxylic acid salt of aluminium, an aluminium complex of organic carboxylic acid or mixtures thereof; (iii) preferably from 2 wt.% to 12 wt.% organic carboxylic acid salt of alkali metal; (iv) preferably from 0.75 wt.% to 3.5 wt.% silica; (v) preferably from 0 wt.% to 2 wt.% 30 silicate salt of alkali metal; (vi) preferably from 0 wt.% to 1 wt.% aluminium hydroxide; (vii) preferably 25 wt.% to 88 wt.% filler; and, (viii) preferably from 1 wt.% to 3.5 wt.% moisture content. Preferably the spray-dried detergent particle includes: (i) from 3 wt.% to 50 wt.% detersive 35 surfactant; preferably anionic detersive surfactant; (ii) from 0.4 wt.% to 10 wt.% of one or more P0000411EP CPL 10 of organic carboxylic acid salt of aluminium, an aluminium complex of organic carboxylic acid or mixtures thereof; (iii) preferably from 0 wt.% to 12 wt.% organic carboxylic acid salt of alkali metal; (iv) preferably from 0 wt.% to 2 wt.% silicate salt of alkali metal; (v) preferably from 0 wt.% to 2 wt.% aluminium hydroxide; (vii) preferably 25 wt.% to 88 wt.% filler; and, (viii) 5 preferably from 1 wt.% to 3.5 wt.% moisture content. Preferably the amount of silicate salt of alkali metal in the spray dried detergent particle is not less than 0.1 wt.%, still preferably not less than 0.2 wt.%, more preferably not less than 0.25 wt.%, still more preferably not less than 0.3 wt.%, but typically not more than 2 wt.%, preferably 10 not more than 1.5 wt.% or still preferably not more than 1 wt.%. Preferably the spray dried detergent particle does not include alkali metal salt of silicate. Preferably the amount of aluminium hydroxide in the spray dried detergent particle is not less than 0.01 wt.%, still preferably not less than 0.04 wt.%, more preferably not less than 0.06 wt.%, 15 still more preferably not less than 1 wt.%, but typically not more than 0.8 wt.%, preferably not more than 0.7 wt.% or still preferably not more than 0.6 wt.%. Preferably the spray-dried detergent particle includes a mixture of aluminium complex of organic carboxylic acid and organic carboxylic acid salt of alkali metal. The amount of organic 20 carboxylic acid of alkali metal in the spray dried detergent particle is not less than 2.5 wt.%, still preferably not less than 3 wt.%, more preferably not less than 3.2, still more preferably not less than 3.5 wt.%, but typically not more than 11.5 wt.%, preferably not more than 11 wt.% or still preferably not more than 10.5 wt.%, more preferably not more than 10.3 wt.%, still more preferably not more than 10 wt.%. 25 Preferably the amount of one or more of the organic carboxylic acid salts of aluminium, aluminium complex of organic carboxylic acid or mixtures thereof in the spray dried detergent particle is not less than 0.45 wt.%, still preferably not less than 1 wt.%, more preferably not less than 1.5 wt.%, still more preferably not less than 2 wt.%, but typically not more than 9.5 wt.%,30 preferably not more than 9 wt.% or still preferably not more than 8.5 wt.%. Organic carboxylic acid salt of alkali metal: Preferably the organic carboxylic acid salt is an organic carboxylic acid salt of alkali metal. Preferably the organic carboxylic acid salt of alkali metal is selected from the group consisting of mono alkali metal, dialkali metal, tri alkali metal35 salt of organic carboxylic acid salt or mixtures thereof. P0000411EP CPL 11 Preferably the spray-dried detergent particle includes a combination of organic carboxylic acid salt of alkali metal and an organic carboxylic acid. More preferably the organic acid salt of alkali metal is present in combination a salt of organic carboxylic acid selected from (a) organic 5 carboxylic acid salt of aluminium, (b) organic carboxylic acid salt of alkaline earth metal, (c) an aluminium complex of organic carboxylic acid and mixtures thereof. Preferably the spray-dried detergent particle includes a combination of organic carboxylic acid salt of alkali metal and silica. 10 Preferably the amount of organic carboxylic acid salt of alkali metal in the spray dried detergent particle ranges from 0.1 wt.% to 12 wt.% organic carboxylic acid salt of alkali metal. Preferably the amount of organic carboxylic acid salt of alkali metal in the spray dried detergent particle is not less than 2.5 wt.%, still preferably not less than 3.5 wt.%, more preferably not less than 5, still more preferably not less than 5.5 wt.%, furthermore preferably not less than 6 wt.%, but 15 typically not more than 11.5 wt.%, preferably not more than 11 wt.% or still preferably not 5 more than 10 wt.%, more preferably not more than 8 wt.%. Preferably the amount of detersive surfactant in the spray dried detergent particle is not less than 3 wt.%, still preferably not less than 5 wt.%, more preferably not less than 8 wt.%, still 20 more preferably not less than 10 wt.%, but typically not more than 45 wt.%, preferably not more than 40 wt.% or still preferably not more than 30 wt.%. Preferably the amount of moisture content present in the spray-dried particle is from 1 wt.% to 3.5 wt.%. Preferably the amount of moisture content present in the spray-dried particle is not 25 less than 2 wt.%, still preferably not less than 2.25 wt.%, more preferably not less than 2.5 wt.%, still more preferably not less than 2.75 wt.%, but typically not more than 3.5 wt.%, preferably not more than 3.25 wt.% or still preferably not more than 3.0 wt.%. Preferably the filler is present in an amount ranging from 25 wt.% to 88 wt.% in the spray-dried 30 detergent particle. Preferably the amount of filler is not less than 26 wt.%, still preferably not less than 30 wt.%, more preferably not less than 32 wt.%, still more preferably not less than 35 wt.%, but typically not more than 87 wt.%, preferably not more than 75 wt.% or still preferably not more than 65 wt.%, still more preferably not more than 50 wt.%. The filler acts as a balancing ingredient and can be a neutral inorganic salt or mineral, preferably sodium sulphate P0000411EP CPL 12 or sodium chloride. In one preferred embodiment, the filler is sodium chloride. In another preferred embodiment the filler is a mixture of sodium chloride and sodium sulphate. Additionally, one or more of optional ingredients may be present in the spray-dried detergent 5 5 particle. The optional ingredients may include but it not limited to polymer, hydrotropes, optical brighteners which is preferably selected from fluorescers, colorants, shading dye, pigments, or mixtures thereof and antifoam. Preferably the spray-dried detergent particle includes silica. Preferably the silica is present in an 10 amount ranging from 0.2 wt.% to 5 wt.%, still preferably from 0.2 wt.% to 3.5 wt.%, further preferably from 0.2 wt.% to 3 wt.%, still more preferably 0.5 wt.% to 2.5 wt.% in the spray-dried detergent particle. The silica may be either performed or generated in-situ. Preferably the spray- dried detergent particle has a mixture of organic carboxylic acid and silica, preferably in-situ formed silica. Preferably the spray-dried detergent particle has a mixture of a salt of organic 15 carboxylic acid according to the present invention and silica, preferably in-situ formed silica. More preferably the spray-dried detergent particle has a salt of organic carboxylic acid which is a combination of organic carboxylic acid salt of alkali metal and any one or more of the (a) organic carboxylic acid salt of alkaline earth metal, (b) organic carboxylic acid salt of aluminium and (c) an aluminium complex of organic carboxylic acid. 20 Preferably the spray-dried detergent particle has less than 2 wt.% alkali metal silicate, still preferably less than 1 wt.%, further preferably 0 wt.% alkali metal silicate. Preferably the spray-dried detergent particle has less than 2 wt.% carbonate builder, still 25 preferably less than 1 wt.%, further preferably 0 wt.% carbonate builder. Examples of the carbonate builder salt includes alkaline earth metal and alkali metal carbonates or mixtures thereof. Typically, the alkali metal carbonates are sodium and / or potassium carbonate of which sodium carbonate is mostly preferred. Alkali metal carbonate according to the invention refers to carbonates, bicarbonates, sesquicarbonates or mixtures thereof. 30 Preferably the spray-dried detergent particle has less than 2 wt.% inorganic phosphate builder, still preferably less than 1 wt.%, further preferably 0 wt.% inorganic phosphate builder. Examples of inorganic phosphate builder includes sodium orthophosphate, pyrophosphate and tripolyphosphate. 35 P0000411EP CPL 13 Optionally, the spray-dried detergent particle includes from 0 wt.% to 5 wt.% polymer, still more preferably from 0.5 to 5 wt.%, still more preferably 0.5 wt.% to 4 wt.% polymer by weight of the spray-dried detergent particle. Preferably the polymer is a carboxylate polymer. Still preferably a polyacrylate polymer, still preferably a copolymer of acrylic acid or methacrylic acid with maleic 5 acid. The spray dried detergent particle may include further polymer selected from antiredeposition polymer, soil release polymer, structuring polymer, or mixtures thereof. Preferably the polymer is a polymeric carboxylate, preferably polyacrylate or a copolymer of acrylic acid and maleic acid. However other polymers may also be suitable such as polyamines (including the ethoxylated variants thereof), polyethylene glycol and polyesters. Polymeric soil10 suspending aids and polymeric soil release agents are particularly suitable. Preferably the anti- redeposition agents are sodium carboxyl methyl cellulose. Preferably the spray-dried detergent particle has less than 2 wt.% zeolite builder, still preferably less than 1 wt.%, further preferably 0 wt.% zeolite builder by weight of the spray-dried detergent 15 particle. Examples of the zeolite builder includes zeolite A, zeolite 4A, aluminium zeolite P (zeolite MAP) described and claimed in EP 384070A (Unilever). Zeolite MAP is an alkali metal aluminosilicate of the P type having a silicon 10 to aluminium ratio not exceeding 1.33, preferably not exceeding 1.15, and more preferably not exceeding 1.07. 20 The spray dried detergent particle may be optionally contacted with a non-ionic surfactant, a fatty acid, or combinations thereof. The non-ionic surfactant and the fatty acid are in liquid form. In addition to the non-ionic surfactant and the fatty acid in liquid form any other liquid laundry ingredient which is not suitable to be added via slurry or tower, may be added by spraying the liquid onto the spray-dried detergent particle. 25 It is also preferred that the spray-dried detergent particle includes (i) 4 wt.% to 35 wt.% anionic surfactant, preferably alkyl benzene sulphonate (ii) 0 wt.% to 8 wt.% zeolite (iii) 0 wt.% to 4 wt.% phosphate builder (iv) 0 wt.% to 8 wt.% alkali metal carbonate, preferably sodium carbonate, (v) from 0 wt.% to 8 wt.% sodium silicate (vi) 1 wt.% to 10 wt.% organic acid, 30 preferably citric acid, (vii) from 0 wt.% to 10 wt.% magnesium sulphate. It is preferably found that when the spray dried detergent particle includes from 0.1 wt.% to 5 wt.% silica it provides good powder properties. Surfactant P0000411EP CPL 14 The spray-dried detergent particle preferably includes a surfactant. Suitable nonionic and anionic surfactants may be chosen from the surfactants described "Surface Active Agents" Vol. 1, by Schwartz & Perry, Interscience 1949, Vol.2 by Schwartz, Perry & Berch, Interscience 1958, in the current edition of "McCutcheon's Emulsifiers and Detergents" published by 5 Manufacturing Confectioners Company or in "Tenside-Taschenbuch", H. Stache, 2nd Edn., Carl Hauser Verlag, 1981 or in Anionic Surfactants: Organic Chemistry edited by Helmut W. Stache (Marcel Dekker 1996). Anionic surfactant 10 The spray-dried detergent particle preferably includes an anionic surfactant. The anionic surfactant may be sulphonate or sulphate surfactant. Preferably the anionic surfactant may be an alkoxylated surfactant. The sulphonate or sulphate surfactant may be linear or branched. The anionic surfactant comprises a sulphonate surfactant. Preferably the sulphonate surfactant 15 is an alkyl aryl sulphonate surfactant. More preferably the alkyl aryl sulphonate surfactant has a linear alkyl group comprising from C10 to C22 alkyl group, more preferably from C10 to C18 alkyl group, more preferably from C10 to C16 alkyl group still more preferably from C10 to C13 alkyl group. 20 Sulphonate surfactant: Preferably the sulphonate surfactant is an alkyl benzene sulphonate surfactant. Preferably the alkyl chain in the alkyl benzene sulphonate is straight or branched, more preferably linear. Preferably the sulphonate surfactant is a linear alkyl benzene sulphonate with a C10 to C18 alkyl group, still preferably C10 to C14 alkyl group and most preferably C10 to C13 linear alkyl benzene sulphonate. Preferably the higher linear alkyl benzene 25 sulfonate is a sodium alkylbenzene sulfonate surfactant (LAS), which preferably has a straight chain alkyl radical of average length of about 11 to 13 carbon atoms. Suitable alkyl benzene sulphonate (LAS) is obtainable, preferably obtained, by sulphonating commercially available linear alkyl benzene (LAB); suitable LAB includes low 2-phenyl LAB, other suitable LAB includes high 2-phenyl LAB, such as those supplied by Sasol under the tradename Hyblene®. 30 Preferably C10to C15alkyl benzene sulfonates (LAS), still preferably C10to C14alkyl benzene sulfonates (LAS), still preferably the benzene sulfonate (LAS) has at least 50 wt.% of C12alkyl benzene sulfonate, still preferably 80 wt.% C12alkyl benzene sulfonates. The alkyl benzene sulphonate is preferably in the salt form with the cation selected from alkali metal, alkaline earth P0000411EP CPL 15 metal or alkanolamine. Preferably alkali metal selected from sodium or potassium, most preferably sodium. Preferably the laundry detergent composition includes from 1 wt.% to 50 wt.% alkyl aryl 5 sulphonate surfactant. More preferably the alkyl aryl sulphonate surfactant is linear alkyl benzene sulphonate surfactant. Preferably the amount of linear alkyl benzene sulphonate surfactant ranges from 1 wt.% to 50 wt.%, still preferably from 5 wt.% to 50 wt.%, more preferably 8 wt.% to 50 wt.%, still more preferably from 10 wt.% to 50 wt.%. Still preferably the amount of linear alkyl benzene sulphonate surfactant is preferably in an amount ranging from 1 10 wt.% to 40 wt.%, still preferably from 5 wt.% to 40 wt.%, more preferably 8 wt.% to 40 wt.%, still more preferably from 10 wt.% to 40 wt.%. Preferably the amount of linear alkyl benzene sulphonate surfactant in the solid laundry detergent composition is not less than 1 wt.%, still preferably not less than 5 wt.%, more preferably not less than 8 wt.%, still more preferably not less than 10 wt.%, but typically not more than 45 wt.%, preferably not more than 40 wt.% or still15 preferably not more than 30 wt.%. Other suitable sulphonate surfactants include methyl ester sulphonates, alpha olefin sulphonates, modified alkylbenzene sulfonate (MLAS) as discussed in WO 99 / 05243, WO 99 / 05242 and WO 99 / 05244 and mixtures thereof. 20 Sulphate surfactant: Suitable sulphate surfactants include alkyl sulphate, preferably C8 to C18 alkyl sulphate, or predominantly C12 to C18 alkyl sulphate. The alkyl sulphate, alkyl alkoxylated sulphate may be linear or branched, substituted or un-substituted. The alkyl sulphate, alkyl alkoxylated sulphate and alkyl benzene sulphonate surfactant may be derived from 25 petrochemical material, biomaterial, or a waste material. Specific sulphated anionic surfactants which can be used in the solid laundry composition of the present invention include sulphated ethoxylated and non-ethoxylated fatty alcohols, preferably linear primary or secondary monohydric alcohols with C10to C18, preferably C12to C16, alkyl 30 groups and, if ethoxylated, on average from 1 to 15, preferably 3 to 12 moles of ethylene oxide (EO) per mole of alcohol, and sulphated ethoxylated alkylphenols with C8to C16alkyl groups, preferably C8to C9alkyl groups, and on average from 4 to 12 moles of EO per mole of alkyl phenol. A preferred sulphate detersive surfactant is alkyl alkoxylated sulphate, preferably alkyl ethoxylated sulphate, preferably a C8to C18alkyl alkoxylated sulphate, preferably a C8to C1835 alkyl ethoxylated sulphate, preferably the alkyl alkoxylated sulphate has an average degree of P0000411EP CPL 16 alkoxylation of from 0.5 to 20, preferably from 0.5 to 10, preferably the alkyl alkoxylated sulphate is a C8to C18alkyl ethoxylated sulphate having an average degree of ethoxylation of from 0.5 to 10, preferably from 0.5 to 5, more preferably from 0.5 to 3 and most preferably from 0.5 to 1.5. 5 Nonlimiting examples of sulphate anionic surfactants useful herein include: C10to C20primary, branched chain and random alkyl sulfates (AS); C10 to C18 secondary (2,3) alkyl sulfates; C10 to C18 alkyl alkoxy sulfates (AES) wherein x is from 1-30; mid-chain branched alkyl sulfates as discussed in US 6,020,303 and US 6,060,443; mid-chain branched alkyl alkoxy sulfates as10 discussed in US 6,008, 181 and US 6,020,303. The spray-dried detergent particle according to the invention may preferably include a hydrotrope. Preferably the hydrotrope is an aryl sulphonate which is either unsubstituted or substituted with a C1 to C4 alkyl group. Suitable example of unsubstituted aryl sulphonate 15 includes benzene sulphonate, preferably sodium benzene sulphonate. The term sulphonate include sulphonic acid. The hydrotrope is preferably present in the salt form which includes alkali metal, alkaline earth metal, alkyl amine or ammonium salt of the sulphonic acid. More preferably sodium salt. More preferably the hydrotrope is selected from the group consisting of a salt of benzene sulphonate, toluene sulphonate, xylene sulphonate, cumene sulphonate and 20 mixtures thereof, more preferably the hydrotrope is a sodium cumene sulphonate, sodium toluene sulphonate, sodium xylene sulphonate and mixtures thereof. Most preferably the hydrotrope is sodium cumene sulphonate. Fabric softening agent 25 According to the first aspect of the present invention, the solid laundry detergent composition includes a fabric softening agent selected from the group consisting of (i) cellulase enzyme (ii) fabric softening clay and chelating agent (iii) fabric softening clay and cationic polymer (iv) cationic polymer and chelating agent and mixtures thereof. Preferably the fabric softening agent includes a further fabric softening component selected from the group consisting of silicone,30 soap, and mixtures thereof. Cellulase: The fabric softening agent is preferably a cellulase enzyme. The term cellulase refers to an enzyme that hydrolzes a cellulosic material. Such enzymes include those selected from 35 endoglucanase (e.g., EC 3.2.1.4), cellobiohydrolase, beta-glucosidase, or combinations thereof. P0000411EP CPL 17 The cellulase may for example be a mono-component or a mixture of endo-1,4-beta-glucanase also referred to as endoglucanase. Suitable cellulases include those from bacterial origin, fungal origin, or a combination thereof. 5 Chemically modified or protein engineered mutants are also contemplated. Suitable cellulases include those from the genera Bacillus, Pseudomonas, Humicola, Myceliophthora, Fusarium, Thielavia, Trichoderma, and Acremonium. Exemplary cellulases include a fungal cellulase from Humicola insolens (US 4,435,307) or from Trichoderma, e.g., T. reesei or T. viride. Other suitable cellulases are from Thielavia e.g., Thielavia terrestris as described in WO 96 / 29397 or10 the fungal cellulases produced from Myceliophthora thermophila and Fusarium oxysporum disclosed in US 5,648,263, US 5,691,178, US 5,776,757, WO 89 / 09259 and WO 91 / 17244. Also relevant are cellulases from Bacillus as described in WO 02 / 099091 and JP 2000210081. Suitable cellulases are alkaline or neutral cellulases, preferably those having colour care benefits. Examples of cellulases are described in EP 0495257, EP 0531372, WO 96 / 11262, 15 WO 96 / 29397, WO 98 / 08940. Other examples are cellulase variants such as those described in WO 94 / 07998, EP 05 / 531315, US 5,457,046, US 5,686,593, US 5,763,254, WO 95 / 24471, WO 98 / 12307. Other cellulases are endo-beta-1,4-glucanase enzyme having a sequence of at least 97% 20 identity to the amino acid sequence of position 1 to position 773 of SEQ ID NO:2 of WO 2002 / 099091 or a family 44 xyloglucanase, which a xyloglucanase enzyme having a sequence of at least 60% identity to positions 40-559 of SEQ ID NO.2 of WO 2001 / 062903. Commercially available cellulases include Carezyme®, Carezyme®Premium, Celluzyme®,25 Celluclean®, Celluclast®, Endolase®, Renozyme®; Whitezyme®Celluclean®Classic, Cellusoft®(Novozymes A / S), Puradax®, Puradax HA, and Puradax EG (available from Genencor International Inc.) and KAC-500(B)™ (Kao Corporation). In an embodiment, the cellulase is obtained from Humicola in particular Humicola insolens. In 30 another embodiment, the cellulase is obtained from Bacillusin, in particular Bacillus akibai. In another embodiment, the cellulase is obtained from Paenibacillus, in particular Paenibacillus polmyxa. In yet another embodiment, the cellulase is obtained from Melanocarpus, in particular Melanocarpus albomyces. P0000411EP CPL 18 Preferably cellulase comprises the amino acid sequence of SEQ ID NO: 10, SEQ ID NO: 11, SEQ ID NO: 12 or SEQ ID NO: 13. More preferably the cellulase comprises an amino acid sequence having at least 60%, e.g., at least 65%, at least 70%, at least 75%, at least 80%, at least 85%, at least 90%, at least 91%, at least 92%, at least 93%, at least 94%, at least 95%, at 5 least 96%, at least 97%, at least 98%, at least 99%, or 100% sequence identity to the polypeptide of SEQ ID NO 10, SEQ ID NO: 10, SEQ ID NO: 11, SEQ ID NO: 12 or SEQ ID NO: 13. In one aspect, the cellulase comprises amino acid sequence which differ by up to 10 amino acids, e.g., 201, 2, 3, 4, 5, 6, 7, 8, 9, or 10, from the cellulase comprising amino acid sequence of SEQ ID NO: 10, SEQ ID NO: 10, SEQ ID NO: 11, SEQ ID NO: 12 or SEQ ID NO: 13. 10 Examples of these cellulase variants are described in WO 2021 / 058023 A1. The cellulase enzyme is preferably formulated in a solid form, preferably a granular form. The granular form may be produced as disclosed in US 4,106,991 and US 4,661,452, and may optionally be coated by methods known in the art. Examples of waxy coating materials are 15 poly(ethylene oxide) products (polyethyleneglycol, PEG) with mean molar weights of 1000 to 20000, ethoxylated nonylphenols having from 16 to 50 ethylene oxide units; ethoxylated fatty alcohols in which the alcohol contains from 12 to 20 carbon atoms and in which there are 15 to 80 ethylene oxide units; fatty alcohols; fatty acids; and mono- and di- and triglycerides of fatty acids. 20 Still preferably the cellulase may be formulated as a granule, preferably a co-granule which combines one or more additional enzymes. Non-limiting examples of the additional preferred enzymes includes proteases, amylases, lipases, cellulases, and / or nucleases (e.g., DNase, RNase). Each enzyme will then be present in more granules securing a more uniform 25 distribution of enzymes in the detergent. This also reduces the physical segregation of different enzymes due to different particle sizes. Methods for producing multi-enzyme co-granulate for the detergent industry are known to a person skilled in the art. Another example of cellulase enzymes in the form of co-granulates are disclosed in WO 2013 / 188331 A1. 30 Also preferred are the enzyme in the form of a granule having a core comprising cellulase enzyme and surrounded by one or more coating layers. The coating layers provide improved storage stability, reduce dust formation, or improve the color or appearance of the granule. The coating layers may include a salt, polyethylene glycol (PEG), methyl hydroxy propyl cellulose (MHPC), and polyvinyl alcohol (PVA). 35 P0000411EP CPL 19 The cellulase enzyme may also be formulated in an encapsulate form. The cellulase may be encapsulated in a matrix, preferably a water-soluble or water dispersible matrix (e.g., water- soluble polymer particles), for example as described in WO 2016 / 023685. An example of a water-soluble polymeric matrix is a matrix composition comprising polyvinyl alcohol. 5 The enzyme may also be encapsulated in core-shell microcapsules, for example as described in WO 2015 / 144784. Such core-shell capsules can be prepared using a number of technologies known in the art, e.g., by interfacial polymerization using either a water-in-oil or an oil-in-water emulsion, where polymers are crosslinked at the surface of the droplets in the emulsion (the10 interface between water and oil), thus forming a wall / membrane around each droplet / capsule. Preferably the cellulase enzyme may also be present as a multienzyme co-granule which in addition to cellulase includes one or more additional preferred enzyme selected from the group consisting of lipases, per hydrolases, peroxidases, laccases, first-wash lipases, proteases,15 mannanase, reductases, oxidases, nuclease, DNase, amylase, or mixtures thereof. It was observed that the fabric is rendered stiff due to the longer wash cycles adopted by the consumers even when a low pH composition having 0 wt.% to 8 wt.% sodium carbonate or even when 0 wt.% to 4 wt.% sodium carbonate is used for washing. When the fabrics have a 20 certain amount of stiffness after the wash, the laundry detergent composition is perceived to be harsh on the fabrics. The present inventors have found that this stiffness is addressed by the addition of a fabric softening agent which is cellulase enzyme as disclosed herein above. Preferably the levels of cellulase enzyme in the composition ranges from 0.0001 wt.% to 0.5 25 wt.%. Preferably the amount of the cellulase present in the composition is at least 0.001 wt.%, still preferably at least 0.01 wt.%, still preferably at least 0.02 wt.%, most preferably at least 0.03 wt.%, but typically not more than 0.3 wt.%, still preferably not more than 0.25 wt.%, most preferably not more than 0.2 wt.%. Levels of enzyme present in the composition preferably relate to the level of enzyme as pure protein. 30 Clay: The detergent composition according to the present invention includes a fabric softening agent which is preferably a mixture of fabric softening clay and cationic polymer. The detergent composition according to the present invention includes a fabric softening agent which is35 preferably a mixture of fabric softening clay and chelating agent. P0000411EP CPL 20 The clay may be selected from the group consisting of allophane clays; chlorite clays, preferred chlorite clays are amesite clays, baileychlore clays, chamosite clays, clinochlore clays, cookeite clays, corundophite clays, daphnite clays, delessite clays, gonyerite clays, nimite clays, odinite 5 clays, orthochamosite clays, pannantite clays, penninite clays, rhipidolite clays, sudoite clays and thuringite clays; illite clays; inter-stratified clays; iron oxyhydroxide clays, preferred iron oxyhydroxide clays are hematite clays, goethite clays, lepidocrite clays and ferrihydrite clays; kaolin clays, preferred kaolin clays are kaolinite clays, halloysite clays, dickite clays, nacrite clays and hisingerite clays; smectite clays; vermiculite clays; and mixtures thereof. 10 Preferably the clay is a smectite clay. The term smectite clays herein includes both the clays in which aluminium oxide is present in a silicate lattice and the clays in which magnesium oxide is present in a silicate lattice. Typical smectite clay compounds include the compounds having the general formula Al2(Si2O5)2(OH)2.nH2O and the compounds having the general formula 15 Mg3(Si2O5)2(OH)2.nH20. Smectite clays tend to adopt an expandable three-layer structure. Preferred may be three-layer, expandable alumino-silicates which having a dioctahedral crystal lattice, while the expandable three-layer magnesium silicates have a trioctahedral crystal lattice. Preferred smectite clay are beidellite clays, hectorite clays, laponite clays, montmorillonite 20 clays, volchonskoite clays, nontonite clays, saponite clays, sauconite clays and mixtures thereof. Preferably the smectite clay is a dioctahedral smectite clay, more preferably a montmorillonite clay. Dioctrahedral smectite clays typically have one of the following two general formulae:25 NaxAl2-xMgxSi4O10(OH)2 …………………………….. Formula (I) CaxAl2-xMgxSi4O10(OH)2…………………………….. Formula (II) where x is a number from 0.1 to 0.5, preferably from 0.2 to 0.4. Preferred clays are low charge montmorillonite clays (also known as a sodium montmorillonite 30 clay or Wyoming-type montmorillonite clay) which have a general formula corresponding to formula (I) above. Preferred clays are also high charge montmorillonite clays (also known as a calcium montmorillonite clay or cheto-type montmorillonite clay) which have a general formula corresponding to formula (II) above. P0000411EP CPL 21 Smectite clays, and more specifically montmorillonite clays, are preferred because of their desirable swelling and dispersing properties, which leads to a good fabric-softening profile. Preferred light coloured crystalline clay minerals are china clays, halloysite clays, dioctahedral 5 clays such as kaolinite, trioctahedral clays such as antigorite and amesite, smectite and honnite clays such as bentonite (montmorillonite), beidilite, nontronite, hectorite, attapulgite, pimelite, mica, muscovite and venniculite clays, as well as pyrophyllite / talc, willemseite and minnesotaite clays. Preferred light coloured crystalline clay minerals are described in GB2357523A and WO01 / 44425. 10 Preferred fabric softening clay have a cationic exchange capacity of at least 70meq / 100g. The cationic exchange capacity of clay can be measured using the method described in Grimshaw, The Chemistry and Physics of Clays, Interscience Publishers, Inc., pp.264-265 (1971). 15 Preferably the fabric softening agent is clay in combination with chelating agent, more preferably along with bicarbonate salt. Preferably the chelating agent is selected from the group consisting of polyacrylate and its derivatives; polyphosphate; phosphonates from the group amino alkane phosphonate, hydroxy alkane phosphonate, preferably HEDP, EDDS and mixtures thereof. Preferably the chelating agent is an amino carboxylate chelating agent. 20 Preferably the bicarbonate is a sodium bicarbonate. The clay preferably has a weight average particle size ranging from 180 micrometers to 1400 micrometres. Preferably, the clay has a weight average primary particle size, typically of greater than 20 micrometers, preferably more than 23 micrometers, preferably more than 25 25 micrometers, or preferably from 21 micrometers to 60 micrometers, more preferably from 22 micrometers to 50 micrometers, more preferably from 23 micrometers to 40 micrometers, more preferably from 24 micrometers to 30 micrometers, more preferably from 25 micrometers to 28 micrometers. However, it may also be preferred for the clay to have a weight average particle size of from 10 to 50 micrometers, more preferably from 20 to 40 micrometers. 30 In the detergent composition according to the present invention, the clay is preferably present in an amount from 2 wt.% to 20 wt.%, preferably from 2 wt.% to 10 wt.%, more preferably from 2 wt.% to 5 wt.%. P0000411EP CPL 22 Preferably the detergent composition comprises at least 2 wt.% clay based on the weight of the detergent composition, still preferably at least 2.5 wt.%, still preferably at least 3 wt.%, most preferably at least 4 wt.%, but typically not more than 15 wt.%, still preferably not more than 10 wt.%, most preferably not more than 8 wt.% of the clay. 5 Silicone: The solid laundry composition preferably includes a further fabric softening component which is a silicone which imparts a softening benefit on the fabric during the wash. 10 The silicone includes but is not limited to 1) non-functionalized silicones such as polydimethylsiloxane (PDMS) or alkyl (or alkoxy) functional silicones 2) functionalized silicones or copolymers with one or more different types of functional groups such as amino, phenyl, polyether, acrylate, silicon hydride, carboxylic acid, quaternized nitrogen, etc. 15 When the silicone is in the form of a silicone emulsion, then preferably the particle size is in the range from about 1 nm to 100 microns and preferably from about 10 nm to about 10 microns including microemulsions (< 150 nm), standard emulsions (about 200 nm to about 500 nm) and macroemulsions (about 1 micron to about 20 microns). 20 Preferred silicone are selected from polydialkylsiloxanes, especially polydimethylsiloxane; amino functionalized silicone; and anionic silicones, especially carboxyl functionalized silicone. Preferably the silicone is a polydimethylsiloxane. The polydimethylsiloxane has the general formula: 25 Formula III wherein, each R1and R2are methyl; and x is a number, typically a number greater than 50. The polydimethylsiloxane typically has a viscosity of from 5,000cP to 1,000,000cP, or from 30 10,000cP to 1,000,000cP, or from 10,000cP to 600,000cP, more preferably from 50,000cP to 400,000cP when measured at a shear rate of 20s-1and at ambient conditions (20°C and 1 atmosphere). Polydimethylsiloxanes having these preferred viscosities have an optimum P0000411EP CPL 23 deposition on fabric to provide a good fabric-softening benefit. The viscosity is typically measured using a Brookfield Viscometer at 25°C according to the method ASTM D 2983. A preferred form of the polydimethylsiloxane is in a pre-emulsified form. Typically, the emulsion 5 has a volume average primary droplet size of from 0.1 micrometers to 5,000 micrometers, preferably from 0.1 micrometers to 50 micrometers, and most preferably from 0.1 micrometers to 5 micrometers. The volume average primary particle size is typically measured using a Coulter MultisizerTMor by the method described in more detail below. The emulsion typically has a viscosity of from 1,500cP to 50,000cP, preferably from 2,000cP to 15,000cP. The 10 emulsion may comprise water and / or other solvents in an effective amount to aid the emulsification of polydimethylsiloxane / solvent mixture. Typically, the polydimethylsiloxane has a weight average molecular weight of greater than 3,700Da. 15 Preferably the further fabric softening silicone when used as the fabric softening agent is in combination with chelating agent, more preferably along with bicarbonate salt. Preferably the chelating agent is selected from the group consisting of polyacrylate and its derivatives; polyphosphate; phosphonates from the group amino alkane phosphonate, hydroxy alkane 20 phosphonate, preferably HEDP, EDDS and mixtures thereof. Preferably the bicarbonate is a sodium bicarbonate. Preferably the detergent composition according to the present invention includes silicone at a level of from 0.1 wt.% to 10 wt.%, preferably from 0.2 wt.% to 5 wt.%, more preferably from 0.5 25 wt.% to 3 wt.%. In the detergent composition according to the present invention, the silicone is preferably present in an amount from 0.1 wt.% to 10 wt.%, preferably from 0.2 wt.% to 10 wt.%, more preferably from 1 wt.% to 5 wt.%. Preferably the detergent composition comprises at least 0.2 wt.% silicone based on the weight of the detergent composition, still preferably at least 0.5 wt.%, still preferably at least 1 wt.%, most preferably at least 1.5 wt.%, but typically not more 30 than 8 wt.%, still preferably not more than 6 wt.%, most preferably not more than 5 wt.% of the silicone. Cationic polymer: Disclosed detergent composition includes a cationic polymer. The fabric softening agent 35 includes a mixture of fabric softening clay and cationic polymer. The cationic polymer preferably P0000411EP CPL 24 has a cationic charge density more than about 0.05 meq / g (meq meaning milliequivalents), to 23 meq / g, preferably from about 0.1 meq / g to about 4 meq / g, even more preferably from about 0.1 meq / g to about 2 meq / g and most preferably from 0.1 meq / g to about 1 meq / g. The above referenced cationic charge densities can be at the pH of intended use, which can be a pH from 5 3 to 12, optionally about 8 to 10. Preferably the cationic polymer is a substituted quaternary ammonium polysaccharide. Cationic charge density of a polymer refers to the ratio of the number of positive charges on the polymer to the molecular weight of the polymer. Charge density is calculated by dividing the 10 number of net charges per repeating unit by the molecular weight of the repeating unit. The positive charges may be located on the backbone of the polymers and / or the side chains of polymers. The charge density relates to the degree of cationic substitution and can be expressed with 15 nitrogen content of the cationic polymer. Preferred are cationic polymer having a nitrogen content % from 0.01 to 2.2%, more preferred are cationic polymers having a nitrogen content from 0.2 to 1.6%, and most preferred are cationic polymers having a nitrogen content from 0.3 to 1.4%. 20 The weight-average molecular weight of the cationic polymer may be from about 500 to about 5,000,000, or from about 1,000 to about 2,000,000, or from about 5000 to about 1,000,000 Daltons, as determined by size exclusion chromatography relative to polyethylene oxide standards with RI detection. In one aspect, the weight-average molecular weight of the cationic polymer may be from about 100,000 to about 800,000 Daltons. Without wishing to be bound by 25 theory, it is believed that polymers that are too high in mass can entrap soils and prevent them from being removed. In a preferred embodiment of the present invention, the use of cationic polymers with a weight average molecular weight of less than about 850,000 daltons is preferred, and even more preferred those with weight average molecular weight of less than 500,000 daltons. The preferred minimum average molecular weight is about 10,000 daltons,30 because smaller molecules are believed to be too small to give an effective softening benefit. Non-limiting examples of cationic polymers are cationic or amphoteric polysaccharides, proteins, and synthetic polymers. Cationic polysaccharides include cationic cellulose derivatives, cationic guar gum derivatives, chitosan and its derivatives and cationic starches. 35 Cationic polysaccharides have a molecular weight from about 1,000 to about 2 million, P0000411EP CPL 25 preferably from 20 about 100,000 to about 800,000. Suitable cationic polysaccharides include cationic cellulose ethers, particularly cationic hydroxyethylcellulose and cationic hydroxypropyl cellulose. Particularly preferred are cationic cellulosic polymers with substituted anhydroglucose units that correspond to the general Structural Formula as follows: 5 wherein R1, R2, R3are each independently selected from H, CH3, C8-24alkyl (linear or branched), 10 N is from about 1 to 10; Rx is selected from the group consisting of H, CH3, C8-24 alkyl (linear or branched), mixture thereof, wherein Z is a water soluble anion, preferably a chlorine ion and / or a bromine ion; R5is H, CH3, CH2CH3 or mixtures thereof; R7is CH3, CH2CH3, a phenyl group, C8-24 alkyl (linear or branched), or mixture thereof; and R8and R9are 15 each independently CH3, CH2CH3, a phenyl group, or mixtures thereof: with the proviso that at least one of R1, R2and R3per anhydroglucose unit is and each polymer has at least one group. The charge density of the cationic celluloses herein (as defined by the number of cationic 20 charges per 100 anhydroglucose units) is preferably from about 0.5 % to about 60%, more preferably from about 151% to about 20%, and most preferably from about 2% to about 10%. Alkyl substitution on the anhydroglucose rings of the polymer ranges from about 0.01% to 5% per glucose unit, more preferably from about 0.05% to 2% per glucose unit, of the polymeric 25 material. P0000411EP CPL 26 The cationic cellulose may lightly be cross-linked with a dialdehyde such as glyoxal to prevent forming lumps, nodules or other agglomerations when added to water at ambient temperatures. Examples of cationic hydroxyalkyl cellulose include those with the INCI name Polyquaternium 5 10 such as those sold under the trade names Ucare Polymer JR 30M, JR 400, JR 125, LR 400 and LK 400, Polymer PK polymers; Polyquaternium 67 such as those sold under the trade name Soltcat SK TM, all of which are marketed by Dow Chemicals, Midlad MI, and Polyquaternium 4 such as those sold under the trade name Celquat H200 and Celquat L-200 25 available from National Starch and Chemical Company, Bridgewater, NJ. Other suitable 10 polysaccharides include Hydroxyethyl cellulose or hydroxypropyl cellulose quaternized with glycidyl C12-C22 alkyl dimethyl ammonium chloride. Examples of such polysaccharides include the polymers with the INCI names Polyquaternium 24 such as those sold under the trade name Quaternium LM 200 by Dow Chemicals of Midland, ML Cationic starches refer to starch that has been chemically modified to provide the starch with a net positive charge in aqueous 15 solution at pH 3. This chemical modification includes, but is not limited to, the addition of amino and / or ammonium group(s) into the starch molecules. Non-limiting examples of these ammonium groups may include substituents such as trimethylhydroxypropyl ammonium chloride, dimethylstearylhydroxypropyl ammonium chloride, or dimethyldodecylhydroxypropyl ammonium chloride. The cationic starches may comprise amylase, amylopectin, or 20 maltodextrin. The cationic starch may comprise one or more additional modifications. For example, these modifications may include cross-linking, stabilization reactions, phophorylations, hydrolyzations, cross-linking. Stabilization reactions may include alkylation and esterification. Suitable cationic starches for use in the present compositions are commercially available from Cerestar under the trade name C*BOND®and from National Starch and Chemical Company 25 under the trade name CATO®2A. Cationic galactomannans include cationic guar gums or cationic locust bean gum. An example of a cationic guar gum is a quaternary ammonium derivative of Hydroxypropyl Guar such as those sold under the trade name Jaguar C13 and Jaguar Excel available from Rhodia, Inc of Cranbury NJ and N-Hance by Aqualon, Wilmington, DE. 30 Other suitable cationic polymers include polysaccharide polymers, cationic guar gum derivatives, quaternary nitrogen-containing cellulose ethers, synthetic polymers, copolymers of etherified cellulose, guar, and starch. Suitable cationic polymers are described in U.S. Pat. Nos. 3,962,418; 3,958,581; and U.S. Publication No.2007 / 0207109A 1. 35 P0000411EP CPL 27 One group of suitable cationic polymers includes those produced by polymerization of ethylenically unsaturated monomers using a suitable initiator or catalyst, such as those disclosed in WO 00 / 56849 and USPN 6,642,200. Suitable cationic polymers may be selected from the group consisting synthetic polymers made by polymerizing one or more cationic 5 monomers selected from the group consisting of N,N-dialkylaminoalkyl acrylate, N,N- dialkylaminoalkyl methacrylate, N,N-dialkylaminoalkyl acrylamide, N,N-dialkylaminoalkyl methacrylamide, quaternized N, N dialkylaminoalkyl acrylate quaternized N,N-dialkylaminoalkyl methacrylate, quaternized N,N-dialkylaminoalkyl aery1 amide, quaternized N,N5 dialkylaminoalkyl methacrylamide, Methacryloamidopropyl-pentamethyl-1,3-propylene-2-10 olammonium dichloride, N,N,N,N',N',N",N"-heptamethyl-N"-3-(1-oxo-2-methyl-2- propenyl)aminopropyl-9- oxo-g-azo-decane-1,4,10-triammonium trichloride, vinylamine and its derivatives, allylamine and its derivatives, vinyl imidazole, quaternized vinyl imidazole and diallyl dialkyl ammonium chloride and combinations thereof, and optionally a second monomer selected from the group consisting of acrylamide, N,N-dialkyl acrylamide, methacrylamide, 15 N,Ndialkylmethacrylamide, C1-C12 alkyl acrylate, C1-C12 hydroxyalkyl acrylate, polyalkylene glyol acrylate, C1-C12 alkyl methacrylate, C1-C12 hydroxyalkyl methacrylate, polyalkylene glycol methacrylate, vinyl acetate, vinyl alcohol, vinyl formamide, vinyl acetamide, vinyl alkyl ether, vinyl pyridine, vinyl pyrrolidone, vinyl imidazole, vinyl caprolactam, and derivatives, acrylic acid, methacrylic acid, maleic acid, vinyl sulfonic acid, styrene sulfonic acid, acrylamido 20 propylmethane sulfonic acid (AMFS) and their salts. The polymer may optionally be branched or cross-linked by using branching and crosslinking monomers. Branching and crosslinking monomers include ethylene glycoldiacrylate divinylbenzene, and butadiene. A suitable polyethyleneimine useful herein is that sold under the tradename Lupasol®by BASF, 20 AG, Lugwigschaefen, Germany. 25 The cationic polymer may be also selected from the group consisting of cationic polysaccharide, polyethylene imine and its derivatives, poly(acrylamide-codiallyldimethylanunonium chloride), poly(acrylamide-methacrylamidopropyltrimethyl ammonium chloride), poly(acrylamide-co-N,N- dimethyl aminoethyl acrylate) and its quaternized derivatives, poly(acrylamide-co-N,N-dimethyl 30 aminoethyl methacrylate) and its quaternized derivative, poly(hydroxyethylacrylate-co-dimethyl aminoethyl methacrylate), poly(hydroxpropylacrylate-co-dimethyl aminoethyl methacrylate), poly(hydroxpropylacrylatediallyldimethylammonium chloride-co-acrylic acid), co- methacrylamidopropyltrimethylammonium chloride), poly(acrylamide-copoly(acrylamide methacrylamidopropyltrimethyl ammonium chloride-co-acrylic acid), poly(diallyldimethyl 35 ammonium chloride), poly(vinylpyrrolidone-co-dimethylaminoethyl methacrylate), poly(ethyl P0000411EP CPL 28 methacrylate-co-quaternized dimethylaminoethyl methacrylate), poly(ethyl methacrylate-co- oleyl methacrylate-co-diethylaminoethyl methacrylate), poly(diallyldimethylammonium chloride- co-acrylic acid), poly(vinyl pyrrolidone-co-quaternized vinyl imidazole) and poly(acrylamide-co- Methacryloamidopropyl-pentamethy1-1,3-propylene-2-ol-ammonium dichloride), Suitable 5 cationic polymers include Polyquaternium- 1, Polyquaternium-5, Polyquaternium-6, Polyquaternium-7, Polyquaternium-8, Polyquaternium-10, Polyquaternium-11, Polyquaternium- 14, Polyquaternium-22, Polyquaternium-28, Polyquaternium-30, Polyquaternium-32 and Polyquaternium-33, as named under the International Nomenclature for Cosmetic Ingredients. 10 The cationic polymer may comprise polyethyleneimine or a polyethyleneimine derivative. In another aspect, the cationic polymer may comprise a cationic acrylic based polymer. In a further aspect, the cationic polymer may comprise a cationic polyacrylamide. In another aspect, the cationic polymer may comprise a polymer comprising polyacrylamide and polymethacrylamidopropyl trimethylammonium cation. In another aspect, the cationic polymer 15 may comprise poly(acrylamide- N-dimethyl aminoethyl acrylate) and its quaternized derivatives. In this aspect, the cationic polymer may be that sold under the tradename SEDIPUR, available from BTC Specialty Chemicals, a BASF Group, Florham Park, 15 N.J. In a yet further aspect, the cationic polymer may comprise poly (acrylamide-co- methacrylamidopropyltrimethyl ammonium chloride). In another aspect, the cationic polymer may comprise a non-acrylamide 20 based polymer, such as that sold under the tradename RHEOVIS CDE, available from Ciba Specialty Chemicals, a BASF group, Florham Park, N.J., or as disclosed in USPA 2006 / 0252668. In another aspect, the cationic polymer may be selected from the group consisting of cationic 25 polysaccharides. In one aspect, the cationic polymer may be selected from the group consisting of cationic cellulose ethers, cationic galactomannan, cationic guar gum, cationic starch, and combinations thereof. Another group of suitable cationic polymers may include alkylamine-epichlorohydrin polymers 30 which are reaction products of amines and oligoamines with epichlorohydrin, for example, those polymers listed in, for example, USPNs 6,642,200 and 6,551,986. Examples include dimethylamine-epichlorohydrin-ethylenediamine, available under the trade name CARTAFIX CB, CARTAFIX TSF, available from Clariant, Basle, Switzerland. P0000411EP CPL 29 Another group of suitable synthetic cationic polymers may include polyamidoamine epichlorohydrin (PAE) resins of polyalkylenepolyamine with polycarboxylic acid. The most common PAE resins are the condensation products of diethylenetriamine with adipic acid followed by a subsequent reaction with epichlorohydrin. They are available from Hercules Inc. 5 of Wilmington DE under the trade name KYMENE from BASF AG (Ludwigshafen, Germany) under the trade name LU RESIN. The cationic polymers may contain charge neutralizing anions such that the overall polymer is neutral under ambient conditions. Non-limiting examples of suitable counter ions (in addition to 10 anionic species generated during use) include chloride, bromide, sulfate, methylsulfate, sulfonate, methylsulfonate, carbonate, bicarbonate, formate, acetate, citrate, nitrate, and mixtures thereof. Most preferably the cationic polymer is a cationic polysaccharide. Preferred example of cationic 15 polysaccharide is a cationic cellulose derivative. Preferably a quaternary ammonium salt of modified cellulose, still preferably the cationic polymer is a quaternary ammonium salt of hydroxy cellulose. An example of this polymer is polyquaternium-10, marketed under the brand name UCARE™ Polymer, for example types of JR-400 and LR-400 (supplied by Amerchol Corporation). 20 The cationic polymer can be provided in a powder form. The cationic polymer can be provided in an anhydrous state. In a preferred embodiment of the present invention, the cationic polymer is contained in a co-granule. Preferably the co-granule comprises a binder, in addition to the cationic polymer. More preferably the co-granule also comprises either an organic or an 25 inorganic salt. Preferred binder materials are polyethylene glycol, soaps, and fatty acids. A preferred organic salt is sodium citrate, and a preferred inorganic salt is sodium sulphate. Soap: Disclosed solid detergent composition preferably includes a fabric softening component in 30 addition to the fabric softening agent, the fabric softening component is preferably a neutralized soap. Soaps are the fatty acid salts having the general formula (I) R3CO-OX ………………. Formula (IV) where R3CO = is a linear or branched, saturated or unsaturated acyl group containing 6 to 22 and preferably 12 to 18 carbon atoms 35 X is alkali and / or alkaline earth metal, ammonium, alkylammonium or alkanolammonium. P0000411EP CPL 30 Typical examples are the sodium, potassium, magnesium, ammonium and triethanolammonium salts of caproic acid, caprylic acid, 2-ethylhexanoic acid, capric acid, lauric acid, isotridecanoic acid, myristic acid, palmitic acid, palmitoleic acid, stearic acid, isostearic acid, oleic acid, elaidic 5 acid, petroselic acid, linoleic acid, linolenic acid, elaeostearic acid, arachic acid, gadoleic acid, behenic acid and erucic acid and technical mixtures thereof. Cocofatty acid or palm kernel oil fatty acid in the form of their salts are preferably used. Water-soluble salts of the higher fatty acids (i.e., "soaps") containing from about 8 to about 24 10 carbon atoms and preferably from about 10 to about 20 carbon atoms are useful, still preferred are those with 10 to 12 carbon atoms, and those with 16 to 18 carbon atoms. The soaps are either sodium, potassium, ammonium and alkanolammonium salts of higher fatty acids. Soaps can be made by direct saponification of fats and oils or by the neutralization of free fatty acids. Particularly useful are the sodium and potassium salts of the mixtures of fatty acids derived15 from coconut oil and tallow, i.e., sodium or potassium tallow and coconut soap. In the detergent composition according to the present invention, the neutralized soap is preferably present in an amount from 5 wt.% to 30 wt.%, preferably from 8 wt.% to 25 wt.%, more preferably from 10 wt.% to 20 wt.%. 20 Preferably the detergent composition comprises at least 8 wt.% neutralized soap based on the weight of the detergent composition, still preferably at least 9 wt.%, still preferably at least 9.5 wt.%, most preferably at least 10 wt.%, but typically not more than 25 wt.%, still preferably not more than 20 wt.%, most preferably not more than 15 wt.% of the neutralized soap. 25 Preferably the soap is used in combination with the cationic polysaccharide. More preferably a combination of soap along with chelating agent and cationic polymer. Chelating agent: 30 Preferably the composition according to the first aspect of the present invention includes a chelating agent along with fabric softening clay or the cationic polymer. Chelating agent as used herein includes those chemicals which interact with divalent ions, cations, and anions, having tendency to precipitate in their saturated aqueous solutions. 35 Chelating agents through threshold inhibition act as catalyst to delay the precipitation reaction P0000411EP CPL 31 of these ions in their saturated aqueous solutions. In the present context the term "chelating agent" comprises the catalyst, a cation of calcium and / or magnesium ions and carbonate anions. Throughout this document chelating agent and crystal growth inhibitor is used interchangeably. 5 The preferred chelating agent may contain an amino group and may be, e.g., an amino- polycarboxylate or a phosphonate. It may be a monomeric molecule comprising one, two or three amino groups (typically secondary or tertiary amino groups), and it may contain two, three, four or five carboxyl groups or even more carboxyl groups. The chelating agents may be 10 phosphorus containing or without phosphorus. Suitable chelating agents includes those based on carboxylate groups includes EDTA (ethylene diamine tetraacetate), NTA (2,2',2"-nitrilotriacetate), citrate, 2-hydroxypropan-l,2,3- tricarboxylate, DTPA (diethylenetriaminepentaacetic acid), MGDA (methylglycinediacetic acid οτ 15 Ν,Ν'-bis(carboxymethyl)alanine), EGTA (ethylene glycol tetraacetic acid), EDDS (ethylenediamine- N,W-disuccinic acid),, GLDA (L-Glutamic acid, Ν,Ν-diacetic acid), Polycarboxylates such as PAA [poly(acrylic acid)], PAA / PMA [copoly(acrylic acid / maleic acid)], or mixtures thereof. 20 Particularly preferred chelating agents includes but are not limited to the following: ethylene- diamine- tetra- acetic acid (EDTA), diethylene triamine penta methylene phosphonic acid (DTMPA, DTPMP), hydroxy-ethane diphosphonic acid (HEDP), ethylenediamine N,N- disuccinic acid (EDDS), methyl glycine di-acetic acid (MGDA), diethylene triamine penta acetic acid (DTPA), propylene diamine tetraacetic acid (PDTA), 2-hydroxypyridine-N-oxide (HPNO), 25 methyl glycine diacetic acid (MGDA), glutamic acid Ν,Ν-diacetic acid (N,N-dicarboxymethyl glutamic acid tetrasodium salt (GLDA) and nitrilotriacetic acid (NTA) or mixtures thereof. The chelating agent may be present in their acid form or a salt, preferably the chelating agents may be present as a sodium, ammonium, or potassium salt. Preferably the chelating agent is a gluconate. 30 Especially preferred chelating agent includes diethylenetriamine pentacetic acid (DTPA), ethylenediamine-N, N’-disuccinic acid (EDDS) and 1,1 hydroxyethane diphosphonic acid (HEDP) or the alkali metal, potassium, alkaline earth metal, ammonium or substituted ammonium salts thereof, or mixtures thereof. Preferably the chelating agent is a phosphonate. P0000411EP CPL 32 HEDP in its acid form or salt form with alkali metal, potassium, alkaline earth metal, ammonium or substituted ammonium is a highly preferred chelating agent. In the detergent composition according to the present invention, the chelating agent is 5 preferably present in an amount from 0.1 wt.% to 5 wt.%, preferably from 0.1 wt.% to 3 wt.%, more preferably from 0.1 wt.% to 1 wt.%. Preferably the detergent composition comprises at least 0.2 wt.% chelating agent based on the weight of the detergent composition, still preferably at least 0.3 wt.%, still preferably at least 0.5 10 wt.%, most preferably at least 0.6 wt.%, but typically not more than 3 wt.%, still preferably not more than 2 wt.%, most preferably not more than 1 wt.% of the chelating agent. Solid detergent composition The solid laundry detergent composition according to the first aspect preferably includes from 15 20 wt.% to 80 wt.% spray-dried detergent particle and a fabric softening agent. The solid detergent composition is a free-flowing particulate composition. The solid detergent composition is preferably a fully formulated composition. The composition according to the present invention may include further detergent particles 20 which may be made via a variety of conventional methods known in the art and those which includes but is not limited to the mixing of ingredients, including dry-mixing, compaction such as agglomerating, extrusion, tabletting, or spray-drying of the various compounds comprised in the detergent component, or mixtures of these techniques, whereby the components herein also can be made by for example compaction, including extrusion and agglomerating, or spray- 25 drying. The detergent composition may be made by any of the conventional processes, especially preferred is the technique of slurry making and spray drying. The compositions herein can take a variety of physical solid forms including forms such as powder, particulate, granule, ribbon, noodle, paste, tablet, flake, pastille, and bar, and 30 preferably the composition is in the form of powder, granules, or a tablet, still preferably the composition is in the form of a powder. The composition may be in the form of a unit dose formulation, delayed delivery formulation, detergent contained on or in a porous substrate or nonwoven sheet, and other suitable forms that may be apparent to one skilled in the art in view of the teachings herein. The composition according to the present invention may preferably be 35 in a form selected from powder, unit dose or pouch form, tablet, gel, paste, bar, or flake. P0000411EP CPL 33 Preferably the composition is for manual-washing or machine-washing. Preferably the composition is in the form of a spray -dried powder. The compositions preferably have a density of more than 350 grams / litre, more preferably more than 450 grams / litre or even more than 570 grams / litre. Preferably the composition is in the form of an agglomerate particle having a density 5 of 300 to 1000 g / L, more preferably from 400 to 850 g / L. Preferably the solid detergent composition includes plurality of chemically different particles that includes but is not limited spray-dried particles, co-granules, agglomerated particles, extruded particles. 10 The solid laundry detergent composition according to the present invention preferably has from 0 wt.% to 4 wt.% phosphate builder. Preferably the amount of phosphate builder is less than 3 wt.%, still preferably less than 2 wt.%, more preferably less than 1 wt.% by weight in the detergent composition and most preferably the detergent composition is substantially free of15 phosphate builder. The solid laundry detergent composition according to the present invention preferably includes from 0 wt.% to 6 wt.% bicarbonate salt, preferably sodium bicarbonate. Preferably the amount of bicarbonate salt is less than 5 wt.%, still preferably less than 2 wt.%, more preferably 20 less than 1 wt.% by weight in the detergent composition and most preferably the detergent composition is substantially free of bicarbonate salt. Preferably the bicarbonate salt is sodium bicarbonate. The solid laundry detergent composition according to the present invention preferably has from25 0 wt.% to 12 wt.% zeolite builder, more preferably 0 wt.% to 8 wt.% zeolite builder. Preferably the amount of zeolite builder is less than 5 wt.%, still preferably less than 3 wt.%, more preferably less than 2 wt.% by weight in the detergent composition and most preferably the detergent composition is substantially free of zeolite builder. 30 The solid laundry detergent composition according to the present invention preferably has from 0 wt.% to 5 wt.% alkali metal silicate, more preferably 0 wt.% to 3 wt.% alkali metal silicate. Preferably the amount of alkali metal silicate is less than 5 wt.%, still preferably less than 3 wt.%, more preferably less than 2 wt.% by weight in the detergent composition and most preferably the detergent composition is substantially free of alkali metal silicate. 35 P0000411EP CPL 34 The term “substantially free” means that the indicated component is at the very minimum, not deliberately added to the composition to form part of it, or, more typically, is not present at analytically detectable levels. It is meant to include compositions whereby the indicated material is present only as an impurity in one of the other materials deliberately included. 5 Preferably the solid laundry detergent composition according to the present invention has a pH from 6 to 10.5, more preferably 6.5 to 10.5, still more preferably 6.5 to 9, more preferably a pH ranging from 7 to 10.5, still more preferably from 7 to 9, when measured using a 1 wt.% solution with distilled water at 25°C. 10 Preferred ingredients The detergent composition of the present invention may preferably include one or more of the optional ingredients selected from the group consisting of cleaning and care ingredients. The optional ingredients include one or more adjunct cleaning additives selected from polymers, 15 enzymes, enzyme stabilizer, brightening agents, hueing agent, bleach, chelating agent, humectant, perfume, filler or carrier, an alkalinity system, a buffer, or combinations thereof. Surfactant: In addition to the anionic surfactant mentioned hereinabove, the solid laundry detergent20 composition may include a rhamnolipid biosurfactant. Preferably the rhamnolipid is a mono- rhamnolipids, di-rhamnolipids or mixtures thereof. Preferably the mono-rhamnolipids has a single rhamnose sugar ring. Preferably the di-rhamnolipids have two rhamnose sugar rings. Carboxylate surfactant: Other suitable anionic detersive surfactants include alkyl ether 25 carboxylate surfactant. Preferably the alkyl ether carboxylate surfactant has a structure: R- (OCH2CH2)n-OCH2-COOH, whereR is selected from saturated C8to C18linear alkyl chains, preferably C12, to C18linear alkyl chains, more preferably a C12or C18linear alkyl chain, most preferably a C12linear alkyl chain; n is the average ethoxylation and n is selected from 1 to 20, 5 to 20, preferably 7 to 14, more preferably 8 to 12, most preferably 9 to 11, also preferred are 30 C10to C18alkyl alkoxy carboxylates comprising 1-5 ethoxy units. Weights of alkyl ether carboxylic acid are calculated as the protonated form, R-(OCH2CH2)n-OCH2COOH. They may be used as salt version for example sodium salt, or amine salt. The alkyl chain is aliphatic and linear and may be selected from: CH3(CH2)7-; CH3(CH2)8-; CH3(CH2)9-; CH3(CH2)10-; CH3(CH2)11-; CH3(CH2)12-; CH3(CH2)13-; CH3(CH2)14-; CH3(CH2)15-; CH3(CH2)16-; and, 35 CH3(CH2)17-.The alkyl chain is preferably selected from CH3(CH2)15- and CH3(CH2)17-. Alkyl P0000411EP CPL 35 ether carboxylic acid are available from Kao (Akypo®), Huntsman (Empicol®) and Clariant (Emulsogen®). Nonionic surfactant: 5 Suitable non-ionic surfactants include C8to C18alkyl ethoxylates, C6to C12alkyl phenol alkoxylates wherein preferably the alkoxylate units are ethyleneoxy units, propyleneoxy units or a mixture thereof; alkylpolysaccharides, preferably alkylpolyglycosides; methyl ester ethoxylates; polyhydroxy fatty acid amides; ether capped poly(oxyalkylated) alcohol surfactants; and mixtures thereof. Preferably the nonionic surfactant is alkylpolyglucoside and / or an alkyl 10 alkoxylated alcohol. Preferably the alkyl alkoxylated alcohol includes C8 to C18 alkyl alkoxylated alcohol, preferably C8 to C18 alkyl ethoxylated alcohol, preferably the alkyl alkoxylated alcohol having an average degree of alkoxylation from 1 to 50, preferably from 1 to 10. Preferably the alkyl alkoxylated alcohol is a C8 to C18 alkyl ethoxylated alcohol having an average degree of ethoxylation of from 1 to 10, preferably from 1 to 7, more preferably from 1 to 5 and most 15 preferably from 3 to 7. The alkyl alkoxylated alcohol may be linear or branched and substituted or un-substituted. Cationic surfactant: Suitable cationic surfactants include alkyl pyridinium compounds, alkyl quaternary ammonium 20 compounds, alkyl quaternary phosphonium compounds, alkyl ternary sulphonium compounds, and mixtures thereof. Preferred cationic surfactants are quaternary ammonium compounds having the general formula: (R)(R1)(R2)(R3)N+X- wherein, R is a linear or branched, substituted or unsubstituted C6 to C18 alkyl or alkenyl moiety, R1 and R2 are independently selected from methyl or ethyl moieties, R3 is a hydroxyl, hydroxymethyl or a hydroxyethyl moiety, X is an anion 25 which provides charge neutrality, preferred anions include: halides, preferably chloride; sulphate; and sulphonate. Polymers: The composition of the present invention may preferably include polymers which provide30 cleaning or care benefits. The cleaning polymer includes but is not limited to soil release polymer, carboxylate polymers, antiredeposition polymers, cellulosic polymers, amphiphilic alkoxylated grease cleaning polymers, clay soil cleaning polymers, soil suspending polymers and mixtures thereof. The P0000411EP CPL 36 polymers providing care benefits includes care polymers, dye-transfer inhibiting polymer and mixtures thereof. Suitable carboxylate polymer includes polymers such as a maleate / acrylate random copolymer 5 or polyacrylate homopolymer. Suitable carboxylate polymers includes polyacrylate homopolymers having a molecular weight of from 4,000 Da to 9,000 Da; maleate / acrylate random copolymers having a molecular weight of from 30,000 Da to 100,000 Da, or from 50,000 Da to 100,000 Da, or from 60,000 Da to 80,000 Da. 10 Also suitable are homopolymer or copolymeric carboxylic acids, such as polyacrylic acid, polymethacrylic acid, polymaleic acid, copolymers of acrylic acid or Methacrylic acid with maleic acid and maleic acid with vinyl methyl ether, these polymeric acids being present as free acids or preferably as sodium salts. Preferred representatives of this group are sodium polyacrylate and sodium salts of acrylic acid-maleic acid copolymers having a weight ratio of acrylic acid: 15 maleic acid of 10: 1 to 1:1, preferably 7: 1 to 2: 1. These compounds generally have molecular weights of 3,000 to 150,000, preferably 5,000 to 100,000. Soil release polymers are designed to modify the surface of the fabric to facilitate the ease of removal of soil. Typically soil release polymers are based on or derivatives of polyethylene 20 glycol / vinyl acetate copolymers or polyethylene glycol terephthalate polyesters and combinations thereof. Preferred soil release polymer includes polymers of aromatic dicarboxylic acids and alkylene glycols (including polymers containing polyalkylene glycols), as described in WO2009 / 153184, EP2692842 and WO2014 / 019903. Suitable soil release polymers are sold by Clariant under the TexCare® series of polymers, e.g. TexCare® SRN240, TexCare® SRN100, 25 TexCare® SRN170, TexCare® SRN300, TexCare® SRN325, TexCare® SRA100 and TexCare® SRA300. Other suitable soil release polymers are sold by Rhodia under the Repel-o- Tex® series of polymers, e.g., Repel-o-Tex® SF2, Repel-o-Tex® SRP6 and Repel-o-Tex® Crystal. A preferred polymer is selected from the group consisting of polyester soil release polymer, both end-capped and non-end-capped sulphonated PET / POET polymers, both end- 30 capped and non-end-capped unsulphonated PET / POET polymers or combinations thereof. Preferably the levels of these soil release polymer in the solid laundry detergent composition ranges from 3 wt.% to 15wt.%, preferably at least 5 wt%, still preferably at least 6wt%, still preferably at least 6.5wt%, most preferably at least 7wt%, but typically not more than 14wt%,35 still preferably not more than 13wt%, most preferably not more than 12wt%. P0000411EP CPL 37 Anti-redeposition polymers are designed to suspend or disperse soil. Typically, antiredeposition polymers are polyethylene glycol polymers, polycarboxylate polymers, polyethyleneimine polymers or mixtures thereof. Such polymers are available from BASF under the trade name 5 Sokalan®CP5 (neutralised form) and Sokalan®CP45 (acidic form). Suitable antiredeposition polymers are ethoxylated and or propoxylated polyethylene imine or polycarboxylate materials, for example, acrylic acid-based homo or copolymers available under the trademark ACUSOL from Dow Chemical, Alcosperse from Akzonobel or Sokalan from BASF. 10 Preferably the composition comprises a biodegradable antiredeposition agent which is selected from the group consisting of cellulase, substituted polysaccharide and mixtures thereof. Preferably the substituted polysaccharide has a functional group present on the polysaccharide backbone and wherein said functional group is selected from the group consisting of alkyl, carboxyalkyl, carboxylic acid, alkoxy or salts thereof. 15 Copolymer acrylic acid and maleic acid or salt thereof: According to the first aspect of the present invention the solid laundry detergent composition preferably includes a copolymer of acrylic acid and maleic acid or salt thereof wherein the copolymer comprises a weight ratio of acrylic acid segment to the maleic acid segment ranging 20 from 1:1 to 1:9. More preferably the weight ratio of acrylic acid segment to the maleic acid segment ranges from 1:1.5 to 1:9, still more preferably from 1:2 to 1:9, furthermore preferably from 1:2.5 to 1:9, still further preferably from 1:3 to 1:9, still furthermore preferably from 1:3.5 to 1:9 and also preferred are ranges from 1:4 to 1:8, more preferably from 1:5 to 1:8, also preferably from 1:6 to 1:8. 25 The copolymer of acrylic acid and maleic acid has a weight average molecular weight ranging from 1000 to 100,000, more preferably from 1000 to 75000, more preferably 1000 to 65000, still more preferably from 1000 to 60000, still more preferably from 1500 to 60000, still more preferably from 2000 to 60000, still more preferably from 2000 to 30000, more preferably from 30 2000 to 25000. It is highly preferred that the copolymer has a weight average molecular weight in the range from 1000 to 25000 and a weight ratio of acrylic acid segment to the maleic acid segment from 1:1 to 1:9, still preferably from a weight average molecular weight in the range from 2000 to 35 25000 and a weight ratio of acrylic acid segment to the maleic acid segment from 1:1 to 1:9 and P0000411EP CPL 38 still further preferably where the weight average molecular weight in the range from 1000 to 5000 and a weight ratio of acrylic acid segment to the maleic acid segment from 1:1 to 1:9. Also preferred are the copolymer of acrylic acid and maleic acid or salt thereof wherein the 5 copolymer comprises a weight ratio of acrylic acid segment to the maleic acid segment ranging from 9:1 to 1:1. More preferably the weight ratio of acrylic acid segment to the maleic acid segment ranges from 9:1 to 8:2, still more preferably from 9:1 to 7:3, also preferably from 9:1 to 6:4. 10 Water-soluble salts of the copolymer of acrylic acid and maleic acid are also suitable for the present invention. The salts include those selected from non-limiting examples selected from alkali metal, ammonium, and substituted ammonium salts. Preferably the amount of copolymer of acrylic acid and maleic acid in the solid laundry 15 detergent composition ranges from 0.05 wt.% to 2 wt.%, more preferably from 0.05 wt.% to 0.5 wt.% still preferably from 0.05 wt.% to 0.3 wt.%, further preferably from 0.05 wt.% to 0.2 wt.%. Preferably the is amount of copolymer of acrylic acid and maleic acid in the solid laundry detergent composition is not less than 0.06 wt.%, still preferably not less than 0.07 wt.%, more preferably not less than 0.08 wt.%, still more preferably not less than 0.09 wt.%, but typically not 20 more than 0.45 wt.%, preferably not more than 0.3 wt.% or still preferably not more than 0.25 wt.%. Suitable care polymers include cellulosic polymers that are cationically modified or hydrophobically modified. Such modified cellulosic polymers can provide anti- abrasion benefits 25 and dye lock benefits to fabric during the laundering cycle. Suitable cellulosic polymers include cationically modified hydroxyethyl cellulose. Other suitable care polymers include dye lock polymers, for example the condensation oligomer produced by the condensation of imidazole and epichlorhydrin, preferably in ratio of 1:4:1. A suitable commercially available dye lock polymer is Polyquart® FDI (Cognis). Other suitable care polymers include amino-silicone, which 30 can provide fabric feel benefits and fabric shape retention benefits. Preferably the solid detergent composition includes care polymer in amounts ranging from 0.01 wt.% to 10 wt.%, preferably from 0.05 wt.% to 0.5 wt.% by weight of the composition. Suitable cellulosic polymers are selected from alkyl cellulose, alkyl alkoxyalkyl cellulose, P0000411EP CPL 39 carboxyalkyl cellulose, alkyl carboxyalkyl cellulose, sulphoalkyl cellulose, more preferably selected from carboxymethyl cellulose, methyl cellulose, methyl hydroxyethyl cellulose, methyl carboxymethyl cellulose, and mixtures thereof. Suitable carboxymethyl celluloses have a degree of carboxymethyl substitution from 0.5 to 0.9 and a molecular weight from 100,000 Da to 5 300,000 Da. Suitable carboxymethyl celluloses have a degree of substitution greater than 0.65 and a degree of blockiness greater than 0.45, e.g., as described in WO09 / 154933. Examples of suitable sequestering polymers are DEQUESTTM, organic phosphonate type sequestering polymers sold by Monsanto and alkanehydroxy phosphonates. 10 The cleaning composition is preferably substantially free of phosphate based sequestering polymers. By substantially free, it is meant herein that no phosphate based sequestering polymers is deliberately added. Preferably the solid laundry composition comprises phosphorous containing chemicals in an 15 amount ranging from 0 wt.% to 2 wt.%, preferably the phosphorous containing chemicals is selected from the group consisting of STPP, HEDP or mixtures thereof. Enzymes: The composition of the present invention preferably includes one or more enzymes. Preferred 20 examples of the enzymes include those which provide cleaning performance and / or fabric care benefits. Examples of suitable enzymes include, but are not limited to, hemicellulases, peroxidases, proteases, cellulases, xylanases, lipases, xyloglucanase, phospholipases, esterases, cutinases, 25 pectinases, mannanases, pectate lyases, keratinases, reductases, oxidases, phenoloxidases, lipoxygenases, ligninases, pullulanases, tannases, pentosanases, malanases, G-glucanases, arabinosidases, hyaluronidase, chondroitinase, laccase, and amylases, or mixtures thereof. A typical combination is an enzyme cocktail that may comprise, for example, a protease and lipase in conjunction with one or more of amylase, mannanase and cellulase. When present in a 30 detergent composition, the aforementioned additional enzymes may be present at levels from about 0.00001% to about 2%, from about 0.0001% to about 1% or from 0.001% to about 0.5% enzyme protein by weight of the detergent composition. In one aspect preferred enzymes would include a protease. Suitable proteases include 35 metalloproteases and serine proteases, including neutral or alkaline serine proteases, such as P0000411EP CPL 40 subtilisins (EC 3.4.21.62). Suitable commercially available protease enzymes include those sold under the trade names Alcalase®, Savinase®, Primase®, Durazym®, Polarzyme®, Kannase®, Liquanase®, Liquanase Ultra®, Savinase Ultra®, Ovozyme®, Neutrase®, Everlase® and Esperase® by Novozymes A / S (Denmark), those sold under the tradename Maxatase®, 5 Maxaca®l, Maxapem®, Properase®, Purafect®, Purafect Prime®, Purafect Ox®, FN3®, FN4®, 10 Excellase® and Purafect OXP® by Genencor International, those sold under the tradename Opticlean® and Optimase by Solvay Enzymes. Suitable commercially available alpha-amylases include DURAMYL®, LIQUEZYME®, 10 TERMAMYL®, TERMAMYL ULTRA®, NATALASE®, SUPRAMYL®, STAINZYME®, STAINZYME PLUS®, FUNGAMYL® and BAN® (Novozymes A / S, Bagsvaerd, Denmark), KEMZYM® AT 9000 Biozym Biotech Trading GmbH Wehlistrasse 27b A-1200 Wien Austria, RAPIDASE®, PURASTAR®, ENZYSIZE®, OPTISIZE HT PLUS®, POWERASE® and PURASTAR OXAM® (Genencor International Inc., Palo Alto, California) and KAM® (Kao, 14-10 15 Suitable amylases include NATALASE®, STAINZYME and STAINZYME PLUS® and mixtures thereof. Preferred lipases would include those sold under the tradenames Lipex® and Lipolex®. 20 Suitable endoglucanases are sold under the tradenames Celluclean® and Whitezyme® (Novozymes A / S, Bagsvaerd, Denmark). Other preferred enzymes include pectate lyases sold under the tradenames Pectawash®, Pectaway®, Xpect® and mannanases sold under the tradenames Mannaway® (all from 25 Novozymes A / S, Bagsvaerd, Denmark), and Purabrite® (Genencor International Inc., Palo Alto, California). Preferably the enzyme may be formulated as a granule, preferably a co-granule which combines one or more additional enzymes. Methods for producing multi-enzyme co-granulate 30 for the detergent industry are known to a person skilled in the art. Another example of cellulase enzymes in the form of co-granulates are disclosed in WO 2013 / 188331 A1. Also preferred are the enzyme in the form of a granule having a core comprising enzyme and surrounded by one or more coating layers. The coating layers provide improved storage 35 stability, reduce dust formation, or improve the color or appearance of the granule. The coating P0000411EP CPL 41 layers may include a salt, polyethylene glycol (PEG), methyl hydroxy propyl cellulose (MHPC), and polyvinyl alcohol (PVA). The enzyme may also be formulated in an encapsulate form. The enzyme may be encapsulated 5 in a matrix, preferably a water-soluble or water dispersible matrix (e.g., water-soluble polymer particles), for example as described in WO 2016 / 023685. An example of a water-soluble polymeric matrix is a matrix composition comprising polyvinyl alcohol. The enzyme may also be encapsulated in core-shell microcapsules, for example as described 10 in WO 2015 / 144784. Such core-shell capsules can be prepared using a number of technologies known in the art, e.g., by interfacial polymerization using either a water-in-oil or an oil-in-water emulsion, where polymers are crosslinked at the surface of the droplets in the emulsion (the interface between water and oil), thus forming a wall / membrane around each droplet / capsule. 15 Preferably the enzyme may also be present as a multienzyme co-granule which includes one or more additional preferred enzyme selected from the group consisting of lipases, peroxidases, laccases, first-wash lipases, proteases, mannanase, oxidases, amylase, and mixtures thereof. Enzyme stabilizing system: 20 The enzyme-containing compositions described herein may optionally comprise from 0.001% to 10%, in some examples from about 0.005% to about 8%, and in other examples, from about 0.01% to about 6%, by weight of the composition, of an enzyme stabilizing system. The enzyme stabilizing system can be any stabilizing system which is compatible with the detersive enzyme. Such a system may be inherently provided by other formulation actives, or be added separately, 25 e.g., by the formulator or by a manufacturer of detergent-ready enzymes. Such stabilizing systems can, for example, comprise calcium ion, boric acid, propylene glycol, short chain carboxylic acids, boronic acids, chlorine bleach scavengers and mixtures thereof, and are designed to address different stabilization problems depending on the type and physical form of the cleaning composition. In the case of detergent compositions comprising protease, a 30 reversible protease inhibitor, such as a boron compound, including borate, 4-formyl phenylboronic acid, phenylboronic acid and derivatives thereof, or compounds such as calcium formate, sodium formate and 1,2-propane diol may be added to further improve stability. Brightening agents: P0000411EP CPL 42 Optical brighteners or other brightening or whitening agents may be incorporated at levels from 0.01% to 1.2%, by weight of the composition. Commercial brighteners suitable for the present invention can be classified into subgroups, including but not limited to: derivatives of stilbene, pyrazoline, coumarin, benzoxazoles, carboxylic acid, methinecyanines, dibenzothiophene-5, 5- 5 dioxide, azoles, 5- and 6-membered-ring heterocycles, and other miscellaneous agents. Preferred commercially available Brighteners includes Tinopal AMS-GX by Ciba Geigy Corporation, Tinopal UNPA-GX by Ciba-Geigy Corporation, Tinopal 5BM-GX by Ciba-Geigy Corporation. The brighteners may be added in particulate form or as a premix with a suitable solvent, for example nonionic surfactant, monoethanolamine, propane diol. 10 Fabric hueing agents: The composition may comprise a fabric hueing agent (sometimes referred to as shading, bluing or whitening agents). Typically, the hueing agent provides a blue or violet shade to fabric. Hueing agents can be used either alone or in combination to create a specific shade of hueing 15 and / or to shade different fabric types. This may be provided for example by mixing a red and green-blue dye to yield a blue or violet shade. Hueing agents may be selected from any known chemical class of dye, including but not limited to acridine, anthraquinone (including polycyclic quinones), azine, azo (e.g., monoazo, disazo, trisazo, tetrakisazo, polyazo), including 30 premetallized azo, benzodifurane and benzodifuranone, carotenoid, coumarin, cyanine, 20 diazahemicyanine, diphenylmethane, formazan, hemicyanine, indigoids, methane, naphthalimides, naphthoquinone, nitro and nitroso, oxazine, phthalocyanine, pyrazoles, stilbene, styryl, triarylmethane, triphenylmethane, xanthenes and mixtures thereof. Suitable fabric hueing agents include dyes, dye-clay conjugates, and organic and inorganic pigments. 25 Preferably the composition comprises a non-biodegradable whitening agent selected from the group consisting of 0.01 to 0.4 wt.% optical brightener, 0.0005 wt.% to 0.005 wt.% shading dye, a mixture of 0.01 wt.% to 0.4 wt.% optical brightener and 0 to 0.005 wt.% shading dye, a pigment, and combinations thereof. 30 Bleach and bleach activator: The solid laundry detergent composition preferably includes a bleach system having a bleach and bleach activator. Highly preferably, the composition is substantially free of pre-formed peracid. The composition may preferably include (a) from 1 wt.% to 20 wt.% sodium percarbonate; (b) from 0.5 wt.% to 5 wt.% bleach activator; and (c) from 0.5 wt.% to 5 wt.% 35 chelant. The bleach activator may comprise sodium tetraacetylethylenediamine, and wherein P0000411EP CPL 43 the composition may comprise from 0.5 wt.% to 5 wt.% sodium tetraacetylethylenediamine. The chelant may comprise sodium salt of methylglycine diacetic acid (MGDA), and wherein the composition may comprise from 0.5 wt.% to 5 wt.% sodium salt of methylglycine diacetic acid (MGDA). The chelant may comprise ethylenediamine disuccinic acid (EDDS), and wherein the 5 composition may comprise from 0.5 wt.% to 5 wt.% ethylenediamine disuccinic acid (EDDS). The chelant may comprise disodium 4,5-dihydroxy-1,3-benzenedisulfonate, and wherein the composition may comprise from 0.5 wt.% to 5 wt.% disodium 4,5-dihydroxy-1,3- benzene disulfonate. 10 Fillers: Optionally the solid laundry detergent composition includes fillers such as sodium sulphate, sodium chloride, calcite, dolomite, or mixtures thereof. Preferably the filler is selected from sodium sulphate, sodium chloride and mixtures thereof. 15 Carbonate salt: The carbonate salt is preferably an alkali metal carbonate, alkaline earth metal carbonate or mixtures thereof. Preferred alkali carbonates are sodium and / or potassium carbonate of which sodium carbonate is particularly preferred. It is further preferred that sodium carbonate makes up at least 75 wt.%, more preferably at least 85 wt.% and even more preferably at least 90 wt.% 20 of the total weight of the carbonate salt. The detergent composition of the present invention includes from 0 wt.% to 10 wt.% carbonate salt. Preferably the detergent composition comprises from 0 wt.% to 4 wt.% carbonate salt based on the weight of the detergent composition. Preferably the composition of the present invention is substantially free of carbonate salt. Preferably the composition of the present invention has 0 wt.% sodium 25 carbonate. By substantially free it is meant that there is no deliberately added carbonate salt in the composition. Non-carbonate builder: In addition to the carbonate salt the detergent composition of the present invention may 30 preferably include a further non-carbonate builder. The preferred inorganic non-carbonate builders may be selected from the group consisting of silicates, silica, zeolites, phosphates, or mixtures thereof. Suitable silicates include the water-soluble sodium silicates with an SiO2: Na2O ratio of from 1.0 to 2.8, with ratios of from 1.6 to 2.4 being preferred, and 2.0 ratio being most preferred. The silicates may be in the form of either the anhydrous salt or a hydrated salt. 35 Sodium silicate with an SiO2: Na2O ratio of 2.0 is the most preferred silicate. Silicates are P0000411EP CPL 44 preferably present in the detergent composition in accord with the invention at a level from 0 wt.% to 5 wt.% by weight of the composition, more preferably from 0 wt.% to 4 wt.% in the detergent composition. Preferably the composition may comprise from 0 wt.% to 2 wt.% sodium silicate. Preferably the composition may comprise from 0 wt.% to 4 wt.% phosphate builder. 5 Preferably the composition may comprise from 0 wt.% to 12 wt.% zeolite builder, 0 wt.% to 8 wt.% zeolite builder, more preferably from 0 wt.% to 4 wt.% zeolite builder. The composition of the present invention preferably includes from 0 wt.% to 8 wt.%, still preferably from 0 wt.% to 5 wt.%, more preferably from 0 wt.% to 1 wt.% of an inorganic non- 10 carbonate builder selected from silica, zeolites, phosphate, or mixtures thereof. Preferably the composition of the present invention is substantially free of silicate salt, zeolite salt and phosphate builder. By substantially free it is meant that there is no deliberately added carbonate salt in the composition. 15 Moisture: Preferably the spray dried detergent particle includes from 1 wt.% to 3.5 wt.% moisture. Preferably the amount of moisture content present in the spray-dried particle is not less than 2 wt.%, still preferably not less than 2.25 wt.%, more preferably not less than 2.5 wt.%, still more preferably not less than 2.75 wt.%, but typically not more than 3.5 wt.%, preferably not more20 than 3.25 wt.% or still preferably not more than 3.0 wt.%. Cleaning ingredient: Preferably the cleaning ingredient is an amphoteric surfactant. Preferably the amphoteric surfactant may be alkyl betaine. Examples include Coco-Betaine, Lauryl Betaine and Oleyl 25 Betaine. Preferably the amphoteric surfactant may be an alkylamidoalkyl betaine. Preferably the amphoteric surfactant may be alkyl amine oxide. Examples include cocamine oxide and lauramine oxide. The most preferred amine oxide is coco dimethylamine oxide. Preferably the amphoteric surfactant may be alkylamidoalkyl amine oxide. Examples include 30 cocamidopropylamine oxide and lauramidopropylamine oxide, and combinations of two or more thereof. More preferably the betaine type amphoteric surfactant is selected from alkyl betaines, alkylamidoalkyl betaines and alkyl sulphobetaines. Preferably the amine oxide type amphoteric P0000411EP CPL 45 surfactant is selected from alkyl amine oxide, alkylamidoalkyl amine oxide or mixtures thereof. Most preferably the amphoteric surfactant is a cocamidopropyl betaine (CAPB). Preferably amphoteric surfactant is present in the solid detergent composition in an amount 5 ranging from 0.2 wt.% to 5 wt.% by weight of the composition. Preferably the cleaning ingredient is a mixture of amphoteric surfactant and a N-acylated lactam compound. Preferably the N-alkylated lactam compound is a pyrrolidone compound. More preferably the N-alkylated lactam compound is in a monomeric form or a polymeric form. Still10 more preferably the N-alkylated lactam compound is selected from the group consisting of: (i) N-alkylated pyrrolidone; N-alkylated piperidone, N-alkylated caprolactam, N-alkylated valerolactam, and mixtures thereof; or, (ii) homopolymer of N-alkylated pyrrolidone; (iii) copolymer of N-alkylated pyrrolidone with N-alkyl imidazole, N-alkyl carprolactam, N- 15 alkyl oxazolidones, polyvinyloxazolidone, or polyvinylimidazole, co-polymer of polyamine N-oxide polymers and N-vinylpyrrolidone; copolymers of N-vinylpyrrolidone and N- vinylimidazole; and combinations thereof; or, (iv) cross-linked polymer of polyamine N-oxide polymers; cross-linked polymer of N- vinylpyrrolidone and N-vinylimidazole; co polymer of polyamine N-oxide polymers and 20 N-vinylpyrrolidone copolymers of N-vinylpyrrolidone and N-vinylimidazole; cross-linked polyvinylpyrrolidone polymers; cross-linked polyvinyloxazolidone polymers; cross-linked polyvinylimidazoles polymer; and mixtures thereof. Preferably N-alkylated lactam compound is present in the solid detergent composition in an amount ranging from 0.2 wt.% to 2 wt.%. of the composition. Preferably the N-alkylated lactam25 compound is PVP. Preferably the cleaning ingredient is a mixture of PVP and CAPB. Preferably the cleaning ingredient is a mixture of non-ionic alkoxylated surfactant and amphoteric surfactant, the non-ionic alkoxylated surfactant is selected from the group consisting of polyoxyethylene-polyoxypropylene block copolymer, or a mixture of polyoxyethylene- 30 polyoxypropylene block copolymer and monomeric surfactant with an average degree of alkoxylation of from 10 to 50. Preferably the nonionic alkoxylated surfactant is a polyoxyethylene-polyoxypropylene block copolymer selected from the group consisting of: P0000411EP CPL 46 (i) a polyoxyethylene-polyoxypropylene block copolymer represented by the general formula (Ia) R-(EO)n-(PO)m-(EO)n-R’ ………….. Formula (Ia) wherein m is an integer from 10 to 130, each n is independently an integer from 2 to 60; and 5 where R and R’ are each independently selected from the group consisting of H, OH, C1to C18alkyl or C1to C18hydroxyalkyl or, (ii) a polyoxyethylene-polyoxypropylene block copolymer represented by the general formula (IIa) R-(PO)n-(EO)m-(PO)n -R’ ………… Formula (IIa) 10 wherein m is an integer of 15 to 150 and n at each end are independently integers of about 2 to 60 and where R and R’ are each independently selected from the group consisting of H, OH, C1 to C18 alkyl or C1 to C18 hydroxyalkyl; or, (iii) a polyoxyethylene-polyoxypropylene block copolymer represented by the general formula (IIIa) 15 ….. Formula (IIIa) where EO is ethylene oxide unit and PO is propylene oxide unit and a, b, and c, d and e each represent the number of ethylene oxide or propylene oxide units in each of the blocks, and where R and R' are independently H, C1 to C18 alkyl, C1 to C18 hydroxyalkyl or mixtures thereof. 20 Preferably nonionic alkoxylated surfactant is present in the solid detergent composition in an amount ranging from 0.2 wt.% to 2 wt.%. of the composition. Preferably the nonionic alkoxylated surfactant are those with Formula (Ia). Preferably the cleaning ingredient is a mixture of R- (EO)n-(PO)m-(EO)n -R’ block copolymer and CAPB. 25 Preferably the cleaning ingredient is a mixture of amphoteric surfactant and a silicone surfactant. Preferably the silicone surfactant is selected from the group consisting of: (i) a polydialkyl siloxane surfactant having the general formula (IVa), (Va) and mixtures thereof, ……….. (IVa) 30 ………( Va) P0000411EP CPL 47 where PE represent a non-ionic group and is represented by the formula (a) -CH2-(CH2)p-O-(EO)m(PO)n-Z, …… (a) wherein EO representing ethylene oxide, PO representing propylene oxide, “x” is a number that ranges from about 0 to about 100, “y” is a number that ranges from about 1 to 100, “m”, “n” and 5 “p” are numbers that range from 0 to 50, m+n ≥ 1 and Z represents hydrogen or R wherein each R independently represents a lower (C1to C6) straight or branched alkyl or PE is represented by formula (b) ………….. (b) or, PE is represented by formula (c) 10 ………. (c) or, Preferably silicone surfactant is present in the solid detergent composition in an amount ranging from 0.1 wt.% to 10 wt.%, more preferably from 0.2 wt.% to 5 wt.%, still more preferably from 0.2 wt.% to 2 wt.% by weight of the composition. Preferably the silicone surfactant herein described are commercially available under the tradename SILWET®and includes Silwet L-77 15 (from Supreme Silicone) or polyether or polybetaine polysiloxane copolymer under the tradename ABIL®. Preferred silicone surfactants are sold under the SILWET trademark or under the ABIL®B trademark. Preferably the cleaning ingredient is a mixture of Silwet L-77 and CAPB. 20 Preferably the cleaning ingredient is a mixture of amphoteric surfactant and a nonionic homopolymer. Preferably the nonionic homopolymer is selected from the group consisting of polyethylene glycol, polypropylene glycol, polybutylene glycol and mixtures thereof. More preferably the homopolymer is a polyethylene glycol, polypropylene glycol, or mixtures thereof. A highly preferred material is polyethylene glycol 6000. Commercially available 25 polyethylene glycol useful for the present invention includes Polymeg 4000 from India Glycols. Preferably the cleaning ingredient is a mixture of polyethylene glycol and CAPB. Slipperiness promoting agent: Preferably the solid laundry detergent composition includes a slipperiness promoting agent. 30 Preferably the slipperiness promoting agent is an ingredient which at 0.5 wt.% dilution in deionized water at 25°C provides a viscosity ranging from 1.5 to 65 cps, still preferably from 2.5 P0000411EP CPL 48 to 50 cps and still more preferably a viscosity ranging from 3 cps to 30 cps. The viscosity of the 0.5 wt.% dilution of the slipperiness promoting agent in deionized water measured at 25°C using a B-type viscometer. Preferably the slipperiness promoting agent provides the aqueous liquor a coefficient of friction from 0.45 to 0.28 in an aqueous solution which gives the desired 5 slipperiness benefits. A coefficient of friction of the aqueous liquor above or below these ranges was found to negatively impact on the benefits. Preferably the slipperiness promoting agent is a polymer. More preferably the polymer is selected from the group consisting of acrylic anionic polymer, long chain nonionic polyethylene 10 oxide polymer, glucamide based polymer, polysaccharide / cellulosic polymer, hyperbranched polymer, hypo conjugated polymer and mixtures thereof. Preferably the slipperiness promoting agent is an acrylic acid polymer. Preferably an anionic acrylic acid polymer. Suitable example of the acrylic anionic polymer includes those 15 commercially available from SNF under the tradename Flogel™and includes Flogel™FG 820, Flogel™FG840 and Flogel™MS 850. Preferably the amount of acrylic based anionic polymer in the solid laundry detergent composition ranges from 0.05 wt.% to 4 wt.%, more preferably from 0.05 wt.% to 2 wt.% still preferably from 0.05 wt.% to 1.5 wt.%, further preferably from 0.05 wt.% to 1 wt.%. 20 Preferably the slipperiness promoting agent is a long chain polyethylene oxide polymer. Preferably the polymer are nonionic. Preferably the long chain polyethylene oxide polymer has a weight average molecular weight of 100,000 Daltons or more, still preferably a weight average molecular weight of 100,000 Daltons to 10,000,000 Daltons. Suitable examples of the 25 commercially available long chain polyethylene oxide polymer include Polyox® WSR polyethylene oxide having a weight average molecular weight, Mw, of 5,000,000 Daltons available from The Dow Chemical Company and Polyox WSR N- 60K polyethylene oxide having a weight average molecular weight of 2, 000,000 Daltons available from The Dow Chemical Company. 30 Preferably the amount of long chain polyethylene oxide polymer having weight average molecular weight of 100,000 Daltons or more in the solid laundry detergent composition ranges from 0.05 wt.% to 2 wt.% P0000411EP CPL 49 Preferably the slipperiness promoting agent is an alkyl glucamide. More preferably N-methyl glucamide. The alkyl glucamide are non-ionic in which the hydrophilic part (an amino sugar derivative) and the hydrophobic part (a fatty acid) are linked by amide bonds. Preferably the alkyl glucamide has a general formula (Ib) 5 wherein R is a linear or branched, saturated or unsaturated hydrocarbyl group comprising 7 to 21 carbon atoms. More preferably a linear, saturated alkyl group comprising 7 to 21 and Ra is a C1to C4alkyl radical. Particularly Ra in the formula (Ib) is a methyl radical. 10 Preferably the alkyl glucamide is a N-methyl glucamide which has a formula (IIb) Formula (IIb) wherein R is a linear or branched, saturated or unsaturated hydrocarbyl group comprising 7 to 21 carbon atoms. 15 Non-limiting examples of the alkyl glucamide slipperiness promoting agent is N-octanoyl-N- methyl glucamide, N-nonanoyl-N-methyl glucamide, N-decanoyl-N-methyl glucamide, N- dodecanoyl-N-methyl glucamide, N-cocoyl-N-methyl glucamide, available under the trade name of GlucoPure Foam from Clariant, N-lauroyl / myristoyl-N-methyl glucamide, (available under the 20 trade name of GlucoPure Beg from Clariant, and N-octanoyl / decanoyI-N-methyl glucamide, available under the trade name of GlucoPure Wet by Clariant. Preferably the amount of alkyl glucamide slipperiness promoting agent present in the solid laundry detergent composition ranges from 0.05 wt.% to 2 wt.%. 25 Preferably the slipperiness promoting agent is a cellulosic polymer. The cellulosic polymer are selected from alkyl cellulose, alkoxyalkyl cellulose, carboxyalkyl cellulose, alkyl carboxyalkyl cellulose, sulphoalkyl cellulose and mixtures thereof. Suitable carboxymethyl cellulose have a degree of carboxymethyl substitution ranging from 0.5 to 0.9 and a molecular weight ranging P0000411EP CPL 50 from 100,000 Daltons to 300,000 Daltons. Suitable carboxymethyl cellulose have a degree of substitution greater than 0.65. More preferably the cellulosic polymer includes carboxymethyl cellulose, methyl cellulose, hydroxypropyl methylcellulose and mixtures thereof. Preferably the carboxymethyl cellulose is a sodium salt of carboxymethyl cellulose. 5 Preferably the amount of cellulosic polymer present in the solid laundry detergent composition ranges from 0.05 wt.% to 2 wt.%. In addition to the above-mentioned slipperiness promoting agent, it is advantageously found 10 that ingredients such as smectite clay, particularly bentonite clay; cationic surfactant, particularly CPC, CTAB; cationic polymer such as those commercially available under the tradename Sokalan HP 20 from BASF or under the tradename Softcat SK-MH and Softcat SL30 available commercially from Dow; fatty acids in amounts ranging from 1 to 3 wt.%, glycerol, polyvinyl alcohol having molecular weight from 85,000 to 124,000 Daltons may be 15 added to the composition for enhancing the slipperiness or soppiness sensorials of the wash liquor. Other ingredients which may also be advantageously included in the composition are polysaccharides in particular alginate, guar gum. Preferably the slipperiness promoting agent further includes a hydroxy alkyl guar gum preferably hydroxy propyl guar gum. Preferably the level of substitution is 0.6 or above, more preferably 1.0 to 1.5 and most preferably 1.2. 20 Preferably the hydroxy alkyl guar gum is available commercially under the tradename Jaguar®HP 11 has a degree of substitution of 0.35 to 0.45; Jaguar HP®60 has a degree of substitution of about 0.6; Jaguar®HP 80 has a degree of substitution of about 0.8 and Jaguar HP®120. Foaming ingredient: 25 Preferably the solid laundry detergent composition includes a foam enhancing ingredient. Preferably the foaming ingredient is a siloxane with a polyoxyalkylene group. The siloxane is preferably having a polyoxyalkylene group represented by the following general Formula (Ic) or Formula (IIc). (R13-aYaSiO1 / 2)j(R3 2-bYbSiO2 / 2)k(R2 2SiO2 / 2)p, (Ic) 30 Or, YaR1 3-aSiO(R2 2SiO)p(YR3SiO)mSiR1 3-aYa, (IIc) wherein: R1is same or different and is selected from an alkyl, alkenyl or aryl alkyl group having from 1 to 20 carbon atoms; or alkyl, alkenyl or aryl alkyl group having from 1 to 20 35 carbon atoms comprising a functional group, or mixtures thereof; Y is a polyoxyalkylene group P0000411EP CPL 51 having 19 to 30 oxyalkylene group, R2and R3are same or different and is selected from an alkyl, alkenyl or aryl alkyl group having from 1 to 20 carbon atoms; or alkyl, alkenyl or aryl alkyl group having from 1 to 20 carbon atoms comprising a functional group, wherein, a is 0, 1 or 2, b is 1 or 2, in Formula (I) where if a is 0 then p is 0 or an integer from 1 to 3, and if a is 1 or 2 then 5 p is 0 or an integer from 1 to 50, j, k, are independent of each other and is 0 or an integer from 1 to 50, where either j or k or both is at least 1, in Formula (Ic) m is an integer from 1 to 50, in Formula (IIc) with the proviso that the siloxane comprises at least one Y radical per molecule. Preferably the foaming ingredient is an isethionate based foaming ingredient which is preferably10 present in the solid laundry composition in an amount ranging from 0.2 wt.% to 5 wt.%. Examples of the isethionate based foaming ingredient includes but is not limited to the group consisting of sodium lauroyl methyl isethionate, ammonium cocoyl isethionate, sodium cocoyl isethionate, sodium hydrogenated cocoyl methyl isethionate, sodium lauroyl isethionate, sodium myristoyl isethionate, sodium oleoyl isethionate, sodium oleoyl methyl isethionate, sodium palm 15 kerneloyl isethionate, sodium stearoyl methyl isethionate, sodium isethionate, dibromopropamidine diisethionate, hexamidine diisethionate, sodium methyl isethionate, and combinations thereof. Most preferably the composition of the present invention comprises sodium lauroyl isethionate and / or sodium cocoyl isethionate. 20 Preferably the foaming ingredient is an alkyl ether carboxylic acid foaming ingredient. Suitable examples of commercially available alkyl ether carboxylic acid surfactant include those marketed under the trade name AKYPO® by Kao Chemicals GmbH, Empicol® by Huntsman and Emulsogen® by Clariant. The sodium salt of the alkyl ether carboxylic acid surfactant is most preferred. 25 The foaming ingredient is preferably a cationic polysaccharide. The cationic polysaccharide foaming ingredient comprises a polysaccharide or a derivative of polysaccharide which is modified with a cationic group selected from the group consisting of ammonium group, quaternary ammonium group, a sulfonium group, a phosphonium group, a transitional metal or 30 any other positively charged functional group. Preferably where the polysaccharide is selected from the group consisting of fructan, dextran, maltodextrin, or mixtures thereof. More preferably a fructan which is inulin. P0000411EP CPL 52 The foaming ingredient is preferably an alkyl amine salt of alkyl benzene sulphonate. Preferably the foaming ingredient is an alkyl amine salt of a linear or branched alkyl benzene sulphonate. More preferably the alkyl amine salt of alkyl benzene sulphonate is MIPA- LAS. 5 Preferably the foaming ingredient is an amide based foaming ingredient or salts thereof. Non limiting examples of the amide cosurfactant according to the present invention includes cocoamide diethanolamine, cocoamide dimethanolamine, cocoamide monoethanolamine, cocoamide monomethanol amine, cocoamide MIPA or mixtures thereof. More preferably the amide foaming ingredient according to the present invention includes cocoamide 10 monoethanolamine, cocoamide monomethanol amine, cocoamide MIPA or mixtures thereof. The foaming ingredient is preferably an amino acid-based foaming ingredient. The amino-acid based foaming ingredient is an anionic N-acyl amino acid surfactant. The foaming ingredient is preferably based on a sulphated ethoxylated C10 Guerbet alcohol with a number average 15 degree of ethoxylation in the range of 2.5 to 6. The foaming ingredient may be a C8 to C12 alkyl sulphate based foaming ingredient. The alkyl sulphate foaming ingredient may be primary or secondary alkyl sulphate with an alkyl chain length of C8 to C12. The foaming ingredient may be a C8 to C12 alkyl polyglucoside based foaming ingredient. The alkyl polyglucoside is a fatty alcohol glucoside with an alkyl chain length of C8 to C12. 20 Also preferred are foaming ingredients selected from amphoteric surfactant, preferably betaine amphoteric surfactant and particularly preferred are CAPB. Preferably the foaming ingredient present in the solid laundry detergent composition may be an 25 aryl sulphonate which is either unsubstituted or substituted with a C1 to C4 alkyl group. Suitable example of unsubstituted aryl sulphonate includes benzene sulphonate, preferably sodium benzene sulphonate. The term sulphonate include sulphonic acid. The hydrotrope is preferably present in the salt form which includes alkali metal, alkaline earth metal, alkyl amine or ammonium salt of the sulphonic acid. More preferably sodium salt. More preferably the foaming 30 ingredient is selected from the group consisting of a salt of benzene sulphonate, toluene sulphonate, xylene sulphonate, cumene sulphonate and mixtures thereof, more preferably the foaming ingredient is a sodium cumene sulphonate, sodium toluene sulphonate, sodium xylene sulphonate and mixtures thereof. Most preferably the foaming ingredient is sodium cumene sulphonate. 35 P0000411EP CPL 53 Fragrance: Preferably the solid laundry detergent composition includes a fragrance. Preferably the composition includes a free fragrance, encapsulated fragrance or combination of free fragrance and encapsulated fragrance. Preferably the solid laundry detergent composition has a free 5 fragrance in an amount ranging from 0.2 wt.% to 5 wt.%, more preferably from 0.2 wt.% to 3 wt.% and furthermore preferably from 0.2 wt.% to 1 wt.%. Preferably the solid laundry detergent composition has an encapsulated fragrance in an amount ranging from 0.2 wt.% to 5 wt.%, more preferably from 0.2 wt.% to 3 wt.% and furthermore preferably from 0.2 wt.% to 1 wt.%. 10 By free fragrance is meant fragrance which is not encapsulated as part of a delayed or controlled release mechanism. Preferably the free fragrance is selected from those having a functional group selected from aldehyde, carboxylic acid, esters and mixtures thereof. The aldehyde may be aliphatic, cycloaliphatic, aromatic, araliphatic and mixtures thereof. The term aldehyde in the context of the free fragrance also includes the corresponding acetals, ester, and 15 lactones. The esters include the aliphatic carboxylic acid esters, esters of cyclic alcohols, esters of cycloaliphatic carboxylic acids, aromatic and araliphatic carboxylic acid esters. The free fragrance may preferably be a fragrance oil. The fragrance oil is preferably selected from the group of extracts from natural raw materials, such as essential oils, concentrates, absolutes, resins, resinoids, balsams, tinctures, and mixtures thereof. 20 Preferably the fragrance is an encapsulated fragrance. Typically, the encapsulated fragrance comprises 10 wt.% to 98 wt.% core material comprising fragrance, 1 wt.% to 40 wt.% wall material and optionally 0.2 wt.% to 6 wt.% crosslinking agent. Preferably the encapsulated fragrance is friable fragrance. Preferably the encapsulated fragrance is a biobased 25 encapsulated fragrance. Preferably the encapsulated fragrance is a microencapsulated fragrance. Preferably the encapsulated fragrance has at least one fragrance encapsulated in an amine-aldehyde resin. More preferably the amine-aldehyde resin is melamine-formaldehyde. Preferably the encapsulated fragrance is a starch-based capsule. 30 Preferably the encapsulated fragrance is bio(micro)encapsulated fragrance. Biopolymers that are derived from alginate, chitosan, collagen, dextran, gelatin, gum arabic, silk and starch can also be used as the encapsulating materials. The wall material or shell material of these microcapsules preferably includes biopolymers, more preferably the shell material comprises protein polymers, polysaccharide polymers and combinations thereof. The protein and / or 35 polysaccharide may be treated by various processes to provide derivatives, including but not P0000411EP CPL 54 limited to hydrolysis, condensation, functionalizing such as ethoxylating, crosslinking, etc. The microcapsule wall materials are preferably in an aqueous solution. The microcapsule wall preferably comprises 20 wt.% to 100 wt.% protein, polysaccharide, or combinations thereof, more preferably 30 wt.% to 98 wt.%, more preferably 35 wt.% to 95 wt.%, and most preferably 5 65 wt.% to 90 wt.% by weight of the microcapsule wall. Suitable proteins for use in this invention include whey proteins, plant proteins and gelatin. Particularly preferred proteins include proteins selected from chickpea, pea proteins, potato proteins, brown rice proteins, white rice proteins, wheat proteins, barley proteins, pumpkin seed proteins, oat proteins, almond proteins, and combinations thereof. This includes derivatives of the aforementioned 10 proteins. Particularly preferred polysaccharides include gum arabic, dextrins, starch, and maltodextrins are particularly preferred. The polysaccharide used in the microcapsule can also be derivatized or modified (e.g., derivatized or chemically modified). For example, the protein can be modified by covalently attaching sugars, lipids, cofactors, peptides, or other chemical groups including phosphate, acetate, methyl, and other natural or unnatural molecule. 15 Examples of suitable polysaccharide derivatives include starch glycolate, carboxymethyl starch, hydroxyalkyl cellulose and cross-linked modified cellulose. Preferably the microencapsulated fragrance has a crosslinking agent. The crosslinking agent includes isocyanate crosslinking, salt bridge cross linking, carbonyl cross linking and internal crosslinking within the microcapsule wall polymer structure. Examples of carbonyl crosslinking agent includes dialdehydes. Polymeric 20 microcapsules suitable for use in the invention may be provided with a deposition aid at the outer surface of the microcapsules. Deposition aids serve to modify the properties of the exterior of the microcapsule, for example to make the microcapsule more substantive to a desired substrate. Desired substrates include cellulosics (including cotton) and polyesters (including those employed in the manufacture of polyester fabrics). The deposition aid may 25 suitably be provided at the outer surface of the microparticle by means of covalent bonding, entanglement, or strong adsorption. Preferably the encapsulated fragrance includes a capsule formation aid. The capsule formation aid improves the performance. The capsule formation aid may be a surfactant, dispersant, protective colloid, or emulsifier. The concentration of the capsule formation aid varies from 0.1 wt.% to 5 wt.% by weight of the capsule composition. The 30 encapsulated fragrance may include a catalyst. A catalyst is added to induce the interfacial polymerization in the formation of the capsule wall. Dissolution agent: Preferably the solid laundry detergent composition includes a dissolution ingredient. Preferably35 the dissolution ingredient improves the dissolution rate of the composition when added to water. P0000411EP CPL 55 The dissolution agent is preferably a hydrotrope, organic acids and organic salts. Foam suppressing agent: The solid laundry detergent composition may optionally include a foam suppressing agent 5 selected from the group consisting of silicone compound, amino silicone compound, diester compound, a glycerol derivative, and mixtures thereof. Preferably the solid detergent composition may include a layering agent. Preferably the levels of the layering agent range from 0 wt.% to 12 wt.%, more preferably from 0 wt.% to 8 wt.%. 10 Preferred layering agent includes zeolite, calcite, and mixtures thereof. Solid laundry detergent composition comprising spray dried detergent particle according to the present invention along with the fabric softening agent were formulated as15 provided in table 1 below. The spray dried detergent particle with the composition as shown in table 1A was prepared by a slurry making and spray-drying step using ingredients at specific levels to result in the spray dried particle as shown in table below and then post dosed with the fabric softening agent to 20 provide the fully formulated solid laundry composition as given in table 1B. The spray-dried particle may preferably include around 1.6 wt.% silica which in-situ formed. Table 1A Ingredients Ex 1a Ex 1b Ex 1c NaLAS 30 30 30 Magnesium citrate 0.56 0 0 Aluminium citrate 0 2.9 0 Aluminium citrate and complex of 0 0 3.18 aluminium with citric acid Sodium citrate (monosodium, 7.91 5.1 5 disodium, trisodium) Sodium carbonate 0 0 0 Sodium silicate 1.09 0.6 0 NDOM 1.28 0.7 0.64 Water 2 2 2 Sodium sulphate (filler) Upto 100 Upto 100 Upto 100 25 Table 1B P0000411EP CPL 56 Ingredients Ex 2 Ex 3 Ex 4 Ex 5 (wt.%) (wt.%) (wt.%) (wt.%) Spray-dried particle from table 1A 50 50 50 50 Fabric softening agent Cellulase 0.05 to 0.3 0 0 0 Softening clay 0 2 to 6 0 0 Cationic polymer 0 0 0.1 to 0.3 0 soap0 0 2 to 10 0 Modified silicone (polydimethylsiloxane) 0 0 0 0.5 to 2 Post dosed ingredients Na carbonate 0 to 10 0 to 10 0 to 10 0 to 10 Na silicate 0 to 5 0 to 5 0 to 5 0 to 5 Zeolite / calcite 0 to 12 0 to 12 0 to 12 0 to 12 Salt / Sulphate and their mixture Upto 100 Upto 100 Upto 100 Upto 100 All the solid laundry detergent composition according to the present invention having the spray dried detergent particle as mentioned in table 1 (Ex 1a, 1b, 1c) and the fabric softening agent (which may be selected from cellulase, fabric softening clay, cationic polymer and soap 5 or modified silicone) were found to provide excellent fabric softening performance. The solid laundry composition comprising low pH spray dried particle also provided good powder properties and storage properties over long periods without caking. Example 2: Different solid spray-dried laundry composition were prepared as shown in table 2. 10 The low pH base powder was prepared using the slurry and spray-drying route. The fabric softening agent and the filler was then post-dosed to formulate the finished solid laundry composition. Softness measurement: The fabric softness was measured using the Phabrometer Model FES- 15 3. A 4gpl aqueous liquor was prepared by weighing required amount of each of the solid laundry composition provided in table 2 and mixing it with 24 FH hardness.30 terry towels were taken, and they were soaked in the aqueous solution for 30 minutes. The cloth to aqueous liquor ratio 20 was maintained at 1:10. After the soaking time the terry towel were removed and manually squeezed softly and then rinsed. The rinsing was carried out in water with 24FH hardness. The rinsing step was repeated 3 times. After rinsing the terry towel were line dried in shade. This P0000411EP CPL 57 constitutes one wash cycle. The above process was repeated 5 times (5 wash cycles). The terry towels were evaluated for softness after 1 wash, 3 wash and 5 washes. Softness evaluation: The softness of the terry towel were evaluated using a PhabrOmeter FES- 5 3 instrument (ex. Nu Cybertek, Inc. in California, USA). The evaluation was conducted according to the AATCC TM202 standard. The measurement were taken at 20ºC and 65% Humidity conditions. The washed and dried terry towels were conditioned by keeping them for minimum 24 hours at 20ºC and 65% (+ / - 5%) humidity conditions before evaluating. 10 Table 2 Ingredients Ex A Ex 6 Anionic surfactant (LAS) 25 25 Sodium citrate 7.4 7.4 Magnesium citrate 1.3 1.3 Sodium silicate 2 2 Silica 1.25 1.25 Softening clay (bentonite) 4 4 Cationic polymer 0 4 Moisture 2.5 2.5 Filler (sodium sulphate and / or salt) Upto 100 Upto 100 Softness data After 1 wash 64.00 64.75 After 3 washes 63.72 64.58 After 5 washes 64.04 65.07 The data provided in table 2 shows that the comparative Ex A which has a fabric softening clay, shows inferior performance towards providing softness benefits when compared to a composition having fabric softening clay and a cationic polymer. The difference is better even15 after multiple washes.

Claims

P0000411EP CPL 58 Claims 1. A solid laundry detergent composition comprising: (i) a spray dried detergent particle wherein the spray dried particle comprises (i) an organic carboxylic acid, or (ii) a salt of organic carboxylic acid selected from (a) organic carboxylic acid salt of alkaline earth metal, (b) organic carboxylic acid salt of aluminium (c) an aluminium complex of organic carboxylic acid (d) organic carboxylic acid salt of alkali metal and mixtures thereof; where the spray-dried detergent particle has an equilibrium pH of 4 or more when measured at 1 wt.% dilution in deionized water at 25°C; and, (ii) a fabric softening agent selected from the group consisting of (i) cellulase enzyme (ii) fabric softening clay and chelating agent (iii) fabric softening clay and cationic polymer (iv) cationic polymer and chelating agent, and mixtures thereof; and wherein the spray dried detergent particle comprises 0 wt.% to 4 wt.% sodium carbonate.

2. A composition according to claim 1 wherein the solid laundry detergent composition has a pH ranging from 6 to 9, more preferably 6.5 to 9 when measured at 1 wt.% dilution in deionized water at 25°C.

3. A composition according to claim 1 or 2 wherein the salt of organic carboxylic acid comprises a combination of organic carboxylic acid salt of alkali metal and any one of (a) organic carboxylic acid salt of alkaline earth metal, (b) organic carboxylic acid salt of aluminium and (c) an aluminium complex of organic carboxylic acid.

4. A composition according to any one of the preceding claims 1 to 3 wherein the spray dried detergent particle comprises silica, preferably where the silica is in-situ formed.

5. A composition according to any one of the preceding claims wherein the fabric softening agent comprises a further fabric softening component selected from the group consisting of silicone, soap, and mixtures thereof.

6. A composition according to claim 5 wherein the silicone is a polydimethylsiloxane.

7. A composition according to any one of the preceding claims wherein the fabric softening clay is smectite clay, preferably bentonite, more preferably sodium form of bentonite.P0000411EP CPL 59 8. A composition according to any one of the preceding claims wherein the cationic polymer is a cationic polysaccharide, more preferably a cationic cellulose derivative, still more preferably a quaternary ammonium salt of modified cellulose, preferably a quaternary ammonium salt of hydroxy cellulose.

9. A composition according to any one of the preceding claims wherein the spray-dried detergent particle comprises an anionic surfactant, preferably the anionic surfactant is selected from the group consisting of alkyl sulphate, alkyl sulphonate, alkyl ether sulphonate or combinations thereof, preferably the anionic surfactant is an alkali metal salt of C10 to C18 alkyl benzene sulfonic acid.

10. A composition according to any preceding claim, wherein the composition comprises: (i) from 0 wt.% to 6 wt.% sodium bicarbonate; (ii) from 0 wt.% to 4 wt.% sodium carbonate; (iii) from 0 wt.% to 4 wt.% sodium silicate; and (iv) from 0 wt.% to 4 wt.% phosphate builder, and optionally wherein the composition is substantially free of phosphate builder, and optionally wherein the composition is substantially free of sodium carbonate, and optionally wherein the composition is substantially free of sodium bicarbonate, and optionally wherein the composition is substantially free of sodium silicate.

11. A composition according to any one of the preceding claims, wherein the composition comprises a soil release polymer, preferably the soil release polymer is a polyester soil release polymer.

12. A composition according to any one of the preceding claims, wherein the composition comprises a chelating agent, preferably the chelating agent is MGDA, GLDA, ALDA, EDDS, gluconate, and mixtures thereof.

13. A composition according to any one of the preceding claims wherein the composition comprises an antiredeposition agent which is selected from the group consisting of cellulase and substituted polysaccharide, and substituted polysaccharide.P0000411EP CPL 60 14. A composition according to any one of the preceding claims wherein the composition comprises an antiredeposition agent selected from the group consisting of polyacrylates, copolymer of acrylic acid or methacrylic acid with maleic acid having a weight ratio of acrylic to maleic acid ranging from 9:1 to 1:9 or maleic acid with vinyl ester and combinations thereof.

15. A composition according to any one of the preceding claims wherein the composition comprises a whitening agent selected from the group consisting of 0.01 wt.% to 0.4 wt.% optical brightener, 0.0005 wt.% to 0.005 wt.% shading dye, a mixture of 0.01 wt.% to 0.4 wt.% optical brightener and 0 to 0.005 wt.% shading dye, a pigment, and combinations thereof.

Citation Information

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