Lignin-based polymers and methods of making the same

Abstract

Disclosed herein are lignin-based polymeric materials and methods of making the same. The disclosed polymeric materials can reversibly capture CO2. Also disclosed are methods of forming high-value chemicals from the captured carbon dioxide by the polymeric materials disclosed herein. Also disclosed herein are methods of making polyhydroxyurethanes by reacting lignin-base materials with polyamines.

Description

Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 LIGNIN-BASED POLYMERS AND METHODS OF MAKING THE SAME CROSS-REFERENCE TO RELATED APPLICATION

[0001] This application claims the benefit of U.S. Provisional Application 63 / 568,120, filed March 21, 2024, the contents of which are hereby incorporated in its entirety. FIELD

[0002] The present invention relates generally to lignin-based polymers that can, for example, be reacted with carbon dioxide and then, if needed, converted to other high-value polymers. The present invention also relates to articles comprising the described lignin- based polymers and methods for the manufacture and use of the same. BACKGROUND

[0003] Carbon dioxide (CO2), a significant greenhouse gas, comprises a major portion of emissions from industry and automobiles. In the last 200 years, there has been a significant increase in human-caused CO2 emissions, which has triggered the concentration of CO2 in the atmosphere to rise exponentially from around 280 parts per million to over 415 parts per million at now. As a consequence of this process, the average worldwide temperature has already risen noticeably (by around 0.8 °C) over preindustrial times. It is widely acknowledged that the significant rise in atmospheric carbon dioxide levels is the prevailing reason for climate changes, including desertification, rising sea levels, melting glaciers and ice shelves, and extreme uncertain weather conditions. In an attempt to reduce global warming, most countries are seeking ways to reduce greenhouse gas emissions and shifting towards the use of renewable resources.

[0004] Therefore, finding a purpose for waste CO2that does not involve releasing it into the environment is crucial. Carbon capture and storage (CCS) and carbon capture and utilization (CCU) are the two potential options. The CCS approach entails the capture and purification of waste CO2 from the environment or from any particular source. Then, the captured gas undergoes a pressurization process for transportation to a storage facility. The CCS process is expensive because CO2 is handled as a useless waste. Contrary to CCS, CO2is regarded as a valuable resource in CCU, where it can be used to synthesize chemicals and fuels that are crucial to the global economy. In such a way, the production of energy and chemicals is moved from a linear to a circular sustainable economy, and CO2is valued as a renewable C1 chemical feedstock.

[0005] Biomass is an essential component of the global carbon cycle and plays an important role in mitigating climate change. Lignin is the most abundant natural aromatic polymer on the planet and is the second most abundant biomass after cellulose. It hasAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 several advantageous potentials, including antioxidant activity, high carbon content, nontoxicity, high thermal stability, rigidity, and antibacterial activity. The pulp and paper industry is anticipated to generate 70 million tons / year of waste lignin, of which less than 10 % is separated and transformed into industrial chemical supplies. The 90 % of the remaining industrial lignin is utilized in low-valorization of lignin for fuel combustion. There has been a growing interest in lignin high-value valorization in recent years. The dependency on fossil fuels is mitigated by the effective management of lignin disposal, where lignin can be used instead of traditional petroleum-based raw materials. Additionally, employing lignin for CO2capture and utilization provides a pioneering approach to combat greenhouse CO2emissions. Similarly, the use of lignin to form high-value chemicals can provide an additional route to reducing dependency on petroleum-based raw materials.

[0006] CO2capturing mechanisms prevalently consist of adsorption and absorption. Adsorption is the process in which CO2adheres to the surface of an adsorbent by either weak van der Waals forces (physisorption) or stronger chemical bonds (chemisorption). In contrast, absorption is governed by the permeation and uniform dispersion of the absorbate (CO2) throughout the absorbent's volume. Sorption is a broader term that encompasses both adsorption and absorption. In physisorption, the carbon atom within the CO2 molecule adopts a sp hybridization, leading to a substantial overlap of bonding orbitals that restricts reactivity. On the contrary, chemically captured CO2 undergoes a structural transformation into a more reactive state with trigonal planar sp2hybridization, resulting in the formation of bicarbonate and carbamates. Bicarbonate (-45 kJ mol-1) demonstrates greater reactivity compared to carbamate (-80 kJ mol-1), indicating that the production of bicarbonate serves to activate CO2 for subsequent reuse.

[0007] The prospect of designing a single material that can be capable of both capturing CO2[carbon capture and storage (CCS)] and converting the captured-CO2into valuable substances [carbon capture and utilization (CCU)] is very appealing but difficult. Capturing CO2 directly from the atmosphere or any concentrated CO2 source has the potential to provide significant environmental advantages. Aqueous solutions of primary, secondary, and tertiary amines-based materials have been studied for CO2 capture, where carbamates are generated after interacting with CO2. Quaternary ammonium groups containing ionic polymers have shown potential as viable candidates for capturing CO2. The reported polymers have only focused on capturing CO2without any further investigation of utilization of captured-CO2. Very few reports have discussed the conversion of captured CO2. It has mainly generated cyclic carbonates from the cycloaddition between released CO2 and epoxides. However, the unstable chemical properties, limited variety of epoxides, and flammability all limit the industrial use of epoxide substrate.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042

[0008] There remains a need for improved compositions and methods for capturing CO2. There remains a need for valorizing commodity chemicals like lignin. DESCRIPTION OF DRAWINGS

[0009] Figure 1 depicts a conceptual illustration of devolving modified ionic lignin polymers for CO2 capturing and conversion thereof.

[0010] Figure 2 depicts the NMR pulse sequence (zgig30) for inverse-gated proton decoupled13C NMR. The notations are as follows, d1: pre-scan delay; CPD: composite pulse decoupling; I and S: electron spin waveforms.

[0011] Figures 3A-3E depict a reaction scheme for the synthesis of modified ionic lignin polymer (P-1) from glycidyl trimethylammonium chloride (GTAC) and lignin under basic conditions. The hydrolysis side reactions also occurred during the quaternization reaction, which generated some by-products as shown in the scheme (FIG.3A); an FT-IR spectrum of lignin, GTAC, and modified ionic lignin polymer (FIG.3B); a stacked1H NMR spectra of lignin, GTAC and P-1 (FIG.3C); a 2D1H–13C heteronuclear single quantum coherence (HSQC) NMR of raw lignin in before reaction (FIG.3D). The notations (A-α, A-γ, C-γ, D-γ, and GA-α) used for assigning the signals were displayed in FIG.4; a HSQC NMR of modified ionic lignin polymer after quaternization (FIG.3E).

[0012] Figures 4A-4B depict chemical structures of lignin with diverse structural units and linkages.

[0013] Figure 5 depicts physical changes during the synthesis of modified ionic lignin polymer. Lignin: dark brown powder; glycidyl trimethyl ammonium chloride (GTAC): colorless viscous liquid; modified ionic lignin polymer: brown fluffy solid.

[0014] Figures 6A-6C depict a synthesis of CO2-captured ionic lignin polymer (P-2) from concentrated carbon dioxide source or direct air capture (FIG.6A); a13C NMR spectra of epoxy salt (Glycidyl trimethylammonium chloride, GTAC), modified ionic lignin polymer (P-1) and CO2-captured ionic lignin polymer (P-2) (FIG.6B); a proposed mechanism on the moisture driven chemical alterations of quaternary ammonium cation containing lignin polymers with hydroxide, bicarbonate, and carbonate ions (OH-, HCO3-, and CO32-) (FIG. 6C).

[0015] Figure 7 depicts a1H NMR spectrum of CO2-captured modified ionic lignin in D2O.

[0016] Figure 8 depicts a photograph of the sample-loaded NMR tubes of modified ionic lignin polymer (left) and CO2-captured modified ionic lignin polymer (right) in D2O after anAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 overnight13C NMR experiment. The NMR solvent D2O induced the CO2release process in the CO2-captured modified ionic lignin polymer. The CO2gas bubbles are observed as the experiment is conducted for a long time (overnight). The mechanism is discussed in FIG.6C.

[0017] Figure 9 depicts1H (top) and13C (bottom) NMR of 1,3,5-trioxane in D2O at room temperature.1,3,5-trioxane is used as an internal standard in the NMR analysis as it shows one type of proton and carbon signal in the spectra.

[0018] Figures 10A-10B depict an inverse-gated proton decoupled13C NMR (pulse sequence: zgig30, solvent D2O) of CO2-captured modified ionic lignin polymer using concentrated CO2source (FIG.10A); a quantitative13C NMR using inverse-gated proton decoupled method (pulse sequence: zgig30, solvent D2O) of CO2-captured modified ionic lignin from direct air capture (FIG.10B).

[0019] Figure 11 depicts quantitative13C NMR using inverse-gated proton decoupled method (pulse sequence: zgig30, solvent D2O) of CO2-captured modified ionic lignin from direct air capture.

[0020] Figure 12 depicts inverse-gated proton decoupled13C of CO2-captured modified ionic lignin polymer using a concentrated CO2source.

[0021] Figures 13A-13D depict a synthetic scheme of model cyclic carbonate synthesis reaction from 1,3 butanediol using CO2-captured ionic lignin polymer as CO2 source (FIG. 13A); the graphic illustration of the developed reaction set-up, where two round bottom flasks (RB-1 and RB-2) were connected via a needle-attached tubing system. The cyclization reaction occurred in RB-1, whereas the heating of aqueous solution of CO2- captured ionic lignin polymer was performed in RB-2 (FIG.13B);1H NMR of the 1,3 butanediol (starting material) and the synthesized cyclic carbonate compound (FIG.13C);13C NMR of the 1, 3 butanediol and cyclic carbonate compound (FIG.13D).

[0022] Figure 14 depicts a photograph of the reaction set-up for the model cyclization reaction of 1,3-butanediol, where the CO2-captured ionic lignin polymer could be utilized as a source of CO2. Two different round bottom flasks (25 mL: RB-1 and 10 mL: RB-2) were utilized, and both flasks were connected through a manually developed needle-attached tubing system.

[0023] Figures 15A-15C depict stacked13C NMR of modified ionic lignin polymer (P-1), CO2-captured modified ionic lignin polymer (P-2), recycled modified ionic lignin polymer (recycled P-1) and recycled CO2-captured modified ionic lignin polymer (Recycled P-2) in deuterium oxide (D2O) solvent (FIG.15A). Graphic presentation on the recycling process of the modified ionic lignin polymer via continuous CO2 release ↔ CO2 capture (FIG.15B).Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 Thermogravimetric analysis (TGA) of lignin, modified ionic lignin and CO2-captured modified ionic lignin using concentrated CO2source [P-2(CO2)] and direct air capture [P-2(Air)] (FIG. 15C).

[0024] Figure 16 depicts a1H NMR spectrum of modified ionic lignin and recycled modified ionic lignin in D2O at room temperature.

[0025] Figure 17 depicts as-obtained polymers after overnight drying at 100oC in the silicone mold. PHU-P, PHU-B, PHU-X (Aromatic xylene unit) ^ Hard; PHU-H ^ Less hard. PHU-O (C8aliphatic chain and two ether linkage) ^ Soft; PHU-D (C10aliphatic chain and three ether linkage ) ^ Very soft (Sticky).

[0026] Figure 18 depicts a schematic for reprocessing polyhydroxyurethanes.

[0027] Figure 19 depicts an NMR spectrum of a polyhydroxyurethane.

[0028] Figure 20 depicts an NMR spectrum of apolyhydroxyurethane.

[0029] Figure 21 depicts stacked NMR spectra of polyhydroxyurethanes.

[0030] Figure 22 depicts the 2D HSQC NMR of polyhydroxyurethane from lignin-based cyclic carbonate and p-xylylenediamine (PHU-X) of a polyhydroxyurethane.

[0031] Figure 23 depicts an FT-IR spectrum of a polyhydroxyurethane (PHU-TA, PHU- X) and cyclic carbonate monomer.

[0032] Figure 24 depicts FT-IR spectra of PHU-P, PHU-B, PHU-H, PHU-O and PHU-D.

[0033] Figure 25 depicts the molecular weight of polyhydroxyurethanes as measured by GPC.

[0034] Figure 26 depicts a thermogravimetric analysis of polyhydroxyurethanes.

[0035] Figure 27 depicts a derivative thermogravimetry (DTG) of polyhydroxyurethanes.

[0036] Figures 28A-28C depict a differential scanning calorimetry (DSC) of polyhydroxyurethanes.

[0037] Figure 29 depicts the properties of polyhydroxyurethanes. DETAILED DESCRIPTION

[0038] The present invention can be understood more readily by referencing the following detailed description, examples, drawings, and claims, and their previous and following description. However, before the present articles, systems, and / or methods are disclosed and described, it is to be understood that this invention is not limited to the specific or exemplary aspects of articles, systems, and / or methods disclosed unless otherwiseAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 specified, as such can, of course, vary. It is also to be understood that the terminology used herein is for the purpose of describing particular aspects only and is not intended to be limiting.

[0039] Throughout the description and claims of this specification, the word “comprise” and other forms of the word, such as “comprising” and “comprises,” means including but not limited to, and are not intended to exclude, for example, other additives, segments, integers, or steps. Furthermore, it is to be understood that the terms comprise, comprising, and comprises as they relate to various aspects, elements, and features of the disclosed invention also include the more limited aspects of “consisting essentially of” and “consisting of.”

[0040] As used herein, the singular forms “a,” “an,” and “the” include plural referents unless the context clearly dictates otherwise. Thus, for example, reference to a “polymer” includes aspects having two or more such polymers unless the context clearly indicates otherwise.

[0041] Ranges can be expressed herein as from “about” one particular value and / or to “about” another particular value. When such a range is expressed, another aspect includes from the one particular value and / or to the other particular value. Similarly, when values are expressed as approximations, by use of the antecedent “about,” it will be understood that the particular value forms another aspect. It should be further understood that the endpoints of each of the ranges are significant both in relation to the other endpoint and independently of the other endpoint.

[0042] Similarly, when values are expressed as approximations, by use of the antecedent “about,” it will be understood that the particular value forms another aspect. It will be further understood that the endpoints of each of the ranges are significant both in relation to the other endpoint and independently of the other endpoint. Unless stated otherwise, the term “about” means within 5% (e.g., within 2% or 1%) of the particular value modified by the term “about.”

[0043] Values can be expressed herein as an “average” value. “Average” generally refers to the statistical mean value.

[0044] As used herein, the terms “optional” or “optionally” mean that the subsequently described event or circumstance may or may not occur, and that the description includes instances where said event or circumstance occurs and instances where it does not.

[0045] For the terms "for example" and "such as" and grammatical equivalences thereof, the phrase "and without limitation" is understood to follow unless explicitly stated otherwise.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 It is further understood that these phrases are used for explanatory purposes only. It is further understood that the term “exemplary,” as used herein, means “an example of” and is not intended to convey an indication of a preferred or ideal aspect.

[0046] As used herein, the term "substantially" means that the subsequently described event or circumstance completely occurs or that the subsequently described event or circumstance generally, typically, or approximately occurs.

[0047] As used herein, the term “substantially” can, in some aspects, refer to at least about 80%, at least about 85%, at least about 90%, at least about 91%, at least about 92%, at least about 93%, at least about 94%, at least about 95%, at least about 96%, at least about 97%, at least about 98%, at least about 99%, or about 100% of the stated property, segment, composition, or other condition for which substantially is used to characterize or otherwise quantify an amount.

[0048] In other aspects, as used herein, the term “substantially free,” when used in the context of a composition or segment of a composition that is substantially absent, is intended to refer to an amount that is less than about 1 % by weight, e.g., less than about 0.5 % by weight, less than about 0.1 % by weight, less than about 0.05 % by weight, or less than about 0.01 % by weight of the stated material, based on the total weight of the composition.

[0049] As used herein, the terms “substantially identical reference composition,” “substantially identical reference article,” or “substantially identical reference electrochemical cell” refer to a reference composition, article, or electrochemical cell comprising substantially identical components in the absence of an inventive component. In another exemplary aspect, the term "substantially," in, for example, the context "substantially identical reference composition," “substantially identical reference article,” or “substantially identical reference electrochemical cell,” refers to a reference composition, article, or an electrochemical cell comprising substantially identical components and wherein an inventive component is substituted with a common in the art component.

[0050] The term “or combinations thereof” as used herein refers to all permutations and combinations of the listed items preceding the term. For example, “A, B, C, or combinations thereof” is intended to include at least one of A, B, C, AB, AC, BC, or ABC, and if the order is important in a particular context, also BA, CA, CB, CBA, BCA, ACB, BAC, or CAB. Continuing with this example, expressly included are combinations that contain repeats of one or more items or terms, such as BB, AAA, AB, BBC, AAABCCCC, CBBAAA, CABABB, and so forth. The skilled artisan will understand that, typically, there is no limit on the number of items or terms in any combination unless otherwise apparent from the context.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042

[0051] References in the specification and concluding claims to parts by weight of a particular element or component in a composition or article, denotes the weight relationship between the element or component and any other elements or components in the composition or article for which a part by weight is expressed. Thus, in a composition or a selected portion of a composition containing 2 parts by weight of component X and 5 parts by weight component Y, X, and Y are present at a weight ratio of 2:5 and are present in such ratio regardless of whether additional components are contained in the composition.

[0052] Throughout this disclosure, various aspects of the invention can be presented in a range format. It should be understood that the description in range format is merely for convenience and brevity and should not be construed as an inflexible limitation on the scope of the invention. Accordingly, the description of a range should be considered to have specifically disclosed all the possible subranges as well as individual numerical values within that range. For example, a description of a range such as from 1 to 6 should be considered to have specifically disclosed subranges such as from 1 to 3, from 1 to 4, from 1 to 5, from 2 to 4, from 2 to 6, from 3 to 6, etc., as well as individual numbers within that range, for example, 1, 2, 2.7, 3, 4, 5, 5.3, 6 and any whole and partial increments therebetween. This applies regardless of the breadth of the range. It is further understood that if individual numbers within the range are disclosed, also disclosed are ranges formed by these individual numbers. For example, if the ranges, such as 1 to 3, from 1 to 4, from 1 to 5, from 2 to 4, from 2 to 6, from 3 to 6, etc., are disclosed as well as individual numbers within that range, for example, 1, 2, 2.7, 3, 4, 5, 5.3, 6 are disclosed, then additional subranges such as 1 to 2.7 or 2 to 5.3, and so on are also disclosed.

[0053] It is understood that the term “between,” when used in the context of ranges, includes the bordering values of the range. For example, a range described as being between 10 and 15 includes both 10 and 15 unless described otherwise.

[0054] In still further aspects, when the specific values are disclosed between two end values, it is understood that these end values can also be included. For example, if individual values of 1, 2, 3, 4, 5, 6, 7, etc. are disclosed, the ranges of 1 to 7, 1 to 6, 1 to 5, 1 to 4, 2 to 7, 3 to 7, and so on are also disclosed.

[0055] In still further aspects, when the range is given, and exemplary values are provided, it is understood that any ranges can be formed between any exemplary values within the broadest range.

[0056] As used herein, the term “composition” is intended to encompass a product comprising the specified ingredients in the specified amounts, as well as any product thatAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 results, directly or indirectly, from a combination of the specified ingredients in the specified amounts.

[0057] A weight percent of a segment, unless specifically stated to the contrary, is based on the total weight of the formulation or composition in which the segment is included.

[0058] It will be understood that when an element is referred to as being "connected" or "coupled" to another element, it can be directly connected or coupled to the other element, or intervening elements may be present. In contrast, when an element is referred to as being "directly connected" or "directly coupled" to another element, there are no intervening elements present. Other words used to describe the relationship between elements or layers should be interpreted in a like fashion (e.g., "between" versus "directly between," "adjacent" versus "directly adjacent," "on" versus "directly on").

[0059] As used herein, the term "and / or" includes any and all combinations of one or more of the associated listed items.

[0060] It will be understood that the terms "first," "second," etc., may be used herein to describe various elements, components, regions, layers, and / or sections. These elements, components, regions, layers, and / or sections should not be limited by these terms. These terms are only used to distinguish one element, component, region, layer, or section from another element, component, region, layer, or section. Thus, a first element, component, region, layer, or section discussed below could be termed a second element, component, region, layer, or section without departing from the teachings of example embodiments.

[0061] As used herein, the term or phrase “effective,” “effective amount,” or “conditions effective to” refers to such amount or condition that is capable of performing the function or property for which an effective amount or condition is expressed. As will be pointed out below, the exact amount or particular condition required will vary from one aspect to another, depending on recognized variables such as the materials employed and the processing conditions observed. Thus, it is not always possible to specify an exact “effective amount” or “condition effective to.” However, it should be understood that an appropriate, effective amount will be readily determined by one of ordinary skill in the art using only routine experimentation.

[0062] As used herein, the term “biodegradable” refers to a material capable of being decomposed by bacteria or other living microorganisms.

[0063] As used herein, the term “chemically degradable” refers to a material capable of being easily decomposed under chemical conditions.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042

[0064] As used herein, “Kraft lignin” refers to a lignin product of the sulfate pulping process. It is understood that Kraft lignin can comprise about 2-3 wt% of sulfur based on the total weight of the Kraft lignin.

[0065] As used herein, the terms “modified” and “functionalized” can be used interchangeably.

[0066] As used herein, the term “substituted” means that a hydrogen atom is removed and replaced by a substituent. It is contemplated to include all permissible substituents of organic compounds. As used herein, the phrase "optionally substituted" means unsubstituted or substituted. It is to be understood that substitution at a given atom is limited by valency. In a broad aspect, the permissible substituents include acyclic and cyclic, branched and unbranched, carbocyclic and heterocyclic, and aromatic and nonaromatic substituents of organic compounds. Illustrative substituents include, for example, those described below. The permissible substituents can be one or more and the same or different for appropriate organic compounds. For purposes of this disclosure, the heteroatoms, such as nitrogen, can have hydrogen substituents and / or any permissible substituents of organic compounds described herein that satisfy the valencies of the heteroatoms. This disclosure is not intended to be limited in any manner by the permissible substituents of organic compounds. Also, the terms “substitution” or “substituted with” include the implicit proviso that such substitution is in accordance with the permitted valence of the substituted atom and the substituent and that the substitution results in a stable compound, e.g., a compound that does not spontaneously undergo transformation such as by rearrangement, cyclization, elimination, etc. In still further aspects, it is understood that when the disclosure describes a group being substituted, it means that the group is substituted with one or more (i.e., 1, 2, 3, 4, or 5) groups as allowed by valence selected from alkyl, halogenated alkyl, alkoxy, alkenyl, alkynyl, aryl, heteroaryl, aldehyde, amino, carboxylic acid, ester, ether, halide, hydroxy, ketone, nitro, silyl, sulfo-oxo, sulfonyl, sulfone, sulfoxide, or thiol.

[0067] The term "compound," as used herein, is meant to include all stereoisomers, geometric isomers, tautomers, and isotopes of the structures depicted. Compounds herein identified by name or structure as one particular tautomeric form are intended to include other tautomeric forms unless otherwise specified.

[0068] Compounds provided herein can also include tautomeric forms. Tautomeric forms result from the swapping of a single bond with an adjacent double bond together with the concomitant migration of a proton. Tautomeric forms include prototropic tautomers, which are isomeric protonation states having the same empirical formula and total charge. Example prototropic tautomers include ketone - enol pairs, amide - imidic acid pairs, lactam -Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 lactim pairs, enamine - imine pairs, and annular forms where a proton can occupy two or more positions of a heterocyclic system, for example, 1H- and 3H-imidazole, 1H-, 2H- and 4H-1,2,4-triazole, 1H- and 2H- isoindole, and 1H- and 2H-pyrazole. Tautomeric forms can be in equilibrium or sterically locked into one form by appropriate substitution.

[0069] Also provided herein are salts of the compounds described herein. It is understood that the disclosed salts can refer to derivatives of the disclosed compounds wherein the parent compound is modified by converting an existing acid or base moiety to its salt form. Examples of the salts include, but are not limited to, mineral or organic acid salts of basic residues such as amines; alkali or organic salts of acidic residues such as carboxylic acids; and the like. The salts of the compounds provided herein include the conventional non-toxic salts of the parent compound formed, for example, from non-toxic inorganic or organic acids. The salts of the compounds provided herein can be synthesized from the parent compound that contains a basic or acidic moiety by conventional chemical methods. Generally, such salts can be prepared by reacting the free acid or base forms of these compounds with a stoichiometric amount of the appropriate base or acid in water or an organic solvent or in a mixture of the two. In various aspects, nonaqueous media like ether, ethyl acetate, alcohols (e.g., methanol, ethanol, isopropanol, or butanol), or acetonitrile (ACN) can be used.

[0070] In various aspects, the compounds provided herein, or salts thereof, are substantially isolated. By "substantially isolated," it meant that the compound is at least partially or substantially separated from the environment in which it was formed or detected. Partial separation can include, for example, a composition enriched in the compounds provided herein. Substantial separation can include compositions containing at least about 50%, at least about 60%, at least about 70%, at least about 80%, at least about 90%, at least about 95%, at least about 97%, or at least about 99% by weight of the compounds provided herein, or salt thereof. Methods for isolating compounds and their salts are routine in the art.

[0071] As used herein, chemical structures that contain one or more stereocenters depicted with dashed and bold bonds are meant to indicate the absolute stereochemistry of the stereocenter(s) present in the chemical structure. As used herein, bonds symbolized by a simple line do not indicate a stereo-preference. Unless otherwise indicated to the contrary, chemical structures, which include one or more stereocenters, illustrated herein without indicating absolute or relative stereochemistry encompass all possible stereoisomeric forms of the compound (e.g., diastereomers and enantiomers) and mixtures thereof. Structures with a single bold or dashed line and at least one additional simple line encompass a single enantiomeric series of all possible diastereomers.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042

[0072] The expressions "ambient temperature" and "room temperature" as used herein are understood in the art and refer generally to a temperature, e.g., a reaction temperature, which is about the temperature of the room in which the reaction is conducted, for example, a temperature from about 20 °C to about 35 °C.

[0001] As used herein, the term “aliphatic group” refers to any carbon-containing substituent, including heteroatoms within the group. The current definition of aliphatic group includes, but not limited to, alkyl and heteroalkyl groups, alkenyl and heteroalkenyl groups, alkynyl and heteroalkenyl groups, cyclic and heterocyclic groups, aryl and heteroalkyl groups. In aspects where the aliphatic group comprises heteroatoms, such an aliphatic group can comprise at least one heteroatom in the chain, for example, an amine, carbonyl, carboxy, oxo, thio, phosphate, phosphonate, nitrogen, phosphorus, silicon, or boron atoms in place of a carbon atom. In certain aspects, the only heteroatom is nitrogen. In certain aspects, the only heteroatom is oxygen. In certain aspects, the only heteroatom is sulfur. In certain aspects, the aliphatic groups comprising one or more heteroatoms can be optionally substituted in a manner that results in the formation of a stable moiety. Nonlimiting examples of the aliphatic groups comprising one or more heteroatoms are polyethylene glycol, polyalkylene glycol, amide, polyamide, polylactide, polyglycolide, thioether, and ether, alkyl- heterocycle-alkyl, -O-alkyl-O-alkyl, alkyl-O-haloalkyl, etc.

[0073] The terms for various functional groups as used herein are not intended to be limited to monovalent radicals and may include polyvalent radical groups as appropriate, such as divalent, trivalent, tetravalent, pentavalent, and hexavalent groups, and the like, based on the position and location of such groups in the compounds described herein as would be readily understood by the skilled person.

[0074] A dash ("-") that is not between two letters or symbols is used to indicate a point of attachment for a substituent. For example, -(C=O)NH2 is attached through the carbon of the keto (C=O) group.

[0002] As used herein, the term "Cn-Cmalkyl" (or “Cn-m”) employed alone or in combination with other terms refers to a saturated hydrocarbon group that may be straight- chain or branched, having n to m carbons. It is understood that the terms Cn-m and Cn-Cm can be used interchangeably and just to show that the specific compound has between n to m carbons. Unless otherwise specified, C1-C24 (e.g., C1-C22, C1-C20, C1-C18, C1-C16, C1-C14, C1-C12, C1-C10, C1-C8, C1-C6, or C1-C4) alkyl groups are intended. Examples of alkyl moieties include, but are not limited to, chemical groups such as methyl, ethyl, n-propyl, isopropyl, n- butyl, tert-butyl, isobutyl, sec-butyl; higher homologs such as 2-methyl-l-butyl, n-pentyl, 3- pentyl, n-hexyl, 1,2,2-trimethylpropyl, heptyl, octyl, nonyl, decyl, dodecyl, tetradecyl,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 hexadecyl, eicosyl, tetracosyl, and the like. The alkyl group can also be substituted or unsubstituted. Throughout the specification, “alkyl” is generally used to refer to both unsubstituted alkyl groups and substituted alkyl groups; however, substituted alkyl groups are also specifically referred to herein by identifying the specific substituent(s) on the alkyl group. The alkyl group can be substituted with one or more groups including, but not limited to, alkyl, halogenated alkyl, alkoxy, alkenyl, alkynyl, aryl, heteroaryl, aldehyde, amino, carboxylic acid, ester, ether, halide, hydroxy, ketone, nitro, silyl, sulfo-oxo, sulfonyl, sulfone, sulfoxide, or thiol, as described below, provided that the substituents are sterically compatible and the rules of chemical bonding and strain energy are satisfied. It is further understood that throughout the specification, “alkyl” can also be referred to as a linking group of saturated hydrocarbons that are divalent radicals. In other words, in a broader description, the term “alkyls” also encompasses alkylenes. It is further understood that the term “alkyl” covers saturated hydrocarbons that are multivalent radicals. Throughout the specification, “alkyl” is generally used to refer to both unsubstituted alkyl groups and substituted alkyl groups; however, substituted alkyl groups are also specifically referred to herein by identifying the specific substituent(s) on the alkyl group.

[0075] The term "heteroalkyl" refers to an alkyl group, which further includes at least one heteroatom (e.g., 1, 2, 3, or 4 heteroatoms) selected from oxygen, nitrogen, or sulfur within (i.e., inserted between adjacent carbon atoms of) and / or placed at one or more terminal position(s) of the parent chain. By way of example, a heteroC1-6alkyl (which may also be designated a C1-6heteroalkyl) group includes, but is not limited to, the following structures:

[0076] As used herein, the term “heterocyclyl” refers to a non-aromatic unsaturated or saturated cyclic hydrocarbon that includes at least one heteroatom in the cycle. For example, the term "heterocyclyl" or "heterocyclic" refers to a radical of a 3- to 14-membered non-aromatic ring system having ring carbon atoms and 1 to 4-ring heteroatoms, wherein each heteroatom is independently selected from nitrogen, oxygen, and sulfur ("3-14 membered heterocyclyl").

[0077] The term "aryl" refers to a radical of a monocyclic or polycyclic (e.g., bicyclic or tricyclic) 4n+2 aromatic ring system (e.g., having 6, 10, or 14 π electrons shared in a cyclic array) having 6-14 ring carbon atoms and zero heteroatoms provided in the aromatic ringAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 system ("C6-14aryl"). It is understood that compounds such as biphenyls and azobenzenes can be generally described as aryls.

[0078] The term "heteroaryl" refers to a radical of a 5-14 membered monocyclic or polycyclic (e.g., bicyclic, tricyclic) 4n+2 aromatic ring system (e.g., having 6, 10, or 14 π electrons shared in a cyclic array) having ring carbon atoms and 1-4 ring heteroatoms provided in the aromatic ring system, wherein each heteroatom is independently selected from nitrogen, oxygen, and sulfur ("5-14 membered heteroaryl").

[0079] When used in the context of nitrogen-containing heteocyclic and heteroaryl rings, an “N-alkyl derivative” refers to instances when one or more of the ring nitrogen atoms is substituted by one or two alkyl groups permitted by valence. For instance, an N-alkyl derivative of piperidine include N-methyl piperidine and N,N-dimethyl piperidine. The skilled person understands which systems can accommodate dialkylation and which cannot. Unless specified to the contrary, the alkyl groups in an N-alkyl derivative can be a C1-4alkyl group.

[0080] In general, the inclusion of the prefix “alk” in front of a substituent name indicates there is an alkyl group (as defined herein) connecting the named substituent with the rest of the compound. For example, "alkaryl" (which is a subset of alkyl) refers to an alkyl group substituted by an aryl group, wherein the point of attachment is on the alkyl moiety and "alkheteroaryl" (which is a subset of "alkyl") refers to an alkyl group substituted by a heteroaryl group, wherein the point of attachment is on the alkyl moiety. The number of carbon atoms may be specified in the alkyl chain, the named substituent, or both. For example, C1-2alkC6aryl refers to a phenyl ring (which may be substituted) connected via a 1- 2 carbon alkylene group.

[0081] Affixing the suffix "-ene" to a group indicates the group is a polyvalent moiety, e.g., bonded to two or more groups. Alkylene is the polyvalent moiety of alkyl, alkenylene is the divalent moiety of alkenyl, alkynylene is the divalent moiety of alkynyl, heteroalkylene is the divalent moiety of heteroalkyl, heteroalkenylene is the divalent moiety of heteroalkenyl, heteroalkynylene is the divalent moiety of heteroalkynyl, carbocyclylene is the divalent moiety of carbocyclyl, heterocyclylene is the divalent moiety of heterocyclyl, arylene is the divalent moiety of aryl, and heteroarylene is the divalent moiety of heteroaryl.

[0082] As used herein, the designation of a polyvalent moiety without specifying the specific order of attachment is intended to cover all possible arrangements. By way of example, a compound that is represented by the formula: A-X-B,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 wherein X is NHC(=O) embraces both: .

[0083] As used herein, aeither a single, double, ortriple bond, valency permitting. By way of example, ;

[0084] The termZ1C(O)OC(O)Z2, where Z1and Z2, independently, can be an alkyl, alkenyl, alkynyl, aryl, heteroaryl, cycloalkyl, cycloalkenyl, heterocycloalkyl, or heterocycloalkenyl group described above.

[0085] The term “cyclic anhydride,” as used herein, is represented by the formula:Z1can be an alkyl, alkenyl, alkynyl, aryl, heteroaryl, cycloalkyl, cycloalkenyl, heterocycloalkyl, or heterocycloalkenyl group described above.

[0086] The term “epoxy” or “epoxide” as used herein refers to a cyclic ether with a three- atom ring and can be represented by the formula: where Z1, Z2, Z3, and Z4can be, independently, H, an alkyl, alkenyl, alkynyl, aryl, heteroaryl, cycloalkyl, cycloalkenyl, heterocycloalkyl, or heterocycloalkenyl group described above.

[0087] The term “halide,” or “halogen,” or “halo,” as used herein, refers to fluorine, chlorine, bromine, and iodine.

[0088] As used herein, the term “thio” refers to a group of formulas -SH.

[0089] As used herein, the term “Cn-Cmalkylthio” refers to a group of formula -S-alkyl, wherein the alkyl group has n to m carbon atoms. In various aspects, the alkyl group has 1 to 6, 1 to 4, or 1 to 3 carbon atoms.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 COMPOSITIONS AND METHODS

[0090] Native lignin is the second most abundant natural polymer on Earth. It is an irregular heterogeneous polymer. The chemical structure of lignin mainly consists of syringyl (S), guaiacyl (G), and p-hydroxyphenyl (H) aromatic units, which are connected through several carbon-oxygen chemical linkages (β-O-4, α-O-4) and carbon-carbon (β-5, β-β). Certainly, the abundant aromatic structure in lignin enables it to be highly promising and feasible to yield high-value chemicals.

[0091] Exemplary lignin structures and moieties are shown in Figure 4.

[0092] Lignin C9-units can contain different functional groups. The most common functional groups are aromatic methoxyl and phenolic hydroxyl, primary and secondary aliphatic hydroxyls, small amounts of carbonyl groups (of the aldehyde and ketone types), and carboxyl groups. The monomeric C9 lignin units are linked together to form the polymeric structure of lignin via C-O-C and C-C linkages. The most abundant lignin inter-unit linkage is the β-O-4 type of linkage. They constitute about 50% of the inter-unit linkages in lignin (about 45% in softwoods and up to 60-65% in hardwoods). Other common lignin inter- unit linkages are the resinol (β-β), phenylcoumaran (β-5), 5-5, and 4-O-5 moieties. Their number varies in different lignins but typically does not exceed 10% of the total lignin moieties. The number of other lignin moieties is usually below 5%.

[0093] The degree of lignin condensation (“DC”) is an important lignin characteristic, as it is often negatively correlated with lignin reactivity. Most commonly, condensed lignin structures are lignin moieties linked to other lignin units via the 2, 5, or 6 positions of the aromatic ring (in H-units also via the C-3 position). The most common condensed structures are 5-5’, β-5, and 4-O-5’ structures. Since the C-5 position of the syringyl aromatic ring is occupied by a methoxyl group, and therefore, it cannot be involved in condensation, hardwood lignins are typically less condensed than softwood lignins.

[0094] Technical lignins are obtained as a result of lignocellulosic biomass processing. Technical lignins are more heterogeneous (in terms of chemical structure and molecular mass) than native lignins. Technical lignins can have a higher amount of phenolic hydroxyls than native lignin and have a smaller molecular weight. Technical lignins can have a smaller amount of aliphatic hydroxyls, oxygenated aliphatic moieties, and the formation of carboxyl groups and saturated aliphatic structures. The actual structure of technical lignins also depends on the specific biomass processing (acidic vs. basic, and the like).

[0095] Lignins suitable for the disclosed processes include those having the following structures:Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 , or O, and Ar1and2Ar are independently an aromatic ring in a lignin structural moiety. When Ar1and Ar2are lignin structural moieties, as shown in Figure 4B, such as any of moieties 1-30, in some implementations, the lignin is one of moieties 2, 3, 4, 9, 10, 15, 16, 17, 18, or 20. When Ar1and Ar2are lignin structural moieties, as shown in Figure 4B, the dashed line indicates a point of attachment to the fragment above. The skilled person understands that other undefined substituents may be selected from H, CH3, or another lignin structural moiety. By way of example, one such fragment that has been observed has the formula: , wherein “lignin” represents onepropane units as described above. Unless specifically stated to the contrary, the use of an exemplary lignin fragment such as shown above is not intended to limit the disclosed processes, monomers, and polymers to the specifically depicted substitution pattern.

[0096] The large abundance of lignin makes it a unique material to be used as a source of other biodegradable polymers. It is understood that the present disclosure is not limited to any specific types of lignin. In certain aspects, the lignin used in the current disclosure can be obtained from natural lignin products or synthetic model lignin compounds. In still further aspects, lignin used in the current disclosure can be obtained from natural lignin products. It is understood that the natural lignin product can comprise softwood lignin, hardwood lignin, or a combination thereof. In certain aspects and without limitations, the natural lignin product can be obtained from agricultural residues (including corn stover and sugarcane bagasse), (2) dedicated energy crops, (3) wood residues (including sawmill and paper mill discards), and (4) municipal waste, and their constituent parts. In still further aspects, the natural lignin product can be obtained from the paper industry. In certain aspects, lignin used herein can comprise Kraft lignin and lignosulfonate. In certain implementations, the lignin can have a weight average molecular weight (Mw) from 10,000-25,000 g / mol, 25,000-50,000 g / mol, 10,000-50,000 g / mol, 1,000-10,000 g / mol, from 1,000-5,000 g / mol, from 1,000-2,000 g / mol,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 from 1,000-3,000 g / mol, from 1,000-4,000 g / mol, from 2,000-5,000 g / mol, from 2,000-4,000 g / mol, from 2,000-3,000 g / mol, from 3,000-5,000 g / mol, or from 4,000-5,000 g / mol. In certain implementations, the lignin can have a number average molecular weight (Mn) from 500-2,000 g / mol, from 500-1,000 g / mol, from 500-750 g / mol, from 750-1,000 g / mol, from 1,000-1,250 g / mol, from 1,000-1,500 g / mol, from 1,250-1,750 g / mol, from 1,250-1,500 g / mol, from 1,500-2,000 g / mol, from 1,500-1,750 g / mol, or from 1,750-2,000 g / mol. In certain implementations, the lignin can have polydispersity index (PDI Mw / Mn) from 1-5, from 2-5, from 3-5, from 4-5, from 1-1.5, from 1.5-2 from 1-2, from 1-3, from 1-4, from 2-5, from 2-4, from 2-3, from 2-2.5, from 2.5-3, from 3-5, from 3-4, from 3-3.5, from 3.5-4, from 4-4.5, from 4.5-5, or from 4-5. In certain implementations, the molecular weights can be determined using HPLC. In some implementations, the molecular weights can be determined using GPC. IONIC-LIGNIN POLYMER

[0097] Lignin polymer is structurally modified in the presence of glycidyltrimethylammonium chloride under aqueous sodium hydroxide solution by incorporating quaternary ammonium groups with hydroxide counter ions. Subsequently, the modified ionic lignin polymer is utilized for capturing CO2 from direct air and concentrated CO2 sources, wherein the hydroxide ions react with CO2, yielding bicarbonate. The structures of the developed polymers are confirmed using Fourier-transform infrared (FT-IR),1H,13C, and1H-13C heteronuclear single quantum coherence (HSQC) NMR. The quantitative analysis of captured-CO2is conducted using inverse-gated proton decoupled13C NMR (Figure 2). Afterward, the CO2-captured modified ionic lignin polymer is utilized as a CO2 source, facilitating a successful model reaction to synthesize cyclic carbonate from 1,3- butanediol in a newly designed reaction setup. Lastly, the effective recycling of modified ionic lignin polymer is also accomplished during the cyclization reaction under controlled heating in aqueous solution via controllable CO2release ↔ CO2capture.

[0098] Disclosed herein is a polymeric material comprising one or more fragments of Formula I: .Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 O C Nwith one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl- )(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; wherein when X is null, R1is not null, or wherein R1is null, X is not null; wherein two of R2, R3,and R4may together form a 5 or 6-membered ring, or wherein R2and R3, each and on each occasion, independent of the other, are selected from C1-C40 aliphatic group, wherein R4is selected from C1-C40 aliphatic group or lignin, and wherein each of R2, R3, and R4is independently and optionally substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl- )(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl- )(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

[0099] In still further aspects, R1can be a C1-C40 aliphatic group selected from C1-C20 alkylene, C1-C20alkenylene, C1-C6alkynylene, -(C0-10alkylene)(C6-C14aryl), or -(C0-10alkyl- ene)( aryl-N=N-aryl group) , wherein squiggly line 1 is a connection to X,is a connection to N+, wherein R1is optionally substituted one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), - (C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

[0100] In some exemplary and unlimiting aspects, the polymeric material disclosed herein can comprise one or more fragments of formula (II)Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 OH OH , wherein is -H,

[0101] While in other aspects, the polymeric material disclosed herein can comprise one or more fragments of formula (III) ,

[0102] In some aspects, disclosed herein is a polymeric material containing one or more fragments of Formula IV:Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 [Formula (IV)], wherein:Z is independently P or N; X is independently: orrepresents the point of attachment to R1; X1is null, S, O, NH, or a 1,2,3,-triazole; x is 0-8; L is a C0-10aliphatic group, for example null, C1-10alkylene, or C1-10heteroalkylene; R1is selected from null or C1-C10aliphatic group, wherein R1is optionally substituted with one or more of C1-10 alkyl, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)COOH, -(C0-10 alkyl)N(C1-4alkyl)3, or -(C0-10 alkyl)-OH; at least one of X and R1is not null; any two or more of R1, R2, R3,and R4may together form a ring, R2, R3, and R4are in each case independently selected from C1-C10aliphatic group, each of R1, R2, R3, and R4is independently and optionally substituted with one or more of a lignin fragment, C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl- )(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), -(C0-10alkyl)COOH, -(C0-10alkyl)N(C1-4alkyl)3, or -(C0-10alkyl)-OH; wherein when Z is a sp2hybridized nitrogen, then R4is optionally null.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042

[0103] In some implementations of Formula (IV), R1, R2, and R3together form a heteroaryl or heterocyclic ring, for example having the formula: .

[0104] The heteroaryls, when R4is null the depicted ring will be electrically neutral, whereas when R4is not null, the depicted ring will bear a cationic charge.

[0105] In some implementations of Formula (IV), R1, R2, and R3together form a heteroaryl or heterocyclic ring, wherein said ring is further substituted by C1-10 alkyl, C1-10 alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl- )(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl- )(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), -(C0-10alkyl)COOH, -(C0-10alkyl- )N(C1-4alkyl)3,or -(C0-10alkyl)-OH. In some implementations said heteroaryl group can be an N-alkyl pyridinum hydroxide, e.g.,

[0106] In someand / or R4together form a heterocyclic ring system, for example having the formula: ,

[0107] In further implementations of Formula (IV), Z is P and each of R2, R3, and R4are C1-10 alkyl, optionally two or more of R2, R3, and R4together forming a ring. In some implementations, Z is P and each of R2, R3, and R4are methyl, ethyl, n-propyl, isopropyl, n- butyl, isobutyl, n-pentyl, or n-hexyl. In some implementations, Z is P and R2and R3are methyl and R4is ethyl, n-propyl, isopropyl, n-butyl, isobutyl, n-pentyl, or n-hexyl. In someAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 implementations Z is P and R2, R3, and R4are the same, for example R2, R3, and R4are each methyl, ethyl, or n-propyl.

[0108] In some implementations X is: , wherein x is 2 or 3, and X1is SX is 1,2,3-triazole, e.g., the product of a click-chemistry cycloaddition: wherein x is 1, 2,

[0109] In some implementations of Formula (IV), R4can be C1-10aliphatic-lignin. In some implementations of Formula (IV) R4can have the formula C1-10aliphatic-L*, wherein L* has the formula: ,represents the point of attachment to the R1Lgroup X1Lis null, S, O, NH, or a 1,2,3,-triazole; x* is 0-8; LLis a C0-10aliphatic group, e.g. null, C1-10alkylene, or C1-10heteroalkylene; R1Lis selected from null or C1-C10aliphatic group, wherein R1Lis optionally substituted with one or more of C1-10 alkyl, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)COOH, -(C0-10alkyl)N(C1-4alkyl)3, or -(C0-10alkyl)-OH; at least one of XLand R1Lis not null; any two or more of R1L, R2L, and R3Lmay together form a ring, R2Land R3Lare in each case independently selected from C1-C10 aliphatic group, each of R1L, R2L, and R3Lis independently and optionally substituted with one or more of a lignin fragment, C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl- )(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), -(C0- 10 alkyl)COOH, -(C0-10 alkyl)N(C1-4alkyl)3, or -(C0-10 alkyl)-OH; wherein when ZLis a sp2hybridized nitrogen, then R3Lis optionally null.

[0110] In some aspects, disclosed herein is a polymeric material containing one or more fragments of Formula V: [Formula (V)] wherein:Z is N or P; X is: X is independently: ,wherein wavy line 1 represents the point of attachment to lignin, and wavy line 2 represents the point of attachment to R1; in certain preferred implementations X is: X1is null, S, O, NH, or a 1,2,3,-x is 0-8;Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 L is a C0-10aliphatic group, for example null, C1-10alkylene, or C1-10heteroalkylene; R1is selected from null or C1-C10 aliphatic group, wherein R1is optionally substituted with one or more of C1-10 alkyl, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)COOH, -(C0-10alkyl)N(C1-4alkyl)3, or -(C0-10alkyl)-OH; at least one of X and R1is not null; any two or more of R1, R2, R3,and R4may together form a ring, R2, R3, and R4are in each case independently selected from C1-C10 aliphatic group, each of R1, R2, R3, and R4is independently and optionally substituted with one or more of a lignin fragment, C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl- )(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), -(C0-10 alkyl)COOH, -(C0-10 alkyl)N(C1-4alkyl)3, or -(C0-10 alkyl)-OH; wherein when Z is a sp2hybridized nitrogen, then R4is optionally null.

[0111] In some implementations of Formula (V), R1, R2, and R3together form a heteroaryl or heterocyclic ring, for example having the formula: .

[0112] Thewhen R4is null the depicted ring will be electrically neutral, whereas when R4is not null, the depicted ring will bear a cationic charge.

[0113] In some implementations of Formula (V), R1, R2, and R3together form a heteroaryl or heterocyclic ring, wherein said ring is further substituted by C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl- )(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl- )(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), -(C0-10 alkyl)COOH, -(C0-10 alkyl- )N(C1-4alkyl)3,or -(C0-10 alkyl)-OH. In some implementations said heteroaryl group can be an N-alkyl pyridinum hydroxide, e.g.,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042

[0114] In some implementations of Formula (V), R1, R2, R3, and / or R4together form a heterocyclic ring system, for example having the formula: ,

[0115] In further implementations of Formula (V), Z is P and each of R2, R3, and R4are C1-10 alkyl, optionally two or more of R2, R3, and R4together forming a ring. In some implementations, Z is P and each of R2, R3, and R4are methyl, ethyl, n-propyl, isopropyl, n- butyl, isobutyl, n-pentyl, or n-hexyl. In some implementations, Z is P and R2and R3are methyl and R4is ethyl, n-propyl, isopropyl, n-butyl, isobutyl, n-pentyl, or n-hexyl. In some implementations Z is P and R2, R3, and R4are the same, for example R2, R3, and R4are each methyl, ethyl, or n-propyl.

[0116] In some implementations of Formula (V) X is: , wherein x is 2 or 3, and X1is Sof Formula (V), X is 1,2,3-triazole, e.g., the product of a click-chemistry cycloaddition: wherein x is 1, 2,

[0117] In some implementations of Formula (V), R4can be C1-10aliphatic-lignin. In some implementations R4can have the formula C1-10aliphatic-L*, wherein L* has the formula: , XLis independently:Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 ,represents to group X1Lis null, S, O, NH, or a 1,2,3,-triazole; x* is 0-8; LLis a C0-10aliphatic group, e.g. null, C1-10alkylene, or C1-10heteroalkylene; R1Lis selected from null or C1-C10 aliphatic group, wherein R1Lis optionally substituted with one or more of C1-10 alkyl, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)COOH, -(C0-10alkyl)N(C1-4alkyl)3, or -(C0-10alkyl)-OH; at least one of XLand R1Lis not null; any two or more of R1L, R2L, and R3Lmay together form a ring, R2Land R3Lare in each case independently selected from C1-C10 aliphatic group, each of R1L, R2L, and R3Lis independently and optionally substituted with one or more of a lignin fragment, C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl- )(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), -(C0- 10 alkyl)COOH, -(C0-10 alkyl)N(C1-4alkyl)3, or -(C0-10 alkyl)-OH; wherein when ZLis a sp2hybridized nitrogen, then R3Lis optionally null.

[0118] In the aspects disclosed herein, the polymeric material is a carbon dioxide- capturing material. The polymeric material disclosed herein can capture the carbon dioxide from any gas stream. In certain aspects, the gas stream comprising carbon dioxide can be a waste gas from manufacturing, automotive vehicles emissions, emissions from the electric grid, pure carbon dioxide stream, carbon monoxide, nitrous oxide, sulfur dioxide, ozone, a stream of chlorofluorocarbon gases, or any combination thereof.

[0119] In still further aspects, it is understood that the carbon dioxide captured by the polymer material disclosed herein can be reversible. In such aspects, the captured carbonAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 dioxide can be released by the polymer material. In certain aspects, the release of carbon dioxide by the polymeric material does not substantially change the composition of the properties of the polymeric material itself. In yet other aspects, the composition and / or properties of the polymeric material can be changed upon release of the captured carbon dioxide.

[0120] In still further aspects, the polymeric material is recyclable. In this context, the term recyclable means that the polymeric material can be reused to capture carbon dioxide after previously captured carbon dioxide is released. In certain aspects, the polymeric material disclosed herein can be used as a storage device for carbon dioxide.

[0121] It is also understood that in certain aspects, the polymeric material can be recycled to form other materials if needed.

[0122] Also disclosed herein are articles comprising the polymeric materials disclosed herein. In still further aspects, the article can be any article that can be used to capture carbon dioxide if needed. In certain aspects, the article is a film, a filter, or membrane, an absorbent, or any combination thereof. In still further aspects, the articles can be recycled for continuous use of carbon dioxide from the gas stream.

[0123] Also disclosed herein is a method comprising reacting lignin-containing material with a nitrogen-containing material to form a polymeric material comprising one or more fragments of formula (I) (I) wherein X is selected from,substituted with one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl- )(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; wherein when X is null, R1is not null, or wherein R1is null, X is not null; wherein two of R2, R3,and R4may together form a 5 or 6-Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 membered ring, or wherein R2and R3, each and on each occasion, independent of the other, are selected from C1-C40aliphatic group, wherein R4is selected from C1-C40aliphatic group or lignin, and wherein each of R2, R3, and R4is independently and optionally substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl- )(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

[0124] In such methods, R1can also be a C1-C40 aliphatic group selected from C1-C20 alkylene, C1-C20 alkenylene, C1-C6 alkynylene, -(C0-10 alkylene)(C6-C14 aryl), or -(C0-10 alkyl- ene)( aryl-N=N-aryl group) , wherein squiggly line 1 is a connection to X, and is a connection to N+, wherei1n R is optionally substituted one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), - (C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

[0125] Any of the polymeric materials disclosed above can be formed. For example, and without limitations, the polymeric material of formula (II) or formula (III) can be formed.

[0126] In still further aspects, the disclosed methods comprise the nitrogen-containing material having a formula , wherein Y is a counter ion that isand wherein X* is selected from wherein R4*is an C1-C40

[0127] In yet still further aspects, the nitrogen-containing material is selected fromAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 orshown below in Figure 3A.

[0129] An exemplary route of forming the one or more fragments of formula (III) is shown below.

[0130] Also disclosed herein are methods of making a lignin material including one or more fragments having the formula (V): , wherein X, R1, R2, R3, and R4(V). by reacting a lignin containing material with a compound having the formula: , wherein x* is 0-8,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 RLGis a leaving group, e.g., a halide like Cl, Br, or I, or a sulfonate like OMs or Ots, and Ruis CH=CH2, C≡CH, or N3. to provide an activated lignin-containing material having the formula: and reacting the activated lignin-containing material with a compound having the formula (Q): [Formula (Q)], wherein: Ψ is an anion other than hydroxide, when Ruis CH=CH2 the Rpis SH; when Ruis C≡CH, the Rpis N3; and when Ruis N3, the Rpis C≡CH;and subjecting the lignin-containing material to ion exchange conditions to replace Ψ with hydroxide (e.g., treat with sodium hydroxide).

[0131] In other implementations Ψ is hydroxide.

[0132] In further implentations the activated lignin is combined with aqeuous hydroxide (e.g., aqueous sodium hydroxide) and reacted with the compound of Formula (Q).

[0133] Also disclosed are lignin materials produced by said process.

[0134] The polymeric material formed by the disclosed methods can be any of the polymeric materials disclosed above. In such aspects, the polymeric material can be a carbon dioxide-capturing material. In further aspects, the polymeric material can release, under the desired conditions, captured carbon dioxide to return to its initial state and can be reused for the following capturing process.

[0135] In still further aspects, the method can further comprise forming an article from the polymeric material. Such articles can comprise a film, a textile, a filter, a membrane, an absorbent, or any combination thereof.

[0136] Also disclosed herein is a method of capturing a carbon dioxide comprising exposing an article comprising any of the disclosed herein polymeric materials to a gasAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 stream comprising the carbon dioxide; and reacting the polymeric material with the carbon dioxide to form a compound comprising one or more fragments of formula (VI), [Formula (VI)],O ,substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; wherein when X is null, R1is not null, or wherein R1is null, X is not null; wherein two of R2, R3,and R4may together form a 5 or 6-membered ring, or wherein R2, and R3, each and on each occasion, independent of the other, are selected from C1-C40 aliphatic group, wherein R4is selected from C1-C40 aliphatic group or lignin, and wherein each of R2, R3, and R4is independently and optionally substituted with one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl- )(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy, thereby removing the carbon dioxide from the gas stream.

[0137] In still further aspects of Formula (VI), the R1can be a C1-C40aliphatic group selected from C1-C20alkylene, C1-C20alkenylene, C1-C6alkynylene, -(C0-10alkylene)(C6- C14aryl), or -(C0-10alkylene)( aryl-N=N-aryl group), , wherein squiggly line 1 is a connection to X, and squiggly line 2 is a connection towherein R1is optionally substituted one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042

[0138] An exemplary route of capturing carbon dioxide is shown in Figure 6A.

[0139] Also disclosed herein is a method of capturing a carbon dioxide comprising exposing an article comprising any of the disclosed herein polymeric materials to a gas stream comprising the carbon dioxide; and reacting the polymeric material with the carbon dioxide to form a compound comprising one or more fragments of formula (VII), [Formula (VII)] wherein: Z is independently P or N; X is independently: orrepresents the point of attachment to R1; X1is null, S, O, NH, or a 1,2,3,-triazole; x is 0-8; L is a C0-10aliphatic group, for example null, C1-10alkylene, or C1-10heteroalkylene R1is selected from null or C1-C10 aliphatic group, wherein R1is optionally substituted with one or more of C1-10 alkyl, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)COOH, -(C0-10 alkyl)N(C1-4alkyl)3, or -(C0-10 alkyl)-OH; at least one of X and R1is not null; any two or more of R1, R2, R3,and R4may together form a ring, R2, R3, and R4are in each case independently selected from C1-C10aliphatic group, each of R1, R2, R3, and R4is independently and optionally substituted with one or more of a lignin fragment, C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl-Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 )(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), -(C0-10 alkyl)COOH, -(C0-10 alkyl)N(C1-4alkyl)3, or -(C0-10 alkyl)-OH; wherein when Z is a sp2hybridized nitrogen, then R4is optionally null.

[0140] In some implementations of Formula (VII), R1, R2, and R3together form a heteroaryl or heterocyclic ring, for example having the formula: .

[0141] The heteroaryls, when4R is null the depicted ring will be electrically neutral, whereas when R4is not null, the depicted ring will bear a cationic charge.

[0142] In some implementations of Formula (VII), R1, R2, and R3together form a heteroaryl or heterocyclic ring, wherein said ring is further substituted by C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl- )(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl- )(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), -(C0-10 alkyl)COOH, -(C0-10 alkyl- )N(C1-4alkyl)3,or -(C0-10 alkyl)-OH. In some implementations said heteroaryl group can be an N-alkyl pyridinum bicarbonate, e.g.,

[0143] In some, and / or R4together form a heterocyclic ring system, for example having the formula: ,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042

[0144] In further implementations of Formula (VII), Z is P and each of R2, R3, and R4are C1-10alkyl, optionally two or more of R2, R3, and R4together forming a ring. In some implementations, Z is P and each of R2, R3, and R4are methyl, ethyl, n-propyl, isopropyl, n- butyl, isobutyl, n-pentyl, or n-hexyl. In some implementations, Z is P and R2and R3are methyl and R4is ethyl, n-propyl, isopropyl, n-butyl, isobutyl, n-pentyl, or n-hexyl. In some implementations Z is P and R2, R3, and R4are the same, for example R2, R3, and R4are each methyl, ethyl, or n-propyl.

[0145] In some implementations of Formula (VII) X is: , wherein x is 2 or 3, and X1is Sof Formula (VII), X is 1,2,3- triazole, e.g., the product of a click-chemistry cycloaddition: wherein x is 1, 2,

[0146] In some implementations of Formula (VII), R4can be C1-10aliphatic-lignin. In some implementations of Formula (VII) R4can have the formula C1-10aliphatic-L*, wherein L* has the formula: ,represents the point of attachment to the R1Lgroup X1Lis null, S, O, NH, or a 1,2,3,-triazole;Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 x* is 0-8; LLis a C0-10aliphatic group, e.g. null, C1-10alkylene, or C1-10heteroalkylene; R1Lis selected from null or C1-C10aliphatic group, wherein R1Lis optionally substituted with one or more of C1-10alkyl, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)COOH, -(C0-10 alkyl)N(C1-4alkyl)3, or -(C0-10 alkyl)-OH; at least one of XLand R1Lis not null; any two or more of R1L, R2L, and R3Lmay together form a ring, R2Land R3Lare in each case independently selected from C1-C10 aliphatic group, each of R1L, R2L, and R3Lis independently and optionally substituted with one or more of a lignin fragment, C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl- )(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), -(C0-10alkyl)COOH, -(C0-10alkyl)N(C1-4alkyl)3, or -(C0-10alkyl)-OH; wherein when ZLis a sp2hybridized nitrogen, then R3Lis optionally null.

[0147] Also disclosed herein is a method of capturing a carbon dioxide comprising exposing an article comprising any of the disclosed herein polymeric materials to a gas stream comprising the carbon dioxide; and reacting the polymeric material with the carbon dioxide to form a compound comprising one or more fragments of formula (VIII), [Formula (VIII)] wherein:Z is N or P; X is: X is independently: ,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 wherein wavy line 1 represents the point of attachment to lignin, and wavy line 2 represents the point of attachment to R1; in certain preferred implementations X is: X1is null, S, O, NH, or a 1,2,3,-x is 0-8; L is a C0-10aliphatic group, for example null, C1-10alkylene, or C1-10heteroalkylene R1is selected from null or C1-C10 aliphatic group, wherein R1is optionally substituted with one or more of C1-10 alkyl, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl),-(C0-10alkyl)COOH, -(C0-10alkyl)N(C1-4alkyl)3, or -(C0-10alkyl)-OH; at least one of X and R1is not null; any two or more of R1, R2, R3,and R4may together form a ring, R2, R3, and R4are in each case independently selected from C1-C10 aliphatic group, each of R1, R2, R3, and R4is independently and optionally substituted with one or more of a lignin fragment, C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl- )(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), -(C0-10 alkyl)COOH, -(C0-10 alkyl)N(C1-4alkyl)3, or -(C0-10 alkyl)-OH; wherein when Z is a sp2hybridized nitrogen, then R4is optionally null.

[0148] In some implementations of Formula (VIII), R1, R2, and R3together form a heteroaryl or heterocyclic ring, for example having the formula: .

[0149] Theheteroaryls, when R4is null the depicted ring will be electrically neutral, whereas when R4is not null, the depicted ring will bear a cationic charge.

[0150] In some implementations of Formula (VIII), R1, R2, and R3together form a heteroaryl or heterocyclic ring, wherein said ring is further substituted by C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl- )(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl- )(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), -(C0-10 alkyl)COOH, -(C0-10 alkyl-Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 )N(C1-4alkyl)3,or -(C0-10alkyl)-OH. In some implementations said heteroaryl group can be an N-alkyl pyridinum bicarbonate, e.g.,

[0151] In some4and / or R together form a heterocyclic ring system, for example having the formula: ,

[0152] In further implementations of Formula (VIII), Z is P and each of R2, R3, and R4are C1-10 alkyl, optionally two or more of R2, R3, and R4together forming a ring. In some implementations, Z is P and each of R2, R3, and R4are methyl, ethyl, n-propyl, isopropyl, n- butyl, isobutyl, n-pentyl, or n-hexyl. In some implementations, Z is P and R2and R3are methyl and R4is ethyl, n-propyl, isopropyl, n-butyl, isobutyl, n-pentyl, or n-hexyl. In some implementations Z is P and R2, R3, and R4are the same, for example R2, R3, and R4are each methyl, ethyl, or n-propyl.

[0153] In some implementations of Formula (VIII) X is: , wherein x is 2 or 3, and X1is Sof Formula (VIII), X is 1,2,3- triazole, e.g., the product of a click-chemistry cycloaddition:wherein x is 1, 2,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042

[0154] In some implementations of Formula (VIII), R4can be C1-10aliphatic-lignin. In some implementations R4can have the formula C1-10aliphatic-L*, wherein L* has the formula: , XLis independently: ,represents the point of attachment to the R1Lgroup X1Lis null, S, O, NH, or a 1,2,3,-triazole; x* is 0-8; LLis a C0-10aliphatic group, e.g. null, C1-10alkylene, or C1-10heteroalkylene; R1Lis selected from null or C1-C10 aliphatic group, wherein R1Lis optionally substituted with one or more of C1-10 alkyl, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)COOH, -(C0-10alkyl)N(C1-4alkyl)3, or -(C0-10alkyl)-OH; at least one of XLand R1Lis not null; any two or more of R1L, R2L, and R3Lmay together form a ring, R2Land R3Lare in each case independently selected from C1-C10 aliphatic group, each of R1L, R2L, and R3Lis independently and optionally substituted with one or more of a lignin fragment, C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl- )(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), -(C0- 10 alkyl)COOH, -(C0-10 alkyl)N(C1-4alkyl)3, or -(C0-10 alkyl)-OH; wherein when ZLis a sp2hybridized nitrogen, then R3Lis optionally null.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042

[0155] In still further aspects, the method of capturing the carbon dioxide is reversible, such that the captured carbon dioxide is released.

[0156] In still further aspects also disclosed are methods utilizing carbon dioxide- lignin based polymer to form other chemical compounds.

[0157] In one aspect, disclosed herein is a method comprising: a) providing a polymer composition comprising one or more fragments of formula (IX) [Formula (IX)] wherein X is selectedO ,substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl- )(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; wherein when X is null, R1is not null, or wherein R1is null, X is not null; wherein two of R2, R3,and R4may together form a 5 or 6- membered ring, or wherein R2and R3, each and on each occasion, independent of the other, are selected from C1-C40aliphatic group, wherein R4is selected from C1-C40aliphatic group or lignin, and wherein each of R2, R3, and R4is independently and optionally substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl- )(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; b) releasing carbon dioxide from the polymer composition; and c) utilizing the released carbon dioxide to form a compound comprising a cyclic carbonate.

[0158] In still further aspects of Formula (IX), in the disclosed methods, R1is selected from null, C1-C20 alkylene, C1-C20 alkenylene, C1-C6 alkynylene, -(C0-10 alkylene)(C6-C14 aryl), or -(C0-10alkylene)( aryl-N=N-aryl ,wherein squiggly line 1 is a connection line 2 is a connection to N+,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 wherein R1is optionally substituted one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, - (C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl- )(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

[0159] In still further aspects, the polymer compositions used in the disclosed methods can comprise one or more fragments of the formula: , wherein is -H,

[0160] In still further aspects, the polymer compositions used in the disclosed methods can comprise one or more fragments of the formula:Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 wherein is a null

[0161] Exemplary route for forming polycarbonate is disclosed in detail below and shown in Figures 13A-13B.

[0162] In one aspect, disclosed herein is a method comprising: a) providing a polymer composition comprising one or more fragments of formula (VII) b) releasing carbon dioxide from the polymer composition; and c) utilizing the released carbon dioxide to form a compound comprising a cyclic carbonate

[0163] In one aspect, disclosed herein is a method comprising: a) providing a polymer composition comprising one or more fragments of formula (VIII) b) releasing carbon dioxide from the polymer composition; and c) utilizing the released carbon dioxide to form a compound comprising a cyclic carbonate. LIGNIN-BASED POLYURETHANE

[0164] Also disclosed is a method comprising: reacting a lignin-based macromonomer of formula (X) with a polyamine to form a polyhydroxyurethane (PHU) having a fragment of formula (XI)Attorney Docket No.10850-103WO1 FSU Ref. No.24-042with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

[0165] The skilled person appreciates that while the connectivity for the carbamate groups may be as depicted above for Formula (XI), other positional isomers are also possible, e.g.:Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 .are within the ambit of Formula (XI).

[0167] In still further aspects, the the polyamine can be an aromatic diamine, an aliphatic diamine, an ether linkage-based aliphatic diamine, a triamine, or a combination thereof.

[0168] For example, and without limitations, the polyamine can be selected from , , , ,the carbon dioxide is conducted at atmospheric pressure. In yet other aspects, the reaction of lignin- containing material with the carbon dioxide is conducted at a temperature of 0 °C to room temperature, for example, 0 °C to 5 °C, 0 °C to 10 °C, or 0 °C to 15 °C, or 0 °C to 20 °C, or 0 °C to 30 °C, or 0 °C to 35 °C, or at any temperatures in between.

[0170] In still further aspects, the polyhydroxyurethane formed by the disclosed methods is chemically degradable. For example, it can be chemically degraded in basic conditions.

[0171] Yet in still further aspects, the method disclosed herein comprises a step wherein the lignin-based macromonomer (X) is formed by reacting a lignin-based material (e.g., of Formula (I), (IV) or (V)) having one or more OH groups with a carbon dioxide.

[0172] An exemplary route for forming the disclosed herein polyhydroxyurethane (PHU) is shown below.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042formed by any of the disclosed methods herein. In such aspects, disclosed is a polyhydroxyurethane having a formula:. O Osubstituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy. In still further aspects, the polyhydroxyurethane polymerAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 disclosed herein is recyclable. In this context, the recyclable refers to the formation of new materials at the end of the life of the disclosed polymer.

[0174] Also disclosed is an article formed from the polyhydroxyurethane polymer. In still further aspects, the articles formed herein can be used in the fields of medicine, bioengineering electronics, textiles, containers, furniture, automotive, military equipment, coatings, appliances, films, and the like. In certain aspects, the articles prepared from the disclosed biodegradable lignin-based polymers can also comprise packaging, food packaging, disposable cutlery, tableware, film, bags, nets, as membranes in any desired application, for example, for ion exchange and selective gas / liquid separation applications, or any combination thereof.

[0175] In still further aspects, disclosed are methods of making the articles, wherein the methods can comprise a step of extrusion, compression molding, injection molding, transfer molding, blow molding, or any combination thereof. EXAMPLES Example 1

[0176] p-Toluenesulfonyl chloride, lignin (softwood kraft lignin, L0045), and 1,3- butanediol were brought from TCI America. Glycidyltrimethylammonium chloride (GTAC), 2,2,6,6-tetramethylpiperidine (TMP), and sodium hydroxide were obtained from MilliporeSigma. The remaining chemicals were purchased from MilliporeSigma and TCI America and utilized without undergoing additional purification. The procurement of carbon dioxide (UN1013) was carried out from Airgas. The conventional Schlenk line (vacuum manifold) was connected to the carbon dioxide cylinder, and balloons loaded with CO2 were used to purge the gas into the reactions. The deionized water was obtained from the PURELAB®Quest water system (ELGA LabWater). The regenerated cellulose dialysis tubing (Repligen Spectra / Por 6, 3.5 kD, 54 mm) from Spectrum Laboratories (CA, USA) was used to purify the synthesized products. 2. Instrumentations and characterization

[0177] The1H,13C, and two-dimensional heteronuclear single quantum coherence (HSQC) experiments were performed to characterize the chemical structures of the monomers and polymers. The modified ionic lignin polymer and CO2-captured ionic lignin polymer were dissolved in D2O at room temperature. Additionally, the DMSO-d6 was used as an NMR solvent for 1,3-butanediol and synthesized cyclic carbonate from the model reaction. NMR experiments were carried out in Bruker Avance 600 MHz and 500 MHz spectrometers. The chemical shifts of the1H and13C NMR spectra were determined withAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 respect to the solvent peaks D2O (4.7 ppm in1H NMR) and DMSO (2.5 ppm in1H NMR and 39.5 ppm in13C NMR). MestreNova (Mestrelab Research) software was used to process the NMR data. The acquisition parameters for recording the1H NMR,13C NMR, and HSQC NMR spectra are elaborated as follows:

[0178] For1H NMR, temperature: 298.0; pulse sequence: zg30; number of scans: 16; receiver gain: 32.0; relaxation delay: 1.00; pulse width: 8.00; acquisition time: 3.2768; spectrometer frequency: 499.86; spectral width: 10000.0; acquired size: 32768; spectral size: 65536; digital resolution: 0.15.

[0179] For13C NMR, temperature: 298.0; pulse sequence: zgpg30; number of scans: 12500-14000; receiver gain: 128.0; relaxation delay: 2.0; pulse width: 12.0; acquisition time: 1.1010; spectrometer frequency: 125.70; spectral width: 36231.9; acquired size: 32768; spectral size: 65536; digital resolution: 0.45.

[0180] For HSQC (F2×F1) NMR, temperature: 298.1; pulse sequence: hsqcgpph; number of scans: 4; receiver gain: 203.0; relaxation delay: 1.50; pulse width: 15.0; acquisition time: 0.0532; spectrometer frequency: (600.13, 150.91); spectral width: (9615.4, 24875.6); nucleus: (1H,13C); acquired size: (512, 256); spectral size: (512, 512); digital resolution: (18.78, 48.59).

[0181] The inverse-gated proton decoupled13C NMR was utilized to quantify the captured CO2 from the bicarbonate ion (HCO3-), which generated a peak at ≈ 160 ppm. Trioxane was used as an internal standard. The detailed procedures are discussed in the method section. The acquisition parameters are elaborated as follows: solvent: D2O; temperature: 298.0; pulse sequence: zgig30; number of scans: 12500; receiver gain: 203.0; relaxation delay: 2.0; pulse width: 10.0; acquisition time: 0.9044; spectrometer frequency: 150.92; spectral width: 36231.9; acquired size: 32768; spectral size: 65536; digital resolution: 0.55.

[0182] JASCO 6800 FT-IR Spectrometer was utilized to acquire the Fourier-transform infrared spectroscopy (FT-IR) spectra. Forty scans were carried out in the range of 250 – 6000 cm-1at a resolution of 4 cm-1for every experiment using an ATR Pro One accessory with an incident angle of 45°. The freeze-dried modified lignin polymer was used for this experiment.

[0183] Thermogravimetric analysis (TGA) was used to assess the synthetic polymers' thermal stability. TA Instruments' simultaneous thermal analyzer (SDT, Model: Q600) was used for the TGA studies. Samples were heated to 600 °C at a rate of 10 °C min-1while an argon gas flow of 100 mL min-1was maintained. Td5%is the polymers' 5% weight lossAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 temperature. Derivative thermogravimetric (DTG) study also provided comprehensive details on the sequential degradation of polymers. 3. Calculation regarding the quantitative analysis of solubilized CO2 by inverse gated proton decoupled13C NMR 3.1. CO2 capturing from direct air

[0184] Internal standard: 1,3,5-trioxane (Molecular weight 90.08 g mol-1).1M stock solution was prepared in deuterium oxide (D2O). Sample preparation: 20 mg of modified ionic lignin polymer and 50 µL trioxane (1 M) were taken in an NMR tube. D2O is used as an NMR solvent. Integration values from NMR: three carbon atoms from trioxane at 93.48 ppm (3); HCO3- peak at 160.20 ppm (0.18); CO2 peak at 124.68 ppm (0.06).50 µL trioxane (1 M) = 0.05 mmol. Amount of HCO3- : (0.05 × 0.18) mmol = 0.009 mmol. Hence, 0.020 gram of modified ionic lignin contained 0.009 mmol HCO3- .So, 1 gram of modified ionic lignin contained (0.009 / 0.020) mmol = 0.45 mmol HCO3-. Amount of CO2: (0.05 × 0.06) mmol = 0.003 mmol. So, 1 gram of modified ionic lignin contained (0.003 / 0.020) mmol CO2= 0.15 mmol CO2. Total captured CO2amount from direct air was = (0.45 + 0.15) = 0.60 mmol gram-1. 3.2. CO2 capturing from concentrated CO2 source

[0185] Sample preparation: 25 mg of modified ionic lignin polymer and 89 µL trioxane (1 M) were taken in an NMR tube. D2O is used as an NMR solvent. Integration values from NMR: three carbon atoms from trioxane at 93.46 ppm (3); HCO3- peak at 160.19 ppm (0.15); CO2 peak at 124.67 ppm (0.15).89 µL trioxane (1 M) = 0.089 mmol. Amount of HCO3- : (0.089 × 0.15) mmol = 0.0133 mmol. Hence, 0.025 gram of modified ionic lignin contained 0.01335 mmol HCO3- .So, 1 gram of modified ionic lignin contained (0.01335 / 0.025) mmol = 0.53 mmol HCO3-. Amount of CO2: (0.089 × 0.15) mmol = 0.0133 mmol. So, 1 gram of modified ionic lignin contained (0.01335 / 0.025) mmol CO2= 0.53 mmol CO2. Total captured CO2 amount from concentrated CO2 source was = (0.534 + 0.534) = 1.06 mmol gram-1. Example 2 Synthesis of modified ionic lignin polymer (P-1)

[0186] Five grams of lignin was dissolved in a freshly prepared 50 mL aqueous solution of 0.5 M sodium hydroxide (NaOH). After getting the homogeneous aqueous lignin solution, glycidyl trimethyl ammonium chloride, GTAC (3.4 mL, 22.5 mmol) was gradually added under constant stirring. Then, the reaction mixture was purged with continuous nitrogen flow and placed under an oil bath. Subsequently, the temperature of the oil bath was raised to 65 °C and stirred for 5 hours. Later, the reaction mixture was cooled down to the roomAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 temperature. Thereafter, the reaction was carried out overnight at room temperature. Following completion, the mixture was transferred to the dialysis membrane tube with a molecular weight cut-off of 3.5 kDa. The dialysis was performed in deionized water for 72 hours, where the water was changed after different intervals. Finally, a dark brown fluffy solid product was obtained after freeze-drying the lignin reaction mixture. The yield of the reaction was 76% (weight) with respect to the lignin. Process for synthesizing CO2-captured ionic lignin polymer (P-2)

[0187] CO2-captured ionic lignin polymer (P-2) was prepared through the CO2 sorption process of the modified ionic lignin polymer (P-1). It demonstrated excellent water solubility. Deuterium oxide (D2O) is therefore used in the CO2capturing process as a solvent. Initially, 50 mg of modified ionic lignin polymer was placed in a pressure relief cap-containing vial, and 1 mL of D2O was added to solubilize the modified ionic lignin polymer. Afterward, a CO2 gas-filled balloon was introduced to bubble the gas into the ionic lignin solution at 25 °C for 15 minutes. Subsequently, the obtained solution was transferred to a clean NMR tube for the NMR analysis. Specifically, the new peak after CO2 capturing would be clearly visible in the13C NMR spectrum.

[0188] The direct extraction of CO2 from the air (direct air capture, DAC) experiment was performed to evaluate the efficiency of the developed polymer for reducing CO2 emissions. The solid-modified ionic lignin polymer sample was placed in a vial and kept open in a normal atmosphere (CO2: 0.04%) for 45 days at room temperature. Then, the sample solution in D2O was bubbled with continuous air for 1 hour to ensure the capture procedure. Lastly, the sample was used for NMR analysis. Analysis of solubilized CO2 by inverse gated proton decoupled13C NMR

[0189] The captured CO2into the modified ionic lignin polymer was experimentally quantified by the inverse-gated proton decoupled13C NMR method. The quantitation was accomplished using an internal standard. It is vital to emphasize that the internal standard with clear, sharp, and un-overlapped signals in the13C NMR spectra was selected cautiously.1,3,5-Trioxane was selected as the internal standard by evaluating all the previously discussed points. Initially, a stock solution of 1 M trioxane was prepared in D2O. In the case of the direct CO2capturing process, 25 mg of modified ionic lignin polymer was dissolved in 0.5 mL of D2O, and CO2gas was bubbled for 15 minutes. Later, the solution was transferred to an NMR tube (outer diameter: 5 mm and length: 7 inches). Then, 1 M trioxane solution (89 µL) was added to the NMR tube. Finally, the inverse-gated proton decoupled13C NMR (pulse sequence: zgig30) was performed by overnight scanningAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 (number of scans: 12500) under a spectrometer frequency of 150.92 MHz and a digital resolution of 0.55.

[0190] For the CO2 capturing via direct air capture, a 20 mg modified ionic lignin polymer, after keeping under direct air exposure for 45 days, was dissolved in 0.5 mL of D2O. Later, the atmospheric air was bubbled for 1 hour, and the solution was transferred to an NMR tube, where 50 µL of trioxane (1 M in D2O) was added to it. The inverse-gated proton decoupled13C NMR was performed by following previous experimental protocols.

[0191] The quantifications of the solubilized CO2 were calculated from the integral values of the peaks of the bicarbonate ion (HCO3-, ≈ 160.2 ppm) and trapped CO2(≈ 124.7 ppm) with reference to the trioxane peak at 93.46 ppm in13C NMR spectra. General procedure cyclic carbonate synthesis using captured CO2 as a source

[0192] The cyclic carbonate synthesis model reaction was performed to investigate if the CO2-captured ionic lignin polymer could be utilized as a source of CO2 for the reaction. A novel and unique reaction set-up was designed to execute this reaction. Two different round bottom flasks (25 mL: RB-1 and 10 mL: RB-2) were utilized, and both flasks were connected through a manually developed needle-attached tubing system.1,3-Butanediol (0.4 g, 0.4 mL, 4.5 mmol), tosylchloride (0.85 g, 4.5 mmol, 1 equivalent) were mixed homogeneously with 15 mL acetonitrile in the 25 mL round bottom flask (RB-1). Then, the closed rection setup was purged with argon gas flow for 15 minutes. Simultaneously, 1.5 grams of CO2-captured ionic lignin polymer (P-2) was dissolved with 4.5 mL deionized water (3 mL gram-1) was taken in the 10 mL flask (RB-2) and placed under an oil bath. At that time, a needle-attached tubing system was connected between the RB-1 and RB-2. Then, the temperature of the oil bath of RB-2 increased to 60 °C. This heating initiated the CO2 release from the P-2 in RB-2, and CO2 gas flowed towards the RB-1. As a result, continuous CO2 gas bubbles were observed in RB-1, and this purging was carried out to make the reaction mixture CO2saturated. Afterward, the reaction mixture of RB-1 cooled down to 0 °C, and 2,2,6,6- tetramethylpiperidine (TMP, 1.5 mL, 9.0 mmol, 2 equivalent) was added dropwise in RB-1 under continuous CO2 flow. Thereafter, the ice bath was removed from RB-1 and allowed to rise to room temperature while stirring. The CO2 flow (i.e., heating in RB-2) continued until bright white precipitation was observed in RB-1. Later the heating of RB-2 was then turned off after the detachment of the tubing system from the two flasks. The reaction mixture in RB-1 was stirred for an additional 6 hours. Later, three times centrifugation for 5 minutes at 4400 rpm followed by filtration was executed to separate the liquid phase. The solvent was eliminated under vacuum and the crude product was purified using column chromatographyAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 followed by recrystallizing in toluene at room temperature. Finally, the cyclic carbonate product is obtained in 49% yield (0.25 g). 4.5. Recycling of modified ionic lignin polymer via controllable CO2 release ↔ CO2 capture

[0193] The recycling experiment was carried out with the recovered aqueous solution of the CO2-captured ionic lignin polymer (P-2) after the model cyclic carbonate synthesis reaction. As the solution heated continuously at 60 °C, the captured CO2 was released during the reaction. The recycled modified ionic lignin polymer was obtained by freeze-drying the aqueous solution. The CO2capturing procedure was repeated to ensure that the recovered product functioned effectively. The chemical structures were confirmed by the NMR studies. Example 3 2.1. Synthesis and characterization of modified ionic lignin polymer

[0194] The chemical transformation of biomass lignin into a valuable product with excellent water solubility involves a unique and environmental-friendly strategy for large- scale applications. In this current research work, a synthetically modified ionic lignin polymer is designed for CO2 capturing and utilization applications. For that purpose, a modified ionic lignin polymer (P-1) was prepared via quaternization using glycidyl trimethylammonium chloride (GTAC), GTAC as shown in Figure 3a. Commercially available lignin (product number: L0045, TCI America), with a total hydroxyl group amount was 4.48 mmol g-1(Figure 4), was used in this example. The key steps involved in the synthesis of P-1 (Figure 3a) were solubilization of lignin in 0.5 M NaOH aqueous solution, cationization of lignin with GTAC at 65 °C for 5 hours followed by an overnight stirring at room temperature, purification by dialysis in water medium for 72 hours, and freeze-drying of the purified product (Figure 5).

[0195] The reaction conditions (reaction time, temperature, ratios, and concentration of NaOH) were selected to ensure the minimal formation of side products. Both the aromatic and aliphatic hydroxy groups of lignin generated nucleophilic hydroxide intermediates in the presence of the alkaline pH condition. However, the phenolic groups of lignin had a greater tendency for the quaternization reaction than the aliphatic hydroxyl groups because of superior equilibrium between the acidity and nucleophilicity of phenolates. The in-situ hydroxide intermediates participated in the nucleophilic attack on the GTAC and formed the quaternary ammonium functionalized lignin. Moreover, it is worth noting that the quaternization process produced several side products despite adjusting the reactionAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 conditions (Figure 3a). The side products by the hydrolysis of GTAC had low molecular weight and were water-soluble. As a result, dialysis (molecular weight cut off: 3.5 kDa) was able to easily eliminate the unreacted GTAC and other side products.

[0196] The preliminary structural analysis was done using the Fourier-transform infrared spectroscopy (FT-IR) by comparing the unmodified lignin and modified lignin (Figure 3b). In contrast to the raw lignin, a broad and intense absorption band was observed in the range of 3600–3200 cm-1due to the O–H stretching of the hydroxyl groups and trapped moisture. The absorption bands at 1481 and 975 cm-1were assigned to the methyl (–CH3) and methylene (–CH2) groups connected to the nitrogen atom of the quaternary ammonium groups (Figure 3b). Moreover, the stretching vibration of the C–O bond of the ether linkages generated an absorption band at 930 cm-1. Afterwards,1H NMR spectroscopy was utilized to confirm the chemical structure of the synthesized product. Figure 3c shows the NMR spectra of lignin (in DMSO-d6), GTAC (in D2O), and synthesized product (in D2O). The intense peaks at 3.05– 3.15 ppm in Figure 3c appeared from the three methyl groups (–CH3) of the quaternary ammonium moieties. The peaks corresponded to the protons from lignin's methoxy groups (–OCH3) observed in the 3.25 - 4.15 ppm region (Figure 3c), along with the other characteristic proton signals from the GTAC unit. This suggested the successful covalent attachment of quaternary ammonium units to the polymeric structure of lignin. In addition, the 2D1H–13C heteronuclear single quantum coherence (HSQC) NMR was performed and compared with the lignin spectrum (Figures 3d and e). The HSQC spectrum of lignin in Figure 3d displayed the existence of a large amount of aliphatic hydroxyl groups. The signals related to the α, β, and γ types of hydroxyl groups were observed in the region of δH / δC: 3.2-4.5 ppm / 58–80 ppm. The signal at δH / δC: 3.78 ppm / 56 ppm appeared from the methoxy group of the lignin units. The details about different structural units of lignin are provided in Figure 4 of supporting information. Figure 3e represents the HSQC spectrum of the modified ionic lignin polymer. The typical hydroxyl groups’ signals of lignin disappeared after the quaternization reaction with GTAC. This clear consumption of the aliphatic hydroxyl groups provided direct proof of their participation in the reaction. The intense signals of the methyl groups from GTAC and methoxy groups from lignin supported the successful integration of these two systems. The signals of the methylene groups (–CH2–) connected to the quaternary ammonium group (noted as 3 in Figure 3e) and next to the oxygen atom (noted as 1 in Figure 3e) were noticed at δH / δC: 4.18 ppm / 66.40 ppm and δH / δC: 3.34 ppm / 68.36 ppm, respectively. Notably, a new hydroxyl group was formed during the ring opening of the epoxy unit, and that signal appeared at δH / δC: 3.51 ppm / 63.60 ppm in Figure 3e. Therefore, after analyzing all the experimental outcomes, it can be stated that theAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 quaternary ammonium units were effectively connected via a covalent bond to the polymeric structure of lignin. 2.2. CO2-capturing of modified ionic lignin polymer

[0197] The method of capturing CO2is extremely difficult and usually needs ionic systems with basic and hygroscopic anions (for example, hydroxide, imidazole, and acetate), which convert the captured CO2 into bicarbonates (HCO3-).Moreover, recent findings indicated that polyionic materials had the potential for capturing CO2 from concentrated sources as well as directly from the atmosphere, presenting a potentially sustainable solution to mitigate carbon emissions.

[0198] The primary hypothesis for this current work was that the hydroxide ions of the modified ionic lignin polymer (P-1) would undergo a chemical transformation to its bicarbonate form by capturing CO2. To validate this hypothesis, the CO2 capturing process of P-1 samples was investigated using both the concentrated CO2source and direct air exposure (Figure 6a). Subsequently, the13C NMR technique was utilized to monitor the bicarbonate formation. A sharp peak around 160-161 ppm signified the emergence of a new species. Consistent with prior studies, this peak was attributed to the HCO3- group. The deuterium oxide was used as the NMR solvent for this study.

[0199] Figure 6b shows the stacked13C NMR spectra of the CO2-captured ionic lignin polymer (P-2), modified ionic lignin polymer (P-1), and epoxy salt (GTAC). The peaks of the methoxy groups (–OCH3) from the lignin unit and methyl groups (–CH3) from the quaternary ammonium groups overlapped within 52-55 ppm (P-2 and P-1, Figure 6b;1H NMR showed in Figure 74). Moreover, the effective ring opening of the epoxide units during quaternization was confirmed from the signals of methylene (–CH2–) and –CH(OH)– groups in the range of 61-66 ppm. Thus, it can be said that the overall polymer backbone of the modified ionic lignin polymer was intact after the CO2-capturing process. The noteworthy difference after the CO2capturing was the appearance of an intense peak at 160.2 ppm in the NMR spectrum of CO2-captured ionic lignin polymer (Figure 6b), which indicated the formation of the bicarbonate (HCO3-) ion. It can be stated that the CO2 underwent chemisorption onto the sorbent via a reaction with hydroxide, resulting in the formation of a saturated bicarbonate sorbent.

[0200] This reaction, facilitated by the strong affinity between CO2and hydroxides, occurred not only in concentrated CO2 conditions but also under the exposure of direct air. Significantly, a peak for CO2 was observed at 124.7 ppm in the NMR spectrum of CO2- captured ionic lignin polymer (Figure 6b). This specified the internal release of CO2 from the bicarbonate salt (P-2). It was noted that the NMR experiment was performed throughAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 overnight scanning (number of scans: 13000) in D2O solvent, which had a significant role in generating the in-situ CO2. The CO2gas bubbles were also observed in the NMR tube, as shown in Figure 8, after the overnight scanning. To explain this phenomenon, a schematic mechanism was presented in Figure 6c, which illustrated the moisture-driven changes for quaternary ammonium cation containing lignin polymer having hydroxide, bicarbonate, and carbonate ions (OH-, HCO3-, and CO32-).

[0201] The proposed mechanism in Figure 6c was developed by following several prior literatures. Initially, the hydroxide ion-containing modified ionic lignin polymer (P-1) was kept dry (Step 1, Figure 6c). Then, after exposing the P-1 to a CO2 environment (direct air or concentrated CO2), the substantial affinity of CO2 initiated its reaction with the hydroxide ion, resulting in a sorbent saturated with bicarbonate ion (Step 2, Figure 6c). The introduction of moisture and heating resulted in the dissociation of bicarbonates and released CO2from the solution. As per the earlier literature, the surface became saturated with water-stabilized carbonates. Finally, the hydrated modified ionic lignin polymer returned to the initial step-1 under heating due to destabilization of the carbonate and bicarbonate ions (Step 3, Figure 6c). 2.3. Quantification of captured CO2

[0202] After confirming the CO2-capturing ability of the modified ionic polymer, it became imperative to quantify the captured CO2. The most significant peaks to track the capturing process were the13C NMR (Figure 6b, CO2-captured ionic lignin polymer) peaks located at 161 ppm for the bicarbonate (HCO3-) and 125 ppm for the CO2. The inverse-gated proton decoupled13C NMR (pulse sequence: zgig30) was employed for quantifying captured CO2. It improved the sensitivity and resolution of the13C NMR spectra and enabled precise measurement of captured CO2 by selectively decoupling protons from the carbon signals. The bicarbonate and CO2 peaks were integrated with reference to an internal standard (trioxane). The trioxane had only one type of carbon atom and it displayed an intense peak, which did not overlap with the other peaks of the modified ionic lignin polymer (Figure 9 and Figure 10a, b).

[0203] The CO2 capture experiments using quantitative inverse-gated proton decoupled13C NMR (solvent: D2O) were conducted with both the concentrated CO2 source (Figure 10a) and direct air exposure (Figure 10b). The mole amounts of HCO3- and CO2 per gram of modified ionic lignin polymer were calculated from the integral values of those two peaks (HCO3-: 160.2 ppm and CO2: 124.7 ppm) compared to the trioxane peak at 93.5 ppm (Figure 10a and b). The comprehensive calculations from the NMR integral values were elaborated in the supporting information (Figures 11 and 12). The bicarbonate formationAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 and CO2amount per gram of modified ionic lignin from the concentrated CO2capture showed an identical value of 0.53 mmol g-1. On the contrary, the values were different in direct air capture, where the quantities were 0.45 mmol g-1for bicarbonate formation and 0.15 mmol g-1for the CO2 amount.

[0204] In the values between concentrated CO2capture and direct air capture, the bicarbonate quantity varied far less than the CO2amount analyzed. The overall CO2quantity comprised not only the physisorbed CO2 but also a portion of released CO2 because the NMR solvent D2O induced some decomposition of bicarbonates to CO2. The chemical CO2 sorption of the modified ionic lignin polymer converted the hydroxide (HO-) into bicarbonate (HCO3-). The chemisorbed CO2 amounts per gram of modified ionic lignin were 23 mg and 20 mg from concentrated CO2source and direct air capture, respectively. Subsequently, combining both chemisorbed and physisorbed CO2values, one gram of modified ionic lignin polymer captured 1.06 mmol (47 mg) from a concentrated CO2source and 0.60 mmol (26 mg) of CO2 from ambient air exposure. The lesser value in CO2 capture using the direct air capture approach was observed because ambient air contains a very low amount of CO2 (0.04%). This quantitative method gave vital insights into CO2 capture processes, enabling improved capture efficiency and the development of more effective carbon capture technology. 2.4. Synthesis of cyclic carbonate using CO2-captured ionic lignin polymer as CO2source

[0205] The notion of carrying out a model reaction for cyclic carbonate synthesis was implemented to utilize the CO2-captured ionic lignin polymer (P-2) as an active CO2source. The CO2emission from the hydrated solution of CO2-captured ionic lignin polymer prompted the current investigation (Figures 8, 11, and 12). Without wishing to be bound by any theory, it was hypothesized that the captured CO2 in P-2 (CO2 source) would react with a 1,3-diol derivative, forming cyclic carbonate. To validate this hypothesis, 1,3-butanediol was chosen for the reaction (Figure 13a). A unique reaction setup comprised two round bottom flasks that were connected via a needle-attached tubing system, as seen in Figure 13b and Figure 14. The solution of P-2 in deionized water is heated to 60 °C to accelerate the CO2release process. The temperature was maintained at 60 °C to minimize the influence of water evaporation. The cyclic carbonate was synthesized using TMP (2,2,6,6- tetramethylpiperidine) as a base in the presence of tosyl chloride. The released CO2 gas from the P-2 in RB-2 (Figure 13b) was constantly transferred towards the RB-1 (Figure 13b), where the cyclization took place. The internal reaction atmosphere was saturated with released CO2, which was observed as CO2gas bubbles in RB-1 (Figure 13b).Attorney Docket No.10850-103WO1 FSU Ref. No.24-042

[0206] After completion of the reaction, the obtained product was thoroughly structurally characterized by the1H and13C NMR spectroscopy (Figure 13c and d). The peaks of the hydroxyl group protons of 1, 3 diols in 4.33-4.39 ppm disappeared from the1H NMR (Figure 13c) of the product, indicating the participation of the hydroxyl groups in the cyclization reaction. Moreover, the typical peaks of –CH2–OH (assignment 1 in Figure 13c) and – CH(OH)– (assignment 3 in Figure 13c) of the product were shifted from 3.46 ppm to 3.62 ppm and 3.70 ppm to 4.08 ppm, respectively. The most significant piece of evidence to support the cyclization reaction was demonstrated by the13C NMR of the product in Figure 13d, which displayed the signal for the carbonyl group (>C=O) of the cyclic carbonate at 145 ppm. Notably, no reaction occurred under the same reaction conditions in the absence of the CO2 source. It is, therefore, possible to conclude that the cyclic carbonate was effectively synthesized without any direct CO2 input to the reaction medium. 2.5. Controllable recycling and CO2-capturing of modified ionic lignin polymer (CO2release ↔ CO2 capture)

[0207] The controlled recycling of modified ionic lignin polymer via CO2release and subsequent capture presents a promising approach for sustainable carbon mitigation strategies. In the recycling study, the product was recovered from the aqueous solution of CO2-captured modified ionic lignin polymer (P-2) from RB-2 (as shown in Figure 13b) after the model cyclic carbonate synthesis reaction (Figure 15a). Subsequently, the recovered product underwent freeze-drying, and its structure was confirmed using1H and13C NMR spectroscopy. Notably, heating at 60 °C was applied during the model reaction. The1H NMR spectrum (Figure 16) of the recycled product exhibited peaks analogous to those observed in the modified ionic lignin polymer, indicating successful structural retention throughout the recycling process.

[0208] Subsequently, the13C NMR spectrum also exhibited a good agreement with that of the ionic lignin polymer, as illustrated in Figure 15a. Following this, the effectiveness of the recycled material was assessed through CO2capture experiments. Significantly, characteristic peaks corresponding to bicarbonate at 160 ppm and CO2at 125 ppm were observed in Figure 15a (starting and recycled CO2-captured ionic lignin polymer). This observation suggested that both the chemisorption and physisorption of CO2remained active in the recycled product, similar to the starting material. Furthermore, figure 15b provides a graphical representation of the recycling process of modified ionic lignin polymer via continuous CO2 release ↔ CO2 capture.

[0209] Thermogravimetric analysis (TGA) experiment was conducted to check the thermal stability of the developed polymers. As the heating was applied during the modelAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 reaction, it was imperative to assess the thermal robustness of the modified ionic lignin polymers. Figure 15c presents the TGA plot illustrating the thermal behavior of lignin and modified ionic lignin polymers both before and after CO2 capture. Interestingly, the CO2- captured modified ionic lignin polymer (utilizing either air or concentrated CO2) displayed additional weight losses within the temperature range of 50 °C to 90 °C, as depicted in the inset of Figure 15c. This phenomenon could appear to be the evaporation of CO2 from the CO2-captured modified ionic lignin polymer. Subsequently, a weight loss near 110 °C was observed, attributed to the moisture evaporation owing to the hygroscopic nature of the modified ionic lignin polymers (P-1 and P-2). Degradation of the polymer backbones commenced above 180 °C. Hence, the prominent thermal stability of the modified ionic lignin polymer emphasized the potential effectiveness and recyclability in CO2 capture and utilization applications. 3. Conclusions

[0210] In this research, an innovative method to develop lignin-derived polymers for CO2 capturing and conversion of the captured CO2 to cyclic carbonate, utilizing abundant and non-food-based biomass, was established. Modified ionic lignin polymer is synthesized methodically from lignin and glycidyltrimethyl ammonium chloride under a basic medium (0.5M sodium hydroxide). Subsequently, the obtained polymers are employed to capture CO2from both direct air and concentrated CO2sources. The chemical structures of the modified ionic lignin polymers are systematically elucidated by using spectroscopic techniques (FT-IR,1H,13C, and 2D-HSQC NMR). The successful CO2 capturing has been confirmed from the13C NMR peak of bicarbonate at 160 ppm, which is generated from the reaction between CO2 and hydroxide ions. Moreover, the amount of captured-CO2 is experimentally quantified using inverse-gated proton decoupled13C NMR with reference to an internal standard. Impressively, the modified ionic lignin polymers have captured 1.06 mmol (47 mg) of CO2per gram from concentrated CO2sources and 0.60 mmol (26 mg) from direct air capture. Notably, the utilization of captured-CO2 (CO2 source) is effectively demonstrated by performing a model reaction of cyclic carbonate synthesis from 1, 3- butanediol in a newly devised reaction set-up, highlighting the versatility of the disclosed approach. Significantly, the disclosed study underscores the potential for recyclability of the modified ionic lignin polymer in aqueous conditions under heating conditions via continuous CO2release ↔ CO2capture, enhancing its sustainability and usability. In summary, the disclosed work signifies a crucial sustainable advancement in recyclable carbon capture, storage, and utilization technologies, pivotal for addressing the impacts of CO2 emissions.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 Example 4

[0211] In this example, a novel non-isocyanate polyhydroxyurethane (NIPU) from lignin was developed. It is innovative to use biomass lignin for the preparation of NIPU, marking the first instance of such a development. In addition, the newly synthesized NIPU incorporates CO2, a greenhouse gas. While previous CO2 gas-based NIPU formulations typically required high-pressure conditions for synthesis, our method enables synthesis at normal pressure and room temperature, demonstrating innovation in green chemistry. Furthermore, this NIPU can be chemically degraded under basic conditions, addressing environmental concerns associated with plastic waste. Notably, this work represents the first work of NIPU synthesis directly from natural lignin rather than using model compound or lignin derivatives.

[0212] Polyurethanes have extensive applications in elastomer, biomedical, coating, sealing, adhesive, and electrical device applications. Non-isocyanate polyurethane, in particular, garners attention for its non-toxicity and environmental friendliness, as it does not require isocyanate during manufacturing. The present study not only advances sustainability but also enhances the functionalities of NIPU materials by incorporating natural lignin and CO2, thereby contributing to environmental stewardship and material innovation.

[0213] The central focus of the presented work revolves around the reactions between cyclocarbonated lignin and amine-containing monomers, as depicted in the scheme.

[0214] The formed polyurethanes by the disclosed methods are characterized as shown in Figures 17-28. Additional Aspects 1. A polymeric material comprising: one or more fragments of Formula I: (I) wherein X is selected fromnull, ,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 wherein R1is selected from null or C1-C40aliphatic group, wherein R1is optionally substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; wherein when X is null, R1is not null, or wherein R1is null, X is not null; wherein two of R2, R3,and R4may together form a 5 or 6-membered ring, or wherein R2and R3, each and on each occasion, independent of the other, are selected from C1-C40 aliphatic group, wherein R4is selected from C1-C40aliphatic group or lignin, and wherein each of R2, R3, and R4is independently and optionally substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), halide, -C(O)-OH, or hydroxy. 2. The polymeric material of aspect 1, wherein R1is a C1-C40 aliphatic group selected from, C1-C20 alkylene, C1-C20 alkenylene, C1-C6 alkynylene, -(C0-10 alkylene)(C6-C14 aryl), or - (C0-10alkylene)( aryl-N=N-aryl , wherein squiggly line 1 is a connection to X,to N+, wherein R1is optionally substituted one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl- )(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl- )(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy. 3. The polymeric material of any one of aspects 1-2, comprising one or more fragments of formula (II)Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 OH OH ,4. The polymeric material of any one of aspects 1-2, comprising one or more fragments of formula (III)Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 ,5. The polymeric material of any one of aspects 1-4, wherein the polymeric material is a carbon dioxide-capturing material. 6. The polymeric material of aspect 5, wherein a carbon dioxide capture is reversible. 7. The polymeric material of aspect 5 or 6, wherein the polymeric material is recyclable. 8. An article comprising the polymeric material of any one of aspects 1-7. 9. The article of aspect 8, wherein the article is a film, a textile, a filter, a membrane, an absorbent, or any combination thereof. 10. The article of aspect 8 or 9 wherein the article is recyclable. 11. A method comprising: reacting lignin-containing material with a nitrogen-containing material to form a polymeric material comprising one or more fragments of formula (I)Attorney Docket No.10850-103WO1 FSU Ref. No.24-042O ,wherein R1is optionally substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; wherein when X is null, R1is not null, or wherein R1is null, X is not null; wherein two of R2, R3,and R4may together form a 5 or 6-membered ring, or wherein R2and R3, each and on each occasion, independent of the other, are selected from C1-C40 aliphatic group, wherein R4is selected from C1-C40aliphatic group or lignin, and wherein each of R2, R3, and R4is independently and optionally substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), halide, -C(O)-OH, or hydroxy. 12. The method of aspect 11, wherein R1is a C1-C40 aliphatic group selected from C1-C20 alkylene, C1-C20 alkenylene, C1-C6 alkynylene, -(C0-10 alkylene)(C6-C14 aryl), or -(C0-10 alkyl- ene)( aryl-N=N-aryl group) , wherein squiggly line 1 is a connection to X,is a connection to N+, wherein R1is optionally substituted one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), - (C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 13. The method of any one of aspects 11-12, wherein the polymeric material comprises one or more fragments of formula (II) OH OH ,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 14. The method of any one of aspects 11-12, wherein the polymeric material comprises one or more fragments of formula (III) ,15. The method of any one of aspects 11-14, wherein the nitrogen-containing material has a formula ,counter ion that is different from OH, and wherein X* is selected from wherein R4*is an C1-C40Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 16. The method of any one of aspects 11-15, wherein the nitrogen-containing material is selected from ordioxide-capturing material. 18. The method of aspect 17, wherein a carbon dioxide capture is reversible. 19. The method of any one of aspects 11-18, wherein the polymeric material is recyclable. 20. The method of any one of aspects 11-19, further comprising making an article from the polymeric material. 21. The method of aspect 20, wherein the article is a film, a textile, a filter, a membrane, an absorbent, or any combination thereof. 22. The method of aspect 20 or 21, wherein the article is recyclable. 23. A method of capturing a carbon dioxide comprising exposing an article comprising a polymeric material of any one of aspects 1-7 to a gas stream comprising the carbon dioxide; and reacting the polymeric material with the carbon dioxide to form a compound comprising one or more fragments of formula (VI),null, ,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 wherein R1is optionally substituted with one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; wherein when X is null, R1is not null, or wherein R1is null, X is not null; wherein two of R2, R3,and R4may together form a 5 or 6-membered ring, or wherein R2and R3, each and on each occasion, independent of the other, are selected from C1-C40aliphatic group, wherein R4is selected from C1-C40 aliphatic group or lignin, and wherein each of R2, R3, and R4is independently and optionally substituted with one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy, thereby removing the carbon dioxide from the gas stream. 24. The method of 23, wherein R1is a C1-C40aliphatic group selected from C1-C20alkylene, C1-C20alkenylene, C1-C6alkynylene, -(C0-10alkylene)(C6-C14aryl), or -(C0-10alkyl- ene)( aryl-N=N-aryl group), wherein squiggly line 1 is a connection to X,is a connection to N+, wherein R1is optionally substituted one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), - (C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), halide, -C(O)-OH, or hydroxy. 25. The method of aspect 24, wherein the method is reversible, is such that the captured carbon dioxide is released. 26. A method comprising: a) providing a polymer composition comprising one or more fragments of formula (IV) whereinAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 Onull, ,wherein R1is optionally substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; wherein when X is null, R1is not null, or wherein R1is null, X is not null; wherein two of R2, R3,and R4may together form a 5 or 6-membered ring, or wherein R2and R3, each and on each occasion, independent of the other, are selected from C1-C40 aliphatic group, wherein R4is selected from C1-C40aliphatic group or lignin, and wherein each of R2, R3, and R4is independently and optionally substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; b) releasing carbon dioxide from the polymer composition; and c) utilizing the released carbon dioxide to form a compound comprising a cyclic carbonate. 27. The method of aspect 25, wherein R1is a C1-C40 aliphatic group selected from C1-C20 alkylene, C1-C20 alkenylene, C1-C6 alkynylene, -(C0-10 alkylene)(C6-C14 aryl), or -(C0-10 alkyl- ene)( aryl-N=N-aryl group), , wherein squiggly line 1 is a connection to X, and squiggly line 2 is a connection to N+,substituted one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), - (C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy. 28. The method of any one of aspects 25-26, wherein the polymer composition comprises one or more fragments of formula:Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 ,29. The method of any one of aspects 25-27, wherein the polymer composition comprises one or more fragments of formula:Attorney Docket No.10850-103WO1 FSU Ref. No.24-04230. A method comprising: reacting a lignin-based macromonomer of formula (X) with a polyamine to form a polyhydroxyurethane (PHU) of formula (XI) ;Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 O O OH O N R N O OH H wherein one or moreof C1-10 10 10-10 14, -10(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy. 31. The method of aspect 30, wherein R12, is selected from C1-C20alkylene, C1-C20alkenylene, C1-C6alkynylene, -(C0-10alkylene)(C6-C14aryl), or -(C0-10alkylene)( aryl-N=N- aryl group), wherein R12is optionally substituted one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy. 32. The method of aspect 30 or 31, wherein the polyamine comprises an aromatic diamine, an aliphatic diamine, an ether linkage-based aliphatic diamine, a triamine, or a combination thereof. 33. The method of any one of aspects 30-32, wherein the lignin-based macromonomer (VII) is formed by reacting a lignin-based material having one or more OH groups with a carbon dioxide. 34. The method of any one of aspects 30-33, wherein polyamine is selected from ,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 a combination thereof. one of aspects 30-34, wherein the reaction of lignin-containingdioxide is conducted at atmospheric pressure. 36. The method of any one of aspects 30-35, wherein the reaction of lignin-containing material with the carbon dioxide is conducted at a temperature of 0 °C to room temperature. 37. The method of any one of aspects 30-36, wherein the polyhydroxyurethane is chemically degradable. 38. A polyhydroxyurethane polymer formed by the methods of any one of aspects 30-37. 39. An article comprising the polyhydroxyurethane polymer of aspect 38. 40. A method recycling of the polymer of aspect 38, comprising degrading the polymer under basic conditions.

Claims

Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 CLAIMS What is claimed is:

1. A polymeric material comprising one or more fragments of Formula I: , (I) wherein X is selected fromO ,wherein R1is optionally substituted with one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; wherein when X is null, R1is not null, or wherein R1is null, X is not null; wherein two of R2, R3,and R4may together form a 5 or 6-membered ring, or wherein R2and R3, each and on each occasion, independent of the other, are selected from C1-C40aliphatic group, wherein R4is selected from C1-C40 aliphatic group or lignin, and wherein each of R2, R3, and R4is independently and optionally substituted with one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

2. The polymeric material of claim 1, wherein R1is a C1-C40 aliphatic group selected from, C1-C20alkylene, C1-C20alkenylene, C1-C6alkynylene, -(C0-10alkylene)(C6-C14aryl), or - (C0-10 alkylene)( aryl-N=N-aryl , wherein squiggly line 1 is a connection to X,wherein R1is optionally substituted one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl-Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 )(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl- )(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

3. The polymeric material of any one of claims 1-2, comprising one or more fragments of formula (II) ,4. The polymeric material of any one of claims 1-2, comprising one or more fragments of formula (III) ,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 5. The polymeric material of any one of claims 1-4, wherein the polymeric material is a carbon dioxide-capturing material.

6. The polymeric material of claim 5, wherein a carbon dioxide capture is reversible.

7. The polymeric material of claim 5 or 6, wherein the polymeric material is recyclable.

8. An article comprising the polymeric material of any one of claims 1-7.

9. The article of claim 8, wherein the article is a film, a textile, a filter, a membrane, an absorbent, or any combination thereof.

10. The article of claim 8 or 9 wherein the article is recyclable.

11. A method comprising reacting lignin-containing material with a nitrogen-containing material to form a polymeric material comprising one or more fragments of formula (I) , (I) wherein X is selected fromO ,wherein R1is optionally substituted with one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; wherein when X is null, R1is not null, or wherein R1is null, X is not null; wherein two of R2, R3,and R4may together form a 5 or 6-membered ring, or wherein R2and R3, each and on each occasion, independent of the other, are selected from C1-C40aliphatic group, wherein R4is selected from C1-C40 aliphatic group or lignin, and wherein each of R2, R3, and R4is independently and optionally substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

12. The method of claim 11, wherein R1is a C1-C40 aliphatic group selected from C1-C20 alkylene, C1-C20alkenylene, C1-C6alkynylene, -(C0-10alkylene)(C6-C14aryl), or -(C0-10alkyl- ene)( aryl-N=N-aryl group) , wherein squiggly line 1 is a connection to X, and is a connection to N+, wherein R1is optionallysubstituted one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), - (C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

13. The method of any one of claims 11-12, wherein the polymeric material comprises one or more fragments of formula (II) , wherein is -H, -CH3, or14. The method of any one of claims 11-12, wherein the polymeric material comprises one or more fragments of formula (III)Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 , wherein is a null or a15. The method of any one of claims 11-14, wherein the nitrogen-containing material has a formula , wherein Y is a counter ion that iswherein X* is selected from wherein R4*is an C1-C4016. The method of any one of claims 11-15, wherein the nitrogen-containing material is selected from R2 R3 ordioxide-capturing material.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 18. The method of claim 17, wherein a carbon dioxide capture is reversible.

19. The method of any one of claims 11-18, wherein the polymeric material is recyclable.

20. The method of any one of claims 11-19, further comprising making an article from the polymeric material.

21. The method of claim 20, wherein the article is a film, a textile, a filter, a membrane, an absorbent, or any combination thereof.

22. The method of claim 20 or 21, wherein the article is recyclable.

23. A method of capturing a carbon dioxide comprising exposing an article comprising a polymeric material of any one of claims 1-7 to a gas stream comprising the carbon dioxide; and reacting the polymeric material with the carbon dioxide to form a compound comprising one or more fragments of formula (VI), wherein X is selected fromO ,wherein R1is optionally substituted with one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; wherein when X is null, R1is not null, or wherein R1is null, X is not null; wherein two of R2, R3,and R4may together form a 5 or 6-membered ring, or wherein R2and R3, each and on each occasion, independent of the other, are selected from C1-C40aliphatic group, wherein R4is selected from C1-C40 aliphatic group or lignin, andAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 wherein each of R2, R3, and R4is independently and optionally substituted with one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy, thereby removing the carbon dioxide from the gas stream.

24. The method of 23, wherein R1is a C1-C40aliphatic group selected from C1-C20alkylene, C1-C20alkenylene, C1-C6alkynylene, -(C0-10alkylene)(C6-C14aryl), or -(C0-10alkyl- ene)( aryl-N=N-aryl group), , wherein squiggly line 1 is a connection to X, and squiggly line 2 is a connection to N+, wherein R1is optionally substituted one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), - (C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)(C3-10cycloalkenyl), -(C0-10alkyl)(C3-10heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

25. The method of claim 24, wherein the method is reversible, is such that the captured carbon dioxide is released.

26. A method comprising providing a polymer composition comprising one or more fragments of formula (VI) wherein X is selected from,wherein R1is optionally substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; wherein when X is null, R1is not null, or wherein R1is null, X is not null; wherein two of R2, R3,and R4may together form a 5 or 6-membered ring, orAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 wherein R2and R3, each and on each occasion, independent of the other, are selected from C1-C40aliphatic group, wherein R4is selected from C1-C40 aliphatic group or lignin, and wherein each of R2, R3, and R4is independently and optionally substituted with one or more of C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy; d) releasing carbon dioxide from the polymer composition; and e) utilizing the released carbon dioxide to form a compound comprising a cyclic carbonate.

27. The method of claim 25, wherein R1is a C1-C40aliphatic group selected from C1-C20alkylene, C1-C20 alkenylene, C1-C6 alkynylene, -(C0-10 alkylene)(C6-C14 aryl), or -(C0-10 alkyl- ene)( aryl-N=N-aryl group) , wherein squiggly line 1 is a connection to X,is a connection to N+, wherein R1is optionally substituted one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), - (C0-10alkyl)(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

28. The method of any one of claims 25-26, wherein the polymer composition comprises one or more fragments of formula: ,wherein is -H, -CH3, orAttorney Docket No.10850-103WO1 FSU Ref. No.24-042 29. The method of any one of claims 25-27, wherein the polymer composition comprises one or more fragments of formula:

30. A method comprising: reacting a lignin-based macromonomer of formula (X) with a polyamine to form a polyhydroxyurethane (PHU) of formula (XII) ;Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 O O OH O N R N O OH H wherein one or moreof C1-10 10 10-10 14, -10(C1-13heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

31. The method of claim 30, wherein R12, is selected from C1-C20alkylene, C1-C20alkenylene, C1-C6alkynylene, -(C0-10alkylene)(C6-C14aryl), or -(C0-10alkylene)( aryl-N=N- aryl group), wherein R12is optionally substituted one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

32. The method of claim 30 or 31, wherein the polyamine comprises an aromatic diamine, an aliphatic diamine, an ether linkage-based aliphatic diamine, a triamine, or a combination thereof.

33. The method of any one of claims 30-32, wherein the lignin-based macromonomer (VII) is formed by reacting a lignin-based material having one or more OH groups with a carbon dioxide.

34. The method of any one of claims 30-33, wherein polyamine is selected from ,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 a combination thereof. one of claims 30-34, wherein the reaction of lignin-containingdioxide is conducted at atmospheric pressure.

36. The method of any one of claims 30-35, wherein the reaction of lignin-containing material with the carbon dioxide is conducted at a temperature of 0 °C to room temperature.

37. The method of any one of claims 30-36, wherein the polyhydroxyurethane is chemically degradable.

38. A polyhydroxyurethane polymer formed by the methods of any one of claims 30-37.

39. An article comprising the polyhydroxyurethane polymer of claim 38.

40. A method recycling of the polymer of claim 38, comprising degrading the polymer under basic conditions.

41. A polymeric material comprising one or more fragments of Formula: R2A Lignin, wherein A is hydroxide, bicarbonate, or aZ is independently P or N; X is independently: orwavy wavy represents the point of attachment to R1; X1is null, S, O, NH, or a 1,2,3,-triazole;Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 x is 0-8; L is a C0-10aliphatic group, for example null, C1-10alkylene, or C1-10heteroalkylene; R1is selected from null or C1-C10aliphatic group, wherein R1is optionally substituted with one or more of C1-10alkyl, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)COOH, -(C0-10 alkyl)N(C1-4alkyl)3, or -(C0-10 alkyl)-OH; at least one of X and R1is not null; any two or more of R1, R2, R3,and R4may together form a ring, R2, R3, and R4are in each case independently selected from C1-C10 aliphatic group, each of R1, R2, R3, and R4is independently and optionally substituted with one or more of a lignin fragment, C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl- )(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), -(C0-10alkyl)COOH, -(C0-10alkyl)N(C1-4alkyl)3, or -(C0-10alkyl)-OH; wherein when Z is a sp2hybridized nitrogen, then R4is optionally null.

42. The polymeric material of claim 41, wherein X is .

43. TheR1is C1-3alkylene, preferably CH2.

44. The polymeric material of claim 41, wherein X is: R1is C2-10alkylene.

45. The polymeric material of claim 41, wherein X is:Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 , and x is 1-4.

46. The polymeric material of claim 41, wherein X is: , and x is 2 and X1is S.

47. The polymeric material of claim 41, wherein X is: , and x is 1, 2, or 3 and X1is 1,2,348. The polymeric material of claim 46 or 47, wherein L is C0-4alkylene.

49. The polymeric material of any of claims 41-48, wherein R1, R2, and R3together form a heteroaryl or heterocyclic ring.

50. The polymeric material of claim 49, wherein R1, R2, and R3together form a pyridine ring.

51. The polymeric material of claim 49, wherein R1, R2, and R3together form an N-alkyl pyridinium group.

52. The polymeric material of claim 49, wherein R1, R2, and R3together form an imidazole ring.

53. The polymeric material of claim 49, wherein R1, R2, and R3together form an N-alkyl imidazolinium group.

54. The polymeric material of claim 49, wherein two or more of R1, R2, and R3together form a benzimidazolyl, benzoxazolyl, benzoxazolinyl, benzthiazolyl, benztriazolyl, benztetrazolyl, benzisoxazolyl, benzisothiazolyl, benzimidazolinyl, carbazolyl, 4aH carbazolyl, carbolinyl, decahydroquinolinyl, 2H,6H-1,5,2-dithiazinyl, dihydrofuro[2,3 b]tetrahydrofuran, furanyl, furazanyl, imidazolidinyl, imidazolinyl, imidazolyl, lH-indazolyl, indolenyl, indolinyl, indolizinyl, indolyl, 3H-indolyl, isatinoyl, isoindazolyl, isoindolinyl, isoindolyl, isoquinolinyl, isothiazolyl, isoxazolyl, morpholinyl, naphthyridinyl, octahydroisoquinolinyl, oxadiazolyl, 1,2,3-oxadiazolyl, 1,2,4-oxadiazolyl, 1,2,5-oxadiazolyl, 1,3,4-oxadiazolyl, oxazolidinyl, oxazolyl, oxindolyl, pyrimidinyl, phenanthridinyl, phenanthrolinyl, phenazinyl, phenoxathinyl, phenoxazinyl, phthalazinyl, piperazinyl, piperidinyl, piperidonyl, 4-piperidonyl, piperonyl, pteridinyl, purinyl, pyranyl, pyrazinyl,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 pyrazolidinyl, pyrazolinyl, pyrazolyl, pyridazinyl, pyridooxazole, pyridoimidazole, pyridothiazole, pyridinyl, pyridyl, pyrimidinyl, pyrrolidinyl, pyrrolinyl, 2H-pyrrolyl, pyrrolyl, quinazolinyl, quinolinyl, 4H-quinolizinyl, quinoxalinyl, quinuclidinyl, tetrahydrofuranyl, tetrahydroisoquinolinyl, tetrahydroquinolinyl, tetrazolyl, 6H-1,2,5-thiadiazinyl, 1,2,3- thiadiazolyl, 1,2,4-thiadiazolyl, 1,2,5-thiadiazolyl, 1,3,4-thiadiazolyl, thiazolyl, thienothiazolyl, thienooxazolyl, thienoimidazolyl, or a N-alkyl derivative thereof.

55. The polymeric material of any of claims 41-54, wherein wherein R1, R2, and R3together form a heteroaryl or heterocyclic ring, substituted by an N-alkyl heteroaryl ring, preferably N-alkylpyridinium or N-alkylimidazolium.

56. The polymeric material of any of claims 41-55, having the formula: ,57. The polymeric material of claim 41, wherein Z is P.

58. The polymeric material of claim 41, wherein Z is P and each of R2, R3, and R4are C1-10 alkyl, optionally two or more of R2, R3, and R4together forming a ring.

59. The polymeric material of claim 41, wherein Z is P and each of R2, R3, and R4are methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, n-pentyl, or n-hexyl.

60. The polymeric material of claim 41, wherein Z is P and R2and R3are methyl and R4is ethyl, n-propyl, isopropyl, n-butyl, isobutyl, n-pentyl, or n-hexyl.

61. The polymeric material of claim 41, wherein Z is P and R2, R3, and R4are the same, for example R2, R3, and R4are each methyl, ethyl, or n-propyl.

62. The polymeric material of any of claims 41-57, wherein R4is C1-10aliphatic-lignin.

63. The polymeric material of any of claims 41-57, wherein R4has the formula C1-10aliphatic-L*, wherein L* has the formula: ,Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 XLis independently: ,represents to R1Lgroup X1Lis null, S, O, NH, or a 1,2,3,-triazole; x* is 0-8; LLis a C0-10aliphatic group, e.g. null, C1-10alkylene, or C1-10heteroalkylene; R1Lis selected from null or C1-C10aliphatic group, wherein R1Lis optionally substituted with one or more of C1-10alkyl, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)COOH, -(C0-10 alkyl)N(C1-4alkyl)3, or -(C0-10 alkyl)-OH; at least one of XLand R1Lis not null; any two or more of R1L, R2L, and R3Lmay together form a ring, R2Land R3Lare in each case independently selected from C1-C10aliphatic group, each of R1L, R2L, and R3Lis independently and optionally substituted with one or more of a lignin fragment, C1-10 alkyl, C1-10 alkoxy, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl- )(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), -(C0- 10alkyl)COOH, -(C0-10alkyl)N(C1-4alkyl)3, or -(C0-10alkyl)-OH; wherein when ZLis a sp2hybridized nitrogen, then R3Lis optionally null.

64. The polymeric material of any of claims 45-48, wherein R4has the formula C1-10aliphatic-L*, wherein L* has the formula: , LX is independently:Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 ,represents to group X1Lis null, S, O, NH, or a 1,2,3,-triazole; x* is 0-8; LLis a C0-10aliphatic group, e.g. null, C1-10alkylene, or C1-10heteroalkylene; R1Lis selected from null or C1-C10 aliphatic group, wherein R1Lis optionally substituted with one or more of C1-10 alkyl, C1-10 heteroalkyl, -(C0-10 alkyl)(C6-14 aryl), -(C0-10 alkyl)(C1-13 heteroaryl), -(C0-10alkyl)(C6-14aryloxy), -(C0-10alkyl)(C3-10cycloalkyl), -(C0-10alkyl)(C3-10heterocycloalkyl),-(C0-10alkyl)COOH, -(C0-10alkyl)N(C1-4alkyl)3, or -(C0-10alkyl)-OH; at least one of XLand R1Lis not null; any two or more of R1L, R2L, and R3Lmay together form a ring, R2Land R3Lare in each case independently selected from C1-C10 aliphatic group, each of R1L, R2L, and R3Lis independently and optionally substituted with one or more of a lignin fragment, C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl- )(C1-13 heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), -(C0- 10 alkyl)COOH, -(C0-10 alkyl)N(C1-4alkyl)3, or -(C0-10 alkyl)-OH; wherein when ZLis a sp2hybridized nitrogen, then R3Lis optionally null 65. The polymeric material of any of claims 63 or 64, wherein R2Land R3Lare methyl.

66. The polymeric material of any of claims 41-65, wherein A is hydroxide.

67. The polymeric material of any of claims 41-65, wherein A is bicarbonate.

68. The polymeric material of any of claims 41-65, wherein A is a mixture of hydroxide and bicarbonate.

69. A method of capturing carbon dioxide, comprising contacting the polymeric material of claim 66 with a carbon dioxide source.Attorney Docket No.10850-103WO1 FSU Ref. No.24-042 70. A method of forming a cyclic carbonate, comprising combining the polymeric material of claim 67 or 68 with a diol, an alcohol activating agent, and a base.

71. The method of claim 70, wherein the alcohol activating agent comprises a sulfonyl halide (e.g., tosylchloride, mesylchloride), hydroiodic acid, hydrobromic acid, or hydrochloric acid.

72. The method of claim 70 or 71, wherein the base comprises a compound having the formula N(Rb)3, wherein Rbis independently selected from C1-6aliphatic wherein any two or more Rbgroups can together form a ring.

73. The method of any of claims 70-72, wherein the diol comprises a separately added diol.

74. The method of any of claims 70-72, wherein the diol comprises a lignin fragment.

75. The method of any of claims 70-72, wherein the diol comprises a lignin fragment present in the polymeric material (of claim 67 or 68).

76. A cyclic carbonate obtained by the method of any of claims 70-75.

77. A method of preparing a polyurethane, comprising contacting the cyclic carbonate of claim 76 with a polyamine.

78. The method of claim 77, wherein the polyamine has the formula NH2-R12-NH2, wherein R12is C1-C40aliphatic group, wherein R12is optionally substituted with one or more of C1-10alkyl, C1-10alkoxy, C1-10heteroalkyl, -(C0-10alkyl)(C6-14aryl), -(C0-10alkyl)(C1-13heteroaryl), -(C0-10 alkyl)(C6-14 aryloxy), -(C0-10 alkyl)(C3-10 cycloalkyl), -(C0-10 alkyl)(C3-10 heterocycloalkyl), -(C0-10 alkyl)(C3-10 cycloalkenyl), -(C0-10 alkyl)(C3-10 heterocycloalkenyl), halide, -C(O)-OH, or hydroxy.

79. The method of claim 77 or 78, wherein the polyamine is selected from: ,80. A polyurethane obtained by the method of any of claims 77-79.

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