Laminated glass
By designing a sandwich structure in building energy-saving glass, combining color discoloration and photoelectric display components, and using specific electrolyte layers and transition layers, the insulation performance is compatible with information display, solving the problem that existing glass cannot provide more display information, and improving the problem that existing glass can't provide more display information. User experience and applicability.
Patent Information
- Application Number
- CN202310339609.0
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2023-03-27
- Publication Date
- 2024-12-10
- Estimated Expiration
- 2043-03-27
AI Technical Summary
Existing building energy-saving glass can only improve thermal insulation performance alone and cannot provide more display information.
Design a laminated glass, through the specific structure of the film layer, combines color-changing components and photoelectric display components, to achieve compatibility between thermal insulation and photoelectric display performance, and use an electrolyte layer composed of lithium-containing compounds, polymers and organic solvents to form a liquid state Or colloidal electrolyte layer, combined with the frame and transition layer, achieve stable and efficient color discoloration and information display.
It improves the application of glass, achieves compatibility between thermal insulation performance and information display, increases user experience, and flexibly controls the display function through the control system.
Smart Images

Figure CN116430629B_ABST
Abstract
Description
Technical Field
[0001] The present invention relates to the technical field of display glass, and in particular to a laminated glass. Background Art
[0002] Energy-saving architectural glass will play an increasingly important role in the development of low-carbon and energy-saving industries. At present, my country's energy-saving architectural glass is mainly low-emissivity glass, which greatly reduces the amount of sunlight passing through the window glass and improves the thermal insulation performance of the window glass. However, when used, it can only achieve the single function of improving the thermal insulation performance of the window glass and cannot obtain more display information from the main body.
[0003] Based on this, providing a glass that can not only improve the thermal insulation performance of window glass but also provide more display information is an urgent problem to be solved by the present invention. Summary of the invention
[0004] The present invention provides a laminated glass, which can achieve the compatibility of the thermal insulation performance of the window glass and the optoelectronic display performance through the specific structural design of the film layer, so as to enhance the user experience.
[0005] Specifically, an embodiment of the present invention proposes a laminated glass, comprising: a color-changing component and an optoelectronic display component; the color-changing component comprises: a first target substrate, a second target substrate, and an electrolyte layer sandwiched between the first target substrate and the second target substrate; the first target substrate comprises: a first glass substrate; a first conductive layer, located on the first glass substrate; a main color-changing layer, located on a side of the first conductive layer away from the first glass substrate; the second target substrate comprises: a second glass substrate; a second conductive layer, located on the second glass substrate; an auxiliary color-changing layer, located on a side of the second conductive layer away from the second glass substrate, wherein the electrolyte layer is located between the main color-changing layer and the auxiliary color-changing layer; the first target substrate further comprises: a first transition layer, located between the main color-changing layer and the electrolyte layer; the second target substrate further comprises: a second transition layer, located between the auxiliary color-changing layer and the electrolyte layer; the electrolyte layer comprises: a lithium-containing compound, a polymer The lithium-containing compound is specifically: one or a combination of at least two of LiAsF6, LiPF6, LiBF4, CF3SO3Li and LiClO4; the high molecular polymer is specifically: one or a combination of polypropylene carbonate, polyaniline, polyethylene oxide, polyacrylonitrile, polyvinylidene fluoride, polyvinylidene fluoride-hexafluoropropylene, polymethyl methacrylate, polyvinyl chloride; the organic solvent is used to dissolve the organic polymer of the high molecular polymer, and is specifically: one or a combination of at least two solvents of propylene carbonate, ethylene carbonate, diethyl carbonate, ethyl methyl carbonate, dimethyl carbonate, methyl formate, methyl acrylate, methyl butyrate, ethyl acetate; the optoelectronic display assembly comprises: a third glass substrate, a fourth glass substrate and a display lamp sandwiched between the third glass substrate and the fourth glass substrate; wherein the third glass substrate of the optoelectronic display assembly is bonded to the second glass substrate of the second target substrate.
[0006] In addition, a laminated glass disclosed in an embodiment of the present invention includes: a color-changing component and a photoelectric display component; the color-changing component includes: a first target substrate, a second target substrate and an electrolyte layer sandwiched between the first target substrate and the second target substrate; the electrolyte layer includes: an organic solvent, a lithium-containing compound and a high molecular polymer; the photoelectric display component includes: a third glass substrate, a fourth glass substrate and a display light sandwiched between the third glass substrate and the fourth glass substrate; wherein the third glass substrate of the photoelectric display component is bonded to the second target substrate.
[0007] In one embodiment of the present invention, the lithium-containing compound is specifically: one or a combination of at least two of LiAsF6, LiPF6, LiBF4, CF3SO3Li and LiClO4; the high molecular polymer is specifically: one or a combination of several of polypropylene carbonate, polyaniline, polyethylene oxide, polyacrylonitrile, polyvinylidene fluoride, polyvinylidene fluoride-hexafluoropropylene, polymethyl methacrylate, and polyvinyl chloride.
[0008] In one embodiment of the present invention, the electrolyte layer further includes: an organic solvent for dissolving the organic polymer of the high molecular polymer to form a liquid electrolyte layer; the organic solvent includes: one or a combination of at least two solvents of propylene carbonate, ethylene carbonate, diethyl carbonate, ethyl methyl carbonate, dimethyl carbonate, methyl formate, methyl acrylate, methyl butyrate, and ethyl acetate; the organic solvent includes: one or a combination of at least two solvents of propylene carbonate, ethylene carbonate, diethyl carbonate, ethyl methyl carbonate, dimethyl carbonate, methyl formate, methyl acrylate, methyl butyrate, and ethyl acetate.
[0009] In one embodiment of the present invention, the electrolyte is a liquid electrolyte layer; the color-changing component further comprises: a frame, forming a receiving cavity with the first target substrate and the second target substrate to receive the liquid electrolyte layer.
[0010] In one embodiment of the present invention, the electrolyte layer further includes: a curing agent; and the electrolyte layer is a gel electrolyte layer or a solid electrolyte layer.
[0011] In one embodiment of the present invention, the first target substrate comprises: a first glass substrate; a first conductive layer located on the first glass substrate; a main color-changing layer located on the first conductive layer; the second target substrate comprises: a second glass substrate; a second conductive layer located on the second glass substrate; an auxiliary color-changing layer located on the second conductive layer; wherein the electrolyte layer is located between the main color-changing layer and the auxiliary color-changing layer, and the third glass substrate of the optoelectronic display assembly is bonded to the second glass substrate of the second target substrate.
[0012] In one embodiment of the present invention, the thicknesses of the first glass substrate, the first conductive layer, the main color-changing layer, the second glass substrate, the second conductive layer, and the auxiliary color-changing layer are at least partially the same.
[0013] In one embodiment of the present invention, the first target substrate further includes: a first transition layer, located between the main color-changing layer and the electrolyte layer; the second target substrate further includes: a second transition layer, located between the auxiliary color-changing layer and the electrolyte layer; wherein the first transition layer is a film layer generated by a chemical reaction after the electrolyte layer and the main color-changing layer are bonded together and subjected to heat treatment; the second transition layer is a film layer generated by a chemical reaction after the electrolyte layer and the auxiliary color-changing layer are bonded together and subjected to heat treatment.
[0014] In one embodiment of the present invention, the electrolyte layer further comprises: an insulating spacer, so that the first target substrate and the second target substrate are spaced apart at a uniform distance.
[0015] In addition, an embodiment of the present invention provides a laminated glass control system, comprising: the laminated glass described in any one of the foregoing; a control device, connecting the color-changing component and the photoelectric display component of the laminated glass to control the color change of the color-changing component and the display information of the photoelectric display component.
[0016] The above technical solution has the following advantages or beneficial effects: through a specific film layer structure, stable and efficient color change can be achieved on one side of the laminated glass to improve the insulation performance of the glass and the information display function on the other side to improve the applicability of the laminated glass; by setting up a control system, the user can flexibly control the laminated glass to realize the display function, which can enhance the user's experience. BRIEF DESCRIPTION OF THE DRAWINGS
[0017] In order to more clearly illustrate the technical solutions of the embodiments of the present invention, the accompanying drawings required for use in the description of the embodiments will be briefly introduced below. Obviously, the accompanying drawings described below are only some embodiments of the present invention. For ordinary technicians in this field, other accompanying drawings can be obtained based on these accompanying drawings without paying creative work.
[0018] Figure 1 The figure is a schematic structural diagram of a laminated glass in one embodiment of the present invention.
[0019] Figure 2 for Figure 1 Schematic diagram of the exploded structure of the optoelectronic display component in the laminated glass.
[0020] Figure 3 It is a schematic structural diagram of a laminated glass control system in another embodiment of the invention. DETAILED DESCRIPTION
[0021] The following will be combined with the drawings in the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
[0022] It should be noted that the terms "first", "second", "one side", "external", "internal", etc. in the specification and claims of the present invention are used to distinguish similar objects, and are not necessarily used to describe a specific order or sequence. It should be understood that the terms used in this way can be interchangeable where appropriate, so that the embodiments of the present invention described herein can be implemented in an order other than those illustrated or described herein. In addition, the term "comprises" and any of their variations are intended to cover non-exclusive inclusions, for example, a process, system, product or device that includes a series of steps or units is not necessarily limited to those steps or units that are clearly listed, but may include other steps or units that are not clearly listed or inherent to these processes, products or devices.
[0023] A laminated glass proposed in the following embodiment of the present invention has a plurality of first display lamps and a plurality of second display lamps with the same light emitting direction respectively arranged on two adjacent side surfaces of two glasses, and the projections of the plurality of first display lamps and the plurality of second display lamps on the second side surfaces are staggered with each other, thereby achieving high-definition display with high dot matrix density which is difficult to achieve without reducing the width of the conductive line in the prior art, thereby improving the density of the display lamps on the glass, increasing the display pixels of the display glass, and achieving high dot matrix density display of the display lamps.
[0024] See also Figure 1 , which shows a laminated glass 10 disclosed in an embodiment of the present invention. The laminated glass 10 includes, for example: a color-changing component 100 and a photoelectric display component 200 .
[0025] The color changing component 100 is used to achieve color change to improve the thermal insulation performance of the window glass. The photoelectric display component 200 is used to display information. The combination of the color changing component 100 and the photoelectric display component 200 constitutes the two sides of the laminated glass 10 relative to the external environment. For example, the laminated glass 10 is installed on the roof or the side of the wall, and one side of the color changing component 100 of the laminated glass 10 faces the external space, that is, it is used outdoors. One side of the photoelectric display component 200 of the laminated glass 10 faces the internal space, that is, it is used indoors. However, in the present embodiment, it is not limited to this, and can be set and used according to the actual scene.
[0026] Further, the color-changing component 100, for example, includes: a first target substrate 110, a second target substrate 130 and an electrolyte layer 120, and the electrolyte layer 120 is sandwiched between the first target substrate 110 and the second target substrate 130. The electrolyte layer 120, for example, includes: an organic solvent, a lithium-containing compound and a high molecular polymer. The optoelectronic display component 200, for example, includes: a third glass substrate 201, a fourth glass substrate 203 and a display lamp 202 sandwiched between the third glass substrate 201 and the fourth glass substrate 203. Among them, the third glass substrate 201 of the optoelectronic display component 200 is bonded to the second target substrate 130.
[0027] The first target substrate 110, the second target substrate 130 and the electrolyte layer 120 are combined to form a "sandwich" structure. The organic solvent is used to dissolve the organic polymer of the high molecular polymer, and specifically includes, for example, one or a combination of at least two solvents of propylene carbonate, ethylene carbonate, diethyl carbonate, ethyl methyl carbonate, dimethyl carbonate, methyl formate, methyl acrylate, methyl butyrate, and ethyl acetate. The lithium-containing compound specifically includes, for example, one or a combination of at least two of LiAsF6, LiPF6, LiBF4, CF3SO3Li, and LiClO4. The high molecular polymer specifically includes, for example, one or a combination of several of polypropylene carbonate, polyaniline, polyethylene oxide, polyacrylonitrile, polyvinylidene fluoride, polyvinylidene fluoride-hexafluoropropylene, polymethyl methacrylate, and polyvinyl chloride. The third glass substrate 201 and the fourth glass substrate 203 are, for example, float glass, ultra-white glass, high aluminum glass, medium aluminum glass, various colored glasses (such as gray glass, green glass, lake blue glass, etc.), PET (Polyethyleneterephthalate) film materials, etc. Figure 2 The display lamp 202 is, for example, a plurality of LED lamps, for example, including three kinds of lamp beads of red, green and blue, embedded between the third glass substrate 201 and the fourth glass substrate 203. Each display lamp 202 also includes an electrode pin. The plurality of LED lamps are connected to the conductive circuit 204 via the electrode pins, and one end of the conductive circuit 204 is connected to the controller 205 for control, wherein the controller 205 is, for example, an LED display driver chip, etc. It is worth mentioning that Figure 2 The relative position of the controller 205 and other structures shown is only for a better understanding of the present embodiment, and the present embodiment does not limit the specific position of the controller 205. In the present embodiment, the optoelectronic display assembly 200 is an existing structure, and the detailed arrangement of the display lamp and the glass substrate is not repeated here. The third glass substrate 201 and the second target substrate 130 are bonded by, for example, glue bonding, high temperature bonding, etc. in the prior art, which is not repeated here, as long as the two glass substrates are combined into one and are not easy to separate.
[0028] It should be noted that the specific film layer structure of the present invention can be understood as being composed of a color-changing component 100 and an optoelectronic display component 200. Considering the operation process of laser etching on the glass substrate for wiring, in order to avoid damage caused by etching on both sides of the glass substrate, when the two components (the color-changing component 100 and the optoelectronic display component 200 in the embodiment) are combined, one of the glass substrates at the combined film layer (the second glass substrate 134 and the third glass substrate 201 in the embodiment) is not reduced. In this embodiment, it is not limited to this. For example, the thickness of one of the glass substrates at the combined layer can be increased to reduce the use of one of the glass substrates.
[0029] Furthermore, the electrolyte layer 120 is a liquid electrolyte layer. The color-changing component 100 further includes, for example: a frame, which forms a receiving cavity with the first target substrate 110 and the second target substrate 130 to receive the liquid electrolyte layer.
[0030] The frame is, for example, a rectangular frame, which is conveniently mounted on the first target substrate 110 and the second target substrate 130. The size and shape of the frame are set according to the first target substrate 110 and the second target substrate 130, and are not limited here. The liquid electrolyte layer is accommodated in the accommodation cavity, for example, by injection, and injected between the first target substrate 110 and the second target substrate 130 for accommodation.
[0031] Furthermore, the electrolyte layer 120 further includes, for example: a curing agent, and the electrolyte layer 120 is a gel electrolyte layer or a solid electrolyte layer.
[0032] The curing agent is used to cure the electrolyte, and the curing agent includes, for example, an ultraviolet curing agent. When the electrolyte layer 120 is a colloidal electrolyte layer, for example, it is injected between the first target substrate 110 and the second target substrate 130 by perfusion, and then the colloidal electrolyte layer is irradiated with ultraviolet light to cure and adhere between the first target substrate 110 and the second target substrate 130. When the electrolyte layer 120 is a solid electrolyte layer, it needs to be heated to adhere between the first target substrate 110 and the second target substrate 130.
[0033] In summary, the electrolyte layer 120 is an ion conductor electrolyte layer, and the beneficial effect achieved by the mixed selection of its materials is that the discoloration stability of the laminated glass 10 can be ensured. In addition, the state of the electrolyte layer 120 includes, for example: liquid, colloidal and solid, which can be understood here as different viscosities of the electrolyte. The state of the electrolyte layer 120 and the selection and mixing of materials in this embodiment are not limited to this, and its state can be designed according to actual needs.
[0034] Further, the first target substrate 110, for example, includes: a first glass substrate 111, a first conductive layer 112, and a main color-changing layer 113. The first conductive layer 112 is located on the first glass substrate 111. The main color-changing layer 113 is located on the side of the first conductive layer 112 away from the first glass substrate 111. The second target substrate 130, for example, includes: a second glass substrate 134, a second conductive layer 133, and an auxiliary color-changing layer 132. The second conductive layer 133 is located on the second glass substrate 134. The auxiliary color-changing layer 132 is located on the side of the second conductive layer 133 away from the second glass substrate 134, the electrolyte layer 120 is located between the main color-changing layer 113 and the auxiliary color-changing layer 132, and the third glass substrate 201 of the optoelectronic display component 200 is bonded to the second glass substrate 134 of the second target substrate 130.
[0035] The first glass substrate 111 and the second glass substrate 134 are, for example, float glass, ultra-white glass, high aluminum glass, medium aluminum glass, various colored glasses (such as gray glass, green glass, lake blue glass, etc.), PET (Polyethyleneterephthalate) film materials, etc. In addition, one side of the first glass substrate 111 faces the outside, and the entire color-changing component (100) faces the external space, such as the outdoors, and light radiation is reduced by color change to improve the thermal insulation performance of the glass.
[0036] The materials of the first conductive layer 112 and the second conductive layer 133 are, for example, selected from semiconductor oxide materials, metal materials or organic conductive materials. The semiconductor oxide material is, for example, one of FTO (fluorine silicon oxide), ITO (indium tin oxide), IGZO (indium gallium zinc oxide), AZO (aluminum zinc oxide), GZO (gallium zinc oxide) or a combination of at least two of them, such as AZO and GZO, or a combination of three of them such as FTO (fluorine silicon oxide), ITO (indium tin oxide) and GZO (gallium zinc oxide), or even more combinations. The metal material is, for example, at least one of silver (Ag), gold (Au), copper (Cu), and aluminum (Al). The organic conductive material is, for example, at least one of polyacetylene, polypyrrole, polyaniline, and polythiophene. Of course, the first conductive layer 112 and the second conductive layer 133 can also be any combination of the above three types of materials, and the materials selected for the first conductive layer 112 and the second conductive layer 133 can be the same or different. The first conductive layer 112 and the second conductive layer 133 are deposited on the first glass substrate 111 and the second glass substrate 134 using semiconductor oxide material, metal material or organic conductive material as a coating material under magnetron sputtering conditions, for example.
[0037] The main color-changing layer 113 is a solar spectrum regulating functional layer. The material of the main color-changing layer 113 is, for example, selected from one or more oxides of W, Mo, No, Ti, and Ta. Specifically, the material of the main color-changing layer is, for example, WO3, WMoO x 、WNoO x , WMoTiO x 、WNbTaO x etc., wherein x represents the stoichiometric ratio of the oxygen element. The stoichiometric ratio of the oxide may be sufficient oxygen or insufficient oxygen. The main color-changing layer 113 is deposited on the first conductive layer 112 under magnetron sputtering conditions, for example, by using one or a combination of at least two of the oxides of W, Mo, Nb, Ti, and Ta as target materials.
[0038] The material of the auxiliary color-changing layer 132 is, for example, selected from oxides of at least two combinations of Ni, V, Co, Ir, Fe, and Mn. Specifically, the material of the auxiliary color-changing layer 132 can be, for example, NiVOx, NiCoO x 、NiIrO x 、NiFeO x Or a combination of three, or even more combinations. Wherein x represents the stoichiometric ratio of the oxygen element. The stoichiometric ratio of the oxide can be sufficient oxygen or insufficient oxygen. The auxiliary color-changing layer 132, for example, is deposited on the second conductive layer 133 under magnetron sputtering conditions by using one or a combination of at least two of the oxides of Ni, V, Co, Ir, Fe, and Mn as target materials.
[0039] Further, the thicknesses of the first glass substrate 111 , the first conductive layer 112 , the primary color-changing layer 113 , the second glass substrate 134 , the second conductive layer 133 , and the auxiliary color-changing layer 132 are at least partially the same.
[0040] The thickness of the first glass substrate 111 and the second glass substrate 134 are, for example, 0.02 mm and less than 2 mm. The thickness of the first conductive layer 112 and the second conductive layer 133 are, for example, greater than 10 nm and less than or equal to 300 nm. The thickness of the main color-changing layer 113 is, for example, greater than 30 nm and less than or equal to 500 nm. The thickness of the auxiliary color-changing layer 132 is, for example, greater than 10 nm and less than or equal to 300 nm. In this embodiment, it is not limited that they are at least partially the same, and they can also be different, and the specific setting can be based on actual conditions.
[0041] Furthermore, the first target substrate 110 further includes, for example, a first transition layer 114 located between the main color-changing layer 113 and the electrolyte layer 120 . The second target substrate 130 further includes, for example, a second transition layer 131 located between the auxiliary color-changing layer 132 and the electrolyte layer 120 .
[0042] The first transition layer 114 is a film layer formed by a chemical reaction after the electrolyte layer 120 and the main color-changing layer 113 are bonded together and heated. The second transition layer 131 is a film layer formed by a chemical reaction after the electrolyte layer 120 and the auxiliary color-changing layer 132 are bonded together and heated.
[0043] Specifically, the material of the first transition layer 114 depends on the materials of the main color-changing layer 113 and the electrolyte layer 120. The material of the second transition layer 131 depends on the materials of the auxiliary color-changing layer 132 and the electrolyte layer 120. For example, when the material of the main color-changing layer 113 is W oxide and the material of the auxiliary color-changing layer 132 is Ni oxide, after the Li compound in the electrolyte layer 120 reacts chemically with the oxides in the main color-changing layer 113 and the auxiliary color-changing layer 132, the first transition layer generated is LiWO salt and the second transition layer is LiNiO salt. The beneficial effect of setting this film layer generation in the present embodiment is that when the power is on, the movement of Li+ can be promoted, and the free extraction and insertion of Li+ can be realized, that is, the efficiency of color change is improved. In addition, it can also be understood that when the power is on, the amount of Li+ generated can be increased, so that only a small amount of charge is required to obtain a higher color change efficiency.
[0044] Furthermore, the electrolyte layer 120 , for example, includes: insulating spacers, so that the first target substrate 110 and the second target substrate 130 are spaced apart at a uniform distance.
[0045] Among them, the material of the insulating spacer is the insulating material of the prior art, such as porcelain, insulating extruded plastic, etc., which can play a supporting and spacing role between the first target substrate layer 110 and the second target substrate layer 130, and can make the electrolyte layer 120 have a uniform thickness between the first target substrate layer 110 and the second target substrate layer 130, so as to further make the glass discoloration uniform.
[0046] In summary, a laminated glass proposed in an embodiment of the present invention can achieve stable and efficient color change on one side of the laminated glass through a specific film layer structure to improve the insulation performance of the glass and the information display function on the other side, and in terms of overall functional realization, it can enhance the user experience.
[0047] See also Figure 3Another embodiment of the present invention provides a laminated glass control system 20, for example, comprising: a control device 21 and a laminated glass 10. The structure and function of the laminated glass 10 disclosed in this embodiment are as described in the above embodiment, and will not be repeated here. The control device 21 is, for example, a remote controller for use by a user. The control device 21 is provided with a function selection button for selecting the state presented on both sides of the laminated glass 10. The laminated glass 10 receives the corresponding control signal transmitted by the control device 21 and displays the state.
[0048] For example, the laminated glass 10 is installed on the roof, one side of the color-changing component 100 in the laminated glass 10 faces the outdoors, and the optoelectronic display component 200 in the laminated glass 10 faces the indoors. To adjust the transmittance of the color-changing component 100 to sunlight, the remote controller is operated to select the transmittance parameter, and the control device 21 transmits the corresponding transmittance parameter signal to the controller of the color-changing component 100 of the laminated glass 10. The controller of the color-changing component 100 of the laminated glass 10 receives the signal and controls the movement of Li+ in the laminated glass 10, promoting the free extraction or insertion of Li+ to change the color of the laminated glass 10 on the outdoor side. At the same time, the desired display content is selected through the remote controller, and the control device 21 transmits the corresponding display content signal to the controller of the optoelectronic display component 200 of the laminated glass 10. The controller of the optoelectronic display component 200 receives the display content signal to display the corresponding content on the indoor side of the laminated glass 10, wherein the controller of the color-changing component 100 mentioned is, for example, a single-chip microcomputer, and the controller of the optoelectronic display component 200 mentioned is, for example, a display driver chip.
[0049] In summary, the laminated glass system proposed in another embodiment of the present invention, by providing a control device connected to the laminated glass, can allow the user to independently select the color change parameters and display content of the laminated glass, and the operation is flexible, which can further enhance the user experience.
[0050] In addition, it can be understood that the aforementioned embodiments are only exemplary descriptions of the present invention. Under the premise that the technical features do not conflict, the structures do not contradict, and the purpose of the present invention is not violated, the technical solutions of the various embodiments can be arbitrarily combined and used in combination.
[0051] Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, rather than to limit it. Although the present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or make equivalent replacements for some of the technical features therein. However, these modifications or replacements do not deviate the essence of the corresponding technical solutions from the spirit and scope of the technical solutions of the embodiments of the present invention.
Claims
1. A laminated glass (10), characterized in that: include: A color changing component (100) and a photoelectric display component (200); The color-changing component (100) comprises: a first target substrate (110), a second target substrate (130), and an electrolyte layer (120) sandwiched between the first target substrate (110) and the second target substrate (130); The first target substrate (110) comprises: A first glass substrate (111); A first conductive layer (112) located on the first glass substrate (111); A main color-changing layer (113) is located on a side of the first conductive layer (112) away from the first glass substrate (111); The second target substrate (130) comprises: A second glass substrate (134); A second conductive layer (133) is located on the second glass substrate (134); an auxiliary color-changing layer (132), located on a side of the second conductive layer (133) away from the second glass substrate (134), wherein the electrolyte layer (120) is located between the main color-changing layer (113) and the auxiliary color-changing layer (132); The first target substrate (110) further comprises: a first transition layer (114) located between the main color-changing layer (113) and the electrolyte layer (120), wherein the first transition layer (114) is a film layer generated by a chemical reaction between the electrolyte layer (120) and the main color-changing layer (113) after being bonded together; The second target substrate (130) further comprises: a second transition layer (131) located between the auxiliary color-changing layer (132) and the electrolyte layer (120), wherein the second transition layer (131) is a film layer generated by a chemical reaction between the electrolyte layer (120) and the auxiliary color-changing layer (132) after being bonded together; The electrolyte layer (120) comprises: a lithium-containing compound, a high molecular polymer and an organic solvent; The lithium-containing compound is specifically: one or a combination of at least two of LiAsF6, LiPF6, LiBF4, CF3SO3Li and LiClO4; The high molecular polymer is specifically: one or a combination of polypropylene carbonate, polyaniline, polyethylene oxide, polyacrylonitrile, polyvinylidene fluoride, polyvinylidene fluoride-hexafluoropropylene, polymethyl methacrylate, polyvinyl chloride; The organic solvent is used to dissolve the organic polymer of the high molecular weight polymer, specifically: one or a combination of at least two solvents of propylene carbonate, ethylene carbonate, diethyl carbonate, ethyl methyl carbonate, dimethyl carbonate, methyl formate, methyl acrylate, methyl butyrate, and ethyl acetate; The optoelectronic display assembly (200) comprises: a third glass substrate (201), a fourth glass substrate (203), and a display light (202) sandwiched between the third glass substrate (201) and the fourth glass substrate (203); wherein the third glass substrate (201) of the optoelectronic display assembly (200) is bonded to the second glass substrate (134) of the second target substrate (130).
2. A laminated glass (10), characterized in that: include: A color changing component (100) and a photoelectric display component (200); The color-changing component (100) comprises: a first target substrate (110), a second target substrate (130), and an electrolyte layer (120) sandwiched between the first target substrate (110) and the second target substrate (130); The first target substrate (110) comprises: A first glass substrate (111); A first conductive layer (112) located on the first glass substrate (111); A main color-changing layer (113), located on the first conductive layer (112); The second target substrate (130) comprises: A second glass substrate (134); A second conductive layer (133) is located on the second glass substrate (134); An auxiliary color-changing layer (132) is located on the second conductive layer (133), wherein the electrolyte layer (120) is located between the main color-changing layer (113) and the auxiliary color-changing layer (132); The color-changing component (100) further comprises a first transition layer (114) and a second transition layer (131), wherein the first transition layer (114) is located between the main color-changing layer (113) and the electrolyte layer (120), and the first transition layer (114) is a film layer generated by a chemical reaction between the electrolyte layer (120) and the main color-changing layer (113) after being bonded together, and the second transition layer (131) is located between the electrolyte layer (120) and the auxiliary color-changing layer (132), and the second transition layer is a film layer generated by a chemical reaction between the electrolyte layer (120) and the auxiliary color-changing layer (132) after being bonded together; The electrolyte layer (120) comprises: an organic solvent, a lithium-containing compound and a high molecular polymer; The optoelectronic display assembly (200) comprises: a third glass substrate (201), a fourth glass substrate (203), and a display light (202) sandwiched between the third glass substrate (201) and the fourth glass substrate (203); wherein the third glass substrate (201) of the optoelectronic display assembly (200) is bonded to the second target substrate (130).
3. The laminated glass according to claim 2, characterized in that: The lithium-containing compound is specifically: one or a combination of at least two of LiAsF6, LiPF6, LiBF4, CF3SO3Li and LiClO4; The high molecular polymer is specifically: one or a combination of polypropylene carbonate, polyaniline, polyethylene oxide, polyacrylonitrile, polyvinylidene fluoride, polyvinylidene fluoride-hexafluoropropylene, polymethyl methacrylate, polyvinyl chloride; The organic solvent includes: one or a combination of at least two of propylene carbonate, ethylene carbonate, diethyl carbonate, ethyl methyl carbonate, dimethyl carbonate, methyl formate, methyl acrylate, methyl butyrate, and ethyl acetate.
4. The laminated glass according to claim 2, characterized in that: The electrolyte layer (120) is a liquid electrolyte layer; the color-changing component (100) further comprises: a frame, which forms a receiving cavity with the first target substrate (110) and the second target substrate (130) to receive the liquid electrolyte layer.
5. The laminated glass according to claim 2, characterized in that: The electrolyte layer (120) further comprises: a curing agent; and the electrolyte layer (120) is a gel electrolyte layer or a solid electrolyte layer.
6. The laminated glass according to claim 2, characterized in that: The third glass substrate (201) of the optoelectronic display component (200) is bonded to the second glass substrate (134) of the second target substrate (130).
7. The laminated glass according to claim 6, characterized in that: The thicknesses of the first glass substrate (111), the first conductive layer (112), the primary color-changing layer (113), the second glass substrate (134), the second conductive layer (133), and the auxiliary color-changing layer (132) are at least partially the same.
8. The laminated glass according to claim 2, characterized in that: The electrolyte layer (120) further comprises: an insulating spacer, so that the first target substrate (110) and the second target substrate (130) are spaced at a uniform distance.
9. A laminated glass control system (20), characterized in that: include: The laminated glass (10) according to any one of claims 1 to 8; A control device (21) is connected to the color changing component (100) and the photoelectric display component (200) of the laminated glass (10) to control the color changing of the color changing component (100) and the display information of the photoelectric display component (200).
