一种聚醚酯多元醇的合成工艺及设备

By designing a series reaction system of transesterification reactor, deep esterification reactor and polycondensation reactor, the problem of large-scale preparation of polyether ester polyols was solved, and low-cost spandex production was achieved.

CN116808947BActive Publication Date: 2026-07-17ZHENGZHOU ZHONGYUAN SPANDEX ENG TECH CO LTD

Patent Information

Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
ZHENGZHOU ZHONGYUAN SPANDEX ENG TECH CO LTD
Filing Date
2023-07-03
Publication Date
2026-07-17

AI Technical Summary

Technical Problem

The lack of existing technologies for the large-scale industrial preparation of polyether ester polyols limits their application in the spandex industry, resulting in high production costs.

Method used

A process and equipment for synthesizing polyether ester polyols are provided. By designing a series of transesterification esterification reactors, deep esterification reactors and polycondensation reactors, combined with a catalyst tank and a vacuum system, a staged esterification and polycondensation reaction is carried out to prepare polyether ester polyols with aromatic group-polyether block structure.

Benefits of technology

This has enabled the large-scale industrial production of polyether ester polyols, reducing the production cost of spandex and meeting the elastic recovery performance and modulus requirements of spandex.

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Abstract

本发明提供了一种聚醚酯多元醇的合成工艺及设备,通过依次设置的酯交换酯化釜,深度酯化釜和缩聚釜,以及过滤器和热交换器等设备,将含有芳族基团的原料和聚醚二醇原料依次连续通过上述设备,上述物料逐步经过相应的初步酯交换 / 酯化反应、深度酯化反应和缩聚反应,经过滤和热交换后,得到特定结构的聚醚酯多元醇。本发明将特定投料比的芳族二元酸或含芳族二元酸酯类物质与聚醚多元醇的酯化或酯交换反应分成不同条件的三个阶段,使得反应更加完全的同时,提高了反应效率,能够大规模工业化进行氨纶用聚醚酯多元醇的生产,制得的聚醚酯多元醇作为聚四氢呋喃醚二醇的替代品,可显著降低氨纶的生产成本。
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