Method for preparing NaP type molecular sieve by using calcined coal series kaolin

Abstract

The invention belongs to the field of coal solid waste resource utilization, and relates to a method for preparing a NaP type molecular sieve by utilizing kaolinite rock type coal gangue. The method comprises the following steps: 1) crushing and grinding blocky kaolinite rock type coal gangue into powder; 2) roasting and activating the coal gangue powder to obtain metakaolin; 3) mixing and stirring metakaolin, sodium hydroxide, a silicon source and deionized water to obtain an initial solution; 4) standing and aging the initial solution to obtain a precursor solution; 5) performing dynamic hydrothermal crystallization treatment on the precursor solution to obtain crystals; and 6) washing, neutralizing, centrifuging and drying the crystal to obtain the NaP type molecular sieve. The kaolinite rock type coal gangue is used as a raw material to replace a traditional chemical raw material required by molecular sieve synthesis, and resource utilization of aluminosilicate solid waste is promoted. According to the method, seed crystals or guiding agents are not required to be added in the molecular sieve crystallization process, and special crystallization methods such as microwaves and ultrasound are also not required, so that the process is simple, the cost is low, and the method is environment-friendly.