Spinel oxygen carrier with capability of deeply releasing lattice oxygen as well as preparation method and application of spinel oxygen carrier

By doping Cu, Mn, Ni, Ca, and Sr elements into Fe2O3 oxygen carrier, a spinel oxygen carrier with deep release lattice oxygen capacity was prepared, which solved the problems of insufficient activity, serious surface carbon in the hydrogen production of chemical chains, and achieved efficient recycling of waste plastics and efficient preparation of high-purity hydrogen.

CN119660813APending Publication Date: 2025-03-21NANJING UNIV OF SCI & TECH
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Patent Information

Application Number
CN202411955029.5
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-12-27
Publication Date
2025-03-21

AI Technical Summary

Technical Problem

In the prior art, Fe2O3 oxygen carriers have problems such as insufficient activity, serious surface carbon and poor circulation stability in the hydrogen production of chemical chains, and lack applications for waste plastics.

Method used

By doping elements such as Cu, Mn, Ni, Ca, Sr, etc. into the metal iron-based oxygen carrier AFe2O4 with spinel-type structure, the multi-metal elements are used to show a dilution effect on the A-position atoms of the spinel-type oxygen carrier, and combined with the polymetal effect that promotes lattice oxygen release, a spinel oxygen carrier with deep release lattice oxygen capacity is prepared.

Benefits of technology

It has achieved efficient recycling and utilization of waste plastics and efficient preparation of high-purity hydrogen, overcomes the problems of insufficient activity of Fe2O3 oxygen carrier, serious carbon surface area and poor circulation stability, improves carbon conversion and hydrogen yield, and meets the requirements of industrial application.

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Abstract

The invention discloses a spinel oxygen carrier with the capability of deeply releasing lattice oxygen as well as a preparation method and application thereof, and belongs to the related technical field of hydrogen energy preparation. Elements such as Cu, Mn, Ni, Ca, Sr and the like are doped into a metal iron-based oxygen carrier AFe2O4 with a spinel type structure according to an equal molar ratio, a dilution effect is shown on A-site atoms of the spinel type oxygen carrier AFe2O4 by virtue of multiple metal elements, and a multi-metal effect for promoting lattice oxygen release is combined. In addition, the spinel type oxygen carrier (AFe2O4) has excellent adsorption capacity and cycling stability, and the novel oxygen carrier is applied to chemical looping hydrogen production (CLR) to realize recycling of waste plastics and efficient preparation of high-purity hydrogen. Therefore, the problems of insufficient activity, serious surface carbon deposition, poor cycling stability and the like of a pure Fe2O3 oxygen carrier in chemical looping hydrogen production (CLR) are solved.
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