Reaction tank, reaction control device and fresh-keeping equipment

Abstract

The utility model discloses a reaction tank, a reaction control device and fresh-keeping equipment, and relates to the technical field of fresh keeping. Wherein the reaction tank comprises a reaction tank body shell, a reaction tank body and a reaction tank cover; a reaction tank inner container is arranged in the reaction tank body shell, a refrigeration heat transfer mechanism is arranged in the reaction tank inner container, and a gap between the reaction tank inner container and the refrigeration heat transfer mechanism is a hydrate generation chamber; a gap between the reaction tank body shell and the reaction tank liner is a cooling capacity collecting layer; wherein the hydrate generation chamber is used for obtaining cold energy, water and carbon dioxide by utilizing the refrigeration heat transfer mechanism and a mixture of water and carbon dioxide in a set proportion; the reaction tank inner container is respectively connected with the humidity discharge branch and the carbon dioxide concentration discharge branch, and the cooling capacity collection layer is connected with the cooling capacity discharge branch. The problem that the temperature, humidity and carbon dioxide for preservation cannot be coordinated and synchronized due to the fact that cooling capacity, water and carbon dioxide are difficult to achieve at the same time is solved, and resource utilization of carbon dioxide is achieved.

Description

Technical Field

[0001] The utility model relates to the technical field of fresh-keeping, in particular to a reaction tank, a reaction control device and fresh-keeping equipment. Background Art

[0002] Fresh-keeping technology is a technology that prolongs the freshness of fruits and vegetables. Currently, common fresh-keeping technologies include refrigeration, freezing, edible film, controlled atmosphere, biological, and chemical preservation.

[0003] Refrigerated preservation technology is a technology that prolongs the shelf life and maintains freshness of food by storing it in a low-temperature environment. The shelf life is usually 5-7 days. Frozen preservation technology is a technology that uses equipment for refrigeration, which can be artificially controlled and maintain a stable low temperature. The shelf life is usually 6-8 days. Edible film preservation technology is a technology that forms a protective layer on the surface of food to block the entry of air, moisture and bacteria, thereby extending the shelf life of food. The shelf life is 2-3 days. Controlled atmosphere preservation technology is a method of extending the shelf life of food by adjusting the gas composition in the atmosphere around the food. The shelf life is 5-7 days. Biological preservation technology is a technology that uses the active ingredients of microorganisms, enzymes or other organisms to delay oxidation and extend the shelf life of food. The shelf life is 10-13 days. Chemical preservation technology is the use of chemical preservatives for preservation, and the shelf life is 3-5 days.

[0004] Refrigerated preservation consumes a lot of energy, has a short preservation time, and cannot maintain appropriate humidity and carbon dioxide concentration; edible film has a short preservation time and poor effect; controlled atmosphere preservation has high requirements for gas ratio and sealing of packaging materials, and the cost is relatively high; biological preservation has high requirements for microorganisms, and although the preservation time is long, the cost is high. Although chemical preservation is simple to operate, it is easy to cause chemical residues, affect human health, and pollute the environment. Moreover, none of the above technologies can coordinate the control of temperature, humidity, and carbon dioxide concentration to keep crops in the best preservation state.

[0005] From the above, it can be seen that the current mainstream solutions have obvious shortcomings and cannot be fully commercialized and promoted. No single preservation method can meet the existing preservation requirements. There is an urgent need for a preservation (method) device that can coordinate the control of temperature, humidity, and carbon dioxide concentration, and a material that can simultaneously meet the coordinated control of temperature, humidity, and carbon dioxide concentration, and that has the practical advantages of comprehensive safety, greenness, high efficiency, low cost, and long preservation time to steadily promote the development of the preservation industry.

[0006] The existing technology has at least the following technical defects: 1. Limitation of coordinated control of temperature, humidity and carbon dioxide concentration: The existing preservation technology cannot achieve coordinated control of temperature, humidity and carbon dioxide concentration, and the preservation effect is poor and the efficiency is low. 2. Limitation of residual hazardous substances: Some chemical preservatives and additives may remain in food, posing certain safety hazards and causing consumer concerns. 3. Limitation of high preservation cost: The materials used in single atmosphere preservation technology and biological preservation technology are expensive and costly, and are not suitable for large-scale batch preservation. Utility Model Content

[0007] In view of this, the utility model provides a technical solution of a reaction tank, a reaction control device and a fresh-keeping equipment.

[0008] In a first aspect, the utility model provides a reaction tank, comprising: a reaction tank shell; a reaction tank liner is arranged in the reaction tank shell, a refrigeration heat transfer mechanism is arranged in the reaction tank liner, a gap between the reaction tank liner and the refrigeration heat transfer mechanism is a hydrate generation chamber; a gap between the reaction tank shell and the reaction tank liner is a cold energy collection layer;

[0009] Among them, the hydrate generation chamber is used to obtain cold, water and carbon dioxide by utilizing the refrigeration heat transfer mechanism and a mixture of water and carbon dioxide in a set proportion; the inner liner of the reaction tank is respectively connected to the humidity discharge branch and the carbon dioxide concentration discharge branch, and the cold collection layer is connected to the cold discharge branch.

[0010] Preferably, the refrigeration heat transfer mechanism includes: a spiral fin and a finned coil arranged outside the spiral fin; wherein one end of the spiral fin and the finned coil are respectively connected to the refrigerant inlet and the refrigerant outlet, and the other end of the spiral fin is connected to the other end of the finned coil.

[0011] Preferably, the refrigerant input port and the refrigerant output port connected to the refrigeration heat transfer mechanism are respectively provided with a refrigerant inlet check valve and a refrigerant outlet check valve for preventing the refrigerant from flowing back.

[0012] Preferably, the humidity discharge branch comprises: a water outlet, the water outlet is communicated with the reaction tank liner or the hydrate generation chamber, the water outlet is connected to one end of a liquid guide pipe, and the other end of the liquid guide pipe is connected to a liquid storage tank.

[0013] Preferably, the carbon dioxide concentration emission branch comprises: a carbon dioxide output port, the carbon dioxide output port being connected to the reaction tank liner or the hydrate formation chamber, the carbon dioxide output port being connected to one end of an air guide pipe, and the other end of the air guide pipe being connected to a gas storage tank.

[0014] Preferably, the cold energy discharge branch comprises: a cold energy output port, the cold energy output port is communicated with the cold energy collection layer, the cold energy output port is connected to one end of a cold energy conducting pipe, and the other end of the cold energy conducting pipe is connected to a cold storage tank.

[0015] Preferably, a fourth one-way valve is provided on the liquid guiding pipe of the humidity discharge branch for preventing the water generated in the hydrate formation chamber from flowing back into the hydrate formation chamber.

[0016] Preferably, a sixth one-way valve is provided on the gas guide pipe of the carbon dioxide concentration discharge branch for preventing the carbon dioxide generated in the hydrate formation chamber from flowing back into the hydrate formation chamber.

[0017] Preferably, a third one-way valve is provided on the cold conduction pipe of the cold discharge branch to prevent the cold generated in the hydrate generation chamber from flowing back to the cold collection layer; and a cold storage tank insulation layer is provided on the outside of the cold storage tank of the cold discharge branch.

[0018] Preferably, the liquid storage tank of the humidity discharge branch is also provided with a water delivery pipe; and / or, the gas storage tank of the carbon dioxide concentration discharge branch is also provided with a carbon dioxide delivery pipe; and / or, the cold storage tank of the cold discharge branch is also provided with a cold delivery pipe.

[0019] Preferably, the water delivery pipe connected to the liquid storage tank of the humidity discharge branch is provided with a second one-way valve for preventing the water in the liquid storage tank from flowing back to the liquid storage tank.

[0020] Preferably, the carbon dioxide delivery pipe connected to the gas tank of the carbon dioxide concentration emission branch is provided with a first one-way valve to prevent the carbon dioxide in the gas tank from flowing back to the gas tank.

[0021] Preferably, the cold transport pipe connected to the cold storage tank of the cold discharge branch is provided with an external one-way valve to prevent the cold in the cold storage tank from flowing back to the cold storage tank.

[0022] Preferably, an upper end cover of the reaction tank which can be opened and closed or fixedly connected is provided at the opening of the shell of the reaction tank body.

[0023] Preferably, a spiral outer coil is provided inside the body of the reaction tank shell, a refrigerant input port and a refrigerant output port are provided at both ends of the outer coil, and a porous medium insulation layer is provided in the gap between the spiral outer coils.

[0024] Preferably, it also includes: an inlet for a mixture of water and carbon dioxide communicated with the inner liner of the reaction tank or the hydrate formation chamber.

[0025] Preferably, the water and carbon dioxide mixture input port connected to the reaction tank liner or the hydrate formation chamber is provided with a raw material inlet one-way valve to prevent the water and carbon dioxide mixture from flowing back.

[0026] In a second aspect, the utility model provides a reaction control device, comprising: a reaction tank as described above; and the carbon dioxide concentration discharge branch, the humidity discharge branch and the cold discharge branch connected to the reaction tank are respectively provided with a carbon dioxide solenoid valve, a water solenoid valve and a cold solenoid valve that can control their opening / closing; and / or,

[0027] The air guide pipe of the carbon dioxide concentration discharge branch, the liquid guide pipe of the humidity discharge branch and the cold guide pipe of the cold discharge branch are respectively provided with a first valve or a first solenoid valve, a third valve or a third solenoid valve, and a second valve or a second solenoid valve that can control their opening / closing.

[0028] Preferably, it also includes: a controller;

[0029] Wherein, the control is respectively connected to the carbon dioxide solenoid valve, the water solenoid valve and the cold solenoid valve connector, and is used to respectively control the cold, water and carbon dioxide in the reaction tank to enter the cold discharge branch, the humidity discharge branch and the carbon dioxide concentration discharge branch respectively; and / or,

[0030] Among them, the control is respectively connected to the first valve or the first solenoid valve, the third valve or the third solenoid valve, the second valve or the second solenoid valve, and is used to respectively control the cold discharge branch, the humidity discharge branch and the carbon dioxide concentration discharge branch to discharge the cold, the water and the carbon dioxide.

[0031] In a third aspect, the utility model provides a fresh-keeping device, which uses or includes a reaction tank as described above to generate cold, water and carbon dioxide and / or uses or includes a reaction control device as described above to control the emission of cold, water and carbon dioxide generated by the reaction tank.

[0032] The utility model has at least the following beneficial effects:

[0033] The utility model provides a reaction tank, a reaction control device and a fresh-keeping device, so as to solve the problem that it is difficult to cool water and carbon dioxide at the same time, resulting in the inability to synchronize the temperature, humidity and carbon dioxide for fresh-keeping, and realizes the resource utilization of carbon dioxide. BRIEF DESCRIPTION OF THE DRAWINGS

[0034] The above and other purposes, features and advantages of the present invention will become more apparent through the following description of the embodiments of the present invention with reference to the accompanying drawings, in which:

[0035] Figure 1It is a top cross-sectional view corresponding to the reaction tank of the embodiment of the utility model;

[0036] Figure 2 It is a front cross-sectional view corresponding to the reaction tank of the embodiment of the utility model;

[0037] Figure 3 This is a cross-sectional view corresponding to the inner liner of the reaction tank of the embodiment of the utility model;

[0038] Figure 4 It is a schematic structural diagram corresponding to the spiral fin of the embodiment of the utility model;

[0039] Figure 5 It is a front cross-sectional view corresponding to the cold storage tank of the embodiment of the utility model;

[0040] Figure 6 It is a front cross-sectional view corresponding to the gas storage tank of the embodiment of the utility model;

[0041] Figure 7 It is a front cross-sectional view corresponding to the liquid storage tank of the embodiment of the utility model;

[0042] Figure 8 This is a front view corresponding to the shell of the fresh-keeping device of the embodiment of the utility model;

[0043] Fig. 9 This is a front cross-sectional view corresponding to the housing of the fresh-keeping device of the embodiment of the utility model;

[0044] Fig.10 It is a right side view corresponding to the shell of the fresh-keeping device of the embodiment of the utility model. DETAILED DESCRIPTION

[0045] The present invention is described below based on embodiments, but it is worth noting that the present invention is not limited to these embodiments. In the detailed description of the present invention below, some specific details are described in detail. However, for the parts that are not described in detail, those skilled in the art can also fully understand the present invention.

[0046] In addition, those skilled in the art should understand that the drawings are only provided to illustrate the purpose, features and advantages of the present invention, and the drawings are not actually drawn according to scale.

[0047] At the same time, unless the context clearly requires otherwise, the words "include", "comprises" and similar words throughout the specification and claims should be interpreted as inclusive rather than exclusive or exhaustive; that is, the meaning is "including but not limited to".

[0048] Figure 1 It is a top cross-sectional view corresponding to the reaction tank of the embodiment of the utility model; Figure 2It is a front cross-sectional view corresponding to the reaction tank of the embodiment of the utility model; Figure 3 1 is a cross-sectional view of the corresponding gallbladder in the reaction tank of the embodiment of the utility model. Figures 1 to 3 As shown, the reaction tank comprises: a reaction tank shell 1; a reaction tank liner 2 is arranged in the reaction tank shell 1, a refrigeration and heat transfer mechanism is arranged in the reaction tank liner 2, and the gap between the reaction tank liner 2 and the refrigeration and heat transfer mechanism is a hydrate generation chamber 37; the gap between the reaction tank shell 1 and the reaction tank liner 2 is a cold energy collection layer 29; wherein, the hydrate generation chamber 37 is used to obtain cold energy, water and carbon dioxide by using the refrigeration and heat transfer mechanism and a mixture of water and carbon dioxide in a set proportion; the reaction tank liner 2 is connected to the humidity discharge branch and the carbon dioxide concentration discharge branch respectively, and the cold energy collection layer 29 is connected to the cold energy discharge branch. This solves the problem that it is difficult to simultaneously obtain cold energy, water and carbon dioxide, resulting in the inability to coordinate and synchronize the temperature, humidity and carbon dioxide for preservation, and realizes the resource utilization of carbon dioxide.

[0049] Figure 4 Schematic diagram of the structure of the spiral fins of the embodiment of the utility model. Figures 1 to 4 As shown, the refrigeration heat transfer mechanism includes: a spiral fin 48, and a finned coil 9 arranged on the outside of the spiral fin 48; wherein, one end of the spiral fin 48 and the finned coil 9 are respectively connected to the refrigerant inlet 10 and the refrigerant outlet, and the other end of the spiral fin 48 is connected to the other end of the finned coil 9; wherein, the refrigerant inlet 10 and the refrigerant outlet connected to the refrigeration heat transfer mechanism are respectively provided with a refrigerant inlet check valve 44 and a refrigerant outlet check valve for preventing the refrigerant from flowing back.

[0050] Figure 5 1 is a front cross-sectional view corresponding to the cold storage tank of the utility model embodiment. Figure 1 and Figure 5 As shown, the cold energy discharge branch includes: a cold energy output port 5, the cold energy output port 5 is connected to the cold energy collection layer 29, the cold energy output port 5 is connected to one end of the cold energy conducting pipe 11, and the other end of the cold energy conducting pipe 11 is connected to the cold storage tank 15.

[0051] In the embodiment of the present disclosure, a third one-way valve 30 is provided on the cold conduction pipe 11 of the cold discharge branch to prevent the cold generated by the hydrate generation chamber 37 from flowing back to the cold collection layer 29; a cold storage tank insulation layer 46 is provided on the outer side of the cold storage tank 15 of the cold discharge branch. The cold storage tank 15 of the cold discharge branch is also provided with a cold transport pipe 24. The cold transport pipe 24 connected to the cold storage tank 15 of the cold discharge branch is provided with an external one-way valve 12 to prevent the cold in the cold storage tank 15 from flowing back to the cold storage tank 15.

[0052] In the embodiment of the present disclosure, a reaction tank upper end cover 3 which can be opened and closed or fixedly connected is provided at the opening of the reaction tank body shell 1 .

[0053] In the embodiment of the present disclosure, a spiral outer coil 36 is provided on the inner side of the body of the reaction tank shell 1, and a refrigerant inlet 38 and a refrigerant outlet 39 are respectively provided at both ends of the outer coil 36, and a porous medium insulation layer 4 is provided in the gap between the spiral outer coil 36.

[0054] In the embodiment of the present disclosure, it further comprises: a water and carbon dioxide mixture input port 8 connected to the reaction tank liner 2 or the hydrate generation chamber 37. The water and carbon dioxide mixture input port 8 connected to the reaction tank liner 2 or the hydrate generation chamber 37 is provided with a raw material inlet one-way valve 43 to prevent the water and carbon dioxide mixture from flowing back.

[0055] Figure 6 1 is a front cross-sectional view corresponding to the gas storage tank of the utility model embodiment. Figure 1 and Figure 6 As shown, the carbon dioxide concentration emission branch includes: a carbon dioxide output port 6, the carbon dioxide output port 6 is connected to the reaction tank inner liner 2 or the hydrate generation chamber 37, the carbon dioxide output port 6 is connected to one end of the gas guide pipe 13, and the other end of the gas guide pipe 13 is connected to the gas storage tank 35.

[0056] In the embodiment of the present disclosure, the gas conduit 13 of the carbon dioxide concentration discharge branch is provided with a sixth one-way valve 30-1 for preventing the carbon dioxide generated in the hydrate formation chamber 37 from flowing back to the hydrate formation chamber 37. The gas storage tank 35 of the carbon dioxide concentration discharge branch is also provided with a carbon dioxide delivery pipe 26. The carbon dioxide delivery pipe 26 connected to the gas storage tank 35 of the carbon dioxide concentration discharge branch is provided with a first one-way valve 14 for preventing the carbon dioxide in the gas storage tank 35 from flowing back to the gas storage tank 35.

[0057] Figure 7 1 is a front cross-sectional view corresponding to the liquid storage tank of the embodiment of the utility model. Figure 1 and Figure 7 As shown, the humidity discharge branch includes: a water outlet 7, the water outlet 7 is connected to the reaction tank liner 2 or the hydrate generation chamber 37, the water outlet 7 is connected to one end of the liquid guide pipe 16, and the other end of the liquid guide pipe 16 is connected to the liquid storage tank 34.

[0058] In the embodiment of the present disclosure, the liquid conduit 16 of the humidity discharge branch is provided with a fourth one-way valve 31 for preventing the water generated in the hydrate generation chamber 37 from flowing back to the hydrate generation chamber 37. The liquid storage tank 34 of the humidity discharge branch is also provided with a water delivery pipe 28. The water delivery pipe 28 connected to the liquid storage tank 34 of the humidity discharge branch is provided with a second one-way valve 17 for preventing the water in the liquid storage tank 34 from flowing back to the liquid storage tank 34.

[0059] In the embodiments of the present disclosure and other possible embodiments, the reaction tank comprises: a reaction tank body shell 1; a reaction tank liner 2 is arranged in the reaction tank body shell 1, a refrigeration and heat transfer mechanism is arranged in the reaction tank liner 2, and a gap between the reaction tank liner 2 and the refrigeration and heat transfer mechanism is a hydrate generation chamber 37; the gap between the reaction tank body shell 1 and the reaction tank liner 2 is a cold energy collection layer 29; wherein the hydrate generation chamber 37 is used to obtain cold energy, water and carbon dioxide by utilizing the refrigeration and heat transfer mechanism and a mixture of water and carbon dioxide in a set proportion; the reaction tank liner 2 is respectively connected to a humidity discharge branch and a carbon dioxide concentration discharge branch, and the cold energy collection layer 29 is connected to the cold energy discharge branch.

[0060] In the embodiment of the present disclosure and other possible embodiments, the refrigeration heat transfer mechanism includes: a spiral fin 48, and a finned coil 9 disposed outside the spiral fin 48; wherein one end of the spiral fin 48 and the finned coil 9 are respectively connected to the brine inlet 10 and the brine outlet, and the other end of the spiral fin 48 is connected to the other end of the finned coil 9. The brine inlet 10 and the brine outlet connected to the refrigeration heat transfer mechanism are respectively provided with a brine inlet check valve 44 and a brine outlet check valve to prevent the brine from flowing back.

[0061] Figure 6 1 is a front cross-sectional view corresponding to the cold storage tank of the utility model embodiment. Figure 3 and Figure 6 As shown, the cold energy discharge branch includes: a cold energy output port 5, the cold energy output port 5 is connected to the cold energy collection layer 29, the cold energy output port 5 is connected to one end of the cold energy conducting pipe 11, and the other end of the cold energy conducting pipe 11 is connected to the cold storage tank 15.

[0062] In the embodiments of the present disclosure and other possible embodiments, a third one-way valve 30 is provided on the cold conduction pipe 11 of the cold discharge branch to prevent the cold generated by the hydrate generation chamber 37 from flowing back to the cold collection layer 29; a cold storage tank insulation layer 46 is provided on the outer side of the cold storage tank 15 of the cold discharge branch.

[0063] Figure 71 is a front cross-sectional view corresponding to the gas storage tank of the utility model embodiment. Figure 3 and Figure 7 As shown, the carbon dioxide concentration emission branch includes: a carbon dioxide output port 6, the carbon dioxide output port 6 is connected to the reaction tank inner liner 2 or the hydrate generation chamber 37, the carbon dioxide output port 6 is connected to one end of the gas guide pipe 13, and the other end of the gas guide pipe 13 is connected to the gas storage tank 35.

[0064] In the embodiment of the present disclosure and other possible embodiments, a sixth one-way valve 30 - 1 is provided on the gas conduit 13 of the carbon dioxide concentration discharge branch to prevent the carbon dioxide generated in the hydrate formation chamber 37 from flowing back into the hydrate formation chamber 37 .

[0065] In the embodiments of the present disclosure and other possible embodiments, Figures 5 to 7 As shown, the liquid storage tank 34 of the humidity discharge branch is also provided with a water delivery pipe 28; the gas storage tank 35 of the carbon dioxide concentration discharge branch is also provided with a carbon dioxide delivery pipe 26, and the cold storage tank 15 of the cold discharge branch is also provided with a cold delivery pipe 24.

[0066] In the embodiments of the present disclosure and other possible embodiments, the water delivery pipe 28 connected to the liquid storage tank 34 of the humidity discharge branch is provided with a second one-way valve 17 for preventing the water in the liquid storage tank 34 from flowing back to the liquid storage tank 34; the carbon dioxide delivery pipe 26 connected to the gas tank 35 of the carbon dioxide concentration discharge branch is provided with a first one-way valve 14 for preventing the carbon dioxide in the gas tank 35 from flowing back to the gas tank 35; the cold delivery pipe 24 connected to the cold storage tank 15 of the cold discharge branch is provided with an external one-way valve 12 for preventing the cold in the cold storage tank 15 from flowing back to the cold storage tank 15.

[0067] In the embodiment of the present disclosure and other possible embodiments, a reaction tank upper end cover 3 that can be opened and closed or fixedly connected is provided at the opening of the reaction tank body shell 1; a spiral outer coil 36 is provided on the inner side of the body of the reaction tank body shell 1, and a refrigerant input port 38 and a refrigerant output port 39 are provided at both ends of the outer coil 36, and a porous medium insulation layer 4 is provided in the gap between the spiral outer coils 36; the reaction tank also includes: a water and carbon dioxide mixture input port 8 connected to the reaction tank inner liner 2 or the hydrate generation chamber 37.

[0068] In the embodiment of the present disclosure and other possible embodiments, the water and carbon dioxide mixture inlet 8 connected to the reaction tank liner 2 or the hydrate formation chamber 37 is provided with a raw material inlet one-way valve 43 to prevent the water and carbon dioxide mixture from flowing back.

[0069] Figure 8 1 is a front cross-sectional view corresponding to the liquid storage tank of the embodiment of the utility model. Figure 3 and 8 As shown, the humidity discharge branch includes: a water outlet 7, the water outlet 7 is connected to the reaction tank liner 2 or the hydrate generation chamber 37, the water outlet 7 is connected to one end of the liquid guide pipe 16, and the other end of the liquid guide pipe 16 is connected to the liquid storage tank 34.

[0070] In the embodiment of the present disclosure and other possible embodiments, a fourth one-way valve 31 is provided on the liquid conduit 16 of the humidity discharge branch to prevent the water generated in the hydrate generation chamber 37 from flowing back into the hydrate generation chamber 37 .

[0071] In the embodiment of the present disclosure and other possible embodiments, the reaction tank body shell 1 has a built-in reaction tank liner 2; the reaction tank liner 2 is provided with a cold output port 5, a carbon dioxide output port 6, a water output port 7, a water and carbon dioxide 1:175 mixture input port 8 and a coolant input port 10.

[0072] In the embodiment of the present disclosure and other possible embodiments, the cold output port 5 is connected to the cold storage tank 15 at the entrance of the cold storage tank 15 through a pipeline passing through the porous medium insulation layer 4, the first valve 40, the cold conduction pipeline 11 and the third one-way valve 30, and the cold storage tank 15 is connected to the outlet of the cold storage tank 15 in sequence with the cold solenoid valve 21 and the external one-way valve 12, the cold delivery pipe 24 and the cold uniform release pipe 25; the carbon dioxide output port 6 is connected to the outside in sequence with the second valve 41, the gas conduction pipeline 13 and the sixth one-way valve 30-1 is connected to the gas tank 35 at the gas tank entrance, and the gas tank 35 outlet is connected to the carbon dioxide solenoid valve 22, the first one-way valve 14, the carbon dioxide delivery pipe 26 and the gas uniform release pipe 27 in sequence; the water output port 7 is connected to the third valve 42, the liquid guide pipe 16 and the fourth one-way valve 31 in sequence, and is connected to the liquid tank 34 at the liquid tank entrance, and the liquid tank 34 outlet is connected to the water solenoid valve 23, the second one-way valve 17, the water delivery pipe 28 and the atomizer 32 in sequence.

[0073] In the embodiment of the present disclosure and other possible embodiments, the reaction tank inner tank 2 has a built-in finned coil 9, one end of the finned coil is connected to the coolant inlet 10, then spirals down around the internal spiral fin 48, connected to the bottom end of the spiral fin 48, and then passes through the top end of the spiral fin 48 to connect to the coolant inlet 10 to form a finned coil.

[0074] In the embodiment of the present disclosure and other possible embodiments, a cold collection layer 29 and a porous medium insulation layer 4 are sequentially arranged outside the reactor liner 2. The porous medium insulation layer 4 is between the cold collection layer 29 and the reactor body shell 1, and the outer peripheral coil 36 is evenly embedded inside the porous medium insulation layer 4. The outer peripheral coil 36 is connected to the refrigerant input port 38 at one end and the refrigerant output port 39 at the other end, and is externally connected to a refrigeration unit; the finned coil 9 has a first interface transition 9-1 and a second interface transition 9-2 at the top and bottom, respectively, and the finned coil is introduced into the coolant input port 10 and the coolant output port respectively; the spiral fin 48 is formed by a plurality of fin segments such as the first spiral fin segment 48-1 and the second spiral fin segment 48-2, which are spirally bent and connected, and the pipes connected to the coolant flow inside the spiral fin can increase the contact surface and accelerate the reaction rate.

[0075] In the embodiment of the present disclosure and other possible embodiments, the peripheral coil 36 and the finned coil 9 have the following functions: 1. The peripheral coil can increase the heat transfer surface area of ​​the porous medium in the porous medium insulation layer 4, and the finned coil can increase the heat transfer surface area in the hydrate generation room 37, improve the heat transfer efficiency, and enable the porous medium and the hydrate generation room to transfer heat and cool more quickly, shortening the time for carbon dioxide hydrate generation and decomposition; 2. The peripheral coil is used to enhance the strength and rigidity of the porous medium material in the porous medium layer 4, and improve the stability and bearing capacity of the structure. Among them, the peripheral coil is externally connected to the refrigeration unit, and carbon dioxide is injected into the equipment by the compressor.

[0076] The present disclosure also proposes a reaction control device, comprising: a reaction tank as described above, wherein the carbon dioxide concentration discharge branch, the humidity discharge branch and the cold capacity discharge branch connected to the reaction tank are respectively provided with a carbon dioxide solenoid valve 22, a water solenoid valve 23 and a cold capacity solenoid valve 21 which can control their opening / closing; and / or, the air guide pipe 13 of the carbon dioxide concentration discharge branch, the liquid guide pipe 16 of the humidity discharge branch and the cold capacity guide pipe 11 of the cold capacity discharge branch are respectively provided with a first valve 40 or a first solenoid valve, a third valve 42 or a third solenoid valve, and a second valve 41 or a second solenoid valve which can control their opening / closing.

[0077] In an embodiment of the present disclosure, the reaction control device further includes: a controller; wherein the controller is respectively connected to the carbon dioxide solenoid valve 22, the water solenoid valve 23 and the cold solenoid valve 21, and is used to respectively control the cold, water and carbon dioxide in the reaction tank to enter the cold discharge branch, the humidity discharge branch and the carbon dioxide concentration discharge branch respectively; and / or, wherein the controller is respectively connected to the first valve 40 or the first solenoid valve, the third valve 42 or the third solenoid valve, the second valve 41 or the second solenoid valve, and is used to respectively control the cold discharge branch, the humidity discharge branch and the carbon dioxide concentration discharge branch to discharge the cold, the water and the carbon dioxide.

[0078] In the embodiments of the present disclosure and other possible embodiments, the reaction control device includes: a controller; and a cold discharge branch, a humidity discharge branch, and a carbon dioxide concentration discharge branch respectively connected to the controller; the cold discharge branch, the humidity discharge branch, and the carbon dioxide concentration discharge branch are also respectively connected to a reaction tank for generating cold, water, and carbon dioxide; wherein the controller is used to respectively control the cold, water, and carbon dioxide in the reaction tank to enter the cold discharge branch, the humidity discharge branch, and the carbon dioxide concentration discharge branch, and / or respectively control the cold discharge branch, the humidity discharge branch, and the carbon dioxide concentration discharge branch to discharge the cold, water, and carbon dioxide. This solves the problem of difficult control of temperature, humidity, and carbon dioxide in the fresh-keeping environment.

[0079] In the embodiments of the present disclosure and other possible embodiments, the controller may be configured as one or more application-specific integrated circuits (ASICs), digital signal processors (DSPs), digital signal processing devices (DSPDs), programmable logic devices (PLDs), field programmable gate arrays (FPGAs), controllers, microcontrollers, single-chip microcomputers, programmable logic controllers (PLCs), microprocessors, etc. For example, the controller may be configured as a single-chip microcomputer of model STC89751.

[0080] Meanwhile, in the embodiments of the present disclosure and other possible embodiments, the controller may also be configured as a terminal device. For example, the terminal device may be a user equipment (UE), a mobile device, a user terminal, a terminal, a cellular phone, a cordless phone, a personal digital assistant (PDA), a handheld device, a computing device, a vehicle-mounted device, a wearable device, etc.

[0081] In an embodiment of the present disclosure, the controller includes: a memory and a processor connected to the memory; the memory is used to preset and store a set temperature, a set humidity and a set carbon dioxide concentration; the processor is used to control the cold, water and carbon dioxide in the reaction tank to enter the cold discharge branch, the humidity discharge branch and the carbon dioxide concentration discharge branch respectively according to the set temperature, the set humidity and the set carbon dioxide concentration, and / or control the cold discharge branch, the humidity discharge branch and the carbon dioxide concentration discharge branch to discharge the cold, the water and the carbon dioxide respectively.

[0082] In the embodiments of the present disclosure and other possible embodiments, it also includes: a temperature sensor, a humidity sensor and a carbon dioxide concentration detection sensor arranged in the fresh-keeping environment; the temperature sensor, the humidity sensor and the carbon dioxide concentration detection sensor of the fresh-keeping environment are used to retrieve the temperature, humidity and carbon dioxide concentration of the fresh-keeping environment, respectively.

[0083] In the embodiments of the present disclosure and other possible embodiments, the processor is used to control the cold, water and carbon dioxide in the reaction tank to enter the cold discharge branch, the humidity discharge branch and the carbon dioxide concentration discharge branch respectively according to the temperature, humidity and carbon dioxide concentration of the fresh-keeping environment and the set temperature, the set humidity and the set carbon dioxide concentration, and / or control the cold discharge branch, the humidity discharge branch and the carbon dioxide concentration discharge branch to discharge the cold, the water and the carbon dioxide according to the temperature, humidity and carbon dioxide concentration of the fresh-keeping environment and the set temperature, the set humidity and the set carbon dioxide concentration.

[0084] For example, if the temperature of the fresh-keeping environment is lower than the set temperature, the controller or the processor of the controller controls the cold in the reaction tank to enter the cold discharge branch and / or controls the cold discharge branch to discharge. For another example, if the humidity of the fresh-keeping environment is lower than the set humidity, the controller or the processor of the controller controls the water in the reaction tank to enter the humidity discharge branch and / or controls the humidity discharge branch to discharge. For another example, if the carbon dioxide concentration of the fresh-keeping environment is lower than the set carbon dioxide concentration, the controller or the processor of the controller controls the cold in the reaction tank to enter the carbon dioxide concentration discharge branch and / or controls the carbon dioxide concentration discharge branch to discharge.

[0085] In the embodiments of the present disclosure and other possible embodiments, the memory can be implemented by any type of volatile or non-volatile storage device or a combination thereof, such as static random access memory (SRAM), electrically erasable programmable read-only memory (EEPROM), erasable programmable read-only memory (EPROM), programmable read-only memory (PROM), read-only memory (ROM), magnetic memory, flash memory, magnetic disk or optical disk. At the same time, those skilled in the art can configure the set temperature, the set humidity and the set carbon dioxide concentration according to the needs of the fresh-keeping environment.

[0086] In the embodiments of the present disclosure and other possible embodiments, the controller or the processor of the controller may also operate based on an operating system stored in the memory, such as Windows ServerTM, Mac OS XTM, UnixTM, LinuxTM, FreeBSDTM or the like.

[0087] The reaction tank in the embodiment of the present disclosure has three control modules (branches) outside, including a cooling control module (cooling discharge branch), a carbon dioxide concentration control module (carbon dioxide concentration discharge branch) and a humidity control module (humidity discharge branch).

[0088] In the embodiments of the present disclosure and other possible embodiments, the cold energy control module: that is, the cold energy collection layer 29 is externally wrapped in the reaction tank inner tank 2, collects the cold energy generated by the decomposition of carbon dioxide hydrate, and transports the cold energy to the cold storage tank 15 through a pipeline passing through the porous medium insulation layer 4, the first valve 40, the cold energy conduction pipeline 11 and the third one-way valve 30. According to external needs, the cold storage tank releases the stored cold energy, which is output through the cold energy solenoid valve 21 and the external one-way valve 12 connected to the cold storage tank for adjusting the temperature of the external environment.

[0089] In the embodiment of the present disclosure and other possible embodiments, the first valve 40 and the third one-way valve 30 are detachably connected; the finned coil 9 is located between the hydrate generation room 37, spirally wrapped, and the refrigerant is injected through the refrigerant inlet 10; the outer coil 36 is evenly embedded in the porous medium insulation layer 4 and is completely wrapped by the porous medium insulation layer 4; the outer coil 36 is connected to the refrigerant inlet 38 and the refrigerant outlet 39, and is externally connected to a refrigeration unit.

[0090] In the embodiment of the present disclosure and other possible embodiments, the cold storage tank 15 is located outside the reaction tank, inside the entire device, and the stored cold energy is input from the cold energy collection layer 29 through the cold energy conduction pipe 11 and the third one-way valve 30.

[0091] In the embodiment of the present disclosure and other possible embodiments, the porous medium insulation layer 4 is located between the cold collection layer 29 and the reaction tank shell 1 to maintain a suitable temperature during the generation and storage of carbon dioxide hydrate.

[0092] In the embodiment of the present disclosure and other possible embodiments, the finned coil 9 is located between the inner tank 2 of the reaction tank, spirally wrapped, and a coolant input port 10 is provided at the top of the coil fin.

[0093] In the embodiment of the present disclosure and other possible embodiments, the cold storage tank 15 is used to store cold energy, and the external cold energy output port 5 of the cold energy collection layer 29 is provided with a cold energy pipe 11 connected to the third one-way valve 30 to transport cold energy to the cold storage tank 15, and the cold storage tank 15 is sequentially connected to the cold energy solenoid valve 21, the external one-way valve 12 and the cold energy delivery pipe 24, and the cold energy pipe 11 and the external one-way valve 12 are made of aluminum alloy, and the cold energy pipe 11 is closely attached to the cold energy collection layer 29. Wherein, the connection is a fixed connection that can be detached.

[0094] In the embodiments of the present disclosure and other possible embodiments, the carbon dioxide concentration control module: that is, the carbon dioxide output port 6 on the inner shell of the reaction tank is connected to the gas guide pipe 13, the second valve 41 and the sixth one-way valve 30-1 in sequence, and the carbon dioxide generated by the decomposition of carbon dioxide hydrate is transported to the gas storage tank 35. The gas storage tank 35 is connected to the carbon dioxide solenoid valve 22 and the first one-way valve 14 in sequence. According to the needs of the outside world, the gas storage tank releases the stored carbon dioxide and outputs it through the first one-way valve 14 connected to the gas storage tank, which is used to adjust the carbon dioxide concentration of the external environment, inhibit plant aerobic respiration, and achieve a preservation effect.

[0095] In the embodiment of the present disclosure and other possible embodiments, the second valve 41 and the third one-way valve 30 are detachably connected; the gas storage tank 35 is located outside the reaction tank, inside the entire device, and the stored carbon dioxide is produced by the decomposition of carbon dioxide hydrate in the reaction tank and is transported to the gas storage tank 35 through the fifth one-way valve 33.

[0096] In the embodiment of the present disclosure and other possible embodiments, the air guide pipe 13 and the first one-way valve 14 are made of aluminum alloy, and the air guide pipe 13 passes through the upper end cover 3 of the reaction tank, and the air guide pipe 13 deviates from the center of the circle and approaches the inner container of the reaction tank. The connection is a fixed connection that can be detached.

[0097] In the embodiments of the present disclosure and other possible embodiments, the humidity control module: that is, the water outlet 7 on the inner tank of the reaction tank is connected to the liquid guide pipe 16, the third valve 42 and the fourth one-way valve 31 in sequence, and the water generated by the decomposition of carbon dioxide hydrate is transported to the liquid storage tank 34 through the pressure inside the reaction tank. The liquid storage tank 34 is connected to the water solenoid valve 23, the second one-way valve 17 and the water delivery pipe 28 in sequence. According to the needs of the outside world (fresh-keeping environment), the liquid storage tank releases the stored water and outputs it through the second one-way valve 17 connected to the liquid storage tank, which is used to adjust the humidity of the external environment and maintain better fresh-keeping conditions.

[0098] In the embodiment of the present disclosure and other possible embodiments, the third valve 42 and the fourth one-way valve 31 are detachably connected; the liquid storage tank 34 is located outside the reaction tank, inside the entire device, and the stored water is produced by the decomposition of carbon dioxide hydrate in the reaction tank, and is transported to the liquid storage tank through the second one-way valve 17. The liquid guide pipe 16 and the second one-way valve 17 are made of aluminum alloy, and the liquid guide pipe 16 passes through the upper end cover 3 of the reaction tank, and the liquid guide pipe 16 deviates from the center of the circle and approaches the inner tank of the reaction tank. Among them, the connection is a fixed connection that can be detached.

[0099] In the embodiment of the present disclosure and other possible embodiments, the cooling capacity control module, the carbon dioxide concentration control module and the humidity control module are all operated after receiving the feedback signal from the intelligent control device.

[0100] In an embodiment of the present disclosure, a fresh-keeping device is also proposed, which uses or includes a reaction tank as described above to generate cold, water and carbon dioxide and / or uses or includes a reaction control device as described above to control the emission of cold, water and carbon dioxide generated by the reaction tank.

[0101] Figure 8 This is a front view corresponding to the shell of the fresh-keeping device of the embodiment of the utility model; Fig. 9 This is a front cross-sectional view corresponding to the housing of the fresh-keeping device of the embodiment of the utility model; Fig.10 It is a right view corresponding to the shell of the fresh-keeping device of the embodiment of the utility model. The fresh-keeping device also includes: a shell 18 arranged outside the reaction tank and / or the reaction control device; wherein the shell 18 is respectively provided with a cold uniform release pipe 25 connected to the cold discharge branch, an atomizer 32 connected to the humidity discharge branch, and a gas uniform release pipe 27 connected to the carbon dioxide concentration discharge branch; wherein the atomizer 32 is used to atomize the water in the humidity discharge branch.

[0102] In the embodiment of the present disclosure, the housing 18 includes: a multi-parameter output mechanism and a device accommodating mechanism; the multi-parameter output mechanism is respectively provided with the cooling uniform release pipe 25, the atomizer 32 and the gas uniform release pipe 27; the device accommodating mechanism is used to accommodate the multi-parameter coordinated control device

[0103] In the embodiment of the present disclosure, the multi-parameter output mechanism of the shell 18 also includes: a cold delivery pipe 24 respectively connected to the cold uniform release pipe 25 and the cold discharge branch, a water delivery pipe 28 respectively connected to the atomizer 32 and the humidity discharge branch, and a carbon dioxide delivery pipe 26 respectively connected to the gas uniform release pipe 27 and the carbon dioxide concentration discharge branch.

[0104] In the embodiment of the present disclosure, a housing door 47 is provided on the outer side of the accommodating mechanism of the housing 18 .

[0105] In the embodiment of the present disclosure, the housing 18 is also provided with a control button 19 connected to the controller and a liquid crystal parameter display panel 20; wherein, the control button 19 is used to input the set temperature, set humidity and set carbon dioxide concentration and / or the first control instruction and the second control instruction to the controller; the liquid crystal parameter display panel 20 is used to display one or more of the set temperature, set humidity and set carbon dioxide concentration, the cold temperature, water content and carbon dioxide concentration in the reaction tank, and the temperature, humidity and carbon dioxide concentration corresponding to the preservation environment.

[0106] In the embodiments of the present disclosure and other possible embodiments, the fresh-keeping device includes: a housing 18, a control button 19, and a liquid crystal parameter display panel 20 connected thereto, and a cold solenoid valve 21, a carbon dioxide solenoid valve 22, and a water solenoid valve 23 controlled thereto; the cold output port 5 delivers cold to the cold storage tank 15 through a cold conduction pipe 11 and a third one-way valve 30; the cold storage tank 15 is externally connected to the cold solenoid valve 21, and the cold delivery pipe 24 is connected to the cold uniform release pipe 25; the carbon dioxide output port 6 is connected to the gas conduction pipe 13 and the sixth one-way valve 30-1 in sequence, and the carbon dioxide is delivered to the gas storage tank 35, and the carbon dioxide in the gas storage tank 35 is connected to the gas uniform release pipe 27 through the carbon dioxide solenoid valve 22 and the carbon dioxide delivery pipe 26; the water output port 7 delivers water to the liquid storage tank 34 through a liquid conduction pipe 16 and a fourth one-way valve 31, and the water in the liquid storage tank 34 is connected to the atomizer 32 through the water solenoid valve 23, the water delivery pipe 28, and the second one-way valve 17 for atomization and release. Wherein, the connection is a detachable fixed connection.

[0107] In the embodiments of the present disclosure and other possible embodiments, reactants are injected at the input port 8 of a water and carbon dioxide mixture in a set ratio of 1:175, and the carbon dioxide hydrate preservative including solid and liquid is generated in the inner liner 2 of the reaction tank through the coolant in the finned coil 9, thereby achieving the generation of the carbon dioxide hydrate preservative; the preservation device detects the preservation conditions of vegetables through a trinity of a temperature sensor, a humidity sensor and a carbon dioxide concentration sensor, and sends the detected data to a control terminal, and the data is displayed on a liquid crystal parameter display panel 20, and the carbon dioxide hydrate is automatically controlled to stably and orderly dissolve and release cold, water and carbon dioxide as required, and the required amount signal is sent to the corresponding solenoid valve, and the required amount is slowly and orderly released through the solenoid valve, thereby suppressing the aerobic respiration of the vegetables, making the preservation environment in an optimal state, and achieving the preservation of the vegetables.

[0108] The embodiments of the present disclosure solve the existing fresh-keeping technology problems that the raw materials for fresh-keeping are difficult to transport and the temperature, humidity and gas conditioning cannot be controlled at the same time. The use of a carbon dioxide hydrate generation tank as a preservative generation device solves the technical problems of the current difficulty in generating fresh-keeping materials and high transportation costs. The use of a detachable carbon dioxide hydrate generation tank is convenient to move and the reaction tank that suddenly breaks can be disassembled in time, solving the problem that the current device cannot operate stably and sustainably. Each pipeline of the reaction tank adopts a one-way valve and is connected through a temperature sensor, a humidity sensor, and a carbon dioxide concentration sensor, which can monitor the fresh-keeping environment in real time, dynamically adjust the release of cold, water mist and carbon dioxide, inhibit the aerobic respiration of plants, and achieve a good fresh-keeping effect. The use of carbon dioxide hydrate as a preservative can meet the full range of control of temperature and wet carbon dioxide concentration in the fresh-keeping environment, realize the coordinated control of temperature, humidity and carbon dioxide concentration, solve the problem of difficult control of the fresh-keeping environment, and realize the resource utilization of carbon dioxide. The technical solution provided by the embodiment of the present disclosure is also simple to operate and the preservative is green, safe and pollution-free. The raw materials can come from factories, the atmosphere, etc., and have a good emission reduction effect.

[0109] In the embodiments of the present disclosure and other possible embodiments, the temperature and pressure corresponding to the reaction tank liner 2 or the hydrate generation chamber 37 in the reaction tank are adjusted by the temperature control unit and the pressure control unit, and the process of hydrate generation and decomposition can be controlled. Further, a catalyst is used to react carbon dioxide with water to generate carbon dioxide water hydrate. In the presence of a catalyst (a promoter for the generation of carbon dioxide hydrate), the reaction of carbon dioxide water hydrate formed by carbon dioxide and water can be promoted, the conditions for the generation of carbon dioxide hydrate can be reduced, and the generation of fresh-keeping materials can be achieved. Then, by adjusting the temperature and pressure of the environment in which the carbon dioxide hydrate is located, the cold, moisture and carbon dioxide generated by the decomposition of carbon dioxide hydrate can be promoted to achieve the control of the fresh-keeping environment to achieve the purpose of fresh-keeping. Based on the fact that solid carbon dioxide hydrate can be slowly and orderly decomposed according to changes in temperature and pressure, and the decomposition can produce cold, water and carbon dioxide. The characteristics of slow and orderly decomposition and decomposition to produce cold, water and carbon dioxide according to changes in temperature and pressure can be used to meet the temperature, humidity and carbon dioxide concentration in the environment in an all-round way, and the resource utilization of carbon dioxide can be achieved.

[0110] In summary, the embodiments of the present disclosure enable comprehensive control of temperature, humidity, and carbon dioxide concentration, while being easy to generate, transport, store, and intelligently control. They are simple to operate, green, safe, and pollution-free, thus promoting energy conservation and emission reduction and realizing the resource utilization of carbon dioxide.

[0111] Compared with the existing technology, under the premise of ensuring that the preservation technology is not lower than the existing average level and safety, the disclosed embodiment has the following obvious advantages: long preservation time and good effect: this equipment can coordinate the control of temperature, humidity and carbon dioxide concentration, effectively inhibit the aerobic respiration of plants while maintaining the color and taste of plants to the greatest extent, delay the loss of nutrients, and greatly extend the preservation time with excellent effect. Intelligent coordinated control of temperature, humidity and carbon dioxide concentration: the equipment can control the temperature and pressure of the hydrate environment under the control of the program according to the needs through the intelligent control terminal, so that the carbon dioxide hydrate can be stably and orderly decomposed, and the preservation efficiency is greatly improved while accurately controlling the preservation conditions. Low generation cost: the generation and storage process of carbon dioxide hydrate only needs to meet 2~5℃ and 1~2MPa, avoiding the energy consumption of high pressure and high temperature conditions for the traditional generation of carbon dioxide hydrate. Green, safe and pollution-free: the raw material for the generation of this hydrate is carbon dioxide, which realizes the resource utilization of carbon dioxide, mild reaction conditions, low risk factor, no harmful substances in the whole process, and solves pollution from the source. The operation method is convenient: adding spiral fins and peripheral coils to the equipment can greatly increase the reaction rate, so that when carbon dioxide hydrate is generated, only the temperature and pressure control unit needs to be started, and the unit needs to be shut down when carbon dioxide hydrate is released. And the detection and control device can control the operation of the temperature and pressure control unit according to environmental requirements. The raw materials are widely available and cheap, and the reaction catalysts can be reused at low cost. Carbon dioxide hydrate has a large gas storage capacity: Carbon dioxide hydrate has a huge gas storage capacity. 1 volume of water can store 175 volumes of carbon dioxide. The generated carbon dioxide hydrate only has carbon dioxide and water when it decomposes, and a part of cold energy is generated (the cold energy is collected to the cold storage layer through the cold energy collection layer for temperature regulation).

[0112] The embodiments of the present disclosure are based on the generation and storage of carbon dioxide hydrate by the hydrate method and a three-in-one coordinated control technology for preservative release that integrates temperature, humidity, and carbon dioxide concentration. Its generation and application conditions are mild, and a large amount of carbon dioxide gas can be stored, avoiding the energy consumption of high pressure and high temperature conditions for the traditional generation of carbon dioxide hydrates. In addition, carbon dioxide hydrates can be stably decomposed to ensure the safety of preservation. The equipment is intelligently controlled by an intelligent control terminal to control the temperature, humidity, and carbon dioxide concentration of the preservation environment to maintain dynamic balance within an appropriate range. This device can be maintained under low temperature and low pressure conditions, and a small amount of water can absorb a large amount of carbon dioxide. The carbon dioxide hydrate generation, release, and temperature, humidity, and carbon dioxide concentration coordinated control device is simple in principle, easy to operate, and low in cost.

[0113] The above-mentioned embodiments are only embodiments of the present invention, and the descriptions thereof are relatively specific and detailed, but they cannot be construed as limiting the scope of the present invention. It should be pointed out that, for a person skilled in the art, without departing from the concept of the present invention, several variations, equivalent substitutions, improvements, etc. can be made, which all fall within the scope of protection of the present invention. Therefore, the scope of protection of the present invention shall be subject to the attached claims.

Claims

1. A reaction tank, characterized in that: include: A reaction tank shell (1); a reaction tank liner (2) is arranged in the reaction tank shell (1); a refrigeration and heat transfer mechanism is arranged in the reaction tank liner (2); a gap between the reaction tank liner (2) and the refrigeration and heat transfer mechanism is a hydrate generation chamber (37); and a gap between the reaction tank shell (1) and the reaction tank liner (2) is a cold energy collection layer (29); The hydrate generation chamber (37) is used to obtain cold energy, water and carbon dioxide by using the refrigeration heat transfer mechanism and a mixture of water and carbon dioxide in a set ratio; the reaction tank liner (2) is connected to the humidity discharge branch and the carbon dioxide concentration discharge branch respectively, and the cold energy collection layer (29) is connected to the cold energy discharge branch.

2. The reaction tank according to claim 1, characterized in that: The refrigeration heat transfer mechanism comprises: a spiral fin (48) and a finned coil (9) arranged on the outside of the spiral fin (48); wherein one end of the spiral fin (48) and the finned coil (9) are respectively connected to a coolant inlet (10) and a coolant outlet, and the other end of the spiral fin (48) is connected to the other end of the finned coil (9).

3. The reaction tank according to any one of claims 1 and 2, characterized in that: The refrigerant input port (10) and the refrigerant output port connected to the refrigeration heat transfer mechanism are respectively provided with a refrigerant inlet check valve (44) and a refrigerant outlet check valve for preventing the refrigerant from flowing back; and / or, The humidity discharge branch comprises: a water outlet (7), the water outlet (7) being in communication with the reaction tank liner (2) or the hydrate generation chamber (37), the water outlet (7) being connected to one end of a liquid guide pipe (16), and the other end of the liquid guide pipe (16) being connected to a liquid storage tank (34).

4. The reaction tank according to any one of claims 1 and 2, characterized in that: The carbon dioxide concentration discharge branch comprises: a carbon dioxide output port (6), the carbon dioxide output port (6) being in communication with the reaction tank liner (2) or the hydrate generation chamber (37), the carbon dioxide output port (6) being connected to one end of an air guide pipe (13), and the other end of the air guide pipe (13) being connected to a gas storage tank (35).

5. The reaction tank according to claim 3, characterized in that: The carbon dioxide concentration discharge branch comprises: a carbon dioxide output port (6), the carbon dioxide output port (6) being in communication with the reaction tank liner (2) or the hydrate generation chamber (37), the carbon dioxide output port (6) being connected to one end of an air guide pipe (13), and the other end of the air guide pipe (13) being connected to a gas storage tank (35).

6. The reaction tank according to any one of claims 1, 2 and 5, characterized in that: The cold energy discharge branch comprises: a cold energy output port (5), the cold energy output port (5) is communicated with the cold energy collection layer (29), the cold energy output port (5) is connected to one end of a cold energy conducting pipe (11), and the other end of the cold energy conducting pipe (11) is connected to a cold storage tank (15).

7. The reaction tank according to claim 3, characterized in that: The cold energy discharge branch comprises: a cold energy output port (5), the cold energy output port (5) is communicated with the cold energy collection layer (29), the cold energy output port (5) is connected to one end of a cold energy conducting pipe (11), and the other end of the cold energy conducting pipe (11) is connected to a cold storage tank (15).

8. The reaction tank according to claim 4, characterized in that: The cold energy discharge branch comprises: a cold energy output port (5), the cold energy output port (5) is communicated with the cold energy collection layer (29), the cold energy output port (5) is connected to one end of a cold energy conducting pipe (11), and the other end of the cold energy conducting pipe (11) is connected to a cold storage tank (15).

9. The reaction tank according to any one of claims 1-2, 5, 7 and 8, characterized in that: A fourth one-way valve (31) is provided on the liquid-conducting pipe (16) of the humidity discharge branch for preventing the water generated in the hydrate generation chamber (37) from flowing back into the hydrate generation chamber (37).

10. The reaction tank according to claim 3, characterized in that: A fourth one-way valve (31) is provided on the liquid-conducting pipe (16) of the humidity discharge branch for preventing the water generated in the hydrate generation chamber (37) from flowing back into the hydrate generation chamber (37).

11. The reaction tank according to claim 4, characterized in that: A fourth one-way valve (31) is provided on the liquid-conducting pipe (16) of the humidity discharge branch for preventing the water generated in the hydrate generation chamber (37) from flowing back into the hydrate generation chamber (37).

12. The reaction tank according to claim 6, characterized in that: A fourth one-way valve (31) is provided on the liquid-conducting pipe (16) of the humidity discharge branch for preventing the water generated in the hydrate generation chamber (37) from flowing back into the hydrate generation chamber (37).

13. The reaction tank according to any one of claims 1-2, 5, 7, 8, 10-12, characterized in that: A sixth one-way valve (30-1) is provided on the gas guide pipe (13) of the carbon dioxide concentration discharge branch for preventing the carbon dioxide generated in the hydrate formation chamber (37) from flowing back into the hydrate formation chamber (37).

14. The reaction tank according to claim 3, characterized in that: A sixth one-way valve (30-1) is provided on the gas guide pipe (13) of the carbon dioxide concentration discharge branch for preventing the carbon dioxide generated in the hydrate formation chamber (37) from flowing back into the hydrate formation chamber (37).

15. The reaction tank according to claim 4, characterized in that: A sixth one-way valve (30-1) is provided on the gas guide pipe (13) of the carbon dioxide concentration discharge branch for preventing the carbon dioxide generated in the hydrate formation chamber (37) from flowing back into the hydrate formation chamber (37).

16. The reaction tank according to claim 6, characterized in that: A sixth one-way valve (30-1) is provided on the gas guide pipe (13) of the carbon dioxide concentration discharge branch for preventing the carbon dioxide generated in the hydrate formation chamber (37) from flowing back into the hydrate formation chamber (37).

17. The reaction tank according to claim 9, characterized in that: A sixth one-way valve (30-1) is provided on the gas guide pipe (13) of the carbon dioxide concentration discharge branch for preventing the carbon dioxide generated in the hydrate formation chamber (37) from flowing back into the hydrate formation chamber (37).

18. The reaction tank according to any one of claims 1-2, 5, 7, 8, 10-12, 14-17, characterized in that: A third one-way valve (30) is provided on the cold conduction pipe (11) of the cold discharge branch for preventing the cold generated in the hydrate generation chamber (37) from flowing back to the cold collection layer (29); and a cold storage tank insulation layer (46) is provided on the outer side of the cold storage tank (15) of the cold discharge branch.

19. The reaction tank according to claim 3, characterized in that: A third one-way valve (30) is provided on the cold conduction pipe (11) of the cold discharge branch for preventing the cold generated in the hydrate generation chamber (37) from flowing back to the cold collection layer (29); and a cold storage tank insulation layer (46) is provided on the outer side of the cold storage tank (15) of the cold discharge branch.

20. The reaction tank according to claim 4, characterized in that: A third one-way valve (30) is provided on the cold conduction pipe (11) of the cold discharge branch for preventing the cold generated in the hydrate generation chamber (37) from flowing back to the cold collection layer (29); and a cold storage tank insulation layer (46) is provided on the outer side of the cold storage tank (15) of the cold discharge branch.

21. The reaction tank according to claim 6, characterized in that: A third one-way valve (30) is provided on the cold conduction pipe (11) of the cold discharge branch for preventing the cold generated in the hydrate generation chamber (37) from flowing back to the cold collection layer (29); and a cold storage tank insulation layer (46) is provided on the outer side of the cold storage tank (15) of the cold discharge branch.

22. The reaction tank according to claim 9, characterized in that: A third one-way valve (30) is provided on the cold conduction pipe (11) of the cold discharge branch for preventing the cold generated in the hydrate generation chamber (37) from flowing back to the cold collection layer (29); and a cold storage tank insulation layer (46) is provided on the outer side of the cold storage tank (15) of the cold discharge branch.

23. The reaction tank according to claim 13, characterized in that: A third one-way valve (30) is provided on the cold conduction pipe (11) of the cold discharge branch for preventing the cold generated in the hydrate generation chamber (37) from flowing back to the cold collection layer (29); and a cold storage tank insulation layer (46) is provided on the outer side of the cold storage tank (15) of the cold discharge branch.

24. The reaction tank according to any one of claims 1-2, 5, 7, 8, 10-12, 14-17, 19-23, characterized in that: The liquid storage tank (34) of the humidity discharge branch is also provided with a water delivery pipe (28); and / or, the gas storage tank (35) of the carbon dioxide concentration discharge branch is also provided with a carbon dioxide delivery pipe (26); and / or, the cold storage tank (15) of the cold discharge branch is also provided with a cold delivery pipe (24).

25. The reaction tank according to claim 3, characterized in that: The liquid storage tank (34) of the humidity discharge branch is also provided with a water delivery pipe (28); and / or, the gas storage tank (35) of the carbon dioxide concentration discharge branch is also provided with a carbon dioxide delivery pipe (26); and / or, the cold storage tank (15) of the cold discharge branch is also provided with a cold delivery pipe (24).

26. The reaction tank according to claim 4, characterized in that: The liquid storage tank (34) of the humidity discharge branch is also provided with a water delivery pipe (28); and / or, the gas storage tank (35) of the carbon dioxide concentration discharge branch is also provided with a carbon dioxide delivery pipe (26); and / or, the cold storage tank (15) of the cold discharge branch is also provided with a cold delivery pipe (24).

27. The reaction tank according to claim 6, characterized in that: The liquid storage tank (34) of the humidity discharge branch is also provided with a water delivery pipe (28); and / or, the gas storage tank (35) of the carbon dioxide concentration discharge branch is also provided with a carbon dioxide delivery pipe (26); and / or, the cold storage tank (15) of the cold discharge branch is also provided with a cold delivery pipe (24).

28. The reaction tank according to claim 9, characterized in that: The liquid storage tank (34) of the humidity discharge branch is also provided with a water delivery pipe (28); and / or, the gas storage tank (35) of the carbon dioxide concentration discharge branch is also provided with a carbon dioxide delivery pipe (26); and / or, the cold storage tank (15) of the cold discharge branch is also provided with a cold delivery pipe (24).

29. The reaction tank according to claim 13, characterized in that: The liquid storage tank (34) of the humidity discharge branch is also provided with a water delivery pipe (28); and / or, the gas storage tank (35) of the carbon dioxide concentration discharge branch is also provided with a carbon dioxide delivery pipe (26); and / or, the cold storage tank (15) of the cold discharge branch is also provided with a cold delivery pipe (24).

30. The reaction tank according to claim 18, characterized in that: The liquid storage tank (34) of the humidity discharge branch is also provided with a water delivery pipe (28); and / or, the gas storage tank (35) of the carbon dioxide concentration discharge branch is also provided with a carbon dioxide delivery pipe (26); and / or, the cold storage tank (15) of the cold discharge branch is also provided with a cold delivery pipe (24).

31. The reaction tank according to claim 24, characterized in that: The water delivery pipe (28) connected to the liquid storage tank (34) of the humidity discharge branch is provided with a second one-way valve (17) for preventing water in the liquid storage tank (34) from flowing back to the liquid storage tank (34); and / or, the carbon dioxide delivery pipe (26) connected to the gas storage tank (35) of the carbon dioxide concentration discharge branch is provided with a first one-way valve (14) for preventing carbon dioxide in the gas storage tank (35) from flowing back to the gas storage tank (35); and / or, the cold delivery pipe (24) connected to the cold storage tank (15) of the cold discharge branch is provided with an external one-way valve (12) for preventing cold in the cold storage tank (15) from flowing back to the cold storage tank (15).

32. The reaction tank according to any one of claims 25 to 30, characterized in that: The water delivery pipe (28) connected to the liquid storage tank (34) of the humidity discharge branch is provided with a second one-way valve (17) for preventing water in the liquid storage tank (34) from flowing back to the liquid storage tank (34); and / or, the carbon dioxide delivery pipe (26) connected to the gas storage tank (35) of the carbon dioxide concentration discharge branch is provided with a first one-way valve (14) for preventing carbon dioxide in the gas storage tank (35) from flowing back to the gas storage tank (35); and / or, the cold delivery pipe (24) connected to the cold storage tank (15) of the cold discharge branch is provided with an external one-way valve (12) for preventing cold in the cold storage tank (15) from flowing back to the cold storage tank (15).

33. The reaction tank according to any one of claims 1-2, 5, 7, 8, 10-12, 14-17, 19-23, 25-31, characterized in that: The opening of the reaction tank shell (1) is provided with an openable or fixedly connected reaction tank upper end cover (3); and / or, A spiral outer coil (36) is arranged on the inner side of the reaction tank shell (1), a refrigerant input port (38) and a refrigerant output port (39) are arranged at both ends of the outer coil (36), and a porous medium insulation layer (4) is arranged in the gap between the spiral outer coil (36); and / or, It also includes: a water and carbon dioxide mixture input port (8) connected to the reaction tank liner (2) or the hydrate generation chamber (37).

34. The reaction tank according to claim 3, characterized in that: The opening of the reaction tank shell (1) is provided with an openable or fixedly connected reaction tank upper end cover (3); and / or, A spiral outer coil (36) is arranged on the inner side of the reaction tank shell (1), a refrigerant input port (38) and a refrigerant output port (39) are arranged at both ends of the outer coil (36), and a porous medium insulation layer (4) is arranged in the gap between the spiral outer coil (36); and / or, It also includes: a water and carbon dioxide mixture input port (8) connected to the reaction tank liner (2) or the hydrate generation chamber (37).

35. The reaction tank according to claim 4, characterized in that: The opening of the reaction tank shell (1) is provided with an openable or fixedly connected reaction tank upper end cover (3); and / or, A spiral outer coil (36) is arranged on the inner side of the reaction tank shell (1), a refrigerant input port (38) and a refrigerant output port (39) are arranged at both ends of the outer coil (36), and a porous medium insulation layer (4) is arranged in the gap between the spiral outer coil (36); and / or, It also includes: a water and carbon dioxide mixture input port (8) connected to the reaction tank liner (2) or the hydrate generation chamber (37).

36. The reaction tank according to claim 6, characterized in that: The opening of the reaction tank shell (1) is provided with an openable or fixedly connected reaction tank upper end cover (3); and / or, A spiral outer coil (36) is arranged on the inner side of the reaction tank shell (1), a refrigerant input port (38) and a refrigerant output port (39) are arranged at both ends of the outer coil (36), and a porous medium insulation layer (4) is arranged in the gap between the spiral outer coil (36); and / or, It also includes: a water and carbon dioxide mixture input port (8) connected to the reaction tank liner (2) or the hydrate generation chamber (37).

37. The reaction tank according to claim 9, characterized in that: The opening of the reaction tank shell (1) is provided with an openable or fixedly connected reaction tank upper end cover (3); and / or, A spiral outer coil (36) is arranged on the inner side of the reaction tank shell (1), a refrigerant input port (38) and a refrigerant output port (39) are arranged at both ends of the outer coil (36), and a porous medium insulation layer (4) is arranged in the gap between the spiral outer coil (36); and / or, It also includes: a water and carbon dioxide mixture input port (8) connected to the reaction tank liner (2) or the hydrate generation chamber (37).

38. The reaction tank according to claim 13, characterized in that: The opening of the reaction tank shell (1) is provided with an openable or fixedly connected reaction tank upper end cover (3); and / or, A spiral outer coil (36) is arranged on the inner side of the reaction tank shell (1), a refrigerant input port (38) and a refrigerant output port (39) are arranged at both ends of the outer coil (36), and a porous medium insulation layer (4) is arranged in the gap between the spiral outer coil (36); and / or, It also includes: a water and carbon dioxide mixture input port (8) connected to the reaction tank liner (2) or the hydrate generation chamber (37).

39. The reaction tank according to claim 18, characterized in that: The opening of the reaction tank shell (1) is provided with an openable or fixedly connected reaction tank upper end cover (3); and / or, A spiral outer coil (36) is arranged on the inner side of the reaction tank shell (1), a refrigerant input port (38) and a refrigerant output port (39) are arranged at both ends of the outer coil (36), and a porous medium insulation layer (4) is arranged in the gap between the spiral outer coil (36); and / or, It also includes: a water and carbon dioxide mixture input port (8) connected to the reaction tank liner (2) or the hydrate generation chamber (37).

40. The reaction tank according to claim 24, characterized in that: The opening of the reaction tank shell (1) is provided with an openable or fixedly connected reaction tank upper end cover (3); and / or, A spiral outer coil (36) is arranged on the inner side of the reaction tank shell (1), a refrigerant input port (38) and a refrigerant output port (39) are arranged at both ends of the outer coil (36), and a porous medium insulation layer (4) is arranged in the gap between the spiral outer coil (36); and / or, It also includes: a water and carbon dioxide mixture input port (8) connected to the reaction tank liner (2) or the hydrate generation chamber (37).

41. The reaction tank according to claim 32, characterized in that: The opening of the reaction tank shell (1) is provided with an openable or fixedly connected reaction tank upper end cover (3); and / or, A spiral outer coil (36) is arranged on the inner side of the reaction tank shell (1), a refrigerant input port (38) and a refrigerant output port (39) are arranged at both ends of the outer coil (36), and a porous medium insulation layer (4) is arranged in the gap between the spiral outer coil (36); and / or, It also includes: a water and carbon dioxide mixture input port (8) connected to the reaction tank liner (2) or the hydrate generation chamber (37).

42. The reaction tank according to claim 33, characterized in that: The water and carbon dioxide mixture input port (8) connected to the reaction tank liner (2) or the hydrate generation chamber (37) is provided with a raw material inlet one-way valve (43) to prevent the water and carbon dioxide mixture from flowing back.

43. A reaction control device comprising: The reaction tank as described in any one of claims 1 to 42 is characterized in that the carbon dioxide concentration discharge branch, the humidity discharge branch and the cold capacity discharge branch connected to the reaction tank are respectively provided with a carbon dioxide solenoid valve (22), a water solenoid valve (23) and a cold capacity solenoid valve (21) which can control their opening / closing.

44. The reaction control device according to claim 43, characterized in that: The air guide pipe (13) of the carbon dioxide concentration discharge branch, the liquid guide pipe (16) of the humidity discharge branch, and the cold volume guide pipe (11) of the cold volume discharge branch are respectively provided with a first valve (40) or a first solenoid valve, a third valve (42) or a third solenoid valve, and a second valve (41) or a second solenoid valve that can control their opening / closing.

45. The reaction control device according to claim 43 or 44, characterized in that: Also includes: Controller; The controller is respectively connected to the carbon dioxide solenoid valve (22), the water solenoid valve (23) and the cold solenoid valve (21), and is used to respectively control the cold, water and carbon dioxide in the reaction tank to enter the cold discharge branch, the humidity discharge branch and the carbon dioxide concentration discharge branch.

46. ​​The reaction control device according to claim 45, characterized in that: in, The controller is respectively connected to the first valve (40) or the first solenoid valve, the third valve (42) or the third solenoid valve, and the second valve (41) or the second solenoid valve, and is used to respectively control the cold discharge branch, the humidity discharge branch, and the carbon dioxide concentration discharge branch to discharge the cold, the water, and the carbon dioxide.

47. A fresh-keeping device, characterized in that: Application or inclusion of a reaction tank as described in any one of claims 1-42 to generate cold, water and carbon dioxide.

48. A fresh-keeping device, characterized in that: A reaction control device as described in any one of claims 43-46 is applied or included to control the emission of generated cold, water and carbon dioxide in the reaction tank.

49. A fresh-keeping device, characterized in that: The method comprises applying or including a reaction tank as described in any one of claims 1 to 42 to generate cold, water and carbon dioxide; and applying or including a reaction control device as described in any one of claims 43 to 46 to control the emission of cold, water and carbon dioxide generated by the reaction tank.

Images