Milky, viscous and sticky perfume complex, ready to use and associated perfume composition.

A perfume complex with a solvent, thickening agent, solubilizer, and opacifier addresses the need for undiluted, long-lasting perfumes by providing a stable, milky, and viscous application with slow evaporation and adherence.

FR3133308B1Active Publication Date: 2026-02-27EXPRESSIONS PARFUMEES
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Patent Information

Application Number
FR2022002141
Authority / Receiving Office
FR · FR
Patent Type
Patents
Current Assignee / Owner
Filing Date
2022-03-11
Publication Date
2026-02-27
Estimated Expiration
2042-03-11

AI Technical Summary

Technical Problem

There is a need for ready-to-use perfumes that can be applied undiluted, particularly with a roll-on applicator, and provide long-lasting diffusion, with a growing demand in Middle Eastern countries for opaque and stable alcoholic solutions.

Method used

A perfume complex comprising a solvent, thickening agent, solubilizer, and opacifier, which results in a milky, viscous, and sticky composition that adheres to the skin, ensuring slow evaporation and stability.

Benefits of technology

The composition provides a stable, milky, and viscous perfume that adheres to the skin, ensuring slow evaporation and long-lasting diffusion without the need for dilution, maintaining homogeneity and olfactory quality over time.

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Abstract

Ready-to-use, viscous, and sticky milky perfume complex and associated perfume composition. The present invention relates to a perfume complex comprising the following components: - 10 to 60% of a solvent, - 5 to 75% of a thickening agent, - 0.2 to 16% of a solubilizer, - 0.2 to 16% of an opacifier, - a perfume in sufficient quantity to reach 100%, the percentages being expressed by weight relative to the total weight of the above components. The invention also relates to a perfume composition comprising 2 to 95% of the perfume complex, by weight relative to the total weight of the composition, and a diluent. The present invention relates to the field of perfumes and perfume compositions. It finds particularly advantageous application in the field of perfumery.
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Description

Title of the invention: Ready-to-use, viscous, and sticky milky perfume complex and associated perfume composition. Technical field

[0001] The present invention relates to the field of perfumes and perfumed compositions. Its application is particularly advantageous in the fields of perfumery, cosmetics, and cleaning products such as detergent bases or air fresheners. State of the art

[0002] Usually, the perfumes sought are rather transparent and liquid like water.

[0003] In the field of perfumery in particular, there is a growing demand in Middle Eastern countries for ready-to-use perfumes that can be used undiluted, especially with a roll-on applicator. Furthermore, the perfume is required to have a long-lasting diffusion.

[0004] The prior art compositions must be modified to adapt to its new requirements. A fragrance in the form of an opaque and stable alcoholic solution is desired.

[0005] There is therefore a need to propose a composition that meets these requirements. Summary

[0006] To achieve this objective, according to one embodiment, the invention relates to a perfume complex comprising the following components: - a solvent, - a thickening agent, - a solubilizer, - an opacifier, - a perfume.

[0007] This fragrance complex can advantageously be used undiluted, that is, without any other solvent or diluent. This fragrance complex advantageously has a milky appearance and a viscous, sticky feel. The fragrance complex thus adheres to the skin, ensuring slow evaporation and resulting in diffusion throughout the day. The fragrance complex is also stable.

[0008] Preferably, the fragrance complex comprises the following components: - 10 to 60% of a solvent, - 5 to 75% of a thickening agent, - 0.2 to 16% of a solubilizer, - 0.2 to 16% of an opacifier, - a perfume in sufficient quantity to reach 100%, the percentages being expressed by weight relative to the total weight of the components above.

[0009] According to another aspect, the invention relates to a perfumed composition comprising the perfume complex, preferably from 2 to 95% perfume complex by weight relative to the total weight of the composition, and a diluent. This perfumed composition advantageously has a milky appearance and a viscous, sticky feel. The perfumed composition is also stable.

[0010] According to another aspect, the invention relates to the use of the perfumed composition or the perfume complex as all or part of a cosmetic base or a perfumery product, in particular fine perfumery, or of a room fragrance. Detailed description

[0011] Before proceeding with a detailed review of embodiments of the invention, optional features that may be used in combination or alternatively are listed below:

[0012] According to one example, the perfume complex comprises 10 to 60%, preferably 15 to 40%, of a solvent.

[0013] According to one example, the perfume complex comprises 5 to 75%, preferably 15 to 70%, of a viscosifying agent.

[0014] According to one example, the fragrance complex comprises 0.2 to 16%, preferably 0.3 to 8%, of a solubilizer.

[0015] According to one example, the perfume complex comprises 0.2 to 16%, preferably 0.3 to 8%, of an opacifier.

[0016] According to one example, the solvent is chosen from the group comprising propan-2-yl tetradecanoate, diethylbenzene-1,2-dicarboxylate, propane-1,2-diol, 2-[(1-hydroxypropan-2-yl)oxy]propan-1-ol, 1,2,3-triethyl 2-hydroxypropane-1,2,3-tricarboxylate, 2-(2-ethoxyethoxy)ethanol, 2-methylpentane-2,4-diol, 2,2-dimethyl-1,3-dioxolanne-4-ylmethanol, 3-methyl-1,3-butandiol, benzyl benzoate, 1,3-diacetyloxypropan-2-yl acetate, 2-octyldodecan-1-ol, decanoyl and octanoyl glycerides, and propan-2-yl hexadecanoate. ,1'ethyl (Z)-octadec-9-enoate, Bis(2-ethylhexyl) hexanedioate, (2-methoxymethylethoxy) propanol, 3-methoxy-3-methylbutan-l-ol, Propanol, (2-methoxymethylethoxy)-), acetate, ethanol, whether of natural or synthetic origin or a mixture thereof.

[0017] According to one example, the perfume complex does not include water.

[0018] According to one example, the thickening agent is chosen from the group comprising an alcohol tricyclodecane dimethanol, glyceryl hydrogenated rosinate, trihydroxystearin, hydrogenated castor oil, paraffin, solemix gel cushion s-00, a hydrogenated vegetable oil, polyamide-3, oleic polyglyceride, linoleic polyglyceride, linolenic polyglyceride, paraffinum liquidum (and) capric / caprylic triglyceride (and) hydrogenated styrene / isoprene copolymer, cl5-19 alkane (and) hydrogenated styrene / isoprene, polyterpene resins, a rosin, preferably a tricyclodecane di-methanol alcohol, or a mixture thereof.

[0019] According to one example, the solubilizer is chosen from the group comprising polysorbate 20, peg-30 castor oil, peg-40 hydrogenated castor oil, glycereth-17 cocoate, poly-glyceryl-4 laurate / sebacate (and) polyglyceryl-6 caprylate / caprate (and) aqua, poly-glyceryl-3 caprylate, caprylyl / capryl glucoside, caprylyl / capryl glucoside, decyl glucoside, heptyl glucoside, ppg 26 buteth-26 (and) peg 40 hydrogenated castor oil (and) water, preferably polysorbate 20 or a mixture of these.

[0020] According to one example, the opacifier is chosen from the group comprising styrene / acrylates copolymer (and) coco-glucoside, titanium dioxide (and) caprylic / capric triglyceride (and) polyhydroxystearic acid (and) stearic acid (and) alumina, micronized titanium dioxides, preferably euperlan pco styrene / acrylates copolymer (and) coco-glucoside, d-glucopyranose, oligomeric, c8-16-alkyl glycosides & methacrylic acid-styrene polymer or a mixture thereof.

[0021] According to one example, the fragrance complex comprises: - 15 to 40% dipropylene glycol as a solvent - 15 to 70% of tricyclodecanedimethanol as viscosity, - 0.3 to 8% polysorbate 20 as a solubilizer, - 0.3 to 8% styrene / acrylates copolymer & coco glucoside as an opacifier - a sufficient quantity of perfume to reach 100%, the percentages are expressed as a percentage of the total weight of the components above.

[0022] According to one example, the perfume complex has a viscosity greater than 1000 mPas, and less than 200,000 mPas.

[0023] According to one example, the perfumed composition includes an alcohol as a diluent.

[0024] According to one example, the perfumed composition includes water.

[0025] According to one example, the perfumed composition does not include water.

[0026] According to one example, the perfumed composition and / or the perfume complex is opaque.

[0027] By "compatible with any type of olfactory family", it is meant that the complex and / or said composition can contain any type of perfume, from any olfactory family.

[0028] By "stable" is meant a composition or complex that does not degrade over time and whose components will not react with each other. By "stable" is meant that The homogeneity, olfactory intensity, olfactory quality, color, and / or viscosity of the composition and / or complex are preserved, advantageously without the effects of time, temperature, pressure, and / or UV radiation. More specifically, the composition and / or complex according to the present invention is stable under accelerated aging after 24 hours under UV light (suntest) and after 2 months at 20-22°C and 45°C compared to a sample stored at 5°C, all samples being stored at temperature and protected from light, or after centrifugation for a minimum of 12 minutes at a speed of 5000 rpm, for example, using a SIGMA brand centrifuge model 2-16 K or equivalent, compared to a sample stored at temperature and protected from light.

[0029] By "opaque," it is understood that the composition and / or complex is not transparent at temperatures between 4 and 50°C, regardless of the fragrance used. The term "milky" is used as a synonym for opaque. By "opaque composition or complex," it is understood that the composition or complex has a turbidity greater than 3 FNU (Formazin turbidity units) or 3 NTU (nephelometric turbidity units). This turbidity is measured, for example, using a Hanna Instruments HI 88713 iso tur-bidimeter or equivalent.

[0030] By "pleasant odor" is meant an odor which is detected by the human sense of smell and which is perceived as pleasant.

[0031] By viscous, we mean "having a viscosity greater than that of water," that is to say, the dynamic viscosity at 20°C of the complex is greater than 15 mPas, preferably greater than 1000 mPas, and preferably less than 400,000 mPas, preferably less than 200,000 mPas. Preferably, according to the present invention, the dynamic viscosity is measured with the Viscotester IQ viscometer, geometry cc27 dg / ti - 01160025, at 20°C, at 500 s⁻¹ for 30 seconds or equivalent.

[0032] By "sticky" is meant that the complex and / or composition has a non-soft, non-silky feel, that the complex and / or composition sticks, adheres to the skin, the complex and / or composition is thick, soft and sticky.

[0033] The term "perfume" means a composition comprising a mixture of perfumer substances, said perfumer substances being in an isolated state, in solution or in suspension, in their usual diluents, solvents or co-ingredients. Such a composition is intended to provide a pleasant olfactory component.

[0034] By “perfuming substance” is meant one or more perfumed raw materials of natural or synthetic origin.

[0035] Percentages are understood as mass percentage, that is to say, weight relative to a weight of the complex or composition.

[0036] According to a first aspect, the present invention relates to a perfume complex comprising a perfume, a solvent, a viscosifier, a solubilizer and an opacifier.

[0037] The perfume complex advantageously comprises a solvent preferably in an amount between 10 and 60% by weight of the total weight of the perfume complex, preferably from 15 to 40%.

[0038] Advantageously, the solvent is selected from the group comprising propan-2-yl tetradecanoate, diethylbenzene-1,2-dicarboxylate, propane-1,2-diol, 2-[(1-hydroxypropan-2-yl)oxy]propan-1-ol, 1,2,3-triethyl 2-hydroxypropane-1,2,3-tricarboxylate, 2-(2-ethoxyethoxy)ethanol, 2-methylpentane-2,4-diol, 2,2-dimethyl-1,3-dioxolanne-4-ylmethanol, 3-methyl-1,3-butandiol, benzyl benzoate, 1,3-diacetyloxypropan-2-yl acetate, 2-octyldodecan-1-ol, decanoyl and octanoyl glycerides, propan-2-yl hexa-decanoate, ethyl (Z)-octadec-9-enoate, Bis(2-ethylhexyl) hexanedioate, (2-methoxymethylethoxy)propanol, 3-methoxy-3-methylbutan-l-ol, propanol, (2-methoxymethylethoxy)-acetate, ethanol, or a mixture thereof, whether of natural or synthetic origin.

[0039] Advantageously, the solvent is chosen to have a log P between -1 and +1.1. This arrangement allows control of the viscosity of the perfume complex and / or the perfume composition.

[0040] Preferably, the solvent is dipropylene glycol. Dipropylene glycol has CAS number 25265-71-8 and IUP name AC: 2-[(1-hydroxypropan-2-yl)oxy]propan-1-ol.

[0041] Dipropylene glycol is a mixture of three constitutional isomers l,l-oxydipropan-2-ol, l,l'-oxydipropan-2-ol and hydroxypropyloxypropanol presented in the table below.

[0042] [Tables 1] Case No. Common name 108-61-2 [Chem.l] oxydipropan-2-ol 110-98-5 [Chem. 2] 1,1'-oxydipropan-2-ol 106-62-7 [Chem. 3] OH 0¾ hydroxypropyloxypropa nol.

[0043] Its general formula is: C6Hi4O3.

[0044] Dipropylene glycol is advantageously used in the fragrance complex according to the invention because it is advantageously virtually odorless, colorless, and chemically stable. Dipropylene glycol advantageously exhibits a low evaporation rate, with a vapor pressure of 0.02 mmHg, which is much lower than that of water, which remains the reference with a vapor pressure of 17.5 mmHg. Furthermore, dipropylene glycol is hygroscopic and miscible with water and most organic solvents.

[0045] Dipropylene glycol is used in particular as a solvent. In perfumery, a solvent is a raw material capable of solubilizing different odoriferous raw materials, making them compatible with each other in an advantageously stable and permanent manner.

[0046] It allows for adjusting the viscosity and, advantageously, also the opacity by acting as a diluent. The solvent is used to stabilize the fragrance complex. The presence of dipropylene glycol advantageously prevents recrystallization / solidification of the fragrance complex and / or the fragrance composition. This recrystallization / solidification can occur following thermal shock and / or excessive or insufficient atmospheric pressure. The phenomenon of crystallization / solidification This process is then irreversible and can occur both on the surface and at the bottom of the fragrance complex and / or the fragrance composition. It is recognizable by its whiter color compared to the rest of the fragrance complex and / or the fragrance composition and by its granular, non-homogeneous, or even solid appearance.

[0047] The perfume complex advantageously comprises a viscosifier, preferably in an amount between 5 and 75% by weight of the total weight of the perfume complex, preferably 15% to 70%.

[0048] Advantageously, the thickening agent is selected from the group comprising loctahydro-4,7-methano-lh-indene-5-dimethanol, glyceryl hydrogenated rosinate (sold under the name Hercolyn D by DRT), trihydroxystearin (sold under the name Thixcin R PC natural by Elementis), hydrogenated castor oil, paraffin, Solemix Gel Cushion S-00 (proprietary blend sold by Premixel), hydrogenated vegetable oil (sold under the name Dermofeel Viscolid MB by Evonik), polyamide-3 (sold under the name OleoCraft MP-32 Polymers by Croda), oleic polyglyceride / linoleic polyglyceride / linolenic polyglyceride (sold under the name Viamerine 10000 deodorized by Aldivia), and liquid paraffin. (and) Capric / Caprylic Triglyceride (and) Hydrogenated Styrene / Isoprene Copolymer Hydrogenated Styrene / Isoprene Copolymer (sold under the name Transgel 110 by SACI), Cl5-19 Alkane (and) Hydrogenated Styrene / Isoprene Copolymer (sold under the name Veggie gel 407 by Aiglon),Polyterpene resins (sold under the name Dercolyte LTG), the range of rosins (sold under the name Hydrogral by DRT) or mixtures thereof.

[0049] Preferably, the thickening agent is Toctahydro-4,7-methano-lh-indene-5-dimethanol, also known as tricyclodecanedimethanol, having CAS number 26160-83-8. Its general formula is Ci2H2O02 and its structural formula is:

[0050] [Chem.4]

[0051] The viscosifier serves to control the viscosity of the fragrance complex according to the invention. The viscosifier contributes to giving a sticky appearance to the fragrance complex and / or the fragrance composition. The viscosifier, and more particularly tricyclodecanedimethanol alcohol, exhibits very low evaporation. This is confirmed by its vapor pressure of 0.750 mmHg, while the reference vapor pressure of water is 17.5 mmHg. This low evaporation rate allows the fragrance complex to diffuse slowly. The stickiness provided by tricyclodecanedimethanol (TCD DM) ensures adhesion to the skin, resulting in a long-lasting fragrance.

[0052] The thickening agent, and more particularly tricyclodecanedimethanol, advantageously contributes to opacifying the fragrance complex and / or the fragrance composition. An increase in the amount of thickening agent, without changing the other weight amounts of the components of the fragrance complex, increases the opacity of the fragrance complex and / or the fragrance composition.

[0053] The fragrance complex advantageously comprises a solubilizer, preferably in an amount between 0.2 and 16% by weight of the total weight of the fragrance complex, preferably from 0.3% to 8%.

[0054] Advantageously, the solubilizer is selected from the group comprising Polysorbate 20, PEG-30 castor oil (sold under the name Cemulsol B by Solvay), PEG-40 hydrogenated castor oil (sold under the name Eumulgin CO 40 by BTC), glycereth-17 cocoate (sold under the name Levenol C201 by KAO), Polyglyceryl-4 Laurate / Sebacate (and) Polyglyceryl-6 Caprylate / Caprate (and) Aqua (sold under the name Natragem S140-NP by CRODA), Polyglyceryl-3 caprylate (and) caprylyl / capryl glucoside (sold under the name Neocare TGM 8 by Biosynthis), caprylyl / capryl glucoside (sold under the name Oramix CG 110 by Seppic), the Decyl Glucoside (sold under the name Plantacare 2000 UP by BASF), Heptyl Glucoside (sold under the name Sepiclear G7 by Seppic), PPG 26 Buteth-26 (and) PEG 40 hydrogenated castor oil (and) Water (sold under the name Solubilisant LRI by LCW Sensient).

[0055] Preferably, the solubilizer is polysorbate 20, having CAS number 9005-64-5, general formula C58Hii4O26 and structural formula:

[0056] [Chem.5]

[0057] Polysorbate 20, also known as Tween 20, or Sorbitan monolaurate, ethoxylated, is a non-ionic surfactant and emulsifier derived from sorbitol based on fruits and berries.

[0058] The solubilizer, and more particularly polysorbate 20, participates in the solubilization of the opacifier within the perfume complex.

[0059] Indeed, the opacifier tends to be unstable and to form agglomerates within the fragrance complex that are not homogeneously re-dispersible within the fragrance complex. Polysorbate 20 ensures the stability of the opacifier within the fragrance complex, and therefore of the fragrance complex and / or the fragrance composition. The solubilizer is used to ensure a homogeneous and stable fragrance complex.

[0060] The choice of polysorbate 20 ensures that no unwanted odor is introduced, as it is odorless. Furthermore, it is easy to use; it can be processed cold without the need for heating or re-homogenization.

[0061] Advantageously, the solubilizer forms a pre-complex in association with the opacifier and the solvent.

[0062] The perfume complex advantageously comprises an opacifier, preferably in an amount between 0.2 and 16% by weight of the total weight of the perfume complex, preferably from 0.3% to 8%.

[0063] The opacifier is also called a bleaching agent.

[0064] Advantageously, the opacifier is chosen from the group comprising Styrene / Acrylates Copolymer (and) Coco-Glucoside (sold under the name Euperlan PCO by AMI), Titanium Dioxide (and) Caprylic / Capric Triglyceride (and) Polyhydroxystearic Acid (and) Stearic Acid (and) Alumina (sold under the name Solaveil XT-300-LQ by Croda), micronized Titanium Dioxide or mixtures thereof.

[0065] Preferably, the opacifier is an acrylate / styrene and coco glucoside copolymer sold under the name Euperlan PCO and having CAS numbers 141464-42-8 & 9010-92-8. The opacifier is also known as D-Glucopyranose, oligomeric, C8-16-alkyl glycosides, methacrylic acid-styrene polymer.

[0066] The opacifier, and more particularly the acrylates / styrene and coco glucoside copolymer, is a dispersion of an opacifying agent with surfactants.

[0067] The preferred opacifier is a mixture of synthetic raw materials (styrene / methacrylic acid copolymer) and vegetable raw materials (coconut / palm kernel oil, glucose).

[0068] The opacifier is chosen to give a luxurious, creamy, rich and dense appearance to the perfume complex, and / or to the perfume composition.

[0069] Surprisingly, this opacifier is advantageously suspended, advantageously with the solubilizer and at least a portion of the solvent (hereinafter referred to as the pre-complex), before forming a fragrance complex to ensure the stability of said fragrance complex. Its incorporation as such into the fragrance complex can lead to solubility problems and the formation of agglomerates. Preparing a pre-complex containing the solvent, solubilizer, and opacifier prevents the formation of these agglomerates. This pre-complex is prepared cold. It is then mixed with the fragrance, followed by the thickener, to obtain a homogeneous and stable fragrance complex.

[0070] The perfume complex advantageously comprises a perfume.

[0071] Preferably, the perfume is in sufficient quantity to complete the perfume complex to 100%.

[0072] According to the invention, the fragrance may comprise ingredients of preferably synthetic origin, possibly natural. The choice of this fragrance depends on the desired olfactory effect and the application in which it will be used.

[0073] Such raw materials, whether of natural or synthetic origin, may include esters, ethers, alcohols, aldehydes, ketones, lactones, acetals, nitriles, phenols, acids, terpenes, nitrogenous or sulfurous heterocyclic compounds, saturated or unsaturated, and complex products of natural origin.

[0074] Examples of esters include, but are not limited to, benzyl acetate, p-tert-butylcyclohexyl acetate, 3,7-dimethyl-1,6-octadien-3-yl acetate (linalyl acetate), dimethylbenzylcarbinyl acetate, phenylethyl acetate, l,l-dimethyl-2-phenylethyl acetate, linalyl benzoate, ethylmethylphenyl glycinate, allylcyclohexyl propionate, styrallyl propionate, benzyl salicylate, methyl-3-oxo-2-pentylcyclopentane acetate, prop-2-enyl-2,3-methylbutoxy acetate (allyl amyl glycolate, 2-propenyl ester of 3-methylbutoxyacetic acid), phenylmethyl ester of acetic acid, isoamyl acetate (isopentyl acetate), cis-hex-3-enyl acetate ((z)-hex-3-enyl acetate), citronellyl acetate (3,7-dimethyl-6-octen-l-ol acetate), hexyl acetate, isobornyl acetate (bicyclo[2.2.1]heptan-2-ol,l,7,7-trimethyl), methanyl acetate (alpha,alpha,4-trimethylcyclohexylmethyl acetate), ethyl acetate, prenyl acetate (3-methyl-2-butenyl acetate), triethyl citrate, 4-ter-butylcyclohexyl acetate, (3r-(3alpha,3abeta,6alpha,7beta,8aalpha))-octahydro-3,6,8,8-tetramethyl-lh-3a-7-methanoazulene-5-yl acetate, 3,7-dimethyl octa-l,6-diene-3-yl, l,4-dioxacyclohexadecane-5,16-dione acetate, benzyl 2-hydroxybenzoate, (z)-3-hexenyl-2-hydroxybenzoate, acetate 2-(l,l(dimethylethyl)cyclohexyl, isopentyl acetate, methyl phenylacetate, (z)-hex-3-enyl acetate, 3,7-dimethyl octa-l,6-diene-3-yl acetate, 3-methyl-2-butenyl acetate, alpha-methylbenzenemethanol acetate, methyl 2-aminobenzoate, 2-propenyl-(cyclohexyloxy)acetate, methyl 2,4-dihydroxy-3,6-dimethylbenzoate, methyl 3-oxo-2-pentylcyclopentaneacetate, propanoate. 3-alpha,4,5,6,7,7-alpha-hexahydro-4,7-methano-lh-inden-6-yl, methyl 3-oxo-2-pentylcyclopentaneacetate, 2-(l,l-dimethylethyl)cyclohexyl,hexyl-2-hydroxybenzoate (2-hydroxy-2-hexyl ester of benzoic acid), 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl, 2-ethyl methylbutyrate, 3a,4,5,6,7,7a-hexahydro-4,7-methano-lh-inden-5-yl, 2-methylpropanoate, alpha,alpha-dimethylphenethyl acetate, 3,7-dimethyl octa-l,6-diene-3-yl acetate d'exo-l,7,7-trimethyl-bicyclo[2.2.1]heptan-2-ol, ethyl hexanoate, 3,7-dimethyl octa-l,6-diene-3-yl acetate, methyl 3-oxo-2-pentylcyclopentane acetate, methyl 2-(methylamino)benzoate, 10-undecenoic acid, ethyl ester, ethyl 2-methylpentanoate, cis-3,7-dimethyl-2,6-octadienyl ethanoate, benzyl 2-hydroxybenzoate, (z)-hex-3-enyl acetate, 2-hydroxy-2-hexyl benzoic acid ester, prop-2-enyl-2-cyclohexyloxyacetate (2-propenyl-(cyclohexyloxy)acetate), acetic acid, (3-methylbutoxy), ester 2-propenyl,2-Phenylethanol, hexyl acetate, (Ir,2s,5r)-5-methyl-2-(l-methylethyl)-cyclohexanol ethanoate, terpenyl acetate (4-methyl-l-propan-2-yl-l-cyclohex-2-enyl acetate), alpha-3,3-trimethylcyclohexyl-methyl formate, 3-methylbutyl butanoate (isoamyl butyrate), alpha,alpha-dimethylphenethyl butanoate, 3-dihydrodicyclopentadien-2,3-yl prop-2-enyl acetate, 3-cyclohexyl propanoate (allyl cyclohexane propionate), allyl heptanoate (2-propenyl heptanoate), 2-phenoxyethyl 2-methylpropanoate (phenoxy isobutyrate) ethyl), ethyl 2-methylpentanoate, ethyl 2-methylbutyrate (ethyl ester of 2-methylbutanoic acid), l,4-dioxacycloheptadecane-5,17-dione (ethylene brassylate), (2S)-2-propyl-l,l-dimethylipropoxy propanoate ((2S)-propyl ester of 2-(l,l-dimethylpropoxy)propanoic acid), 2-tert-butylcyclohexyl acetate (2-(l,l-dimethylethyl)cyclohexyl acetate), ci-3-hexenyl salicylate,[(1s)-3-(4-methylpent-3-enyl)-1-cyclohex-3-enyl]methyl acetate, 3-pentyltetrahydro[2h]pyranyl acetate, linalyl propionate, cetyl acetate, cedryl acetate, anisyl acetate, nopyl acetate, neryl acetate, 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate, 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl propanoate, 2-propenyl 3-cyclohexanepropanoate, 1,2,3-triethyl 2-hydroxypropane-1,2,3-tricarboxylate, acetate (2e)-3,7-dimethylocta-2,6-dien-l-yl, 3,5,5-trimethylhexyl acetate, 3,7-dimethyl-octa-l,6-diene-3-yl acetate, cis-3,7-dimethyl-2,6-octadienyl ethanoate, 1-methylethyl ester of tetradecanoic acid, 3-methylbutyl ester of 2-hydroxybenzoic acid, phenylmethyl ester of 2-hydroxybenzoic acid, 2-hexyl ester of 2-hydroxybenzoic acid, methyl ester of 2-hydroxybenzoic acid, ethyl ester of acetoacetic acid, 3,7-dimethyl-octa-l,6-dien-3-yl acetate, ester 1,2-Diethyl acid, 1,2-benzenedicarboxylic acid, (z)-hex-3-enyl 2-methylpropanoate, (4-methyl-l-propan-2-yl-l-cyclohex-2-enyl acetate, 3a,4,5,6,7,7a-hexahydro-4,7-methanoinden-6-yl acetate, ethyl 2,3-epoxy-3-phenylbutyrate, methyl 2-aminobenzoate, methyl 2-(methylamino)benzoate, methyl benzoate, methyl 2,4-dihydroxy-3,6-dimethylbenzoate, (3r-(3alpha,3beta,6beta,7beta,8alpha))-octahydro-6-methoxy-3,6,8,8-tetramethyl-lh-3a,7-methanoazulene acetate, hexyl salicylate, 4-tert-butylcyclohexyl acetate, methyl palmitate, 1,6-octadien-3-ol, 3,7-dimethyl acetate and triethyl citrate.Preferably, examples of esters include linalyl propionate, cetyl acetate, cedryl acetate, anisyl acetate, nopyl acetate, neryl acetate, (3r-(3alpha,3beta,6beta,7beta,8alpha))-octahydro-6-methoxy-3,6,8,8-tetramethyl-1h-3a,7-methanoazulene, hexyl salicylate, 4-tert-butylcyclohexyl acetate, methyl palmitate, l,6-octadien-3-ol, 3,7-dhnethyl acetate, linalyl acetate and triethyl citrate.

[0075] Examples of ethers include, but are not limited to, benzyl ether, ethyl ether, ambergris, diphenyl oxide, 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene, carane amber, 1,1-dimethoxy-2,2,5-trimethyl-4-hexene, 3,4,4a,5,8,8a-hexahydro-3',7'-dimethylspiro(1,4-methanonaphthalene-2(1h),2'-oxirane), 2,4,6-trimethyl-4-phenyl-1,3-dioxane, benzene, 1,1'-oxybis, methyl 2-naphthyl ether, ethyl 2-naphthyl ether, 2,4-Dimethyl-4-phenyltetrahydrofuran, (ethoxymethoxy)cyclododecane, (e)-l-methoxy-4-(l-propenyl)-benzene, l-methoxy-4-(2-propenyl)-benzene, methyl cedryl ether, and 2-naphthyl ethyl ether. Preferably, examples of ethers include l,l-dimethoxy-2,2,5-trimethyl-4-hexene, methyl cedryl ether, and 2-naphthyl ethyl ether.

[0076] Examples of alcohols include, but are not limited to, menthol ([lr-(lalpha,2beta,5alpha)]-5-methyl-2-isopropylcyclohexanol), citronellol, geraniol, linalool (e.g., ethyl linalool and tetrahydro linalool), phenylethyl alcohol, terpineol, 2,6-dimethylheptan-2-ol, 2-methyl-l-phenylpropan-2-ol (dimethyl phenyl carbinol), 3-methyl-5-[2,2,3-trimethylcyclopent-3-en-l-yl]pent-4-en-2-ol, 2-phenylethanol, 2-ethyl-4-(2,2,3-trimethyl-l-cyclopent-3-enyl)but-2-en-l-ol, (e)-4-methyldec-3-en-5-ol, alcohol cinnamic acid (3-phenyl-2-propen-l-ol), 3,7-dimethyl-6-octen-l-ol, p-menth-l-en-8-ol, cis-hex-3-en-l-ol, 4-methyl-3-decen-5-ol, 2,6-dimethyloct-7-en-2-ol, l,l'-oxydipropan-2-ol, 3,7-dimethyl-1,6-nonadien-3-ol, 1,1'-oxydipropan-2-ol, 2,6-dimethyloct-7-en-2-ol 3,7-dimethyl octa-1,6-diene-3-ol, 2-ethyl-4-(2,2,3-trimethyl-3-cyclopenten-l-yl)-2-buten-l-ol, phenylmethanol, 4-methyl-3-decen-5-ol, 2,6-dimethyloctan-2-ol, 3,7-dimethyl-6-octen-l-ol, 4-(l,l-dimethylethyl)-cyclohexanol, (2e)-3,7-dimethyl-2,6-octadien-l-ol, hexan-l-ol, exo-l,7,7-trimethylbicyclo[2.2.1]heptan-2-ol, 2-(2,2,7,7-tetramethyltricyclo[6.2.1.0 (1,6)]undec-5(4)-en-5-yl)propan-1-ol, 1-phenylethanol, 1,1'-oxydipropan-2-ol, 3,7-dimethyloctan-3-ol, cis-3,7-dimethyl-2,6-octadien-l-ol, 3,7-dimethyl-6-octen-l-ol, hex-2-en-l-ol, 3,7-dimethyl octa-l,6-diene-3-ol, 2-methyl-4-phenylbutan-2-ol, 2,6-octadien-l-ol, 3,7-dimethyl-, (2e)-, p-menth-l-en-8-ol, 3-phenylpropan-l-ol, phenylmethanol, 2,6-dimethyloct-7-en-2-ol, alpha,beta,2,2,3-pentamethylcyclopent-3-ene-l-butanol, 3-(5,5,6-trimethylbicyclo[2.2.1]hept-2-yl)cyclohexan-l-ol (ibch), cis-3-hexen-l-ol, methyl-trimethylbicyclo-hexylmethyl-cyclopropyl methanol benzyl alcohol, endo-l,7,7-trimethyl-bicyclo-[2.2.1]heptan-2-ol, 3,7-dimethyl-6-octén-l-ol, 3,7-dimethyl-1-octanol, (2e)-3,7-dimethyl-2,6-octadien-l-ol, cis-3,7-dimethyl-2,6-octadien-l-ol, 3,7-dimethyl-octa-l,6-dien-3-ol, 2-(4-methyl-l-cyclohex-3-enyl)propan-2-ol, 4-methyl-l-(l-methylethyl)-3-cyclohexen-l-ol, (Ir, 2s, 5r)-5-methyl-2-(l-methylethyl)-cyclohexanol, (2e)-3,7-dimethyl-2,6-octadien-l-ol and 3-methylbutan-l-ol. Preferably, examples of alcohols include alpha,beta,2,2,3-pentamethylcyclopent-3-ene-l-butanol, 3-(5,5,6-trimethylbicyclo[2.2.1]hept-2-yl)cyclohexan-l-ol (ibch), cis-3-hexenol, methyl-trimethylbicyclo-hexylmethyl-cyclopropyl methanol, 3-methylbutan-1-ol, ethyl linalool, tetrahydro linalool and [lr-(lalpha,2beta,5alpha)]-5-meethyl-2-isopropylcyclohexanol (menthol).

[0077] Examples of aldehydes include, but are not limited to, linear alkanals comprising between 8 and 18 carbon atoms, 3,7-dimethyl-2,6-octadienal (citral), citronellal, cyclamen aldehyde, hydroxycitronellal, 3,7-dimethyl-2,6-octadienal, undecanal, alpha-methyl-4-(l-methylethyl)-benzenepropanal, 3-(4-isopropylphenyl)-2-methylpropanal, 2,4-dimethylcyclohex-3-ene-l-carbaldehyde, 2,4-dimethylcyclohex-3-ene-l-carbaldehyde, (2e)-2-dodecenal, octanal, lauryl aldehyde, nonanal, (e)-2-benzylideneoctanal, 2,4-dimethylcyclohex-3-ene-l-carbaldehyde, 3-(4-ethylphenyl)-2,2-dimethylpropanal, 4-hydroxy-3-methoxybenzaldehyde, 3-(4-tert-butylphenyl)-2-methylpropanal, 3-(4-tert-butylphenyl)propanal, 2,6,10-trimethylundec-9-enal, 4(octahydro-4,7-methano[5H]inden-5-ylidene)butanal, 3-(3-propan-2-ylphenyl)butanal, 7-hydroxy-3,7-dimethyloctanal (hydroxycitronellal, 3,7-dimethyl-7-hydroxyoctane-1-al), 4-(4-hydroxy-4-methylpentyl)cyclohex-3-ene-l-carbaldehyde, octahydro-5-methoxy-4,7-methano-lh-indene-2-carboxaldehyde, alpha-methylcinnamic aldehyde (2-methyl-3-phenyl-2-propenal), 4-methoxybenzaldehyde (anisic aldehyde), clO aldehyde (decanal), undec-10-enal, cl2 aldehyde (lauric or dodecanal), methylnonyl acetaldehyde (2-methylundecanal), cl6 aldehyde, c6 aldehyde (hexanal), cinnamaldehyde (3-phenyl-2-propenal), 3-ethyloxy-4-hydroxybenzaldehyde (ethylvanillin), hexylcinnamic aldehyde (2-benzylideneheptanal), 3-phenylbutanal (3-phenylbutyraldehyde), 2,4-Dimethylcyclohex-3-ene-l-carbaldehyde, 5-heptanal, 2,6-dimethylhept-5-enal, 4-hydroxy-3-methoxybenzaldehyde (vanillin), alpha-methyl-1,3-benzodioxole-5-propionaldehyde, 4-isopropylbenzaldehyde, 3,7-dimethyl-6-octenal, 3,7-dimethyl-2,6-octadienal, 4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-l-carboxaldehyde, trans-hex-2-enal, 2,4,6-trimethyl-3-cyclohexene-l-carboxaldehyde,2-(4-tert-butylbenzyl)propionaldehyde and benzaldehyde. Preferably, examples of aldehydes include 2,4-dimethylcyclohex-3-ene-l-carbaldehyde, 5-heptanal, 2,6-dimethyl-hept-5-enal, 4-hydroxy-3-methoxybenzaldehyde (vanillin), alpha-methyl-l,3-benzodioxole-5-propionaldehyde, citral, and benzaldehyde.

[0078] Examples of ketones include, but are not limited to, ionones, isomethylionone, methyl cedryl, (e)-l-(2,6,6-trimethyl-l-cyclohex-2-enyl)but-2-en-l-one (alpha-damascone), 3-methyl-2-[(2z)-pent-2-en-l-yl]cyclopent-2-en-l-one (cis-jasmone), 4-(4-methoxyphenyl)-butan-2-one, 4(3)-(4-methylpent-3-enyl)cyclohex-3-enecarbaldehyde, l-(l,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone, 3-methyl-4-(2,6,6-trimethyl-2-cyclohexenyl)-3-buten-2-one, (e)-4-(2,6,6-trimethyl-l-cyclohexen-l-yl)-3-buten-2-one, e)-4-(2,6,6-trimethylcyclohex-2-eneyl)-but-3-en-2-one, 7-methyl-2h-benzo-1,5-dioxepin-3(4h)-one, l-(2,6,6-trimethyl-l,3-cyclohexadienyl)-2-buten-l-one, methyl hydroxypyrone, 2,2,5-trimethyl-5-pentylcyclopentan-l-one, 1-(5,5-dimethyl-1-cyclohexenyl)pent-4-en-1-one, 3-methyl-4-(2,6,6-trimethyl-2-cyclohexenyl)-3-buten-2-one, 2-[2-(4-methyl-3-cyclohexen-l-yl)propyl]-cyclopentanone, l-(l,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone,(e)-4-(2,6,6-trimethyl-l-cyclohexen-l-yl)-3-buten-2-one, 4-phenylbutan-2-one, 2-cyclohexyl-l,6-heptadien-3-one, l-(5,5-dimethyl-l-cyclohexenyl)pent-4-en-l-one, 2-buten-l-one, l-(2,6,6-trimethyl-3-cyclohexen-l-yl)-, 2h-l-benzopyran-2-one, , 1 - spiro(4.5)-7-decen-7-yl-4-penten-1 -one and 1 - spiro(4.5)-6-decen-7-yl-4-penten-1 -one, (e) 1-(2,6,6-trimethyl-2-cyclohexen-1-yl)-2-buten-1-one, (e)-4-(2,6,6-trimethyl-l-cyclohexen-l-yl)-3-buten-2-one, dihydro-5-pentyl-2(3h)-furanone, 2,2,5-trimethyl-5-pentylcyclopentan-l-one, l-(l,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthalenyl)ethanone, methyl cedryl ketone, 7-methylbenzo[b][l,4]dioxepin-3-one, l,7,7-trimethylbicyclo[2,2,l]heptan-2-one, l-benzopyran-2-one (coumarin), l-(2,6,6-trimethyl-l-cyclohex-3-enyl)but-2-en-l-one, butan-2,3-dione (diacetyl), l-(l,2,3,4,5,6,7,8-octahydro-2,3,8,8,-tetramethyl-2-naphthyl)ethan-l-one, irones, l-(2-naphthalenyl)ethanone (2-acetonaphtone), menthone, carvone, 3-methyl-2-pentyl-2-cyclopentenone, l-(2,6,6-trimethyl-3-cyclohexen-l-yl)-2-buten-l-one, l-(2,6,6-trimethyl-2-cyclohexenyl)hepta-l,6-dien-3-one, 2-ethyl-3-hydroxy-4h-pyran-4-one, (5r)-2-methyl-5-prop-1-en-2-ylcyclohex-2-en-1-one, l-(6-tert-butyl-l,l-dimethyl-2,3-dihydro-lh-inden-4-yl)ethanone, l-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-l-one, 4-(2,6,6-trimethylcyclohex-2-enyl)-but-3-ene-2-one, octan-2-one, l-(l,2,3,4,5,6,7,8-octahydro-2,3,8,8-tetramethyl-2-naphthyl)ethan-l-one and the l,3,4,6,7,8a-hexahydro-l,l,5,5-tetramethyl-2h-2,4a-methanonaphthalen-8(5h)-one. Preferably, examples of ketones include irones, l-(2-naphthalenyl)ethanone (2-acetonaphtone), menthone, carvone, 3-methyl-2-pentyl-2-cyclopentenone, l-(l,2,3,4,5,6,7,8-octahydro-2,3,8,8-te-tramethyl-2-naphthalyl)ethan-l-one and l,3,4,6,7,8a-hexahydro-l,l,5,5-tetramethyl-2h-2,4a-methanonaphthalen-8(5h)-one.

[0079] Examples of lactones include, but are not limited to, gamma-decalactone (decan-4-olide), decan-5-olide, decan-4-olide, undecan-4-olide, gamma-undecalactone (undecan-4-olide), cis-jasmone lactone, gamma-undecalactone, delta-octalacone, delta-decalactone, and hexahydro-3,6-dimethyl-2(3h)-benzofuranone. Preferably, examples of lactones include gamma-undecalactone, delta-octalacone, delta-decalactone, and hexahydro-3,6-dimethyl-2(3h)-benzofuranone.

[0080] Examples of acetals include, but are not limited to, 2,4-dimethyl tetrahydroindenodioxine, phenylacetic aldehyde diacetal, phenylacetaldehyde glyceryl acetal, citral diethyl acetal, citral dimethyl acetal, 2,6-octadienal, 1,1-dimethoxy-2-phenylethane, and 3,7-dimethyl isomerized acid. Preferably, examples of acetals include phenylacetaldehyde glyceryl acetal, citral diethyl acetal, citral dimethyl acetal, 2,6-octadienal, and 3,7-dimethyl isomerized acid. 3,7-dimethyl isomerized.

[0081] Examples of nitriles include, but are not limited to, 3,7-dimethyloct-6-ene nitrile (citronellyl nitrile), tridec-2-enenitrile, 3-phenyl-2-propenenitrile, 3,7-dimethyl-6-enenitrile, dodecanenitrile, and 3,7-dimethylnona-2,6-dienenitrile. Preferably, examples of nitriles include tridec-2-enenitrile, 3-phenyl-2-propenenitrile, dodecanenitrile, and 3,7-dimethylnona-2,6-dienenitrile.

[0082] Examples of phenols include, but are not limited to, eugenol (2-methoxy-4-(2-propenyl)-phenol), iso-eugenol, 5-methyl-2-(l-methylethyl)-phenol, 2-ethoxy-4-methylphenol, 2-isopropyl-5-methylphenol, 5-methyl-2-(l-methylethyl)-phenol, 2,6-di-tert-butyl-p-cresol and 2-ethoxy-4-(methoxymethyl)-phenol.

[0083] Examples of acids include, but are not limited to, pentanoic acid, butyric acid and 2-methylpent-2-en-l-oic acid.

[0084] Examples of terpenes such as cyclic (e.g. sesquiterpenic) or non-cyclic terpene hydrocarbons include, but are not limited to, limonene, l-methyl-4-isopropenyl-l-cyclohexene, 1-methyl-4-isopropyl-1,4-cyclohexadiene, 7-methyl-3-methyleneocta-1,6-diene, l-methyl-4-(l-methylethyl)-l,3-cyclohexadiene, 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene, 6,6-dimethyl-2-methylenebicyclo[3.1.l]heptane, 2,2-dimethyl-3-methylenebicyclo-[2.2.1]-heptane, (3r-(3alpha,3abeta,6beta,7beta,8aalpha))-octahydro-6-methoxy-3,6,8,8-tetramethyl-lh-3a,7-methanoazulene, 4,11,1 l-trimethyl-8-methylene-(lr,4e,9s)-bicyclo[7.2.0.]Undec-4-ene, [lr,(lr*,4e,9s*)]-4,ll,ll-trimethyl-8-methylene-bicyclo[7.2.0]undec-4-ene, l-methyl-4-(l-methylethyl)benzene and sesquiterpene essential oils. Preferably, examples of terpenes include sesquiterpene-rich essential oils.

[0085] Examples of nitrogenous or sulfurous heterocyclic compounds, saturated or unsaturated, include, but are not limited to, indole, 1,3-benzopyrrole, tetrahydro-4-methyl-2-(2-methyl-l-propenyl)-2h-pyran, 2-methyl-pyrazine, 4-methyl-5-hydroxyethyl thiazole (2-(4-methylthiazol-5-yl)ethanol), 6-tert-butylquinoline, 6-(isopropyl)quinoline, (3ar-(3aalpha,5abeta,9aalpha,9bbeta))-dodecahydro-3a,6,6,9a-tetramethylnaphtho(2,lb)furan, 2-isopropyl-4-methyl-1,3-thiazole, cis-2-methyl-4-propyl-1,3-oxathiane, 6(8)-(l-methylpropyl)quinoline and the Pyrazines. Preferably, examples of nitrogenous or sulfurous heterocyclic compounds, saturated or unsaturated, include the 6-tert-butylquinoline, 6-(isopropyl)quinoline, cis-2-methyl-4-propyl-1,3-oxathiane, 6(8)-(l-methylpropyl)quinoline and pyrazines.

[0086] Examples of complex products of natural origin include, but are not limited to, essential oils extracted from the different parts of plants (flowers, stems, leaves, fruits, barks, roots, woody parts, herbs, needles, sap and gums), resinoids, concretes, or absolutes obtained from the latter. Preferably, examples of complex products of natural origin include white wormwood (Artemisia herba-alba) oil, pogostemon cablin leaf oil, citrus nobilis peel oil, barosma betulina leaf extract, lemon peel extract, eucalyptus globulus leaf oil, dipterocarpus turbinatus balsam oil, pogostemon cablin leaf oil, and rosmarinus officinalis leaf oil.Juniperus virginiana oil, field mint (Mentha arvensis) leaf oil, spearmint (Mentha viridis) leaf oil, citrus aurantium dulcis bark oil, citrus aurantium dulcis bark extract, Mediterranean cypress (Cupressus sempervirens) leaf oil, patchouli (Pogostemon cablin) leaf oil, Texas cedar (Juniperus mexicana) oil, and lavandula hybrida oil.

[0087] Preferably, the fragrance complex has a viscosity greater than that of water. More specifically, the viscosity of the fragrance complex is greater than 1000 mPas. More preferably, the viscosity of the fragrance complex is less than or equal to 200,000 mPas.

[0088] The perfume complex is thus configured to be introduced into packaging of different shapes and uses such as a roll-on or to be distributed using a spatula, etc.

[0089] According to a second aspect, the present invention relates to a perfume composition comprising the perfume complex described above preferably in an amount between 2 and 95% by weight of the total weight of the perfume composition.

[0090] Preferably, the perfume composition comprises the perfume complex and a diluent.

[0091] According to one possibility, in which the fragrance composition consists of the fragrance complex and the diluent. The total weight of the fragrance composition is understood to be the sum of the fragrance complex and the diluent.

[0092] Preferably, the diluent is an alcohol, for example ethanol.

[0093] According to one possibility, the perfumed composition comprising water.

[0094] According to one embodiment, the perfumed composition comprises materials first non-perfume ingredients such as colorants, UV filters and / or antioxidants.

[0095] According to another aspect, the invention relates to a method for preparing the perfume complex.

[0096] Advantageously, the process for preparing the perfume complex includes a first step of forming a pre-complex comprising the solubilizer, the solvent and the opacifier.

[0097] Advantageously, the process includes a second step of adding the perfume to the pre-complex to form a perfumed pre-complex.

[0098] Advantageously, the process includes a third step comprising heating the viscosifier, preferably to a temperature between 60°C and 80°C, preferably 70°C.

[0099] Advantageously, the process for preparing the fragrance complex further comprises a fourth step of forming the fragrance complex, which includes adding the viscosifier, previously heated, to the pre-fragrance complex. The fourth step comprises complete homogenization of the fragrance complex.

[0100] Preferably, the first and / or second and / or fourth stage does not include heating.

[0101] According to one embodiment, the pre-complex includes a portion of the solvent. This embodiment allows, when the fragrance used in the fragrance complex contains a quantity of solvent, for this quantity of solvent to be taken into account in the total quantity of solvent in the fragrance complex. The quantity of solvent added to the fragrance complex, and in particular to the pre-complex, is preferably reduced by the quantity of solvent already present in the fragrance. Preferably, the solvent of the fragrance and the solvent of the fragrance complex, in particular the pre-complex, are preferably identical.

[0102] According to another aspect, the invention relates to a method for preparing the fragrance composition. The method for preparing the fragrance composition comprises mixing the fragrance complex in an amount of between 2% and 95%, preferably between 3% and 30% by weight of the total weight of the composition, with a diluent. The diluent being, for example, preferably alcohol.

[0103] The fragrance complex and the fragrance composition are suitable for packaging in many types of containers suitable for a liquid composition. For example, but not limited to, tubes, bottles, sprays, atomizers, roll-ons, jars, brush pens with reservoirs, pencil pens with reservoirs, etc. Preferably, the preferred packaging is a roll-on or spray applicator. The fragrance complex can be presented ready-to-use or diluted in an alcoholic solution to form the more or less opalescent fragrance composition. coloured, and stable over time.

[0104] According to a particular embodiment, the perfume complex and / or the perfumed composition according to the invention further comprises at least one additive selected from the following: antioxidants, chelating agents, UV filters, preservatives, thickening agents, cosmetic active ingredients, moisturizing agents, humectants, softeners, pigments, colorants, refrigerating agents, pH adjusting agents, bactericidal agents, bacteriostatic agents, insecticides, repellents, glitter, actives, and mixtures thereof.

[0105] The present invention also relates to a cosmetic base comprising the composition or complex according to the present invention.

[0106] The term “cosmetic base” means a cosmetic product or a personal care product in the form of a cream, emulsion, foam, wax, oil, lotion, gel, suspension, mist, solution, powder, balm, serum, mask, or scrub. Examples of cosmetic products include, but are not limited to, perfumes, eau de parfum, eau de toilette for adults and babies, hair care products, shaving and aftershave products, essential oils, skin care products, deodorants, antiperspirants, depilatory products, self-tanning products, sunscreens, makeup products, body mist, etc.Examples of hygiene care include, but are not limited to, refreshing and / or cleansing wipes, talcum powder, nappies, bibs, tissues, paper towels, soaps, shower gels, shampoos and other body cleaning products, oral care, feminine hygiene products, air fresheners, deodorants, etc.

[0107] The present invention also relates to a detergent base comprising the composition or complex according to the present invention.

[0108] The term "detergent base" means maintenance or cleaning products. Examples of maintenance or cleaning products include, but are not limited to, surface, textile and dishwashing detergents, bleaching agents, fabric softeners, conditioners, washing machine or dryer fragrances, paint strippers, varnishes and other household products.

[0109] The present invention also relates to weed killers and fertilizers comprising the composition or complex according to the present invention.

[0110] The present invention also relates to an ambient fragrance comprising the composition or complex according to the present invention.

[0111] The term "air fragrance" refers to products intended to perfume the air. Air fragrance products may, but are not limited to, be contained in aerosols, vaporizers, sprays, candles, scented gels, solid carriers, oil burners, reed diffusers, incense, beads, and fragrance diffusers. The air fragrance of the present invention may be used in enclosed public and professional spaces. or private spaces; for example, cars, homes, administrative buildings, public transportation, museums, historical monuments, churches, cellars, schools, restaurants, cinemas, hospitals, factories, water or waste treatment plants, shops, and hotels. Air fresheners can also be used in air conditioning systems.

[0112] The present invention also relates to materials comprising or coated with the composition or complex according to the invention, in particular polymers such as plastics, macromolecules such as cellulose, etc. For example, the composition according to the invention may be used as a fragrance for linen, in particular as a pillow mist.

[0113] The composition or complex according to the invention is intended to be applied in concentrated or non-concentrated form in cosmetic bases, detergent bases or room fragrances.

[0114] The present invention also relates to the use of the composition or complex according to the invention to prepare a cosmetic composition, a detergent base or an ambient fragrance.

[0115] The present invention also relates to the use of the composition or complex according to the invention, of the cosmetic base, of the detergent base or of the room fragrance to mask bad odors.

[0116] By "bad odors," we mean odors that are detected by the human sense of smell and that are perceived as offensive or unpleasant. For the purposes of the present invention, the bad odors to be masked may result intrinsically from the cosmetic, detergent, or room fragrance base itself, or may originate from the external environment.

[0117] By "masking bad odors" is meant the modification of the qualitative perception of the odor by means of the addition of a substance or mixture of substances capable of providing a new, distinct and pleasant odor.

[0118] In a particular embodiment, the composition or complex according to the present invention masks unpleasant odors without degrading the molecules responsible for the unpleasant odors. Indeed, the molecules of the composition olfactorily mask the molecules responsible for the unpleasant odors.

[0119] The detailed embodiments above can be easily combined with each other in a non-limiting manner.

[0120] The invention is not limited to the embodiments described above and extends to all the embodiments covered and uses of the application. EXAMPLES

[0121] Example 1: composition of a perfume.

[0122] A perfume 1 is prepared according to the composition below. Parfum 1 composition IUPAC % l-(5,6,7,8-tetrahydro-3,5,5,6,8,8-hexamethyl-2-naphthyl)ethan-l-on e 21,9780 1,4-Dioxacycloheptadecane-5,17-dione 10,9890 4-tert-Butylcyclohexyl Acetate 8,7912 3-methyl-4-(2,6,6-trimethylcyclohex-2-en-l-yl)but-3-en-2-one 5,4945 (3aR-(3aalpha,5abeta,9aalpha,9bbeta))-Dodecahydro-3a,6,6,9a-tetramethylnaphtho(2,1 -b)furan 4,3956 benzyl acetate 4,3956 3,7-Dimethyl octa-l,6-diene-3-yl acetate 4,3956 oxacyclohexadecan-2-one 4,3956 Tetrahydro-4-methyl-2-(2-methylpropyl)-2H-pyran-4-ol 4,2154 (2E)-2-(phenylmethylidene)octanal 3,7363 benzyl 2-hydroxybenzoate 3,2967 Citrus Aurantium Dulcis Oil 3,2967 2-Phenylethanol 2,1978 2H-1 -Benzopyran-2-one 2,1978 4-(4-Hydroxyphenyl)butan-2-one 2,1978 2,2,2-Trichloro- 1-phenylethyl Acetate 1,7582 1,2,3-Triethyl 2-hydroxypropane-1,2,3-tricarboxylate 1,5613 4-hy droxy- 3 -methoxybenzaldehy de 1,0989 2-[(l-hydroxypropan-2-yl)oxy]propan-l-ol 0,9234 2-ethylhexyl 3-(4-methoxyphenyl)acrylate l-(4-tert-butylphenyl)-3-(4-methoxyphenyl)propane-l,3-dione 2-ethylhexyl salicylate 0,8791 1-phenylethyl acetate 0,8791 3-Ethoxy-4-hydroxybenzaldehyde 0,8791 2-ethyl-3-hydroxypyran-4-one 0,6725 3,7-Dimethyl octa-l,6-diene-3-ol 0,6593 , cis-Hex-3-en-l-ol 0,4400 (Z)-Hex-3-enyl acetate 0,4396 4-methyl-2-(2-methylprop-1 -en-1 -yl)tetrahydro-2H-pyran 0,3328 2-Phenoxyethyl 2-methylpropanoate 0,3297 1,1 -Dimethoxy-2-phenylethane 0,2637 2,2,5-Trimethyl-5-pentylcyclopentan-l-one 0,2429 1,2-diethyl benzene-1,2-dicarboxylate 0,2403 6-heptyltetrahydro-2H-pyran-2-one 0,2330 6-Hexyltetrahydro-2H-pyran-2-one 0,2242 4-Hydroxy-2,5-dimethylfuran-2(3H)-one 0,2198 3,7-dimethylocta-2,6-dien-1 -yl acetate 0,2198 methyl 2-aminobenzoate 0,2198 methyl (3-oxo-2-pentylcyclopentyl)acetate 0,2154 Pin-2(10)-ene 0,1539 3-(4-isobutyl-2-methylphenyl)propanal 0,1319 Ethyl butanoate 0,1099 n-Butyl acetate 0,1099 (3R-(3alpha,3abeta,6beta,7beta,8aalpha))-Octahydro-6-methoxy-3,6 ,8,8- tetramethyl-lH-3a,7-methanoazulene 0,1099 2-Buten-l-one, l-(2,6,6-trimethyl-3-cyclohexen-l-yl)- 0,1099 methyl oct-2-ynoate 0,0879 3,7-Dimethyl-6-octen-1 -ol 0,0646 5-heptyldihydrofuran-2(3H)-one 0,0440 (E / Z)-9-hydroxy-5,9-dimethyldec-4-enal 0,0440 GALBEX 183 EB 0,0308 3,4,4a,5,8,8a-Hexahydro-3',7'-dimethylspiro(l,4-methanonaphthalen e-2(lH),2'-oxirane) 0,0200 2-methyl-4-propyl-1,3-oxathiane 0,0200 2,4-dimethylcyclohex-3-ene-l-carbaldehyde 0,0169 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene 0,0077 , 3-hydroxy-2-methyl-4H-pyran-4-one 0,0077 2-(4-Methylthiazol-5-yl)ethanol 0,0066 (4-isopropylcyclohexyl)methanol 0,0044 Methyl 2,4-dihydroxy-3,6-dimethylbenzoate 0,0044 6-pentyltetrahydro-2H-pyran-2-one 0,0039 1 -(5,5-Dimethyl-1 -cyclohexenyl)pent-4-en-1 -one 0,0031 1 - {[4-(phenyldiazenyl)phenyl]diazenyl} -2-naphthol 0,0015 Barosma Betulina Leaf Extract is an extract of the leaves of Barosma betulina, Rutaceae 0,0011 Dimethyl sulphide 0,0007 5-methyl-2-(l-methyl-l-sulfanylethyl)cyclohexanone 0,00005

[0124] Exemple 2 : Pré complexe

[0125] Un pré complexe 1 selon l’invention comprenant un solubilisant, un solvant et un opacifiant est préparé selon le tableau ci-dessous

[0126] [Tableaux3] Pre Complex 1 Function IUPAC % SOLUBILISA NT Sorbitan monolaurate, ethoxylated 40 SOLVENT 2- [( 1 -hydroxypropan-2-yl)oxy ]propan-1 -ol 20 OPACIFIER D-Glucopyranose, oligomeric, C8-16-alkyl glycosides, methacrylic acid-styrene polymer 40

[0127] Example 3: Fragrance complexes

[0128] Fragrance complexes were prepared according to the table below. Their stability was then tested by centrifugation tests for 12 minutes at a speed of 5000 rpm carried out using a SIGMA brand centrifuge model 2-16 K or equivalent to create crystallization / solidification of the fragrance complex. Unstable formula Stable formula IUPAC FUNCTION Fragrance complex 1 g Fragrance complex 2 g PERFUME Fragrance 1 0.455 0.455 VIGILANT Octahydro-4,7-methano-Ih-in dene- 5-dimethanol 0.707 0.707 SOLUBILIZING, SOLVENT, OPACIFYING Pre-complex 1 0.238 0.238 SOLVENT 2-[(1-hydroxypropan-2-yl)oxy]propan-l-ol 0.25 TOTAL in g 1.4 1.650 A crystallization / solidification of the fragrance complex was observed for fragrance complex 1. Whereas fragrance complex 2 comprising at least 15% solvent by weight of the total weight of the fragrance complex, notably dipropylene glycol, does not exhibit this phenomenon.

[0130] Example 4: Fragrance complexes

[0131] Fragrance complexes were prepared according to the table below. Fragrance complex 4 contains the fragrance, thickener, solvent, and opacifier, but no solubilizer. Fragrance complex 3 is formulated with pre-complex 1 combined with the fragrance, thickener, and additional solvent. Their stability was tested by centrifugation tests for 12 minutes at a speed of 5000 rpm using a SIGMA 2-16 K centrifuge or equivalent to induce crystallization / solidification of the fragrance complex. Unstable formula Stable formula IUPAC FUNCTION Fragrance complex 4 g Fragrance complex 3 g PERFUME Fragrance 1 0.455 0.455 VISCOSANT Octahydro-4,7-methano-Ih-in dene-5-dimethanol 0.7071 0.7071 SOLUBILIZING, SOLVENT, OPACIFYING Pre-complex 1 0.238 SOLVENT 2-[(1-hydroxypropan-2-yl)oxy]propan-l-ol 0.1976 0.15 OPACIFYING D-Glucopyranose, oligomeric, C8-16-alkyl glycosides, methacrylic acid-styrene polymer 0.0952 TOTAL in g 1.455 1.5501

[0133] A crystallization / solidification of the fragrance complex was observed for fragrance complex 4. Whereas fragrance complex 3 comprising the solubilizer does not exhibit this phenomenon.

Claims

Demands

1. A fragrance complex comprising the following components: - a solvent selected from the group including propane-1,2-diol, 2-[(l-hydroxypropan-2-yl)oxy]propan-l-ol, 2-(2-ethoxyethoxy)ethanol, 2-methylpentane-2,4-diol, (2-methoxymethylethoxy)propanol, whether of natural or synthetic origin, or a mixture thereof; - a thickening agent, being tricyclodecane dimethanol; - a solubilizer selected from the group including polysorbate 20, PEG-30 hydrogenated castor oil, PEG-40 hydrogenated castor oil, PEG-17 glyceryl cocoate, a mixture of polyglyceryl-4 laurate / sebacate and polyglyceryl-6 caprylate / caprate, polyglyceryl-3 caprylate, caprylyl / capryl glucoside, decyl glucoside, heptyl glucoside, a mixture of PEG-26 buteth-26 and PEG-40 hydrogenated castor oil, or a mixture thereof, - an opacifier being a styrene / acrylates copolymer mixture and coco-glucoside, - a perfume, and not containing water.

2. Perfume complex according to claim 1 comprising the following components: - 10 to 60% solvent, - 5 to 75% viscosifying agent, - 0.2 to 16% solubilizer, - 0.2 to 16% opacifier, - a perfume in sufficient quantity to reach 100%, the percentages being expressed by weight relative to the total weight of the above components.

3. Perfume complex according to any one of the preceding claims comprising - 15 to 40% dipropylene glycol as solvent - 15 to 70% tricyclodecane dimethanol as thickener, - 0.3 to 8% polysorbate 20 as solubilizer, - 0.3 to 8% styrene / acrylates & coco glucoside copolymer as opacifier - perfume in sufficient quantity to reach 100%, the percentages being expressed by weight relative to the total weight of the above components.

4. Perfume complex according to any one of the preceding claims having a viscosity greater than 1000 mPas, and less than 200,000 mPas.

5. Perfumed composition comprising the perfume complex according to any one of the preceding claims and a diluent.

6. Perfumed composition according to the preceding claim, wherein it comprises from 2 to 95% perfume complex, by weight relative to the total weight of the composition.

7. Perfumed composition according to any one of the two preceding claims wherein the diluent is an alcohol.

8. Perfumed composition according to any one of the three preceding claims comprising water.

9. Perfumed composition according to any one of claims 5 to 7 not comprising water.

10. Perfumed composition according to any one of claims 5 to 9 and / or perfumed complex according to any one of claims 1 to 4 being opaque.

11. Use of the perfumed composition according to any one of claims 5 to 10 and / or of the perfume complex according to any one of claims 1 to 4 as all or part of a cosmetic base or a fine perfumery product or a room fragrance.