Improved ebullated bed reactor and process

Abstract

Improved ebullated bed reactors, methods for modifying existing ebullated bed reactors for improved performance, and related processes for improving the performance of ebullated reactors during hydroprocessing operations. In one aspect, the addition of a catalyst withdrawal outlet located at the top of the ebullated bed reactor allows fine spent catalyst to be withdrawn during reactor operation, and certain performance improvements can be realized.

Description

[Technical field]

[0001] CROSS-REFERENCE TO RELATED APPLICATIONS This application is a related application to U.S. Provisional Patent Application No. 63 / 299,406, entitled "IMPROVED EBULLATED BED REACTOR AND PROCESS," filed on January 13, 2022, and claims the benefit of priority to that provisional application, the disclosure of which is incorporated herein by reference in its entirety. The present invention relates to an improved ebullated bed reactor, a method for modifying existing ebullated bed reactors for improved performance, and related processes for improving the performance of ebullated reactors during hydroprocessing operations. [Background technology]

[0002] Ebullated bed reactors are a type of fluidized bed reactor that utilizes boiling, or bubbling, to achieve proper distribution of reactants and catalyst. Ebullated bed technology utilizes a three-phase reactor (liquid, vapor, and catalyst) and is best suited for feedstocks that are difficult to process in fixed-bed or plug-flow reactors, including those with exothermic reactions and high levels of contaminants. Ebullated bed reactors generally provide high quality, continuous mixing of liquid and catalyst particles and are characterized by stirred-reactor-type operation with fluidized catalyst. Advantages of ebullated bed reactors include, for example, good complete backmixed bed performance, excellent temperature control, and low and constant pressure drop with reduced bed plugging and channeling. Ebullated bed reactors are used in the hydroconversion of heavy petroleum and petroleum fractions, especially vacuum residua.

[0003] The catalyst used in ebullated bed reactors is typically a millimeter-sized extrudate held in a fluidized state with the liquid reactants and gas suspended therein. The liquid and gas enter through the reactor plenum and are distributed throughout the catalyst bed via a distributor and grid plate. The height of the boiling catalyst bed can be controlled by the flow rate of the liquid recycle. This liquid flow rate is adjusted by varying the speed of a boiling pump, e.g., a centrifugal pump that controls the flow of boiling liquid obtained from an internal vapor / liquid separator in the reactor. Fresh catalyst can be added to the reactor and spent catalyst can be withdrawn from the bottom of the reactor. Small amounts of fresh catalyst are generally added periodically to achieve the performance of the ebullated bed reactor to maintain product quality over long periods of time. The type of catalyst used can also be changed without shutting down the reactor, allowing operation to be adjusted and / or different feedstocks to be used.

[0004] The catalyst used is held in a fluidized state suspended in the liquid reactants (feedstock and recycle) and gas (hydrogen feed) which enter the reactor plenum and are distributed throughout the bed via a distributor and grid plate. The height of the boiling catalyst bed is controlled by the flow rate of the liquid recycle. This liquid flow rate is adjusted by varying the speed of the boiling pump (i.e. centrifugal pump) which controls the flow of boiling liquid obtained from an internal vapor / liquid separator inside the reactor.

[0005] The catalyst used in ebullated bed reactors typically has a cylindrical extruded shape with a diameter of about 1 mm and L / D = 1 to 6, or 2 to 4. As the catalytic activity in the reactor deteriorates due to coke and metal deposition, it is periodically (daily) withdrawn and added (about 1% to 5% of the total loading amount) to maintain a constant catalytic activity.

[0006] Although ebullated bed reactor technology and design have advanced over time leading to certain improvements, there is a continuing need for improved processes for utilizing ebullated bed reactors with both difficult to process feedstocks and improved designs that provide improved performance of ebullated beds for hydroprocessing applications. Summary of the Invention

[0007] The present invention relates to an improved ebullated bed reactor, a method for modifying an existing ebullated bed reactor for improved performance, and related processes for improving the performance of the ebullated reactor during hydroprocessing operations. One of the objectives of the present invention, but not necessarily limited thereto, is to provide a relatively uncomplicated and improved ebullated bed reactor design and a process for using said improved reactor to improve reactor operational performance.

[0008] In general, the ebullated bed (EB) reactor of the present invention includes a catalyst withdrawal outlet suitable for selectively withdrawing fine spent catalyst during reactor operation. Existing EB reactors may also be modified in accordance with the present invention by adding a catalyst withdrawal outlet suitable for selectively withdrawing fine spent catalyst during reactor operation. In some embodiments, the present invention allows for performance improvements in one or more ways via reduction and / or removal of fully or partially deactivated fine spent catalyst. Such improvements include, for example, reduced catalyst precipitates in the product from the ebullated bed reactor, reduced axial catalyst segregation, or a combination thereof, as well as other advantageous benefits.

[0009] The improved boil-up reactor may optionally include a catalyst withdrawal outlet located at the top of the EB reactor, which allows for the withdrawal of fine spent catalyst from the top of the reactor during operation.

[0010] It should be understood that the scope of the present invention is not limited by any of the representative drawings attached to this disclosure, but is defined by the claims of this application. [Brief description of the drawings]

[0011] [Figure 1] 1 is an illustration of a conventional ebullated bed (EB) reactor incorporating features according to the present invention. [Diagram 2] 1 is an illustration of comparative particle size distributions achieved in the inventive and comparative EB reactors described in the Examples. DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0012] Although exemplary embodiments of one or more aspects are provided herein, the disclosed processes may be implemented using any number of methods. The present disclosure is not limited to the exemplary or specific embodiments, drawings, and techniques illustrated herein, including any exemplary designs and embodiments illustrated and described herein, but may be modified within the scope of the appended claims, along with the full range of equivalents.

[0013] The following terms, nomenclature, and definitions are applicable to this disclosure unless otherwise specified. If a term is used in this disclosure but not specifically defined herein, the definition from the IUPAC Compendium of Chemical Terminology, 2nd ed (1997) may be applied, provided that such definition does not conflict with any other disclosure or definition applied herein or render any claim to which it applies unclear or unacceptable. In the event that any definition or usage set forth in any document incorporated herein by reference conflicts with the definition or usage set forth herein, the definition or usage set forth herein shall apply.

[0014] "Hydrocarbonaceous," "hydrocarbon," and similar terms refer to compounds containing only carbon and hydrogen atoms. When a particular group is present in the hydrocarbon, other identifiers may be used to indicate the presence of that particular group (e.g., a halogenated hydrocarbon indicates the presence of one or more halogen atoms replacing an equal number of hydrogen atoms in the hydrocarbon).

[0015] The terms "Hydrogen" or "hydrogen" refer to hydrogen itself and / or the compound(s) that provide a source of hydrogen.

[0016] "Hydroprocessing" refers to a process in which a carbonaceous feedstock is contacted with hydrogen and a catalyst at elevated temperature and pressure for the purpose of removing undesirable impurities and / or converting the feedstock into desired products. Examples of hydroprocessing processes include hydrocracking, hydrotreating, catalytic dewaxing, and hydrofinishing.

[0017] "Hydrocracking" refers to the process of hydrogenation and dehydrogenation accompanied by the cracking / cracking of hydrocarbons, e.g., converting heavier hydrocarbons to lighter hydrocarbons or converting aromatics and / or cycloparaffins (naphthenes) to non-cyclic branched paraffins.

[0018] "Hydrotreating" refers to the process of converting sulfur- and / or nitrogen-containing hydrocarbon feedstocks to hydrocarbon products having reduced sulfur and / or nitrogen content, typically in combination with hydrocracking, and producing hydrogen sulfide and / or ammonia (respectively) as by-products.

[0019] "Processing," "processed," "upgrade," "upgraded," and "upgraded," when used in conjunction with an oil feed, describe a hydrotreated or hydrotreated feedstock, or a resulting material or crude product, with a reduction in the molecular weight of the feedstock, a reduction in the boiling range of the feedstock, a reduction in the concentration of asphaltenes, a reduction in the concentration of hydrocarbon free radicals, and / or a reduction in the amount of impurities such as sulfur, nitrogen, oxygen, halides, and metals.

[0020] The term "support", particularly when used in the term "catalyst support", refers to conventional materials, typically solids with a large surface area, that support catalytic materials. Support materials may be inert or may participate in the catalytic reaction and may be porous or non-porous. Typical catalyst supports include various types of carbon, alumina, silica and silica-alumina, such as amorphous silica aluminates, zeolites, alumina-boria, silica-alumina-magnesia, silica-alumina-titania, as well as materials obtained by adding other zeolites and other composite oxides.

[0021] "Molecular sieve" refers to a material that has pores of uniform molecular size within a framework structure such that, depending on the type of molecular sieve, only certain molecules can access the pore structure of the molecular sieve, while other molecules are excluded, for example, due to molecular size and / or reactivity. Zeolites, crystalline aluminophosphates, and crystalline silicoaluminophosphates are representative examples of molecular sieves.

[0022] The term "bulk catalyst" may be used interchangeably with "unsupported catalyst" to mean that the catalyst composition is not in the traditional catalyst form having a preformed shaped catalyst support that is then loaded with metals by catalyst impregnation or deposition. In one embodiment, the bulk catalyst is formed by precipitation. In another embodiment, the bulk catalyst includes a binder incorporated into the catalyst composition. In yet another embodiment, the bulk catalyst is formed from metal compounds without a binder. In a fourth embodiment, the bulk catalyst is a dispersed type catalyst ("slurry catalyst") for use as catalyst particles dispersed in a mixture of liquids (e.g., hydrocarbon oils).

[0023] The term "heavy oil" feedstock or feedstock refers to heavy and extra heavy crude oils, including, but not limited to, residual oil, coal, bitumen, tar sands, and the like. Heavy oil feedstocks may be liquid, semi-solid, and / or solid. Examples of heavy oil feedstocks that may be upgraded as described herein include, but are not limited to, Canadian tar sands, the Santos and Campos Basins of Brazil, the Gulf of Suez of Egypt, Chad, Zulia of Venezuela, Malaysia, and vacuum residues of Sumatra, Indonesia. Other examples of heavy oil feedstocks include "bottom of the barrel" and "residual oil" (i.e., "residuals"), residual oils left over from refining processes, including atmospheric bottoms having a boiling point of at least 343°C (650°F), vacuum bottoms having a boiling point of at least 524°C (975°F), or "resid pitches" and "vacuum residues" having a boiling point of 524°C (975°F) or higher.

[0024] Although compositions and methods or processes are often described in this disclosure in terms of "comprising" various components or steps, the compositions and methods may "consist essentially of" or "consist of" the various components or steps, unless otherwise indicated.

[0025] The terms "a," "an," and "the" are intended to include multiple options, e.g., at least one. For example, a "transition metal" or "alkali metal" as disclosed is meant to encompass one or a mixture of multiple transition metals or alkali metals or combinations thereof, unless otherwise specified.

[0026] All numerical values ​​within the detailed description and claims herein are modified by "about" or "approximately" the indicated value to account for experimental error and variations that would be expected by one of ordinary skill in the art.

[0027] In one aspect, the present invention relates to a novel ebullated bed (EB) reactor with a catalyst withdrawal outlet suitably located to allow for withdrawal of fine spent catalyst during reactor operation. The term "fine spent catalyst" is intended to refer to catalyst withdrawn from the top withdrawal outlet, but is not necessarily limited thereto. Typically, such withdrawn catalyst particles have a size in the range of about 0.01-3 mm, or 0.1-1 mm (depending in part on the size of the unused catalyst), and include extruded catalyst fragments. Additionally, catalyst solids, referred to as "ultrafine solids", having particle sizes less than about 0.01 mm, are carried out of the reactor into the liquid product as inorganic precipitates. The catalyst withdrawal outlet may be conveniently located at or near the top of the EB reactor. By positioning a tube, pipe, or other catalyst withdrawal conduit with an opening at one end within the height range of the operating EB bed and the other end connected to a catalyst withdrawal outlet, fine spent catalyst can flow through the tube, pipe, or other conduit and be withdrawn from the reactor through the catalyst withdrawal outlet. In contrast to conventional ebullated bed (EB) reactors in which operationally active catalyst is typically withdrawn from the bottom of the EB reactor during operation, the present EB reactor allows for the selective withdrawal of fine spent catalyst from the reactor while leaving the majority of the remaining active catalyst within the reactor.

[0028] The terms "operationally active catalyst" (as used herein with respect to a conventional EB reactor), as well as "fines spent catalyst" and "residual active catalyst" (as used with respect to the inventive EB reactor described herein) are relative terms that depend on various parameters including, for example, the properties of the unused catalyst, the reactor operating conditions, and the catalyst withdrawal procedures and conditions. In conventional EB reactors, i.e., EB reactors of the present invention that do not have a fines spent catalyst withdrawal outlet at the top, the spent catalyst is withdrawn from the bottom of the reactor and is typically large in size and denser compared to the average catalyst properties of the EB reactor. The catalyst remaining in a conventional EB reactor is considered operationally active because the remaining catalyst particles, on average, have activity within the operating specifications. In contrast, in the inventive EB reactor, the "fines spent catalyst" is withdrawn from the top, which removes catalyst particles that are typically denser and smaller in size than the average catalyst in the reactor, i.e., the "residual active catalyst". Such "fines spent catalyst" typically has little or no remaining catalytic activity, and its removal increases the average particle size of the remaining active catalyst in the reactor, improving overall catalytic activity.

[0029] The term "fine spent catalyst" may generally be characterized based on average particle size or particle size range, or percentage, relative to the particle size of unused catalyst. For example, based on percentage, "fine spent catalyst" may be within up to about 30%, or 20%, or 10%, or 5%, or 2%, or 1% of the average particle size, particle size range, and / or length / diameter (L / D) or L / D range of unused catalyst. For example, for typical EB extruded catalyst particles, including catalysts having a diameter of about 1 mm and L / D=1-6, or 2-4, the "fine spent catalyst" particle size typically varies between about 0.01-3 mm, or 0.1-1 mm.

[0030] The present invention is also suitable for modifying existing conventional EB reactors, in which catalyst is withdrawn from the bottom of the EB reactor, with the provision of a catalyst withdrawal outlet, which may optionally be located at or near the top of the EB reactor. The modified EB reactor is also modified to include a tube, pipe, or other catalyst withdrawal conduit connected to the catalyst withdrawal outlet, such that fine spent catalyst may flow through the tube, pipe, or other conduit and be withdrawn from the reactor through the catalyst withdrawal outlet during operation of the EB reactor.

[0031] The present invention further relates to a method for improving the performance of an ebullated bed (EB) reactor, comprising selectively withdrawing fine spent catalyst from a catalyst withdrawal outlet during operation of the EB reactor, providing at least one improvement comprising reducing and / or removing fully or partially deactivated fine spent catalyst, reducing catalyst precipitates in the product from the ebullated bed reactor, reducing axial catalyst segregation, or a combination thereof.

[0032] Advantages associated with the present EB reactor, the present modified EB reactor, and / or the present method include reduction and / or removal of fully or partially deactivated spent catalyst fines from the EB reactor during operation, reduction of catalyst precipitates in the product from the EB reactor, reduction of axial catalyst segregation during operation of the EB reactor, improved reactor volume utilization, improved reactor operating efficiency and / or catalyst activity, improved ability to maintain a well-defined interface between the two-phase and three-phase zones during operation of the reactor, reduced catalyst attrition rate, and reduced risk of reactor instability and / or loss of catalyst bed level control. Such advantages include combinations of each of the foregoing advantages.

[0033] In certain embodiments, the present and / or modified EB reactors include catalyst withdrawal tubes, pipes, or other catalyst conduits that extend into the expanded catalyst bed during operation, and in some embodiments, extend at least about 2%, or 4%, or 6%, or 10%, or 20%, or 30%, or 40%, or 50% from the top of the expanded catalyst bed during operation, the distance from the top expressed as a percentage of the total expanded bed height. Although not necessarily limited or required, the dimensions of the catalyst withdrawal tubes in typical embodiments range from 2 to 6 inches in diameter, more particularly, from 2 to 4 inches in diameter. The catalyst withdrawal tubes may also be positioned such that the opening of the tube faces downward. Hydrogen may be passed downward through the tubes when the catalyst is not being withdrawn during reactor operation to reduce coke formation.

[0034] In another aspect, the invention relates to the operation of the present EB reactor and / or modified EB reactors in which fine spent catalyst may be continuously or periodically withdrawn from the EB reactor during operation. For example, the improvements described herein may be achieved by scheduling the periodic withdrawal of fine spent catalyst such that a certain percentage or amount of fine spent catalyst is withdrawn from the EB reactor. Continuous withdrawal is also possible and may allow for more automated process control of the EB reactor operation.

[0035] During operation of the EB reactor, the constant movement of catalyst particles within the bed causes attrition, which very slowly erodes the catalyst particles and breaks them into smaller pieces. Some of these very small catalyst fines are constantly discharged from the reactor with the process effluent. However, some very short catalyst particles, or fines, are not small enough to be carried away by the process effluent into the reactor and may even be concentrated at the top of the catalyst bed and separated from the bulk particle population in the catalyst bed. The accumulation of fine spent catalyst at the top of the reactor bed can cause operational problems. For example, a level-indicating density detector used to detect the expanded catalyst bed height during normal operation may misinterpret the fine spent catalyst at the top of the reactor bed as the normal expanded bed height of the catalyst bed and reduce the recycle pump speed, which causes a large portion of the catalyst bed to settle on the distribution grid.

[0036] Inorganic precipitates formed in the liquid product due to catalyst depletion can also cause fouling of downstream equipment such as heat exchangers and distillation columns. Drawing off fine particles of fine spent catalyst at the surface of the ebullated bed can reduce entrainment in the internal recycle pumps and reduce the amount of ultra-fines carried away by the liquid product to downstream equipment.

[0037] Axial catalyst segregation can also be a problem during operation of conventional EB reactors. For example, axial catalyst segregation as a function of size and density can exist in EB reactors and provide some benefits, but such segregation can also promote plug-flow-like catalyst migration from unused catalyst at the top of the catalyst bed to an accumulation of the most used catalyst at the bottom of the reactor bed (i.e., where conventional catalyst withdrawal nozzles are located). Thus, axial catalyst segregation can also cause accumulation of fine spent catalyst at the top bed surface, which, due to its small size, causes little or no migration to the bottom withdrawal nozzle.

[0038] The present invention also provides beneficial improvements in reactor operating efficiency and / or overall catalyst activity. For example, during normal EB operation and maintenance, the reactor is emptied for maintenance to eliminate the reactor's catalyst load, a certain amount of spent catalyst is discarded, and the remaining catalyst is retained for the next operating cycle. The first few batches of spent catalyst drawn from the bottom of a conventional EB reactor contain large amounts of dense metal contaminants and are discarded. The same amount of unused catalyst is then replenished when the EB reactor is restarted.

[0039] However, during one routine maintenance cycle of the EB reactor, the same amount of spent catalyst was withdrawn during the commissioning run according to the previous operating cycle, but the total amount of catalyst discarded was divided between the beginning and the end of the run to eliminate the catalyst hold-up. The same amount of spent catalyst was withdrawn and discarded from both the bottom and the top of the bed, instead of only from the bottom withdrawal outlet (as per the normal maintenance cycle procedure). After the start-up of the new operating cycle, it was shown that the activity of the catalyst in the reactor was higher than in the previous cycle, and the loading rate of unused catalyst was lower than in the previous cycle. This surprising result indicates that the fine spent catalyst in the upper zone of the reactor has a lower catalytic activity, which may reduce the operating efficiency of the reactor.

[0040] Reactor instability during reactor operation and the risk of loss of a well-defined interface between the two-phase and three-phase zones are concerns for the operation of conventional EB reactors. In general, the catalyst bed expands according to the rotation speed (liquid flow rate) of the internal recycle pump, which is controlled by the flow of liquid fed through the internal recycle pump and the elevation of the interface between the two-phase and three-phase zones. Accumulation of fine spent catalyst at the interface can potentially cause false signals to the pump to reduce or increase the pump speed. Indeed, in at least one case, the internal recycle pump speed was reduced to cause catalyst bed settling in the three-phase zone, resulting in the formation of hot spots that led to emergency shutdowns and production halts for several days. Removal of catalyst fines at the two-phase / three-phase interface according to the present invention makes it possible to avoid such cases and improve the operational reliability of the EB reactor.

[0041] An illustration of an ebullated bed (EB) reactor, or modified EB reactor, according to the present invention is shown in FIG. 1. As shown in FIG. 1, the EB reactor 10 includes an upper two-phase gas / liquid zone 20a and a bottom three-phase gas / liquid / solid zone 20b, with a conventional expanded catalyst bed height 20 separating the two zones. A distributor grid 30 is disposed in the lower region of the reactor and contains catalyst in the three-phase zone 20b. A recycle pump 40, gas / liquid feed inlet 50, and a bottom catalyst withdrawal line 60 are shown disposed at the bottom of the reactor. A reactor effluent outlet 70, catalyst addition inlet 80, density detector source well 90, and thermowell nozzle 100 are disposed at the top of the reactor. A top catalyst withdrawal outlet 110 is also shown disposed at the top of the reactor, with the withdrawal line extending below the top surface of the expanded catalyst bed height 20.

[0042] Suitable catalysts for use in EB reactors and related processes include any of the suitable catalysts conventionally used in EB reactors. A variety of suitable catalysts are described in the patent literature, such as U.S. Pat. Nos. 9,206,361 and 9,169,449 (for details regarding particulate catalysts, see U.S. Pat. Nos. 7,803,266, 7,185,870, 7,449,103, 8,024,232, 7,618,530, 6,589,908, and 6,589,908). (See U.S. Patent Publications Nos. 6,667,271, 7,642,212, 7,560,407, 6,030,915, 5,980,730, 5,968,348, 5,498,586, and U.S. Patent Publications Nos. 2011 / 0226667, 2009 / 0310435, and 2011 / 0306490.) The catalyst used in the ebullated bed is typically, but not limited to, a millimeter diameter size extrudate containing nickel-molybdenum active metals. EXAMPLES

[0043] To evaluate catalyst particle segregation and the benefits of removing fine spent catalyst from an operating EB reactor, model studies and operational testing of a commercial EB reactor were conducted.

[0044] Example 1 Tests were performed in a cold flow model of a tubular reactor to evaluate catalyst particle segregation dynamics in comparison to an operating EB reactor performance. In one study, a 2-inch ID column was used to test catalyst segregation under ebullated bed conditions that are hydrodynamically similar to an operating EB reactor. EB reactor operation was previously thought to occur under fully backmixed conditions with minimal axial segregation (from top to bottom along the length of the reactor), but these studies showed that axial catalyst segregation as a function of size and density can occur based on normal bed expansion and gas / liquid velocities.

[0045] Example 2 During the operation of a commercial EB reactor, catalyst was withdrawn from the top of the reactor and the bottom of the reactor to compare particle size distribution. A lower catalyst sample was removed from just above the distributor grid tray, and an upper catalyst sample was removed approximately 2 m below the top of the expanded catalyst bed surface. The samples were washed of solvent with toluene using a Soxhlet, and then the particle size and distribution were determined by Cam Sizer analysis.

[0046] The results of both the top and bottom catalyst pulls are shown in Table 1. [Table 1]

[0047] Figure 2 shows the particle size distribution (L / D) of spent catalyst withdrawn from the top of an operating EB reactor and catalyst withdrawn from the bottom of the same reactor. From Figure 2, it can be seen that the particle size distribution of the fine spent catalyst withdrawn from the top of the reactor is shifted to smaller L / D particle sizes, while the catalyst withdrawn from the bottom of the reactor has a larger L / D particle size distribution.

[0048] Example 3 During operation of the commercial EB reactor system, approximately 10% of the equilibrium catalyst from each of the three EB reactors was discarded and replaced with unused catalyst. Results indicate that the oldest and most inactive spent catalyst was discarded. After returning to operation, the units demonstrated improved performance compared to the previous run at the same normal reactor temperature and liquid hourly space velocity (LHSV), with a 5%-7% increase in conversion at 560°C, an approximately 6% increase in total reactor heat generation across the three EB reactor systems, and an approximately 3% improvement in overall hydrodesulfurization (HDS). Further evaluation of these improvements indicated that withdrawing the fine spent catalyst from the top of the reactor bed reduced the particle population of low activity catalyst (i.e., smaller catalyst particles) present in the reactor, leading to significant performance improvements.

[0049] It will be recognized that the foregoing description of one or more embodiments of the invention is primarily for purposes of illustration and that modifications may be employed which still remain incorporated within the essence of the invention. In determining the scope of the invention, reference should be made to the following claims.

[0050] For purposes of United States patent practice, and where permitted, in other patent offices, any patents and publications cited in the above description of the invention are hereby incorporated by reference to the extent that any information contained therein is consistent with and / or supplements the above disclosure.

Claims

1. 1. An ebullated bed reactor comprising a catalyst withdrawal outlet suitable for selectively withdrawing finely divided spent catalyst during operation of said ebullated bed reactor.

2. 1. A modified ebullated bed reactor comprising an ebullated bed reactor modified by adding a catalyst withdrawal outlet suitable for selectively withdrawing fine spent catalyst during operation of an existing ebullated bed reactor.

3. 1. A method for improving performance of an ebullated bed reactor, comprising: selectively withdrawing the fine spent catalyst from a catalyst withdrawal outlet during operation of the ebullated bed reactor, the method providing at least one improvement comprising reducing and / or removing fully or partially deactivated fine spent catalyst, reducing catalyst precipitates in a product from the ebullated bed reactor, reducing axial catalyst segregation, or a combination thereof.

4. 4. The ebullated bed reactor of claim 1, the modified ebullated bed reactor of claim 2, or the method of claim 3, wherein a catalyst withdrawal outlet is disposed at the top of the reactor from which finely divided spent catalyst is withdrawn.

5. 10. The ebullated bed reactor of claim 1, the modified ebullated bed reactor of claim 2, or the method of claim 3, wherein the length / diameter (L / D) of the fine spent catalyst is within a range of up to about 30%, or 20%, or 10%, or 5%, or 2%, or 1% of the length / diameter (L / D) or L / D range of the unused catalyst used in the reactor.

6. 6. The ebullated bed reactor, modified ebullated bed reactor or method according to any of claims 1 to 5, wherein the volumetric utilization of the reactor is improved by withdrawing the fine spent catalyst from the catalyst withdrawal outlet.

7. 7. The ebullated bed reactor, modified ebullated bed reactor or method according to any of claims 1 to 6, wherein the reactor operating efficiency and / or catalytic activity is improved by withdrawal of the fine spent catalyst from the catalyst withdrawal outlet.

8. 8. The ebullated bed reactor, modified ebullated bed reactor or method according to any of claims 1 to 7, wherein the catalyst attrition rate is reduced by withdrawing the fine spent catalyst from the catalyst withdrawal outlet.

9. 9. The ebullated bed reactor, modified ebullated bed reactor or method according to any of claims 1 to 8, wherein the risk of reactor instability and / or loss of control of catalyst bed level is reduced by withdrawal of said fine spent catalyst from said catalyst withdrawal outlet.

10. 10. The ebullated bed reactor, modified ebullated bed reactor or method according to any of claims 1 to 9, wherein the ability to maintain a well-defined interface between the two-phase zone and the three-phase zone during reactor operation is improved by withdrawal of said fine spent catalyst from said catalyst withdrawal outlet.

11. 11. The ebullated bed reactor, modified ebullated bed reactor, or method according to any of claims 1 to 10, wherein the catalyst withdrawal outlet comprises a catalyst withdrawal pipe extending from an upper portion of the reactor to the catalytic zone within the reactor during operation of the reactor.

12. 12. The ebullated bed reactor, modified ebullated bed reactor, or method of claim 11, wherein the catalyst withdrawal pipe extends up to about 50%, or 40%, or 30%, or 20%, or 10%, or 5%, or 2%, or 1% of the expanded catalyst bed height during operation.

13. 13. The ebullated bed reactor, modified ebullated bed reactor, or method of any of claims 1 to 12, wherein the catalyst withdrawal outlet is configured for continuous or periodic withdrawal of the fine spent catalyst.

14. 4. The method of claim 3, wherein catalyst is selectively withdrawn by periodic catalyst withdrawal from said catalyst withdrawal outlet.

15. 15. The method of claim 14, wherein the periodic withdrawal of the catalyst is based on a lump-sum withdrawal of a portion of the fines spent catalyst.

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