The application belongs to the technical field of
thermoplastic polyester imides, and particularly relates to a
biphenyl-bridged
thermoplastic polyester imide, a preparation method thereof, a
biphenyl-bridged
thermoplastic polyester imide film and application. The
biphenyl-bridged thermoplastic polyester
imide is polymerized from biphenyl diphenylate-3,3',4,4'-tetracarboxylic dianhydride, 3,3',4,4',-biphenyl tetracarboxylic dianhydride and 2-(4-aminobenzoate)-5-aminobiphenyl. The biphenyl-bridged thermoplastic polyester imide provided by the application has a linear
thermal expansion coefficient close to that of
copper foil, and excellent thermoplasticity, high-temperature dimensional stability and
dielectric properties.