The invention relates to a roll-to-roll plasma device for enhancing chemical vapor deposition, which is characterized in that the device comprises a roll-out roller (2), a winding roller (11), a heating cavity (15), a vertical transmission rail (3), a rail (16), tension pulley groups (4,6,13) and a cooling roller (12), wherein the rail (16) connected with a horizontal transmission rail (20) and arranged in a vacuum chamber (22) is used for feeding deposited flexible matrix material into the winding roller (11); the tension pulley groups (4,6,13) are respectively arranged in a vacuum chamber (1), the vacuum chamber (22) and the heating chamber (15) and used for keeping the tensile force of the matrix material in the transmission process, and the cooling roller (12) is arranged in the vacuum chamber (22) and used for cooling the deposited flexible matrix material loaded on the winding roller (11). The device greatly improves the transport efficiency of the flexible matrix in the vacuum cavity, furthermore accurately controls the surface tension of the matrix at high temperature conveniently, and greatly reduces the phenomenon of uneven surface of the flexible matrix caused by thermal contraction at high temperature.