Sodium-ion battery health state estimation method in energy storage scene

By establishing a complete attenuation data set and correlation analysis of sodium ion battery, combining the integral gradient algorithm and KAN network, the Temporal Residual KAN-LSTM network model was used to solve the problem of insufficient estimation accuracy of sodium ion battery health status, and achieve high accuracy and Interpretable health status estimation significantly improves the SOH estimation effect in energy storage applications.

CN119270088AActive Publication Date: 2025-01-07HENAN INST OF SCI & TECH

Patent Information

Application Number
CN202411794467.8
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-12-09
Publication Date
2025-01-07
Estimated Expiration
2044-12-09

AI Technical Summary

Technical Problem

The long-term stability and reliability challenges of sodium ion batteries in energy storage applications, especially due to the lack of long-term use and experimental data, the existing health status estimation methods are insufficiently accurate, especially in terms of capacity management and energy scheduling.

Method used

A method of estimating the health status of sodium ion batteries in energy storage scenarios was adopted. By establishing a complete battery attenuation data set with standard and lower charging rate, the battery degradation characteristics were extracted, and the characteristics were screened using Spearman, Kendall and Pearson correlation analysis methods, combined with integral Gradient algorithm and KAN network are used for feature screening, and finally, the health status estimation is used using the Temporal Residual KAN-LSTM network model.

Benefits of technology

High-precision estimation of health status of sodium ion batteries and its interpretability are achieved, improving the adaptability to complex timing data, and significantly better than the SOH estimation accuracy and robustness of other models in energy storage applications.

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Abstract

The invention provides a sodium ion battery health state estimation method in an energy storage scene. The method comprises the following steps: establishing a sodium ion battery complete attenuation data set under two working conditions and extracting a plurality of battery degradation characteristics; respectively measuring the correlation between the battery degradation characteristics and the SOH by using three correlation analysis methods, and carrying out preliminary screening on the battery degradation characteristics and the SOH to obtain battery degradation characteristics after preliminary screening; carrying out secondary feature screening by using an integral gradient algorithm, and carrying out interpretability analysis by using a KAN network as an agent model, so as to obtain a feature combination with relatively strong contribution to battery life prediction; and the battery degradation features in the feature combination are sent to a Temporal Residual KAN-LSTM network model for training, and the SOH of the sodium ion battery is estimated, so that high-precision SOH estimation and interpretability of the sodium ion battery are realized.
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Description

Technical Field

[0001] The present invention relates to the technical field of sodium ion battery health state estimation, and in particular to a method for estimating the health state of a sodium ion battery in an energy storage scenario. Background Art

[0002] Sodium-ion batteries have gradually shown their potential to replace lithium-ion batteries due to their abundant resources, low cost and environmental advantages. In addition, the high material stability, good cycle performance and low operating voltage of this type of battery make it safer and more reliable in large-scale energy storage applications. However, their long-term stability and reliability in energy storage applications remain challenging due to the unique aging mechanism and limited existing state of health (SOH) estimation data. With the improvement of sensor technology and data storage capabilities, data-driven battery SOH estimation methods have gradually become mainstream. With the help of deep learning models, these methods are able to use a large amount of historical data and real-time monitoring data to automatically learn the complex patterns of battery aging and achieve accurate predictions. However, there are still many challenges in the current development of sodium-ion batteries. Compared with lithium-ion batteries, sodium-ion batteries are still in the early stages of development and lack long-term use and experimental data. Existing research mainly focuses on lithium-ion vehicle battery management systems, while energy storage systems have higher requirements for SOH estimation accuracy, especially in capacity management and energy scheduling. Summary of the invention

[0003] In response to the needs in the prior art, the present invention provides a method for estimating the state of health of a sodium ion battery in an energy storage scenario, aiming to achieve high-precision SOH estimation of a sodium ion battery and its interpretability.

[0004] A method for estimating the health status of a sodium ion battery in an energy storage scenario comprises the following steps: Step 1: Establish a complete attenuation data set for sodium-ion batteries at two operating conditions: standard charge rate and lower charge rate; Step 2: Extract several battery degradation features based on the complete attenuation data set of sodium-ion batteries; Step 3: Use the three correlation analysis methods of Spearman, Kendall and Pearson to measure the linear correlation, nonlinear monotonicity and rank order consistency between the battery degradation characteristics and SOH respectively, and preliminarily screen the battery degradation characteristics and SOH to obtain the battery degradation characteristics after preliminary screening; Step 4: The battery degradation features after the initial screening are subjected to secondary feature screening using the integral gradient algorithm, and the KAN network is used as a proxy model for interpretability analysis, thereby obtaining a feature combination that contributes strongly to battery life prediction; Step 5: The battery degradation features in the feature combination are sent to the Temporal Residual KAN-LSTM network model for training. The output of the Temporal Residual KAN-LSTM network model is the estimated health state of the sodium-ion battery.

[0005] Further: The Temporal Residual KAN-LSTM network model includes a first-layer LSTMCell, a second-layer LSTMCell and a third-layer KAN network. The first-layer LSTMCell and the second-layer LSTMCell are both the smallest units of LSTM. The data passes through the first-layer LSTMCell and the second-layer LSTMCell in sequence and is sent to the third-layer KAN network. The output result of the third-layer KAN network is dynamically residually connected to obtain the final SOH result.

[0006] Further: The battery characteristic data is recorded as a time series Xt, where each time step t contains the state characteristics of the battery, and the data dimension of Xt is , is the feature dimension, and the time series length is , each time step The final output of the corresponding Temporal Residual KAN-LSTM network model is , which is the final SOH result, the batch size is defined as , the final output feature dimension is , then the final output of the Temporal Residual KAN-LSTM network model in the time dimension is expressed as:

[0007] in, and is a learnable weight parameter used to balance the contributions of different paths, and They are the hidden states of the first and second layers of LSTMCell corresponding to the t-th time step; and is the projection matrix, and is the corresponding bias vector, is the hidden state of LSTMCell, is the output of the KAN layer, and is a univariate nonlinear function.

[0008] Further, in step 1, the standard charging rate is: the battery is first charged at a constant current of 1C to a set voltage, and then switched to a constant current and constant voltage charging mode of 0.5C until the voltage reaches 3.8V; then, the battery is discharged at a constant current of 1C to a cut-off voltage of 1.5V; The lower charging rate is: the battery is charged at a constant current and constant voltage of 0.5C, the maximum charging voltage is also set to 3.8V, and then discharged to 1.5V in a constant current mode of 1C.

[0009] Further, step 2 includes 30 battery degradation characteristics, and the 30 battery degradation characteristics are shown in Table 1: Table 1

[0010] in, For time; is the time proportion; For constant current charging; Charging for constant voltage; It is a constant current discharge; is the temperature data; is the current; is the voltage; is the slope of the voltage curve; is the slope of the current curve; is the charging current; For capacity.

[0011] Further: Pearson's output for:

[0012] in, and They are two battery degradation characteristics; for and The Pearson correlation coefficient of is in the range of [-1,1]. =1, and is completely positively correlated; when = -1, and is completely negatively correlated; when =0, and For wireless linearity; For the observations in the variable The value in For the observations in the variable The value in for The mean of for The mean of is the sample size; Spearman Output for:

[0013] in, is the Spearman rank correlation coefficient, when =1, indicating that there is a completely monotonically increasing relationship between the two variables; = -1, indicating that there is a completely monotonically decreasing relationship between the two variables; =0, indicating that there is no monotonic relationship between the two variables; is the sample size of the data; For the data points in the first variable The original value in For the data points in the second variable The original value in For the data points in the variable The ranking value in For the data points in the variable The ranking value in For the two variables The ranking difference of data points is: ; Kendall's Output for:

[0014] in, is the number of consistent pairs, is the number of discordant pairs, is the number of tie pairs; : Kendall's Tau coefficient, which reflects the degree of association between variables, ranging from -1≤ ≤1; =1 means positive correlation; =-1 means negative correlation; =0 means there is no correlation.

[0015] Further: Step 4 specifically includes the following steps: Step 4.1: The integrated gradient algorithm calculates the cumulative rate of change of the model output with respect to the input features by comparing the difference between the baseline input and the actual input; Step 4.2: The initial structure of the proxy model KAN network is [15, [5, 3], 1], which shrinks to [8, [2, 2], 1] after training; the final expression is:

[0016] in, is the SOH value of some samples in the feature selection stage, Indicates the rate of voltage change during the discharge process, It is the average voltage level during constant current charging; Represents the constant current charging time, is the peak value of the IC curve; and They are the energy conversion efficiency and aging degree of the battery respectively; and It is the voltage and current integrals that quantify the total energy output during the discharge process; Step 4.3: Combining the surrogate model KAN network with the integral gradient algorithm, six features are retained based on the contribution of the remaining features to the model prediction, namely .

[0017] Further: Cumulative rate of change Used to measure the contribution of each input feature to the model prediction, namely:

[0018] in, is the baseline input, is the function of the deep learning model, is the number of steps into which the integration path is divided.

[0019] Beneficial effects of the present invention: The Temporal Residual KAN-LSTM network model combines the time series processing capability of LSTMCell and the nonlinear feature extraction capability of the KAN network, and improves the adaptability to complex time series data by introducing the Temporal Residual mechanism. In energy storage applications, high-precision SOH estimation of sodium-ion batteries and its interpretability are achieved. BRIEF DESCRIPTION OF THE DRAWINGS

[0020] Figure 1 is a flow chart of the present invention; Figure 2 It is a secondary feature screening and interpretable analysis process; Figure 3 It is the Temporal Residual KAN-LSTM model diagram in the present invention; Figure 4 This is a graph showing the estimation results of different models for sodium-ion battery SOH; Figure 5 Error diagram of different model estimation results for sodium-ion battery SOH. DETAILED DESCRIPTION

[0021] The present invention is described in detail below in conjunction with the accompanying drawings. The embodiments of the present invention are described in detail below, and examples of the embodiments are shown in the accompanying drawings, wherein the same or similar reference numerals throughout represent the same or similar elements or elements with the same or similar functions. The embodiments described below with reference to the accompanying drawings are exemplary and are only used to explain the present invention, and cannot be interpreted as limiting the present invention. The directional terms such as left, middle, right, top, and bottom in the embodiments of the present invention are only relative concepts or are based on the normal use state of the product, and should not be considered as restrictive.

[0022] A method for estimating the health status of sodium-ion batteries in energy storage scenarios, such as Figure 1 As shown, the following steps are included: Step 1: Establish a complete attenuation data set of sodium-ion batteries under two working conditions: standard charge rate and lower charge rate. The standard charge rate is: the battery is first charged to a set voltage at a constant current of 1C, and then switched to a constant current and constant voltage charging mode of 0.5C until the voltage reaches 3.8V; then, the battery is discharged at a constant current of 1C to a cut-off voltage of 1.5V. This working condition design mainly simulates the battery performance under standard charging conditions, aiming to study the aging characteristics of sodium-ion batteries at standard rates. The lower charging rate is: the battery is charged at a constant current and constant voltage of 0.5C, and the maximum charging voltage is also set to 3.8V, and then discharged to 1.5V at a constant current mode of 1C. This condition simulates milder charging conditions to evaluate the performance degradation of sodium-ion batteries at lower charging rates. Step 2: Based on the complete attenuation data set of sodium-ion batteries, these complex data are converted into indicators with physical meaning and statistical relevance from multiple change dimensions such as voltage, current, and temperature, and 30 battery degradation features are extracted, which provides a rich and reasonable basis for interpretability. The 30 battery degradation features are shown in Table 1: Table 1

[0023] in, For time; is the time proportion; For constant current charging; Charging for constant voltage; It is a constant current discharge; is the temperature data; is the current; is the voltage; is the slope of the voltage curve; is the slope of the current curve; is the charging current; is capacity; Step 3: Use the three correlation analysis methods of Spearman, Kendall and Pearson to measure the linear correlation, nonlinear monotonicity and rank order consistency between the battery degradation characteristics and SOH respectively, and preliminarily screen the battery degradation characteristics and SOH to obtain the battery degradation characteristics after preliminary screening; among them, the output of Pearson for:

[0024] in, and They are two battery degradation characteristics; for and The Pearson correlation coefficient of is in the range of [-1,1]. =1, and is completely positively correlated; when = -1, and is completely negatively correlated; when =0, and For wireless linearity; For the observations in the variable The value in For the observations in the variable The value in for The mean of for The mean of is the sample size (i.e. and The Pearson correlation coefficient assumes that the relationship between variables is linear and the data follows a normal distribution or approximate normality. It is only suitable for capturing linear relationships between variables. The Spearman correlation coefficient is used to measure the monotonic relationship between two variables. Even if the relationship between the variables is not linear, as long as they show a monotonically increasing or decreasing trend, the Spearman correlation coefficient can still capture the correlation. First, for each variable and The observed values ​​are ranked and the and , that is, the variable and rank; Spearman's output for:

[0025] in, is the Spearman rank correlation coefficient, when =1, indicating that there is a completely monotonically increasing relationship between the two variables; = -1, indicating that there is a completely monotonically decreasing relationship between the two variables; =0, indicating that there is no monotonic relationship between the two variables; is the sample size of the data; For the data points in the first variable The original value in For the data points in the second variable The original value in For the data points in the variable The ranking value in For the data points in the variable The ranking value in For the two variables The ranking difference of data points is: ; It does not require the data to follow a specific distribution type and is less sensitive to outliers. It is especially suitable when the features and SOH show different increase and decrease trends in different states; Kendall's correlation coefficient measures the consistency of the rank order between two variables, mainly capturing the rank correlation between variables. It is calculated based on the consistency and inconsistency of the rank order between pairs of observations. The output of Kendall for:

[0026] in, is the number of consistent pairs, is the number of discordant pairs, is the number of tie pairs; : Kendall's Tau coefficient, which reflects the degree of association between variables, ranging from -1≤ ≤1; =1 means positive correlation; =-1 means negative correlation; =0 means no correlation; it measures the stability of the order relationship when the data may contain noise or irregularities; Step 4: Combine the battery degradation characteristics after preliminary screening with Figure 2 As shown, the integral gradient algorithm is used for secondary feature screening, and the KAN network is used as a proxy model for interpretability analysis; thereby obtaining a feature combination that contributes strongly to battery life prediction; specifically, the following steps are included: Step 4.1: The integrated gradient algorithm calculates the cumulative rate of change of the model output to the input features by comparing the difference between the baseline input and the actual input; the cumulative rate of change Used to measure the contribution of each input feature to the model prediction, namely:

[0027] in, is the baseline input, is the function of the deep learning model, is the number of steps into which the integration path is divided; A deep learning model can be viewed as a complex function , for any input , can be calculated by the model to get an output , when the input Parameters Changed Finally, if you want to know which input parameter has a greater impact on the result, just look at the output change. Relative to the input change The ratio of , that is, the corresponding partial differential gradient:

[0028] Assuming a deep learning model Accepting Input and produces the output , the baseline input is , then for the input No. The attribution value of the integrated gradient algorithm is calculated by the following formula:

[0029] Since it is impractical to calculate the integral directly, a numerical approximation method is used to estimate the integral, dividing the integral path into equally spaced points, and calculate the gradient at these points, and then take their weighted average:

[0030] After obtaining the importance scores of the features, the number of features is selected based on the difference in the score ratios and the prior knowledge of past work; the sum of the attribution values ​​of all input features is equal to the total change in the model output, which ensures the consistency of the interpretation results of the integral gradient method; Step 4.2: The initial structure of the proxy model KAN network is [15, [5, 3], 1], which shrinks to [8, [2, 2], 1] after training; the final expression is:

[0031] in, is the SOH value of some samples in the feature selection stage, Indicates the rate of voltage change during discharge, which is often related to the internal resistance of the battery. An increase in internal resistance will lead to an increase in the rate of voltage change, reflecting battery aging; is the average voltage level in constant current charging. High voltage means higher charging efficiency. As the battery ages, the voltage decreases. This trend is reflected in the formula through a negative exponential relationship, indicating the significant inhibitory effect of voltage on SOH. represents the constant current charging time. The extension of constant current charging time means the increase of battery internal resistance and the decrease of charge receiving efficiency, indicating the aging process. The negative exponential term in the denominator further amplifies the negative impact of constant current charging time on SOH. If the value is large, the denominator will approach zero, thus amplifying the negative impact of the term and causing a significant decrease in SOH; is the peak value of the IC curve. The decrease of this feature means that the internal reaction rate slows down and the active material decreases. The complex exponential form in the formula reflects the high sensitivity of the IC peak to SOH; and are the energy conversion efficiency and aging degree of the battery respectively. The exponential form of this item reflects the overall impact of the combined changes of different slopes on the battery state; and The voltage and current integrals quantify the total energy output during the discharge process. The exponential form and denominator structure of this term indicate that changes in the discharge voltage and current integrals can have a significant nonlinear effect on SOH, especially when the battery is discharged at a large depth, which can have a negative impact on battery life. The symbolic formula and the integral gradient algorithm are combined to further understand the contribution of the remaining features. The first 6 features are retained and the features with contributions of -0.0185 and -0.0127 are removed. and At the same time, from the formula, when multiple variables are combined into the denominator through multiplication and addition, the impact of a single variable will be weakened by the value of other variables. Specifically, the denominator contains and , where As the coefficient of another exponential term, it has a greater impact on the value of the denominator. In addition, the constant term (-1.06) in the denominator further suppresses The sensitivity of the denominator to changes in or Even if there is a large change in the total denominator, the change in the total denominator is relatively limited, which may result in a smaller contribution of this term in the formula; Step 4.3: Combining the surrogate model KAN network with the integral gradient algorithm, six battery degradation features are retained according to the contribution of the remaining features to the model prediction, namely, ; Step 5: The battery degradation features obtained in step 4.3 are fed into the Temporal Residual KAN-LSTM network model for training. The output of the Temporal Residual KAN-LSTM network model is the estimated health state of the sodium-ion battery. Among them, combined Figure 3 As shown in the figure, the TemporalResidual KAN-LSTM network model includes a first-layer LSTMCell, a second-layer LSTMCell and a third-layer KAN network. The first-layer LSTMCell and the second-layer LSTMCell are both the smallest units of LSTM. The data is sent to the third-layer KAN network after passing through the first-layer LSTMCell and the second-layer LSTMCell in turn. The output results of the third-layer KAN network are dynamically residual connected to obtain the final SOH result. Specifically, the battery feature data is recorded as a time series Xt, where each time step t contains the state characteristics of the battery, and the data dimension of Xt is , is the feature dimension, and the time series length is , each time step The final output of the corresponding Temporal Residual KAN-LSTM network model is , which is the final SOH result, the batch size is defined as , the final output feature dimension is , then the final output of the Temporal Residual KAN-LSTM network model in the time dimension is expressed as:

[0032] in, and is a learnable weight parameter used to balance the contributions of different paths, and They are the hidden states of the first and second layers of LSTMCell corresponding to the t-th time step; and is the projection matrix, which maps the hidden state to the same dimension as the KAN output. and is the corresponding bias vector, is the hidden state of LSTMCell, is the output of the KAN layer, and is a univariate nonlinear function.

[0033] In view of the higher accuracy requirements for SOH estimation in energy storage applications, the designed Temporal ResidualKAN-LSTM (TRKL) model was verified, and SOH estimation comparison experiments were carried out on different working condition data sets with the Kolmogorov-ArnoldNetwork (KAN), CNN-LSTM-MLP and the Bagging Temporal Attention Network (BTANet) previously used for SOH estimation of fast-charging batteries. The method of the invention was comprehensively evaluated using six evaluation indicators: mean square error (MSE), root mean square error (RMSE), mean absolute error (MAE), mean absolute percentage error (MAPE), coefficient of determination (R2) and maximum error (MAXE).

[0034] Table 2 Estimation results of different models for sodium-ion battery SOH

[0035] As shown in Table 2, Figure 4 and Figure 5 As shown in the figure, B101~B104 and B201~B204 are different sodium batteries. The TRKL model shows its significant advantages over other models in multiple error indicators, especially in accuracy and robustness. The TRKL model combines the time series processing capability of LSTM and the nonlinear feature extraction capability of KAN network, and improves the adaptability to complex time series data by introducing the Temporal Residual mechanism. TRKL is significantly better than KAN, CNN-LSTM-MLP and BATNet models in MSE indicator. This has practical application significance for energy storage applications that require stable SOH estimation results. In addition, the evaluation indicators of other models converge within a reasonable range, indicating the effectiveness and importance of feature engineering.

[0036] The above shows and describes the basic principles, main features and advantages of the present invention. It should be understood by those skilled in the art that the present invention is not limited to the above embodiments. The above embodiments and descriptions are only for explaining the principles of the present invention. Without departing from the spirit and scope of the present invention, the present invention may have various changes and improvements, which fall within the scope of the present invention. The scope of protection of the present invention is defined by the attached claims and their equivalents.

Claims

1. A method for estimating the health status of a sodium ion battery in an energy storage scenario, characterized in that: The following steps are involved: Step 1: Establish a complete attenuation data set for sodium-ion batteries at standard charge rate and lower charge rate. Step 2: Extract several battery degradation features based on the complete attenuation data set of sodium-ion batteries; Step 3: Use the three correlation analysis methods of Spearman, Kendall and Pearson to measure the linear correlation, nonlinear monotonicity and rank order consistency between the battery degradation characteristics and SOH respectively, and preliminarily screen the battery degradation characteristics and SOH to obtain the battery degradation characteristics after preliminary screening; Step 4: The battery degradation features after the initial screening are subjected to secondary feature screening using the integral gradient algorithm, and the KAN network is used as a proxy model for interpretability analysis, thereby obtaining a feature combination that contributes strongly to battery life prediction; Step 5: The battery degradation features in the feature combination are sent to the Temporal Residual KAN-LSTM network model for training. The output of the Temporal Residual KAN-LSTM network model is the estimated health state of the sodium-ion battery.

2. The method for estimating the health status of a sodium ion battery in an energy storage scenario according to claim 1, characterized in that: The Temporal Residual KAN-LSTM network model includes the first layer LSTMCell, the second layer LSTMCell and the third layer KAN network. The first layer LSTMCell and the second layer LSTMCell are the smallest units of LSTM. The data passes through the first layer LSTMCell and the second layer LSTMCell in turn and is sent to the third layer KAN network. The output results of the third layer KAN network are dynamically residual connected to obtain the final SOH result.

3. The method for estimating the health status of a sodium ion battery in an energy storage scenario according to claim 2, characterized in that: The battery characteristic data is recorded as a time series Xt, where each time step t contains the state characteristics of the battery, and the data dimension of Xt is , is the feature dimension, and the time series length is , each time step The final output of the corresponding Temporal ResidualKAN-LSTM network model is , which is the final SOH result, the batch size is defined as , the final output feature dimension is , then the final output of the Temporal Residual KAN-LSTM network model in the time dimension is expressed as: ; in, and is a learnable weight parameter used to balance the contributions of different paths, and They are the hidden states of the first and second layers of LSTMCell corresponding to the t-th time step; and is the projection matrix, and is the corresponding bias vector, is the hidden state of LSTMCell, is the output of the KAN layer, and is a univariate nonlinear function.

4. The method for estimating the health status of a sodium ion battery in an energy storage scenario according to claim 1, characterized in that: The standard charging rate in step 1 is: the battery is first charged at a constant current of 1C to a set voltage, and then switched to a constant current and constant voltage charging mode of 0.5C until the voltage reaches 3.8V; then, the battery is discharged at a constant current of 1C to a cut-off voltage of 1.5V; The lower charging rate is: the battery is charged at a constant current and constant voltage of 0.5C, the maximum charging voltage is also set to 3.8V, and then discharged to 1.5V in a constant current mode of 1C.

5. The method for estimating the health status of a sodium ion battery in an energy storage scenario according to claim 1, characterized in that: Step 2 includes 30 battery degradation characteristics, which are shown in Table 1: Table 1 ; in, For time; is the time proportion; For constant current charging; Charging for constant voltage; It is a constant current discharge; is the temperature data; is the current; is the voltage; is the slope of the voltage curve; is the slope of the current curve; is the charging current; For capacity.

6. The method for estimating the health status of a sodium ion battery in an energy storage scenario according to claim 1, characterized in that: Pearson's output for: ; in, and They are two battery degradation characteristics; for and The Pearson correlation coefficient of , and the value range is [−1,1]. =1, and is completely positively correlated; when = -1, and is completely negatively correlated; when =0, and For wireless linearity; For the observations in the variable The value in For the observations in the variable The value in for The mean of for The mean of is the sample size; Spearman Output for: ; in, is the Spearman rank correlation coefficient, when =1, indicating that there is a completely monotonically increasing relationship between the two variables; = -1, indicating that there is a completely monotonically decreasing relationship between the two variables; =0, indicating that there is no monotonic relationship between the two variables; is the sample size of the data; For the data points in the first variable The original value in For the data points in the second variable The original value in For the data points in the variable The ranking value in For the data points in the variable The ranking value in For the two variables The ranking difference of data points is: ; Kendall's Output for: ; in, is the number of consistent pairs, is the number of discordant pairs, is the number of tie pairs; : Kendall's Tau coefficient, which reflects the degree of association between variables, ranges from -1≤ ≤1; =1 means positive correlation; =-1 means negative correlation; =0 means there is no correlation.

7. The method for estimating the health status of a sodium ion battery in an energy storage scenario according to claim 6, characterized in that: Step 4 specifically includes the following steps: Step 4.1: The integrated gradient algorithm calculates the cumulative rate of change of the model output with respect to the input features by comparing the difference between the baseline input and the actual input; Step 4.2: The initial structure of the proxy model KAN network is [15, [5, 3], 1], which shrinks to [8, [2, 2], 1] after training; the final expression is: ; in, is the SOH value of some samples in the feature selection stage, Indicates the rate of voltage change during the discharge process, It is the average voltage level during constant current charging; Represents the constant current charging time, is the peak value of the IC curve; and They are the energy conversion efficiency and aging degree of the battery respectively; and It is the voltage and current integrals that quantify the total energy output during the discharge process; Step 4.3: Combining the surrogate model KAN network with the integral gradient algorithm, six features are retained based on the contribution of the remaining features to the model prediction, namely .

8. The method for estimating the health status of a sodium ion battery in an energy storage scenario according to claim 7, characterized in that: Cumulative rate of change Used to measure the contribution of each input feature to the model prediction, namely: ; in, is the baseline input, is the function of the deep learning model, is the number of steps into which the integration path is divided.

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