Integrated pultrusion molding method and preparation system for composite material evacuation platform with vertical ribs
Through the dual-system impregnation liquid design and high-temperature curing mold, the efficient integrated preparation of the composite material evacuation platform is achieved, which solves the problems of incomplete curing of the vertical ribs and high energy consumption, and improves the production efficiency and the mechanical strength of the product.
Patent Information
- Application Number
- CN202411448304.4
- Authority / Receiving Office
- CN · China
- Patent Type
- Patents(China)
- Current Assignee / Owner
- Filing Date
- 2024-10-17
- Publication Date
- 2024-12-17
- Estimated Expiration
- 2044-10-17
AI Technical Summary
In the prior art, composite material evacuation platforms with fireproof materials and vertical ribs are prepared. Under the same production efficiency, the vertical ribs are not cured completely, the strength is insufficient, and the overall performance is reduced. The production speed is required to extend the curing time, resulting in energy consumption. High and not conducive to mass production, while the strength of the outer plate decreases in high temperature environment.
Using a dual-system impregnation liquid design, the outer plate body and vertical ribs are used to prepare the same temperature as the fireproof material, avoiding the extension of the high-temperature curing time and passing through high temperature. The curing molds and conveying devices realize automated production, reducing the intensity of labor.
While ensuring production speed, it meets the mechanical strength requirements and ensures the platform's fire resistance and flatness. It is suitable for large-size composite evacuation platforms, reducing labor costs and improving installation efficiency and production efficiency.
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Figure CN118952725B_ABST
Abstract
Description
Technical Field
[0001] The invention relates to the field of composite material preparation, and in particular to an integrated pultrusion molding method and a preparation system for a composite material evacuation platform with vertical ribs. Background Art
[0002] With the development of my country's economy and urban construction, the subway has gradually become an effective way to solve these urban traffic problems with its advantages such as speed and comfort.
[0003] In order to quickly and orderly evacuate passengers from the section tunnel in special circumstances, and eliminate or reduce casualties caused by blocked evacuation passages, an evacuation platform leading to the station is installed on the side wall of the section tunnel. The installation height of the platform is consistent with the height of the station platform. In the event of an accident, the doors can be opened immediately to organize passengers to evacuate to a safe place. In special circumstances, passenger evacuation often results in crowding and running, which causes a great impact on the transport platform, making the evacuation platform bear a great force. Therefore, the transport platform must have sufficient structural strength, stability and fire resistance.
[0004] Patent 202111258607.6 discloses a method for preparing an integral composite material evacuation platform for a subway tunnel. An integral composite material evacuation platform for a subway tunnel is obtained by one-piece molding. The interior is filled with fireproof materials arranged at intervals. Two adjacent fireproof materials are provided with supporting ribs. The integral composite material evacuation platform for a subway tunnel eliminates the assembly process, avoids height differences during splicing, and makes the surface of the evacuation platform flat. At the same time, due to the filling of fireproof materials, it has better fire resistance. However, it was found during the preparation process that compared with the composite material board without fireproof material filling, the preparation of an evacuation platform with fireproof material and ribs, under the same production efficiency, the ribs are not completely cured, the strength is insufficient, and the overall performance is reduced. It is necessary to reduce the production speed, thereby extending the curing time. If the internal ribs are to be cured, the production speed needs to be reduced by 3-4 times, which has high energy consumption and is not conducive to mass production. At the same time, due to the long-term exposure of the outer panel to a high temperature environment, the strength of the outer panel will also decrease.
[0005] Therefore, in view of the above problems, the present invention urgently needs to provide an integrated pultrusion molding method and a preparation system for a composite material evacuation platform with vertical ribs. Summary of the invention
[0006] The purpose of the present invention is to provide an integrated pultrusion molding method and a preparation system for a composite material evacuation platform with vertical ribs. The integrated pultrusion molding method for a composite material evacuation platform with vertical ribs is proposed to solve the technical problems in the prior art of preparing an evacuation platform with fireproof materials and vertical ribs. Under the same production efficiency, the vertical ribs are not completely cured, the strength is insufficient, and the overall performance is reduced. It is necessary to reduce the production speed to extend the curing time. To ensure the curing of the internal vertical ribs, the production speed needs to be reduced by 3-4 times, the energy consumption is high, and it is not conducive to mass production. At the same time, since the outer panel is in a high temperature environment for a long time, the strength of the outer panel will also be reduced.
[0007] The present invention provides a composite material evacuation platform with vertical ribs, which is an integrated pultrusion method, comprising the following steps:
[0008] Mixing phenolic resin, solvent, filler, pigment, dispersant and release agent to obtain impregnation liquid A; mixing phenolic resin and phenolic resin curing agent to obtain impregnation liquid B;
[0009] A part of the fiber yarn is drawn into the impregnation liquid A for immersion, and a part of the fiber yarn is drawn into the impregnation liquid B for immersion;
[0010] The fibers, fiber fabrics, fireproof filling blocks impregnated with impregnation liquid A and the fibers impregnated with impregnation liquid B are simultaneously passed through a rubber extrusion plate, excess rubber is removed, and the fibers are pulled into a high-temperature curing mold and cured at high temperature to obtain a composite material evacuation platform with vertical ribs; wherein the fibers and fiber fabrics impregnated with impregnation liquid A form an outer plate body, and the fibers impregnated with impregnation liquid B are located between two adjacent fireproof filling blocks to form vertical ribs.
[0011] Preferably, in the impregnation liquid A, the mass ratio of phenolic resin: solvent: filler: pigment: release agent is 100: (20-50): (80-150): (1-4): (1-4);
[0012] In the impregnation liquid B, the mass ratio of the phenolic resin to the phenolic resin curing agent is 100:(5-20); the phenolic resin curing agent includes a medium-low temperature curing agent and a solvent, and the mass ratio of the medium-low temperature curing agent to the solvent is 1:(1.5-3).
[0013] Preferably, the medium and low temperature curing agent includes at least one of hydrochloric acid, phosphoric acid, p-toluenesulfonic acid or phenolsulfonic acid.
[0014] Preferably, high temperature curing adopts a zoned heating method, with the temperature of the first stage set at 120-150°C, the temperature of the second stage set at 220-260°C, and the temperature of the third stage set at 230-270°C.
[0015] Preferably, the solvent in the immersion liquid A and the immersion liquid B includes one of ethanol, propanol or water.
[0016] Preferably, the fireproof filling block is made of inorganic material.
[0017] Preferably, the width and height of the composite material evacuation platform with vertical ribs are 200-2500 mm and 30-100 mm respectively; the gap between two adjacent fireproof filling blocks is 2-10 mm.
[0018] Preferably, an anti-skid layer is laid on the composite material evacuation platform with vertical ribs, and the thickness of the anti-skid layer is set to 0.1-10 mm.
[0019] Preferably, one outer side of the outer plate body of the composite material evacuation platform with vertical ribs is provided with a U-shaped tongue and groove groove, and the other opposite outer side is provided with a U-shaped tongue and groove tenon, wherein the U-shaped tongue and groove tenon of one composite material evacuation platform with vertical ribs is adapted to the U-shaped tongue and groove groove of another composite material evacuation platform with vertical ribs.
[0020] The present invention discloses a system for preparing a composite material evacuation platform with vertical ribs, comprising:
[0021] a plurality of fiber rolls having fibers wound thereon;
[0022] a plurality of fiber fabric rolls around which the fiber fabric is wound;
[0023] A first impregnation tank, used to store the impregnation liquid A in the integrated pultrusion molding method of the composite material evacuation platform with vertical ribs as described in any one of the above;
[0024] A second impregnation tank, used for storing the impregnation liquid B in the integrated pultrusion molding method of the composite material evacuation platform with vertical ribs as described in any one of the above;
[0025] A conveying device, used for conveying the fireproof filling block to the high temperature curing device;
[0026] Extrusion board, used for fireproof filling blocks, impregnated fibers and fiber fabrics to pass through and squeeze out excess impregnation liquid;
[0027] A high temperature curing device, used to cure and shape the fibers, fiber fabrics and fireproof filling blocks into an integrated form;
[0028] A traction mechanism, used for traction of fibers and fiber fabrics;
[0029] The cutting mechanism is used for cutting a composite material evacuation platform with vertical ribs.
[0030] The integrated pultrusion molding method and preparation system of a composite material evacuation platform with vertical ribs provided by the present invention have the following improvements compared with the prior art:
[0031] 1. The integrated pultrusion molding method of the composite material evacuation platform with vertical ribs provided by the present invention can realize integrated curing molding with the fireproof material at the same temperature by configuring the fiber impregnation liquid for preparing the outer plate body and the fiber impregnation liquid for preparing the vertical ribs, without extending the high-temperature curing time, while meeting the mechanical strength requirements required for use and ensuring the original production speed.
[0032] 2. The integrated pultrusion molding method of the composite material evacuation platform with vertical ribs provided by the present invention can achieve the fire resistance limit requirement of 1h. The integrated preparation can ensure the flatness of the platform plane, and no post-processing is required, which greatly improves the installation efficiency.
[0033] 3. The integrated pultrusion molding method of the composite material evacuation platform with vertical ribs provided by the present invention can prepare a large-sized composite material evacuation platform with vertical ribs through a dual-system impregnation liquid design. The width and height of the composite material evacuation platform with vertical ribs can reach up to 2500mm and 100mm at most, which can ensure the strength requirements.
[0034] 4. The preparation system of the composite material evacuation platform with vertical ribs provided by the present invention, the conveying device is installed between the immersion tank and the high-temperature curing device, including an active roller and a conveying device, relying on the friction generated between the active roller and the core material and the synchronous movement of the conveying device to achieve continuous and uniform automatic conveying of fireproof materials. Only one person is needed to operate a production line, which reduces the labor intensity, reduces the use of personnel, and saves 50% of labor costs. BRIEF DESCRIPTION OF THE DRAWINGS
[0035] In order to more clearly illustrate the specific implementation methods of the present invention or the technical solutions in the prior art, the drawings required for use in the specific implementation methods or the description of the prior art will be briefly introduced below. Obviously, the drawings described below are some implementation methods of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without paying creative work.
[0036] Figure 1 It is a schematic structural diagram of a system for preparing a composite material evacuation platform with vertical ribs described in the present invention.
[0037] Description of reference numerals:
[0038] 1. Fiber roller; 2. Fiber fabric roller; 3. First immersion tank; 4. Second immersion tank; 5. Conveying device; 6. Rubber squeezing plate; 7. High temperature curing device; 8. Traction mechanism. DETAILED DESCRIPTION
[0039] The technical solution of the present invention will be described clearly and completely below in conjunction with the accompanying drawings. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
[0040] The present invention provides a composite material evacuation platform with vertical ribs, which is an integrated pultrusion method, comprising the following steps:
[0041] Mixing phenolic resin, solvent, filler, pigment, dispersant and release agent to obtain impregnation liquid A; mixing phenolic resin and phenolic resin curing agent to obtain impregnation liquid B;
[0042] A part of the fiber yarn is drawn into the impregnation liquid A for immersion, and a part of the fiber yarn is drawn into the impregnation liquid B for immersion;
[0043] The fibers, fiber fabrics, fireproof filling blocks impregnated with impregnation liquid A and the fibers impregnated with impregnation liquid B are simultaneously passed through a rubber extrusion plate, excess rubber is removed, and the fibers are pulled into a high-temperature curing mold and cured at high temperature to obtain a composite material evacuation platform with vertical ribs; wherein the fibers and fiber fabrics impregnated with impregnation liquid A form an outer plate body, and the fibers impregnated with impregnation liquid B are located between two adjacent fireproof filling blocks to form vertical ribs.
[0044] Specifically, in the impregnation liquid A, the mass ratio of phenolic resin: solvent: filler: pigment: release agent is 100: (20-50): (80-150): (1-4): (1-4);
[0045] In the impregnation liquid B, the mass ratio of the phenolic resin to the phenolic resin curing agent is 100:(5-20); the phenolic resin curing agent includes a medium-low temperature curing agent and a solvent, and the mass ratio of the medium-low temperature curing agent to the solvent is 1:(1.5-3).
[0046] Specifically, the medium and low temperature curing agent includes at least one of hydrochloric acid, phosphoric acid, p-toluenesulfonic acid or phenolsulfonic acid.
[0047] Specifically, high temperature curing adopts a zoned heating method, with the temperature of the first stage set at 120-150°C, the temperature of the second stage set at 220-260°C, and the temperature of the third stage set at 230-270°C.
[0048] Specifically, the solvent in the immersion liquid A and the immersion liquid B includes one of ethanol, propanol or water.
[0049] Specifically, the fireproof filling block is made of inorganic materials.
[0050] Specifically, the pigment is iron oxide powder.
[0051] Specifically, the width and height of the composite material evacuation platform with vertical ribs are 200-2500 mm and 30-100 mm respectively; the gap between two adjacent fireproof filling blocks is 2-10 mm.
[0052] Specifically, an anti-skid layer is laid on the composite material evacuation platform with vertical ribs, and the thickness of the anti-skid layer is set to 0.1-10 mm.
[0053] Specifically, one outer side of the outer plate body of the composite material evacuation platform with vertical ribs is provided with a U-shaped tongue and groove groove, and the other opposite outer side is provided with a U-shaped tongue and groove convex tenon, wherein the U-shaped tongue and groove convex tenon of one composite material evacuation platform with vertical ribs is adapted to the U-shaped tongue and groove groove of another composite material evacuation platform with vertical ribs.
[0054] The present invention discloses a system for preparing a composite material evacuation platform with vertical ribs, comprising:
[0055] A plurality of fiber rollers 1 wound with fibers;
[0056] A plurality of fiber fabric rolls 2 with fiber fabrics wound thereon;
[0057] A first impregnation tank 3, used for storing an impregnation liquid A in the integrated pultrusion molding method of a composite material evacuation platform with vertical ribs as described in any one of the above;
[0058] A second impregnation tank 4, used for storing the impregnation liquid B in the integrated pultrusion molding method of the composite material evacuation platform with vertical ribs as described in any one of the above;
[0059] A conveying device 5, used for conveying the fireproof filling block to the high temperature curing device;
[0060] The rubber extrusion plate 6 is used for the fireproof filling block, the impregnated fibers and the fiber fabric to pass through and squeeze out the excess impregnation liquid;
[0061] High temperature curing device 7, used for curing and molding the fibers, fiber fabrics and fireproof filling blocks into an integrated form;
[0062] A traction mechanism 8, used for traction of fibers and fiber fabrics;
[0063] The cutting mechanism 9 is used to cut the composite material evacuation platform with vertical ribs.
[0064] It also includes an environmental protection device placed between the high-temperature curing device 7 and the traction mechanism 8 for absorbing exhaust gas.
[0065] The integrated pultrusion molding method of the composite material evacuation platform with vertical ribs provided by the present invention can realize integrated curing molding with the fireproof material at the same temperature by mixing the fiber impregnation liquid for preparing the outer plate body and the fiber impregnation liquid for preparing the vertical ribs, without extending the high-temperature curing time, while meeting the mechanical strength requirements required for use and ensuring the original production speed.
[0066] The present invention provides an integrated pultrusion molding method for a composite material evacuation platform with vertical ribs. The obtained composite material evacuation platform with vertical ribs can meet the fire resistance limit requirement of 1h. The integrated preparation can ensure the flatness of the platform plane, and no post-processing is required, which greatly improves the installation efficiency.
[0067] The integrated pultrusion molding method of the composite material evacuation platform with vertical ribs provided by the present invention can prepare a large-sized composite material evacuation platform with vertical ribs through a dual-system impregnation liquid design. The width and height of the composite material evacuation platform with vertical ribs can reach a maximum of 2500 mm and 100 mm, which can ensure the strength requirements.
[0068] The preparation system of the composite material evacuation platform with vertical ribs provided by the present invention has a conveying device installed between the immersion tank and the high-temperature curing device, including an active roller and a conveying device. The friction generated between the active roller and the core material and the synchronous movement of the conveying device can realize continuous and uniform automatic conveying of the fireproof material. Only one person is needed to operate a production line, which reduces the labor intensity, reduces the use of personnel, and saves 50% of labor costs.
[0069] Embodiment 1
[0070] The present invention provides a composite material evacuation platform with vertical ribs, which is an integrated pultrusion method, comprising the following steps:
[0071] 101) mixing phenolic resin, solvent, filler, pigment, dispersant and release agent to obtain impregnation liquid A; mixing phenolic resin and phenolic resin curing agent to obtain impregnation liquid B; wherein, in impregnation liquid A, phenolic resin: solvent: filler: pigment: release agent = 100:20:80:1:1; in impregnation liquid B, the mass ratio of phenolic resin to phenolic resin curing agent is 100:5;
[0072] 102) a portion of the fiber yarn is drawn into the impregnation liquid A for immersion, and a portion of the fiber yarn is drawn into the impregnation liquid B for immersion;
[0073] 103) The fibers, fiber fabrics, fireproof filling blocks impregnated with impregnating liquid A and the fibers impregnated with impregnating liquid B are simultaneously passed through a rubber extrusion plate, excess rubber is removed, and they are pulled into a high-temperature curing mold and cured at high temperature to obtain a composite material evacuation platform with vertical ribs; wherein the fibers and fiber fabrics impregnated with impregnating liquid A form an outer plate body, and the fibers impregnated with impregnating liquid B are located between two adjacent fireproof filling blocks to form vertical ribs.
[0074] Specifically, the phenolic resin curing agent includes a medium-low temperature curing agent and a solvent, and the mass ratio of the medium-low temperature curing agent to the solvent is 1:1.5.
[0075] Specifically, the medium and low temperature curing agent is hydrochloric acid.
[0076] Specifically, high temperature curing adopts a zoned temperature increase method, with the temperature of the first stage set at 120°C, the temperature of the second stage set at 220°C, and the temperature of the third stage set at 230°C.
[0077] Specifically, the solvent in the immersion liquid A and the immersion liquid B is ethanol.
[0078] Specifically, the fireproof filling block is made of inorganic materials.
[0079] The width and height of the obtained composite material evacuation platform with vertical ribs are 2000 mm and 70 mm respectively; the gap between two adjacent fireproof filling blocks is 5 mm;
[0080] One outer side of the outer plate body of the composite material evacuation platform with vertical ribs is provided with a U-shaped tongue and groove groove, and the other opposite outer side is provided with a U-shaped tongue and groove mortise and tenon, wherein the U-shaped tongue and groove mortise of one composite material evacuation platform with vertical ribs is adapted to the U-shaped tongue and groove groove of another composite material evacuation platform with vertical ribs.
[0081] The obtained composite material evacuation platform with vertical ribs is paved with an anti-skid layer, and the thickness of the anti-skid layer is set to 2 mm.
[0082] The physical properties of the composite material evacuation platform with vertical ribs obtained in this example are shown in Table 1.
[0083] Embodiment 2
[0084] The present invention provides a composite material evacuation platform with vertical ribs, which is an integrated pultrusion method, comprising the following steps:
[0085] 201) mixing phenolic resin, solvent, filler, pigment, dispersant and release agent to obtain impregnation liquid A; mixing phenolic resin and phenolic resin curing agent to obtain impregnation liquid B; wherein, in impregnation liquid A, phenolic resin: solvent: filler: pigment: release agent = 100:50:150:4:4; in impregnation liquid B, the mass ratio of phenolic resin to phenolic resin curing agent is 100:20;
[0086] 202) a part of the fiber yarn is drawn into the impregnation liquid A for immersion, and a part of the fiber yarn is drawn into the impregnation liquid B for immersion;
[0087] 203) The fibers, fiber fabrics, fireproof filling blocks impregnated with impregnating liquid A and the fibers impregnated with impregnating liquid B are simultaneously passed through a rubber extrusion plate, excess rubber is removed, and they are pulled into a high-temperature curing mold and cured at high temperature to obtain a composite material evacuation platform with vertical ribs; wherein the fibers and fiber fabrics impregnated with impregnating liquid A form an outer plate body, and the fibers impregnated with impregnating liquid B are located between two adjacent fireproof filling blocks to form vertical ribs.
[0088] Specifically, the phenolic resin curing agent includes a medium-low temperature curing agent and a solvent, and the mass ratio of the medium-low temperature curing agent to the solvent is 1:3.
[0089] Specifically, the medium and low temperature curing agent is p-toluenesulfonic acid.
[0090] Specifically, high temperature curing adopts a zoned temperature increase method, with the temperature of the first stage set at 150°C, the temperature of the second stage set at 260°C, and the temperature of the third stage set at 270°C.
[0091] Specifically, the solvent in the immersion liquid A and the immersion liquid B is propanol.
[0092] Specifically, the fireproof filling block is made of inorganic materials.
[0093] The width and height of the composite material evacuation platform with vertical ribs obtained in this embodiment are 200 mm and 30 mm respectively; the gap between two adjacent fireproof filling blocks is 2 mm.
[0094] One outer side of the outer plate body of the composite material evacuation platform with vertical ribs is provided with a U-shaped tongue and groove groove, and the other opposite outer side is provided with a U-shaped tongue and groove mortise and tenon, wherein the U-shaped tongue and groove mortise of one composite material evacuation platform with vertical ribs is adapted to the U-shaped tongue and groove groove of another composite material evacuation platform with vertical ribs.
[0095] The physical properties of the composite material evacuation platform with vertical ribs obtained in this example are shown in Table 1.
[0096] Embodiment 3
[0097] The present invention provides a composite material evacuation platform with vertical ribs, which is an integrated pultrusion method, comprising the following steps:
[0098] 301) mixing phenolic resin, solvent, filler, pigment, dispersant and release agent to obtain impregnation liquid A; mixing phenolic resin and phenolic resin curing agent to obtain impregnation liquid B; wherein, in impregnation liquid A, phenolic resin: solvent: filler: pigment: release agent = 100:30:100:2:2; in impregnation liquid B, the mass ratio of phenolic resin to phenolic resin curing agent is 100:10;
[0099] 102) a portion of the fiber yarn is drawn into the impregnation liquid A for immersion, and a portion of the fiber yarn is drawn into the impregnation liquid B for immersion;
[0100] 103) The fibers, fiber fabrics, fireproof filling blocks impregnated with impregnating liquid A and the fibers impregnated with impregnating liquid B are simultaneously passed through a rubber extrusion plate, excess rubber is removed, and they are pulled into a high-temperature curing mold and cured at high temperature to obtain a composite material evacuation platform with vertical ribs; wherein the fibers and fiber fabrics impregnated with impregnating liquid A form an outer plate body, and the fibers impregnated with impregnating liquid B are located between two adjacent fireproof filling blocks to form vertical ribs.
[0101] Specifically, the phenolic resin curing agent includes a medium-low temperature curing agent and a solvent, and the mass ratio of the medium-low temperature curing agent to the solvent is 1:2.
[0102] Specifically, the medium and low temperature curing agent is phenolsulfonic acid.
[0103] Specifically, high temperature curing adopts a zoned temperature increase method, with the first stage temperature set at 130°C, the second stage temperature set at 240°C, and the third stage temperature set at 260°C.
[0104] Specifically, the solvent in the immersion liquid A and the immersion liquid B is water.
[0105] Specifically, the fireproof filling block is made of inorganic materials.
[0106] The width and height of the composite material evacuation platform with vertical ribs obtained in this embodiment are 2500 mm and 80 mm respectively; the gap between two adjacent fireproof filling blocks is 5 mm;
[0107] One outer side of the outer plate body of the composite material evacuation platform with vertical ribs is provided with a U-shaped tongue and groove groove, and the other opposite outer side is provided with a U-shaped tongue and groove mortise and tenon, wherein the U-shaped tongue and groove mortise of one composite material evacuation platform with vertical ribs is adapted to the U-shaped tongue and groove groove of another composite material evacuation platform with vertical ribs.
[0108] The physical properties of the composite material evacuation platform with vertical ribs obtained in this example are shown in Table 1.
[0109] Embodiment 4
[0110] The only difference between this embodiment and the first embodiment is that a plurality of heat storage long holes are arranged at intervals along the length of one side of the fireproof filling block.
[0111] The fireproof filling block is made of inorganic material with low thermal conductivity. Through the design of the heat storage long holes, it can absorb part of the heat during the heating process. In the composite material evacuation platform with vertical ribs, the heat in the heat storage long holes can continue to heat the vertical ribs, which can ensure the curing effect of the vertical ribs and ensure the later strength.
[0112] The physical properties of the composite material evacuation platform with vertical ribs obtained in this example are shown in Table 1.
[0113] Embodiment 5
[0114] like Figure 1 As shown, the present invention also provides a preparation system for a composite material evacuation platform with vertical ribs, comprising:
[0115] A plurality of fiber rollers 1 wound with fibers;
[0116] A plurality of fiber fabric rolls 2 with fiber fabrics wound thereon;
[0117] A first impregnation tank 3, used for storing an impregnation liquid A in the integrated pultrusion molding method of a composite material evacuation platform with vertical ribs as described in any one of the above;
[0118] A second impregnation tank 4, used for storing the impregnation liquid B in the integrated pultrusion molding method of the composite material evacuation platform with vertical ribs as described in any one of the above;
[0119] A conveying device 5, used for conveying the fireproof filling block to the high temperature curing device;
[0120] The rubber extrusion plate 6 is used for the fireproof filling block, the impregnated fibers and the fiber fabric to pass through and squeeze out the excess impregnation liquid;
[0121] High temperature curing device 7, used for curing and molding the fibers, fiber fabrics and fireproof filling blocks into an integrated form;
[0122] A traction mechanism 8, used for traction of fibers and fiber fabrics;
[0123] A cutting mechanism 9, used for cutting the composite material evacuation platform with vertical ribs;
[0124] It also includes an environmental protection device placed between the high-temperature curing device 7 and the traction mechanism 8 for absorbing exhaust gas.
[0125] Comparative Example 1
[0126] The only difference between this comparative example and Example 1 is that no phenolic resin curing agent is added to the impregnation liquid B.
[0127] The physical properties of the composite evacuation platform with vertical ribs are shown in Table 1.
[0128] Comparative Example 2
[0129] The difference between this comparative example and Example 1 lies in the setting of the high-temperature curing temperature. The high-temperature curing temperature of this comparative example is directly raised to 230-270° C. and kept warm for 5-10 hours.
[0130] The physical properties of the composite evacuation platform with vertical ribs are shown in Table 1.
[0131] Comparative Example 3
[0132] The only difference between this embodiment and the first embodiment is that the mass ratio of the medium and low temperature curing agent to the solvent is 1:1.
[0133] Comparative Example 4
[0134] The difference between this embodiment and the first embodiment is that the mass ratio of the medium and low temperature curing agent to the solvent is 1:4.
[0135] Table 1 Physical properties of composite evacuation platform with ribs .
[0136] Compared with Example 1, since the vertical ribs and the outer panel fibers use the same impregnation liquid, at the same temperature, the fireproof filling block reduces the heat transfer toward the inner ribs due to its insulation property. After the composite material evacuation platform with vertical ribs is formed, the vertical ribs cannot be formed due to insufficient heat, resulting in a decrease in compressive strength and failure to meet application conditions.
[0137] Compared with Example 1, in the high-temperature curing process, curing at the same temperature in Comparative Example 2 will result in too fast a heating speed, rapid curing of the vertical ribs and the outer panel surface, and the inability of heat to be transferred to the interior, resulting in a decrease in the compressive strength and failure to meet the application conditions.
[0138] Compared with Example 1, the ratio of medium and low temperature curing agent and solvent in Comparative Examples 3 and 4 has a great influence on the strength of the later ribs. Too much solvent or too little solvent will affect the later compression strength and cannot meet the application conditions.
[0139] Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, rather than to limit it. Although the present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or replace some or all of the technical features therein with equivalents. However, these modifications or replacements do not cause the essence of the corresponding technical solutions to deviate from the scope of the technical solutions of the embodiments of the present invention.
Claims
1. A method for integrally pultruding a composite material evacuation platform with vertical ribs, characterized in that: The steps include: Mixing phenolic resin, solvent, filler, pigment, dispersant and release agent to obtain impregnation liquid A; mixing phenolic resin and phenolic resin curing agent to obtain impregnation liquid B; A part of the fiber yarn is drawn into the impregnation liquid A for immersion, and a part of the fiber yarn is drawn into the impregnation liquid B for immersion; The fibers, fiber fabrics, fireproof filling blocks impregnated with impregnation liquid A and the fibers impregnated with impregnation liquid B are simultaneously passed through a rubber extrusion plate, excess glue is removed, and the fibers are pulled into a high-temperature curing mold and cured at high temperature to obtain a composite material evacuation platform with vertical ribs; wherein the fibers and fiber fabrics impregnated with impregnation liquid A form an outer plate body, and the fibers impregnated with impregnation liquid B are located between two adjacent fireproof filling blocks to form vertical ribs; In the impregnation liquid A, the mass ratio of phenolic resin: solvent: filler: pigment: release agent is 100: (20-50): (80-150): (1-4): (1-4); In the impregnation liquid B, the mass ratio of the phenolic resin to the phenolic resin curing agent is 100:(5-20); the phenolic resin curing agent includes a medium-low temperature curing agent and a solvent, and the mass ratio of the medium-low temperature curing agent to the solvent is 1:(1.5-3).
2. The integrated pultrusion molding method of a composite material evacuation platform with vertical ribs according to claim 1 is characterized in that: The medium and low temperature curing agent includes at least one of hydrochloric acid, phosphoric acid, p-toluenesulfonic acid or phenolsulfonic acid.
3. The integrated pultrusion method of a composite material evacuation platform with vertical ribs according to claim 1 is characterized in that: High temperature curing adopts a zoned heating method, with the first stage temperature set at 120-150°C, the second stage temperature set at 220-260°C, and the third stage temperature set at 230-270°C.
4. The integrated pultrusion molding method of the composite material evacuation platform with vertical ribs according to claim 1 is characterized in that: The solvent in the immersion liquid A and the immersion liquid B includes one of ethanol, propanol or water.
5. The integrated pultrusion molding method of the composite material evacuation platform with vertical ribs according to claim 1 is characterized in that: The fireproof filling block is made of inorganic material.
6. The integrated pultrusion molding method of the composite material evacuation platform with vertical ribs according to claim 1 is characterized in that: The width and height of the composite material evacuation platform with vertical ribs are 200-2500mm and 30-100mm respectively; the gap between two adjacent fireproof filling blocks is 2-10mm.
7. The integrated pultrusion molding method of a composite material evacuation platform with vertical ribs according to claim 1 is characterized in that: An anti-skid layer is laid on the composite material evacuation platform with vertical ribs, and the thickness of the anti-skid layer is set to 0.1-10mm.
8. The integrated pultrusion molding method of a composite material evacuation platform with vertical ribs according to claim 1 is characterized in that: One outer side of the outer plate body of the composite material evacuation platform with vertical ribs is provided with a U-shaped tongue and groove groove, and the other opposite outer side is provided with a U-shaped tongue and groove mortise and tenon, wherein the U-shaped tongue and groove mortise of one composite material evacuation platform with vertical ribs is adapted to the U-shaped tongue and groove groove of another composite material evacuation platform with vertical ribs.
Citation Information
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