Low drift aqueous liquid formulations for low, medium and high spray volume applications

Abstract

The present invention relates to low drift aqueous liquid formulations for low, medium and high spray volume applications comprising a combination of different drift reducing agents.

Description

[0001] The present invention relates to low drift aqueous liquid formulations for low, medium and high spray volume applications comprising a combination of different drift reducing agents.

[0002] Low and medium volume spray applications are becoming increasingly popular because they require less water, lighter vehicles, and in some cases, less adjuvants to be introduced into the environment.

[0003] However, the formulations currently on the market are usually only suitable for high spray volumes or medium spray volumes, or low spray volumes and medium spray volumes, but never cover the entire range. However, for farmers, it is desirable and economically feasible if one formulation can be used for all types of applications depending on the application method, requirements, environmental conditions, etc.

[0004] On the other hand, there are economic advantages for suppliers to offer only one formulation suitable for all ranges.

[0005] It is well known in the art that different drift reduction additives work better at different spray volumes due to their different concentrations in the spray liquid after dilution.

[0006] Polymer-based drift reduction additives work best at higher concentrations, where their viscosity increasing effect is greater. However, drift reduction polymers increase the viscosity of flowable formulations, and there is an upper viscosity limit, above which the formulation becomes too viscous to be useful. As a result, in a 1 l / ha formulation, it is difficult to include enough polymer to reduce drift when spraying at high spray volumes, as large amounts of polymer would make the formulation too viscous to be useful. However, this is not the case at low spray volumes, where very little polymer is needed in the formulation to achieve an effective concentration in the spray liquor. Conversely, a formulation that contains enough drift reducing polymer at high spray volumes will not be sprayable at low spray volumes, as the high polymer concentration will stop the atomization process, making the spray liquor unsprayable.

[0007] Oil-based drift reduction additives work well over a wide concentration range. However, surfactants (such as dispersants, wetting agents, spreading agents or absorption enhancers) required in the formulation can reduce their effectiveness, with the result that at higher concentrations of these surfactants in the spray liquid, oil-based drift reduction additives may become ineffective at lower spray volumes.

[0008] Therefore, there is a need for a drift reduction additive that can be effective at both low and high spray volumes without causing high viscosity or other adverse effects in the formulation. This is achieved by the present invention, wherein a polymer-based drift reduction additive and an oil-based drift reduction additive are combined in an effective amount in a formulation. The present invention is particularly beneficial when the formulation contains a surfactant-based spreading additive and an absorption enhancing additive, because otherwise these formulations have a higher risk of drift and off-field losses.

[0009] Combinations of hydroxypropylated guar gum or other guar gums with oils in drift reduction compositions have been disclosed in US 2002 / 108415 A1, WO 2022 / 023255 A1, WO 2021 / 127865 A1 and US 2018 / 184647 A1. However, the oil component is always used in very high amounts and has different uses in addition to drift reduction, such as as a carrier and absorption enhancer.

[0010] In addition to the drift reducing effect, oils are also commonly used as absorption enhancers, but the amounts required here are much higher, typically 100 to 500 g / ha, which leaves little room for including a second polymeric drift reducer in the formulation. In this case, the amount of drift reducing oil in the formulation of the present invention is much lower than 100 g / ha, thereby enabling the second polymeric drift reducer to be easily included in the formulation.

[0011] Additionally, as spray volume decreases, the concentration of the various surfactant-based components of the formulation increases in the spray liquid. The relatively high concentrations of these surfactants at low spray volumes can neutralize the drift-reducing effect of the oil, thus creating a critical need for a secondary drift reducer that can still reduce drift in the presence of higher surfactant concentrations. This can be accomplished with drift-reducing polymers. It is also important to note that each of the other adjuvants in this context can affect the efficacy and handling of the formulation and interact physically and chemically with the other adjuvants and active ingredients, resulting in formulation instability or reduced efficacy.

[0012] Surprisingly, it has been discovered that agricultural chemical formulations comprising certain polymer and oil combinations at very low concentrations can provide reduced drift of the formulation over a wide range of spray rates.

[0013] The various formulations are described below.

[0014] In one aspect, the present invention relates to an agricultural chemical formulation comprising:

[0015] a) one or more active ingredients,

[0016] b) one or more polymer-based drift reduction additives selected from poly(ethylene oxide) (hereinafter referred to as PEO) and hydroxypropylated guar gum (hereinafter referred to as HP guar gum),

[0017] c) one or more oil-based drift reduction additives,

[0018] d) one or more spreading agents and / or absorption-enhancing additives,

[0019] e) Other formulants,

[0020] f) one or more carriers to make up the total amount, wherein at least one carrier is water,

[0021] wherein a) is present in 10-550 g / l, preferably 15-300 g / l and more preferably 20-200 g / l,

[0022] wherein b) is present at 0.2-50 g / l, preferably 0.5-40 g / l and more preferably 1-15 g / l, wherein c) is present at 0.5-45 g / l, preferably 1-30 g / l and more preferably 5-25 g / l, wherein d) is present at 10-200 g / l, preferably 20-160 g / l and more preferably 25-140 g / l, and

[0023] wherein e) is present in 20-300 g / l, preferably 30-180 g / l and more preferably 30-135 g / l.

[0024] In a preferred embodiment,

[0025] a) present in the range of 10-550 g / l,

[0026] b) present in an amount of 0.2-50 g / l,

[0027] c) present in the range of 0.5-45 g / l,

[0028] d) present in an amount of 10-200 g / l,

[0029] e) present at 20-300 g / l,

[0030] f) Make up the total amount of carrier.

[0031] In another preferred embodiment,

[0032] a) present at 15-300 g / l,

[0033] b) present in the range of 0.5-40 g / l,

[0034] c) present in the range of 1 to 30 g / l,

[0035] d) present at 20-160 g / l,

[0036] e) present at 30-180 g / l.

[0037] f) Make up the total amount of carrier.

[0038] In an even more preferred embodiment,

[0039] a) present at 20-200 g / l,

[0040] b) present at 1-15 g / l,

[0041] c) present at 5-25 g / l,

[0042] d) present at 25-140 g / l,

[0043] e) present at 30-135 g / l,

[0044] f) Make up the total amount of carrier.

[0045] It will be appreciated that in the case of various combinations of components, the percentages of all components in the preparation always add up to 100.

[0046] If not stated otherwise, % in the present application means percentage by weight (% w / w).

[0047] In addition, if not otherwise stated, reference to "to volume" for a carrier means that the total volume of the formulation is made up to 1000 ml (1 1) with the carrier (particularly water). For the sake of clarity, it should be understood that if it is not clear, the density of the formulation should be understood as 1 g / cm 3 .

[0048] If not defined otherwise in this application, molecular weight refers to the weight average molecular weight Mw determined by GPC in dichloromethane at 25°C using polystyrene as standard.

[0049] In the context of the present invention, the formulations can be applied using a wide range of spray rates of 1 l / ha to 2000 l / h, preferably 5 l / ha to 1500 l / ha and more preferably 8 l / ha to 1200 l / ha.

[0050] Therefore, another aspect of the present invention is a method of applying the formulation of the invention to crops, wherein the formulation is applied at a spray rate of 1 l / ha to 2000 l / ha, preferably 5 l / ha to 1500 l / ha and more preferably 8 l / ha to 1200 l / ha.

[0051] Therefore, another aspect of the present invention is the use of the formulation according to the invention for applying it to crops, wherein the formulation is applied at a spray rate of 1 l / ha to 2000 l / ha, preferably 5 l / ha to 1500 l / ha and more preferably 8 l / ha to 1200 l / ha.

[0052] Furthermore, for low spray rates, the formulations according to the invention are applied at a spray rate of 1 to 25 l / ha, preferably 2 to 20 l / ha and more preferably 5 to 15 l / ha.

[0053] Therefore, another aspect of the present invention is a method of applying the formulation according to the invention to crops, wherein the formulation is applied at a spray rate of 1 to 25 l / ha, preferably 2 to 20 l / ha and more preferably 5 to 15 l / ha.

[0054] Therefore, a further aspect of the present invention is the use of a formulation according to the invention for applying it to crops, wherein the formulation is applied at a spray rate of 1 to 25 l / ha, preferably 2 to 20 l / ha and more preferably 5 to 15 l / ha.

[0055] Preferably, the preparation is applied in the form of a spray liquid containing the preparation at the above-mentioned spray rate.

[0056] The ratio of b) to c) in the preparation of the present invention is 1:40 to 10:1, more preferably 1:10 to 5:1, most preferably 1:6 to 2:1.

[0057] In the preparation of the present invention, the ratio of b) to c) to d) is 1:40:150 to 10:1:10, more preferably 1:12:120 to 2:1:5, most preferably 1:8:50 to 1:2:5.

[0058] Preferably, the above ratios also apply to the spray liquid containing the preparation.

[0059] Another aspect of the invention is the use of the formulation of the invention for delivery to an agricultural target plot:

[0060] The amount of b) is from 0.5 to 15 g / ha, more preferably from 1 to 12 g / ha, most preferably from 1 to 10 g / ha.

[0061] The amount of c) is from 0.5 to 40 g / ha, more preferably from 1 to 20 g / ha, most preferably from 2 to 10 g / ha.

[0062] The amount of d) is from 10 to 200 g / ha, more preferably from 15 to 160 g / ha, most preferably from 20 to 100 g / ha.

[0063] In another preferred embodiment of the present invention, the preparation consists only of the above-mentioned ingredients a) to f) in the specified amounts and ranges.

[0064] Furthermore, it should be understood that the preferred given ranges for application amounts or application rates and the preferred given ranges for the individual ingredients given in this specification can be freely combined, and all combinations are disclosed herein, however, in a more preferred embodiment, the ingredients are preferably present in the ranges with the same degree of preference, and even more preferably the ingredients are present in the most preferred ranges.

[0065] In the context of the present invention, suitable formulation types are defined as suspension concentrates, aqueous suspensions, suspoemulsions, capsule suspensions, aqueous dispersible concentrates, soluble solutions, aqueous emulsions or aqueous emulsion concentrates, preferably suspension concentrates, aqueous suspensions and suspoemulsions.

[0066] Active ingredients a):

[0067] The active compounds identified here by their common names are known and are described, for example, in the Pesticide Manual ("The Pesticide Manual" 16th edition, British Crop Protection Council 2012) or can be found on the Internet (e.g. http: / / www.alanwood.net / pesticides). The classification is based on the IRAC Mode of Action Classification Scheme current at the time of filing this patent application.

[0068] The active ingredients a) are preferably agrochemically active compounds which are selected from the group consisting of fungicides, herbicides or insecticides.

[0069] Examples of fungicides a) according to the invention are:

[0070] 1) Inhibitors of ergosterol biosynthesis, for example (1.001) cyproconazole, (1.002) difenoconazole, (1.003) epoxiconazole, (1.004) fenhexamid, (1.005) fenpropidin, (1.006) fenpropimorph, (1.007) fenpyrazamine, (1.008) fluquinconazole, (1.009) flutriafol, (1.010) imazalil, (1.011) imazalil sulfate sulfate), (1.012) ipconazole, (1.013) metconazole, (1.014) myclobutanil, (1.015) paclobutrazol, (1.016) prochloraz, (1.017) propiconazole, (1.018) prothioconazole, (1.019) pyrisoxazole, (1.020) spiroxamine, (1.021) tebuconazole, (1.022) tetraconazole, (1.023) triadimenol, (1.024) tridemorph, (1.025) trichlorfonazole triticonazole), (1.026) (1R, 2S, 5S) -5- (4-chlorobenzyl) -2- (chloromethyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol, (1.027) (1S, 2R, 5R) -5- (4-chlorobenzyl) -2- (chloromethyl) -2-methyl-1- (1H-1,2,4-triazol-1-ylmethyl) cyclopentanol, (1.028) (2R) -2- (1-chlorocyclopropyl) -4- [ (1R)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.029) (2R)-2-(1-chlorocyclopropyl)-4-[(1S)-2,2-dichlorocyclopropyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.030) (2R)-2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.031) (2S) -2- (1-chlorocyclopropyl) -4- [(1R) -2,2-dichlorocyclopropyl] -1- (1H-1,2,4-triazol-1-yl) butan-2-ol, (1.032) (2S) -2- (1-chlorocyclopropyl) -4- [(1S) -2,2-dichlorocyclopropyl] -1- (1H-1,2,4-triazol-1-yl) butan-2-ol, (1.033) (2S) -2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1H-1,2,4-triazol-1-yl) propan-2-ol, (1.034) (R) - [3- (4-chloro-2-fluorophenyl) -5- (2,4-difluorophenyl) -1,2-oxazol-4-yl] ( pyridin-3-yl)methanol, (1.035) (S)-[3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.036) [3-(4-chloro-2-fluorophenyl)-5-(2,4-difluorophenyl)-1,2-oxazol-4-yl](pyridin-3-yl)methanol, (1.037) 1-({(2R,4S)-2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl-1,3-dioxolan-2-yl}methyl)-1H-1,2,4-triazole, (1.038) 1-({(2S,4S)-2-[2-chloro-4-(4-chlorophenoxy)phenyl]-4-methyl 1-{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate, (1.041) 1-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazol-5-yl thiocyanate thiocyanate, (1.042) 2-[(2R,4R,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.043) 2-[(2R,4R,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.044) 2-[(2R,4S,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.046)045) 2-[(2R,4S,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.046) 2-[(2S,4R,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.047) 2-[(2S,4R,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.0 48) 2-[(2S,4S,5R)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.049) 2-[(2S,4S,5S)-1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.050) 2-[1-(2,4-dichlorophenyl)-5-hydroxy-2,6,6-trimethylhept-4-yl]-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.051) 2-[2-chloro-4-( 2-[2-chloro-4-(4-chlorophenoxy)phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.053) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)butan-2-ol, (1.054) 2-[4-(4-chlorophenoxy)-2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)pentan-2-ol, (1.055) Mefentrifluconazoline le), (1.056) 2-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.057) 2-{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.058) 2-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-2,4-dihydro-3H-1,2,4-triazole-3-thione, (1.059) 5-(4-chlorobenzyl)-2-(chloromethyl)-2-methyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol, (1.060) 5-(allylthio)-1-{[3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazole, (1.061) 5-(allylthio)-1-{[rel(2R,3R)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazole, (1.062) 5-(allylthio)-1-{[rel(2R,3S)-3-(2-chlorophenyl)-2-(2,4-difluorophenyl)oxiran-2-yl]methyl}-1H-1,2,4-triazole )-2-(2,4-difluorophenyl)oxirane-2-yl]methyl}-1H-1,2,4-triazole, (1.063) N'-(2,5-dimethyl-4-{[3-(1,1,2,2-tetrafluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methyliminocarboxamide, (1.064) N'-(2,5-dimethyl-4-{[3-(2,2,2-trifluoroethoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methyliminocarboxamide, (1.065) N'-(2,5-dimethyl-4-{[3-(2,2,3,3-tetrafluoropropoxy)phenyl]sulfanyl}phenyl)-N-ethyl-N-methyliminocarboxamide N-(2,5-dimethyl-4-{[3-(pentafluoroethoxy)phenyl]thio}phenyl)-N-ethyl-N-methyliminocarboxamide, (1.067) N'-(2,5-dimethyl-4-{3-[(1,1,2,2-tetrafluoroethyl)thio]phenoxy}phenyl)-N-ethyl-N-methyliminocarboxamide, (1.068) N'-(2,5-dimethyl-4-{3-[(2,2,2-trifluoroethyl)thio]phenoxy}phenyl)-N-ethyl-N-methyliminocarboxamide, (1.069) N'-(2,5-dimethyl-4-{3-[(2,2,3,3-tetrafluoropropyl)thio]phenoxy}phenyl N'-(2,5-dimethyl-4-{3-[(pentafluoroethyl)thio]phenoxy}phenyl)-N-ethyl-N-methyliminocarboxamide, (1.071) N'-(2,5-dimethyl-4-phenoxyphenyl)-N-ethyl-N-methyliminocarboxamide, (1.072) N'-(4-{[3-(difluoromethoxy)phenyl]thio}-2,5-dimethylphenyl)-N-ethyl-N-methyliminocarboxamide, (1.073) N'-(4-{3-[(difluoromethyl)thio]phenoxy}-2,5-dimethylphenyl)-N-ethyl-N-methyliminocarboxamide, (1.074) N'-(4-{3-[(difluoromethyl)thio]phenoxy}-2,5-dimethylphenyl)-N-ethyl-N-methyliminocarboxamide, (1.076)074) N'-[5-bromo-6-(2,3-dihydro-1H-inden-2-yloxy)-2-methylpyridin-3-yl]-N-ethyl-N-methyliminocarboxamide, (1.075) N'-{4-[(4,5-dichloro-1,3-thiazol-2-yl)oxy]-2,5-dimethylphenyl}-N-ethyl-N-methyliminocarboxamide, (1.076) N'-{5-bromo-6-[(1R)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methyliminocarboxamide, (1.077) N'-{5-bromo-6-[(1S)-1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl N-{5-bromo-6-[(cis-4-isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methyliminocarboxamide, (1.078) N'-{5-bromo-6-[(cis-4-isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methyliminocarboxamide, (1.079) N'-{5-bromo-6-[(trans-4-isopropylcyclohexyl)oxy]-2-methylpyridin-3-yl}-N-ethyl-N-methyliminocarboxamide, (1.080) N'-{5-bromo-6-[1-(3,5-difluorophenyl)ethoxy]-2-methylpyridin-3-yl}-N-ethyl-N-methyliminocarboxamide, (1.081) Ipfentrifluconazole, (1.082) 2-[4-(4-chlorophenoxy) -2-(trifluoromethyl)phenyl]-1-(1H-1,2,4-triazol-1-yl)propan-2-ol, (1.083) 2-[6-(4-bromophenoxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol, (1.084) 2-[6-(4-chlorophenoxy)-2-(trifluoromethyl)-3-pyridyl]-1-(1,2,4-triazol-1-yl)propan-2-ol, (1.085) 3-[2-(1-chlorocyclopropyl)-3-(3-chloro-2-fluorophenyl)-2-hydroxy-propyl]imidazole-4-carbonitrile, (1.086) 4-[[6-[rac-(2R)-2-(2,4-difluorophenyl)-1,1-difluoro -2-hydroxy-3-(5-thio-4H-1,2,4-triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile, (1.087) N-isopropyl-N'-[5-methoxy-2-methyl-4-(2,2,2-trifluoro-1-hydroxy-1-phenylethyl)phenyl]-N-methyliminocarboxamide, (1.088) N'-{5-bromo-2-methyl-6-[(1-propoxyprop-2-yl)oxy]pyridin-3-yl}-N-ethyl-N-methyliminocarboxamide, (1.089) hexaconazole, (1.090) penconazole, (1.091) fenbuconazole. .

[0071] 2) Inhibitors of respiratory complex I or II, for example (2.001) benzovindiflupyr, (2.002) bixafen, (2.003) boscalid, (2.004) carboxin, (2.005) fluopyram, (2.006) flutolanil, (2.007) fluxapyroxad, (2.008) furametpyr, (2.009) isofetamid, (2.010) pyrazolone isopyrazam (trans epimeric enantiomers 1R, 4S, 9S), (2.011) pyraclostrobin (trans epimeric enantiomers 1S, 4R, 9R), (2.012) pyraclostrobin (trans epimeric racemates 1RS, 4SR, 9SR), (2.013) pyraclostrobin (mixture of cis epimeric racemates 1RS, 4SR, 9RS and trans epimeric racemates 1RS, 4SR, 9SR), (2.014) pyraclostrobin (cis epimeric enantiomers 1R, 4S, 9R), (2.015) pyraclostrobin (cis epimeric enantiomers 1S, 4R, 9S), (2.016) pyraclostrobin (cis (2.017) penflufen, (2.018) penthiopyrad, (2.019) pydiflumetofen, (2.020) pyraziflumid, (2.021) sedaxane, (2.022) 1,3-dimethyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-indene-4-yl)-1H-pyrazole-4-carboxamide, (2.023) 1,3-dimethyl-N-[(3R)-1,1,3-trimethyl-2,3-dihydro-1H-indene-4-yl]-1H-pyrazole-4-carboxamide 1H-pyrazole-4-carboxamide, (2.024) 1,3-dimethyl-N-[(3S)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.025) 1-methyl-3-(trifluoromethyl)-N-[2'-(trifluoromethyl)biphenyl-2-yl]-1H-pyrazole-4-carboxamide, (2.026) 2-fluoro-6-(trifluoromethyl)-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)benzamide, (2.027) 3-(difluoromethyl)-1-methyl-N-(1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl)-1H-pyrazole-4-carboxamide, (2.028) inpyrfluxam, (2.029) 3-(difluoromethyl)-1-methyl-N-[(3S)-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1H-pyrazole-4-carboxamide, (2.030) fluindapyr, (2.031) 3-(difluoromethyl)-N-[(3R)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide, (2.032) 3-(difluoromethyl)-N-[(3S)-7-fluoro-1,1,3-trimethyl-2,3-dihydro-1H-inden-4-yl]-1-methyl-1H-pyrazole-4-carboxamide amine, (2.033) 5,8-difluoro-N-[2-(2-fluoro-4-{[4-(trifluoromethyl)pyridin-2-yl]oxy}phenyl)ethyl]quinazolin-4-amine, (2.034) N-(2-cyclopentyl-5-fluorobenzyl-)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.035) N-(2-tert-butyl-5-methylbenzyl-)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.036) N-(2-tert-butylbenzyl-)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.037 )N-(5-chloro-2-ethylbenzyl-)-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.038) isoflucypram, (2.039) N-[(1R,4S)-9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-naphthol-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.040) N-[(1S,4R)-9-(dichloromethylene)-1,2,3,4-tetrahydro-1,4-naphthol-5-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.041) N-[1- (2,4-dichlorophenyl)-1-methoxyprop-2-yl]-3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.042) N-[2-chloro-6-(trifluoromethyl)benzyl-]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.043) N-[3-chloro-2-fluoro-6-(trifluoromethyl)benzyl-]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.044) N-[5-chloro-2-(trifluoromethyl)benzyl-]-N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.045) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-1-methyl-N-[5-methyl-2-(trifluoromethyl)benzyl]-1H-pyrazole-4-carboxamide, (2.046) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-fluoro-6-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.047) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropyl-5-methylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.048) N-cyclopropyl-3-(difluoromethyl)-5-fluoro- N-(2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.049) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.050) N-cyclopropyl-3-(difluoromethyl)-5-fluoro-N-(5-fluoro-2-isopropylbenzyl)-1-methyl-1H-pyrazole-4-carboxamide, (2.051) N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-4,5-dimethylbenzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide , (2.052) N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-fluorobenzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.053) N-cyclopropyl-3-(difluoromethyl)-N-(2-ethyl-5-methylbenzyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.054) N-cyclopropyl-N-(2-cyclopropyl-5-fluorobenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.055) N-cyclopropyl-N-(2-cyclopropyl-5-methylbenzyl) )-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.056) N-cyclopropyl-N-(2-cyclopropylbenzyl)-3-(difluoromethyl)-5-fluoro-1-methyl-1H-pyrazole-4-carboxamide, (2.057) pyrapropoyne, (2.058) N-[rac-(1S,2S)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)-nicotinamide, (2.059) N-[(1S,2S)-2-(2,4-dichlorophenyl)cyclobutyl]-2-(trifluoromethyl)nicotinamide. .

[0072] 3) Inhibitors of respiratory complex III, such as (3.001) ametoctradin, (3.002) amisulbrom, (3.003) azoxystrobin, (3.004) coumethoxystrobin, (3.005) coumoxystrobin, (3.006) cyazofamid, (3.007) dimoxystrobin, (3.008) enoxastrobin, (3.009) famoxa done), (3.010) fenamidone, (3.011) flufenoxystrobin, (3.012) fluoxastrobin, (3.013) kresoxim-methyl, (3.014) metominostrobin, (3.015) orysastrobin, (3.016) picoxystrobin, (3.017) pyraclostrobin, (3.018) pyramet ostrobin), (3.019) pyraoxystrobin, (3.020) trifloxystrobin, (3.021) (2E)-2-{2-[({[(1E)-1-(3-{[(E)-1-fluoro-2-phenylvinyl]oxy}phenyl)ethylidene]amino}oxy)methyl]phenyl}-2-(methoxyimino)-N-methylacetamide, (3.022) (2E,3Z)-5-{[1-(4-chlorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide, (3.023) (2R)-2-{2-[( 2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide, (3.024) (2S)-2-{2-[(2,5-dimethylphenoxy)methyl]phenyl}-2-methoxy-N-methylacetamide, (3.025) fenpicoxamid, (3.026) mandestrobin, (3.027) N-(3-ethyl-3,5,5-trimethylcyclohexyl)-3-formamido-2-hydroxybenzamide, (3.028) (2E,3Z)-5-{[1-(4-chloro-2-fluorophenyl)-1H-pyrazol-3-yl]oxy}-2-(methoxyimino)-N,3-dimethylpent-3-enamide, (3.029)029) methyl {5-[3-(2,4-dimethylphenyl)-1H-pyrazol-1-yl]-2-methylbenzyl}carbamate, (3.030) metyltetraprole, (3.031) florylpicoxamid. .

[0073] 4) Inhibitors of mitosis and cell division, for example (4.001) carbendazim, (4.002) diethofencarb, (4.003) ethaboxam, (4.004) fluopicolide, (4.005) pencycuron, (4.006) thiabendazole, (4.007) thiophanate-methyl, (4.008) zoxamide, (4.009) pyridachlometyl, (4.010) .010) 3-chloro-5-(4-chlorophenyl)-4-(2,6-difluorophenyl)-6-methylpyridazine, (4.011) 3-chloro-5-(6-chloropyridin-3-yl)-6-methyl-4-(2,4,6-trifluorophenyl)pyridazine, (4.012) 4-(2-bromo-4-fluorophenyl)-N-(2,6-difluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.013) 4-(2-bromo-4-fluorophenyl)-N-(2-bromo-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.014) 4-(2-bromo-4-fluorophenyl)-N-(2-bromophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.015 )4-(2-bromo-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.016)4-(2-bromo-4-fluorophenyl)-N-(2-chlorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.017)4-(2-bromo-4-fluorophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.018)4-(2-chloro-4-fluorophenyl)-N-(2,6-difluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.019)4-(2-chloro-4-fluorophenyl)-N-(2-chloro-6-fluorophenyl)-1,3-dimethyl-1H-pyrazol- 5-amine, (4.020) 4-(2-chloro-4-fluorophenyl)-N-(2-chlorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.021) 4-(2-chloro-4-fluorophenyl)-N-(2-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.022) 4-(4-chlorophenyl)-5-(2,6-difluorophenyl)-3,6-dimethylpyridazine, (4.023) N-(2-bromo-6-fluorophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.024) N-(2-bromophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.025) N-(4-chloro-2,6-difluorophenyl)-4-(2-chloro-4-fluorophenyl)-1,3-dimethyl-1H-pyrazol-5-amine, (4.026) fluopimomide. .

[0074] 5) Compounds that can have multi-site effects, such as (5.001) Bordeaux mixture, (5.002) captafol, (5.003) captan, (5.004) chlorothalonil, (5.005) copper hydroxide, (5.006) copper naphthenate, (5.007) copper oxide, (5.008) copper oxychloride, (5.009) copper chlorate, (5.010) copper chlorate, (5.011) copper chlorate, (5.012) copper chlorate, (5.013) copper chlorate, (5.014) copper chlorate, (5.015) copper chlorate, (5.016) copper chlorate, (5.017) copper chlorate, (5.018) copper chlorate, (5.019) copper chlorate, (5.020) copper chlorate, (5.021) copper chlorate, (5.022) copper chlorate, (5.023) copper chlorate, (5.024) copper chlorate, (5.025) copper chlorate, (5.026) copper chlorate, (5.027) copper chlorate, (5.028) copper chlorate, (5.029) copper chlorate, (5.030) copper chlorate, (5.031) copper chlorate, (5.032) copper chlorate, (5.033) copper chlorate, (5.034) copper chlorate, (5.035) copper chlorate, (5.036) copper chlorate, (5.037) copper chlorate, (5.038) copper chlorate, (5.039) copper chlorate, (5.040) copper chlorate, (5.041) copper chlorate, (5.042) oxychloride), (5.009) copper (2+) sulfate, (5.010) dithianon, (5.011) dodine, (5.012) folpet, (5.013) mancozeb, (5.014) maneb, (5.015) metiram, (5.016) metiram zinc zinc), (5.017) oxine-copper, (5.018) propineb, (5.019) sulfur and sulfur preparations (including calcium polysulfide), (5.020) thiram, (5.021) zineb, (5.022) ziram, (5.023) 6-ethyl-5,7-dioxo-6,7-dihydro-5H-pyrrolo[3',4':5,6][1,4]dithiino[2,3-c][1,2]thiazole-3-carbonitrile.

[0075] 6) Compounds that can induce host defense, such as (6.001) acibenzolar-S-methyl, (6.002) isotianil, (6.003) probenazole, and (6.004) tiadinil.

[0076] 7) Inhibitors of amino acid and / or protein biosynthesis, for example (7.001) cyprodinil, (7.002) kasugamycin, (7.003) kasugamycin hydrochloride hydrate, (7.004) oxytetracycline, (7.005) pyrimethanil, (7.006) 3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl)quinoline.

[0077] 8) ATP production inhibitors, for example (8.001) silthiofam.

[0078] 9) Inhibitors of cell wall synthesis, for example (9.001) benthiavalicarb, (9.002) dimethomorph, (9.003) flumorph, (9.004) iprovalicarb, (9.005) mandipropamid, (9.006) pyrimorph, (9.007) valifenalate, (9.008) (2E)-3-(4-tert-butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one, (9.009) (2Z)-3-(4-tert-butylphenyl)-3-(2-chloropyridin-4-yl)-1-(morpholin-4-yl)prop-2-en-1-one.

[0079] 10) Inhibitors of lipid and membrane synthesis, for example (10.001) propamocarb, (10.002) propamocarb hydrochloride, (10.003) tolclofos-methyl.

[0080] 11) Melanin biosynthesis inhibitors, for example (11.001) tricyclazole, (11.002) tolprocarb.

[0081] 12) Nucleic acid synthesis inhibitors, for example (12.001) benalaxyl, (12.002) kiralaxyl, (12.003) metalaxyl, (12.004) mefenoxam.

[0082] 13) Signal transduction inhibitors, for example (13.001) fludioxonil, (13.002) iprodione, (13.003) procymidone, (13.004) proquinazid, (13.005) quinoxyfen, (13.006) vinclozolin.

[0083] 14) Compounds that can act as uncouplers, for example (14.001) fluazinam and (14.002) meptyldinocap.

[0084] 15) Other fungicides selected from (15.001) abscisic acid, (15.002) benthiazole, (15.003) bethoxazin, (15.004) capsimycin, (15.005) carvone, (15.006) chinomethionat, (15.007) cufraneb, (15.008) cyflufenamid, (15.010) cyflufenamid, (15.011) cyflufenamid, (15.012) cyflufenamid, (15.013) cyflufenamid, (15.014) cyflufenamid, (15.015) cyflufenamid, (15.016) cyflufenamid, (15.017) cyflufenamid, (15.018) cyflufenamid, (15.019) cyflufenamid, (15.020) cyflufenamid, (15.021) cyflufenamid, (15.022) cyflufenamid, (15.023) cyflufenamid, (15.024) cyflufenamid, (15.025) cyflufenamid, (15.026) cyflufenamid, (15.027) cyflufenamid, (15.028) cyflufenamid, (15.029) cyflufenamid, (15.030) cyflufenamid, (15.031) cyflufenamid, (15.032) cyflufenamid, (15.033) cyflufenamid, (15.034) cyflufenamid, (15.035) cyflufenamid, (1 009) cymoxanil, (15.010) cyprosulfamide, (15.011) flutianil, (15.012) fosetyl-aluminum, (15.013) fosetyl-calcium, (15.014) fosetyl-sodium, (15.015) methyl isothiocyanate, (15.016) metrafenone, (15.017) mildiomycin, (15.018) natamycin, (15.019) nickel dimethyl dithiocarbamate dimethyldithiocarbamate), (15.020) nitrothal-isopropyl, (15.021) oxamocarb, (15.022) oxathiapiprolin, (15.023) oxyfenthiin, (15.024) pentachlorophenol and its salts, (15.025) phosphorous acid and its salts, (15.026) propamocarb-fosetylate, ( 15.027) pyriofenone (chlazafenone), (15.028) tebufloquin, (15.029) tecloftalam, (15.030) tolnifanide, (15.031) 1-(4-{4-[(5R)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (15.032) 1-(4-{4-[(5R)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (15.033) 1-(4-{4-[(5R)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (15.034) 1-(4-{4-[(5R)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (15.035) 1-(4-{4032) 1-(4-{4-[(5S)-5-(2,6-difluorophenyl)-4,5-dihydro-1,2-oxazol-3-yl]-1,3-thiazol-2-yl}piperidin-1-yl)-2-[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]ethanone, (15.033) 2-(6-benzylpyridin-2-yl)quinazoline, (15.034) dipymetitrone, (15.035) 2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1 -yl]ethanone, (15.036) 2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-chloro-6-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanone, (15.037) 2-[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]-1-[4-(4-{5-[2-fluoro-6-(prop-2-yn-1-yloxy)phenyl]-4,5-dihydro-1,2-oxazol-3-yl}-1,3-thiazol-2-yl)piperidin-1-yl]ethanone, (15.038) 2-[6-(3-fluoro-4-methoxy 2-{(5S)-3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenyl methanesulfonate, (15.040) 2-{(5S)-3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}-3-chlorophenyl methanesulfonate, (15.041) Ipflufenoquinoline, (1 5.042) 2-{2-fluoro-6-[(8-fluoro-2-methylquinolin-3-yl)oxy]phenyl}propan-2-ol, (15.043) fluoxapiprolin, (15.044) 2-{3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-4,5-dihydro-1,2-oxazol-5-yl}phenyl methanesulfonate, (15.045) 2-phenylphenol and salts, (15.046) 3-(4,4,5-trifluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)quinoline, (15.047) quinofumelin, (15.048) 4-amino-5-fluoropyrimidin-2-ol (tautomeric form: 4-amino-5-fluoropyrimidin-2(1H)-one), (15.049) 4-oxo-4-[(2-phenylethyl)amino]butyric acid, (15.050) 5-amino-1,3,4-thiadiazole-2-thiol, (15.051) 5-chloro-N'-phenyl-N'-(prop-2-yn-1-yl)thiophene-2-sulfonylhydrazide, (15.052) 5-fluoro-2-[(4-fluorobenzyl)oxy]pyrimidin-4-amine, (15.053) 5-fluoro-2-[(4-methylbenzyl)oxy]pyrimidin-4-amine, (15.054) 9-fluoro-2,2-dimethyl-5-(quinolin-3-yl)-2,3-dihydro-1 ,4-benzoxazepine, (15.055) but-3-yn-1-yl {6-[({[(Z)-(1-methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate, (15.056) (2Z)-3-amino-2-cyano-3-phenylacrylate, (15.057) phenazine-1-carboxylic acid, (15.058) propyl 3,4,5-trihydroxybenzoate, (15.059) quinolin-8-ol, (15.060) quinolin-8-ol sulfate (2:1), (15.061) {6-[({[(1-methyl-1H-tetrazol-5-yl)(phenyl)methylene]amino}oxy)methyl]pyridin-2-yl}carbamate} tert-butyl carbamate, (15.062) 5-fluoro-4-imino-3-methyl-1-[(4-methylphenyl)sulfonyl]-3,4-dihydropyrimidin-2(1H)-one, (15.063) aminopyrifen, (15.064) (N'-[2-chloro-4-(2-fluorophenoxy)-5-methylphenyl]-N-ethyl-N-methyliminocarboxamide), (15.065) (N'-(2-chloro-5-methyl-4-phenoxyphenyl)-N-ethyl-N-methyliminocarboxamide), (15.066) (2-{2-[(7,8-difluoro-2-methylquinolin-3-yl)oxy]-6-fluorophenyl}propan-2-ol), (15.067) (5- bromo-1-(5,6-dimethylpyridin-3-yl)-3,3-dimethyl-3,4-dihydroisoquinoline), (15.068) (3-(4,4-difluoro-5,5-dimethyl-4,5-dihydrothieno[2,3-c]pyridin-7-yl)quinoline), (15.069) (1-(4,5-dimethyl-1H-benzoimidazol-1-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline), (15.070) 8-fluoro-3-(5-fluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)quinolone, (15.071) 8-fluoro-3-(5-fluoro-3,3,4,4-tetramethyl-3,4-dihydroisoquinolin-1-yl)quinolone, (15.072) 3-(4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl)-8-fluoroquinoline, (15.073) (N-methyl-N-phenyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide), (15.074) (methyl {4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}carbamate), (15.075) (N-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzyl}cyclopropanecarboxamide), (15.076) N-methyl-4-(5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.077 )N-[(E)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.078)N-[(Z)-methoxyiminomethyl]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.079)N-[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]cyclopropanecarboxamide, (15.080)N-(2-fluorophenyl)-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.081)2,2-difluoro-N-methyl-2-[4-[5-(trifluoromethyl)-1,2,4 1,2,4-oxadiazol-3-yl]phenyl]acetamide, (15.082) N-allyl-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl)phenyl]methyl]acetamide, (15.083) N-[(E)-N-methoxy-C-methyl-carbonimino]-4-(5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.084) N-[(Z)-N-methoxy-C-methyl-carbonimino]-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.085) N-allyl-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]acetamide 1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrrolidin-2-one, (15.087) N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]thiobenzamide, (15.088) 5-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrrolidin-2-one, (15.089) N-((2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]-3,3,3-trifluoro-propionamide, (15.087) N-methyl-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrrolidin-2-one, (15.088) 5-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]pyrrolidin-2-one, (15.089) N-((2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]-3,3,3-trifluoro-propionamide ...090) 1-methoxy-1-methyl-3-[[4-[5-(trifluoromethyl}-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.091) 1,1-diethyl-3-[[4-[5-(trifluoromethyl}-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.092) N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl)methyl)propanamide, (15.093) N-methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]cyclopropanecarboxamide, (15.094) 1-methoxy-3-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl] 1,2,4-oxadiazol-3-yl]phenyl]methyl]propionamide, (15.098) 1-methoxy-3-methyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propionamide, (15.099) N-(2-methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propionamide, (15.100) N-(2-methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propionamide, (15.201) N-(2-methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propionamide, (15.202) N-(2-methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propionamide, (15.203) N-(2-methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propionamide, (15.204) N-(2-methoxy-N-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]propionamide 1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.099) 1,3-dimethoxy-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.100) 3-ethyl-1-methoxy-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]urea, (15.101) 1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]piperidin-2-one, (15.102) 4,4-dimethyl-2-[[4-(5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one, (15.103 )5,5-dimethyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one, (15.104)3,3-dimethyl-1-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]piperidin-2-one, (15.105)1-[[3-fluoro-4-(5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]azepan-2-one, (15.106)4,4-dimethyl-2-[[4-(5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one, (15.107)107) 5,5-dimethyl-2-[[4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl]methyl]isoxazolidin-3-one, (15.108) 1-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzyl}-1H-pyrazole-4-carboxylic acid ethyl ester, (15.109) N,N-dimethyl-1-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzyl}-1H-1,2,4-triazol-3-amine, (15.110) N-{2,3-difluoro-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzyl}butanamide, (15.111) N-(1-methylcyclopropyl)-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.112) N-(2,4-difluorophenyl)-4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]benzamide, (15.113) 1-(5,6-dimethylpyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.114) 1-(6-(difluoromethyl)-5-methyl-pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.115) 1-(5-(fluoromethyl)-6-methyl-pyridin-3-yl)- 4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.116) 1-(6-(difluoromethyl)-5-methoxy-pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.117) dimethyl-carbamic acid 4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl ester, (15.118) N-{4-[5-(trifluoromethyl)-1,2,4-oxadiazol-3-yl]phenyl}propionamide, (15.119) 3-[2-(1-{[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazole- 4-yl]-1,5-dihydro-2,4-benzodioxepin-6-yl methanesulfonate, (15.120) 9-fluoro-3-[2-(1-{[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-1,5-dihydro-2,4-benzodioxepin-6-yl methanesulfonate, (15.121) 3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-1,5-dihydro-2,4-benzodioxepin-6-yl methanesulfonate, (15.122) 9-fluoro-3-[2-(1-{[5-methyl-3-(trifluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-1,5-dihydro-2,4-benzodioxepin-6-yl methanesulfonate, (15.123)122) 3-[2-(1-{[3,5-bis(difluoromethyl)-1H-pyrazol-1-yl]acetyl}piperidin-4-yl)-1,3-thiazol-4-yl]-9-fluoro-1,5-dihydro-2,4-benzodioxin-6-yl methanesulfonate, (15.123) 1-(6,7-dimethylpyrazolo[1,5-a]pyridin-3-yl)-4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinoline, (15.124) 8-fluoro-N-(4,4,4 -trifluoro-2-methyl-1-phenylbutan-2-yl)quinoline-3-carboxamide, (15.125) 8-fluoro-N-[(2S)-4,4,4-trifluoro-2-methyl-1-phenylbutan-2-yl]quinoline-3-carboxamide, (15.126) N-(2,4-dimethyl-1-phenylpentan-2-yl)-8-fluoroquinoline-3-carboxamide and (15.127) N-[(2S)-2,4-dimethyl-1-phenylpentan-2-yl]-8-fluoroquinoline-3-carboxamide. .

[0085] Examples of insecticides a) according to the invention are:

[0086] (1) Acetylcholinesterase (AChE) inhibitors, such as carbamates: Alanycarb, Aldicarb, Bendiocarb, Benfuracarb, Butocarboxim, Butoxycarboxim, Carbaryl, Carbofuran, Carbosulfan, Ethiofencarb, Fenobucarb, Formetanate, Furathiocarb, b), isoprocarb, metiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, triazamate, trimethacarb, XMC and xylylcarb, or organophosphates such as acephate, azamethiphos, azinphos-methyl, chlorpyrifos, chlorpyrifos-methyl ... phos-ethyl), Azinphos-methyl, Cadusafos, Chlorethoxyfos, Chlorfenvinphos, Chlormephos, Chloropyrifos-methyl, Coumaphos, Cyanophos, Demeton-S-methyl, Diazinon, Dichlorvos / DDVP, Dicrotophos, Dimethoate Dimethoat), Dimethylvinphos, Disulfoton, EPN, Ethion, Ethoprophos, Famphur, Fenamiphos, Fenitrothion, Fenthion, Fosthiazate, Heptenophos, Imicyafos, Isofenphos, Isopropyl O-(methoxyaminothiophosphoryl) salicylate, Isoxathion,Malathion, Mecarbam, Methamidophos, Methidathion, Mevinphos, Monocrotophos, Naled, Omethoate, Oxydemeton-methyl, Parathion-methyl, Phenthoat, Phorat, Phosalone, Phosmet, Phosphamidon, Phoxim, Pirimphos-methyl iphos-methyl), Profenofos, Propetamphos, Prothiofos, Pyraclofos, Pyridaphenthion, Quinalphos, Sulfotep, Tebupirimfos, Temephos, Terbufos, Tetrachlorvinphos, Thiometon, Triazophos, Trichlorfon and Vamidothion.

[0087] (2) GABA-gated chloride channel antagonists, preferably cyclodiene-organochlorines selected from Chlordane and Endosulfan, or phenylpyrazoles selected from Ethiprole and Fipronil.

[0088] (3) Sodium channel modulators / voltage-dependent sodium channel blockers, such as pyrethroids, for example, acrinathrin, allethrin, d-cis-trans allethrin, d-trans allethrin, bifenthrin, bioallethrin, bioallethrin S-cyclopentenyl isomer, bioresmethrin, cycloprothrin, cyfluthrin, beta-cyfluthrin, cyhalothrin Cyhalothrin, lambda-Cyhalothrin, gamma-Cyhalothrin, Cypermethrin, alpha-Cypermethrin, beta-Cypermethrin, theta-Cypermethrin, zeta-Cypermethrin, Cyphenothrin [(1R)-trans-isomer], Deltamethrin n), Empenthrin [(EZ)-(1R)-isomer], Esfenvalerate, Etofenprox, Fenpropathrin, Fenvalerate, Flucythrinate, Flumethrin, tau-Fluvalinate, Halfenprox, Imiprothrin, Kadethrin, Momfluorothrin, Permethrin (Permethrin), Phenothrin [(1R)-trans-isomer], Prallethrin, Pyrethrins (Pyrethrum), Resmethrin, Silafluofen, Tefluthrin, Tetramethrin, Tetramethrin [(1R)-isomer], Tralomethrin and Transfluthrin or DDT or methoxychlor.

[0089] (4) Competitive activators of nicotinic acetylcholine receptors (nAChR), preferably neonicotinoids selected from acetamiprid, clothianidin, dinotefuran, imidacloprid, nitenpyram, thiacloprid and thiamethoxam, or nicotine, or sulfoximines selected from sulfoxaflor, or butenolides selected from flupyradifurone, or mesoionics selected from triflumezopyrim.

[0090] (5) Allosteric activators of nicotinic acetylcholine receptor (nAChR), preferably spinosynes, selected from spinetoram and spinosad.

[0091] (6) Allosteric modulators of glutamate-dependent chloride channels (GluCl), preferably Avermectins / Milbemycins, selected from Abamectin, Emamectin benzoate, Lepimectin and Milbemectin.

[0092] (7) Juvenile hormone mimetics, preferably juvenile hormone analogs selected from the group consisting of hydropren, kinopren and methopren, or fenoxycarb or pyriproxyfen.

[0093] (8) Various non-specific (multi-site) inhibitors, preferably alkyl halides selected from methyl bromide and other alkyl halides, or chloropicrin or sulfurylfluorid or borax or tartar emetic, or methyl isocyanate generators selected from Diazomet and Metam.

[0094] (9) A chord organ TRPV channel modulator selected from pymetrozin and pyrifluquinazon.

[0095] (10) A mite growth inhibitor selected from the group consisting of Clofentezin, Hexythiazox, Diflovidazin and Etoxazol.

[0096] (11) An insect intestinal membrane microbial disruptor, which is selected from Bacillus thuringiensis subspecies israelensis, Bacillus sphaericus, Bacillus thuringiensis subspecies aizawai, Bacillus thuringiensis subspecies kurstaki, Bacillus thuringiensis subspecies tenebrionis and Bacillus thuringiensis plant protein, and the Bacillus thuringiensis subspecies is selected from Cry1Ab, Cry1Ac, Cry1Fa, Cry1A.105, Cry2Ab, Vip3A, mCry3A, Cry3Ab, Cry3Bb and Cry34Ab1 / 35Ab1.

[0097] (12) Mitochondrial ATP synthase inhibitors, preferably ATP disruptors selected from diafenthiuron, or organotin compounds selected from azocyclotin, cyhexatin and fenbutatin-oxid, or propargit or tetradifon.

[0098] (13) An uncoupler of oxidative phosphorylation that interrupts the proton gradient, selected from chlorfenapyr, dinitrocresol (DNOC) and sulfluramid.

[0099] (14) Nicotinic acetylcholine receptor channel blockers selected from the group consisting of Bensultap, Cartap-hydrochlorid, Thiocylam and Thiosultap-Sodium.

[0100] (15) A type O chitin biosynthesis inhibitor selected from the group consisting of Bistrifluron, Chlorfluazuron, Diflubenzuron, Flucycloxuron, Flufenoxuron, Hexaflumuron, Lufenuron, Novaluron, Noviflumuron, Teflubenzuron and Triflumuron.

[0101] (16) A type 1 chitin biosynthesis inhibitor selected from Buprofezin.

[0102] (17) Molting disruptors (especially dipteras, i.e. two-winged insects) selected from cyromazine.

[0103] (18) An ecdysone receptor agonist selected from the group consisting of chromafenozid, chlorfenapyr, methoxyfenozid and tebufenozid.

[0104] (19) An octopamine receptor agonist selected from amitraz.

[0105] (20) A mitochondrial complex III electron transport inhibitor selected from the group consisting of hydramethylnon, acequinocyl and fluacrypyrim.

[0106] (21) Mitochondrial complex I electron transport inhibitors, preferably so-called METI acaricides selected from fenazaquin, fenpyroximat, pyrimidifen, pyridaben, tebufenpyrad and tolfenpyrad; or rotenon (Derris).

[0107] (22) A voltage-dependent sodium channel blocker selected from the group consisting of indoxacarb and metaflumizone.

[0108] (23) Acetyl-CoA carboxylase inhibitors, preferably tetronic acid and tetramic acid derivatives selected from the group consisting of spirodiclofen, spiromesifen, spirotetramat and spiroxifen (IUPAC name: 11-(4-chloro-2,6-dimethylphenyl)-12-hydroxy-1,4-dioxa-9-azadispiro[4.2.4.2]tetradecane-11-en-10-one).

[0109] (24) Mitochondrial complex IV electron transport inhibitors, preferably phosphines selected from aluminum phosphide, calcium phosphide, phosphine and zinc phosphide; or cyanides selected from calcium cyanide, potassium cyanide and sodium cyanide.

[0110] (25) Mitochondrial complex II electron transport inhibitors, preferably β-ketonitrile derivatives selected from cyenopyrafen and cyflumetofen, or selected from the carboxanilide class of pyflubumid.

[0111] (28) A ryanodine receptor modulator, preferably a diamide selected from the group consisting of chlorantraniliprole, cyantraniliprole and flubendiamid.

[0112] (29) A chord organ modulator (with an unclear target structure), selected from Flonicamid.

[0113] (30) Other active ingredients selected from the group consisting of Acynonapyr, Afidopyropen, Afoxolaner, Azadirachtin, Benclothiaz, Benzoximat, Benzpyrimoxan, Bifenazat, Broflanilide, Bromopropylat, Chinomethionat, Chloroprallethrin, Cryolit, Cycla niliprol), Cycloxaprid, Cyhalodiamid, Dicloromezotiaz, Dicofol, Dimpropyridaz, Epsilon-Metofluthrin, Epsilon-Momfluthrin, Flometoquin, Fluazaindolizin, Fluensulfon, Flufenerim, Flufenoxystrobin, Flufipro l), Fluhexafon, Fluopyram, Flupyrimin, Fluralaner, Fluxametamid, Fufenozid, Guadipyr, Heptafluthrin, Imidaclothiz, Iprodione, Isocycloseram, Kappa-Bifenthrin, Kappa-Tefluthrin, Lotilaner, Meperfluthrin, Oxazosulfyl, Paic hongding), pyridalyl, pyrifluquinazon, pyriminostrobin, spirobudiclofen, spiropidion, tetramethylfluthrin, tetraniliprol, tetrachlorantraniliprole, tigolaner, tioxazafen, thiofluoximat, and iodomethane; produced by Bacillus firmusfirmus) (I-1582, BioNeem, Votivo) and the following compounds: 1-{2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl}-3-(trifluoromethyl)-1H-1,2,4-triazol-5-amine (known from WO2006 / 043635) (CAS 885026-50-6), {1'-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]-5-fluorospiro[indole-3,4'-piperidinyl]-1(2H)-yl}(2-chloropyridin-4-yl)methanone (known from WO2003 / 106457) (CAS 637360-23-7), 2-chloro-N-[2-{1-[(2E)-3-(4-chlorophenyl)prop-2-en-1-yl]piperidin-4-yl}-4-(trifluoromethyl)phenyl]isonicotinamide (known from WO2006 / 003494) (CAS 872999-66-1), 3-(4-chloro-2,6-dimethylphenyl)-4-hydroxy-8-methoxy-1,8-diazaspiro[4.5]dec-3-en-2-one (known from WO 2010052161) (CAS 1225292-17-0), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-yl carbonate (known from EP2647626) (CAS 1440516-42-6), 4-(but-2-yn-1-yloxy)-6-(3,5-dimethylpiperidin-1-yl)-5-fluoropyrimidine (known from WO 2004 / 099160) (CAS 792914-58-0), PF1364 (known from JP2010 / 018586) (CAS registration number 1204776-60-2), (3E)-3-[1-[(6-chloro-3-pyridyl)methyl]-2-pyridylidene]-1,1,1-trifluoropropane-2-one (known from WO2013 / 144213) (CAS 1461743-15-6), N-[3-(benzylcarbamoyl)-4-chlorophenyl]-1-methyl-3-(pentafluoroethyl)-4-(trifluoromethyl)-1H-pyrazole-5-carboxamide (known from WO2010 / 051926) (CAS1226889-14-0), 5-bromo-4-chloro-N-[4-chloro-2-methyl-6-(methylcarbamoyl)phenyl]-2-(3-chloro-2-pyridyl)pyrazole-3-carboxamide (known from CN103232431) (CAS1449220-44-3), 4-[5-(3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(cis-1-oxo-3- Thietanyl)-benzamide, 4-[5-(3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(trans-1-oxo-3-thietanyl)-benzamide and 4-[(5S)-5-(3,5-dichlorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-2-methyl-N-(cis-1-oxo-3-thietanyl)benzamide (by WO 2013 / 050317 A1) (CAS 1332628-83-7), N-[3-chloro-1-(3-pyridyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]-propionamide, (+)-N-[3-chloro-1-(3-pyridyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]-propionamide and (-)-N-[3-chloro-1-(3-pyridyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)sulfinyl]-propionamide (known from WO 2013 / 162715 A2, WO 2013 / 162716 A2, US 2014 / 0213448A1) (CAS 1477923-37-7), 5-[[(2E)-3-chloro-2-propen-1-yl]amino]-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-4-[(trifluoromethyl)sulfinyl]-1H-pyrazole-3-carbonitrile (known from CN 101337937 A) (CAS 1105672-77-2), 3-bromo-N-[4-chloro-2-methyl-6-[(methylamino)thiomethyl]phenyl]-1-(3-chloro-2-pyridyl)-1H-pyrazole-5-carboxamide, (Liudaibenjiaxuanan, known from CN 103109816 A) (CAS 1232543-85-9); N-[4-chloro-2-[[(1,1-dimethylethyl)amino]carbonyl]-6-methylphenyl]-1-(3-chloro-2-pyridyl)-3-(fluoromethoxy)-1H-pyrazole-5-carboxamide (from WO 2012 / 034403A1 known) (CAS 1268277-22-0), N-[2-(5-amino-1,3,4-thiadiazol-2-yl)-4-chloro-6-methylphenyl]-3-bromo-1-(3-chloro-2-pyridyl)-1H-pyrazole-5-carboxamide (known from WO 2011 / 085575 A1) (CAS 1233882-22-8), 4-[3-[2,6-dichloro-4-[(3,3-dichloro-2-propen-1-yl)oxy]phenoxy]propoxy]-2-methoxy-6-(trifluoromethyl)-pyrimidine (known from CN 101337940 A known) (CAS 1108184-52-6); (2E)-2-[2-(4-cyanophenyl)-1-[3-(trifluoromethyl)phenyl]ethylidene]-N-[4-(difluoromethoxy)phenyl]-hydrazinecarboxamide and 2(Z)-2-[2-(4-cyanophenyl)-1-[3-(trifluoromethyl)phenyl]ethylidene]-N-[4-(difluoromethoxy)phenyl]-hydrazinecarboxamide (known from CN 101715774A) (CAS 1232543-85-9); cyclopropanecarboxylic acid 3-(2,2-dichlorovinyl)-2,2-dimethyl-4-(1H-benzimidazol-2-yl)phenyl ester (known from CN 103524422 A known) (CAS 1542271-46-4); (4aS)-7-chloro-2,5-dihydro-2-[[(methoxycarbonyl)[4-[(trifluoromethyl)thio]phenyl]amino]carbonyl]-indeno[1,2-e][1,3,4]oxadiazine-4a(3H)-carboxylic acid methyl ester (known from CN 102391261 A) (CAS 1370358-69-2); 6-deoxy-3-O-ethyl-2,4-di-O-methyl-1-[N-[4-[1-[4-(1,1,2,2,2-pentafluoroethoxy)phenyl]-1H-1,2,4-triazol-3-yl]phenyl]carbamate]-α-L-pyranose (known from US 2014 / 0275503 A1) (CAS 1181213-14-8); 8-(2-cyclopropylmethoxy-4-trifluoromethyl-phenoxy)-3-(6-trifluoromethyl-pyridazin-3-yl)-3-aza-bicyclo[3.2.1]octane (CAS 1253850-56-4), (8-trans)-8-(2-cyclopropylmethoxy-4-trifluoromethyl-phenoxy)-3-(6-trifluoromethyl-pyridazin-3-yl)-3-aza-bicyclo[3.2.1]octane (CAS 933798-27-7), (8-cis)-8-(2-cyclopropylmethoxy-4-trifluoromethyl-phenoxy)-3-(6-trifluoromethyl-pyridazin-3-yl)-3-aza-bicyclo[3.2.1]octane (from WO 2007040280A1, WO 2007040282 A1 known)(CAS934001-66-8), N-[3-chloro-1-(3-pyridyl)-1H-pyrazol-4-yl]-N-ethyl-3-[(3,3,3-trifluoropropyl)thio]-propionamide (known from WO 2015 / 058021 A1, WO 2015 / 058028 A1) (CAS 1477919-27-9) and N-[4-(aminothiomethyl)-2-methyl-6-[(methylamino)carbonyl]phenyl]-3-bromo-1-(3-chloro-2-pyridyl)-1H-pyrazole-5-carboxamide (known from CN 103265527 A) (CAS 1452877-50-7), 5-(1,3-dioxan-2-yl)-4-[[4-(trifluoromethyl)phenyl]methoxy]-pyrimidine (known from WO 2013 / 115391 A1) (CAS1449021-97-9), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-1-methyl-1,8-diazaspiro[4.5]decane-2,4-dione (known from WO 2014 / 187846 A1) (CAS1638765-58-8), 3-(4-chloro-2,6-dimethylphenyl)-8-methoxy-1-methyl-2-oxo-1,8-diazaspiro[4.5]dec-3-en-4-yl carbonate (known from WO 2010 / 066780 A1, WO 2011151146 A1 is known) (CAS1229023-00-0), 4-[(5S)-5-(3,5-dichloro-4-fluorophenyl)-4,5-dihydro-5-(trifluoromethyl)-3-isoxazolyl]-N-[(4R)-2-ethyl-3-oxo-4-isoxazolidinyl]-2-methyl-benzamide (known from WO 2011 / 067272, WO2013 / 050302) (CAS1309959-62-3).

[0114] Examples of herbicides a) according to the invention are:

[0115] Acetochlor, acifluorfen, acifluorfen-sodium, aclonifen, alachlor, allidochlor, alloxydim, alloxydim-sodium, ametryn, amicarbazone, amidochlor, amidosulfuron, 4-amino-3-chloro-5-fluoro-6-(7-fluoro-1H-indol-6-yl)pyridine -2-carboxylic acid, aminocyclopyrachlor, aminocyclopyrachlor-potassium, aminocyclopyrachlor-methyl, aminopyralid, amitrole, ammoniumsulfamate, anilofos, asulam, atrazine, azafenidin, azimsulfuron, flubutyric acid beflubutamid), benazolin, benazolin-ethyl, benfluralin, benfuresate, bensulfuron, bensulfuron-methyl, bensulide, bentazone, benzobicyclon, benzofenap, bicyclopyron, bifenox, bialafos, bicyclopyron bilanafos-sodium, bispyribac, bispyribac-sodium, bixlozone, bromacil, bromobutide, bromofenoxim, bromoxynil, bromoxynil-butyrate, bromoxynil-potassium, bromoxynil-heptanoate, and bromoxynil-octanoate,busoxinone, butachlor, butafenacil, butamifos, butenachlor, butralin, butroxydim, butylate, cafenstrole, carbetamide, carfentrazone, carfentrazone-ethyl, chloramben, chlorbromuron, 1-{2- Chloro-3-[(3-cyclopropyl-5-hydroxy-1-methyl-1H-pyrazol-4-yl)carbonyl]-6-(trifluoromethyl)phenyl}piperidin-2-one, 4-{2-chloro-3-[(3,5-dimethyl-1H-pyrazol-1-yl)methyl]-4-(methylsulfonyl)benzoyl}-1,3-dimethyl-1H-pyrazol-5-yl-1,3-dimethyl-1H-pyrazole-4-carboxylate, chlorfenac, chlorfenac-sodium, chlorfenprop, chlorflurenol, chlorflurenol-methyl, chlorfenamine loridazon), chlorimuron, chlorimuron-ethyl, 2-[2-chloro-4-(methylsulfonyl)-3-(morpholin-4-ylmethyl)benzoyl]-3-hydroxycyclohex-2-ene-1-one, 4-{2-chloro-4-(methylsulfonyl)-3-[(2,2,2-trifluoroethoxy)methyl]benzoyl}-1-ethyl-1H-pyrazol-5-yl-1,3-dimethyl-1H-pyrazole-4-carboxylate, chlorophthalimide, chlorotoluron, chlorthal-dimethyl, 3-[5 -chloro-4-(trifluoromethyl)pyridin-2-yl]-4-hydroxy-1-methylimidazolidin-2-one, chlorsulfuron, cinidon, cinidon-ethyl, cinmethylin, cinosulfuron, clacyfos, clethodim, clodinafop, clodinafop-propargyl, clomazone, clomeprop, clopyralid,cloransulam, cloransulam-methyl, cumyluron, cyanamide, cyanazine, cycloate, cyclopyranil, cyclopyrimorate, cyclosulfamuron, cycloxydim, cyhalofop, cyhalofop-butyl, cyprazine, 2,4-D, 2,4-D-butyl 2,4-D-butotyl, 2,4-D-butyl, 2,4-D-dimethylammonium, 2,4-D-diolamin, 2,4-D-ethyl, 2,4-D-2-ethylhexyl, 2,4-D-isobutyl, 2,4-D-isooctyl, 2,4-D-isopropylammonium, 2,4-D-potassium, 2,4-D-triisopropanolammonium and 2,4-D-triethanolamine, 2,4-DB, 2,4-DB-butyl, 2,4- DB-dimethylammonium, 2,4-DB-isooctyl ester, 2,4-DB-potassium and 2,4-DB-sodium, daimuron (dymron), dalapon, dazomet, n-decanol, desmedipham, detosyl-pyrazolate (DTP), dicamba, dichlobenil, dichlorprop, dichlorprop-P, diclofop, diclofop-methyl, dichlorprop-P-methyl, dichlorprop-Methyl ... diclofop-P-methyl, diclosulam, difenzoquat, diflufenican, diflufenzopyr, diflufenzopyr-sodium, dimefuron, dimepiperate, dimethachlor, dimethametryn, dimethenamid, dimethenamid-P,3-(2,6-dimethylphenyl)-6-[(2-hydroxy-6-oxocyclohex-1-en-1-yl)carbonyl]-1-methylquinazoline-2,4(1H,3H)-dione, 1,3-dimethyl-4-[2-(methylsulfonyl)-4-(trifluoromethyl)benzoyl]-1H-pyrazol-5-yl-1,3-dimethyl-1H-pyrazole-4-carboxylate, dimetrasulfuron, dinitramine, dinoterb, diphenamid, diquat, diquat-dibromid, dithiopyr, diquat- diuron, DMPA, DNOC, endothal, EPTC, esprocarb, ethalfluralin, ethametsulfuron, ethametsulfuron-methyl, ethiozin, ethofumesate, ethoxyfen, ethoxyfen-ethyl, ethoxysulfuron, etobenzanid, [(3-{2-chloro-4 ethyl 2-fluoro-5-[3-methyl-2,6-dioxo-4-(trifluoromethyl)-3,6-dihydropyrimidin-1(2H)-yl]phenoxy}pyridin-2-yl)oxy]acetate, F-9960, F-5231 (i.e. N-[2-chloro-4-fluoro-5-[4-(3-fluoropropyl)-5-oxo-4,5-dihydro-1H-tetrazol-1-yl]phenyl]ethanesulfonamide), F-7967 (i.e. 3-[7-chloro-5-fluoro-2-(trifluoromethyl)-1H-benzimidazol-4-yl]-1-methyl-6-(trifluoromethyl)pyrimidine-2,4(1H,3H)-dione), fenoxaprop, fenoxaprop-P, fenoxaprop-ethyl, fenoxaprop-P-ethyl, fenoxasulfone, fenquinotrione, fentrazamide, flamprop, flamprop-M-isopropyl, flamprop-M-methyl, flazasulfuron, florasulam, fluazifop, fluazifop-P,fluazifop-butyl, fluazifop-P-butyl, flucarbazone, flucarbazone-sodium, flucetosulfuron, fluchloralin, flufenacet, flufenpyr, flufenpyr-ethyl, flumetsulam, flumiclorac, flumiclor ac-pentyl), flumioxazin, fluometuron, flurenol, flurenol-butyl, flurenol-dimethylammonium and flurenol-methyl, fluoroglycofen, fluoroglycofen-ethyl, flupropanate, flupyrsulfuron, flupyrsulfuron sodium on-methyl-sodium), fluridone, fluro-chloridone, fluroxypyr, fluroxypyr-meptyl, flurtamone, fluthiacet, fluthiacet-methyl, fomesafen, fomesafen-sodium, foramsulfuron, fosamine, glufosinate glyphosate, glufosinate-ammonium, glufosinate-P-sodium, glyphosate, glyphosate-ammonium, glyphosate-isopropylammonium, glyphosate-diammonium, glyphosate-dimethylammonium, glyphosate-potassium, glyphosate-sodium, glyphosate-trimesium, H-9201 (i.e. O-(2,4-dimethyl-6-nitrophenyl)-O-ethylisopropylthiophosphoramidate), halauxifen, halauxifen-methyl, halosafen, halosulfuron,Halosulfuron-methyl, haloxyfop, haloxyfop-P, haloxyfop-ethoxyethyl, haloxyfop-ethoxyethyl, haloxyfop-methyl, haloxyfop-P-methyl, hexazinone, HW-02 (i.e., 1-(dimethoxyphosphoryl)ethyl (2,4-dichlorophenoxy)acetate), 4-hydroxy-1-methoxy-5-methyl-3-[4-(trifluoromethyl)pyridin-2-yl]imidazolidin-2-one, 4-hydroxy-1-methyl-3-[4-(trifluoromethyl)pyridin-2-yl]imidazolidin-2-one imidazolidin-2-one, (5-hydroxy-1-methyl-1H-pyrazol-4-yl)(3,3,4-trimethyl-1,1-dioxo-2,3-dihydro-1-benzothiophene-5-yl)methanone, 6-[(2-hydroxy-6-oxocyclohex-1-en-1-yl)carbonyl]-1,5-dimethyl-3-(2-methylphenyl)quinazoline-2,4(1H,3H)-dione, imazamethabenz, imazamethabenz-methyl, imazamox, imazapic, imazapyr, imidazolin Isopropylammonium nicotinate, imazaquin, imazethapyr, imazethapyr-ammonium, imazosulfuron, indanofan, indaziflam, iodosulfuron, iodosulfuron-methyl-sodium, ioxynil, ioxynil-octanoate, ioxynil potassium and sodium, ipfencarb azone), isoproturon, isouron, isoxaben, isoxaflutole, karbutilate, KUH-043 (i.e. 3-({[5-(difluoromethyl)-1-methyl-3-(trifluoromethyl)-1H-pyrazol-4-yl]methyl}sulfonyl)-5,5-dimethyl-4,5-dihydro-1,2-oxazole), keto-spiradox, lactofen, lenacil, linuron, MCPA, MCPA-butoxyethyl ester, MCPA-dimethylammonium,MCPA-2-ethylhexyl ester, MCPA-isopropylammonium, MCPA-potassium and MCPA-sodium, MCPB, MCPB-methyl ester, MCPB-ethyl ester and MCPB-sodium, 2-methyl-4-chloropropionic acid (mecoprop), 2-methyl-4-chloropropionic acid sodium and 2-methyl-4-chloropropionic acid butoxyethyl ester, 2-methyl-4-chloropropionic acid (mecoprop-P), 2-methyl-4-chloropropionic acid butoxyethyl ester, 2-methyl-4-chloropropionic acid dimethylammonium, 2-methyl-4-chloropropionic acid-2-ethylhexyl ester and 2-methyl-4-chloropropionic acid potassium, mefenacet, mefluidide, mesosulfuron, mesosulfuron on-methyl), mesotrione, methabenzthiazuron, metam, metamifop, metamitron, metazachlor, metazosulfuron, methabenzthiazuron, methiopyrsulfuron, methiozolin, 2-({2-[(2-methoxyethoxy)methyl]-6-(trifluoromethyl)pyridin-3-yl}carbonyl)cyclohexane-1,3-dione, methyl isothiocyanate isothiocyanate), 1-methyl-4-[(3,3,4-trimethyl-1,1-dioxo-2,3-dihydro-1-benzothiophen-5-yl)carbonyl]-1H-pyrazol-5-ylpropane-1-sulfonate, metobromuron, metolachlor, S-metolachlor, metosulam, metoxuron, metribuzin, metsulfuron, metsulfuron- methyl), molinat, monolinuron, monosulfuron, monosulfuron-ester, MT-5950 (i.e. N-[3-chloro-4-(1-methylethyl)-phenyl]-2-methylpentanamide), NGGC-011, napropamide, NC-310 (i.e. benzyloxy)-1-methyl-1H-pyrazol-4-yl](2,4-dichlorophenyl)-methanone), neburon, nicosulfuron,nonanoic acid (pelargonic acid), norflurazon, oleic acid (fatty acid), orbencarb, orthosulfamuron, oryzalin, oxadiargyl, oxadiazon, oxasulfuron, oxaziclomefon, oxyfluorfen, paraquat, paraquatdichloride, pebulate, pendimethalin, penoxsulam, pentachlorphenol, pentoxazone, pethoxamid, mineral oil (petroleum oils), phenmedipham, picloram, picolinafen, pinoxaden, piperophos, pretilachlor, primisulfuron, primisulfuron-methyl, prodiamine, profoxydim, prometon, prometryn, propachlor, propanil, propaquizafop, propazine, propham, propisochlor 、propoxy-carbazone、propoxycarbazone-sodium、propyrisulfuron、propyzamide、prosulfocarb、prosulfuron、pyraclonil、pyraflufen、pyraflufen-ethyl、pyrasulfotole、pyrazolynate(pyrazolate)、pyrazosulfuron、pyrazosulfuron-ethyl、pyrazoxyfen、pyribambenz、Pyribambenz-isopropyl, pyribambenz-propyl, pyribenzoxim, pyributicarb, pyridafol, pyridate, pyriftalid, pyriminobac, pyriminobac-methyl, pyrimi-sulfan, pyrithiobac, pyrithiobac-sodium, pyroxazone sulfone), pyroxsulam, quinclorac, quinmerac, quino-clamine, quizalofop, quizalofop-ethyl, quizalofop-P, quizalofop-P-ethyl, quizalofop-P-tefuryl, QYM-201, QYR-301, rimsulfuron, saflufenacil , sethoxydim, siduron, simazine, simetryn, SL-261, sulcotrion, sulfentrazone, sulfometuron, sulfometuron-methyl, sulfosulfuron, SYN-523, SYP-249 (i.e., 1-ethoxy-3-methyl-1-oxobut-3-en-2-yl 5-[2-chloro-4-(trifluoromethyl)phenoxy]-2-nitrobenzoate), SYP-300 (i.e., 1- [7-fluoro-3-oxo-4-(prop-2-yn-1-yl)-3,4-dihydro-2H-1,4-benzoxazin-6-yl]-3-propyl-2-thioxoimidazolidine-4,5-dione), 2,3,6-TBA, TCA, TCA-sodium, tebuthiuron, tefuryltrione, tembotrione, tepraloxydim, terbacil, terbucarb, terbumeton, terbuthylazine,Terbutryn, tetflupyrolimet, thenylchlor, thiazopyr, thiencarbazone, thiencarbazone-methyl, thifensulfuron, thifensulfuron-methyl, thiobencarb, tiafenacil, tolpyralate, topramezone, tralkoxydim, triafamone, tri-allate, triasulfuron, tri- triaziflam, tribenuron, tribenuron-methyl, triclopyr, trietazine, trifloxysulfuron, triflusulfuron-methyl, tritosulfuron, urea sulfate, vernolate, ZJ-0862 (i.e. 3,4-dichloro-N-{2-[(4,6-dimethoxypyrimidin-2-yl)oxy]benzyl}aniline), (2R*,4R*)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2-carboxylic acid methyl ester.

[0116] Preferably, at least one active ingredient a) is selected from the group consisting of fungicides selected from the classes as described above (1) inhibitors of respiratory chain complexes, in particular azoles, (2) inhibitors of respiratory chain complexes I or II, (3) inhibitors of respiratory chain complexes, (4) inhibitors of mitosis and cell division, (6) compounds capable of eliciting host defenses, (10) inhibitors of lipid and membrane synthesis, and (15).

[0117] Further preferably, the at least one active ingredient a) being a fungicide is selected from the group consisting of Trifloxystrobin, Bixafen, Prothioconazole, Inpyrfluxam, Isoflucypram and Fluoxapiprolin.

[0118] Preferably, the at least one insecticide is selected from the class of insecticides as described above (2) GABA-gated chloride channel antagonists, (3) sodium channel modulators / voltage-dependent sodium channel blockers, (4) nicotinic acetylcholine receptor (nAChR) competitive modulators, (23) acetyl-CoA carboxylase inhibitors, (28) ryanodine receptor modulators, (30) other active ingredients.

[0119] Still further preferably, the at least one active ingredient a) as insecticide is selected from spirotetramat, deltamethrine and ethiprole.

[0120] Finally, it is further preferred that the at least one active ingredient a) as herbicide is selected from fluazifop, tembotrione and ethofumesat, preferably in combination with a safener.

[0121] Even more preferably, the at least one active ingredient is selected from trifloxystrobin, bixafen, prothioconazole, inpyrfluxam, isoflucypram, fluoxapiprolin, spirotetramat, ethiprole, deltamethrin, flutosulfuron, tembotrione and ethoxyfuroxan.

[0122] All active ingredients specified above can be present in the form of free compounds or, if their functional groups permit, in the form of their agrochemically active salts.

[0123] Furthermore, where applicable, the racemic forms as well as stereoisomers or enantiomers are included, since these modifications as well as polymorphic modifications are well known to those skilled in the art.

[0124] If not stated otherwise, solid agrochemically active compounds a) are understood in the context of the present invention to mean all substances customarily used for plant treatment whose melting point is above 20° C.

[0125] Polymer-based drift reduction additives b)

[0126] Suitable drift reduction polymers are poly(ethylene oxide), wherein the average molecular weight of the polymer is preferably 0.5 to 14 million g / mol, more preferably 0.75 to 10 million g / mol, most preferably 1 to 8 million g / mol, and hydroxypropyl guar (HP guar).

[0127] In one embodiment, the polymer-based drift reduction additive is poly(ethylene oxide) (PEO), wherein even further preferably the formulation exhibits a PEO polymer concentration factor (PCF) value of 0.5 to 12, more preferably 1 to 10, even more preferably 2 to 9.

[0128] The polymer concentration factor (PCF) for the PEO polymer content in the formulation is defined as: where C is the concentration of the drift reducing polymer (b) in the formulation (g / l), M is the molar mass of the drift reducing polymer (b) (g / mol / 1x10 6 ), a is 1.4, and D is the dosage rate of the formulation per hectare (l / ha). The PCF value is calculated according to the following equation:

[0129] PCF=C×M a ×D

[0130] In another embodiment, the polymer-based drift reduction additive is HP guar gum.

[0131] Oil-based drift reduction additives c)

[0132] Suitable drift reduction oils are vegetable oils and vegetable oil esters and diesters (including esters with glycerol and propylene glycol).

[0133] Particularly preferred are the methyl, ethyl, isopropyl, isobutyl, butyl, hexyl and ethylhexyl esters.

[0134] More preferably, the vegetable oils and esters are selected from methyl oleate, methyl palmitate, rapeseed oil methyl ester, isopropyl myristate, isopropyl palmitate, ethylhexyl palmitate, ethylhexyl oleate, a mixture of ethylhexyl myristate / ethylhexyl laurate, ethylhexyl laurate, a mixture of ethylhexyl caprylate / ethylhexyl caprate, diisopropyl adipate, cocopropylene glycol diester, sunflower oil, rapeseed oil, corn oil, soybean oil, rice bran oil, olive oil, peanut oil, mixed caprylic and capric triglycerides, and mixed decanoyl and octanoyl glycerides.

[0135] Particular preference is given to rapeseed oil, rapeseed oil methyl ester, corn oil, ethylhexyl palmitate, isopropyl palmitate or sunflower oil.

[0136] Mineral oil is also suitable as a drift reducer.

[0137] Spreading agents and absorption-promoting additives d):

[0138] Some compounds which are suitable as spreading agents may also act as absorption-promoting additives due to their chemical properties and vice versa. These compounds are therefore summarized under compounds d).

[0139] Spreading agents are compounds which are capable of enhancing the spreading of a tank-mix additive or an agrochemical formulation containing a tank-mix additive on plant parts, in particular on leaves.

[0140] Suitable spreading agents are selected from the monoesters and diesters of metal salts of sulfosuccinic acid with branched or linear alcohols containing 1 to 10 carbon atoms, in particular alkali metal salts, more in particular sodium salts, most in particular sodium dioctyl sulfosuccinate;

[0141] and organosilicon alkoxylates, such as organomodified polysiloxane / trisiloxane alkoxylates, preferably polyalkylene oxide-modified heptamethyltrisiloxane, wherein the alkylene oxide is preferably selected from ethylene oxide (EO) or propylene oxide (PO), in particular those with the following CAS numbers: 27306-78-1 (poly(oxy-1,2-ethanediyl), α-methyl-ω-[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl) )oxy]disiloxanyl]propyl]), 67674-67-3 (poly(oxy-1,2-ethanediyl), α-[3-[1,3,3,3-tetramethyl-1-[(trimethylsilyl)oxy]disiloxanyl]propyl]-ω-hydroxy), 134180-76-0 (polymer of methyl oxirane and oxirane mono-3-1,3,3,3-tetramethyl-1-(trimethylsilyl)oxydisiloxanylpropyl ether), for example L77, 408, 806, S240, S278.

[0142] Other suitable spreading agents are ethoxylated diacetylenediols having 1 to 6 ethylene oxide (EO) units, for example 420 and 440;

[0143] and alcohol alkoxylates, preferably selected from ethoxylated alcohols or propoxy-ethoxylated alcohols, more preferably containing 6 to 22 carbon atoms and an average of 5 to 40 ethylene oxide (EO) and / or propylene oxide (PO) units, in particular EP 0244, EP 2584 or W06, or ethoxylated propoxylated 3,5,5-trimethyl-1-hexanol (CAS No. 204336-40-3), e.g. Vibrant;

[0144] and other alkyl polysaccharides, such as BASF's PG8107, PG8105; Croda 438, AL-2559, AL-2575.

[0145] In the present context, the term "alcohol" refers to branched or straight-chain, saturated or unsaturated alcohols which may have 6 to 22 carbon atoms and optionally carry additional substituents, such as OH groups.

[0146] Preferably, the spreading agent is selected from the group consisting of monoesters and diesters of metal salts of sulfosuccinates with branched or linear alcohols containing 1 to 10 carbon atoms, organomodified polysiloxane / trisiloxane alkoxylates, ethoxylated diacetylenediol having 1 to 6 ethylene oxide (EO) units, alcohol alkoxylates containing 6 to 22 carbon atoms or alkyl polysaccharides;

[0147] More preferably selected from sodium dioctyl sulfosuccinate, polyalkylene oxide-modified heptamethyl trisiloxane, ethoxylated diacetylene glycols having 1 to 6 EO units or ethoxylated alcohols or propoxy-ethoxylated alcohols having 6 to 22 carbon atoms and an average of 5 to 40 ethylene oxide (EO) and / or propylene oxide (PO) units;

[0148] And in particular chosen from sodium dioctyl sulfosuccinate, polyalkylene oxide-modified heptamethyltrisiloxane and ethoxylated diacetylene glycols having 1 to 6 ethylene oxide units.

[0149] In another preferred embodiment of the present invention, the spreading agent c) is selected from polyalkylene oxide-modified heptamethyl trisiloxane, dioctyl sulfosuccinate, alcohol ethoxylates and ethoxylated diacetylene glycols having 1 to 6 EOs, more preferably selected from polyalkylene oxide-modified heptamethyl trisiloxane, dioctyl sulfosuccinate and ethoxylated diacetylene glycols having 1 to 6 EOs.

[0150] Absorption-enhancing additives are compounds which are able to enhance the absorption of tank-mix additives or agricultural chemical formulations containing tank-mix additives in plants or plant parts, in particular in the leaves.

[0151] Other suitable absorption-promoting additives are alcohol alkoxylates, preferably selected from ethoxylated alcohols, propoxy-ethoxylated alcohols, more preferably containing 6 to 22 carbon atoms and an average of 5 to 40 ethylene oxide (EO) and / or propylene oxide (PO) units;

[0152] Ethoxylated carboxylic acids or propoxy-ethoxylated carboxylic acids, preferably containing 6 to 22 carbon atoms and an average of 5 to 40 ethylene oxide (EO) and / or propylene oxide (PO) units;

[0153] Or ethoxylated monoesters, diesters or triesters of glycerol containing fatty acids having 8 to 18 carbon atoms and an average of 5 to 60, preferably 5 to 40, EO units.

[0154] The ethoxylated or propoxy-ethoxylated alcohols or carboxylic acids are optionally further modified by the addition of methyl groups to the remaining alcohol functions (see "methyl-terminated").

[0155] Other suitable absorption-enhancing additives are selected from alkoxylated sorbitan fatty acid esters comprising fatty acids having 8 to 18 carbon atoms and an average of 10 to 50 ethylene oxide and propylene oxide units;

[0156] or ethoxylated coconut alcohol comprising 2 to 20 EO units;

[0157] Or castor oil ethoxylates containing on average 5 to 40 EO units.

[0158] In the present context, the term "alcohol" refers to branched or linear, saturated or unsaturated alcohols which may have 6 to 22 carbon atoms and may optionally carry additional substituents, such as OH groups. In the present context, the term "carboxylic acid" refers to branched or linear, saturated or unsaturated carboxylic acids which may have 6 to 22 carbon atoms and may optionally carry additional substituents, such as OH groups.

[0159] Preferably, the absorption-promoting additive according to d) is selected from: alcohol alkoxylates containing 6 to 22 carbon atoms; ethoxylated carboxylic acids or propoxy-ethoxylated carboxylic acids containing 6 to 22 carbon atoms; ethoxylated mono-, di- or triesters of glycerol containing fatty acids having 8 to 18 carbon atoms and an average of 5 to 60 EO units; alkoxylated sorbitan fatty acid esters containing fatty acids having 8 to 18 carbon atoms and an average of 10 to 50 ethylene oxide and propylene oxide units; ethoxylated coconut alcohol containing 2 to 20 EO units; or castor oil ethoxylates containing an average of 5 to 40 EO units;

[0160] More preferably selected from: ethoxylated alcohols or propoxy-ethoxylated alcohols containing 6-22 carbon atoms and an average of 5-40 ethylene oxide (EO) and / or propylene oxide (PO) units; ethoxylated carboxylic acids or propoxy-ethoxylated carboxylic acids containing 6-22 carbon atoms and an average of 5-40 ethylene oxide (EO) and / or propylene oxide (PO) units; ethoxylated monoesters, diesters or triesters of glycerol containing fatty acids having 8-18 carbon atoms and an average of 5-60 EO units; or alkoxylated sorbitan fatty acid esters containing fatty acids having 8-18 carbon atoms and an average of 10-50 ethylene oxide and propylene oxide units; ethoxylated coconut alcohol containing 2-20 EO units; or castor oil ethoxylates containing an average of 5-40 EO units;

[0161] and in particular are chosen from: ethoxylated alcohols or propoxy-ethoxylated alcohols containing 6 to 22 carbon atoms and an average of 5 to 40 ethylene oxide (EO) and / or propylene oxide (PO) units; ethoxylated carboxylic acids or propoxy-ethoxylated carboxylic acids containing 6 to 22 carbon atoms and an average of 5 to 40 ethylene oxide (EO) and / or propylene oxide (PO) units; ethoxylated monoesters, diesters or triesters of glycerol containing fatty acids having 8 to 18 carbon atoms and an average of 5 to 60 ethylene oxide units; alkoxylated sorbitan fatty acid esters containing fatty acids having 8 to 18 carbon atoms and an average of 10 to 50 ethylene oxide and propylene oxide units.

[0162] In another preferred embodiment of the present invention, the absorption promoter c) is selected from the group consisting of ethoxylated alcohols, propoxy-ethoxylated alcohols, ethoxylated carboxylic acids, propoxy-ethoxylated carboxylic acids or ethoxylated glycerol monoesters, diesters or triesters containing fatty acids having 8 to 18 carbon atoms and an average of 5 to 40 EO units, alkoxylated sorbitan fatty acid esters containing fatty acids having 8 to 18 carbon atoms and an average of 10 to 50 EO and PO units.

[0163] Suitable components d) are, for example:

[0164] - ethoxylated linear and / or branched fatty alcohols having 2 to 20 EO units (e.g. X-type);

[0165] - methyl-terminated ethoxylated linear and / or branched fatty alcohols containing 2 to 20 EO units (e.g. XM type);

[0166] - ethoxylated coconut alcohol containing 2 to 20 EO units (e.g. Clariant's Type C);

[0168] - ethoxylated C12 / 15 alcohols containing 2 to 20 EO units (e.g. Croda's Type A);

[0170] - branched or linear propoxy-ethoxylated alcohols, for example Solvay's B / 848, Croda G5000, Levaco HOT 5902;

[0171] - Methyl terminated propoxy-ethoxylated fatty acids, such as Lion's OC0503M;

[0172] - Alkyl ether citrate surfactants (e.g. Adsee CE series, Akzo Nobel);

[0173] -Alkyl polysaccharides (e.g. BASF's PG8107, PG8105; Croda 438, AL-2559, AL-2575);

[0175] - ethoxylated monoesters or diesters of glycerol containing fatty acids having 8 to 18 carbon atoms and an average of 10 to 60, preferably 10 to 40, EO units (e.g. Croda's product line);

[0177] - castor oil ethoxylates containing an average of 5 to 40 EO units (e.g. castor oil ethoxylates from Nouryon Series, Clariant EL series);

[0179] - ethoxylated oleic acid containing 2 to 20 EO units (e.g. A and AP);

[0180] - alkoxylated sorbitan fatty acid esters comprising fatty acids having 8 to 18 carbon atoms and an average of 10 to 50 EO and / or PO units (e.g. T, Tween series).

[0181] Other additives e):

[0182] In the context of the present invention, further auxiliaries e) are further additives customary in agrochemical preparations which are not yet covered by components a) to d).

[0183] Preferably, the other auxiliary agents are one or more substances selected from the following: rainproof additives, surfactants, rheology modifiers, defoaming substances, antifreeze agents, preservatives, biocides, colorants, pH regulators, buffers, stabilizers, antioxidants, inert filler materials, wetting agents, crystal growth inhibitors or trace nutrients.

[0184] More preferably, the further auxiliaries e) comprise at least one nonionic and / or ionic surfactant, one rheology modifier, one antifoaming substance and at least one antifreeze agent.

[0185] e1) Rain-resistant additives:

[0186] Suitable rainproof additives are acrylic-based emulsion polymers or polymer dispersions and styrene-based emulsion polymers or polymer dispersions, d) aqueous polymer dispersions, whose Tg is -100°C to 30°C, preferably -60°C to 20°C, more preferably -50°C to 10°C, most preferably -45°C to 5°C, such as Acronal V215, Acronal 3612, Licomer ADH 205 and Atplus FA. Licomer ADH205 and Atplus FA are particularly preferred.

[0187] Preferably, the polymer is selected from acrylic polymers, styrene polymers, vinyl polymers and derivatives thereof, polyolefins, polyurethanes and natural polymers and derivatives thereof.

[0188] More preferably, the polymer is selected from acrylic polymers, styrene butadiene copolymers, styrene-maleic anhydride copolymers, polyvinyl alcohol, polyvinyl acetate, partially hydrolyzed polyvinyl acetate, methyl vinyl ether-maleic anhydride copolymers, carboxyl-modified polyvinyl alcohol, acetoacetyl-modified polyvinyl alcohol, diacetone-modified polyvinyl alcohol and silicon-modified polyvinyl alcohol, isopropylene-maleic anhydride copolymers, polyurethanes, cellulose, gelatin, casein, oxidized starch, starch-vinyl acetate graft copolymers, hydroxyethyl cellulose, methyl cellulose, ethyl cellulose, carboxymethyl cellulose and acetyl cellulose.

[0189] Most preferably, the polymer is selected from a copolymer of acrylate and styrene, wherein the acrylate is selected from 2-ethyl-hexyl acrylate, butyl acrylate, sec-butyl acrylate, ethyl acrylate, methyl acrylate, acrylic acid, acrylamide, isobutyl acrylate, methyl methacrylate or a combination thereof. The styrene is selected from styrene, tert-butyl styrene, p-methyl styrene or a combination thereof.

[0190] In a preferred embodiment, the molecular weight of the polymer as described above does not exceed 40,000 g / mol, preferably does not exceed 10,000 g / mol.

[0191] In a preferred embodiment, polymer D is an emulsion polymer as described in WO 2017 / 202684.

[0192] The glass transition temperature (Tg) of many polymers is known and, if not otherwise defined, is determined in the present invention according to ASTM E1356-08 (2014) "Standard Test Method for Assignment of the Glass Transition Temperatures by Differential Scanning Calorimetry", wherein the sample is dried at 110°C for one hour before DSC to eliminate the influence of water and / or solvent, the DSC sample size is 10-15 mg, and the measurement is performed from -100°C to 100°C at 20°C / min under N2, wherein Tg is defined as the midpoint of the transition zone.

[0193] e2) Surfactant:

[0194] Suitable nonionic surfactants or dispersing aids e1) are all such substances which can usually be used in agricultural chemicals. Preference is given to polyethylene oxide-polypropylene oxide block copolymers (preferably with a molecular weight of more than 5000 g / mol or a polyethylene oxide content of more than 35%, more preferably with a molecular weight of more than 6000 g / mol and a polyethylene oxide content of more than 45%), polyoxyalkyleneamine derivatives, polyvinylpyrrolidone, copolymers of polyvinyl alcohol and polyvinylpyrrolidone, and copolymers of (meth)acrylic acid and (meth)acrylic acid esters. In the examples mentioned above, the selected species can optionally be phosphorylated, sulfonated or sulfated and neutralized with a base.

[0195] Possible anionic surfactants are all such substances which are usually used in agricultural chemicals. Alkali metal salts, alkaline earth metal salts and ammonium salts of alkylsulfonic acids or alkylphosphonic acids and alkylarylsulfonic acids or alkylarylphosphonic acids are preferred. Another group of preferred anionic surfactants or dispersing aids are alkali metal salts, alkaline earth metal salts and ammonium salts of polystyrenesulfonic acid, salts of polyethylenesulfonic acid, salts of alkylnaphthalenesulfonic acids, salts of naphthalene-sulfonic acid-formaldehyde condensation products, salts of naphthalenesulfonic acid, phenolsulfonic acid and formaldehyde condensation products, and salts of ligninsulfonic acid.

[0196] e3) Rheology modifier:

[0197] A rheology modifier is an additive that, when added to a formulation at a concentration that reduces gravity separation of the dispersed active ingredient during storage, results in a significant increase in viscosity at low shear rates. For the purposes of this invention, low shear rates are defined as 0.1 s -1 and below, and increases significantly for values ​​greater than x2. Viscosity can be measured by a rotational shear rheometer.

[0198] Suitable rheology modifiers e3) are, for example:

[0199] - Polysaccharides including xanthan gum and hydroxyethylcellulose. Examples are G and 23, CX911 and 250 Series.

[0201] - Clays, including montmorillonite, bentonite, sepiolite, attapulgite, laponite, hectorite. Examples are R. Van B. 34, 38, CT, HC, EW, M100, M200, M300, S, M, W, 50. RD,

[0203] - fumed silica and precipitated silica, examples being 200, twenty two.

[0205] -Microcrystalline cellulose.

[0206] Xanthan gum, montmorillonite clay, bentonite and fumed silica are preferred.

[0207] e4) Defoaming substances:

[0208] Suitable antifoam substances e4) are all substances which can usually be used for this purpose in agrochemicals. Preference is given to silicone oils and silicone oil preparations. Examples are the following: 426 and 432, from Wacker SRE and SC132 from Silchem Foam-Clear by Basildon Chemical Company Ltd From Momentive 1572 and 30 [Dimethylsiloxane and silicone, CAS No. 63148-62-9]. 1572.

[0209] e5) Antifreeze:

[0210] Suitable antifreeze agents are all substances which can usually be employed for this purpose in agrochemicals. Suitable examples are propylene glycol, ethylene glycol, urea and glycerol.

[0211] e6) Other additives:

[0212] Further suitable auxiliaries e6) are selected from preservatives, biocides, colorants, pH regulators, buffers, stabilizers, antioxidants, inert filler materials, wetting agents, crystal growth inhibitors, micronutrients.

[0213] For example, the other auxiliary agents are:

[0214] Possible preservatives are all substances which can usually be used for this purpose in agricultural chemicals. Suitable examples of preservatives are preparations containing 5-chloro-2-methyl-4-isothiazolin-3-one [CAS No. 26172-55-4], 2-methyl-4-isothiazolin-3-one [CAS No. 2682-20-4] or 1,2-benzisothiazol-3-(2H)-one [CAS No. 2634-33-5]. Examples which may be mentioned are D7 (Lanxess), CG / ICP(Dow), SPX (Thor GmbH) and GXL (Arch Chemicals).

[0215] Possible colorants are all substances which can usually be used for this purpose in agrochemicals. For example, mention may be made of titanium dioxide, carbon black, zinc oxide, blue pigments, brilliant blue FCF, red pigments and permanent red FGR.

[0216] Possible pH regulators and buffers are all substances which can usually be used for this purpose in agrochemicals. For example, citric acid, sulfuric acid, hydrochloric acid, sodium hydroxide, sodium hydrogen phosphate (Na2HPO4), sodium dihydrogen phosphate (NaH2PO4), potassium dihydrogen phosphate (KH2PO4), potassium hydrogen phosphate (K2HPO4) may be mentioned.

[0217] Suitable stabilizers and antioxidants are all substances which can usually be employed for this purpose in agrochemicals. Preference is given to butylhydroxytoluene [3,5-di-tert-butyl-4-hydroxytoluene, CAS No. 128-37-0].

[0218] Carriers f) are those carriers which can usually be used for this purpose in agrochemical formulations.

[0219] CarrierIt is a solid or liquid, natural or synthetic, organic or inorganic substance that is generally inert and can be used as a solvent. The carrier can generally improve the application of the compound to, for example, plants, plant parts or seeds. Examples of suitable solid carriers include, but are not limited to, ammonium salts, particularly ammonium sulfate, ammonium phosphate and ammonium nitrate, natural rock powders (e.g., kaolin, clay, talc, chalk, quartz, attapulgite, montmorillonite and diatomaceous earth), silica gel and synthetic rock powders (e.g., finely divided silicon dioxide, aluminum oxide and silicates). Examples of useful solid carriers commonly used to prepare granules include, but are not limited to, pulverized and graded natural rocks (e.g., calcite, marble, pumice, sepiolite and dolomite), synthetic particles of inorganic and organic powders and particles of organic materials (e.g., paper, sawdust, coconut shells, corn cobs and tobacco stalks).

[0220] Preferred solid carriers are selected from clay, talc and silica.

[0221] Examples of suitable liquid carriers include, but are not limited to, water, organic solvents, and combinations thereof. Examples of suitable solvents include polar and non-polar organic chemical liquids, such as from the following categories:

[0222] - alcohols and polyols (which may also optionally be substituted, etherified and / or esterified, for example ethanol, propanol, butanol, benzyl alcohol, cyclohexanol or ethylene glycol, 2-ethylhexanol),

[0223] - ethers, such as dioctyl ether, tetrahydrofuran, isosorbide dimethyl ether, solketal, cyclopentyl methyl ether, solvents of the Dowanol product series provided by Dow (such as Dowanol DPM), anisole, phenethyl ether, dimethyl polyethylene glycol of different molecular weight grades (less than 1000 g / mol), dimethyl polypropylene glycol of different molecular weight grades (less than 1000 g / mol), dibenzyl ether,

[0224] - ketones (e.g. acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclopentanone, cyclohexanone, cycloheptanone, acetophenone, propiophenone),

[0225] - lactic acid esters, such as methyl lactate, ethyl lactate, propyl lactate, butyl lactate, 2-ethylhexyl lactate,

[0226] - unsubstituted and substituted amines,

[0227] - amides (for example dimethylformamide, or N,N-dimethyllactamide, or N-formylmorpholine, or fatty acid amides, such as N,N-dimethyldecylamide or N,N-dimethyldec-9-enamide) and esters thereof,

[0228] - lactams (e.g. 2-pyrrolidone, or N-alkylpyrrolidone, for example N-methylpyrrolidone, or N-butylpyrrolidone, or N-octylpyrrolidone, or N-dodecylpyrrolidone, or N-methylcaprolactam, N-alkylcaprolactam),

[0229] - lactones (for example γ-butyrolactone, γ-valerolactone, δ-valerolactone, or α-methyl γ-butyrolactone),

[0230] - sulfones and sulfoxides (for example dimethyl sulfoxide),

[0231] - Nitriles, for example linear or cyclic alkylnitriles, in particular acetonitrile, cyclohexanecarbonitrile, octanonitrile, dodecanonitrile.

[0232] - linear and cyclic carbonates, for example diethyl carbonate, dipropyl carbonate, dibutyl carbonate, dioctyl carbonate, or ethylene carbonate, propylene carbonate, butylene carbonate, carbonate esters.

[0233] The most preferred carrier is water.

[0234] With the aid of the formulations according to the invention, active agrochemicals can be delivered to plants and / or their habitat in a particularly advantageous manner.

[0235] The invention further relates to the use of the agrochemical preparations according to the invention for applying the agrochemically active compounds contained therein to plants and / or their habitat.

[0236] All plants and plant parts can be processed using the formulation of the present invention. Plants herein mean all plants and plant populations, such as desired and unwanted wild plants or crop plants (including naturally occurring crop plants). Crop plants can be plants that can be obtained by conventional breeding and optimization methods or by biotechnology and gene technology methods or a combination of these methods, including transgenic plants, and including plant cultivars that can or cannot be protected by variety property rights. Plant parts mean all parts and organs above and below the ground of plants, such as buds, leaves, flowers and roots, and exemplary lists include leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds, as well as roots, tubers and rhizomes. Plant parts also include harvested materials and asexual and sexual propagation materials.

[0237] The application rate of the formulations according to the invention or of the spray liquors containing them can be varied within relatively wide ranges. It is guided by the particular active agrochemical and its amount in the formulation or spray liquor.

[0238] The formulations according to the invention or spray solutions containing them are applied by conventional methods, i.e., for example by spraying, pouring or injection, in particular by spraying, and most particularly by spraying via an unmanned aerial vehicle UAV or an unmanned guided vehicle UGV or a nozzle device using pulse width modulation PWM.

[0239] Another aspect of the present invention is the use of the formulation of the present invention in applying agricultural chemical compounds to control pests, wherein the formulation or a spray liquid containing the formulation is applied by an unmanned aerial vehicle UAV or an unmanned guided vehicle UGV or a nozzle device using pulse width modulation PWM.

[0240] Attached photos:

[0241] Figure 1 The % of spray droplet size < 100 microns for the formulation of Example FN1 at different spray rates is shown.

[0242] Figure 2 The % of spray droplet size < 100 microns for the formulation of Example FN2 at different spray rates is shown.

[0243] Figure 3 The % of spray droplet size < 100 microns for the formulation of Example FN3 at different spray rates is shown.

[0244] Figure 4 The % of spray droplet size < 100 microns for the formulation of Example FN4 at various spray rates is shown.

[0245] Figure 5 The % of spray droplet size < 100 microns for the formulation of Example FN5 at various spray rates is shown.

[0246] Figure 6 The % of spray droplet size < 100 microns for the formulation of Example FN6 at different spray rates is shown.

[0247] Figure 7 The % of spray droplet size < 100 microns for Example Polymer 1 is shown for different PEO polymer molar masses and concentrations.

[0248] Figure 8 The % of spray droplet size < 100 microns for Example Polymer 2 is shown for different PEO polymer molar masses and PCF values.

[0249] Fig. 9 The % of spray droplet size < 100 microns for the formulation of Example IN1 at different spray rates is shown.

[0250] Fig.10 The % of spray droplet size < 100 microns for the formulation of Example HB1 at different spray rates is shown.

[0251] Fig.11 The % of spray droplet size < 100 microns for the formulation of Example HB2 at various spray rates is shown.

[0252] Fig.12 The % of spray droplet size < 100 microns for the formulation of Example HB3 at various spray rates is shown.

[0253] Fig.13 The % of spray droplet size < 100 microns for the formulation of Example HB4 at various spray rates is shown.

[0254] Fig.14 The % of spray droplet size < 100 microns for the formulation of Example HB5 at various spray rates is shown.

[0255] Materials

[0256] Material

[0257] Table MAT1: Exemplary trade names and CAS numbers of preferred drift reduction materials - polymers b)

[0258]

[0259]

[0260] Table MAT2: Exemplary Trade Names and CAS Numbers of Preferred Drift Reduction Materials - Oil c)

[0261]

[0262]

[0263]

[0264] Table MAT3: Exemplary trade names and CAS numbers of preferred spreading agents d).

[0265]

[0266]

[0267] Table MAT4: Exemplary trade names and CAS numbers of preferred absorption-enhancing additives d)

[0268]

[0269]

[0270] Table MAT5: Exemplary trade names of preferred rainproof additives e)

[0271]

[0272]

[0273] Table MAT6: Exemplary trade names and CAS numbers of preferred further auxiliaries e)

[0274]

[0275]

[0276]

[0277] Experimental methods

[0278] Method 1: Flowable SC preparation

[0279] Methods for preparing flowable suspension concentrate formulations are known in the art and may be prepared by known methods familiar to those skilled in the art. A 5% gel of Van Gel B (e) is prepared by mixing 5% of the dispersion with water under high shear. A 2% gel of Rhodopol 23 (xanthan gum) (e) in water and the biocide (e) is prepared under low shear stirring. A 1-4% solution of the drift reducing polymer (b) is prepared by mixing the polymer with glycerol (25%) under stirring and pouring the mixture into water (to 100%) until uniform. A 50% oil-in-water emulsion of the drift reducing oil (c) is prepared by mixing the polymer with glycerol (25%) under high shear stirring and pouring the mixture into water (to 100%) until uniform. Oil (50%) was added to water (49%) and Synperonic PE / F127 (1%) solution to obtain a droplet size (Dv50) of 1 to 4 microns. The active ingredient (a), nonionic and anionic dispersants (e), defoamers (e) and other adjuvants (e) were mixed with water to form a slurry, which was first mixed with a high shear rotor-stator mixer. Mixing reduces the particle size D(v, 0.9) to about 50 μm and then passes through one or more bead mills ( 250Mini Motormill) to obtain a particle size D (v, 0.9) of generally 1 to 15 microns. Then, if present in the formulation, a spreading agent and / or an absorption-promoting additive (d) are added under stirring and mixed, and then the polymer (b) solution prepared above, 50% of the oil (b) emulsion prepared above, 5% of the Van Gel B gel prepared above and 2% of the Rhodopol 23 (xanthan gum) gel prepared above are added under low shear stirring, and mixed until uniform. Additional water is added as needed to reach the final total amount. Finally, if necessary, the pH is adjusted with an acid or base (e).

[0280] Prepare polymer (b) solution according to the viscosity concentration limit and content required in the formulation. Typical example values ​​are: Polyox WSR301 (1-2%), Polyox WSR N60K (1-3%), Polyox WSR N12K (2-4%), AgRhoDR2000 (1-2%).

[0281] Flowable preparations containing small amounts of emulsified oil can be described as suspension concentrates and suspoemulsions ( www.croplife.org , Technical Monograph No:2, Catalogue of pesticide formulation types and international coding system, Edition: March 2017).

[0282] Method 2: Spray droplet size P15 measurement

[0283] The formulation was diluted in water (deionized) to the desired concentration by The TP8002EVS nozzle sprayed at a pressure of 3 bar and the droplet size spectrum was measured using an Oxford Lasers VisiSize P15, which captured images of the spray droplets and measured their size. The spray nozzle was located 20 cm above the image capture point and was slowly moved across the image capture window of the VisiSize P15 by a motorized slider, ensuring that the entire width of the spray blower was measured. At least 5000 to 10000 droplet images were captured. The droplet size spectrum was calculated by the instrument software as the volume % less than 100 microns and the volume % less than 150 microns, which is generally considered to be the driftable fraction of the spray droplets.

[0284] Method 3: Viscosity Measurement

[0285] The viscosity was measured in a rotational shear rheometer at 22°C from 0.2 s -1 Increase to 1000s -1 The measurement includes a series of logarithmically spaced shear rates (including 1s -1 , 20s -1 and 100s -1 ) and the viscosity was recorded. The samples were not pre-sheared before measurement.

[0286] Method 4: SL preparation method

[0287] Methods for preparing soluble liquid formulations are known in the art and may be prepared by known methods familiar to those skilled in the art. A 1-4% solution of drift reducing polymer (b) is prepared by mixing the polymer with glycerol (25%) and pouring the mixture into water (to 100%) under stirring until homogeneous. A 50% oil-in-water emulsion of drift reducing oil (c) is prepared by mixing the polymer with glycerol (25%) under stirring until homogeneous. Under stirring, the oil (50%) is added to the water (49%) and Synperonic PE / F127 (1%) solution to obtain a droplet size (Dv50) of 1 to 4 microns. The active ingredient (a) previously neutralized with a base (e.g. diethylene glycol amine) is added to the other surfactants in the form of a 55% aqueous solution under stirring. Additional water is added to reach the total amount. The active ingredient (a), other auxiliary agents (e), spreading agents and / or absorption-promoting additives (d) are mixed with water under stirring, and then mixed with the polymer (b) solution prepared above, the 50% oil (c) emulsion prepared above under low shear stirring until uniform. Finally, if necessary, the pH is adjusted with an acid or base (e).

[0288] --------------------------------------------------------------- Example

[0289] Fungicides

[0290] Example FN1 :Trifloxystrobin 80SC

[0291] Table FN1.1 : Formulas FN1.1, FN1.2, FN1.3, FN1.4 and FN1.5.

[0292]

[0293]

[0294] The preparation method used is the same as method 1.

[0295] Physical properties

[0296] Physical properties with regard to viscosity were assessed visually.

[0297] Table FN1.2: Physical properties of formulations.

[0298]

[0299] Viscosity measurements were performed by Method 3.

[0300] The results showed that the polymer DR2000 (HP guar gum) can be added to the SC formulation at a concentration of 2.0 to 10.0 g / l. It can also be seen that the polymer The increase of DR2000 concentration will cause the viscosity of SC preparation to increase, and for customers, the viscosity value is greater than 600mPa s (at 20s -1 Shear rates) generally result in poor pouring properties, which is undesirable.

[0301] Spray droplet size

[0302] The spray droplet size was determined according to Method 2.

[0303] Table FN1.3: Driftable fraction of spray droplets.

[0304]

[0305]

[0306] The formulation was sprayed at a dosage rate of 1 l / ha.

[0307] The results showed that the addition of rapeseed oil at higher spray volumes reduced the driftable fraction of spray droplets <100 μm and <150 μm, and the polymer The addition of DR2000 was able to reduce the driftable fraction of spray droplets at lower spray volumes. The combination of DR2000 polymers can reduce the driftable fraction of spray droplets at both high and low spray volumes. In addition, it can be seen that The amount of DR2000 polymer used is important, where 2 g / l is not enough for reduction at low spray volumes, 6 g / l and 10 g / l are sufficient for reduction (see Figure 1 ). This corresponds to only 6 to 10 g / ha of polymer, which is a surprisingly low amount for reducing the driftable fraction of the spray droplets. Even more surprisingly, the amounts of rapeseed oil required to reduce the driftable fraction of the spray droplets are very low, these amounts being far below the usual use rates of these materials. The corresponding concentrations in the spray liquor are shown in Table FN1.4, and the results show that 0.06 to 2.4 g / l of rapeseed oil in the spray liquor is comparable to 0.03 to 2.0 g / l of The DR2000 polymer combination (FN1.3 and FN1.5) can achieve the reduction in the driftable fraction of the spray droplets observed in Table FN1.3.

[0308] Table FN1.4: Concentrations of drift reduction polymers, drift reduction oils, and spreading agents and absorption enhancers in the spray dilution.

[0309]

[0310]

[0311] The formulation was sprayed at a dosage rate of 1 l / ha.

[0312] Example FN2 :Bixafen SC

[0313] Table FN2.1: Formulations FN2.1, FN2.2, FN2.3, FN2.4 and FN2.5.

[0314]

[0315]

[0316] The preparation method used is the same as method 1.

[0317] Physical properties

[0318] Physical properties with regard to viscosity were assessed visually.

[0319] Table FN2.2: Physical properties of formulations.

[0320]

[0321] The results showed that the polymer WSR301 can be added to SC formulations at a concentration of 2.0 g / L.

[0322] Spray droplet size The spray droplet size was determined according to Method 2. Table FN2.3: Driftable fraction of spray droplets.

[0323]

[0324]

[0325] The formulation was sprayed at a dosage rate of 0.5 l / ha.

[0326] The results showed that the polymer WSR301 (PEO 4 million) and oil The combination of OP can reduce the driftable fraction of spray droplets <100 μm and <150 μm in the spray rate range of 5 to 200 l / ha (see Figure 2 ).polymer WSR301 and oil were applied at rates of 1 g / ha and 5 g / ha respectively, which are very low rates and well below the usual rates of use of these materials. The corresponding concentrations in the spray liquor are shown in Table FN2.4.

[0327] Table FN2.4: Concentrations of drift reduction polymers, drift reduction oils, and spreading agents and absorption enhancers in the spray dilution.

[0328]

[0329]

[0330] The formulation was sprayed at a dosage rate of 0.5 l / ha.

[0331] Example FN3 :Isoflucypram SC

[0332] Table FN3.1 : Formulas FN3.1, FN3.2, FN3.3, FN3.4 and FN3.5.

[0333]

[0334]

[0335] The preparation method used is the same as method 1.

[0336] Physical properties

[0337] Physical properties with regard to viscosity were assessed visually.

[0338] Table FN3.2: Physical properties of formulations.

[0339]

[0340] The results showed that the polymer WSR N60K can be added to SC formulations at a concentration of 2.0 g / L.

[0341] Spray droplet size

[0342] The spray droplet size was determined according to Method 2.

[0343] Table FN3.3: Driftable fraction of spray droplets.

[0344]

[0345]

[0346] The formulation was sprayed at a dosage rate of 0.5 l / ha.

[0347] The results showed that the polymer The combination of WSR N12K (PEO 1 million) and methylated rapeseed oil reduced the driftable fraction of spray droplets <100 μm and <150 μm in the spray rate range of 5 to 200 l / ha (see Figure 3 ).polymer WSR N12K and oil were applied at 1 g / ha and 5 g / ha per hectare (ha), respectively, which are very low rates and well below the usual rates of use of these materials. The corresponding concentrations in the spray liquor are shown in Table FN3.4. Here, the limited effect at low spray rates (5 l / ha and 10 l / ha) indicates that 2 g / l of the formulation applied at 0.5 l / ha (corresponding to a dose of 1 g / ha) WSR N12K is the lower limit below which the polymer concentration is too low to affect the spray droplet size.

[0348] Table FN3.4: Concentrations of drift reduction polymers, drift reduction oils, and spreading agents and absorption enhancers in the spray dilution.

[0349]

[0350]

[0351] The formulation was sprayed at a dosage rate of 0.5 l / ha.

[0352] Example FN4: Inpyrfluxam SC

[0353] Table FN4.1 : Formulas FN4.1, FN4.2, FN4.3, FN4.4 and FN4.5.

[0354]

[0355]

[0356] The preparation method used is the same as method 1.

[0357] Physical properties

[0358] Physical properties with regard to viscosity were assessed visually.

[0359] Table FN4.2: Physical properties of formulations.

[0360]

[0361] The results showed that the polymer WSR N60K can be added to SC formulations at a concentration of 2.0 g / L.

[0362] Spray droplet size

[0363] The spray droplet size was determined according to Method 2.

[0364] Table FN4.3: Driftable fraction of spray droplets.

[0365]

[0366]

[0367] The formulation was sprayed at a dosage rate of 0.5 l / ha.

[0368] The results showed that the polymer The combination of WSR N12K (PEO 1 million) and sunflower oil reduced the driftable fraction of spray droplets <100 μm and <150 μm in the spray rate range of 5 to 200 l / ha (see Figure 4 ).polymer WSR N12K and oil were applied at rates of 1 g / ha and 5 g / ha respectively, which are very low rates and well below the usual rates of use for these materials.

[0369] Table FN4.4: Concentrations of drift reduction polymers, drift reduction oils, and spreading agents and absorption enhancers in the spray dilution.

[0370]

[0371] The formulation was sprayed at a dosage rate of 0.5 l / ha.

[0372] Example FN5 : Fluoxapiprolin 40SC

[0373] Table FN5.1 : Formulas FN5.1, FN5.2, FN5.3, FN5.4 and FN5.5.

[0374]

[0375]

[0376] The preparation method used is the same as method 1.

[0377] Physical properties

[0378] Physical properties with regard to viscosity were assessed visually.

[0379] Table FN5.2: Physical properties of formulations.

[0380]

[0381] The results showed that the polymer WSR301 (PEO 4 million) can be added to the SC formulation at a concentration of 2.2 g / l.

[0382] Spray droplet size

[0383] The spray droplet size was determined according to Method 2.

[0384] Table FN5.3: Driftable fraction of spray droplets.

[0385]

[0386]

[0387] The formulation was sprayed at a dosage rate of 0.5 l / ha.

[0388] The results showed that the polymer The combination of WSR301 and corn oil can reduce the driftable fraction of spray droplets <100 μm and <150 μm in the spray rate range of 5 to 200 l / ha (see Figure 5 ).polymer The application rates of WSR301 and oil per hectare (ha) were 1 g / ha and 5 g / ha respectively, which are very low rates and well below the usual rates of use of these materials. WSR301 has The stronger effect of WSR N12K (Examples FN2 and FN3) suggests that at the same usage rate, higher molecular weight (molar mass) grades of PEO are more effective, allowing lower usage levels in the formulation.

[0389] Table FN5.4: Concentrations of drift reduction polymers, drift reduction oils, and spreading agents and absorption enhancers in the spray dilution.

[0390]

[0391]

[0392] The formulation was sprayed at a dosage rate of 0.5 l / ha.

[0393] Example FN6 :Prothioconazole 200SC

[0394] Table FN6.1 : Formulas FN6.1, FN6.2, FN6.3, FN6.4 and FN6.5.

[0395]

[0396]

[0397] The preparation method used is the same as method 1.

[0398] Physical properties

[0399] Physical properties with regard to viscosity were assessed visually.

[0400] Table FN6.2: Physical properties of formulations.

[0401]

[0402] The results showed that the polymer WSR N12K can be added to SC formulations at a concentration of 10.0 g / L.

[0403] Spray droplet size

[0404] The spray droplet size was determined according to Method 2.

[0405] Table FN6.3: Driftable fraction of spray droplets.

[0406]

[0407]

[0408] The formulation was sprayed at a dosage rate of 0.5 l / ha.

[0409] The results showed that the polymer WSR N12K and oil The combination of IPPs can reduce the driftable fraction of spray droplets <100 μm and <150 μm in the spray rate range of 5 to 200 l / ha (see Figure 6 ).polymer WSR N12K and oil were applied at rates of 5 g / ha and 7 g / ha respectively, which are very low rates and well below the usual rates of use for these materials.

[0410] Table FN6.4: Concentrations of drift reduction polymers, drift reduction oils, and spreading agents and absorption enhancers in the spray dilution.

[0411]

[0412]

[0413] The formulation was sprayed at a dosage rate of 0.5 l / ha.

[0414] Example Polymer 1 :

[0415] Table P1.1 : Spray droplet size of polymer aqueous solution

[0416]

[0417]

[0418] The measurement was performed by method 2.

[0419] These results indicate that many high molecular weight (molar mass) polymers have little or no effect on reducing the driftable fraction of spray droplets. However, the effect of poly(ethylene oxide) (PEO) is clearly visible and shows the strongest effect herein. DR2000 (HP guar gum) also stood out for its effectiveness in reducing the driftable fraction of the spray droplets.

[0420] For kappa-carrageenan and xanthan gum polymers, limited reduction in the driftable fraction of the spray droplets was observed. However, in order to achieve a significant reduction in the driftable fraction of the spray droplets, the amount of polymer required in the formulation is very high, with the result that, at such an amount, the formulation is too viscous to pour from a bottle and is difficult to disperse in the spray liquid. In addition, although xanthan gum ( 23) is commonly used in SC formulations, but the dosage is usually 2 to 3.5 g / l, which is so low that the concentration in the spray liquid is not sufficient to significantly reduce the driftable droplet fraction, as shown in Table P1.1.

[0421] Example Polymer 2 :

[0422] Table P2.1: Spray droplet sizes of aqueous polymer solutions of PEO.

[0423]

[0424]

[0425] The measurements were carried out by method 2. The dosage rate of the polymer used for the PCF calculation was: 0.5 l / ha.

[0426] The results in Table P2.1 show that the molar mass (molecular weight) of the PEO Polyox polymer has a significant effect on the driftable droplet fraction, with 4 million mol PEO having a significantly stronger effect than 2 million mol PEO, which in turn has a stronger effect than 1 million mol PEO. Figure 7 Drawn in.

[0427] To account for this effect, a polymer concentration factor (PCF) was defined for the PEO polymer content in the formulation, where C is the concentration of the drift reducing polymer (b) in the formulation (g / l), M is the molar mass of the drift reducing polymer (b) (g / mol / 1x10 6 ), a is 1.4, and D is the dosage rate of SC (or formulation) per hectare (l / ha). The PCF value is calculated according to the following equation:

[0428] PCF=C×M a ×D

[0429] The PCF values ​​of the formulations used in the examples are listed in Table P2.2 and cover a range of about 2 to 9. The correlation between the PCF value and the driftable fraction of the spray droplets is plotted in Figure 8 In the embodiment of the present invention, the PCF value of the present invention is about 2, about 10, and shows that higher PCF value corresponds to lower driftable spray droplet fraction.These results show that the preferred range of PCF value is about 2 to about 10.In addition, PCF value can also be used for the polymer content of PEO of other molar mass grades (for example as low as 500,000 g / mol and up to 10,000,000 g / mol) and intermediate molar mass grades (for example 1,500,000 and 3,000,000 g / mol).

[0430] Table P2.2 PCF values ​​of example formulations

[0431]

[0432] Insecticides Example 11 : Deltamethrin 200SC, Spirotetramat 200SC and Ethiopromide 200SC.

[0433] Table IN1.1 : Formulas IN1.1, IN1.2, IN1.3, IN1.4, IN1.5 and IN1.6.

[0434]

[0435]

[0436] The preparation method used is the same as method 1.

[0437] Physical Properties Physical properties with regard to viscosity were assessed visually.

[0438] Table IN1.2: Physical properties of formulations.

[0439]

[0440] The results showed that the polymer WSR 301 can be added to SC formulations at a concentration of 2.4 g / L.

[0441] Spray droplet size

[0442] The spray droplet size was determined according to Method 2.

[0443] Table IN1.3: Driftable fraction of spray droplets.

[0444]

[0445]

[0446] The formulation was sprayed at a dosage rate of 0.5 l / ha.

[0447] The results showed that the polymer The combination of WSR 301 and rapeseed oil can reduce the driftable fraction of spray droplets <100 μm and <150 μm in the spray rate range of 5 to 200 l / ha (see Figure 5 ).polymer The rates of WSR301 and oil per hectare (ha) were 1.2 g / ha and 10 g / ha respectively, which are very low rates and well below the usual rates of use of these materials. Furthermore, it can be seen that similar results were achieved with the same formulation containing a range of active ingredients.

[0448] Table IN 1.4: Concentrations of drift reduction polymers, drift reduction oils, and spreading agents and absorption enhancers in the spray dilution.

[0449]

[0450]

[0451] The formulation was sprayed at a dosage rate of 0.5 l / ha.

[0452] herbicide

[0453] Example HB1 :Ethoxyfuroxil SC 50 Table HB1.1 : Formulations HB1.1, HB1.2 and HB1.3

[0454]

[0455]

[0456] The preparation method used is the same as method 1.

[0457] Physical Properties Physical properties with regard to viscosity were assessed visually.

[0458] Table HB1.2: Physical properties of formulations.

[0459]

[0460] Spray droplet size The spray droplet size was determined according to Method 2. Table HB 1.3: Driftable fraction of spray droplets.

[0461]

[0462]

[0463] The formulation was sprayed at a dosage rate of 1 l / ha.

[0464] The results showed that the polymer WSR N60K or The combination of WSR 301 and methylated rapeseed oil can reduce the driftable fraction of spray droplets <100 μm and <150 μm in the spray rate range of 5 to 1000 l / ha.

[0465] Table HB1.4: Concentrations of drift reduction polymers, drift reduction oils, and spreading agents and absorption enhancers in the spray dilution.

[0466]

[0467] The formulation was sprayed at a dosage rate of 1 l / ha.

[0468] Example HB2: Tembotrione SC 50 Table HB2.1: Formulations HB2.1, HB2.2 and HB2.3

[0469]

[0470]

[0471] The preparation method used is the same as method 1.

[0472] Physical Properties Physical properties with regard to viscosity were assessed visually. Table HB2.2: Physical properties of formulations.

[0473]

[0474] Spray droplet size The spray droplet size was determined according to Method 2. Table HB2.3: Driftable fraction of spray droplets.

[0475]

[0476]

[0477] The formulation was sprayed at a dosage rate of 1 l / ha.

[0478] The results showed that the polymer WSR N60K or The combination of WSR 301 and methylated rapeseed oil can reduce the driftable fraction of spray droplets <100 μm and <150 μm in the spray rate range of 5 to 1000 l / ha.

[0479] Table HB2.4: Concentrations of drift reduction polymers, drift reduction oils, and spreading agents and absorption enhancers in the spray dilution.

[0480]

[0481]

[0482] The formulation was sprayed at a dosage rate of 1 l / ha.

[0483] Example HB3 :Flucarbamide SC 50 Table HB3.1 : Formulations HB3.1, HB3.2 and HB3.3

[0484]

[0485]

[0486] The preparation method used is the same as method 1.

[0487] Physical Properties Physical properties with regard to viscosity were assessed visually. Table HB1.2: Physical properties of formulations.

[0488]

[0489] Spray droplet size The spray droplet size was determined according to Method 2. Table HB3.3: Driftable fraction of spray droplets.

[0490]

[0491] The formulation was sprayed at a dosage rate of 1 l / ha.

[0492] The results showed that the polymer WSR N60K or The combination of WSR 301 and methylated rapeseed oil can reduce the driftable fraction of spray droplets <100 μm and <150 μm in the spray rate range of 5 to 1000 l / ha.

[0493] Table HB3.4: Concentrations of drift reduction polymers, drift reduction oils, and spreading agents and absorption enhancers in the spray dilution.

[0494]

[0495] The formulation was sprayed at a dosage rate of 1 l / ha.

[0496] Example HB4 :(2R*,4R*)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2-carboxylic acid methyl ester SC 50

[0497] Table HB4.1 : Formulations HB4.1, HB4.2 and HB4.3

[0498]

[0499]

[0500] The preparation method used is the same as method 1.

[0501] Physical Properties Physical properties with regard to viscosity were assessed visually.

[0502] Table HB4.2: Physical properties of formulations.

[0503]

[0504]

[0505] Spray droplet size The spray droplet size was determined according to Method 2. Table HB4.3: Driftable fraction of spray droplets.

[0506]

[0507] The formulation was sprayed at a dosage rate of 1 l / ha.

[0508] The results showed that the polymer WSR N60K or The combination of WSR 301 and methylated rapeseed oil can reduce the driftable fraction of spray droplets <100 μm and <150 μm in the spray rate range of 5 to 1000 l / ha.

[0509] Table HB4.4: Concentrations of drift reduction polymers, drift reduction oils, and spreading agents and absorption enhancers in the spray dilution.

[0510]

[0511] The formulation was sprayed at a dosage rate of 1 l / ha.

[0512] Example HB5 :Dicamba-diglycolamin SL 110 (aqueous emulsion (ae))

[0513] Table HB5.1 : Formulation HB5.1 and HB5.2

[0514]

[0515] The preparation method used is the same as method 4.

[0516] Physical Properties Physical properties with regard to viscosity were assessed visually. Table HB5.2: Physical properties of formulations.

[0517]

[0518] Spray droplet size The spray droplet size was determined according to Method 2. Table HB5.3: Driftable fraction of spray droplets.

[0519]

[0520]

[0521] The formulation was sprayed at a dosage rate of 2 l / ha.

[0522] The results showed that the polymer The combination of WSR N60K and methylated rapeseed oil can reduce the driftable fraction of spray droplets <100 μm and <150 μm in the spray rate range of 5 to 1000 l / ha.

[0523] Table HB5.4: Concentrations of drift reduction polymers, drift reduction oils, and spreading agents and absorption enhancers in the spray dilution.

[0524]

[0525]

[0526] The formulation was sprayed at a dosage rate of 2 l / ha.

Claims

1. An agricultural chemical preparation comprising: a) one or more active ingredients, b) one or more polymer-based drift reduction additives selected from poly(ethylene oxide) and hydroxypropylated guar gum, c) one or more oil-based drift reduction additives, d) one or more spreading agents and / or absorption-enhancing additives, e) Other additives, f) one or more carriers to make up the total amount, wherein at least one carrier is water, It is characterized in that a) present in the range of 10-550 g / l, b) present in an amount of 0.2-50 g / l, c) present in the range of 0.5-45 g / l, d) present in an amount of 10-200 g / l, e) present at 20-300 g / l.

2. The agricultural chemical formulation according to claim 1, wherein a) present at 20-200 g / l, b) present at 1-15 g / l, c) present at 5-25 g / l, d) present at 25-140 g / l, e) present at 30-135 g / l, f) Make up the total amount of carrier.

3. The agrochemical formulation according to claim 1 or 2, wherein b) is selected from poly(ethylene oxide) having an average molecular weight of preferably 500,000 to 14 million g / mol, more preferably 750,000 to 10 million g / mol, most preferably 1 million to 8 million g / mol.

4. The agricultural chemical formulation according to claim 3, wherein the PCF of the formulation is 1 to 10.

5. The agricultural chemical formulation according to claim 4, wherein the polymer concentration factor PCF for the PEO polymer content in the formulation is calculated according to the following equation: PCF=C×M a ×D in, C is the concentration of the drift-reducing polymer (a) in the formulation (g / l), M is the molar mass of the drift-reducing polymer (a) (g / mol / 1x10 6 ), a is 1.4, and D is the dosage rate of the formulation per hectare (l / ha).

6. Agrochemical formulation according to claims 1 to 5, wherein c) is selected from vegetable oils and vegetable oil esters and vegetable oil diesters, including esters with glycerol and propylene glycol.

7. Agrochemical formulation according to one or more of claims 1 to 6, wherein the spreading agent d) is selected from sodium dioctyl sulfosuccinate, polyalkylene oxide-modified heptamethyltrisiloxane, ethoxylated diacetylenediol having 1 to 6 ethylene oxide units or ethoxylated alcohols or propoxy-ethoxylated alcohols having 6 to 22 carbon atoms and an average of 5 to 40 ethylene oxide and / or propylene oxide units, preferably selected from sodium dioctyl sulfosuccinate, polyalkylene oxide-modified heptamethyltrisiloxane and ethoxylated diacetylenediol having 1 to 6 ethylene oxide units.

8. Agrochemical formulation according to one or more of claims 1 to 7, wherein the absorption-promoting additive d) is selected from: alcohol alkoxylates containing 6 to 22 carbon atoms; ethoxylated carboxylic acids or propoxy-ethoxylated carboxylic acids containing 6 to 22 carbon atoms; ethoxylated monoesters, diesters or triesters of glycerol containing fatty acids having 8 to 18 carbon atoms and an average of 5 to 60 ethylene oxide units; alkoxylated sorbitan fatty acid esters containing fatty acids having 8 to 18 carbon atoms and an average of 10 to 50 ethylene oxide and propylene oxide units; ethoxylated coconut alcohol containing 2 to 20 EO units; or castor oil ethoxylated The invention relates to an ethoxylated alcohol or propoxy-ethoxylated alcohol comprising an average of 5 to 40 EO units, preferably selected from: ethoxylated alcohols or propoxy-ethoxylated alcohols comprising 6 to 22 carbon atoms and an average of 5 to 40 ethylene oxide and / or propylene oxide units; ethoxylated carboxylic acids or propoxy-ethoxylated carboxylic acids comprising 6 to 22 carbon atoms and an average of 5 to 40 ethylene oxide and / or propylene oxide units; ethoxylated monoesters, diesters or triesters of glycerol comprising fatty acids having 8 to 18 carbon atoms and an average of 5 to 60 ethylene oxide units; alkoxylated sorbitan fatty acid esters comprising fatty acids having 8 to 18 carbon atoms and an average of 10 to 50 ethylene oxide and propylene oxide units.

9. Agrochemical formulation according to one or more of claims 1 to 8, wherein the ratio of b) to c) in the formulation is from 1:40 to 10:1, more preferably from 1:10 to 5:1, most preferably from 1:6 to 2:

1.

10. Agrochemical formulation according to one or more of claims 1 to 9, wherein the ratio of b) to c) to d) in the formulation is from 1:40:150 to 10:1:10, more preferably from 1:12:120 to 2:1:5, most preferably from 1:8:50 to 1:2:

5.

11. Agrochemical formulation according to one or more of claims 1 to 10, wherein the active ingredient is selected from the group consisting of trifloxystrobin, bixafen, prothioconazole, inpyrfluxam, isoflucypram, fluoxapiprolin, spirotetramat, ethiprole, deltamethrin, flutosulfuron, tembotrione, ethoxyfuroxol and methyl (2R*,4R*)-4-[[(5S)-3-(3,5-difluorophenyl)-5-vinyl-4H-isoxazole-5-carbonyl]amino]tetrahydrofuran-2-carboxylate.

12. Agrochemical formulation according to one or more of claims 1 to 11, wherein the further adjuvants e) are one or more substances selected from the group consisting of: rainproof additives, surfactants, rheology modifiers, antifoaming substances, antifreeze agents, preservatives, biocides, colorants, pH regulators, buffers, stabilizers, antioxidants, inert filler materials, wetting agents, crystal growth inhibitors or micronutrients.

13. The agrochemical formulation according to claim 11, wherein the further formulation e) comprises at least one nonionic and / or ionic surfactant, one rheology modifier, one antifoam substance and at least one antifreeze agent.

14. Method for applying a formulation according to one or more of claims 1 to 13 to crops, wherein the formulation is applied at a spray rate of 1 l / ha to 2000 l / ha, preferably 5 l / ha to 1500 l / ha and more preferably 8 l / ha to 1200 l / ha.

15. Method for applying an agrochemical formulation according to one or more of claims 1 to 13 to crops, wherein the formulation is applied at a spray rate of 1 to 20 l / ha, preferably 2 to 15 l / ha and more preferably 5 to 15 l / ha.

16. Use of a formulation according to one or more of claims 1 to 13 for delivery to an agricultural target plot in the following amounts: b) in an amount of 0.5 to 15 g / ha, more preferably 1 to 12 g / ha, most preferably 1 to 10 g / ha, and c) in an amount of 0.5 to 40 g / ha, more preferably 1 to 20 g / ha, most preferably 2 to 10 g / ha, and The amount of d) is from 10 to 200 g / ha, more preferably from 15 to 160 g / ha, most preferably from 20 to 100 g / ha.

17. Use of an agrochemical formulation according to one or more of claims 1 to 13 for applying agrochemical compounds for controlling pests, wherein the formulation or a spray liquid containing the formulation is applied by an unmanned aerial vehicle (UAV) or an unmanned guided vehicle (UGV) or a nozzle device using pulse width modulation (PWM).

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