Anti-corrosion packaging method of ocean induction transmission magnetic ring and ocean induction transmission device

Abstract

The invention discloses an anti-corrosion packaging method of a marine induction transmission magnetic ring and a marine induction transmission device. The marine induction transmission device comprises a shell and a magnetic ring. The magnetic ring is a split magnetic ring and comprises an upper half ring and a lower half ring which respectively comprise a split surface and a non-split surface; the shell comprises an upper cabin body and a lower cabin body, opposite cavities are formed in the upper cabin body and the lower cabin body respectively, and the upper cabin body and the lower cabin body are used for containing the magnetic ring; the subdivision surfaces of the upper half ring and the lower half ring are opposite and connected; the anti-corrosion packaging method comprises the following steps. Depositing a nano metal film on the surface of the magnetic ring; electroplating a porous alloy shell layer on the outer side of the nano metal film on the non-subdivision surface of the magnetic ring; a compact magnetic conductive coating is arranged on the subdivision surface; and the upper half ring and the lower half ring are respectively packaged in the upper cabin body and the lower cabin body through a filling agent. The electromagnetic effect and heat accumulation magnetic ring deformation are reduced, the stability and reliability of induction transmission are improved, and the service life is prolonged.

Description

Technical Field

[0001] The invention belongs to the technical field of marine measuring instruments, and in particular relates to an anti-corrosion packaging method for a marine induction transmission magnetic ring and a marine induction transmission device. Background Art

[0002] With the rapid development of profile observation technology for underwater environmental elements in the ocean, the requirements for the timeliness of ocean data are becoming increasingly higher. The real-time acquisition technology of underwater profile data using inductive coupling transmission technology has laid a technical foundation for the real-time acquisition of data from offshore platforms such as real-time buoys and real-time submersibles. Due to its high efficiency and low loss, inductive coupling transmission technology has also been widely used in power transmission, data communication, wireless charging and other fields.

[0003] Ferrite rings are key components in inductively coupled transmission systems, and their performance directly affects transmission efficiency and stability. However, in marine applications, ferrite rings are susceptible to microcracks due to periodic electromagnetic tension and seawater erosion and corrosion, which in turn leads to overall cracking of the ferrite rings, causing the performance of the inductively coupled transmission system to decline, shorten its service life, and even fail, seriously affecting the normal operation of the ocean observation and detection system.

[0004] Therefore, improving the durability of ferrite magnetic rings in seawater environments is the key to ensuring the long-term stable operation of the inductively coupled transmission system. Summary of the invention

[0005] The present invention provides an anti-corrosion packaging method for a marine induction transmission magnetic ring and a marine induction transmission device, which reduce heat accumulation due to electromagnetic action, deformation caused by electromagnetic force and mechanical scouring, improve the stability and reliability of induction transmission, and extend the life of the marine induction transmission device.

[0006] In order to solve the above technical problems, the present invention adopts the following technical solutions to achieve the above problems:

[0007] A method for anti-corrosion packaging of a marine induction transmission magnetic ring, wherein the magnetic ring is a split ferrite magnetic ring, comprising an upper half ring and a lower half ring; the surfaces of the upper half ring and the lower half ring respectively comprise a split surface and a non-split surface; the shell comprises an upper cabin body and a lower cabin body, which respectively form cavities opposite to each other and used to place the upper half ring and the lower half ring; when the upper half ring and the lower half ring are placed in the upper cabin body and the lower cabin body, the split surfaces thereof are opposite to each other and connected;

[0008] The anti-corrosion packaging method comprises:

[0009] Depositing a nano-metal film on the surface of the magnetic ring;

[0010] Electroplating a porous alloy shell layer on the outer side of the nano metal film on the non-split surface of the magnetic ring;

[0011] Disposing a magnetic conductive coating on the split surface of the magnetic ring;

[0012] The upper half ring and the lower half ring are respectively encapsulated in the upper cabin body and the lower cabin body by means of a filler.

[0013] In some specific embodiments, the deposition of the nano-metal film on the surface of the magnetic ring is achieved by a magnetron sputtering method;

[0014] The components of the nano metal film include any two or three of iron, nickel, cobalt and their alloys.

[0015] In some specific embodiments, the sputtering power of the magnetron sputtering method ranges from 11 to 50 W / cm2, and the thickness of the nano-metal film ranges from 0.1 to 5 μm.

[0016] In some specific embodiments, the preparation of the shell layer and the magnetic conductive coating comprises the following steps:

[0017] Using a porous filter membrane to wrap the non-split surface of the magnetic ring;

[0018] The magnetic ring is placed in a plating solution; the plating solution comprises any two or three metal ions of FeSO4, CoCl2, NiSO4·6H2O, NiCl2·5H2O, and MnSO4 (1.5-45 g / L), H3BO3 (45 g / L); the pH value is 2.0-4.1;

[0019] Electrochemical deposition; current density range is 0.2~12A / dm 2 ; The electroplating temperature is maintained at 55-60°C; the electroplating solution is continuously stirred at a speed of 250r / min and the solution temperature is kept constant; the shell layer is formed on the non-split surface; and an initial coating is formed on the split surface.

[0020] In some specific embodiments, the thickness of the shell layer ranges from 5 to 25 μm; the thickness of the initial coating layer ranges from 0.1 to 5 μm.

[0021] In some specific embodiments, the forming of the magnetic conductive coating further comprises the following steps:

[0022] The initial coating is treated by a chemical method to obtain the magnetic conductive coating; the chemical method is to place the initial coating in an oxidant and complexing agent solution under an ultrasonic environment of -10 to 2°C and soak it for 2 to 6 hours; the oxidant is persulfate, and its concentration range is 10 to 30 g / L; the complexing agent is sodium citrate, and its concentration range is 20 to 50 g / L; the pH range is 4.1 to 6.1; and the ultrasonic power is 10 to 60 W.

[0023] In some specific embodiments, the filler includes a first filler and a second filler; and the step of encapsulating the upper half ring and the lower half ring in the upper cabin and the lower cabin respectively by the filler includes:

[0024] The upper half ring and the lower half ring are respectively installed into the cavities of the upper cabin body and the lower cabin body, with the split surfaces facing outwards;

[0025] Filling the first filler into the gap between the non-split surface of the magnetic ring and the cavity and performing curing and heat preservation treatment; the first filler includes aliphatic epoxy resin, aliphatic amine curing agent, and diluent benzyl alcohol in a volume ratio of (3-5):1, and the ratio is 0.15-0.25; the curing temperature is -5-5°C, and the curing time is 36-108 hours; after curing, the mixture is kept at 25°C for 8-24 hours;

[0026] The second filler is filled into the non-split surface of the magnetic ring, the surface of the first filler and the gap between the first filler and the cavity, and then cured and heat-insulated; the second filler includes 3 to 5 parts of epoxy resin, 1 part of fatty amine curing agent, and 0.01-0.03 parts of barium carbonate filler, and is obtained by mixing the above ingredients evenly and degassing them at a temperature of -5 to 15°C for 0.5 to 5 minutes; the vacuum degree is 0.15 to 0.85 standard atmospheric pressure; the curing temperature is 0 to 5°C; the curing time is 24 to 96 hours; after curing, it is kept warm at 25°C for 12 to 24 hours.

[0027] A marine induction transmission device comprises a split magnetic ring and a shell; the magnetic ring is a split ferrite magnetic ring, which is anti-corrosion treated by the above-mentioned anti-corrosion packaging method and packaged in the shell.

[0028] Compared with the prior art, the advantages and positive effects of the present invention are as follows: the marine induction transmission device and the anti-corrosion packaging method of the marine induction transmission magnetic ring of the present invention not only improve the heat conduction performance generated by the magnetic ring and reduce the temperature of the magnetic ring by depositing a nano-metal film on the surface of the magnetic ring, but also produce a substrate that is easy to electroplate, so that the shell layer and the magnetic conductive coating generated by electroplating are more closely combined with the magnetic ring, and combined with the porous alloy material, the mechanical strength and wear resistance of the magnetic ring are improved, and the deformation resistance and impact resistance are improved. In addition, the magnetic ring is encapsulated in the shell to improve the sealing, prevent corrosion from seawater, and improve the stability and reliability of the marine induction transmission device and extend its life. BRIEF DESCRIPTION OF THE DRAWINGS

[0029] In order to more clearly illustrate the technical solutions in the embodiments of the present invention, the following briefly introduces the drawings required for use in the embodiments. Obviously, the drawings described below are some embodiments of the present invention. For ordinary technicians in this field, other drawings can be obtained based on these drawings without creative work.

[0030] Figure 1 It is a structural schematic diagram of the ocean induction transmission device proposed by the present invention;

[0031] Figure 2 is a cross-sectional structural diagram of a marine inductive transmission device according to an embodiment;

[0032] Figure 3 is a cross-sectional structural diagram of a marine inductive transmission device according to an embodiment;

[0033] Figure 4 is a schematic structural diagram of a magnetic ring according to an embodiment;

[0034] Figure 5 is a schematic structural diagram of an upper half ring according to an embodiment;

[0035] Figure 6 Schematic diagram of the structure of the lower half ring according to the embodiment

[0036] Figure 7 It is a schematic flow chart of the anti-corrosion packaging method according to an embodiment.

[0037] In the figure,

[0038] 1. Shell; 11. Upper cabin; 12. Lower cabin; 13. Cavity; 2. Magnetic ring; 21. Upper half ring; 22. Lower half ring; 23. Split surface; 24. Non-split surface. DETAILED DESCRIPTION

[0039] Embodiments of the present invention are described in detail below, examples of which are shown in the accompanying drawings, wherein the same or similar reference numerals throughout represent the same or similar elements or elements having the same or similar functions. The embodiments described below with reference to the accompanying drawings are exemplary and are intended to be used to explain the present invention, and should not be construed as limiting the present invention.

[0040] Reference Figure 1 , Figure 2 , Figure 3 , Figure 4 , Figure 5 , Figure 6 , Figure 7 The present invention discloses an anti-corrosion packaging method for a marine inductive transmission magnetic ring 2 and a marine inductive transmission device obtained by the anti-corrosion packaging method.

[0041] The marine induction transmission device includes a shell 1 and a magnetic ring 2; the magnetic ring 2 is a ferrite split magnetic ring, including an upper half ring 21 and a lower half ring 22, which respectively include a split surface 23 and a non-split surface 24; and the split surface 23 is parallel to the axis of the magnetic ring 2.

[0042] The shell 1 includes an upper cabin body 11 and a lower cabin body 12, which respectively form cavities 13 that are opposite to each other and are used to install an upper half ring 21 and a lower half ring 22; the upper half ring 21 and the lower half ring 22 are respectively fixedly installed in the cavities 13 of the upper cabin body 11 and the lower cabin body 12; the upper cabin body 11 and the lower cabin body 12 are installed and fixed together, and the split surface 23 of the upper half ring 21 located in the upper cabin body 11 and the split surface 23 of the lower half ring 22 located in the lower cabin body 12 are opposite to each other and connected, so that the upper half ring 21 and the lower half ring 22 form a complete magnetic ring 2.

[0043] The anti-corrosion packaging method of the magnetic ring 2 in the marine induction transmission device includes:

[0044] S1, depositing a nano-metal film on the surface of the magnetic ring 2; the surface of the magnetic ring 2 includes a split surface 23 and a non-split surface 22; that is, the nano-metal film is deposited on both the split surface 23 and the non-split surface 24 of the magnetic ring 2 to improve the thermal conductivity of the magnetic ring 2;

[0045] S2, electroplating a porous alloy shell layer on the nano metal film on the non-split surface 24 of the magnetic ring 2; that is, electroplating is performed on the non-split surface 24 of the magnetic ring 2 using the nano metal film as a substrate, and a porous alloy shell layer is formed on the outside of the metal film, which plays a role in enhancing the mechanical strength and preventing the magnetic ring 2 from being deformed due to electromagnetic effects and external force impacts;

[0046] S3, a dense magnetic conductive coating is provided on the split surface 23 of the magnetic ring 2; that is, a dense magnetic conductive coating is formed with the nano-metal film on the split surface 23 as a matrix, so as to enhance the mechanical strength of the magnetic ring 2 while ensuring the conduction of the magnetic flux circuit;

[0047] S4. The upper half ring 21 and the lower half ring 22 are respectively encapsulated in the cavities 13 of the upper cabin body 11 and the lower cabin body 12 by means of a filler, thereby achieving encapsulation and mechanical protection of the magnetic ring 2 and the shell 1.

[0048] Of course, the order of step S2 and step S3 can be adjusted as needed.

[0049] The marine inductive transmission device and the anti-corrosion packaging method of the marine inductive transmission magnetic ring of the present invention not only improve the heat conduction performance generated by the magnetic ring 2 and reduce the temperature of the magnetic ring 2 by depositing a nano-metal film on the surface of the magnetic ring 2, but also produce a substrate that is easy to electroplate, so that the shell layer and the magnetic conductive coating generated by electroplating are more closely combined with the magnetic ring 2. Combined with the porous alloy material, the mechanical strength and wear resistance of the magnetic ring 2 are improved, and the deformation resistance and impact resistance are improved. In addition, the magnetic ring 2 is packaged into the shell 1 to improve the sealing, prevent corrosion from seawater, and improve the stability and reliability of the marine inductive transmission device and extend its life.

[0050] The specific process and principle of the anti-corrosion packaging method of the present invention and the structure and principle of the marine induction transmission device are described in detail below through specific embodiments.

[0051] In some specific embodiments, reference Figure 1 , Figure 2 , Figure 3 , Figure 4 , Figure 5 , Figure 6 , Figure 7 In the anti-corrosion packaging method, the nano-metal film is deposited on the surface of the magnetic ring 2 by magnetron sputtering; and the components of the nano-metal film include any two or three of iron, cobalt, nickel and their alloys.

[0052] The nano-metal film of the magnetic ring 2 of the ocean induction transmission device includes any two or three of iron, cobalt, nickel and their alloys, and is generated by magnetron sputtering.

[0053] The anti-corrosion packaging method and marine inductive transmission device of this embodiment can not only improve the cumulative heat conduction performance of the ferrite magnetic ring 2, but also inhibit the expansion of microcracks during the ferrite processing process by depositing nano-metal films of iron, cobalt, nickel and their alloys on the surface of the magnetic ring 2; the reduction of microcracks helps prevent seawater from penetrating into the interior of the magnetic ring 2 through the cracks, avoiding electrochemical corrosion, thereby protecting the mechanical properties and magnetic properties of the magnetic ring 2, and further improving the performance and reliability of the entire inductive coupling transmission system, delaying its aging and failure in the seawater environment. In addition, a metal electroplating matrix is ​​formed to improve the bonding of electroplating.

[0054] In some specific embodiments, reference Figure 1 , Figure 2 , Figure 3 , Figure 4 , Figure 5 , Figure 6 , Figure 7 The sputtering power range of magnetron sputtering method is 11~50W / cm 2 , thickness is 0.1~5μm.

[0055] In some specific embodiments, reference Figure 1 , Figure 2 , Figure 3 , Figure 4 , Figure 5 , Figure 6 , Figure 7 , the preparation of the shell layer comprises the following steps:

[0056] The non-split surface 24 of the magnetic ring 2 is wrapped with a porous filter membrane; illustratively, the porous filter membrane is made of polyvinylidene fluoride (PVDF);

[0057] The magnetic ring 2 wrapped with the porous filter membrane is placed in the electroplating solution; the components of the electroplating solution include any two or three metal ions of FeSO4, CoCl2, NiSO4·6H2O, NiCl2·5H2O, and MnSO4 (1.5-45g / L), H3BO3 (45g / L); the pH value is 2.0-4.1; the concentration range of divalent iron ions is 50-150g / L, the concentration range of divalent cobalt ions is The concentration range of the electroplating solution is 30-100 g / L, and the concentration range of the divalent nickel ion is 250-550 g / L; illustratively, the electroplating solution components include FeSO4 (50-150 g / L), CoCl2 (30-100 g / L), NiSO4·6H2O (205-505 g / L), NiCl2·5H2O (45 g / L), MnSO4 (1.5-45 g / L), and H3BO3 (45 g / L);

[0058] Electrochemical deposition was performed; the current density range was 0.2-12A / dm 2 ; The electroplating temperature is maintained at 55-60°C; the electroplating solution is continuously stirred at a speed of 250r / min and the solution temperature is kept constant.

[0059] A shell layer is formed on the non-split surface; an initial coating is formed on the split surface.

[0060] Of course, the stirring speed of the plating solution can fluctuate around 250r / min.

[0061] The shell layer of the magnetic ring 2 of the marine inductive transmission device is produced by the above-mentioned electroplating deposition method.

[0062] The anti-corrosion packaging method of this embodiment enables the magnetic ring 2 of the marine induction transmission device to generate a shell with enhanced thermal conductivity and stress absorption capability, effectively suppressing the deformation of the magnetic ring 2 under the action of temperature and electromagnetic cycle, reducing its structural stress, and effectively avoiding the generation of cracks and corrosion in the magnetic ring, thereby further improving the stability, reliability and life of the marine induction transmission device.

[0063] In some specific embodiments, the thickness of the shell layer is in the range of 15 to 25 μm, and the porosity is in the range of 0.1 to 0.8 cells / cm2 ; The thickness of the initial coating is 0.1~5μm.

[0064] In some specific embodiments, reference Figure 1 , Figure 2 , Figure 3 , Figure 4 , Figure 5 , Figure 6 , Figure 7 The step of forming the magnetic conductive coating further includes:

[0065] The initial coating is treated by a chemical method to obtain a magnetic conductive coating; the chemical method is to place the initial coating in an oxidant and complexing agent solution and soak it for 2 to 6 hours in an ultrasonic environment of -10 to 2°C; the oxidant is persulfate, and its concentration range is 10 to 30 g / L; the complexing agent is sodium citrate, and its concentration range is 20 to 50 g / L; the pH range is 4.1 to 6.1; and the ultrasonic power is 10 to 60 W.

[0066] Cobalt-manganese alloy has specific magnetic properties. The ions of cobalt and manganese form an arrangement that is conducive to the transfer of magnetic moment and the conduction of magnetic flux, so that electrons can move relatively easily therein, thereby ensuring the conduction performance of the magnetic circuit, so that the magnetic flux can effectively pass through the magnetic conductive coating and the split ferrite magnetic ring 2;

[0067] The anti-corrosion packaging method and the marine inductive transmission device of this embodiment ensure the conduction of the magnetic flux circuit under the action of the AC signal by setting a magnetic conductive coating with properties similar to spinel, maintain the magnetic properties of the magnetic ring 2, and ensure the normal operation of the inductive coupling transmission system; in addition, the magnetic conductive coating increases the strength of the split surface 23 of the magnetic ring 2, improves the mechanical properties, and thereby improves the stability and reliability of the marine inductive transmission device and extends its life.

[0068] In some specific embodiments, reference Figure 1 , Figure 2 , Figure 3 , Figure 4 , Figure 5 , Figure 6 , Figure 7 The filling agent includes a first filling agent and a second filling agent; the steps of encapsulating the upper half ring 21 and the lower half ring 22 to the upper cabin body 11 and the lower cabin body 12 respectively include:

[0069] Install the upper half ring 21 and the lower half ring 22 into the cavities 13 of the upper cabin 11 and the lower cabin 12 respectively, with the split surface 23 facing outwards;

[0070] Filling the first filler into the gap between the non-split surface 24 of the magnetic ring 2 and the cavity 13 and performing curing and heat preservation treatment; the first filler includes aliphatic epoxy resin, aliphatic amine curing agent, and diluent benzyl alcohol in a volume ratio of (3-5):1, and the ratio is 0.15-0.25; the curing temperature is -5-5°C, and the curing time is 36-108 hours; after curing, the mixture is kept at 25°C for 8-24 hours;

[0071] The second filler is filled into the non-split surface 24 of the magnetic ring 2, the surface of the first filler and the gap between it and the cavity 13, and then cured and heat-insulated. The second filler includes 3 to 5 parts of epoxy resin, 1 part of fatty amine curing agent, and 0.01-0.03 parts of barium carbonate filler, and is obtained by mixing the above ingredients evenly and degassing them at a temperature of -5 to 15°C for 0.5 to 5 minutes; the vacuum degree is 0.15 to 0.85 standard atmospheric pressure; the curing temperature is 0 to 5°C; the curing time is 24 to 96 hours; after curing, it is kept warm at 25°C for 12 to 24 hours.

[0072] In the description of the present invention, it is necessary to understand that the directions or positional relationships indicated by the terms "up", "down", "front", "back", "left", "right", etc. are based on the directions or positional relationships shown in the accompanying drawings, and are only for the convenience of describing the present invention and simplifying the description, rather than indicating or implying that the device or element referred to must have a specific direction, be constructed and operated in a specific direction, and therefore cannot be understood as a limitation on the present invention.

[0073] In addition, the terms "first" and "second" are used for descriptive purposes only and should not be understood as indicating or implying relative importance or implicitly indicating the number of the indicated technical features. Therefore, the features defined as "first" and "second" may explicitly or implicitly include at least one of the features. In the description of the present invention, the meaning of "plurality" is at least two, such as two, three, etc., unless otherwise clearly and specifically defined.

[0074] In the present invention, unless otherwise clearly specified and limited, the terms "installed", "connected", "connected", "fixed" and the like should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium, it can be the internal connection of two elements or the interaction relationship between two elements, unless otherwise clearly defined. For ordinary technicians in this field, the specific meanings of the above terms in the present invention can be understood according to specific circumstances.

[0075] In the present invention, unless otherwise clearly specified and limited, a first feature being "above" or "below" a second feature may mean that the first and second features are in direct contact, or the first and second features are in indirect contact through an intermediate medium. Moreover, a first feature being "above", "above" or "above" a second feature may mean that the first feature is directly above or obliquely above the second feature, or simply means that the first feature is higher in level than the second feature. A first feature being "below", "below" or "below" a second feature may mean that the first feature is directly below or obliquely below the second feature, or simply means that the first feature is lower in level than the second feature.

[0076] In the description of this specification, the description with reference to the terms "one embodiment", "some embodiments", "example", "specific example", or "some examples" etc. means that the specific features, structures, materials or characteristics described in conjunction with the embodiment or example are included in at least one embodiment or example of the present invention. In this specification, the schematic representations of the above terms do not necessarily refer to the same embodiment or example. Moreover, the specific features, structures, materials or characteristics described may be combined in any one or more embodiments or examples in a suitable manner. In addition, those skilled in the art may combine and combine the different embodiments or examples described in this specification and the features of the different embodiments or examples, without contradiction.

[0077] Although the embodiments of the present invention have been shown and described above, it is to be understood that the above embodiments are exemplary and are not to be construed as limitations of the present invention. A person skilled in the art may change, modify, replace and vary the above embodiments within the scope of the present invention.

Claims

1. A method for anti-corrosion packaging of a marine induction transmission magnetic ring, wherein the magnetic ring is a split ferrite magnetic ring, comprising an upper half ring and a lower half ring; the surfaces of the upper half ring and the lower half ring respectively comprise a split surface and a non-split surface; the shell comprises an upper cabin body and a lower cabin body, which respectively form cavities opposite to each other and used to place the upper half ring and the lower half ring; when the upper half ring and the lower half ring are placed in the upper cabin body and the lower cabin body, the split surfaces thereof are opposite to each other and connected; It is characterized in that include: Depositing a nano-metal film on the surface of the magnetic ring; Electroplating a porous alloy shell layer on the outer side of the nano metal film on the non-split surface of the magnetic ring; Disposing a magnetic conductive coating on the split surface of the magnetic ring; The upper half ring and the lower half ring are respectively encapsulated in the upper cabin body and the lower cabin body by means of a filler.

2. The anti-corrosion packaging method according to claim 1, characterized in that: Depositing the nano-metal film on the surface of the magnetic ring is achieved by a magnetron sputtering method; The components of the nano metal film include any two or three of iron, nickel, cobalt and their alloys.

3. The anti-corrosion packaging method according to claim 2, characterized in that: The sputtering power range of the magnetron sputtering method is 11 to 50 W / cm 2 The thickness of the nano metal film is 0.1 to 5 μm.

4. The anti-corrosion packaging method according to claim 1, characterized in that: The preparation of the shell layer and the magnetic conductive coating comprises the following steps: Using a porous filter membrane to wrap the non-split surface of the magnetic ring; The magnetic ring is placed in a plating solution; the plating solution comprises any two or three metal ions of FeSO4, CoCl2, NiSO4·6H2O, NiCl2·5H2O, and MnSO4 (1.5-45 g / L), H3BO3 (45 g / L); the pH value is 2.0-4.1; Electrochemical deposition; current density range is 0.2~12A / dm 2 ; The electroplating temperature is maintained at 55-60°C; the electroplating solution is continuously stirred at a speed of 250r / min and the solution temperature is kept constant; the shell layer is formed on the non-split surface; and an initial coating is formed on the split surface.

5. The anti-corrosion packaging method according to claim 4, characterized in that: The thickness of the shell layer ranges from 5 to 25 μm; the thickness of the initial coating layer ranges from 0.1 to 5 μm.

6. The anti-corrosion packaging method according to claim 4, characterized in that: The formation of the magnetic conductive coating further comprises the following steps: The initial coating is treated by a chemical method to obtain the magnetic conductive coating; the chemical method is to place the initial coating in an oxidant and complexing agent solution under an ultrasonic environment of -10 to 2°C and soak it for 2 to 6 hours; the oxidant is persulfate, and its concentration range is 10 to 30 g / L; the complexing agent is sodium citrate, and its concentration range is 20 to 50 g / L; the pH range is 4.1 to 6.1; and the ultrasonic power is 10 to 60 W.

7. The anti-corrosion packaging method according to any one of claims 1 to 6, characterized in that: The filler includes a first filler and a second filler; and the step of respectively encapsulating the upper half ring and the lower half ring in the upper cabin and the lower cabin by the filler includes: The upper half ring and the lower half ring are respectively installed into the cavities of the upper cabin body and the lower cabin body, with the split surfaces facing outwards; Filling the first filler into the gap between the non-split surface of the magnetic ring and the cavity and performing curing and heat preservation treatment; the first filler includes aliphatic epoxy resin, aliphatic amine curing agent, and diluent benzyl alcohol in a volume ratio of (3-5):1, and the ratio is 0.15-0.25; the curing temperature is -5-5°C, and the curing time is 36-108 hours; after curing, the mixture is kept at 25°C for 8-24 hours; The second filler is filled into the non-split surface of the magnetic ring, the surface of the first filler and the gap between the first filler and the cavity, and then cured and heat-insulated; the second filler includes 3 to 5 parts of epoxy resin, 1 part of fatty amine curing agent, and 0.01-0.03 parts of barium carbonate filler, and is obtained by mixing the above ingredients evenly and degassing them at a temperature of -5 to 15°C for 0.5 to 5 minutes; the vacuum degree is 0.15 to 0.85 standard atmospheric pressure; the curing temperature is 0 to 5°C; the curing time is 24 to 96 hours; after curing, it is kept warm at 25°C for 12 to 24 hours.

8. An ocean induction transmission device, characterized in that: It comprises a split magnetic ring and a shell; the magnetic ring is a split ferrite magnetic ring, which is treated with anti-corrosion and packaged in the shell using the anti-corrosion packaging method described in any one of claims 1 to 7.

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