Laser-assisted sintering of molybdenum-manganese method ceramic metallization method

Abstract

The application discloses a kind of laser-assisted sintering molybdenum manganese method ceramic metallization methods, comprising the following steps: S1, ceramic substrate is pretreated;S2, preparation metallization mixed powder;S3, preparation organic solvent;S4, preparation metallization slurry;S5, laser-assisted alumina ceramic substrate metallization sintering.The application adopts the above-mentioned laser-assisted sintering molybdenum manganese method ceramic metallization method, can solve the problem of alumina ceramic metallization sintering temperature higher and ceramic-metal section combination force insufficient.

Description

Technical Field

[0001] The invention belongs to the technical field of ceramic material processing, and in particular relates to a laser-assisted sintering molybdenum-manganese ceramic metallization method. Background Art

[0002] Metal-ceramic composites, with their exceptional hardness, wear resistance, high temperature resistance, corrosion resistance, good thermal stability, excellent mechanical properties, electrical and thermal conductivity, low thermal expansion coefficient, biocompatibility, and environmental friendliness, demonstrate broad application potential in a wide range of industries, including aerospace, automotive, machining, electronics, chemicals, healthcare, energy, construction, military, and environmental engineering. By combining the toughness of metals with the rigidity of ceramics, these materials offer a solution that maintains stable performance in extreme environments. They also play a vital role in improving product durability, efficiency, and safety, making them indispensable high-performance materials in modern industrial and technological development.

[0003] The connection problems between ceramics and metals are mainly caused by the differences in thermal expansion coefficient, wettability, brittleness and metallurgical compatibility between the two. These differences lead to residual stress, cracks and loose connections during the connection process. To solve these problems, researchers have developed a variety of connection technologies, including mechanical connection, adhesive connection, brazing connection, solid-phase diffusion connection, transient liquid phase connection, melting welding, self-propagating high-temperature synthesis connection and other methods. Each method has its applicable scenarios and limitations. With the advancement of technology, these connection methods are constantly being improved and optimized to meet the growing demand of modern industry for ceramic-metal connections, ensure the strength, airtightness and high-temperature resistance of the connection, thereby expanding the application areas of ceramic materials and improving their application potential in high-end fields such as new energy vehicles, electronics and electrical, and semiconductor packaging.

[0004] Therefore, a new ceramic metallization technology needs to be developed in this field to effectively solve the above problems. Summary of the Invention

[0005] The purpose of the present invention is to provide a laser-assisted sintering molybdenum-manganese ceramic metallization method, which can solve the problems of high sintering temperature of alumina ceramic metallization and insufficient ceramic-metal cross-section bonding strength.

[0006] To achieve the above object, the present invention provides a laser-assisted sintering molybdenum-manganese ceramic metallization method, comprising the following steps:

[0007] S1, pre-treating the ceramic substrate;

[0008] The 95 alumina ceramic substrate was polished with sandpaper and then ultrasonically cleaned in alcohol for 10-30 minutes.

[0009] S2, preparing metallized mixed powder;

[0010] S21. Weigh raw material powders according to the mass percentages of molybdenum powder 40-65%, manganese powder 10-25%, NiO 5-28%, SiO2 1-10%, Al2O3 1-10%, CuO 1-20%, and Fe2O3 1-5%;

[0011] S22, dispersing the weighed raw material powder into anhydrous ethanol and ball milling;

[0012] S23, ball milling and drying to obtain a metallized mixed powder;

[0013] S3, preparing an organic solvent;

[0014] Weigh 95-98% terpineol and 2-5% ethyl cellulose by mass, and add the weighed ethyl cellulose to the terpineol under heating at 60-80° C. to dissolve the mixture, thereby obtaining an organic solvent;

[0015] S4, preparing metallization slurry;

[0016] Add the metallized mixed powder to the organic solvent in a mass ratio of metallized mixed powder to organic solvent = 4:1, heat at 45-60°C and stir thoroughly to obtain a metallized slurry;

[0017] S5, laser-assisted metallization sintering of alumina ceramic substrate;

[0018] The metallized slurry prepared in step S4 is evenly coated on the 95 alumina ceramic substrate pretreated in step S1, and then dried, subjected to laser sintering treatment with different powers, and sintered to obtain a metallized ceramic product.

[0019] Preferably, in step S1, the mesh number of the sandpaper used for polishing is 400-1000 mesh; and the volume fraction of ethanol in the alcohol is 60-80%.

[0020] Preferably, in step S2, the particle size D of molybdenum powder, manganese powder, NiO, Al2O3, CuO, and Fe2O3 is 50 All ≤1μm; SiO2 powder particle size is D 50 ≤0.5μm.

[0021] Preferably, in step S2, the ball milling time is 20-40 min, and the ball milling speed is 400-600 r / min; the temperature when drying the metallized mixed powder is 100-140° C., and the drying time is 30-50 min.

[0022] Preferably, in step S3, the heating and dissolving time is 70 to 90 minutes.

[0023] Preferably, in step S4, the metallization mixed powder should be added while stirring during the preparation of the metallization slurry.

[0024] Preferably, in step S5, the metallization slurry is evenly coated manually using a brush; the drying temperature is 110-150° C., and the drying time is 40-70 minutes; and the laser used in the laser sintering process is a fiber continuous laser.

[0025] Preferably, the processing power of the laser is 150-380W; the sintering temperature of the 95 alumina ceramic substrate after laser sintering is controlled to be 1250-1380°C, and the sintering holding time is 60-100min.

[0026] The present invention adopts the above-mentioned laser-assisted sintering molybdenum-manganese ceramic metallization method, and the beneficial effects are as follows:

[0027] (1) The ceramic metallization method provided by the present invention has a sintering temperature between 1250 and 1400°C after laser treatment, which is about 80°C lower than the current mainstream molybdenum-manganese metallization method. This reduces the negative effects of conventional high firing temperatures on the ceramic substrate, such as deformation and cracking, and improves the metallization quality.

[0028] (2) The metal layer of the present invention, after laser sintering pretreatment, partially diffuses into the ceramic matrix, thereby achieving the purpose of reducing the sintering temperature during subsequent high-temperature sintering, and at the same time increasing the interface bonding strength between the metal layer and the ceramic matrix, thereby improving the physical properties of the ceramic-metal composite material, such as wear resistance and tensile strength;

[0029] (3) The present invention strictly controls the purity and particle size of the raw materials and performs preliminary ball milling on the molybdenum metal powder. These measures can effectively improve the activity of the powder. This not only reduces the sintering temperature to a certain extent, but also enhances the permeability of the slurry, thereby achieving the formation of a thicker single-sintering metallization layer.

[0030] The technical solution of the present invention is further described in detail below through the accompanying drawings and embodiments. BRIEF DESCRIPTION OF THE DRAWINGS

[0031] Figure 1 This is a flow chart of an embodiment of a laser-assisted sintering molybdenum-manganese ceramic metallization method of the present invention;

[0032] Figure 2 Figure 1 shows a cross-sectional microscopic image of a metallized ceramic product prepared in Example 1 of the laser-assisted sintering method for metallizing ceramics using a molybdenum-manganese process according to the present invention. (a) shows a microscopic image of the metallized ceramic sample sintered after 180W laser treatment at a 10µm scale. (b) shows a magnified portion of (a).

[0033] Figure 3 Figure 1 shows a cross-sectional microscopic image of a metallized ceramic product prepared in Example 2 of the present invention's laser-assisted sintering method for ceramic metallization using a molybdenum-manganese process. (a) shows a 20 μm microscopic image of the metallized ceramic sample sintered after 230 W laser treatment. (b) shows a magnified portion of (a).

[0034] Figure 4 Figure 3 shows a cross-sectional micromorphology of a metallized ceramic product prepared in Example 3 of the laser-assisted sintering method for ceramic metallization using a molybdenum-manganese process according to the present invention. (a) shows a 200 μm micromorphology of a metallized ceramic sample sintered after 280 W laser treatment. (b) shows a magnified portion of (a).

[0035] Figure 5 This is a cross-sectional micromorphology of a metallized ceramic product prepared in Example 1 of the laser-assisted sintering molybdenum-manganese method for ceramic metallization according to the present invention; wherein (a) is a micromorphology at a scale of 100 μm of a metallized ceramic sample obtained without laser treatment and sintering; (b) is a magnified portion of the image in (a). DETAILED DESCRIPTION

[0036] The technical solution of the present invention is further described below with reference to the accompanying drawings and embodiments.

[0037] Unless otherwise defined, technical or scientific terms used in the present invention shall have the same meaning as commonly understood by one of ordinary skill in the art to which the present invention belongs.

[0038] like Figure 1 As shown, a laser-assisted sintering molybdenum-manganese ceramic metallization method includes the following steps:

[0039] S1. Pre-treating the ceramic substrate.

[0040] The 95 alumina ceramic substrate was polished with sandpaper and then placed in alcohol for ultrasonic cleaning for 10 to 30 minutes to increase the surface roughness of the alumina ceramic substrate and remove surface oil stains.

[0041] The grit of sandpaper used for polishing is 400-1000. The volume fraction of ethanol in alcohol is 60-80%.

[0042] S2. Prepare metallized mixed powder.

[0043] S21. Weigh raw material powders according to the mass percentages of molybdenum powder 40-65%, manganese powder 10-25%, NiO 5-28%, SiO2 1-10%, Al2O3 1-10%, CuO 1-20%, and Fe2O3 1-5%.

[0044] Particle size D of molybdenum powder, manganese powder, NiO, Al2O3, CuO, Fe2O3 50 All ≤1μm. SiO2 powder particle size is D 50 ≤0.5μm, all raw material powders are analytical grade.

[0045] The addition of silicon dioxide (SiO2) improves the wettability of metal powder on ceramics, enhancing their sealing properties. Aluminum oxide (Al2O3) helps strengthen the connection between the metal skeletons and enhance the seal strength. Furthermore, the addition of activators CuO and Fe2O3 increases the glass phase of the metallization slurry during high-temperature sintering, enhancing its diffusion capacity and promoting high-temperature liquid-phase sintering, which facilitates a close bond between the metallization layer and the ceramic substrate.

[0046] S22. Disperse the weighed raw material powder in anhydrous ethanol and ball-mill for 20-40 minutes at a speed of 400-600 rpm.

[0047] S23, ball milling and drying to obtain a metallized mixed powder. The drying temperature is 100-140° C. and the drying time is 30-50 minutes.

[0048] S3. Prepare an organic solvent.

[0049] Weigh 95-98% terpineol and 2-5% ethyl cellulose by weight, then add the weighed ethyl cellulose to the terpineol at 60-80°C for heating and dissolving to obtain an organic solvent. The heating and dissolving time is 70-90 minutes.

[0050] S4. Prepare metallization slurry.

[0051] Add the metallizing mixed powder to the organic solvent at a mass ratio of 4:1, heat at 45-60°C, and stir thoroughly to obtain the metallizing slurry. The metallizing mixed powder should be added while stirring during the preparation of the metallizing slurry.

[0052] S5. Laser-assisted metallization sintering of alumina ceramic substrate.

[0053] The metallized slurry prepared in step S4 is evenly applied to the 95 alumina ceramic substrate pretreated in step S1 by hand using a brush, and then dried, sintered with lasers of different powers, and sintered to obtain a metallized ceramic product.

[0054] The drying temperature is 110~150℃ and the drying time is 40~70min.

[0055] The laser used in laser sintering is a fiber continuous laser with a processing power of 150~380w.

[0056] The sintering temperature of the 95 alumina ceramic substrate after laser sintering is controlled at 1250~1380℃, and the sintering holding time is 60~100min.

[0057] Example 1

[0058] A laser-assisted sintering molybdenum-manganese ceramic metallization method comprises the following steps:

[0059] S1. Pre-treating the ceramic substrate.

[0060] The prepared 95% alumina ceramic substrate was polished with 500-grit sandpaper for 15 minutes to increase the surface roughness of the ceramic plate. The polished 95% alumina ceramic substrate was ultrasonically cleaned in 85% alcohol for 20 minutes to remove surface oil stains.

[0061] S2. Prepare metallized mixed powder.

[0062] S21, weigh 50g of molybdenum powder, 15g of manganese powder, 6g of NiO, 5g of SiO2, 3g of Al2O3, 8g of CuO, and 2g of Fe2O3. 50 ≤0.5μm. Particle size of molybdenum powder, manganese powder, NiO, Al2O3, CuO, Fe2O3 50 All the raw material powders are ≤1μm, and all the raw material powders are analytical grade.

[0063] S22. The raw material powders are mixed and dissolved in anhydrous ethanol and ball-milled for 30 minutes at a rotation speed of 500 r / min.

[0064] S23. After ball milling, the mixture is placed in an oven and dried at 120° C. for 45 minutes to obtain a metallized mixed powder.

[0065] S3. Prepare an organic solvent.

[0066] Weigh 100 g of terpineol in a beaker, then weigh 6 g of ethyl cellulose and add them to the terpineol while stirring at 70° C. Stop heating and stirring after the cellulose is completely dissolved.

[0067] S4. Prepare metallization slurry.

[0068] 10 g of the organic solvent prepared in step S3 was weighed in a beaker, and then 40 g of the metal mixed powder prepared in step S2 was weighed and added to the organic solvent while being heated at 55° C. while stirring to uniformly disperse the powder to obtain a metallization slurry.

[0069] S5. Laser-assisted metallization sintering of alumina ceramic substrate.

[0070] The metallization slurry obtained in step S4 was manually applied with a brush to the 95% alumina ceramic substrate degreased in step S1. The substrate was then dried in an oven at 120°C for 60 minutes. After drying, the substrate was sintered using a continuous fiber laser at a power of 180W and a scanning speed of 500 mm / s. The laser-sintered ceramic substrate coated with the metallization slurry was then sintered in a high-temperature tube furnace at 1280°C for 90 minutes to produce the metallized ceramic product.

[0071] Example 2

[0072] A laser-assisted sintering molybdenum-manganese ceramic metallization method comprises the following steps:

[0073] S1. Pre-treating the ceramic substrate.

[0074] The prepared 95% alumina ceramic substrate was polished with 500-grit sandpaper for 15 minutes to increase the surface roughness of the ceramic plate. The polished 95% alumina ceramic substrate was then ultrasonically cleaned in 85% alcohol for 20 minutes to remove surface oil stains.

[0075] S2. Prepare metallized mixed powder.

[0076] S21, weigh 50g of molybdenum powder, 15g of manganese powder, 6g of NiO, 5g of SiO2, 3g of Al2O3, 8g of CuO, and 2g of Fe2O3. 50 ≤0.5μm. Particle size of molybdenum powder, manganese powder, NiO, Al2O3, CuO, Fe2O3 50 All the raw material powders are ≤1μm, and all the raw material powders are analytical grade.

[0077] S22. The raw material powders are mixed and dissolved in anhydrous ethanol and ball-milled for 30 minutes at a rotation speed of 500 r / min.

[0078] S23. After ball milling, the mixture is placed in an oven and dried at 120° C. for 45 min to obtain a metallized mixed powder.

[0079] S3. Prepare an organic solvent.

[0080] Weigh 100 g of terpineol in a beaker, then weigh 6 g of ethyl cellulose and add them to the terpineol while stirring at 70°C. Stop heating and stirring after the cellulose is completely dissolved.

[0081] S4. Prepare metallization slurry.

[0082] 10 g of the organic solvent prepared in step S3 was weighed in a beaker, and then 40 g of the metal mixed powder prepared in step S2 was weighed and added to the organic solvent while being heated at 55° C. while stirring to uniformly disperse the powder to obtain a metallization slurry.

[0083] S5. Laser-assisted metallization sintering of alumina ceramic substrate.

[0084] The metallization slurry obtained in step S4 was manually applied with a brush to the 95% alumina ceramic substrate degreased in step S1. The substrate was then dried in an oven at 120°C for 60 minutes. After drying, the substrate was sintered using a continuous fiber laser at a power of 230W and a scanning speed of 500 mm / s. The laser-sintered ceramic substrate coated with the metallization slurry was then sintered in a high-temperature tube furnace at 1280°C for 90 minutes to produce the metallized ceramic product.

[0085] Example 3

[0086] A laser-assisted sintering molybdenum-manganese ceramic metallization method comprises the following steps:

[0087] S1. Pre-treating the ceramic substrate.

[0088] The prepared 95% alumina ceramic substrate was polished with 500-grit sandpaper for 15 minutes to increase the surface roughness of the ceramic plate. The polished 95% alumina ceramic substrate was then ultrasonically cleaned in 85% alcohol for 20 minutes to remove surface oil stains.

[0089] S2. Prepare metallized mixed powder.

[0090] S21, weigh 50g of molybdenum powder, 15g of manganese powder, 6g of NiO, 5g of SiO2, 3g of Al2O3, 8g of CuO, and 2g of Fe2O3. 50 ≤0.5μm. Particle size of molybdenum powder, manganese powder, NiO, Al2O3, CuO, Fe2O3 50 All the raw material powders are ≤1μm, and all the raw material powders are analytical grade.

[0091] S22. The raw material powders are mixed and dissolved in anhydrous ethanol and ball-milled for 30 minutes at a rotation speed of 500 r / min.

[0092] S23. After ball milling, the mixture is placed in an oven and dried at 120° C. for 45 min to obtain a metallized mixed powder.

[0093] S3. Prepare an organic solvent.

[0094] Weigh 100 g of terpineol in a beaker, then weigh 6 g of ethyl cellulose and add them to the terpineol while stirring at 70°C. Stop heating and stirring after the cellulose is completely dissolved.

[0095] S4. Prepare metallization slurry.

[0096] 10 g of the organic solvent prepared in step S3 was weighed in a beaker, and then 40 g of the metal mixed powder prepared in step S2 was weighed and added to the organic solvent while being heated at 55° C. while stirring to uniformly disperse the powder to obtain a metallization slurry.

[0097] S5. Laser-assisted metallization sintering of alumina ceramic substrate.

[0098] The metallization slurry obtained in step S4 was manually applied with a brush to the 95% alumina ceramic substrate degreased in step S1. The substrate was then dried in an oven at 120°C for 60 minutes. After drying, the substrate was sintered using a continuous fiber laser at a power of 280W and a scanning speed of 500mm / s. The laser-sintered ceramic substrate coated with the metallization slurry was then sintered in a high-temperature tube furnace at 1280°C for 90 minutes to produce the metallized ceramic product.

[0099] Comparative Example 1

[0100] A method for metallizing alumina ceramics comprises the following steps:

[0101] S1. Pre-treating the ceramic substrate.

[0102] The prepared 95% alumina ceramic substrate was polished with 500-grit sandpaper for 15 minutes to increase the surface roughness of the ceramic plate. The polished 95% alumina ceramic substrate was then ultrasonically cleaned in 85% alcohol for 20 minutes to remove surface oil stains.

[0103] S2. Prepare metallized mixed powder.

[0104] S21, weigh 50g of molybdenum powder, 15g of manganese powder, 6g of NiO, 5g of SiO2, 3g of Al2O3, 8g of CuO, and 2g of Fe2O3. 50 ≤0.5μm. Particle size of molybdenum powder, manganese powder, NiO, Al2O3, CuO, Fe2O3 50 All the raw material powders are ≤1μm, and all the raw material powders are analytical grade.

[0105] S22. The raw material powders are mixed and dissolved in anhydrous ethanol and ball-milled for 30 minutes at a rotation speed of 500 r / min.

[0106] S23. After ball milling, the mixture is placed in an oven and dried at 120° C. for 45 min to obtain a metallized mixed powder.

[0107] S3. Prepare an organic solvent.

[0108] Weigh 100 g of terpineol in a beaker, then weigh 6 g of ethyl cellulose and add them to the terpineol while stirring at 70°C. Stop heating and stirring after the cellulose is completely dissolved.

[0109] S4. Prepare metallization slurry.

[0110] 10 g of the organic solvent prepared in step S3 was weighed in a beaker, and then 40 g of the metal mixed powder prepared in step S2 was weighed and added to the organic solvent while being heated at 55° C. while stirring to uniformly disperse the powder to obtain a metallization slurry.

[0111] S5. Direct metallization sintering of alumina ceramic substrate

[0112] The metallization slurry obtained in step S4 was manually applied to the 95% alumina ceramic substrate degreased in step S1 using a brush, and then dried in an oven at 120°C for 60 minutes. After drying, the ceramic substrate coated with the metal slurry was sintered in a high-temperature tube furnace at 1280°C for 90 minutes to obtain a metallized ceramic product.

[0113] The metallized ceramic products prepared in Example 1, Example 2, Example 3 and Comparative Example 1 were tested.

[0114] like Figure 2 、 Figure 3 、 Figure 4 、 Figure 5 As shown in FIG, the upper half of the layers are all metal layers, and the lower half are all alumina ceramic layers. It can be seen that in the cross-sectional microscopic SEM images of the metallized ceramic products prepared in Example 1, Example 2, and Example 3 after laser scanning, as shown in FIG. Figure 2 Middle (a), Figure 2 Middle (b), Figure 3 Middle (a), Figure 3 Middle (b), Figure 4 Middle (a), Figure 4 As shown in (b), the metal layer is relatively uniform and closely bonded to the ceramic substrate. Figure 5 Middle (a), Figure 5 As shown in (b), there is an obvious gap between the metal layer and the ceramic substrate, that is, the bonding strength between the two is poor. Therefore, it can be considered that laser-assisted processing has a certain positive effect on the ceramic metallization performance.

[0115] Therefore, the present invention adopts the above-mentioned laser-assisted sintering molybdenum-manganese method for ceramic metallization to solve the problems of high sintering temperature of alumina ceramic metallization and insufficient bonding strength between ceramic and metal sections.

[0116] Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention rather than to limit the same. Although the present invention has been described in detail with reference to the preferred embodiments, those skilled in the art should understand that they can still modify or replace the technical solutions of the present invention with equivalents, and these modifications or equivalent replacements cannot cause the modified technical solutions to deviate from the spirit and scope of the technical solutions of the present invention.

Claims

1. A laser-assisted sintering molybdenum-manganese ceramic metallization method, characterized in that: The following steps are involved: S1, pre-treating the ceramic substrate; The 95 alumina ceramic substrate was polished with sandpaper and then ultrasonically cleaned in alcohol for 10-30 minutes. S2, preparing metallized mixed powder; S21. Weigh raw material powders according to the mass percentages of molybdenum powder 40-65%, manganese powder 10-25%, NiO 5-28%, SiO2 1-10%, Al2O3 1-10%, CuO 1-20%, and Fe2O3 1-5%; S22, dispersing the weighed raw material powder into anhydrous ethanol and ball milling; S23, ball milling and drying to obtain a metallized mixed powder; S3, preparing an organic solvent; Weigh 95-98% terpineol and 2-5% ethyl cellulose by mass, and add the weighed ethyl cellulose to the terpineol under heating at 60-80° C. to dissolve the mixture, thereby obtaining an organic solvent; S4, preparing metallization slurry; Add the metallized mixed powder to the organic solvent in a mass ratio of metallized mixed powder to organic solvent = 4:1, heat at 45-60°C and stir thoroughly to obtain a metallized slurry; S5, laser-assisted metallization sintering of alumina ceramic substrate; The metallized slurry prepared in step S4 is evenly coated on the 95 alumina ceramic substrate pretreated in step S1, and then dried, subjected to laser sintering treatment with different powers, and sintered to obtain a metallized ceramic product.

2. The laser-assisted sintering molybdenum-manganese ceramic metallization method according to claim 1, characterized in that: In step S1, the mesh number of the sandpaper used for polishing is 400-1000 mesh; the volume fraction of ethanol in the alcohol is 60-80%.

3. The laser-assisted sintering molybdenum-manganese ceramic metallization method according to claim 1, characterized in that: In step S2, the particle size D of molybdenum powder, manganese powder, NiO, Al2O3, CuO, and Fe2O3 50 All ≤1μm; SiO2 powder particle size is D 50 ≤0.5μm.

4. The laser-assisted sintering molybdenum-manganese ceramic metallization method according to claim 1, characterized in that: In step S2, the ball milling time is 20-40 minutes, and the ball milling speed is 400-600 r / min; the temperature when drying the metallized mixed powder is 100-140° C., and the drying time is 30-50 minutes.

5. The laser-assisted sintering molybdenum-manganese ceramic metallization method according to claim 1, characterized in that: In step S3, the heating and dissolving time is 70 to 90 minutes.

6. The laser-assisted sintering molybdenum-manganese ceramic metallization method according to claim 1, characterized in that: In step S4, the metallization mixed powder should be added while stirring during the preparation of the metallization slurry.

7. The laser-assisted sintering molybdenum-manganese ceramic metallization method according to claim 1, characterized in that: In step S5, the metallization slurry is evenly coated manually using a brush; the drying temperature is 110-150° C., and the drying time is 40-70 minutes; the laser used in the laser sintering process is a fiber continuous laser.

8. The laser-assisted sintering molybdenum-manganese ceramic metallization method according to claim 7, characterized in that: The processing power of the laser is 150~380w; the sintering temperature of the 95 alumina ceramic substrate after laser sintering is controlled at 1250~1380℃, and the sintering holding time is 60~100min.

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