The invention relates to a combined passive sampler for collecting rainwater samples and extracting pollutants. The combined passive sampler structurally comprises an upper bottle body, a lower bottle body, a bottle cap, a sieve plate and a sharp opening, the bottle body is formed by connecting an upper bottle body and a lower bottle body in an involution and screwed mode, a bottle opening is formed in the top of the upper bottle body, and a sharp opening is formed in the lower portion of the upper bottle body; the bottle cap is formed by combining a sharp opening cover plate and a buoyancy cover plate through a soft connecting line. In the water sample bottle injection process, the bottle cap automatically ascends and is finally closed, sampling does not need to be finished manually, sample volatilization and inconsistency caused by untimely manual operation are avoided, sampling manpower is saved, and the uniformity of collected samples is improved; a sampling bottle adopts an upper and lower split combined structure, an upper bottle body is of an upper and lower opening structure and a sharp opening structure, gas exchange between the upper bottle body and the lower bottle body is performed through the opening structure of the upper bottle body, a specific sampling mode of 'upper water entry and lower extraction' can be realized, the step of later pretreatment of the samples is omitted, and the storage effect of the collected samples is improved; in the water sample collection process, two times of filtration are carried out at the upper bottle opening and the lower bottle opening of the upper bottle body, and the lower bottle opening can be connected with different solid-phase extraction small columns, so that the requirement for extracting various pollutants can be flexibly met, and the time for sample collection and pollutant extraction is saved.