Production process of bio-based waterproof moisture-permeable glove lining material

Abstract

The invention discloses a production process of a bio-based waterproof and moisture-permeable glove lining material, and belongs to the technical field of glove lining material production.The production process comprises the following steps that PP non-woven fabric and a bio-based fiber membrane are subjected to high-temperature hot-pressing compounding through a film laminating machine, and then the bio-based waterproof and moisture-permeable glove lining material is obtained through cooling shaping, cutting and sewing. The bio-based waterproof and moisture-permeable glove lining material prepared by the invention is formed by hot-pressing and compounding a PP non-woven fabric and a bio-based fiber membrane, in a double-layer composite structure, the bio-based fiber membrane on the outer layer is obtained by melt spinning, hydrophobic modification and weaving of a bio-based PA11 material, and the PP non-woven fabric and the bio-based fiber membrane on the outer layer are subjected to melt spinning, hydrophobic modification and weaving to form the bio-based waterproof and moisture-permeable glove lining material. The bio-based fiber membrane on the outer layer has a fine and uniform microporous structure, the pore size and distribution are uniform, and meanwhile, the prepared bio-based glove lining material has excellent waterproof, moisture permeable and antibacterial properties.

Description

Technical Field

[0001] The invention belongs to the technical field of glove lining material production, and specifically relates to a production process of a bio-based waterproof and breathable glove lining material. Background Art

[0002] In the research and development of bio-based polyamide materials (bio-based PA), commonly used renewable raw material resources include castor oil, oleic acid and linoleic acid, and glucose, etc. Among them, as the raw material of castor oil, castor beans are a fast-growing crop with a quarterly stem growth rate of up to 2m. They can be planted on barren land without competing with food crops for land. The yield of castor beans per hectare can reach about 10t, which is an excellent renewable raw material.

[0003] The technology of developing bio-based polyamide materials using castor oil is already very mature. For example, the bio-based PA610 developed by BASF uses 60% of sebacic acid from castor oil; the bio-based PA11 developed by Arkema uses castor beans as raw materials to produce 11-aminoundecanoic acid, which is polymerized in three stages to obtain poly-11-aminoundecanoic acid. According to the research and test results of the French Textile and Clothing Institute (IFTH), PA11 fibers and their fabrics have many characteristics, including high wear resistance, good chlorine resistance, good fiber flame retardancy and quick drying.

[0004] The present invention aims to apply bio-based PA11 materials to the field of waterproof and breathable glove lining materials, wherein the waterproof and breathable glove lining material refers to a glove lining material in which water does not penetrate into the glove lining material under a certain pressure, while the sweat emitted by the human body can be conducted to the outside world through the glove lining material in the form of water vapor. The waterproof and breathable glove lining material can prevent sweat from accumulating and condensing between the body surface and the glove lining material, thereby achieving the purpose of maintaining the comfort of clothing. It is a high-tech, unique functional glove lining material. The application of bio-based PA11 materials in the field of textile glove lining materials has positive application prospects. Summary of the invention

[0005] The purpose of the present invention is to provide an application method of bio-based PA11 material in the field of waterproof and breathable glove lining materials. At the same time, through the improvement of process methods and process parameters, as well as directional modification of materials, a production process of bio-based waterproof and breathable glove lining materials is finally formed.

[0006] The purpose of the present invention can be achieved through the following technical solutions:

[0007] A production process of a bio-based waterproof and breathable glove lining material, comprising the following steps:

[0008] The PP non-woven fabric and the bio-based fiber film are laminated by high-temperature hot pressing through a laminating machine, and then cooled, shaped, cut and sewn to obtain the bio-based waterproof and breathable glove lining material;

[0009] The bio-based fiber membrane is obtained by melt spinning of bio-based polyamide material to obtain bio-based fibers; the bio-based fibers are modified by sizing with a hydrophobic modified slurry and then plain weaving to obtain the bio-based fiber membrane.

[0010] Furthermore, the bio-based waterproof and breathable glove lining material is a two-layer composite structure or a three-layer composite structure; the two-layer composite structure is PP non-woven fabric + bio-based fiber membrane; the three-layer composite structure is PP non-woven fabric + bio-based fiber membrane + PP non-woven fabric.

[0011] Furthermore, the gram weight of the PP nonwoven fabric is 15-25 g / m 2 The bio-based fiber membrane has a gram weight of 15-25 g / m 2 .

[0012] Furthermore, the bio-based fiber membrane is prepared by the following steps:

[0013] Step S1: putting the dried pretreated bio-based polyamide into a spinning machine for melt spinning, the temperature range of the melt spinning machine is: the temperature of the first zone is a preheating temperature of 100-105°C, the temperature of the second zone is a compression temperature of 125-130°C, the temperature of the third zone is a compression temperature of 150-155°C, and the temperature of the fourth zone is an extrusion temperature of 185°C. The screw speed of the spinning machine is controlled to be 50rpm, the drafting speed is 10m / min, and the extrusion pressure is 2MPa. After the extrusion is completed, the bio-based fiber is obtained;

[0014] Step S2: Use hydrophobic modified slurry to size the bio-based fiber by high-pressure sizing, control the bio-based fiber delivery tension to 60-65mN, and the winding tension to 65-70mN. After slurrying, dry it in sections, the temperature of the first section is 136-138°C, the temperature of the second section is 130-132°C, the temperature of the third section is 98-110°C, and the temperature of the fourth section is 90-92°C. Control the sizing rate to ensure that the sizing rate is 4.8-5.2%. After sizing, plain weave is performed at a weaving speed of 520-550rpm / min. After weaving, place it at 70-80°C for shaping treatment. After treatment, a bio-based fiber membrane is obtained.

[0015] Furthermore, the preprocessing process in step S1 includes the following steps:

[0016] The bio-based polyamide material was placed in a vacuum oven at 60°C for drying pretreatment for 6 hours, taken out and cooled to room temperature for standby use.

[0017] Furthermore, in the melt spinning process in step S1, the outlet diameter of the melt spinning machine is 0.30 mm.

[0018] Furthermore, the bio-based polyamide material is bio-based PA11.

[0019] Furthermore, the hydrophobically modified slurry for high pressure sizing is prepared by the following steps:

[0020] Add 5-difluoromethoxy-2-mercapto-1H-benzimidazole to anhydrous ethanol, stir to dissolve, then add dichloromethane and vinyltrimethoxysilane, stir to mix, add initiator and catalyst, react under 30W ultraviolet light for 20 minutes to obtain a fluorine-containing silane solution, add polypropylene resin to the fluorine-containing silane solution, stir at high speed to obtain a hydrophobically modified slurry.

[0021] Furthermore, the usage ratio of anhydrous ethanol, 5-difluoromethoxy-2-mercapto-1H-benzimidazole, dichloromethane, vinyltrimethoxysilane, initiator, catalyst and polypropylene resin is 40mL: 0.22-0.23g: 60mL: 11.5-12.0mL: 0.02g: 0.01g: 3.1-3.2g.

[0022] Furthermore, the initiator is 2,2-dimethoxyphenylacetophenone; and the catalyst is triethylenetetramine.

[0023] Beneficial effects of the present invention:

[0024] (1) The bio-based waterproof and breathable glove lining material prepared by the present invention is formed by hot-pressing a PP non-woven fabric and a bio-based fiber film. In the double-layer composite structure, the bio-based fiber film is the outer layer and the PP non-woven fabric is the inner layer. The outer layer of the bio-based fiber film is obtained by melt spinning, hydrophobic modification and weaving of a bio-based PA11 material. The bio-based fiber film has a fine and uniform microporous structure, and the pore size and distribution are uniform. At the same time, the prepared bio-based glove lining material has excellent waterproof, breathable and antibacterial properties.

[0025] (2) The bio-based fiber membrane prepared by the present invention is modified by a hydrophobic modified slurry. The fluorinated silane solution in the hydrophobic modified slurry has good hydrophobicity. At the same time, the imidazole ring structure of the silane side chain in the fluorinated silane solution has excellent antibacterial properties, which helps to improve the antibacterial effect of the glove lining material. Then, the PP non-woven fabric of the inner layer of the bio-based fiber membrane is water-absorbent. After being made into the glove lining material, the outer bio-based fiber membrane has excellent waterproof properties. The inner PP non-woven fabric can absorb the heat and sweat generated by the human body, and then diffuse through the outer layer to promptly remove the excess heat and sweat generated by the human body during activities, maintain a relatively comfortable and suitable condition inside, and have excellent waterproof and breathable properties. In addition, the bio-based PA11 material is made of 100% castor oil bio-based. The present invention provides a modification and application direction of a bio-based PA11 material. BRIEF DESCRIPTION OF THE DRAWINGS

[0026] The present invention will be further described below in conjunction with the accompanying drawings.

[0027] Figure 1 It is a schematic diagram of the structure of finished gloves in which the lining material prepared in Example 7 of the present invention is applied to the production of bio-based waterproof and breathable gloves. DETAILED DESCRIPTION

[0028] The following will be combined with the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

[0029] Example 1

[0030] Preparation of hydrophobically modified slurry:

[0031] 0.22 g of 5-difluoromethoxy-2-mercapto-1H-benzimidazole was added to 40 mL of anhydrous ethanol, and after stirring to dissolve, 60 mL of dichloromethane and 11.5 mL of vinyltrimethoxysilane were added, and after stirring and mixing, 0.02 mL of initiator 2,2-dimethoxyphenylacetophenone (content 99%) and 0.01 mL of catalyst triethylenetetramine were added, and the mixture was reacted under 30 W ultraviolet light for 20 min to obtain a fluorine-containing silane solution. 3.1 g of polypropylene resin (purchased from ExxonMobil) was added to the fluorine-containing silane solution, and after high-speed stirring, a hydrophobically modified slurry was obtained.

[0032] Example 2

[0033] Preparation of hydrophobically modified slurry:

[0034] 0.23 g of 5-difluoromethoxy-2-mercapto-1H-benzimidazole was added to 40 mL of anhydrous ethanol, and after stirring to dissolve, 60 mL of dichloromethane and 11.8 mL of vinyltrimethoxysilane were added, and after stirring and mixing, 0.02 mL of initiator 2,2-dimethoxyphenylacetophenone (content 99%) and 0.01 mL of catalyst triethylenetetramine were added, and the mixture was reacted under 30 W ultraviolet light for 20 min to obtain a fluorine-containing silane solution. 3.2 g of polypropylene resin (purchased from ExxonMobil) was added to the fluorine-containing silane solution, and after high-speed stirring, a hydrophobically modified slurry was obtained.

[0035] Example 3

[0036] Preparation of hydrophobically modified slurry:

[0037] 0.23 g of 5-difluoromethoxy-2-mercapto-1H-benzimidazole was added to 40 mL of anhydrous ethanol, and after stirring to dissolve, 60 mL of dichloromethane and 12.0 mL of vinyltrimethoxysilane were added, and after stirring and mixing, 0.02 mL of initiator 2,2-dimethoxyphenylacetophenone (content 99%) and 0.01 mL of catalyst triethylenetetramine were added, and the mixture was reacted under 30 W ultraviolet light for 20 min to obtain a fluorine-containing silane solution. 3.2 g of polypropylene resin (purchased from ExxonMobil) was added to the fluorine-containing silane solution, and after high-speed stirring, a hydrophobically modified slurry was obtained.

[0038] Example 4

[0039] Preparation of bio-based fiber membranes:

[0040] Step S1: placing the bio-based polyamide material in a vacuum oven at 60°C for drying pretreatment for 6 hours, taking it out and cooling it to room temperature, and then putting the dried pretreated bio-based polyamide into a spinning machine for melt spinning. The outlet diameter of the melt spinning machine is 0.30 mm. The temperature range of the melt spinning machine is: the temperature of the first zone is a preheating temperature of 100°C, the temperature of the second zone is a compression temperature of 125°C, the temperature of the third zone is a compression temperature of 150°C, and the temperature of the fourth zone is an extrusion temperature of 185°C. The screw speed of the spinning machine is controlled to be 50 rpm, the drawing speed is 10 m / min, and the extrusion pressure is 2 MPa. After the extrusion is completed, the bio-based fiber is obtained;

[0041] Step S2: Using the hydrophobic modified slurry prepared in Example 1, the bio-based fiber is sized by high-pressure sizing. The feeding tension of the bio-based fiber is controlled to be 60mN, and the winding tension is 65mN. After slurrying, it is dried in sections. The temperature of the first section is 136°C, the temperature of the second section is 130°C, the temperature of the third section is 98°C, and the temperature of the fourth section is 90°C. The sizing rate is controlled to ensure that the sizing rate is 5.2%. After sizing, plain weaving is performed at a weaving speed of 520rpm / min. After weaving, it is placed at 70°C for shaping treatment. After treatment, a bio-based fiber membrane is obtained. After testing, the gram weight of the bio-based fiber membrane is 15g / m 2 .

[0042] Example 5

[0043] Preparation of bio-based fiber membranes:

[0044] Step S1: placing the bio-based polyamide material in a vacuum oven at 60°C for drying pretreatment for 6 hours, taking it out and cooling it to room temperature, and then putting the dried pretreated bio-based polyamide into a spinning machine for melt spinning. The outlet diameter of the melt spinning machine is 0.30 mm. The temperature range of the melt spinning machine is: the temperature of the first zone is a preheating temperature of 102°C, the temperature of the second zone is a compression temperature of 128°C, the temperature of the third zone is a compression temperature of 154°C, and the temperature of the fourth zone is an extrusion temperature of 185°C. The screw speed of the spinning machine is controlled to be 50 rpm, the drawing speed is 10 m / min, and the extrusion pressure is 2 MPa. After the extrusion is completed, the bio-based fiber is obtained;

[0045] Step S2: The hydrophobic modified slurry prepared in Example 2 is used to size the bio-based fiber by high-pressure sizing. The feeding tension of the bio-based fiber is controlled to be 64mN, and the winding tension is 67mN. After the slurry is discharged, it is dried in sections. The temperature of the first section is 137°C, the temperature of the second section is 131°C, the temperature of the third section is 105°C, and the temperature of the fourth section is 91°C. The sizing rate is controlled to ensure that the sizing rate is 4.9%. After sizing, plain weaving is performed at a weaving speed of 540rpm / min. After weaving, it is placed at 75°C for shaping treatment. After the treatment, a bio-based fiber membrane is obtained. After testing, the gram weight of the bio-based fiber membrane is 20g / m 2 .

[0046] Example 6

[0047] Preparation of bio-based fiber membranes:

[0048] Step S1: placing the bio-based polyamide material in a vacuum oven at 60°C for drying pretreatment for 6 hours, taking it out and cooling it to room temperature, and then putting the dried pretreated bio-based polyamide into a spinning machine for melt spinning. The outlet diameter of the melt spinning machine is 0.30 mm. The temperature range of the melt spinning machine is: the temperature of the first zone is a preheating temperature of 105°C, the temperature of the second zone is a compression temperature of 130°C, the temperature of the third zone is a compression temperature of 155°C, and the temperature of the fourth zone is an extrusion temperature of 185°C. The screw speed of the spinning machine is controlled to be 50 rpm, the drawing speed is 10 m / min, and the extrusion pressure is 2 MPa. After the extrusion is completed, the bio-based fiber is obtained;

[0049] Step S2: The hydrophobic modified slurry prepared in Example 3 is used to size the bio-based fiber by high-pressure sizing. The feeding tension of the bio-based fiber is controlled to be 65mN, and the winding tension is 70mN. After the slurry is discharged, it is dried in sections. The temperature of the first section is 138°C, the temperature of the second section is 132°C, the temperature of the third section is 110°C, and the temperature of the fourth section is 92°C. The sizing rate is controlled to ensure that the sizing rate is 5.2%. After sizing, plain weaving is performed at a weaving speed of 520rpm / min. After weaving, it is placed at 80°C for shaping treatment. After the treatment is completed, a bio-based fiber membrane is obtained. After testing, the gram weight of the bio-based fiber membrane is 25g / m 2 .

[0050] Example 7

[0051] A production process of a bio-based waterproof and breathable glove lining material, comprising the following steps:

[0052] The PP non-woven fabric (weight 15g / m 2 ) and one side of the bio-based fiber membrane prepared in Example 4 are laminated by high temperature hot pressing, and then cooled, shaped, cut and sewn to obtain a bio-based waterproof and breathable glove lining material, wherein the non-woven fabric side is the inner side and the bio-based fiber membrane side is the outer side, and finally a bio-based waterproof and breathable glove can be produced, and the glove structure is as shown in the attached Figure 1 as shown in .

[0053] Example 8

[0054] A production process of a bio-based waterproof and breathable glove lining material, comprising the following steps:

[0055] The PP non-woven fabric (weight 20g / m 2 ) is hot-pressed and composited with one side of the bio-based fiber membrane prepared in Example 5, and then cooled, shaped, cut and sewn to obtain a bio-based waterproof and breathable glove lining material, wherein the non-woven fabric side is the inner side and the bio-based fiber membrane side is the outer side.

[0056] Example 9

[0057] A production process of a bio-based waterproof and breathable glove lining material, comprising the following steps:

[0058] The PP non-woven fabric (weight 25g / m 2 ) is hot-pressed and composited with one side of the bio-based fiber membrane prepared in Example 6, and then cooled, shaped, cut and sewn to obtain a bio-based waterproof and breathable glove lining material, wherein the non-woven fabric side is the inner side and the bio-based fiber membrane side is the outer side.

[0059] Example 10

[0060] A production process of a bio-based waterproof and breathable glove lining material, comprising the following steps:

[0061] Two layers of PP nonwoven fabric (weight 15g / m 2 ) are respectively hot-pressed and laminated with both sides of the bio-based fiber membrane prepared in Example 4, and then cooled, shaped, cut and sewn to obtain a bio-based waterproof and breathable glove lining material.

[0062] Embodiment 11

[0063] A production process of a bio-based waterproof and breathable glove lining material, comprising the following steps:

[0064] Two layers of PP nonwoven fabric (weight 20g / m 2 ) are respectively hot-pressed and laminated with both sides of the bio-based fiber membrane prepared in Example 5, and then cooled, shaped, cut and sewn to obtain a bio-based waterproof and breathable glove lining material.

[0065] Example 12

[0066] A production process of a bio-based waterproof and breathable glove lining material, comprising the following steps:

[0067] Through the laminating machine, two layers of PP non-woven fabric (weight 25g / m 2 ) are respectively hot-pressed and laminated with both sides of the bio-based fiber membrane prepared in Example 6, and then cooled, shaped, cut and sewn to obtain a bio-based waterproof and breathable glove lining material.

[0068] Comparative Example 1

[0069] Comparative Example 1 is the control group of Example 8.

[0070] First, a bio-based fiber membrane is prepared: the hydrophobically modified slurry prepared in Example 2 in step S2 of Example 5 is replaced with polyvinyl alcohol (PVA; viscosity: 45.0-55.0 mPa*s; Mw about 45000), and the other raw materials and preparation methods remain unchanged, and finally, a bio-based fiber membrane is obtained;

[0071] Then, a production process of a bio-based waterproof and breathable glove lining material comprises the following steps:

[0072] The PP non-woven fabric is hot-pressed with one side of the prepared bio-based fiber membrane by a laminating machine, and then cooled, shaped, cut and sewn to obtain a bio-based waterproof and breathable glove lining material, wherein the non-woven fabric side is the inner side and the bio-based fiber membrane side is the outer side.

[0073] Embodiment 13

[0074] The pore size of the bio-based fiber membranes in Examples 7 to 9 and Comparative Example 1 was tested. Then, the moisture permeability, air permeability and antibacterial performance of the bio-based waterproof and breathable glove lining materials prepared in Examples 7 to 9 and Comparative Example 1 were tested. The test results are shown in Table 1. Specifically:

[0075] Pore ​​size determination: The gas permeation bubble point method was used to test the pore size and distribution of the bio-based fiber membrane;

[0076] The moisture permeability shall comply with GB / T 12704-2009 “Test method for moisture permeability of textile fabrics”;

[0077] The air permeability performance is in accordance with GB / T 5453-1997 "Determination of air permeability of textile fabrics";

[0078] The surface water repellency shall comply with GB / T 4745-2012 “Testing and evaluating the water repellency of textiles - Water-repellent method”;

[0079] The antibacterial properties are in accordance with GB / T 20944.1-2007 “Evaluation of antibacterial properties of textiles Part 1: Agar plate diffusion method”.

[0080] Table 1

[0081]

[0082]

[0083] It can be seen from Table 1 that the bio-based fiber membrane prepared by the present invention has a fine and uniform microporous structure, and the pore size and distribution are uniform. At the same time, the prepared bio-based glove lining material has excellent waterproof, moisture permeability and antibacterial properties.

[0084] It should be noted that, in this article, terms such as "comprises", "includes" or any other variations thereof are intended to cover non-exclusive inclusion, so that a process, method, article or apparatus that includes a series of elements includes not only those elements, but also other elements not explicitly listed, or also includes elements inherent to such process, method, article or apparatus.

[0085] Although embodiments of the present invention have been shown and described, it will be appreciated by those skilled in the art that various changes, modifications, substitutions and variations may be made to the embodiments without departing from the principles and spirit of the invention, and the scope of the invention is defined by the appended claims and their equivalents.

Claims

1. A production process for bio-based waterproof and breathable glove lining materials, It is characterized in that The following steps are involved: The PP non-woven fabric and the bio-based fiber film are laminated by high-temperature hot pressing through a laminating machine, and then cooled, shaped, cut and sewn to obtain the bio-based waterproof and breathable glove lining material; The bio-based fiber membrane is obtained by melt spinning a bio-based polyamide material to obtain a bio-based fiber; The bio-based fiber is modified by sizing with a hydrophobic modified slurry and then plain woven to obtain a bio-based fiber membrane.

2. The production process of a bio-based waterproof and breathable glove lining material according to claim 1, It is characterized in that The bio-based waterproof and breathable glove lining material is a two-layer composite structure or a three-layer composite structure; the two-layer composite structure is PP non-woven fabric + bio-based fiber membrane; the three-layer composite structure is PP non-woven fabric + bio-based fiber membrane + PP non-woven fabric.

3. The production process of a bio-based waterproof and breathable glove lining material according to claim 1, It is characterized in that The gram weight of the PP nonwoven fabric is 15-25g / m 2 The bio-based fiber membrane has a gram weight of 15-25 g / m 2 .

4. The production process of a bio-based waterproof and breathable glove lining material according to claim 1, It is characterized in that The bio-based fiber membrane is prepared by the following steps: Step S1: putting the dried pretreated bio-based polyamide into a spinning machine for melt spinning, the temperature range of the melt spinning machine is: the temperature of the first zone is a preheating temperature of 100-105°C, the temperature of the second zone is a compression temperature of 125-130°C, the temperature of the third zone is a compression temperature of 150-155°C, and the temperature of the fourth zone is an extrusion temperature of 185°C. The screw speed of the spinning machine is controlled to be 50rpm, the drafting speed is 10m / min, and the extrusion pressure is 2MPa. After the extrusion is completed, the bio-based fiber is obtained; Step S2: Use hydrophobic modified slurry to size the bio-based fiber by high-pressure sizing, control the bio-based fiber delivery tension to 60-65mN, and the winding tension to 65-70mN. After slurrying, dry it in sections, the temperature of the first section is 136-138°C, the temperature of the second section is 130-132°C, the temperature of the third section is 98-110°C, and the temperature of the fourth section is 90-92°C. Control the sizing rate to ensure that the sizing rate is 4.8-5.2%. After sizing, plain weave is performed at a weaving speed of 520-550rpm / min. After weaving, place it at 70-80°C for shaping treatment. After treatment, a bio-based fiber membrane is obtained.

5. The production process of a bio-based waterproof and breathable glove lining material according to claim 4, It is characterized in that The pre-processing process in step S1 includes the following steps: The bio-based polyamide material was placed in a vacuum oven at 60°C for drying pretreatment for 6 hours, taken out and cooled to room temperature for standby use.

6. The production process of a bio-based waterproof and breathable glove lining material according to claim 4, It is characterized in that The outlet diameter of the melt spinning machine during the melt spinning process in step S1 is 0.30 mm.

7. The production process of a bio-based waterproof and breathable glove lining material according to claim 4, It is characterized in that The bio-based polyamide material is bio-based PA11.

8. The production process of a bio-based waterproof and breathable glove lining material according to claim 4, It is characterized in that The hydrophobically modified slurry for high pressure sizing is prepared by the following steps: Add 5-difluoromethoxy-2-mercapto-1H-benzimidazole to anhydrous ethanol, stir to dissolve, then add dichloromethane and vinyltrimethoxysilane, stir to mix, add initiator and catalyst, react under 30W ultraviolet light for 20 minutes to obtain a fluorine-containing silane solution, add polypropylene resin to the fluorine-containing silane solution, stir at high speed to obtain a hydrophobically modified slurry.

9. The production process of a bio-based waterproof and breathable glove lining material according to claim 8, It is characterized in that The usage ratio of anhydrous ethanol, 5-difluoromethoxy-2-mercapto-1H-benzimidazole, dichloromethane, vinyltrimethoxysilane, initiator, catalyst and polypropylene resin is 40mL:0.22-0.23g:60mL:11.5-12.0mL:0.02mL:0.01mL:3.1-3.2g.

10. The production process of a bio-based waterproof and breathable glove lining material according to claim 8, It is characterized in that The initiator is 2,2-dimethoxyphenylacetophenone; and the catalyst is triethylenetetramine.

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