Epoxy-based alkene and alkene ether modified rosin phenol resin

Abstract

The invention discloses epoxy-based alkene and alkene ether modified rosin phenol resin and a preparation method thereof. The preparation method comprises the following steps: reacting a phenol-sourced reagent and rosin under the acid catalyzing condition to prepare rosin phenol resin acid; adding 100 weight parts of the rosin phenol resin acid prepared in S1 into a solvent B, and heating to 50-150 DEG C; melting the rosin phenol resin, adding 0.2-6 weight parts of an organic alkali ammonium catalyst; dropwise adding epoxy-based alkene and alkene ether raw materials for 0.5-1 hour, regulatingthe temperature to 50-180 DEG C, and stopping reacting when the acid value of the product is not more than 6mg KOH / g; supplementing a solvent B after the reaction is stopped, and adding acid to neutralize the organic alkali ammonium catalyst; rinsing to obtain substrate, and distilling the substrate at reduced pressure at 50-180 DEG C to obtain epoxy-based alkene and alkene ether modified rosin phenol resin. The epoxy-based alkene and alkene ether modified rosin phenol resin have the characteristics of high reaction activity and good tackifying effect.

Description

technical field

[0001] The invention belongs to the field of deep processing of rosin, and in particular relates to an epoxy olefin and olefin ether modified rosin phenol resin and a preparation method thereof. Background technique

[0002] With the increasing improvement of global human science and technology life, it will become an inevitable trend of sustainable development for people to look for non-polluting and renewable resources that can replace petrochemicals between resource acquisition and environmental protection. Therefore, the green and recyclable biomass rosin Materials are reprocessed into various polymer materials, which have a wide range of applications due to their special chemical and physical properties. Rosin has the advantages of large output, green and environmental harmony, renewable, biodegradable, etc., and it contains a stable triple ring rigid structure, so it has the potential to replace petrochemical aromatic ring raw materials to prepare funct...

Examples

Embodiment 1

[0023] A preparation method of epoxy olefin and olefin ether modified rosin phenol resin, comprising the following steps:

[0024] S1. In parts by weight, add 100 parts of rosin to solvent A, then heat up to 210°C, add 25 parts of phenol source reagent after the rosin melts, then add 11 parts of acid catalyst, neutralize the acid catalyst after 10 hours of reaction, and then Adjust the temperature to 220° C. to obtain rosinol resin acid by distillation under reduced pressure, and recycle the obtained solvent A after cooling and separating, and the solvent A is toluene;

[0025] S2. In parts by weight, add 100 parts of rosin phenol resin acid prepared in S1 to solvent B, then heat up to 120°C, add 3 parts of organic alkali ammonium catalyst after melting the rosin phenol resin acid, and then dropwise add epoxy base olefin and alkene ether raw materials, the time for adding drops is 0.8h, then adjust the temperature to 110°C, and stop the reaction until the acid value of the pro...

Embodiment 2

[0035] A preparation method of epoxy olefin and olefin ether modified rosin phenol resin, comprising the following steps:

[0036] S1. In parts by weight, add 100 parts of rosin to solvent A, then heat up to 230°C, add 3 parts of phenol source reagent after the rosin melts, then add 0.2 parts of acid catalyst, neutralize the acid catalyst after reacting for 6 hours, and then The temperature is adjusted to 120 DEG C and distilled under reduced pressure to obtain rosinol resin acid, and the solvent A obtained by the reduced pressure distillation is recycled after cooling and separation. The solvent A is a mixture of methyl ethyl ketone, methyl isobutyl ketone and propyl acetate, and its weight The ratio is 2:4:3;

[0037] S2. In parts by weight, add 100 parts of rosin phenol resin acid prepared in S1 to solvent B, then heat up to 150°C, add 0.9 parts of organic alkali ammonium catalyst after melting the rosin phenol resin acid, and then dropwise add epoxy base olefin and alkene...

Embodiment 3

[0047] A preparation method of epoxy olefin and olefin ether modified rosin phenol resin, comprising the following steps:

[0048] S1. In parts by weight, add 100 parts of rosin to solvent A, then heat up to 50°C, add 30 parts of phenol source reagent after the rosin melts, then add 12 parts of acid catalyst, neutralize the acid catalyst after 2 hours of reaction, and then Adjust the temperature to 160° C. to obtain rosinol resin acid by distillation under reduced pressure, and recycle the solvent A obtained by the distillation under reduced pressure after cooling and separation, and the solvent A is 120# solvent gasoline;

[0049] S2. In parts by weight, add 100 parts of rosin phenol resin acid prepared in S1 to solvent B, then heat up to 50°C, add 0.2 parts of organic alkali ammonium catalyst after melting the rosin phenol resin acid, and then dropwise add epoxy Base olefin and olefin ether raw materials, the time for adding drops is 0.5h, then adjust the temperature to 180°...

technical field

[0001] The invention belongs to the field of deep processing of rosin, and in particular relates to an epoxy olefin and olefin ether modified rosin phenol resin and a preparation method thereof. Background technique

[0002] With the increasing improvement of global human science and technology life, it will become an inevitable trend of sustainable development for people to look for non-polluting and renewable resources that can replace petrochemicals between resource acquisition and environmental protection. Therefore, the green and recyclable biomass rosin Materials are reprocessed into various polymer materials, which have a wide range of applications due to their special chemical and physical properties. Rosin has the advantages of large output, green and environmental harmony, renewable, biodegradable, etc., and it contains a stable triple ring rigid structure, so it has the potential to replace petrochemical aromatic ring raw materials to prepare funct...

Examples

Embodiment 1

[0023] A preparation method of epoxy olefin and olefin ether modified rosin phenol resin, comprising the following steps:

[0024] S1. In parts by weight, add 100 parts of rosin to solvent A, then heat up to 210°C, add 25 parts of phenol source reagent after the rosin melts, then add 11 parts of acid catalyst, neutralize the acid catalyst after 10 hours of reaction, and then Adjust the temperature to 220° C. to obtain rosinol resin acid by distillation under reduced pressure, and recycle the obtained solvent A after cooling and separating, and the solvent A is toluene;

[0025] S2. In parts by weight, add 100 parts of rosin phenol resin acid prepared in S1 to solvent B, then heat up to 120°C, add 3 parts of organic alkali ammonium catalyst after melting the rosin phenol resin acid, and then dropwise add epoxy base olefin and alkene ether raw materials, the time for adding drops is 0.8h, then adjust the temperature to 110°C, and stop the reaction until the acid value of the pro...

Embodiment 2

[0035] A preparation method of epoxy olefin and olefin ether modified rosin phenol resin, comprising the following steps:

[0036] S1. In parts by weight, add 100 parts of rosin to solvent A, then heat up to 230°C, add 3 parts of phenol source reagent after the rosin melts, then add 0.2 parts of acid catalyst, neutralize the acid catalyst after reacting for 6 hours, and then The temperature is adjusted to 120 DEG C and distilled under reduced pressure to obtain rosinol resin acid, and the solvent A obtained by the reduced pressure distillation is recycled after cooling and separation. The solvent A is a mixture of methyl ethyl ketone, methyl isobutyl ketone and propyl acetate, and its weight The ratio is 2:4:3;

[0037] S2. In parts by weight, add 100 parts of rosin phenol resin acid prepared in S1 to solvent B, then heat up to 150°C, add 0.9 parts of organic alkali ammonium catalyst after melting the rosin phenol resin acid, and then dropwise add epoxy base olefin and alkene...

Embodiment 3

[0047] A preparation method of epoxy olefin and olefin ether modified rosin phenol resin, comprising the following steps:

[0048] S1. In parts by weight, add 100 parts of rosin to solvent A, then heat up to 50°C, add 30 parts of phenol source reagent after the rosin melts, then add 12 parts of acid catalyst, neutralize the acid catalyst after 2 hours of reaction, and then Adjust the temperature to 160° C. to obtain rosinol resin acid by distillation under reduced pressure, and recycle the solvent A obtained by the distillation under reduced pressure after cooling and separation, and the solvent A is 120# solvent gasoline;

[0049] S2. In parts by weight, add 100 parts of rosin phenol resin acid prepared in S1 to solvent B, then heat up to 50°C, add 0.2 parts of organic alkali ammonium catalyst after melting the rosin phenol resin acid, and then dropwise add epoxy Base olefin and olefin ether raw materials, the time for adding drops is 0.5h, then adjust the temperature to 180°...

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