Catalyst for preparing methylacrolein through oxidation of isobutene and preparation and application of catalyst

Abstract

The invention relates to a preparation method of a catalyst for preparing methylacrolein through oxidation of isobutene. The preparation method comprises the following steps: fully mixing a precursor solution of molybdenum, bismuth, cobalt, nickel, iron, manganese and alkaline metal with a carrier 1 to form slurry, fully mixing the obtained mixed slurry with a carrier 2, and roasting to obtain a core-shell morphology catalyst. The catalyst with the morphology solves the technical problems of local overheating of the catalyst, sublimation loss of the active component Mo and deep oxidation in the oxidation process, and meanwhile, the catalyst with the morphology has good mechanical strength, good hydrothermal stability, high selectivity to products and good industrial application value.

Description

technical field

[0001] The present invention relates to a preparation method for the preparation of methacrolein catalyst for the oxidation of isobutene, in particular to the method of fully mixing the precursor solution of molybdenum, bismuth, cobalt, nickel, iron, manganese and basic metal with the carrier 1 to form a slurry , and then fully mixed the obtained mixed slurry with the carrier 2 and then roasted to obtain a catalyst with a core-shell morphology. Background technique

[0002] Methacrolein (MAL) is an important intermediate for the synthesis of methacrylic acid (MAA) and methyl methacrylate (MMA), and is also an important fine chemical intermediate for the synthesis of pharmaceuticals and pesticides. Isobutene oxidation to MAL is a key step in the preparation of MAA and MMA (referred to as isobutene oxidation). Compared with the traditional ACH method, the isobutene oxidation method for the preparation of MAA has better technical and economical efficiency. This ...

Examples

Embodiment 1

[0020] 1.4g ammonium molybdate was dissolved in 8.0g water to obtain solution A;

[0021] 0.5g bismuth nitrate, 0.3g iron nitrate, 1.6g cobalt nitrate, 0.01g nickel nitrate, 0.05g cesium nitrate, 0.01g potassium nitrate were dissolved in 2.0g 10wt% nitric acid aqueous solution to obtain solution B;

[0022] 40g of alumina and 50g of water were evenly stirred at 45°C to obtain solution C.

[0023] Add solution B and solution A to solution C at the same time, stir evenly to obtain solution D.

[0024] Solution D and 6 g of spherical silica were stirred and mixed uniformly to obtain solution E.

[0025] Stir and age solution E for 0.1-24 hours, dry at 90-110°C for 3-24 hours, and dry at 180-300°C for 3-6 hours to obtain a solid powder, then roast the solid powder at 500°C for 3.5 hours, and analyze it by scanning electron microscope and BET specific surface area , to obtain a specific surface area of ​​122m 3 / g of core-shell catalysts.

[0026] Take 1ml of core-shell catalys...

technical field

[0001] The present invention relates to a preparation method for the preparation of methacrolein catalyst for the oxidation of isobutene, in particular to the method of fully mixing the precursor solution of molybdenum, bismuth, cobalt, nickel, iron, manganese and basic metal with the carrier 1 to form a slurry , and then fully mixed the obtained mixed slurry with the carrier 2 and then roasted to obtain a catalyst with a core-shell morphology. Background technique

[0002] Methacrolein (MAL) is an important intermediate for the synthesis of methacrylic acid (MAA) and methyl methacrylate (MMA), and is also an important fine chemical intermediate for the synthesis of pharmaceuticals and pesticides. Isobutene oxidation to MAL is a key step in the preparation of MAA and MMA (referred to as isobutene oxidation). Compared with the traditional ACH method, the isobutene oxidation method for the preparation of MAA has better technical and economical efficiency. This ...

Examples

Embodiment 1

[0020] 1.4g ammonium molybdate was dissolved in 8.0g water to obtain solution A;

[0021] 0.5g bismuth nitrate, 0.3g iron nitrate, 1.6g cobalt nitrate, 0.01g nickel nitrate, 0.05g cesium nitrate, 0.01g potassium nitrate were dissolved in 2.0g 10wt% nitric acid aqueous solution to obtain solution B;

[0022] 40g of alumina and 50g of water were evenly stirred at 45°C to obtain solution C.

[0023] Add solution B and solution A to solution C at the same time, stir evenly to obtain solution D.

[0024] Solution D and 6 g of spherical silica were stirred and mixed uniformly to obtain solution E.

[0025] Stir and age solution E for 0.1-24 hours, dry at 90-110°C for 3-24 hours, and dry at 180-300°C for 3-6 hours to obtain a solid powder, then roast the solid powder at 500°C for 3.5 hours, and analyze it by scanning electron microscope and BET specific surface area , to obtain a specific surface area of ​​122m 3 / g of core-shell catalysts.

[0026] Take 1ml of core-shell catalys...