Surface treatment method for copper foil

By immersing and drying the copper foil in a surface treatment solution, the surface roughness of the copper foil is controlled within the range of 0.8-2.8 μm. This solves the problem of performance degradation of lithium-ion secondary batteries caused by uneven surface roughness of copper foil, and improves the bonding strength between the copper foil and the negative electrode coating and the uniformity of the battery.

CN117758242BActive Publication Date: 2026-04-07HUIZHOU EVE UNITED ENERGY CO LTD
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Patent Information

Application Number
CN202311591952.0
Authority / Receiving Office
CN · China
Patent Type
Patents(China)
Current Assignee / Owner
Filing Date
2023-11-24
Publication Date
2026-04-07
Estimated Expiration
2043-11-24

AI Technical Summary

Technical Problem

In the prior art, the uneven surface roughness of the copper foil leads to a decrease in the charging and discharging efficiency of lithium-ion secondary batteries and inconsistent bonding strength of the negative electrode coating, which in turn accelerates the capacity decay of the battery.

Method used

A roughening treatment solution using deionized water as the main solvent, containing copper trifluoroacetate hydrate and peracetic acid, is used to improve the surface roughness of copper foil to the range of 0.8-2.8 μm through soaking and drying, while controlling the roughness difference between the two sides to within 0.1 μm. This increases the specific surface area and active sites of the copper foil, thereby enhancing its adhesion.

Benefits of technology

It effectively improves the bonding strength between copper foil and negative electrode coating, reduces the probability of coating peeling, uniformizes battery performance, and extends battery life.

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Abstract

The present application relates to a kind of surface treatment methods of copper foil, comprising the following steps: step one, preparation roughing treatment solution, roughing treatment solution uses deionized water as main solvent, and roughing treatment solution includes mass fraction 0.2wt%-1.0wt% copper trifluoroacetate hydrate and mass fraction 5wt%-10wt% peracetic acid;Step two, copper foil is placed in roughing treatment solution and soaked for 60-300s;Step three, after using deionized water to clean the surface of copper foil, dry processing is carried out.
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