Polypropylene composite plastic for logistics packaging box and production method thereof

Abstract

The invention discloses a polypropylene composite plastic for logistics packaging box and a production method thereof, and belongs to the field of logistics packaging technology. The invention comprises the following raw materials in parts by weight: 90-110 parts of polypropylene resin, 10-20 parts of modified carbon nanotubes, 0.2-0.5 parts of initiator, 6-10 parts of antioxidant, 4-6 parts of nucleating agent, and 6-8 parts of azodicarbonamide. The invention uses polypropylene as a matrix, and the composite plastic prepared by chemical foaming is endowed with excellent buffering performance and mechanical properties; wherein the modified carbon nanotubes not only give the composite plastic extremely strong antistatic properties, but also give the composite plastic significant flame retardant properties, and the performance is stable; therefore, the composite plastic prepared by the invention has stable and efficient mechanical properties, antistatic properties and flame retardant and smoke suppression properties, and the performance is long-term and stable, halogen-free and environmentally friendly, and has important application value in the field of logistics packaging technology.

Description

Technical Field

[0001] The invention belongs to the technical field of logistics packaging, and in particular, relates to a polypropylene composite plastic for a logistics packaging box and a production method thereof. Background Art

[0002] In recent years, more and more people choose to buy goods online, which has accelerated the rapid development of logistics and e-commerce industries. With the development of e-commerce, the number of express parcels has increased year by year. When transporting some fragile goods, especially the packaging and transportation of glass lamps, the packaging and transportation of spherical lamps have higher requirements for packaging boxes, and they need to be filled with plastic foam materials. Plastic foam materials are plastics with countless micropores in the whole body. Using different resins and foaming methods, plastic foam materials with different properties can be produced, which can play a role in heat insulation, sound absorption, shockproof, etc., and can protect goods from damage during transportation.

[0003] Made from polypropylene, EPP (Expanded polypropylene) is the abbreviation of a new type of foam plastic. EPP is a polypropylene plastic foam material, a high-crystalline polymer / gas composite material with excellent performance, good thermal stability (maximum operating temperature of 130°C), high toughness, tensile strength, impact strength and excellent microwave adaptability, and environmentally friendly. Due to its superior performance, it has become the fastest growing new environmentally friendly compression-resistant buffer insulation material and a good substitute for polystyrene (PS) foam plastics and polyurethane (PU) foam plastics.

[0004] Polypropylene material itself has a low oxygen index, and it is easier to ignite after being made into foamed material. It will burn quickly when encountering open flames, endangering people's lives and property safety, and posing a great safety hazard. In addition, when filling, polypropylene foam material is difficult to fit 100% with the goods, resulting in friction during transportation, causing static electricity, and even fire. Therefore, the above problems need to be solved to meet the higher demand for polypropylene foam materials in the field of logistics packaging. Summary of the invention

[0005] The purpose of the present invention is to overcome the defects of the prior art and provide a polypropylene composite plastic for a logistics packaging box and a production method thereof.

[0006] The purpose of the present invention can be achieved by the following technical solutions:

[0007] A method for producing polypropylene composite plastic for logistics packaging boxes comprises the following steps:

[0008] The polypropylene resin, modified carbon nanotubes, initiator, antioxidant, nucleating agent and azodicarbonamide (foaming agent) are mixed, added into a high-speed mixer and stirred for 3 hours, poured into a twin-screw extruder, melt blended, extruded and foamed to obtain a polypropylene composite plastic for logistics packaging boxes.

[0009] Furthermore, the raw materials are calculated in parts by weight as follows: 90-110 parts of polypropylene resin, 10-20 parts of modified carbon nanotubes, 0.2-0.5 parts of initiator, 6-10 parts of antioxidant, 4-6 parts of nucleating agent, and 6-8 parts of azodicarbonamide.

[0010] Furthermore, the antioxidant is one of antioxidant 1010 and antioxidant 264.

[0011] Furthermore, the initiator is one of benzoyl peroxide and lauroyl peroxide.

[0012] Furthermore, the nucleating agent is one of calcium oxide and magnesium oxide.

[0013] The prepared plastic is based on polypropylene resin, and through chemical foaming, the plastic is given excellent cushioning, thermal insulation and mechanical properties; the addition of nucleating agent accelerates the crystallization rate, shortens the processing cycle, and further improves the mechanical properties of the plastic.

[0014] Furthermore, the modified carbon nanotubes are prepared by the following steps:

[0015] S1. Add boric acid, diethanolamine and toluene to a four-necked flask equipped with a thermometer, a stirrer, a water separator and a spherical condenser, stir and mix evenly, heat to boiling state, until liquid separates in the water separator, control the reaction temperature to 120°C, and keep the reaction warm until the amount of water in the water separator no longer increases, continue the reaction for 30 minutes, the reaction is completed, stand and separate, the upper layer is colorless and transparent toluene, the lower layer is light yellow transparent viscous liquid, filter, take the lower layer of liquid, add tetrahydrofuran to remove unreacted diethanolamine, distill under reduced pressure to remove residual tetrahydrofuran and toluene, and dry in vacuo to obtain intermediate 1; the ratio of boric acid, diethanolamine, toluene and tetrahydrofuran is 6.2g:27.1g:100mL:30mL;

[0016] Boric acid reacts with diethanolamine, and the intermediate 1 is obtained by controlling the molar ratio of the two to be close to 1:2 and the diethanolamine to be slightly excessive. The specific reaction process is as follows:

[0017]

[0018] S2. At room temperature, under nitrogen protection, in a three-necked flask equipped with a stirring device, phenylphosphonyl dichloride, intermediate 1, toluene and triethylamine were mixed and stirred uniformly, the reaction temperature was controlled to 63°C, the reaction was carried out for 4 hours, the reaction was completed, filtered, and the solvent was removed by distillation under reduced pressure to obtain intermediate 2; the ratio of phenylphosphonyl dichloride, intermediate 1, toluene and triethylamine was 21.6 g: 21.8 g: 100 mL: 15 mL;

[0019] Phenylphosphonyl dichloride and intermediate 1 undergo nucleophilic substitution. By controlling the molar ratio of the two to be close to 1:1 and the amount of phenylphosphonyl dichloride to be slightly excessive, only one chlorine group on the phenylphosphonyl dichloride participates in the reaction. Triethylamine removes the hydrogen chloride generated by the reaction to obtain intermediate 2. The specific reaction process is as follows:

[0020]

[0021] S3, at room temperature, under nitrogen protection, in a three-necked flask equipped with a stirring device, vinylguanamine, intermediate 2, triethylamine and toluene were mixed and stirred uniformly, the reaction temperature was controlled to 71 ° C, and the reaction was kept warm for 5 hours. After the reaction was completed, it was filtered, and part of the solvent was distilled off under reduced pressure, and then purified by column chromatography (the eluent was a mixed solvent of benzene / ethyl acetate, and the volume ratio of the two was 4:3), and the eluent was removed by rotary evaporation to obtain intermediate 3; the ratio of vinylguanamine, intermediate 2, triethylamine and toluene was 14.9g:37.6g:15mL:100mL;

[0022] Intermediate 2 reacts with vinylguanamine, and the molar ratio of the two is controlled to be close to 1:1 and the vinylguanamine is slightly excessive, and triethylamine removes the hydrogen chloride generated by the reaction to obtain intermediate 3; the specific reaction process is as follows:

[0023]

[0024] S4. In a three-necked flask equipped with a stirring device, the carboxylated carbon nanotubes were mixed with N,N-dimethylformamide (DMF), and magnetically stirred for 2 hours to make the carboxylated carbon nanotubes evenly dispersed, and then the intermediate 3, dicyclohexylcarbodiimide (DCC, dehydrating agent) and 4-dimethylaminopyridine (DMAP, catalyst) were added in sequence, and after stirring evenly, the mixture was placed in a 45°C water bath for 2 hours for ultrasonication, and then the water bath was removed and magnetically stirred for 8 hours at room temperature. After the reaction was completed, the mixture was filtered, washed with anhydrous ethanol for 2-3 times, dried, and ground to obtain modified carbon nanotubes; the ratio of the amount of carboxylated carbon nanotubes, N,N-dimethylformamide, intermediate 3, dicyclohexylcarbodiimide, and 4-dimethylaminopyridine was 10g:100mL:25g:20g:0.2g;

[0025] Under the action of the dehydrating agent and the catalyst, -COOH on the surface of the carboxylated carbon nanotubes undergoes an amidation reaction with -NH2 on the intermediate 3, and organic molecules are grafted onto the surface of the carbon nanotubes to obtain modified carbon nanotubes; the structure of the modified carbon nanotubes is shown below:

[0026]

[0027] The prepared modified carbon nanotubes are grafted with organic molecular chains through chemical bonding, that is, an organic layer is formed on the surface, which can greatly improve the interface compatibility between the carbon nanotubes and the matrix, reduce the agglomeration of the carbon nanotubes, and thus promote the uniform dispersion of the modified carbon nanotubes in the matrix, give full play to the antistatic properties of the carbon nanotubes, and also strengthen the matrix; not only that, the carbon nanotubes grafted with organic molecular chains can effectively prevent the migration and seepage of organic molecules, and ensure the durability of various properties; in addition, the organic molecular chains contain benzene rings , triazine structure, PN flame retardant component and boron anion, among which the introduction of benzene ring can further improve the mechanical properties of the matrix; the triazine structure will produce nitrogen-containing gas during combustion, which dilutes and reduces the smoke density, and self-condenses at high temperature to form melem to make the carbon layer tight, giving the matrix flame retardant and smoke suppression properties; the introduction of PN flame retardant component has the synergistic flame retardant effect of phosphorus and nitrogen flame retardants, further improving the flame retardant properties of the matrix; finally, boron anion can not only improve the flame retardancy of the matrix and reduce the smoke emission, but also improve the antistatic property of the matrix to a certain extent;

[0028] It should be noted that one end of the modified carbon nanotube contains a carbon-carbon double bond, which can cross-link with the matrix during the blending process, so that the modified carbon nanotube is combined with the matrix in a chemical bond block manner, thereby improving the bonding strength between the modified carbon nanotube and the matrix and making the performance more stable.

[0029] Furthermore, the carboxylated carbon nanotubes are prepared by the following steps:

[0030] The carbon nanotubes are placed in a conical flask, and then mixed acid is added, and ultrasonic treatment is performed in a water bath at 45°C for 5 hours. After the mixture is cooled to room temperature, deionized water is added for dilution, centrifugation is performed, and the mixture is washed with anhydrous ethanol and deionized water for 3-4 times in sequence, dried, and ground to obtain carboxylated carbon nanotubes; the mixed acid is a mixture of concentrated sulfuric acid with a mass fraction of 98% and concentrated hydrochloric acid with a mass fraction of 33.5% in a volume ratio of 4:1; the ratio of the carbon nanotubes to the mixed acid is 1g:100mL;

[0031] By subjecting carbon nanotubes to ultrasonic shearing and oxidation treatment with strong acid, a certain number of carboxyl active groups can be introduced into the side walls and tops of the carbon nanotubes, thus laying the foundation for reaction sites for subsequent chemical reactions.

[0032] Beneficial effects of the present invention:

[0033] 1. The composite plastic of the present invention is made of polypropylene as a matrix and through chemical foaming, which gives it excellent cushioning properties and mechanical properties;

[0034] 2. By modifying the carbon nanotubes, the agglomeration phenomenon is significantly reduced compared with ordinary carbon nanotubes, and the antistatic performance is fully exerted, giving the composite plastic extremely strong antistatic properties; the various groups in the modified carbon nanotubes play a synergistic role, giving the composite plastic significant flame retardant and smoke suppression properties, and the performance is stable;

[0035] Therefore, the composite plastic prepared by the present invention has stable and efficient mechanical properties, antistatic properties and flame retardant and smoke suppression properties, and has long-term stable properties, is halogen-free and environmentally friendly, and has important application value in the field of logistics packaging technology. DETAILED DESCRIPTION

[0036] The following will be combined with the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

[0037] Example 1

[0038] Preparation of carboxylated carbon nanotubes:

[0039] 10 g of carbon nanotubes were placed in a conical flask, and then 1000 mL of mixed acid was added, and ultrasonic treatment was performed in a 45°C water bath for 5 hours. After the mixture was cooled to room temperature, deionized water was added to dilute it, centrifuged, and washed with anhydrous ethanol and deionized water for 4 times in sequence, dried, and ground to obtain carboxylated carbon nanotubes; the mixed acid was prepared by compounding concentrated sulfuric acid (mass fraction 98%) and concentrated hydrochloric acid (mass fraction 33.5%) in a volume ratio of 4:1.

[0040] Example 2

[0041] Preparation of modified carbon nanotubes:

[0042] S1. In a four-necked flask equipped with a thermometer, a stirrer, a water separator and a spherical condenser, add 6.2 g of boric acid, 27.1 g of diethanolamine and 100 mL of toluene, stir and mix evenly, heat to boiling state, until liquid separates out of the water separator, control the reaction temperature to 120°C, and keep the reaction warm until the amount of water in the water separator no longer increases, continue the reaction for 30 min, the reaction is completed, stand for stratification, filter, take the lower layer of liquid, add 30 mL of tetrahydrofuran to remove unreacted diethanolamine, distill under reduced pressure to remove residual tetrahydrofuran and toluene, and dry in vacuo to obtain intermediate 1;

[0043] S2. At room temperature, under nitrogen protection, 21.6 g of phenylphosphonyl dichloride, 21.8 g of intermediate 1, 100 mL of toluene and 15 mL of triethylamine were mixed and stirred evenly in a three-necked flask equipped with a stirring device. The reaction temperature was controlled to 63° C. and the reaction was carried out for 4 h. After the reaction was completed, the mixture was filtered and the solvent was removed by distillation under reduced pressure to obtain intermediate 2.

[0044] S3, at room temperature, under nitrogen protection, in a three-necked flask equipped with a stirring device, 14.9 g of vinylguanamine, 37.6 g of intermediate 2, 15 mL of triethylamine and 100 mL of toluene were mixed and stirred uniformly, the reaction temperature was controlled to 71 ° C, and the reaction was kept warm for 5 hours. After the reaction was completed, it was filtered, and part of the solvent was distilled off under reduced pressure, and then purified by column chromatography (the eluent was a mixed solvent of benzene / ethyl acetate, and the volume ratio of the two was 4:3), and the eluent was removed by rotary evaporation to obtain intermediate 3;

[0045] S4. In a three-necked flask equipped with a stirring device, mix 10g of carboxylated carbon nanotubes with 100mLDF, and stir magnetically for 2h to evenly disperse the carboxylated carbon nanotubes. Then add 25g of intermediate 3, 20g of DCC and 0.2g of DMAP in sequence. After stirring evenly, place in a 45°C water bath for 2h, remove the water bath and stir magnetically for 8h at room temperature. After the reaction is complete, filter, wash with anhydrous ethanol 2-3 times, dry and grind to obtain modified carbon nanotubes.

[0046] Example 3

[0047] Preparation of modified carbon nanotubes:

[0048] S1. In a four-necked flask equipped with a thermometer, a stirrer, a water separator and a spherical condenser, 12.4 g of boric acid, 54.2 g of diethanolamine and 200 mL of toluene were added and stirred to mix evenly. The mixture was heated to boiling until liquid was separated out of the water separator. The reaction temperature was controlled to 120° C. and the reaction was kept warm until the amount of water in the water separator no longer increased. The reaction was continued for 30 min. After the reaction was completed, the mixture was allowed to stand for stratification, filtered, the lower layer of liquid was taken, 60 mL of tetrahydrofuran was added to remove the unreacted diethanolamine, and the residual tetrahydrofuran and toluene were removed by distillation under reduced pressure. The mixture was dried in vacuo to obtain intermediate 1.

[0049] S2. At room temperature, 43.2 g of phenylphosphonyl dichloride, 43.6 g of intermediate 1, 200 mL of toluene and 30 mL of triethylamine were mixed and stirred evenly in a three-necked flask equipped with a stirring device under nitrogen protection. The reaction temperature was controlled to 63° C. and the reaction was carried out for 4 h. After the reaction was completed, the mixture was filtered and the solvent was removed by distillation under reduced pressure to obtain intermediate 2.

[0050] S3, at room temperature, under nitrogen protection, in a three-necked flask equipped with a stirring device, 29.8 g of vinylguanamine, 75.2 g of intermediate 2, 30 mL of triethylamine and 200 mL of toluene were mixed and stirred evenly, the reaction temperature was controlled to 71 ° C, and the reaction was kept warm for 5 hours. After the reaction was completed, it was filtered, and part of the solvent was distilled off under reduced pressure, and then purified by column chromatography (the eluent was a mixed solvent of benzene / ethyl acetate, and the volume ratio of the two was 4:3), and the eluent was removed by rotary evaporation to obtain intermediate 3;

[0051] S4. In a three-necked flask equipped with a stirring device, mix 20g of carboxylated carbon nanotubes with 200mLDMF, and stir magnetically for 2h to evenly disperse the carboxylated carbon nanotubes. Then add 50g of intermediate 3, 40g of DCC and 0.4g of DMAP in sequence. After stirring evenly, place in a 45°C water bath for ultrasonic treatment for 2h, remove the water bath and stir magnetically for 8h at room temperature. After the reaction is completed, filter, wash with anhydrous ethanol three times, dry and grind to obtain modified carbon nanotubes.

[0052] Example 4

[0053] 90 g of polypropylene resin, 10 g of modified carbon nanotubes prepared in Example 2, 0.2 g of benzoyl peroxide, 6 g of antioxidant 1010, 4 g of calcium oxide and 6 g of azodicarbonamide were mixed, added to a high-speed mixer and stirred for 3 hours, poured into a twin-screw extruder, melt blended, extruded and foamed to obtain a polypropylene composite plastic for logistics packaging boxes.

[0054] Example 5

[0055] 100 g of polypropylene resin, 15 g of modified carbon nanotubes obtained in Example 3, 0.4 g of lauroyl peroxide, 8 g of antioxidant 264, 5 g of magnesium oxide and 7 g of azodicarbonamide were mixed, added to a high-speed mixer and stirred for 3 hours, poured into a twin-screw extruder, melt blended, extruded and foamed to obtain a polypropylene composite plastic for logistics packaging boxes.

[0056] Example 6

[0057] 110 g of polypropylene resin, 20 g of modified carbon nanotubes prepared in Example 3, 0.5 g of lauroyl peroxide, 10 g of antioxidant 264, 6 g of magnesium oxide and 8 g of azodicarbonamide were mixed, added to a high-speed mixer and stirred for 3 hours, poured into a twin-screw extruder, melt blended, extruded and foamed to obtain a polypropylene composite plastic for logistics packaging boxes.

[0058] Comparative Example 1

[0059] Ordinary carbon nanotubes of the same mass were used to replace the modified carbon nanotubes in Example 6, and the remaining steps were the same as those in Example 6.

[0060] Comparative Example 2

[0061] 110 g of polypropylene resin, 10 g of octadecylamine polyoxyethylene ether (antistatic agent), 10 g of piperazine pyrophosphate (flame retardant), 0.5 g of lauroyl peroxide, 10 g of antioxidant 264, 6 g of magnesium oxide and 8 g of azodicarbonamide were mixed, added to a high-speed mixer and stirred for 3 hours, poured into a twin-screw extruder, melt blended, extruded and foamed to obtain a polypropylene composite plastic.

[0062] Examples 4-6 and comparative examples 1-2 were made into corresponding shapes according to different test standards and subjected to the following performance tests:

[0063] The surface resistivity is measured using the national standard GB / T 1410-2006 "Test method for volume resistivity and surface resistivity of solid insulating materials" (the smaller the surface resistivity, the better the conductive performance);

[0064] The notched impact strength is measured using the national standard GB / T 1843-2008 "Determination of Izod Impact Strength of Plastics";

[0065] The national standard GB / T 1040.1-2018 "Determination of tensile properties of plastics" was used to measure the tensile strength at a temperature of 25°C and a tensile rate of 100 mm / min;

[0066] The smoke density is measured using the national standard GB / T 8323.2-2008 "Plastic smoke generation Part 2: Single chamber method for determination of smoke density test method";

[0067] The national standard GB / T 2406-2008 "Test method for combustion performance of plastics" is used to determine the limiting oxygen index;

[0068] After the samples were placed at room temperature for 30 days, the surface resistivity and limiting oxygen index of the samples were measured using the same standard;

[0069] The measured results are shown in the following table:

[0070]

[0071]

[0072] It can be seen from the above table that the mechanical properties, antistatic properties and flame retardancy and smoke suppression properties of the polypropylene composite plastic prepared in the embodiment of the present invention are higher than those of the control example, and the performance is long-lasting and stable, and it has important application value in the field of logistics packaging technology.

[0073] In the description of the specification, the description with reference to the terms "one embodiment", "example", "specific example", etc. means that the specific features, structures, materials or characteristics described in conjunction with the embodiment or example are included in at least one embodiment or example of the present invention. In this specification, the schematic representation of the above terms does not necessarily refer to the same embodiment or example. Moreover, the specific features, structures, materials or characteristics described can be combined in any one or more embodiments or examples in a suitable manner.

[0074] The above contents are merely examples and explanations of the present invention. Those skilled in the art may make various modifications or additions to the specific embodiments described or replace them in a similar manner. As long as they do not deviate from the invention or exceed the scope defined by the claims, they shall all fall within the protection scope of the present invention.

Claims

1. A polypropylene composite plastic for logistics packaging box, characterized in that: The invention comprises the following raw materials in parts by weight: 90-110 parts of polypropylene resin, 10-20 parts of modified carbon nanotubes, 0.2-0.5 parts of initiator, 6-10 parts of antioxidant, 4-6 parts of nucleating agent and 6-8 parts of azodicarbonamide; The modified carbon nanotubes are prepared by the following steps: S1. Stir and mix boric acid, diethanolamine and toluene evenly, heat to boiling state, until liquid is separated in the water separator, control the reaction temperature to 120°C, keep the reaction warm until the amount of water in the water separator no longer increases, continue the reaction for 30 minutes, and after the reaction is completed, stand for stratification, filter, take the lower layer of liquid, add tetrahydrofuran, distill under reduced pressure, and dry in vacuo to obtain intermediate 1; the ratio of boric acid, diethanolamine and toluene is 6.2g:27.1g:100mL; S2. At room temperature, under nitrogen protection, phenylphosphonyl dichloride, intermediate 1, toluene and triethylamine were mixed and stirred evenly, and reacted at 63°C for 4 hours. After the reaction was completed, the mixture was filtered and distilled under reduced pressure to obtain intermediate 2. The ratio of phenylphosphonyl dichloride, intermediate 1, toluene and triethylamine was 21.6 g: 21.8 g: 100 mL: 15 mL. S3, at room temperature, under nitrogen protection, ethyleneguanamine, intermediate 2, triethylamine and toluene were mixed and stirred evenly, reacted at 71°C for 5 hours, and after the reaction was completed, filtered, distilled under reduced pressure, purified by column chromatography, and rotary evaporated to obtain intermediate 3; the ratio of ethyleneguanamine, intermediate 2, triethylamine, toluene and tetrahydrofuran was 14.9 g: 37.6 g: 15 mL: 100 mL: 30 mL; S4. Mix the carboxylated carbon nanotubes with N,N-dimethylformamide, stir magnetically for 2 hours, then add intermediate 3, dicyclohexylcarbodiimide and 4-dimethylaminopyridine in sequence, stir evenly, place in a 45°C water bath for 2 hours, remove the water bath and stir magnetically for 8 hours at room temperature. After the reaction is completed, filter, wash, dry and grind to obtain modified carbon nanotubes; the ratio of carboxylated carbon nanotubes, N,N-dimethylformamide, intermediate 3, dicyclohexylcarbodiimide and 4-dimethylaminopyridine is 10g:100mL:25g:20g:0.2g.

2. The polypropylene composite plastic for logistics packaging box according to claim 1, characterized in that: The antioxidant is one of antioxidant 1010 and antioxidant 264.

3. The polypropylene composite plastic for logistics packaging box according to claim 1, characterized in that: The initiator is one of benzoyl peroxide and lauroyl peroxide.

4. The polypropylene composite plastic for logistics packaging box according to claim 1, characterized in that: The nucleating agent is one of calcium oxide and magnesium oxide.

5. The method for producing a polypropylene composite plastic for a logistics packaging box according to claim 1, characterized in that: The following steps are involved: The polypropylene resin, modified carbon nanotubes, initiator, antioxidant, nucleating agent and azodicarbonamide are mixed, stirred, poured into a twin-screw extruder, melt-blended, extruded and foamed to obtain a polypropylene composite plastic for a logistics packaging box.

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