High-adhesiveness water-based dye dyed fabric and preparation method thereof

Abstract

The invention relates to the technical field of woven fabrics, in particular to a high-adhesiveness water-based dye dyed fabric and a preparation method thereof.The preparation method comprises the following steps that modified polyester yarn serves as warp yarn and weft yarn to be subjected to spooling treatment, the speed of a spooling machine is set to be 1200 m / min, and the spooling tension is 5-10 g; the warp yarn and the weft yarn which are subjected to spooling treatment are subjected to warping treatment, the warping speed is set to be 500 m / min, and the winding density is 0.5 g / cm < 3 >. According to the fabric, the modified polyester yarns are adopted as the warp yarns and the weft yarns respectively, and through operations such as spooling, warping, sizing, weaving and the like, the specially-made modified polyester yarns and water-based dye treatment are adopted, so that the obtained fabric has the advantages that the fabric air permeability, the mechanical property and the color fastness performance are balanced and coordinated; and the product has obvious washing resistance and scraping stability.

Description

Technical Field

[0001] The invention relates to the technical field of woven fabrics, and in particular to a fabric dyed with a high-adhesion water-based dye and a preparation method thereof. Background Art

[0002] Fabric is a flat soft piece of material formed by cross-entanglement and connection of small and soft long objects. Woven fabric is composed of yarns in a cross-relationship, knitted fabric is composed of yarns in a entanglement relationship, non-woven fabric is composed of yarns in a connected relationship, and the third fabric is composed of yarns in a cross / entanglement relationship.

[0003] The fabrics woven by the prior art have poor air permeability, and it is difficult to balance the air permeability, mechanical properties and color fastness properties of the fabrics. In addition, the products have poor water resistance and scratch stability, which limits the use efficiency of the products.

[0004] For example, the Chinese patent document publication number CN117888258A discloses a conductive fabric and a preparation method thereof, which belongs to the technical field of lightweight flexible materials. The preparation of the conductive fabric includes the following steps: adding carbon black, silver nanoparticles, and polyurethane to an organic solvent to obtain a spinning solution, and preparing a conductive yarn by a wet spinning method; weaving the conductive yarn to obtain a conductive fabric. The product has conductive properties, but it is difficult to balance the air permeability, mechanical properties, and color fastness. Based on this, the applicant further improves it. Summary of the invention

[0005] In view of the defects of the prior art, the object of the present invention is to provide a fabric dyed with a high-adhesion water-based dye and a preparation method thereof, so as to solve the problems raised in the above-mentioned background technology.

[0006] The present invention solves the technical problem by adopting the following technical solution: The present invention provides a method for preparing a fabric dyed with a high-adhesion water-based dye, comprising the following steps: Step 1: The modified polyester yarn is used as warp yarn and weft yarn for winding, the speed of the winding machine is set to 1200m / min, and the winding tension is 5-10g; Step 2: The warp and weft yarns that have been wound are then warped. The warping speed is set to 500m / min and the winding density is 0.5g / cm 3 ; Step 3: The warp yarn treated by warping is sizing by water-based dye, the sizing machine speed of the sizing is 50m / min, and after the sizing treatment, it is dried at 110°C for 2min; Step 4: Weaving the warp yarn and the weft yarn after sizing and drying, and obtaining a fabric dyed with a high-adhesion water-based dye after weaving.

[0007] Preferably, during the weaving process, the loom speed is 700 r / min and the upper machine tension is 1900-2000 N.

[0008] Preferably, the preparation method of the modified polyester yarn is: S01: Preparation of modified additives: S101: mixing carbon nanotubes, chitosan solution and silane coupling agent KH560 in a weight ratio of (3-5):(6-10):2 to obtain a carbon nanotube solution; S102: adding 4-7 parts of diatomaceous earth and 2-5 parts of lanthanum oxide to 6-10 parts of sodium dodecylbenzene sulfonate solution by weight, and then adding 2-3 parts of citric acid to mix and ball milling, the ball milling speed is 1500r / min, the ball milling is carried out for 2h, and after the ball milling is completed, the diatomaceous earth agent is washed with water and dried; S103: mixing the carbon nanotube liquid and the diatomaceous earth agent in a weight ratio of 5:3, and ball milling the mixture at a speed of 1000-1200 r / min for 2 h. After the ball milling is completed, washing and drying are performed to obtain a modified additive; S02: The polyester resin and the modified additive are mixed thoroughly in a weight ratio of 10:(2-3), and then spun to obtain modified polyester yarn.

[0009] Preferably, the spinning metering pump supply of the spinning process is 750-800 g / min, the spinning temperature is 295° C., the spinning speed is 950-1000 m / min, and the drafting multiple is 2.8-3.0 times.

[0010] Preferably, the mass fraction of the chitosan solution is 2-5%; the mass fraction of the sodium dodecylbenzene sulfonate solution is 3-6%.

[0011] Preferably, the preparation method of the water-based dye is: S11: Preparation of auxiliary additives: Mixing nano-bentonite in a sufficient amount of dopamine hydrochloride solution to obtain a nano-bentonite agent; The nano-bentonite agent, the auxiliary agent and the melamine body are mixed in a weight ratio of 5:3:1, and the ball milling is carried out at a ball milling speed of 1000-1500r / min for 2h. After the ball milling is completed, the auxiliary agent is filtered and dried to obtain the auxiliary agent; The preparation method of melamine body is as follows: Melamine and paraformaldehyde were mixed in a ratio of 1:3, and then distilled water and alkali were added, and the temperature was raised to 76°C under stirring, and the reaction was carried out for 30 minutes, and then terephthalaldehyde, a modifier, was added, and the pH was adjusted to 7.5 for standby use to obtain a melamine body; S12: Mix the dye matrix, the auxiliary additive and the silane coupling agent KH550 in a weight ratio of (9-11):(3-5):2 to obtain a water-based dye.

[0012] Preferably, the mass fraction of the dopamine hydrochloride solution is 2-5%; the dye matrix is ​​prepared by mixing 5-8 parts of disperse red FB dye, 35-40 parts of deionized water and 1-3 parts of polyacrylic acid in parts by weight.

[0013] Preferably, the auxiliary agent includes the following raw materials in parts by weight: 2-5 parts of silicon carbide whiskers, 4-6 parts of yttrium nitrate solution, 2-5 parts of sodium alginate solution, 1-2 parts of stearic acid and 0.2-0.3 parts of nano-silica sol.

[0014] Preferably, the mass fraction of the yttrium nitrate solution is 4-6%; the mass fraction of the sodium alginate solution is 2-5%.

[0015] The invention also provides a high-adhesion water-based dye dyed fabric, which is prepared by the method for preparing the high-adhesion water-based dye dyed fabric.

[0016] Compared with the prior art, the present invention has the following beneficial effects: The dyed fabric of the present invention adopts modified polyester yarn as warp yarn and weft yarn respectively, and undergoes operations such as winding, warping, sizing and looming. By adopting the specially prepared modified polyester yarn of the present invention and water-based dye treatment, the obtained dyed fabric has balanced and coordinated fabric air permeability, mechanical properties and color fastness properties, and the product has remarkable effects of water washing resistance and scratch stability. The modified polyester yarn adopts carbon nanotubes, chitosan solution and silane coupling agent KH560 for coordination, and diatomaceous earth is used as a matrix material, and diatomaceous earth agent obtained by coordination and preparation of lanthanum oxide, sodium dodecylbenzene sulfonate and citric acid is added. The diatomaceous earth agent is coordinated with the carbon nanotube liquid for coordination, the carbon nanotube has a tubular bearing property with a high specific surface area, and the diatomaceous earth has a porous effect. The modified additive prepared by a specific method is added to the polyester resin for spinning treatment, so as to optimize the mechanical properties of the modified polyester yarn body and the air permeability of the fabric, and at the same time improve the water washing resistance and scratch stability of the product. The water-based dye adopts nano- Bentonite is stirred evenly in a sufficient amount of dopamine hydrochloride solution, and then mixed with an auxiliary agent and melamine body for ball milling to obtain an auxiliary additive. The melamine body has multiple active groups, which improves the better combination of the dye product with the fabric, and the nano-bentonite agent has a lamellar structure, which uses the interlayer distance as a breathable channel to enhance the breathability. After being treated with the dopamine hydrochloride solution, the nano-bentonite agent is better able to cooperate with the auxiliary agent in the distribution system. At the same time, the auxiliary agent added is silicon carbide whiskers combined with yttrium nitrate solution, sodium alginate solution, stearic acid and nano-silica sol raw materials, which are distributed in the system through whisker-like whisker structures, and yttrium nitrate and other raw materials are jointly blended, so that the water-based dye can be better attached to the fabric, the coloring efficiency is improved, and the color fastness is improved. At the same time, through the specific combination of the water-based dye and the modified polyester yarn, the obtained product can achieve a balanced coordination of the fabric's breathability, mechanical properties and color fastness properties, and the product has remarkable effects on water resistance and scratch stability. DETAILED DESCRIPTION

[0017] The following is a clear and complete description of the technical solutions in the embodiments of the present invention in conjunction with specific embodiments. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.

[0018] A method for preparing a fabric dyed with a high-adhesion water-based dye in this embodiment comprises the following steps: Step 1: The modified polyester yarn is used as warp yarn and weft yarn for winding, the speed of the winding machine is set to 1200m / min, and the winding tension is 5-10g; Step 2: The warp and weft yarns that have been wound are then warped. The warping speed is set to 500m / min and the winding density is 0.5g / cm 3 ; Step 3: The warp yarn treated by warping is sizing by water-based dye, the sizing machine speed of the sizing is 50m / min, and after the sizing treatment, it is dried at 110°C for 2min; Step 4: Weaving the warp yarn and the weft yarn after sizing and drying, and obtaining a fabric dyed with a high-adhesion water-based dye after weaving.

[0019] In the weaving process of this embodiment, the loom speed is 700r / min and the upper machine tension is 1900-2000N.

[0020] The preparation method of the modified polyester yarn of this embodiment is: S01: Preparation of modified additives: S101: mixing carbon nanotubes, chitosan solution and silane coupling agent KH560 in a weight ratio of (3-5):(6-10):2 to obtain a carbon nanotube solution; S102: adding 4-7 parts of diatomaceous earth and 2-5 parts of lanthanum oxide to 6-10 parts of sodium dodecylbenzene sulfonate solution by weight, and then adding 2-3 parts of citric acid to mix and ball milling, the ball milling speed is 1500r / min, the ball milling is carried out for 2h, and after the ball milling is completed, the diatomaceous earth agent is washed with water and dried; S103: mixing the carbon nanotube liquid and the diatomaceous earth agent in a weight ratio of 5:3, and ball milling the mixture at a speed of 1000-1200 r / min for 2 h. After the ball milling is completed, washing and drying are performed to obtain a modified additive; S02: The polyester resin and the modified additive are mixed thoroughly in a weight ratio of 10:(2-3), and then spun to obtain modified polyester yarn.

[0021] The spinning metering pump supply of the spinning process in this embodiment is 750-800 g / min, the spinning temperature is 295° C., the spinning speed is 950-1000 m / min, and the drafting multiple is 2.8-3.0 times.

[0022] The mass fraction of the chitosan solution in this embodiment is 2-5%; the mass fraction of the sodium dodecylbenzene sulfonate solution is 3-6%.

[0023] The preparation method of the water-based dye of the present embodiment is: S11: Preparation of auxiliary additives: Mixing nano-bentonite in a sufficient amount of dopamine hydrochloride solution to obtain a nano-bentonite agent; The nano-bentonite agent, the auxiliary agent and the melamine body are mixed in a weight ratio of 5:3:1, and the ball milling is carried out at a ball milling speed of 1000-1500r / min for 2h. After the ball milling is completed, the auxiliary agent is filtered and dried to obtain the auxiliary agent; The preparation method of melamine body is as follows: Melamine and paraformaldehyde were mixed in a ratio of 1:3, and then distilled water and alkali were added, and the temperature was raised to 76°C under stirring, and the reaction was carried out for 30 minutes, and then terephthalaldehyde, a modifier, was added, and the pH was adjusted to 7.5 for standby use to obtain a melamine body; S12: Mix the dye matrix, the auxiliary additive and the silane coupling agent KH550 in a weight ratio of (9-11):(3-5):2 to obtain a water-based dye.

[0024] The mass fraction of the dopamine hydrochloride solution in this embodiment is 2-5%; the dye matrix is ​​prepared by mixing 5-8 parts of disperse red FB dye, 35-40 parts of deionized water and 1-3 parts of polyacrylic acid in parts by weight.

[0025] The auxiliary agent of this embodiment includes the following raw materials in parts by weight: 2-5 parts of silicon carbide whiskers, 4-6 parts of yttrium nitrate solution, 2-5 parts of sodium alginate solution, 1-2 parts of stearic acid and 0.2-0.3 parts of nano-silica sol.

[0026] The mass fraction of the yttrium nitrate solution in this embodiment is 4-6%; the mass fraction of the sodium alginate solution is 2-5%.

[0027] The high-adhesion water-based dye dyed fabric of this embodiment is prepared by the preparation method of the high-adhesion water-based dye dyed fabric.

[0028] Embodiment 1: A method for preparing a fabric dyed with a high-adhesion water-based dye, comprising the following steps: Step 1: The modified polyester yarn is used as warp yarn and weft yarn for winding, and the speed of the winding machine is set to 1200m / min and the winding tension is 5g; Step 2: The warp and weft yarns that have been wound are then warped. The warping speed is set to 500m / min and the winding density is 0.5g / cm 3 ; Step 3: The warp yarn treated by warping is sizing by water-based dye, the sizing machine speed of the sizing is 50m / min, and after the sizing treatment, it is dried at 110°C for 2min; Step 4: Weaving the warp yarn and the weft yarn after sizing and drying, and obtaining a fabric dyed with a high-adhesion water-based dye after weaving.

[0029] In the weaving process of this embodiment, the loom speed is 700r / min and the upper machine tension is 1900N.

[0030] The preparation method of the modified polyester yarn of this embodiment is: S01: Preparation of modified additives: S101: mixing carbon nanotubes, chitosan solution and silane coupling agent KH560 in a weight ratio of 3:6:2 to obtain a carbon nanotube solution; S102: adding 4 parts of diatomaceous earth and 2 parts of lanthanum oxide to 6 parts of sodium dodecylbenzene sulfonate solution by weight, and then adding 2 parts of citric acid to mix and ball milling, the ball milling speed is 1500r / min, the ball milling is carried out for 2h, and after the ball milling is completed, the diatomaceous earth agent is washed with water and dried; S103: mixing the carbon nanotube liquid and the diatomaceous earth agent in a weight ratio of 5:3 and ball milling the mixture at a speed of 1000 r / min for 2 h. After the ball milling is completed, washing with water and drying are performed to obtain a modified additive; S02: The polyester resin and the modified additive are mixed thoroughly in a weight ratio of 5:1, and then spun to obtain modified polyester yarn.

[0031] The spinning metering pump supply of the spinning process in this embodiment is 750 g / min, the spinning temperature is 295° C., the spinning speed is 950 m / min, and the drafting multiple is 2.8 times.

[0032] The mass fraction of the chitosan solution in this embodiment is 2%; the mass fraction of the sodium dodecylbenzene sulfonate solution is 3%.

[0033] The preparation method of the water-based dye of the present embodiment is: S11: Preparation of auxiliary additives: Mixing nano-bentonite in a sufficient amount of dopamine hydrochloride solution to obtain a nano-bentonite agent; The nano-bentonite agent, the auxiliary agent and the melamine body were mixed and ball-milled at a weight ratio of 5:3:1, the ball-milling speed was 1000r / min, the ball-milling was carried out for 2h, and after the ball-milling was completed, the auxiliary agent was filtered and dried to obtain the auxiliary agent; The preparation method of melamine body is as follows: Melamine and paraformaldehyde were mixed in a ratio of 1:3, and then distilled water and alkali were added, and the temperature was raised to 76°C under stirring, and the reaction was carried out for 30 minutes, and then terephthalaldehyde, a modifier, was added, and the pH was adjusted to 7.5 for standby use to obtain a melamine body; S12: The dye matrix, the auxiliary additive and the silane coupling agent KH550 are mixed in a weight ratio of 9:3:2 to obtain a water-based dye.

[0034] The mass fraction of the dopamine hydrochloride solution in this embodiment is 2%; the dye matrix is ​​prepared by mixing 5 parts of disperse red FB dye, 35 parts of deionized water and 1 part of polyacrylic acid in parts by weight.

[0035] The auxiliary agent of this embodiment includes the following raw materials in parts by weight: 2 parts of silicon carbide whiskers, 4 parts of yttrium nitrate solution, 2 parts of sodium alginate solution, 1 part of stearic acid and 0.2 parts of nano-silica sol.

[0036] The mass fraction of the yttrium nitrate solution in this embodiment is 4%; the mass fraction of the sodium alginate solution is 2%.

[0037] The high-adhesion water-based dye dyed fabric of the present embodiment is prepared by the preparation method of the high-adhesion water-based dye dyed fabric.

[0038] Embodiment 2: A method for preparing a fabric dyed with a high-adhesion water-based dye, comprising the following steps: Step 1: The modified polyester yarn is used as warp yarn and weft yarn for winding, the speed of the winding machine is set to 1200m / min, and the winding tension is 10g; Step 2: The warp and weft yarns that have been wound are then warped. The warping speed is set to 500m / min and the winding density is 0.5g / cm 3 ; Step 3: The warp yarn treated by warping is sizing by water-based dye, the sizing machine speed of the sizing is 50m / min, and after the sizing treatment, it is dried at 110°C for 2min; Step 4: Weaving the warp yarn and the weft yarn after sizing and drying, and obtaining a fabric dyed with a high-adhesion water-based dye after weaving.

[0039] In the weaving process of this embodiment, the loom speed is 700r / min and the upper tension is 2000N.

[0040] The preparation method of the modified polyester yarn of this embodiment is: S01: Preparation of modified additives: S101: mixing carbon nanotubes, chitosan solution and silane coupling agent KH560 in a weight ratio of 5:5:1 to obtain a carbon nanotube solution; S102: adding 7 parts of diatomaceous earth and 5 parts of lanthanum oxide to 10 parts of sodium dodecylbenzene sulfonate solution by weight, and then adding 3 parts of citric acid to mix and ball milling, the ball milling speed is 1500r / min, the ball milling is carried out for 2h, and after the ball milling is completed, the diatomaceous earth agent is washed with water and dried; S103: mixing the carbon nanotube liquid and the diatomaceous earth agent in a weight ratio of 5:3, and ball milling the mixture at a speed of 1200 r / min for 2 h. After the ball milling is completed, washing with water and drying the mixture to obtain a modified additive; S02: The polyester resin and the modified additive are mixed thoroughly in a weight ratio of 10:3, and then spun to obtain modified polyester yarn.

[0041] The spinning process of this embodiment has a spinning metering pump supply of 800 g / min, a spinning temperature of 295° C., a spinning speed of 1000 m / min, and a draft ratio of 3.0.

[0042] The mass fraction of the chitosan solution in this embodiment is 5%; the mass fraction of the sodium dodecylbenzene sulfonate solution is 6%.

[0043] The preparation method of the water-based dye of the present embodiment is: S11: Preparation of auxiliary additives: Mixing nano-bentonite in a sufficient amount of dopamine hydrochloride solution to obtain a nano-bentonite agent; The nano-bentonite agent, the auxiliary agent and the melamine body were mixed and ball-milled at a weight ratio of 5:3:1, the ball-milling speed was 1500r / min, the ball-milling was carried out for 2h, and after the ball-milling was completed, the auxiliary agent was filtered and dried to obtain the auxiliary agent; The preparation method of melamine body is as follows: Melamine and paraformaldehyde were mixed in a ratio of 1:3, and then distilled water and alkali were added, and the temperature was raised to 76°C under stirring, and the reaction was carried out for 30 minutes, and then terephthalaldehyde, a modifier, was added, and the pH was adjusted to 7.5 for standby use to obtain a melamine body; S12: The dye matrix, the auxiliary additive and the silane coupling agent KH550 are mixed in a weight ratio of 11:5:2 to obtain a water-based dye.

[0044] The mass fraction of the dopamine hydrochloride solution in this embodiment is 5%; the dye matrix is ​​prepared by mixing 8 parts of disperse red FB dye, 40 parts of deionized water and 3 parts of polyacrylic acid in parts by weight.

[0045] The auxiliary agent of this embodiment includes the following raw materials in parts by weight: 5 parts of silicon carbide whiskers, 6 parts of yttrium nitrate solution, 5 parts of sodium alginate solution, 2 parts of stearic acid and 0.3 parts of nano-silica sol.

[0046] The mass fraction of the yttrium nitrate solution in this embodiment is 6%; the mass fraction of the sodium alginate solution is 5%.

[0047] The high-adhesion water-based dye dyed fabric of the present embodiment is prepared by the preparation method of the high-adhesion water-based dye dyed fabric.

[0048] Embodiment 3: A method for preparing a fabric dyed with a high-adhesion water-based dye, comprising the following steps: Step 1: The modified polyester yarn is used as warp yarn and weft yarn for winding, the speed of the winding machine is set to 1200m / min, and the winding tension is 7.5g; Step 2: The warp and weft yarns that have been wound are then warped. The warping speed is set to 500m / min and the winding density is 0.5g / cm 3 ; Step 3: The warp yarn treated by warping is sizing by water-based dye, the sizing machine speed of the sizing is 50m / min, and after the sizing treatment, it is dried at 110°C for 2min; Step 4: Weaving the warp yarn and the weft yarn after sizing and drying, and obtaining a fabric dyed with a high-adhesion water-based dye after weaving.

[0049] In the weaving process of this embodiment, the loom speed is 700r / min and the upper machine tension is 1950N.

[0050] The preparation method of the modified polyester yarn of this embodiment is: S01: Preparation of modified additives: S101: mixing carbon nanotubes, chitosan solution and silane coupling agent KH560 in a weight ratio of 4:8:2 to obtain a carbon nanotube solution; S102: adding 5.5 parts of diatomaceous earth and 3.5 parts of lanthanum oxide to 8 parts of sodium dodecylbenzene sulfonate solution by weight, and then adding 2.5 parts of citric acid to mix and ball milling, the ball milling speed is 1500r / min, the ball milling is carried out for 2h, and after the ball milling is completed, the diatomaceous earth agent is washed with water and dried; S103: mixing the carbon nanotube liquid and the diatomaceous earth agent in a weight ratio of 5:3, and ball milling the mixture at a speed of 1100 r / min for 2 h. After the ball milling is completed, washing with water and drying are performed to obtain a modified additive; S02: The polyester resin and the modified additive are mixed thoroughly in a weight ratio of 10:2.5, and then spun to obtain modified polyester yarn.

[0051] The spinning metering pump supply of the spinning process in this embodiment is 770 g / min, the spinning temperature is 295° C., the spinning speed is 980 m / min, and the drafting multiple is 2.9 times.

[0052] The mass fraction of the chitosan solution in this embodiment is 3.5%; the mass fraction of the sodium dodecylbenzene sulfonate solution is 4.5%.

[0053] The preparation method of the water-based dye of the present embodiment is: S11: Preparation of auxiliary additives: Mixing nano-bentonite in a sufficient amount of dopamine hydrochloride solution to obtain a nano-bentonite agent; The nano-bentonite agent, the auxiliary agent and the melamine body were mixed and ball-milled at a weight ratio of 5:3:1, the ball-milling speed was 1250r / min, the ball-milling was performed for 2h, and after the ball-milling was completed, the auxiliary agent was filtered and dried to obtain the auxiliary agent; The preparation method of melamine body is as follows: Melamine and paraformaldehyde were mixed in a ratio of 1:3, and then distilled water and alkali were added, and the temperature was raised to 76°C under stirring, and the reaction was carried out for 30 minutes, and then terephthalaldehyde, a modifier, was added, and the pH was adjusted to 7.5 for standby use to obtain a melamine body; S12: The dye matrix, the auxiliary additive and the silane coupling agent KH550 are mixed in a weight ratio of 10:4:2 to obtain a water-based dye.

[0054] The mass fraction of the dopamine hydrochloride solution in this embodiment is 3.5%; the dye matrix is ​​prepared by mixing 6.5 parts of disperse red FB dye, 37.5 parts of deionized water and 2 parts of polyacrylic acid in parts by weight.

[0055] The auxiliary agent of this embodiment includes the following raw materials in parts by weight: 3.5 parts of silicon carbide whiskers, 5 parts of yttrium nitrate solution, 3.5 parts of sodium alginate solution, 1.5 parts of stearic acid and 0.25 parts of nano-silica sol.

[0056] The mass fraction of the yttrium nitrate solution in this embodiment is 5%; the mass fraction of the sodium alginate solution is 3.5%.

[0057] The high-adhesion water-based dye dyed fabric of the present embodiment is prepared by the preparation method of the high-adhesion water-based dye dyed fabric.

[0058] Comparative Example 1: The difference from Example 3 is that no modifying additive is added to the modified polyester filament.

[0059] Comparative Example 2: The difference from Example 3 is that no diatomaceous earth agent is added to the modified additive.

[0060] Comparative Example 3: The difference from Example 3 is that lanthanum oxide and citric acid are not added to the diatomaceous earth agent.

[0061] Comparative Example 4: The difference from Example 3 is that no carbon nanotube liquid is added to the modified additive.

[0062] Comparative Example 5: The difference from Example 3 is that no carbon nanotubes and silane coupling agent KH560 are added to the carbon nanotube liquid.

[0063] Comparative Example 6: The difference from Example 3 is that no auxiliary additive is added to the water-based dye.

[0064] Comparative Example 7: The difference from Example 3 is that no nano bentonite agent is added to the auxiliary additives.

[0065] Comparative Example 8: The difference from Example 3 is that the nano bentonite agent is replaced by nano bentonite.

[0066] Comparative Example 9: The difference from Example 3 is that no melamine is added into the auxiliary additive.

[0067] Comparative Example 10: The difference from Example 3 is that no auxiliary adjusting agent is added to the auxiliary additive.

[0068] Comparative Example 11: The difference from Example 3 is that silicon carbide whiskers and stearic acid are not added to the auxiliary agent.

[0069] Comparative Example 12: The difference from Example 3 is that no yttrium nitrate solution is added to the auxiliary agent.

[0070] Comparative Example 13: The difference from Example 3 is that no sodium alginate solution and nano-silica sol are added to the auxiliary agent.

[0071] The products of Examples 1-3 and Comparative Examples 1-13 were tested for product performance under normal conditions, and the test results are as follows. At the same time, the products were scratched 10 times with a load of 2N, and then washed in water 10 times to test the water resistance and scratch stability of the products. The performance measurement results are as follows: From Examples 1-3 and Comparative Examples 1-13, it can be concluded that the product of Example 3 has excellent fabric air permeability, mechanical properties and color fastness properties, and the three properties can be improved in a coordinated manner, and the product has a significant performance stability effect under washing and scratching conditions; Without adding modified additives to the modified polyester yarn and without adding auxiliary additives to the water-based dye, the performance of the product has a significant trend of deterioration. The product performance effect is most obvious when the two are blended and coordinated. The performance of the products tended to deteriorate when diatomite agent was not added to the modified additive, lanthanum oxide and citric acid were not added to the diatomite agent, carbon nanotube liquid was not added to the modified additive, and carbon nanotube and silane coupling agent KH560 were not added to the carbon nanotube liquid; The modified additive obtained by the specific method of the present invention has the most significant product performance effect, and the specific carbon nanotube liquid combined with the specific diatomaceous earth agent has the most significant product performance effect; The performance of the products without adding nano bentonite to the additives, replacing nano bentonite with nano bentonite, without adding melamine to the additives, and without adding auxiliary adjusters to the additives all showed a trend of deterioration to varying degrees, and the performance of the products without adding auxiliary adjusters also showed a more obvious trend of deterioration; At the same time, the performance of the product tended to deteriorate when silicon carbide whiskers and stearic acid, yttrium nitrate solution, sodium alginate solution and nano-silica sol were not added to the auxiliary agent; The auxiliary agent obtained by the specific method of the present invention is combined with the nano-bentonite agent and melamine body of the present invention to obtain the auxiliary additive, and the product performance effect is the most significant. Other methods are not as obvious as the effect of the present invention.

[0072] It will be apparent to those skilled in the art that the present invention is not limited to the details of the exemplary embodiments described above and that the present invention can be implemented in other specific forms without departing from the spirit or essential features of the present invention. Therefore, the embodiments should be considered exemplary and non-restrictive in all respects, and the scope of the present invention is defined by the appended claims rather than the above description, and it is intended that all changes falling within the meaning and scope of the equivalent elements of the claims be included in the present invention.

[0073] In addition, it should be understood that although the present specification is described according to implementation modes, not every implementation mode contains only one independent technical solution. This description of the specification is only for the sake of clarity. Those skilled in the art should regard the specification as a whole. The technical solutions in each embodiment may also be appropriately combined to form other implementation modes that can be understood by those skilled in the art.

Claims

1. A method for preparing a fabric dyed with a high-adhesion water-based dye, characterized in that: The following steps are involved: Step 1: The modified polyester yarn is used as warp yarn and weft yarn for winding, the speed of the winding machine is set to 1200m / min, and the winding tension is 5-10g; Step 2: The warp and weft yarns that have been wound are then warped. The warping speed is set to 500m / min and the winding density is 0.5g / cm 3 ; Step 3: The warp yarn treated by warping is sizing by water-based dye, the sizing machine speed of the sizing is 50m / min, and after the sizing treatment, it is dried at 110°C for 2min; Step 4: Weaving the warp yarn and the weft yarn after sizing and drying, and obtaining a fabric dyed with a high-adhesion water-based dye after weaving.

2. The method for preparing a fabric dyed with a high-adhesion water-based dye according to claim 1, characterized in that: During the weaving process, the loom speed is 700r / min and the upper tension is 1900-2000N.

3. The method for preparing a fabric dyed with a high-adhesion water-based dye according to claim 1, characterized in that: The preparation method of the modified polyester yarn is: S01: Preparation of modified additives: S101: mixing carbon nanotubes, chitosan solution and silane coupling agent KH560 in a weight ratio of (3-5):(6-10):2 to obtain a carbon nanotube solution; S102: adding 4-7 parts of diatomaceous earth and 2-5 parts of lanthanum oxide to 6-10 parts of sodium dodecylbenzene sulfonate solution by weight, and then adding 2-3 parts of citric acid to mix and ball milling, the ball milling speed is 1500r / min, the ball milling is carried out for 2h, and after the ball milling is completed, the diatomaceous earth agent is washed with water and dried; S103: mixing the carbon nanotube liquid and the diatomaceous earth agent in a weight ratio of 5:3, and ball milling the mixture at a speed of 1000-1200 r / min for 2 h. After the ball milling is completed, washing and drying are performed to obtain a modified additive; S02: The polyester resin and the modified additive are mixed thoroughly in a weight ratio of 10:(2-3), and then spun to obtain modified polyester yarn.

4. The method for preparing a fabric dyed with a high-adhesion water-based dye according to claim 3, characterized in that: The spinning metering pump supply of the spinning process is 750-800g / min, the spinning temperature is 295°C, the spinning speed is 950-1000m / min, and the drafting multiple is 2.8-3.0 times.

5. The method for preparing a fabric dyed with a high-adhesion water-based dye according to claim 3, characterized in that: The mass fraction of the chitosan solution is 2-5%; the mass fraction of the sodium dodecylbenzene sulfonate solution is 3-6%.

6. The method for preparing a fabric dyed with a high-adhesion water-based dye according to claim 1, characterized in that: The preparation method of the water-based dye is: S11: Preparation of auxiliary additives: Mixing nano-bentonite with a sufficient amount of dopamine hydrochloride solution to obtain a nano-bentonite agent; The nano-bentonite agent, the auxiliary agent and the melamine body are mixed in a weight ratio of 5:3:1, and the ball milling is carried out at a ball milling speed of 1000-1500r / min for 2h. After the ball milling is completed, the auxiliary agent is filtered and dried to obtain the auxiliary agent; The preparation method of melamine body is as follows: Melamine and paraformaldehyde were mixed in a ratio of 1:3, and then distilled water and alkali were added, and the temperature was raised to 76°C under stirring, and the reaction was carried out for 30 minutes, and then terephthalaldehyde, a modifier, was added, and the pH was adjusted to 7.5 for standby use to obtain a melamine body; S12: Mix the dye matrix, the auxiliary additive and the silane coupling agent KH550 in a weight ratio of (9-11):(3-5):2 to obtain a water-based dye.

7. The method for preparing a fabric dyed with a high-adhesion water-based dye according to claim 6, characterized in that: The mass fraction of the dopamine hydrochloride solution is 2-5%; the dye matrix is ​​prepared by mixing 5-8 parts of disperse red FB dye, 35-40 parts of deionized water and 1-3 parts of polyacrylic acid according to weight.

8. The method for preparing a fabric dyed with a high-adhesion water-based dye according to claim 6, characterized in that: The auxiliary agent includes the following raw materials in parts by weight: 2-5 parts of silicon carbide whiskers, 4-6 parts of yttrium nitrate solution, 2-5 parts of sodium alginate solution, 1-2 parts of stearic acid and 0.2-0.3 parts of nano-silica sol.

9. The method for preparing a fabric dyed with a high-adhesion water-based dye according to claim 8, characterized in that: The mass fraction of the yttrium nitrate solution is 4-6%; the mass fraction of the sodium alginate solution is 2-5%.

10. A fabric dyed with a high-adhesion water-based dye, prepared by the method for preparing a fabric dyed with a high-adhesion water-based dye according to any one of claims 1 to 9.

Images