Silver electrolysis device

By forming an anti-corrosion layer on the conductive beam of the silver electrolytic device and closely connected with the conductive block, the problem of patina generated by corrosion of the conductive beam is solved, the conductivity and system electric efficiency are improved, the residual electrode rate is reduced, and the silver powder is improved quality.

CN119465307APending Publication Date: 2025-02-18铜陵有色金属集团股份有限公司
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Patent Information

Application Number
CN202311015161.3
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2023-08-09
Publication Date
2025-02-18

AI Technical Summary

Technical Problem

In existing silver electrolytic devices, the conductive beam is easily corroded by the electrolyte to produce patina, resulting in a decrease in conductivity, a decrease in system electrical efficiency, an increase in residual electrode rate, and a patina enters the silver powder, causing the problem of copper exceeding the standard in silver powder.

Method used

A silver electrolytic device is designed. The conductive beam includes a conductive beam body and an anti-corrosion layer. The anti-corrosion layer is formed on the surface of the conductive beam body and is connected to the cathode conductive busbar through a conductive block. The protrusion passes through the anti-corrosion layer. The notch is connected to the connecting part to ensure that the conductive beam body and the conductive block are closely fitted, thereby avoiding corrosion.

Benefits of technology

Through the protection of the anti-corrosion layer, the conductive beam is avoided from being corroded during the electrolysis process, the conductivity of the conductive beam is improved, the system's electrical efficiency is improved, the residual electrode rate is reduced, and the problem of copper exceeding the standard in silver powder is solved.

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Abstract

The invention discloses a silver electrolysis device. The silver electrolysis device comprises: an electrolytic cell housing; the cathode conductive busbar is arranged on one side of the electrolytic cell shell; the anode conductive busbar is arranged on the other side of the electrolytic cell shell and is opposite to the cathode conductive busbar; the conductive block is connected with the cathode conductive busbar, and a protruding part is arranged on one side of the conductive block; the conductive beam comprises a conductive beam body and an anti-corrosion layer, one end of the conductive beam body is provided with a connecting part, the anti-corrosion layer is formed on the surface of the conductive beam body and is provided with a notch corresponding to the connecting part, and the protruding part penetrates through the notch and is connected with the connecting part. The silver electrolysis device can prevent the conductive beam from generating verdigris, so that the conductivity of the conductive beam is improved, the electrical efficiency of a system is improved, the anode scrap rate is reduced, and the problem that silver powder copper exceeds the standard is solved.
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Description

Technical Field

[0001] The invention relates to the technical field of nonferrous metal smelting, and in particular to a silver electrolysis device. Background Art

[0002] At present, the silver electrolysis industry mostly adopts large-plate and high-current density processes, and the supporting cathode device uses titanium plates and copper conductive beams. During the electrolysis process, the copper conductive beam is very susceptible to corrosion by the electrolyte to produce verdigris that is difficult to clean, and it is repeatedly produced after cleaning and tank filling. It will cause the following effects in the production process: the conductivity of the corroded conductive beam is reduced, resulting in a decrease in system efficiency and an increase in residual pole rate; the verdigris produced on the conductive beam will enter the silver powder from time to time, causing the copper detection of the obtained silver powder to exceed the standard. Summary of the invention

[0003] The present invention aims to solve at least one of the technical problems in the related art to a certain extent. To this end, one object of the present invention is to provide a silver electrolysis device, which can prevent the conductive beam from generating verdigris, thereby improving the conductivity of the conductive beam, improving the system efficiency, reducing the residual pole rate, and solving the problem of excessive silver powder copper.

[0004] In one aspect of the present invention, the present invention provides a silver electrolysis device. According to an embodiment of the present invention, the silver electrolysis device comprises:

[0005] Electrolyzer shell;

[0006] A cathode conductive busbar, wherein the cathode conductive busbar is arranged on one side of the electrolytic cell shell;

[0007] an anode conductive busbar, the anode conductive busbar being arranged on the other side of the electrolytic cell shell and opposite to the cathode conductive busbar;

[0008] A conductive block, the conductive block is connected to the cathode conductive busbar, and a protrusion is provided on one side of the conductive block;

[0009] A conductive beam, the conductive beam comprising a conductive beam body and an anti-corrosion layer, one end of the conductive beam body having a connecting portion, the anti-corrosion layer being formed on a surface of the conductive beam body and having a notch corresponding to the connecting portion, the protrusion passing through the notch and connected to the connecting portion;

[0010] A cathode plate, the top of which is connected to the anti-corrosion layer at the bottom of the conductive beam;

[0011] An anode plate, one end of which is connected to the anode conductive busbar.

[0012] According to the silver electrolysis device of the above embodiment of the present invention, the conductive beam includes a conductive beam body and an anti-corrosion layer. By forming the anti-corrosion layer on the surface of the conductive beam body, the conductive beam can be prevented from being corroded during the electrolysis process to produce verdigris, thereby improving the conductivity of the conductive beam, improving the system electrical efficiency, reducing the residual pole rate, and solving the problem of excessive silver powder copper; in addition, the conductive block is connected to the cathode conductive busbar, a protrusion is provided on one side of the conductive block, and a connecting portion is provided at one end of the conductive beam body. The anti-corrosion layer is formed on the surface of the conductive beam body and has a notch corresponding to the connecting portion. The protrusion passes through the notch and is connected to the connecting portion, so that the conductive beam body and the conductive block can be closely fitted, which is further beneficial to improving the conductivity of the conductive beam body, improving the system electrical efficiency, and reducing the residual pole rate.

[0013] In addition, the silver electrolysis device according to the above embodiment of the present invention may also have the following additional technical features:

[0014] In some embodiments of the present invention, the protruding portion has a first through hole, the connecting portion has a second through hole, and the protruding portion and the connecting portion are fixedly connected by bolts passing through the first through hole and the second through hole, thereby further improving the conductivity of the conductive beam body, improving the system electrical efficiency, and reducing the residual pole rate.

[0015] In some embodiments of the present invention, the thickness of the anti-corrosion layer is 1.4 mm to 1.6 mm, thereby protecting the conductive beam body, improving the conductivity of the conductive beam body, improving the system electrical efficiency, and reducing the residual pole rate.

[0016] In some embodiments of the present invention, the thickness of the protrusion is not less than the thickness of the anti-corrosion layer.

[0017] In some embodiments of the present invention, the thickness of the conductive beam body is 2.8 mm to 3.2 mm, thereby ensuring that the strength and conductivity of the conductive beam meet the requirements of large electrode plates and high current density operations.

[0018] In some embodiments of the present invention, the notch of the anti-corrosion layer of the conductive beam is square, and the side length of the notch is 28 mm to 32 mm.

[0019] In some embodiments of the present invention, the other end of the anode plate is placed on the electrolytic cell shell and has a gap between it and the cathode conductive busbar.

[0020] In some embodiments of the present invention, one end of the conductive beam close to the protrusion is placed on the cathode conductive busbar, and the other end of the conductive beam is placed on the electrolytic cell shell with a gap between the conductive beam and the anode conductive busbar.

[0021] In some embodiments of the present invention, the cathode plate is made of titanium, and the anti-corrosion layer is made of the same material as the cathode plate.

[0022] In some embodiments of the present invention, the conductive beam body is made of copper, and the conductive block is made of the same material as the conductive beam body.

[0023] Additional aspects and advantages of the present invention will be given in part in the following description and in part will be obvious from the following description, or will be learned through practice of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS

[0024] The above and / or additional aspects and advantages of the present invention will become apparent and easily understood from the description of the embodiments in conjunction with the following drawings, in which:

[0025] Figure 1 is a top view of a silver electrolysis device according to an embodiment of the present invention;

[0026] Figure 2 is a side view of a silver electrolysis device according to an embodiment of the present invention;

[0027] Figure 3 is a front view of a conductive beam according to an embodiment of the present invention;

[0028] Figure 4 is a side view of a conductive beam according to an embodiment of the present invention;

[0029] Figure 5 is a front view of a conductive block according to an embodiment of the present invention;

[0030] Figure 6 is a side view of a conductive block according to an embodiment of the present invention.

[0031] Reference numerals:

[0032] 10-electrolytic cell shell; 20-cathode conductive busbar; 21-first slot; 30-anode conductive busbar; 31-second slot; 40-conductive block; 41-protrusion; 42-first through hole; 43-bolt; 44-nut; 50-conductive beam; 51-conductive beam body; 511-connecting part; 512-second through hole; 52-anti-corrosion layer; 521-notch; 60-cathode plate; 70-anode plate. DETAILED DESCRIPTION

[0033] Embodiments of the present invention are described in detail below, examples of which are shown in the accompanying drawings, wherein the same or similar reference numerals throughout represent the same or similar elements or elements having the same or similar functions. The embodiments described below with reference to the accompanying drawings are exemplary and are intended to be used to explain the present invention, and should not be construed as limiting the present invention.

[0034] In the description of the present invention, it should be understood that the terms "center", "longitudinal", "lateral", "length", "width", "thickness", "up", "down", "front", "back", "left", "right", "vertical", "horizontal", "top", "bottom", "inside", "outside", "clockwise", "counterclockwise", "axial", "radial", "circumferential" and the like indicate orientations or positional relationships based on the orientations or positional relationships shown in the accompanying drawings, and are only for the convenience of describing the present invention and simplifying the description, and do not indicate or imply that the referred device or element must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be understood as limiting the present invention.

[0035] In addition, the terms "first" and "second" are used for descriptive purposes only and should not be understood as indicating or implying relative importance or implicitly indicating the number of the indicated technical features. Therefore, the features defined as "first" and "second" may explicitly or implicitly include at least one of the features. In the description of the present invention, the meaning of "plurality" is at least two, such as two, three, etc., unless otherwise clearly and specifically defined.

[0036] In the present invention, unless otherwise clearly specified and limited, the terms "installed", "connected", "connected", "fixed" and the like should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium, it can be the internal connection of two elements or the interaction relationship between two elements, unless otherwise clearly defined. For ordinary technicians in this field, the specific meanings of the above terms in the present invention can be understood according to specific circumstances.

[0037] In the present invention, unless otherwise clearly specified and limited, a first feature being "above" or "below" a second feature may mean that the first and second features are in direct contact, or the first and second features are in indirect contact through an intermediate medium. Moreover, a first feature being "above", "above" or "above" a second feature may mean that the first feature is directly above or obliquely above the second feature, or simply means that the first feature is higher in level than the second feature. A first feature being "below", "below" or "below" a second feature may mean that the first feature is directly below or obliquely below the second feature, or simply means that the first feature is lower in level than the second feature.

[0038] In one aspect of the present invention, the present invention provides a silver electrolysis device, which is suitable for production operations in various silver electrolysis refineries. Figure 1-2 The silver electrolysis device includes: an electrolytic cell shell 10, a cathode conductive busbar 20, an anode conductive busbar 30, a conductive block 40, a conductive beam 50, a cathode plate 60 and an anode plate 70.

[0039] The silver electrolysis device according to the embodiment of the present invention is further described in detail below.

[0040] According to an embodiment of the present invention, referring to Figure 1-6 The electrolytic cell shell 10 can be set as a rectangular shell with an open top for placing electrolyte; the cathode conductive busbar 20 can be set at the top of the side wall on one side of the electrolytic cell shell 10, and the anode conductive busbar 30 is set at the top of the side wall on the other side of the electrolytic cell shell 10 and is arranged opposite to the cathode conductive busbar 20; the conductive block 40 is connected to the cathode conductive busbar 20, and a protrusion 41 is provided on one side of the conductive block 40; the conductive beam 50 includes a conductive beam body 51 and an anti-corrosion layer 52, one end of the conductive beam body 51 has a connecting portion 511, the anti-corrosion layer 52 is formed on the surface of the conductive beam body 51 and has a notch 521 corresponding to the connecting portion 511, and the protrusion 41 passes through the notch 521 and is connected to the connecting portion 511; the top of the cathode plate 60 is connected to the anti-corrosion layer 52 at the bottom of the conductive beam 50; one end of the anode plate 70 is connected to the anode conductive busbar 30. By forming an anti-corrosion layer 52 on the surface of the conductive beam body 51, the conductive beam 50 can be prevented from being corroded and producing verdigris during the electrolysis process, thereby improving the conductivity of the conductive beam 50, improving the system electrical efficiency, reducing the residual pole rate, and preventing the produced verdigris from entering the obtained silver powder, solving the problem of excessive copper in the silver powder; in addition, the conductive block 40 is connected to the cathode conductive busbar 20, and a protrusion 41 is provided on one side of the conductive block 40, and a connecting portion 511 is provided at one end of the conductive beam body 51. The anti-corrosion layer 52 is formed on the surface of the conductive beam body 51 and has a notch 521 corresponding to the connecting portion 511. The protrusion 41 passes through the notch 521 on the anti-corrosion layer 52 and is connected to the connecting portion 511 on the conductive beam body 51, so that the conductive beam body 51 can be closely fitted with the conductive block 40, which is further beneficial to improving the conductivity of the conductive beam body 51, improving the system electrical efficiency, and reducing the residual pole rate.

[0041] According to an embodiment of the present invention, referring to Figure 1-2 The cathode conductive busbar 20 has a first slot 21 evenly arranged along its length, and one end of the conductive beam 50 is engaged with the first slot 21, thereby facilitating the installation and removal of the conductive beam 50 and the cathode plate 60. Similarly, the anode conductive busbar 30 has a second slot 31 evenly arranged along its length, and one end of the anode plate 70 is engaged with the second slot 31, thereby facilitating the installation and removal of the anode plate 70. Further, the conductive block 40 can be welded to the cathode conductive busbar 20.

[0042] According to the embodiment of the present invention, the materials of the cathode plate 60 and the anti-corrosion layer 52 are not particularly limited, and those skilled in the art can select them according to actual needs. For example, the material of the cathode plate 60 can be titanium, and the material of the anti-corrosion layer 52 can be the same as the material of the cathode plate 60. Thus, the anti-corrosion layer 52 can prevent the conductive beam body 51 from being corroded during the electrolysis process to produce patina, thereby improving the conductivity of the conductive beam 50, improving the system electrical efficiency, reducing the residual pole rate, and preventing the generated patina from entering the obtained silver powder, thereby solving the problem of excessive copper in the silver powder.

[0043] According to the embodiment of the present invention, the materials of the conductive beam body 51 and the conductive block 40 are not particularly limited, and those skilled in the art can select them according to actual needs. For example, the material of the conductive beam body 51 can be copper, and the material of the conductive block 40 can be the same as that of the conductive beam body 51. This is further beneficial to improving the conductivity of the conductive beam body 51, improving the system electrical efficiency, and reducing the residual pole rate.

[0044] As a specific example, the conductive beam 50 can be obtained by completely and tightly compounding a titanium sleeve and a copper rod through a rolling process. The titanium sleeve forms an anti-corrosion layer 52, and the copper rod forms the conductive beam body 51. It is not easy to delaminate, which can greatly reduce the corrosion of the electrolyte to the conductive beam body 51, and at the same time reduce the current resistance of the conductive beam 50, thereby ensuring the quality of the silver powder.

[0045] According to an embodiment of the present invention, referring to Figure 1-6 The specific way of connecting the protruding portion 41 and the connecting portion 511 is not particularly limited, and those skilled in the art can select it according to actual needs. As a specific example, the protruding portion 41 can have a first through hole 42, and the connecting portion 511 can have a second through hole 512. The protruding portion 41 and the connecting portion 511 are fixedly connected by a bolt 43 that passes through the first through hole 42 and the second through hole 512, and the bolt 43 can be threadedly connected with a nut 44. Thus, the conductive beam body 51 and the conductive block 40 can be closely attached and fixedly connected together by the bolt 43 and the nut 44, which is further beneficial to improve the conductivity of the conductive beam body 51, improve the system efficiency, reduce the residual pole rate, and play a role in fixing the cathode plate 60 through the conductive block 40, so as to prevent the scraper from driving the cathode plate 60 to move forward and backward during the movement of scraping silver powder.

[0046] According to an embodiment of the present invention, the connection method between the top of the cathode plate 60 and the anti-corrosion layer 52 at the bottom of the conductive beam 50 is not particularly limited, and those skilled in the art can choose according to actual needs. As a specific example, the top of the cathode plate 60 can be welded to the anti-corrosion layer 52 at the bottom of the conductive beam 50 using a double-sided seamless welding process.

[0047] According to an embodiment of the present invention, the thickness of the anti-corrosion layer 52 may be 1.4 mm to 1.6 mm, for example, 1.4 mm, 1.42 mm, 1.44 mm, 1.46 mm, 1.48 mm, 1.5 mm, 1.52 mm, 1.54 mm, 1.56 mm, 1.58 mm, 1.6 mm, etc. The inventors have found that if the thickness of the anti-corrosion layer 52 is too large, the resistance of the conductive beam 50 will increase. If the thickness of the anti-corrosion layer 52 is too small, the anti-corrosion layer 52 may be damaged due to collision and wear during installation and removal from the slot, thereby losing the protective effect on the conductive beam body 51. The present invention controls the thickness of the anti-corrosion layer 52 within the above range, which can not only protect the conductive beam body 51, but also improve the conductivity of the conductive beam body 51, improve the system electrical efficiency, and reduce the residual pole rate.

[0048] According to an embodiment of the present invention, the thickness of the protrusion 41 is not less than the thickness of the anti-corrosion layer 52. Thus, the protrusion 41 can pass through the notch 521 on the anti-corrosion layer 52 and fit tightly with the connecting portion 511 on the conductive beam body 51. This is further beneficial to improving the conductivity of the conductive beam body 51, enhancing the system electrical efficiency, and reducing the residual pole rate.

[0049] According to an embodiment of the present invention, the thickness of the conductive beam body 51 is 2.8 mm to 3.2 mm, for example, it can be 2.8 mm, 2.85 mm, 2.9 mm, 2.95 mm, 3.0 mm, 3.05 mm, 3.10 mm, 3.15 mm, 3.2 mm, etc. The inventor found that if the thickness of the conductive beam body 51 is too large, the conductive beam 50 formed will be too thick, and the gap between the cathode scraper and the cathode plate 60 arranged outside the conductive beam 50 will be too large, which will easily lead to the accumulation of electrolytic silver powder and cause a short circuit at the bottom of the electrolysis device; if the thickness of the conductive beam body 51 is too small, it will affect the conductivity and strength of the conductive beam 50. The present invention controls the thickness of the conductive beam body 51 within the above range, which can not only reduce the accumulation of electrolytic silver powder and avoid a short circuit at the bottom of the electrolysis device, but also ensure that the conductivity and strength of the conductive beam 50 can meet the requirements of large plate and high current density operation. It can be understood that other structures of the silver electrolysis device, such as the cathode scraper, are all prior art, so they will not be described one by one here.

[0050] According to an embodiment of the present invention, referring to Figure 3The notch 521 may be square, and the side length of the notch 521 may be 28 mm to 32 mm, for example, 28 mm, 28.5 mm, 29 mm, 29.5 mm, 30 mm, 30.5 mm, 31 mm, 31.5 mm, 32 mm, etc. The inventors have found that by controlling the side length of the notch 521 within the above range, it is possible to ensure that the electrolysis device can be used normally when the silver electrolysis current is increased to the designed maximum value of 1000 A. Furthermore, the shape and size of the protrusion 41 and the connecting portion 511 may be the same as the notch 521, so that the protrusion 41 and the notch 521 are closely fitted to transmit current.

[0051] According to an embodiment of the present invention, referring to Figure 1 The other end of the anode plate 70 can be placed on the top of the side wall of one side of the electrolytic cell shell 10, and there is a gap between the anode plate 70 and the cathode conductive busbar 20 to prevent the anode plate 70 from contacting the cathode conductive busbar 20.

[0052] According to an embodiment of the present invention, referring to Figure 1 One end of the conductive beam 50 close to the protrusion 41 can be placed on the cathode conductive busbar 20, and the other end of the conductive beam 50 can be placed on the top of the side wall on the other side of the electrolytic cell shell 10, with a gap between the conductive beam 50 and the anode conductive busbar 30 to prevent the conductive beam 50 from contacting the anode conductive busbar 30.

[0053] The present invention is described below with reference to specific embodiments. It should be noted that these embodiments are merely illustrative and do not limit the present invention in any way.

[0054] Example 1

[0055] This embodiment provides a silver electrolysis device, referring to Figure 1-6The electrolytic cell shell 10 is a rectangular parallelepiped with an open top. The cathode conductive busbar 20 is arranged on the top of the side wall on one side of the electrolytic cell shell 10. The anode conductive busbar 30 is arranged on the top of the side wall on the other side of the electrolytic cell shell 10 and is arranged opposite to the cathode conductive busbar 20. The cathode conductive busbar 20 has a first card slot 21 evenly arranged along its length direction. One end of the conductive beam 50 is clamped with the first card slot 21. The other end of the conductive beam 50 is placed on the top of the side wall on the other side of the electrolytic cell shell 10, and there is a gap between the conductive block 40 and the cathode conductive busbar 20. A protrusion 41 is provided on one side of the conductive block 40. The conductive beam 50 includes a conductive beam body 51 and an anti-corrosion layer 52. One end of the conductive beam body 51 has a connecting portion 511. The anti-corrosion layer 52 is formed on the surface of the conductive beam body 51. The surface of the cathode plate 60 has a notch 521 corresponding to the connecting portion 511, the cathode plate 60 and the anti-corrosion layer 52 are both made of titanium, the conductive beam body 51 and the conductive block 40 are both made of copper, the protrusion 41 has a first through hole 42, the connecting portion 511 has a second through hole 512, the protrusion 41 and the connecting portion 511 are fixedly connected by a bolt 43 passing through the first through hole 42 and the second through hole 512, the bolt 43 is threadedly connected to the nut 44, the top of the cathode plate 60 and the anti-corrosion layer 52 at the bottom of the conductive beam 50 are welded by a double-sided seamless welding process, the anode conductive busbar 30 has a second card groove 31 evenly arranged along its length direction, one end of the anode plate 70 is carded with the second card groove 31, and the other end of the anode plate 70 is placed on the top of the side wall on one side of the electrolytic cell shell 10, and there is a gap between it and the cathode conductive busbar 20. The thickness of the protrusion 41 and the anti-corrosion layer 52 are both 1.5 mm, the thickness of the conductive beam body 51 is 3 mm, and the notch 521, the protrusion 41 and the connecting portion 511 are all square with a side length of 30 mm.

[0056] The resistance test revealed that the resistance of the cathode device composed of the conductive beam 50 wrapped by the titanium material and the cathode plate 60 was 0.3 ohms.

[0057] Under the conditions of a constant current of 750A, a power-on time of 60 hours, a voltage of 3.7V, 8 silver electrolysis devices in series in a single system, and a total weight of the anode plates loaded in the tank of 1440±20kg, a single cycle of 60 hours, an output of 1150kg of silver powder, a current efficiency of 79%, and a copper content of 12ppm in the silver powder.

[0058] During the one-year use of the silver electrolysis device provided in this embodiment, no verdigris appeared on the conductive beam 50 .

[0059] Comparative Example 1

[0060] The conductive beam body is directly used as the conductive beam, excluding the anti-corrosion layer, which is the same as Example 1. After resistance detection, it is found that the resistance of the cathode device composed of the conductive beam and the cathode plate made of pure copper is 0.4 ohms. Under the conditions of constant current 750A, power-on time of 60 hours, voltage 3.7V, 8 silver electrolysis devices in a single system connected in series, and the total weight of the anode plate tank is 1440±20kg, a single cycle of 60 hours, the output of silver powder is 1100kg, the current efficiency is 74%, and the silver powder contains 26ppm of copper.

[0061] It can be seen from Example 1 and Comparative Example 1 that, under the conditions of the same current intensity, the same power-on time, and the same slot surface operation management, the weight of the silver powder out of the slot in Example 1 is increased by 50 kg on average in a single system and a single cycle compared with Comparative Example 1, and the converted current efficiency is increased by 5%. At the same time, the copper content of the silver powder is reduced from 26 ppm to 12 ppm, indicating that the silver electrolysis device of the present invention can completely prevent the conductive beam 50 from generating verdigris, thereby improving the system current efficiency and the quality of the silver powder.

[0062] In the description of this specification, the description with reference to the terms "one embodiment", "some embodiments", "example", "specific example", or "some examples" etc. means that the specific features, structures, materials or characteristics described in conjunction with the embodiment or example are included in at least one embodiment or example of the present invention. In this specification, the schematic representations of the above terms do not necessarily refer to the same embodiment or example. Moreover, the specific features, structures, materials or characteristics described may be combined in any one or more embodiments or examples in a suitable manner. In addition, those skilled in the art may combine and combine the different embodiments or examples described in this specification and the features of the different embodiments or examples, without contradiction.

[0063] Although the embodiments of the present invention have been shown and described above, it is to be understood that the above embodiments are exemplary and are not to be construed as limitations of the present invention. A person skilled in the art may change, modify, replace and vary the above embodiments within the scope of the present invention.

Claims

1. A silver electrolysis device, characterized in that: include: Electrolyzer shell; A cathode conductive busbar, wherein the cathode conductive busbar is arranged on one side of the electrolytic cell shell; an anode conductive busbar, the anode conductive busbar being arranged on the other side of the electrolytic cell shell and opposite to the cathode conductive busbar; A conductive block, the conductive block is connected to the cathode conductive busbar, and a protrusion is provided on one side of the conductive block; A conductive beam, the conductive beam comprising a conductive beam body and an anti-corrosion layer, one end of the conductive beam body having a connecting portion, the anti-corrosion layer being formed on a surface of the conductive beam body and having a notch corresponding to the connecting portion, the protrusion passing through the notch and connected to the connecting portion; A cathode plate, the top of which is connected to the anti-corrosion layer at the bottom of the conductive beam; An anode plate, one end of which is connected to the anode conductive busbar.

2. The silver electrolysis device according to claim 1, characterized in that: The protruding portion has a first through hole, the connecting portion has a second through hole, and the protruding portion and the connecting portion are fixedly connected by bolts penetrating the first through hole and the second through hole.

3. The silver electrolysis device according to claim 1, characterized in that: The thickness of the anti-corrosion layer is 1.4 mm to 1.6 mm.

4. The silver electrolysis device according to claim 1, characterized in that: The thickness of the protrusion is not less than the thickness of the anti-corrosion layer.

5. The silver electrolysis device according to claim 1, characterized in that: The thickness of the conductive beam body is 2.8 mm to 3.2 mm.

6. The silver electrolysis device according to claim 1, characterized in that: The notch is square, and the side length of the notch is 28 mm to 32 mm.

7. The silver electrolysis device according to claim 1, characterized in that: The other end of the anode plate is placed on the electrolytic cell shell and has a gap between it and the cathode conductive busbar.

8. The silver electrolysis device according to claim 7, characterized in that: One end of the conductive beam close to the protrusion is placed on the cathode conductive busbar, and the other end of the conductive beam is placed on the electrolytic cell shell with a gap between the conductive beam and the anode conductive busbar.

9. The silver electrolysis device according to claim 1, characterized in that: The cathode plate is made of titanium, and the anti-corrosion layer is made of the same material as the cathode plate.

10. The silver electrolysis device according to claim 1, characterized in that: The conductive beam body is made of copper, and the conductive block is made of the same material as the conductive beam body.