Hydrogen production system for improving hydrogen production purity and hydrogen production method thereof
By designing a hydrogen production system including hydrogen preparation module, gas-liquid separation module, impurity removal module, purity detection module and hydrogen storage module, the problems of severe reaction and insufficient hydrogen purity in aluminum powder chemical hydrogen production technology were solved, and the problem of severe reaction and insufficient hydrogen purity was achieved. Improved temperature stability and multi-stage hydrogen removal effect.
Patent Information
- Application Number
- CN202411701705.6
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2024-11-26
- Publication Date
- 2025-02-21
- Estimated Expiration
- Not applicable · inactive patent
AI Technical Summary
The existing chemical hydrogen production technology of aluminum powder has a severe reaction and is difficult to control the temperature, resulting in unstable hydrogen preparation and insufficient hydrogen purity, making it difficult to achieve circulation and decomposition removal.
A hydrogen production system including a hydrogen preparation module, a gas-liquid separation module, a decontamination module, a purity detection module and a hydrogen storage module are designed. The temperature in the preparation box is stabilized by recycling reaction water and cooling and heat dissipation using a refrigeration sheet. At the same time, the hydrogen gas is decomposed through a purity detection module to ensure high purity of hydrogen.
The temperature stability of the hydrogen preparation process is achieved, the purity of hydrogen is improved, the multi-stage impurity removal effect of hydrogen is ensured, and the overall performance of the hydrogen production system is improved.
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Figure CN119488865A_ABST
Abstract
Description
Technical Field
[0001] The present invention relates to the technical field of hydrogen production equipment, and in particular to a hydrogen production system and a hydrogen production method for improving the purity of hydrogen production. Background Art
[0002] As a high-enthalpy energy source, hydrogen energy has attracted much attention in solving energy crises and environmental pollution. Currently, the commercial applications of hydrogen mainly include high-pressure gaseous hydrogen storage, liquid hydrogen storage, and metal hydrogen storage. Among them, high-pressure gaseous hydrogen storage has problems such as low energy density, easy leakage, and poor safety; liquid hydrogen storage has the problem of insulation failure, resulting in short hydrogen storage time and high cost; metal hydrogen storage has the advantages of immediate production and high energy density, and has been widely researched, developed and applied. Hydrogen is regarded as an ideal energy carrier for its advantages such as green, low-carbon, high efficiency, storability and transportability.
[0003] A Chinese patent (publication number: CN115057408A) discloses a hydrogen production device and a hydrogen production method. The application inputs reaction water into the hydrogen production reactor through a first water inlet so that the reaction water reacts with the metal hydrogen storage material to produce hydrogen.
[0004] The existing aluminum water hydrogen production technology is considered to be a low-cost, high hydrogen storage density, and environmentally friendly hydrogen production solution. However, the chemical properties of aluminum powder are relatively active, resulting in violent reactions, high reaction temperatures that are difficult to control, high heat release, and difficulty in heat dissipation, making hydrogen production unstable. In addition, the produced hydrogen is not convenient for recycling and impurity removal, resulting in insufficient purity of the produced hydrogen. Summary of the invention
[0005] The object of the present invention is to provide a hydrogen production system and a hydrogen production method for improving the purity of hydrogen production, so as to solve the problems raised in the above background technology.
[0006] In order to solve the above technical problems, the present invention provides the following technical solutions: a hydrogen production system for improving the purity of hydrogen production, the hydrogen production system for improving the purity of hydrogen production comprises a hydrogen preparation module, a gas-liquid separation module, an impurity removal module, a purity detection module and a hydrogen storage module; The gas-liquid separation module is used to perform gas-liquid separation on the prepared hydrogen; The impurity removal module is used to purify the prepared hydrogen; The purity detection module is used to detect the purity of hydrogen; The hydrogen storage module is used to store hydrogen; The hydrogen preparation module comprises a preparation box, a gas delivery pipe, a reaction water box, a first water pump, a first water suction pipe, a spray pipe, a first water delivery pipe, a second water pump, a second water suction pipe, a second water delivery pipe and a refrigeration plate; An air delivery pipe is installed at the upper part of one side of the preparation box, and a reaction water tank is installed at the bottom of one side of the preparation box, a first water pump and a second water pump are installed on the reaction water tank, the input end of the first water pump is connected to the reaction water tank through a first water suction pipe, a spray pipe is installed at the inner upper part of the preparation box, the output end of the first water pump is connected to the spray pipe through the first water delivery pipe, the input end of the second water pump is connected to the preparation box through the second water suction pipe, the output end of the second water pump is connected to the reaction water tank through the second water delivery pipe, a cooling sheet is installed in the reaction water tank, and when hydrogen is produced in the preparation box, the first water pump is started, and hydrogen is supplied through the first water suction pipe and the first delivery pipe. The water pipe transports the reaction water to the spray pipe, which is convenient for the spray pipe to spray the reaction water toward the metal hydrogen storage material in the preparation box, so as to realize the reaction between the metal hydrogen storage material and the water body to produce hydrogen. At the same time, the second water pump is started during the hydrogen production reaction, and the reaction water that absorbs heat in the preparation box is transported back to the reaction water tank through the second water suction pipe and the second water delivery pipe, so that the refrigeration plate can cool and dissipate the hot water flow, which is beneficial to lowering the water temperature and ensuring the temperature stability in the preparation box during the hydrogen production reaction. In addition, the purity of the produced hydrogen is detected by the purity detection module, and the hydrogen with insufficient purity can be returned to the impurity removal module for further impurity removal, so as to realize multi-stage impurity removal of hydrogen.
[0007] As an optimal technical solution, the first water suction pipe and the second water delivery pipe are arranged in an alternating manner, a rotating column is rotatably installed in the reaction water tank, a plurality of baffles are installed at the bottom of the rotating column, and a stirring blade is installed on the rotating column, the baffle is flush with the first water suction pipe and the second water delivery pipe, and the water flow can push the baffle by utilizing the adsorption force of the first water suction pipe on the water flow and the drainage force of the second water delivery pipe, so that the water flow can push the baffle, and the baffle drives the rotating column to rotate under the force of the water flow, so that the rotating column can drive the stirring blade to stir the reaction water in the reaction water tank, which is beneficial to improving the cooling and heat dissipation treatment of the reaction water by the refrigeration plate.
[0008] As a preferred technical solution, the preparation box is provided with a primary cooling utilization component and a secondary cooling utilization component, and the rapid flow of reaction water in the first water pipe is used to provide operating driving force for the primary cooling utilization component and the secondary cooling utilization component.
[0009] As a preferred technical solution, the cooling first-level utilization component includes a fixed block, a working cylinder, a piston, a connecting pipe, a transmission shaft, a sliding hole, a spiral slideway, a transmission collar, a driving shaft, a driving ring wheel, a rotating shaft, a transmission wheel, a transmission chain and an adsorption fan; A fixed block is installed on the preparation box, a working cylinder is installed on the fixed block, a piston is slidably installed in the working cylinder, and the bottom input end of the working cylinder is connected to the first water pipe through a connecting pipe, the piston is connected to the inner bottom of the working cylinder through a supporting spring, an electrically controlled one-way valve is arranged on the connecting pipe, a transmission shaft is installed on the piston, a sliding hole is opened on the top of the working cylinder, the transmission shaft passes through the sliding hole, and a spiral slideway is arranged on the transmission shaft, a fixed rod is installed on the top of the working cylinder, a transmission ring is rotatably installed on the fixed rod, the transmission shaft passes through the transmission ring, a driving shaft is installed on the transmission ring, the driving shaft is inserted in the spiral slideway, a driving ring wheel is installed on the transmission ring, and the top of the preparation box is rotatably installed A rotating shaft is provided, a transmission wheel is installed on the upper end of the rotating shaft, a transmission chain is sleeved on the driving ring wheel and the transmission wheel, and an adsorption fan is installed on the lower end of the rotating shaft. When the reaction water is rapidly transported in the first water delivery pipe, the first water delivery pipe forms a negative pressure in the working cylinder through the limiting effect of the electrically controlled one-way valve on the connecting pipe, so that the piston can move downward in the working cylinder, and the piston drives the transmission shaft to move downward synchronously. The extrusion force of the spiral slideway on the driving shaft during the movement process can be used to drive the transmission sleeve ring to rotate during the movement process, and the transmission sleeve ring drives the driving ring wheel to rotate. The pulley transmission composed of the driving ring wheel, the transmission wheel and the transmission chain can drive the adsorption fan to rotate, thereby forming an upwelling airflow in the preparation box, which is conducive to the rapid transportation of the prepared hydrogen.
[0010] As a preferred technical solution, an electrically controlled pressure relief valve is installed on the bottom output end of the working cylinder, an end block is installed on the top of the transmission shaft, a touch controller is installed on the lower part of the end block, the touch controller is electrically connected to the electrically controlled pressure relief valve and the electrically controlled one-way valve, and a height sensor is installed on the upper part of the end block, the height sensor is electrically connected to the touch controller, when the touch controller is squeezed, the electrically controlled one-way valve is controlled to be closed and the electrically controlled pressure relief valve is opened, when the height sensor reaches the highest point, the height sensor controls the electrically controlled one-way valve to be opened and the electrically controlled pressure relief valve to be closed through the touch controller, through the cooperation of the height sensor and the touch controller, the piston can move downward under the action of negative pressure and move upward under the elastic force of the supporting spring, which is conducive to the longitudinal reciprocating movement of the piston in the working cylinder, thereby continuously providing operating driving force for the cooling secondary utilization component.
[0011] As a preferred technical solution, the cooling secondary utilization component includes a fixed plate, a slider, a linkage rod, a perforation, a linkage plate, a first transmission column, a rotating disk, a second transmission column and a traction plate; Two fixed plates are symmetrically installed on the inner top of the preparation box, and sliders are slidably installed on the two fixed plates. The two sliders are connected by a spray pipe, and a linkage rod is installed on the slider. A through hole is opened on the preparation box, and the linkage rod passes through the through hole, and a linkage plate is installed on the end of the linkage rod. A first transmission column is installed on the linkage plate, and a turntable is installed on the upper part of the transmission wheel. A second transmission column is eccentrically installed on the turntable, and the first transmission column and the second transmission column are connected by a traction plate. When the transmission wheel rotates, the transmission wheel can drive the turntable to rotate synchronously, and the second transmission column can be driven to move in a circular trajectory during the rotation of the turntable. Through the horizontal movement difference during the movement of the second transmission column, the linkage plate can be driven to move back and forth laterally through the second transmission column, the first transmission column and the traction plate. Since the spray pipe can move laterally through the slider, the linkage plate can drive the spray pipe to move back and forth synchronously laterally through the linkage rod during the movement, which is beneficial for the spray pipe to evenly spray reaction water on the metal hydrogen storage material.
[0012] As a preferred technical solution, both ends of the traction plate are provided with connection holes, and the first transmission column and the second transmission column both pass through the connection holes and are rotationally matched.
[0013] The present invention provides a method for producing hydrogen in a hydrogen production system for improving the purity of hydrogen production, the steps of which are as follows: S10, producing hydrogen through a hydrogen preparation module; S20, performing gas-liquid separation on the produced hydrogen through a gas-liquid separation module to remove moisture in the hydrogen; S30, removing impurities from the hydrogen through an impurity removal module to improve the purity of the hydrogen; S40, the purity of the produced hydrogen is tested through the purity testing module. If it is qualified, it is directly transported to the hydrogen storage module. If it is unqualified, it is returned to the impurity removal module. The purity of the direct hydrogen meets the requirements.
[0014] Compared with the prior art, the beneficial effects achieved by the present invention are: The reaction water is circulated through the first water absorption pipe, the first water delivery pipe, the second water absorption pipe and the second water delivery pipe. The hot water flow is cooled and dissipated by the refrigeration plate, which is beneficial to lowering the water temperature and ensuring the temperature stability in the preparation box during the hydrogen production reaction. In addition, the purity of the produced hydrogen is detected by the purity detection module, and the hydrogen with insufficient purity can be returned to the impurity removal module for further impurity removal, thereby realizing multi-stage impurity removal of hydrogen.
[0015] The longitudinal reciprocating movement of the piston can drive the adsorption fan to rotate, thereby forming an upward airflow in the preparation box, which is conducive to the rapid transportation of the produced hydrogen and can also continuously provide operating driving force for cooling the secondary utilization components.
[0016] When the transmission wheel rotates, the turntable can drive the second transmission column to move in a circular trajectory. Through the horizontal movement difference of the second transmission column, the spray pipe can be driven to move back and forth synchronously, which is beneficial for the spray pipe to evenly spray reaction water on the metal hydrogen storage material. BRIEF DESCRIPTION OF THE DRAWINGS
[0017] The accompanying drawings are used to provide a further understanding of the present invention and constitute a part of the specification. Together with the embodiments of the present invention, they are used to explain the present invention and do not constitute a limitation of the present invention. In the accompanying drawings: Figure 1 It is a schematic diagram of the hydrogen production process of the present invention; Figure 2 It is a schematic diagram of the structure of the preparation box of the present invention from a first viewing angle; Figure 3 is a schematic structural diagram of the preparation box of the present invention from a second viewing angle; Figure 4 It is a schematic diagram of the first cutaway structure of the preparation box of the present invention; Figure 5 It is a second cross-sectional structural schematic diagram of the preparation box of the present invention; Figure 6 yes Figure 3 A is an enlarged structural diagram; Figure 7 yes Figure 5 The enlarged structural diagram at B in FIG. Figure 8 yes Figure 4 The enlarged structural diagram at C in the figure.
[0018] In the figure: 1, preparation box; 2, gas pipe; 3, reaction water box; 4, first water pump; 5, first water suction pipe; 6, spray pipe; 7, first water pipe; 8, second water pump; 9, second water suction pipe; 10, second water pipe; 11, refrigeration plate; 301, rotating column; 302, baffle; 303, stirring blade; 12. Cooling first-stage utilization components; 1201. Fixed block; 1202. Working cylinder; 1203. Piston; 1204. Connecting pipe; 1205. Transmission shaft; 1206. Slide hole; 1207. Spiral slideway; 1208. Transmission sleeve; 1209. Drive shaft; 1210. Drive ring wheel; 1211. Rotating shaft; 1212. Transmission wheel; 1213. Transmission chain; 1214. Adsorption fan; 1215. End block; 1216. Touch controller; 1217. Height sensor; 13. Cooling secondary utilization component; 1301. Fixed plate; 1302. Sliding block; 1303. Linkage rod; 1304. Perforation; 1305. Linkage plate; 1306. First transmission column; 1307. Turntable; 1308. Second transmission column; 1309. Pulling plate; 1310. Connecting hole. DETAILED DESCRIPTION
[0019] The following will be combined with the drawings in the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the present invention.
[0020] Example: Figure 1-Figure 5 As shown, the present invention provides the following technical solutions: a hydrogen production system for improving the purity of hydrogen production and a hydrogen production method thereof, the hydrogen production system for improving the purity of hydrogen production comprises a hydrogen preparation module, a gas-liquid separation module, an impurity removal module, a purity detection module and a hydrogen storage module; The gas-liquid separation module is used to perform gas-liquid separation on the prepared hydrogen; The impurity removal module is used to purify the prepared hydrogen; The purity detection module is used to detect the purity of hydrogen; The hydrogen storage module is used to store hydrogen; The hydrogen preparation module comprises a preparation box 1, a gas delivery pipe 2, a reaction water box 3, a first water pump 4, a first water suction pipe 5, a spray pipe 6, a first water delivery pipe 7, a second water pump 8, a second water suction pipe 9, a second water delivery pipe 10 and a cooling plate 11; An air supply pipe 2 is installed on the upper part of one side of the preparation box 1, and a reaction water tank 3 is installed on the bottom of one side of the preparation box 1, a first water pump 4 and a second water pump 8 are installed on the reaction water tank 3, the input end of the first water pump 4 is connected to the reaction water tank 3 through a first water suction pipe 5, a spray pipe 6 is installed on the inner upper part of the preparation box 1, the output end of the first water pump 4 is connected to the spray pipe 6 through a first water supply pipe 7, the input end of the second water pump 8 is connected to the preparation box 1 through a second water suction pipe 9, the output end of the second water pump 8 is connected to the reaction water tank 3 through a second water supply pipe 10, and a cooling plate 11 is installed in the reaction water tank 3.
[0021] When hydrogen is produced in the preparation box 1, the first water pump 4 is started, and the reaction water is transported to the spray pipe 6 through the first water suction pipe 5 and the first water delivery pipe 7, so that the spray pipe 6 can spray the reaction water toward the metal hydrogen storage material in the preparation box 1, so as to realize the reaction between the metal hydrogen storage material and the water body to produce hydrogen. At the same time, the second water pump 8 is started during the hydrogen production reaction, and the reaction water that absorbs heat in the preparation box 1 is transported back to the reaction water tank 3 through the second water suction pipe 9 and the second water delivery pipe 10, so that the refrigeration plate 11 can cool and dissipate the hot water flow, which is beneficial to lowering the water temperature and ensuring the temperature stability in the preparation box 1 during the hydrogen production reaction. In addition, the purity of the produced hydrogen is detected by the purity detection module, and the hydrogen with insufficient purity can be returned to the impurity removal module for further impurity removal, so as to realize multi-stage impurity removal of hydrogen.
[0022] The first water suction pipe 5 and the second water delivery pipe 10 are arranged in a staggered manner. A rotating column 301 is rotatably installed in the reaction water tank 3. A plurality of baffles 302 are installed at the bottom of the rotating column 301, and a stirring blade 303 is installed on the rotating column 301. The baffle 302 is flush with the first water suction pipe 5 and the second water delivery pipe 10. By utilizing the adsorption force of the first water suction pipe 5 on the water flow and the drainage force of the second water delivery pipe 10, the water flow can push the baffle 302, and the baffle 302 drives the rotating column 301 to rotate under the force of the water flow, so that the rotating column 301 can drive the stirring blade 303 to stir the reaction water in the reaction water tank 3, which is beneficial to improving the cooling and heat dissipation treatment of the reaction water by the refrigeration plate 11.
[0023] The preparation box 1 is provided with a primary cooling utilization component 12 and a secondary cooling utilization component 13 , and the rapid flow of reaction water in the first water pipe 7 is used to provide operating driving force for the primary cooling utilization component 12 and the secondary cooling utilization component 13 .
[0024] like Figure 2-Figure 8 As shown, the cooling primary utilization component 12 includes a fixed block 1201, a working cylinder 1202, a piston 1203, a connecting pipe 1204, a transmission shaft 1205, a sliding hole 1206, a spiral slideway 1207, a transmission collar 1208, a driving shaft 1209, a driving ring wheel 1210, a rotating shaft 1211, a transmission wheel 1212, a transmission chain 1213 and an adsorption fan 1214; The preparation box 1 is provided with a fixed block 1201, a working cylinder 1202 is provided on the fixed block 1201, a piston 1203 is slidably provided in the working cylinder 1202, and the bottom input end of the working cylinder 1202 is connected to the first water delivery pipe 7 through a connecting pipe 1204, the piston 1203 is connected to the inner bottom of the working cylinder 1202 through a supporting spring, an electric-controlled one-way valve is provided on the connecting pipe 1204, a transmission shaft 1205 is provided on the piston 1203, and the top of the working cylinder 1202 is opened. A slide hole 1206 is provided, the transmission shaft 1205 passes through the slide hole 1206, and a spiral slideway 1207 is provided on the transmission shaft 1205. A fixing rod is installed on the top of the working cylinder 1202, and a transmission collar 1208 is rotatably installed on the fixing rod. The transmission shaft 1205 passes through the transmission collar 1208, and a driving shaft 1209 is installed on the transmission collar 1208. The driving shaft 1209 is inserted in the spiral slideway 1207, and a driving ring wheel 1210 is installed on the transmission collar 1208. The preparation box 1 is rotatably mounted with a rotating shaft 1211, a transmission wheel 1212 is mounted on the upper end of the rotating shaft 1211, a transmission chain 1213 is sleeved on the driving ring wheel 1210 and the transmission wheel 1212, and an adsorption fan 1214 is mounted on the lower end of the rotating shaft 1211. When the reaction water is rapidly transported in the first water delivery pipe 7, the first water delivery pipe 7 forms a negative pressure in the working cylinder 1202 through the limiting effect of the electric-controlled one-way valve on the connecting pipe 1204, so that the piston 1203 can move downward in the working cylinder 1202, so that the piston 1203 can move downward in the working cylinder 1202. The driving shaft 1205 moves downward synchronously, and the spiral slide 1207 exerts an extruding force on the driving shaft 1209 during the movement, so that the driving shaft 1205 can drive the driving sleeve 1208 to rotate during the movement, and the driving sleeve 1208 drives the driving ring wheel 1210 to rotate. The pulley transmission composed of the driving ring wheel 1210, the transmission wheel 1212 and the transmission chain 1213 can drive the adsorption fan 1214 to rotate, thereby forming an upward airflow in the preparation box 1, which is beneficial to the rapid transportation of the produced hydrogen.
[0025] An electrically controlled pressure relief valve is installed on the bottom output end of the working cylinder 1202, an end block 1215 is installed on the top of the transmission shaft 1205, a touch controller 1216 is installed at the bottom of the end block 1215, and the touch controller 1216 is electrically connected to the electrically controlled pressure relief valve and the electrically controlled one-way valve, and a height sensor 1217 is installed at the top of the end block 1215, and the height sensor 1217 is electrically connected to the touch controller 1216. When the touch controller 1216 is squeezed, the electrically controlled one-way valve is controlled to close and the electrically controlled pressure relief valve is released. The valve is opened. When the height sensor 1217 reaches the highest point, the height sensor 1217 controls the opening of the electric one-way valve and the closing of the electric pressure relief valve through the touch controller 1216. Through the cooperation of the height sensor 1217 and the touch controller 1216, the piston 1203 can move downward under the action of negative pressure and move upward under the elastic force of the supporting spring, which is conducive to the longitudinal reciprocating movement of the piston 1203 in the working cylinder 1202, thereby continuously providing operating driving force for the cooling secondary utilization component 13.
[0026] like Figure 2-Figure 8 As shown, the cooling secondary utilization component 13 includes a fixing plate 1301, a slider 1302, a linkage rod 1303, a through hole 1304, a linkage plate 1305, a first transmission column 1306, a rotating disk 1307, a second transmission column 1308 and a traction plate 1309; Two fixed plates 1301 are symmetrically installed on the inner top of the preparation box 1, and sliders 1302 are slidably installed on the two fixed plates 1301. The two sliders 1302 are connected by a spray pipe 6. A linkage rod 1303 is installed on the slider 1302. A through hole 1304 is opened on the preparation box 1. The linkage rod 1303 passes through the through hole 1304, and a linkage plate 1305 is installed on the end of the linkage rod 1303. A first transmission column 1306 is installed on the linkage plate 1305, and a turntable 1307 is installed on the upper part of the transmission wheel 1212. A second transmission column 1308 is eccentrically installed on the turntable 1307. The first transmission column 1306 and the second transmission column 1308 are connected by a traction plate 1309 is connected. When the transmission wheel 1212 rotates, the transmission wheel 1212 can drive the turntable 1307 to rotate synchronously. During the rotation of the turntable 1307, the second transmission column 1308 can be driven to move in a circular trajectory. Through the horizontal movement difference during the movement of the second transmission column 1308, the second transmission column 1308, the first transmission column 1306 and the traction plate 1309 can drive the linkage plate 1305 to move back and forth laterally. Since the spray pipe 6 can move laterally through the slider 1302, the linkage plate 1305 can drive the spray pipe 6 to move back and forth laterally synchronously through the linkage rod 1303 during the movement, which is beneficial for the spray pipe 6 to evenly spray the reaction water on the metal hydrogen storage material.
[0027] Both ends of the traction plate 1309 are provided with connection holes 1310 , and the first transmission column 1306 and the second transmission column 1308 both pass through the connection holes 1310 and are rotatably fitted.
[0028] The present invention provides a method for producing hydrogen in a hydrogen production system for improving the purity of hydrogen production, the steps of which are as follows: S10, producing hydrogen through a hydrogen preparation module; S20, performing gas-liquid separation on the produced hydrogen through a gas-liquid separation module to remove moisture in the hydrogen; S30, removing impurities from the hydrogen through an impurity removal module to improve the purity of the hydrogen; S40, the purity of the produced hydrogen is tested through the purity testing module. If it is qualified, it is directly transported to the hydrogen storage module. If it is unqualified, it is returned to the impurity removal module. The purity of the direct hydrogen meets the requirements.
[0029] Working principle of the present invention: When hydrogen is produced in the preparation box 1, the first water pump 4 is started, and the reaction water is transported to the spray pipe 6 through the first water suction pipe 5 and the first water delivery pipe 7, so that the spray pipe 6 can spray the reaction water toward the metal hydrogen storage material in the preparation box 1, so as to realize the reaction between the metal hydrogen storage material and the water body to produce hydrogen. At the same time, the second water pump 8 is started during the hydrogen production reaction, and the reaction water that absorbs heat in the preparation box 1 is transported back to the reaction water tank 3 through the second water suction pipe 9 and the second water delivery pipe 10, so that the refrigeration plate 11 can cool and dissipate the hot water flow, which is beneficial to lowering the water temperature and ensuring the temperature stability in the preparation box 1 during the hydrogen production reaction. In addition, the purity of the produced hydrogen is detected by the purity detection module, and the hydrogen with insufficient purity can be returned to the impurity removal module for further impurity removal, so as to realize multi-stage impurity removal of hydrogen.
[0030] By utilizing the adsorption force of the first water suction pipe 5 on the water flow and the drainage force of the second water delivery pipe 10, the water flow can push the baffle 302, and the baffle 302 drives the rotating column 301 to rotate under the force of the water flow, so that the rotating column 301 can drive the stirring blade 303 to stir the reaction water in the reaction water tank 3, which is beneficial to improving the cooling and heat dissipation treatment of the reaction water by the refrigeration plate 11.
[0031] When the reaction water is rapidly transported in the first water pipe 7, the first water pipe 7 forms a negative pressure in the working cylinder 1202 through the limiting effect of the electrically controlled one-way valve on the connecting pipe 1204, so that the piston 1203 can move downward in the working cylinder 1202, and the piston 1203 drives the transmission shaft 1205 to move downward synchronously. The spiral slide 1207 exerts an extruding force on the drive shaft 1209 during the movement, so that the transmission shaft 1205 can drive the transmission ring 1208 to rotate during the movement, and the transmission ring 1208 drives the driving ring wheel 1210 to rotate. The pulley transmission composed of the driving ring wheel 1210, the transmission wheel 1212 and the transmission chain 1213 can drive the adsorption fan 1214 to rotate, thereby forming an upwelling airflow in the preparation box 1, which is beneficial to the rapid transportation of the produced hydrogen.
[0032] When the touch controller 1216 is squeezed, the electric one-way valve is controlled to close and the electric pressure relief valve is controlled to open. When the height sensor 1217 reaches the highest point, the height sensor 1217 controls the electric one-way valve to open and the electric pressure relief valve to close through the touch controller 1216. Through the cooperation of the height sensor 1217 and the touch controller 1216, the piston 1203 can move downward under the action of negative pressure and move upward under the elastic force of the supporting spring, which is conducive to the longitudinal reciprocating movement of the piston 1203 in the working cylinder 1202, thereby continuously providing operating driving force for the cooling secondary utilization component 13.
[0033] When the transmission wheel 1212 rotates, the transmission wheel 1212 can drive the turntable 1307 to rotate synchronously. During the rotation of the turntable 1307, the second transmission column 1308 can be driven to move in a circular trajectory. Through the horizontal movement difference during the movement of the second transmission column 1308, the second transmission column 1308, the first transmission column 1306 and the traction plate 1309 can drive the linkage plate 1305 to move back and forth laterally. Since the spray pipe 6 can move laterally through the slider 1302, the linkage plate 1305 can drive the spray pipe 6 to move back and forth laterally synchronously through the linkage rod 1303 during the movement, which is beneficial for the spray pipe 6 to evenly spray reaction water on the metal hydrogen storage material.
[0034] It will be apparent to those skilled in the art that the invention is not limited to the details of the exemplary embodiments described above and that the invention can be implemented in other specific forms without departing from the spirit or essential features of the invention. Therefore, the embodiments should be considered exemplary and non-limiting in all respects, and the scope of the invention is defined by the appended claims rather than the foregoing description, and it is intended that all variations falling within the meaning and scope of the equivalent elements of the claims be included in the invention. Any reference numeral in a claim should not be considered as limiting the claim to which it relates.
Claims
1. A hydrogen production system for improving the purity of hydrogen production, characterized in that: The hydrogen production system for improving the purity of hydrogen production comprises a hydrogen preparation module, a gas-liquid separation module, an impurity removal module, a purity detection module and a hydrogen storage module; The gas-liquid separation module is used to perform gas-liquid separation on the prepared hydrogen; The impurity removal module is used to purify the prepared hydrogen; The purity detection module is used to detect the purity of hydrogen; The hydrogen storage module is used to store hydrogen; The hydrogen preparation module comprises a preparation box (1), a gas delivery pipe (2), a reaction water box (3), a first water pump (4), a first water suction pipe (5), a spray pipe (6), a first water delivery pipe (7), a second water pump (8), a second water suction pipe (9), a second water delivery pipe (10) and a cooling plate (11); An air delivery pipe (2) is installed at the upper part of one side of the preparation box (1), and a reaction water tank (3) is installed at the bottom of one side of the preparation box (1). A first water pump (4) and a second water pump (8) are installed on the reaction water tank (3). The input end of the first water pump (4) is connected to the reaction water tank (3) through a first water suction pipe (5). A spray pipe (6) is installed at the upper inner part of the preparation box (1). The output end of the first water pump (4) is connected to the spray pipe (6) through a first water delivery pipe (7). The input end of the second water pump (8) is connected to the preparation box (1) through a second water suction pipe (9). The output end of the second water pump (8) is connected to the reaction water tank (3) through a second water delivery pipe (10). A cooling plate (11) is installed in the reaction water tank (3).
2. A hydrogen production system for improving the purity of hydrogen production according to claim 1, characterized in that: The first water absorption pipe (5) and the second water delivery pipe (10) are arranged in a staggered manner. A rotating column (301) is rotatably installed in the reaction water tank (3). A plurality of baffles (302) are installed at the bottom of the rotating column (301). A stirring blade (303) is installed on the rotating column (301). The baffles (302) are flush with the first water absorption pipe (5) and the second water delivery pipe (10).
3. A hydrogen production system for improving the purity of hydrogen production according to claim 1, characterized in that: The preparation box (1) is provided with a primary cooling utilization component (12) and a secondary cooling utilization component (13), and the rapid flow of reaction water in the first water delivery pipe (7) is used to provide operating driving force for the primary cooling utilization component (12) and the secondary cooling utilization component (13).
4. A hydrogen production system for improving the purity of hydrogen production according to claim 3, characterized in that: The cooling primary utilization component (12) comprises a fixed block (1201), a working cylinder (1202), a piston (1203), a connecting pipe (1204), a transmission shaft (1205), a sliding hole (1206), a spiral slideway (1207), a transmission collar (1208), a driving shaft (1209), a driving ring wheel (1210), a rotating shaft (1211), a transmission wheel (1212), a transmission chain (1213) and an adsorption fan (1214); The preparation box (1) is provided with a fixed block (1201), a working cylinder (1202) is provided on the fixed block (1201), a piston (1203) is slidably provided in the working cylinder (1202), and the bottom input end of the working cylinder (1202) is connected to the first water delivery pipe (7) via a connecting pipe (1204), the piston (1203) is connected to the inner bottom of the working cylinder (1202) via a supporting spring, an electrically controlled one-way valve is provided on the connecting pipe (1204), a transmission shaft (1205) is provided on the piston (1203), a sliding hole (1206) is provided on the top of the working cylinder (1202), the transmission shaft (1205) passes through the sliding hole (1206), and a spiral slideway (1203) is provided on the transmission shaft (1205). 7), a fixed rod is installed on the top of the working cylinder (1202), a transmission ring (1208) is rotatably installed on the fixed rod, the transmission shaft (1205) passes through the transmission ring (1208), a drive shaft (1209) is installed on the transmission ring (1208), the drive shaft (1209) is inserted in the spiral slideway (1207), a drive ring wheel (1210) is installed on the transmission ring (1208), a rotating shaft (1211) is rotatably installed on the top of the preparation box (1), a transmission wheel (1212) is installed on the upper end of the rotating shaft (1211), a transmission chain (1213) is sleeved on the drive ring wheel (1210) and the transmission wheel (1212), and an adsorption fan (1214) is installed on the lower end of the rotating shaft (1211).
5. A hydrogen production system for improving the purity of hydrogen production according to claim 4, characterized in that: An electrically controlled pressure relief valve is installed at the bottom output end of the working cylinder (1202); an end block (1215) is installed at the top of the transmission shaft (1205); a touch controller (1216) is installed at the bottom of the end block (1215); the touch controller (1216) is electrically connected to the electrically controlled pressure relief valve and the electrically controlled one-way valve; a height sensor (1217) is installed at the top of the end block (1215); the height sensor (1217) is electrically connected to the touch controller (1216); when the touch controller (1216) is squeezed, the electrically controlled one-way valve is controlled to be closed and the electrically controlled pressure relief valve is opened; when the height sensor (1217) reaches the highest point, the height sensor (1217) controls the electrically controlled one-way valve to be opened and the electrically controlled pressure relief valve to be closed through the touch controller (1216).
6. A hydrogen production system for improving the purity of hydrogen production according to claim 5, characterized in that: The cooling secondary utilization component (13) comprises a fixing plate (1301), a sliding block (1302), a linkage rod (1303), a perforation (1304), a linkage plate (1305), a first transmission column (1306), a rotating disk (1307), a second transmission column (1308) and a traction plate (1309); Two fixed plates (1301) are symmetrically mounted on the inner top of the preparation box (1), and sliders (1302) are slidably mounted on the two fixed plates (1301). The two sliders (1302) are connected via a spray pipe (6), and a linkage rod (1303) is mounted on the slider (1302). A through hole (1304) is provided on the preparation box (1), and the linkage rod (1303) passes through the through hole (1304). A linkage plate (1305) is mounted on the end of the linkage rod (1303), and a first transmission column (1306) is mounted on the linkage plate (1305). A rotating disk (1307) is mounted on the upper part of the transmission wheel (1212), and a second transmission column (1308) is eccentrically mounted on the rotating disk (1307). The first transmission column (1306) and the second transmission column (1308) are connected via a traction plate (1309).
7. A hydrogen production system for improving the purity of hydrogen production according to claim 6, characterized in that: Both ends of the traction plate (1309) are provided with connection holes (1310), and the first transmission column (1306) and the second transmission column (1308) both pass through the connection holes (1310) and are rotatably matched.
8. A method for producing hydrogen in a hydrogen production system for improving the purity of hydrogen production according to any one of claims 1 to 7, comprising the steps of: S10, producing hydrogen through a hydrogen preparation module; S20, performing gas-liquid separation on the produced hydrogen through a gas-liquid separation module to remove moisture in the hydrogen; S30, removing impurities from the hydrogen through an impurity removal module to improve the purity of the hydrogen; S40, the purity of the produced hydrogen is tested through the purity testing module. If it is qualified, it is directly transported to the hydrogen storage module. If it is unqualified, it is returned to the impurity removal module. The purity of the direct hydrogen meets the requirements.
Citation Information
Patent Citations
Hydrogen production device and hydrogen production method
CN115057408A
Cited By
Beverage equipment flushing wastewater treatment equipment and treatment method
CN119841509A
