Water-based scorching treatment agent and preparation method thereof

The aqueous scalding treatment agent is prepared by polymerizing emulsifier and monomer, and combined with thickener and pH adjustment, the environmental protection and complex operation of traditional solvent-based treatment agents is solved, achieving more stable scalding effects and higher environmentally friendly performance.

CN119490622APending Publication Date: 2025-02-21ZHEJIANG XINNUO POLYMER MATERIAL CO LTD
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Patent Information

Application Number
CN202411833316.9
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-12-13
Publication Date
2025-02-21

AI Technical Summary

Technical Problem

Traditional solvent-based hot-cooling treatment agents have problems such as poor environmental protection, complex operation and unstable hot-cooling effect, especially under high temperature conditions.

Method used

The emulsifier is used to polymerize with mixed monomers to prepare an aqueous scalding treatment agent, and the pH value is adjusted to neutral or weakly alkaline by adding organic and inorganic thickening agents and auxiliary additives.

Benefits of technology

It improves the environmental protection performance and use safety of the hot coke treatment agent, ensures the stability and adhesion of the product in application, and reduces the emission of volatile organic compounds.

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Abstract

The invention discloses a water-based scorching treatment agent and a preparation method thereof, and the preparation method comprises the following steps: S100, carrying out polymerization reaction treatment on an emulsifier and a mixed monomer to obtain a scorching treatment agent emulsion; s200, an organic thickening agent and an inorganic thickening agent are mixed for treatment, and a scorching treatment agent thickening agent is obtained; s300, stirring and mixing the prepared scorching treatment agent emulsion with deionized water to obtain a scorching treatment agent mother solution; s400, adding a scorching treatment agent thickening agent and an auxiliary additive into the scorching treatment agent mother liquor to obtain a water-based scorching treatment agent; and S500, the pH value of the water-based scorching treatment agent is adjusted to be neutral or alkalescent. According to the invention, the use of an organic solvent in the scorching treatment agent can be reduced, the environmental protection property and the operation safety are better, and the stability of the treatment effect can be improved at the same time.
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Description

Technical Field

[0001] The present invention relates to the field of chemical materials, in particular to the field of surface treatment agents. Background Art

[0002] In the traditional surface treatment field, scorching treatment agents are often mainly solvent-based. Although this type of treatment agent can provide a good scorching effect, it contains a large amount of organic solvents, which easily volatilize harmful gases during use, endangering human health and polluting the environment. Especially in the process of high-temperature treatment, the volatility problem of solvent-based treatment agents is more prominent. The shortcomings of existing technologies are mainly concentrated in the following aspects: poor environmental protection: solvent-based treatment agents contain a large amount of organic volatiles, which are not friendly to the environment and have safety hazards; complex operation: solvent-based treatment agents require strict operating specifications during use to avoid the release of harmful gases and the risk of explosion; unstable scorching effect: after traditional treatment agents are treated under high temperature conditions, the scorching effect often fluctuates due to uneven solvent evaporation rate, affecting the consistency of product quality.

[0003] Based on the above shortcomings of the existing technology, the development of a water-based scorch treatment agent to replace the traditional solvent-based products has become the direction of technological development. The water-based treatment agent not only reduces the use of organic solvents, has better environmental protection and operational safety, but also improves the stability of the treatment effect. Summary of the invention

[0004] The purpose of the embodiments of the present application is to provide a water-based scorch treatment agent and a preparation method thereof, which can solve the problem that solvent-based treatment agents contain a large amount of organic volatiles, are unfriendly to the environment, and have safety hazards.

[0005] In order to solve the above technical problems, the embodiments of the present application are implemented as follows:

[0006] The present application provides a method for preparing an aqueous scorch treatment agent, which may include the following steps S100 to S500.

[0007] S100, using an emulsifier and a mixed monomer to perform a polymerization reaction to obtain a scorch treatment agent emulsion;

[0008] S200, mixing an organic thickener with an inorganic thickener to obtain a scorch treatment agent thickener;

[0009] S300, stirring and mixing the prepared scorch treatment agent emulsion with deionized water to obtain a scorch treatment agent mother solution;

[0010] S400, adding a thickener and auxiliary additives of the scorch treatment agent to the scorch treatment agent mother liquor to obtain an aqueous scorch treatment agent;

[0011] S500, adjust the pH value of the water-based scorch treatment agent to neutral or weak alkaline.

[0012] In the above technical solution, S100 specifically includes:

[0013] S110, adding a nonionic emulsifier to deionized water to obtain an emulsion;

[0014] S120, mixing a plurality of monomers with the emulsion to obtain a first mixed solution, wherein the monomers include: acrylic acid, methyl methacrylate, and butyl acrylate;

[0015] S130, initiating a polymerization reaction, dissolving an initiator in water, and adding the first mixed solution to obtain a scorch treatment agent emulsion;

[0016] S140, using a pH regulator to adjust the pH value of the scorch treatment agent emulsion.

[0017] In the above technical solution, S100 specifically includes:

[0018] S110, add 140-150 parts of deionized water to the reactor, start the agitator, gradually add 2-3 parts of non-ionic emulsifier, maintain the temperature between 40-50° C., and stir for 30 minutes to ensure that the non-ionic emulsifier is completely dissolved to form a stable liquid phase;

[0019] S120, gradually adding 25-30 parts of acrylic acid, 30-35 parts of methyl methacrylate, 35-40 parts of butyl acrylate and 20-25 parts of styrene into the reaction kettle, and continuously stirring to ensure that each monomer is evenly dispersed in the liquid phase;

[0020] S130, dissolving 0.5-1 part of initiator in a small amount of deionized water, slowly adding it dropwise to the reaction kettle to initiate free radical polymerization of the monomer, maintaining the reaction temperature at 80-90° C., and continuously stirring for 2-3 hours;

[0021] S140. Use an appropriate amount of pH regulator to adjust the pH value of the scorch treatment agent emulsion to 7-8.

[0022] In the above technical solution, S200 specifically includes:

[0023] S210, mixing water and bentonite to prepare an inorganic thickener solution;

[0024] S220, mixing water and hydroxyethyl cellulose to prepare an organic thickener solution;

[0025] S230, mixing the inorganic thickener solution and the organic thickener solution, adding a pH regulator, and obtaining a scorch treatment agent thickener.

[0026] In the above technical solution, S200 specifically includes:

[0027] S210, taking 80-90 parts of water and adding them into the first stirring tank, slowly adding 5-8 parts of bentonite and 0.5-2 parts of dispersant during stirring, and continuing stirring for 30-60 minutes after the addition is completed to obtain an inorganic thickener solution;

[0028] S220, add 25-30 parts of water into a second stirring tank, maintain 30-40° C., gradually add 2-3 parts of hydroxyethyl cellulose, and stir for 30 minutes to obtain an organic thickener solution;

[0029] S230, mixing the inorganic thickener solution and the organic thickener solution in a mass ratio of inorganic thickener solution: organic thickener solution = 3:1, continuing stirring for 20-30 minutes, adding a pH adjuster to adjust the pH to 7-8, and obtaining a scorch treatment agent thickener.

[0030] In the above technical solution, S300 specifically includes:

[0031] Add 10 parts of deionized water into the stirrer, start stirring, gradually add 80 parts of the scorch treatment agent emulsion, keep the stirring speed at 300-500 rpm, and after stirring for 20-30 minutes, obtain the scorch treatment agent mother liquor.

[0032] In the above technical solution, S400 specifically includes:

[0033] S400, slowly add 1.5 parts of defoamer, 2 parts of thickener, 1 part of wetting agent and 0.5 part of preservative to 90 parts of the mother liquor of the scorch treatment agent in sequence to obtain a water-based scorch treatment agent.

[0034] In the above technical solution, S500 specifically includes:

[0035] S500, adjust the pH value and viscosity, stir for 30 minutes, detect the pH value, and adjust the system to neutral or weak alkaline with a pH adjuster.

[0036] Beneficial Effects

[0037] This application adopts an aqueous medium and a reasonable emulsion polymerization process. The method can effectively improve the environmental performance and safety of the scorch treatment agent, ensure the stability and adhesion of the product in the application, and compared with traditional treatment agents using organic solvents, this method can better reduce volatile organic compound (VOC) emissions and reduce environmental pollution and human health hazards caused by organic solvents. DETAILED DESCRIPTION

[0038] The purpose of the present invention is to provide a high-performance scorch treatment agent emulsion to effectively improve the stability, processability and performance of the final product of the material. Scorch treatment agents play a vital role in various industrial applications, especially in enhancing the durability and adaptability of materials. The present invention combines the advantages of various monomers and emulsifiers through an innovative process flow, aiming to provide a scorch treatment agent emulsion with excellent performance and environmental friendliness.

[0039] To achieve the above object, the method adopted by the present invention is to add a nonionic emulsifier with excellent emulsification performance to deionized water, then mix a plurality of monomers with the emulsion, and initiate a polymerization reaction to obtain the desired emulsion.

[0040] In the above technical solution, S100 specifically includes:

[0041] S110. Add nonionic emulsifier to deionized water to obtain a uniform emulsion. Nonionic emulsifiers have good biocompatibility and degradability, which is essential for improving the environmental protection characteristics of the emulsion. In addition, nonionic emulsifiers also have good stability and can effectively reduce the surface tension between the liquid phase and the gas phase, preventing the emulsion from stratification and precipitation during storage;

[0042] S120, mixing a plurality of monomers with the emulsion to obtain a first mixed solution. The monomers include acrylic acid, methyl methacrylate, butyl acrylate, etc.;

[0043] S130, initiating a polymerization reaction, dissolving an initiator in water, and adding the first mixed solution to obtain the scorch treatment agent emulsion;

[0044] S140, using a pH regulator to adjust the pH value of the scorch treatment agent emulsion.

[0045] Preferably, S100 specifically includes:

[0046] S110, add 140-150 parts of deionized water to the reactor, start the stirrer, and gradually add 2-3 parts of non-ionic emulsifiers, such as polyethoxylated alkylphenols, alkyl polysaccharides or fatty acid soaps. These emulsifiers not only have good biodegradability, but also provide good stability during the emulsion formation process. Keep the temperature between 40-50°C and continue stirring for 30 minutes to ensure that the emulsifier is completely dissolved and a stable liquid phase is formed, thereby effectively avoiding the occurrence of stratification and precipitation;

[0047] S120, gradually adding 25-30 parts of acrylic acid, 30-35 parts of methyl methacrylate, 35-40 parts of butyl acrylate and 20-25 parts of styrene into the reaction kettle, ensuring continuous stirring during the mixing process to ensure that the monomers are evenly dispersed in the liquid phase to avoid agglomeration;

[0048] S130, when initiating the polymerization reaction, dissolve 0.5-1 part of ammonium persulfate in a small amount of deionized water, and slowly add it to the reactor to start the free radical polymerization reaction. At this time, the reaction temperature needs to be maintained at 80-90°C, and stirring is continued for 2-3 hours until the viscosity of the emulsion increases significantly, indicating that the monomer has been completely polymerized to form an emulsion;

[0049] S140, during the post-treatment and pH adjustment process, use an appropriate amount of pH regulator to adjust the pH value of the emulsion to 7-8 to ensure the stability of the emulsion during storage and use and prevent performance degradation caused by pH changes. This step helps to improve the compatibility of the emulsion and make it show excellent stability in a variety of application environments.

[0050] The reason for adopting the above steps is that through precise reaction conditions and component ratios, the excellent performance of the scorch treatment agent emulsion can be ensured. This emulsion can not only effectively enhance the material's resistance to hydrolysis, but also improve the material's durability and processing performance, thereby adapting to a wider range of application needs. Ultimately, the resulting scorch treatment agent emulsion will have efficient processing performance and good environmental characteristics.

[0051] Considering the poor compatibility of common thickeners with the scorch treatment agent of the present invention and the lack of environmental protection, the present invention provides an efficient thickener for the scorch treatment agent to improve the rheological properties and application effect of the scorch treatment agent. Through reasonable formula design and process steps, the present invention can effectively improve the performance of the thickener.

[0052] In the above technical solution, S200 specifically includes:

[0053] S210, mixing water and bentonite to prepare the inorganic thickener solution;

[0054] S220, mixing water and hydroxyethyl cellulose to prepare the organic thickener solution;

[0055] S230, mixing the inorganic thickener solution and the organic thickener solution, adding a pH regulator, and obtaining the scorch treatment agent thickener.

[0056] The specific steps are as follows:

[0057] S210, take 80-90 parts of water and add them to a stirring tank, and slowly add 5-8 parts of bentonite during stirring. In order to ensure the good dispersion of bentonite, 0.5-2 parts of dispersants (such as sodium hexametaphosphate, sodium pyrophosphate or sodium tripolyphosphate) are added simultaneously, and these dispersants can effectively reduce the mutual attraction between bentonite particles and help them to disperse better. Continue stirring for 30-60 minutes until bentonite is fully dispersed to form a uniform inorganic colloid. At this point, bentonite should be fully hydrated to form a good thickening matrix to enhance the stability and effectiveness of subsequent thickeners.

[0058] S220. In another container, add 25-30 parts of water and heat it to 30-40°C to increase the dissolution rate of hydroxyethyl cellulose. Subsequently, gradually add 2-3 parts of hydroxyethyl cellulose and stir slowly to avoid the formation of lumps. During this process, it is necessary to maintain uniform stirring to ensure that the hydroxyethyl cellulose is completely dissolved in the water. After about 30 minutes of stirring, a viscous transparent solution is finally formed. Since hydroxyethyl cellulose is a heat-sensitive material, excessively high temperatures may cause it to degrade and produce by-products, affecting its thickening properties and the quality of the final product. Within the range of 30-40°C, this thermal degradation phenomenon can be effectively avoided to ensure that its functionality is maintained.

[0059] S230. Mix the dispersed inorganic part with the organic part and continue stirring for 20-30 minutes to ensure that the two parts are evenly combined. During the mixing process, gradually add 0.2-0.5 parts of pH regulator (such as sodium hydroxide, potassium hydroxide, ammonia or citric acid) to adjust the pH value of the system to between 8 and 9. This adjustment helps to enhance the thickening effect of bentonite and stabilize the thickening performance of hydroxyethyl cellulose. The appropriate pH value can improve the rheological properties of the thickener, improve its performance in practical applications, and ensure that the scorch treatment agent has good fluidity and stability.

[0060] Through the above steps, the prepared thickener for scorch treatment agent can not only significantly improve the viscosity and stability of the treatment agent, but also provide better performance support for subsequent industrial applications. This efficient thickener has broad prospects in the application of coatings, inks and other related fields, and can meet the needs of different customers.

[0061] In the above technical solution, S300 specifically includes:

[0062] S300, prepare a mother solution, add 10 parts of deionized water into a stirrer, start stirring, gradually add 80 parts of the emulsion, maintain the stirring speed at 300-500 rpm, and continue stirring for 20-30 minutes.

[0063] In the above technical solution, S400 specifically includes:

[0064] S400, add auxiliary additives, continue stirring, and slowly add 1.5 parts of defoamer (polydimethylsiloxane, polydimethylsiloxane can be used as the defoamer), 2 parts of thickener, 1 part of wetting agent (fatty alcohol polyoxyethylene ether, nonylphenol polyoxyethylene ether) and 0.5 parts of preservative (isothiazolinone preservatives, sodium benzoate, methylisothiazolinone and phenoxyethanol combination) in turn to ensure that each ingredient is fully dispersed.

[0065] Among them, the defoaming agent can use polydimethylsiloxane, alcohol defoaming agent (isomeric alkanol: such as n-pentanol, n-hexanol), fatty acid ester defoaming agent, ethyl hexyl ester, glycerol ester, silicon-based defoaming agent, natural defoaming agent (such as vegetable oil-based defoaming agent, modified starch), surfactant defoaming agent (such as polyether).

[0066] Preferably, polydimethylsiloxane (PDMS) is used mainly because of its excellent defoaming performance and good chemical stability. This defoamer can effectively reduce the surface tension of the liquid, thereby improving the uniformity and effect of the treatment agent. In addition, PDMS has good temperature resistance and wide compatibility.

[0067] The wetting agent may include fatty alcohol polyoxyethylene ether, nonylphenol polyoxyethylene ether, polyvinyl alcohol (PVA), polyether-modified silicone oil, nonionic surfactant (such as hexadecyl alcohol polyoxyethylene ether), fatty acid polyoxyethylene ether and alcohol ether wetting agent.

[0068] Preferably, fatty alcohol polyoxyethylene ether has good biocompatibility and is suitable for water-based formulations. It can effectively reduce the surface tension of the liquid, thereby improving the wettability and dispersibility of the treatment agent. Nonylphenol polyoxyethylene ether has strong wetting and emulsifying ability, which can enhance the contact between the liquid and the substrate and ensure uniform coating. These two wetting agents perform well in a variety of industrial applications and have good compatibility with other ingredients.

[0069] As the preservative, a combination of isothiazolinone preservatives, sodium benzoate, methylisothiazolinone and phenoxyethanol can be used.

[0070] Preferably, the combination of methylisothiazolinone and phenoxyethanol has excellent broad-spectrum antibacterial properties and stability. This combination can effectively inhibit the growth of various bacteria and fungi, thereby improving the shelf life and safety of the treatment agent.

[0071] In the above technical solution, S500 specifically includes:

[0072] S500, adjust the pH value and viscosity, stir for 30 minutes, detect the pH value, and adjust the system to neutral or weak alkaline with a pH adjuster.

[0073] Example 1

[0074] This embodiment provides a water-based scorch treatment agent, which is prepared by the following steps:

[0075] S1. Add 150 parts of deionized water into the reactor, start the agitator, gradually add 3 parts of polyethoxylated alkylphenol, which are all biodegradable emulsifiers, keep the temperature between 40-50°C, stir for 30 minutes, and form a stable liquid phase.

[0076] S2. 30 parts of acrylic acid, 30 parts of methyl methacrylate, 40 parts of butyl acrylate and 20 parts of styrene are gradually added into the reaction kettle, and stirring is continued to ensure that each monomer is evenly dispersed in the liquid phase.

[0077] S3. Initiate polymerization reaction: dissolve 0.5 parts of ammonium persulfate in a small amount of deionized water, slowly add it to the reactor, start the free radical polymerization reaction of the monomer, keep the reaction temperature at 80°C, and continue stirring for 3 hours until the viscosity of the emulsion increases significantly and the monomer is completely polymerized to form an emulsion.

[0078] S4. Use an appropriate amount of pH regulator to adjust the pH value of the emulsion to 7 to obtain a scorch treatment agent emulsion.

[0079] S5. Take 80 parts of water and add it into a stirring tank. During the stirring process, slowly add 5 parts of bentonite and 0.5 parts of sodium hexametaphosphate to help the bentonite to disperse better. Continue stirring for 30 minutes until the bentonite is completely dispersed to form a uniform inorganic colloid.

[0080] S6. In another container, add 25 parts of water, maintain 30°C, gradually add 2 parts of hydroxyethyl cellulose, stir slowly to avoid the formation of lumps, stir for 30 minutes to ensure that the hydroxyethyl cellulose is completely dissolved to form a viscous transparent solution.

[0081] S7. Mix the dispersed inorganic part with the organic part and continue stirring for 20 minutes to ensure that the two parts are evenly combined. During the mixing process, add 0.2-0.5 parts of ammonia water to gradually adjust the pH value so that the pH value of the system is adjusted to 8.

[0082] S8. Add 10 parts of deionized water into the stirrer, start stirring, gradually add 80 parts of the emulsion, maintain the stirring speed at 300 rpm, and continue stirring for 30 minutes to obtain a scorch treatment agent thickener.

[0083] S9. Slowly add 1.5 parts of polydimethylsiloxane, 2 parts of scorch treatment agent thickener, 1 part of fatty alcohol polyoxyethylene ether and 0.5 parts of isothiazolinone preservative in sequence.

[0084] S10, adjusting the pH value and viscosity, stirring for 30 minutes, detecting the pH value, and adjusting the system to neutral with ammonia water to obtain a water-based scorch treatment agent.

[0085] Example 2

[0086] This embodiment provides a water-based scorch treatment agent, which is prepared by the following steps:

[0087] S1. Add 150 parts of deionized water into the reaction kettle, start the stirrer, gradually add 3 parts of polyethoxylated alkylphenol, maintain the temperature between 40-50°C, stir for 30 minutes, and form a stable liquid phase.

[0088] S2. 30 parts of acrylic acid, 30 parts of methyl methacrylate, 40 parts of butyl acrylate and 20 parts of styrene are gradually added into the reaction kettle, and stirring is continued to ensure that each monomer is evenly dispersed in the liquid phase.

[0089] S3. Initiate polymerization reaction: dissolve 0.5 parts of ammonium persulfate in a small amount of deionized water, slowly add it to the reactor, start the free radical polymerization reaction of the monomer, keep the reaction temperature at 80°C, and continue stirring for 3 hours until the viscosity of the emulsion increases significantly and the monomer is completely polymerized to form an emulsion.

[0090] S4. Use an appropriate amount of pH regulator to adjust the pH value of the emulsion to 7 to obtain a scorch treatment agent emulsion.

[0091] S5. Take 80 parts of water and add it into a stirring tank. During the stirring process, slowly add 5 parts of bentonite and 0.5 parts of sodium hexametaphosphate to help the bentonite to disperse better. Continue stirring for 30 minutes until the bentonite is completely dispersed to form a uniform inorganic colloid.

[0092] S6. In another container, add 25 parts of water, maintain 30°C, gradually add 2 parts of hydroxyethyl cellulose, stir slowly to avoid the formation of lumps, stir for 30 minutes to ensure that the hydroxyethyl cellulose is completely dissolved to form a viscous transparent solution.

[0093] S7. Mix the dispersed inorganic part with the organic part and continue stirring for 20 minutes to ensure that the two parts are evenly combined. During the mixing process, add 0.2-0.5 parts of ammonia water to gradually adjust the pH value so that the pH value of the system is adjusted to 8.

[0094] S8. Add 10 parts of deionized water into the stirrer, start stirring, gradually add 80 parts of the emulsion, maintain the stirring speed at 300 rpm, and continue stirring for 30 minutes to obtain a scorch treatment agent thickener.

[0095] S9. Slowly add in sequence 1.5 parts of polydimethylsiloxane, 2 parts of scorch treatment agent thickener, 1 part of nonylphenol polyoxyethylene ether and 0.5 parts of a combination of methylisothiazolinone and phenoxyethanol (the mass ratio of methylisothiazolinone to phenoxyethanol is 1:1).

[0096] S10, adjusting the pH value and viscosity, stirring for 30 minutes, detecting the pH value, and adjusting the system to neutral with ammonia water to obtain a water-based scorch treatment agent.

[0097] Comparative Example 1

[0098] This comparative example provides a water-based scorch treatment agent, which is prepared by the following steps:

[0099] S1. Add 150 parts of deionized water into the reactor, start the agitator, gradually add 3 parts of polyethoxylated alkylphenol, which are all biodegradable emulsifiers, keep the temperature between 40-50°C, stir for 30 minutes, and form a stable liquid phase.

[0100] S2. 30 parts of acrylic acid, 30 parts of methyl methacrylate, 40 parts of butyl acrylate and 20 parts of styrene are gradually added into the reaction kettle, and stirring is continued to ensure that each monomer is evenly dispersed in the liquid phase.

[0101] S3. Initiate polymerization reaction: dissolve 0.5 parts of ammonium persulfate in a small amount of deionized water, slowly add it to the reactor, start the free radical polymerization reaction of the monomer, keep the reaction temperature at 80°C, and continue stirring for 3 hours until the viscosity of the emulsion increases significantly and the monomer is completely polymerized to form an emulsion.

[0102] S4. Use an appropriate amount of pH regulator to adjust the pH value of the emulsion to 7 to obtain a scorch treatment agent emulsion.

[0103] S5. Add 10 parts of deionized water into the stirrer, start stirring, gradually add 80 parts of the emulsion, maintain the stirring speed at 300 rpm, and continue stirring for 30 minutes to obtain a scorch treatment agent thickener.

[0104] S6. Slowly add 1.5 parts of polydimethylsiloxane, 2 parts of hydroxyethyl cellulose, 1 part of fatty alcohol polyoxyethylene ether and 0.5 parts of isothiazolinone preservative in sequence.

[0105] S7. Adjust the pH value and viscosity, stir for 30 minutes, detect the pH value, and adjust the system to neutral with ammonia water to obtain a water-based scorch treatment agent.

[0106] Performance Testing

[0107] The performance test results of the samples obtained in Examples 1 to 2 and Comparative Example 1 are listed in Table 1. VOC and TVOC: VOC and TVOC content tests were performed using a GC-MS mass spectrometer in accordance with GS 97014-3 standard.

[0108] Table 1

[0109] Performance Indicators Example 1 Example 2 Comparative Example 1 Viscosity (cps / 25℃) 1210 1180 1100 <![CDATA[Formaldehyde (mg / m 3 )]]> 12 14 53 <![CDATA[Acetaldehyde (mg / m 3 )]]> 14 19 33.7 <![CDATA[TVOC(C6~C16)(mg / m 3 )]]> 328 333 1041

[0110] Although the present invention is disclosed as above, the present invention is not limited thereto. Any person skilled in the art can make various changes and modifications without departing from the spirit and scope of the present invention. Therefore, the protection scope of the present invention shall be subject to the scope defined by the claims.

Claims

1. A method for preparing a water-based scorch treatment agent, characterized in that: The preparation method comprises: S100, using an emulsifier and a mixed monomer to perform a polymerization reaction to obtain a scorch treatment agent emulsion; S200, mixing an organic thickener with an inorganic thickener to obtain a scorch treatment agent thickener; S300, stirring and mixing the prepared scorch treatment agent emulsion with deionized water to obtain a scorch treatment agent mother solution; S400, adding the thickener and auxiliary additives of the scorch treatment agent to the scorch treatment agent mother liquor to obtain an aqueous scorch treatment agent; S500, adjusting the pH value of the aqueous scorch treatment agent to neutral or weak alkaline.

2. The preparation method according to claim 1, characterized in that: S100 specifically includes: S110, adding a nonionic emulsifier to deionized water to obtain an emulsion; S120, mixing a plurality of monomers with the emulsion to obtain a first mixed solution, wherein the monomers include: acrylic acid, methyl methacrylate, and butyl acrylate; S130, initiating a polymerization reaction, dissolving an initiator in water, and adding the first mixed solution to obtain the scorch treatment agent emulsion; S140, using a pH regulator to adjust the pH value of the scorch treatment agent emulsion.

3. The preparation method according to claim 1, characterized in that: S200 specifically includes: S210, mixing water and bentonite to prepare the inorganic thickener solution; S220, mixing water and hydroxyethyl cellulose to prepare the organic thickener solution; S230, mixing the inorganic thickener solution and the organic thickener solution, adding a pH regulator, and obtaining the scorch treatment agent thickener.

4. The preparation method according to claim 1, characterized in that: S300 specifically includes: Add 10 parts of deionized water into the stirrer, start stirring, gradually add 80 parts of the scorch treatment agent emulsion, keep the stirring speed at 300-500 rpm, and after stirring for 20-30 minutes, obtain the scorch treatment agent mother liquor.

5. The preparation method according to claim 1, characterized in that: S400 specifically includes: In 90 parts of the scorch treatment agent mother liquor, 1.5 parts of a defoamer, 2 parts of the scorch treatment agent thickener, 1 part of a wetting agent and 0.5 parts of a preservative were slowly added in sequence to obtain the water-based scorch treatment agent.

6. The preparation method according to claim 1, characterized in that: S100 specifically includes: S110, adding 140-150 parts of deionized water to the reactor, starting the agitator, gradually adding 2-3 parts of the nonionic emulsifier, maintaining the temperature between 40-50° C., stirring for 30 minutes to ensure that the nonionic emulsifier is completely dissolved to form a stable liquid phase; S120, gradually adding 25-30 parts of acrylic acid, 30-35 parts of methyl methacrylate, 35-40 parts of butyl acrylate and 20-25 parts of styrene into the reaction kettle, and continuously stirring to ensure that each monomer is evenly dispersed in the liquid phase; S130, dissolving 0.5-1 part of initiator in a small amount of deionized water, and slowly adding the solution to the reactor to initiate free radical polymerization of the monomers, maintaining the reaction temperature at 80-90° C., and continuously stirring for 2-3 hours; S140, using an appropriate amount of pH regulator to adjust the pH value of the scorch treatment agent emulsion to 7-8.

7. The preparation method according to claim 1, characterized in that: S200 specifically includes: S210, taking 80-90 parts of water and adding them into the first stirring tank, slowly adding 5-8 parts of bentonite and 0.5-2 parts of dispersant during stirring, and continuing stirring for 30-60 minutes after the addition is completed to obtain the inorganic thickener solution; S220, adding 25-30 parts of water into a second stirring tank, maintaining 30-40° C., gradually adding 2-3 parts of hydroxyethyl cellulose, stirring for 30 minutes, to obtain the organic thickener solution; S230, mixing the inorganic thickener solution and the organic thickener solution at a mass ratio of inorganic thickener solution: organic thickener solution = 3:1, continuing stirring for 20-30 minutes, adding a pH adjuster to adjust the pH to 7-8, and obtaining the scorch treatment agent thickener.

8. The preparation method according to claim 6, characterized in that: The nonionic emulsifier includes at least one of the following or a combination thereof: polyethoxylated alkylphenol, polysorbate, fatty alcohol polyoxyethylene ether, nonylphenol polyoxyethylene ether.

9. The preparation method according to claim 6, characterized in that: The initiator is ammonium persulfate.

10. A water-based scorch treatment agent, characterized in that: The aqueous scorching treatment agent is obtained by the preparation method according to any one of claims 1 to 9.