Production system of platinum-loaded cobalt-nitrogen-carbon carrier catalyst for hydrogen production by water electrolysis

By developing a production system for platinum-supported cobalt nitrogen carbon carbon support catalyst for electrolytic water hydrogen production, the problems of high energy consumption and high catalyst cost in the prior art were solved, efficient energy conversion and large-scale production were achieved, and the industrial application of this technology was promoted.

CN222586536UActive Publication Date: 2025-03-11JIANGXI NAIHUA ENVIRONMENTAL PROTECTION TECH CO LTD +6
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Patent Information

Application Number
CN202420407552.3
Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
Filing Date
2024-03-04
Publication Date
2025-03-11
Estimated Expiration
2034-03-04

AI Technical Summary

Technical Problem

The existing electrolytic hydrogen production technology has high energy consumption and low energy conversion efficiency due to its high electricity price and high catalyst cost, which limits its large-scale promotion in industry.

Method used

A production system for platinum-supported cobalt nitrogen carbon support catalyst for electrolytic hydrogen production was developed. Through the combination of the cobalt nitrogen carbon support production system and the platinum-supported cobalt nitrogen carbon support catalyst production system, the efficient and large-scale production of catalysts was achieved.

Benefits of technology

By using a platinum-supported cobalt nitrogen carbon support catalyst, the overpotential of the hydrogen evolution reaction is significantly reduced, the energy conversion efficiency is improved, and the energy consumption of hydrogen production by electrolyzing water is reduced, which promotes the industrial application of this technology.

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Abstract

The utility model discloses a production system of a platinum-loaded cobalt-nitrogen-carbon carrier catalyst for producing hydrogen by electrolyzing water. The production system comprises a cobalt-nitrogen-carbon carrier production system and a platinum-loaded cobalt-nitrogen-carbon carrier catalyst production system, the cobalt-nitrogen-carbon carrier production system comprises a raw material storage tank and a reaction tank, materials are uniformly mixed and then flow to a stirring reaction tank, the materials are treated by a centrifugal pump, a drying tank and a high-temperature tube furnace which are communicated and then flow to the stirring reaction tank with a temperature controller for acid pickling, and the materials are treated by the drying tank to obtain a cobalt-nitrogen-carbon carrier; the platinum-loaded cobalt-nitrogen-carbon carrier catalyst production system comprises a raw material storage tank and a stirring reaction tank, the platinum-loaded cobalt-nitrogen-carbon carrier catalyst and a cobalt-nitrogen-carbon carrier are subjected to low-temperature impregnation reaction in the stirring reaction tank with a temperature controller, and the platinum-loaded cobalt-nitrogen-carbon carrier catalyst is obtained through treatment in a freeze drying tank. The catalyst provided by the utility model is short in production process and complete in function, and can be used for producing the platinum-loaded cobalt-nitrogen-carbon carrier catalyst for producing hydrogen by electrolyzing water in a large scale.
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Description

Technical Field

[0001] The utility model belongs to the technical field of production of catalysts for hydrogen production by electrolysis of water, and specifically relates to a production system of platinum-loaded cobalt-nitrogen-carbon carrier catalysts for hydrogen production by electrolysis of water. Background Art

[0002] At present, the main source of hydrogen is industrial fossil fuels, including methane reforming, alcohol cracking, and coal gasification, which will cause harm to the environment again. The products of water electrolysis hydrogen production are hydrogen and oxygen, which are completely green and pollution-free. It is a truly clean and sustainable energy conversion technology. Although the technology of water electrolysis hydrogen production is mature, due to the high electricity price and low hydrogen production efficiency, it is difficult to achieve large-scale promotion of water electrolysis hydrogen production in industry. Therefore, how to reduce the energy consumption of water electrolysis and improve the energy conversion efficiency is an urgent problem to be solved in water electrolysis hydrogen production technology.

[0003] Electrocatalysts are the key to hydrogen production by water electrolysis. The use of suitable electrocatalysts can significantly reduce the overpotential of the hydrogen evolution reaction and promote the hydrogen evolution reaction, which plays an important role in reducing energy consumption and improving energy conversion efficiency. Platinum-based catalysts have always been considered as the benchmark electrocatalysts for hydrogen production by water electrolysis. However, their high price and low abundance limit their large-scale application. Therefore, developing electrocatalysts with higher catalytic activity and more economic benefits, reducing the overpotential of water electrolysis, and improving energy conversion efficiency are the key to reducing the energy consumption of hydrogen production by water electrolysis, and are also the bottleneck restricting the development of the hydrogen production industry by water electrolysis. Utility Model Content

[0004] The utility model aims to solve at least one of the technical problems existing in the prior art. To this end, the utility model provides a production system for platinum-loaded cobalt-nitrogen-carbon-supported catalyst for electrolysis of water to produce hydrogen, which aims to mass-produce platinum-loaded cobalt-nitrogen-carbon-supported catalyst for electrolysis of water to produce hydrogen.

[0005] In order to achieve the above purpose, the utility model adopts the following technical solutions:

[0006] A production system of a platinum-loaded cobalt-nitrogen-carbon carrier catalyst for electrolysis of water to produce hydrogen, comprising a cobalt-nitrogen-carbon carrier production system and a platinum-loaded cobalt-nitrogen-carbon carrier catalyst production system; the cobalt-nitrogen-carbon carrier production system comprises: a zinc nitrate hexahydrate storage tank, a methanol storage tank, a dimethylimidazole storage tank and a dilute sulfuric acid solution storage tank; a first reaction tank and a second reaction tank, wherein the first inlets of the first reaction tank and the second reaction tank are respectively connected to the outlets of the zinc nitrate hexahydrate storage tank and the dimethylimidazole storage tank, and the second inlets of the first reaction tank and the second reaction tank are connected to the outlet of the methanol storage tank; a first stirring reaction tank, wherein the first inlet and the second inlet of the first stirring reaction tank are respectively connected to the outlets of the first reaction tank and the second reaction tank, and the first stirring reaction tank is used to stir the zinc nitrate slurry and the dimethylimidazole slurry. Stir and react to obtain a cobalt-nitrogen-carbon precursor solution; a second stirring reaction tank, wherein the first inlet of the second stirring reaction tank is connected to the outlet of the dilute sulfuric acid solution storage tank, the second inlet of the second stirring reaction tank is connected to the outlet of the first stirring reaction tank, and the second stirring reaction tank is used to stir the cobalt-nitrogen-carbon precursor slurry and the dilute sulfuric acid solution and perform an acid washing reaction to obtain a cobalt-nitrogen-carbon carrier; the platinum-loaded cobalt-nitrogen-carbon carrier catalyst production system comprises: a chloroplatinic acid solution storage tank; a third stirring reaction tank, wherein the first inlet of the third stirring reaction tank is connected to the outlet of the chloroplatinic acid solution storage tank, the second inlet of the third stirring reaction tank is connected to the outlet of the second stirring reaction tank, and the third stirring reaction tank is used to stir the cobalt-nitrogen-carbon carrier and the chloroplatinic acid solution and perform a low-temperature impregnation reaction to obtain a platinum-loaded cobalt-nitrogen-carbon carrier catalyst.

[0007] Preferably, the cobalt-nitrogen-carbon carrier production system further comprises a centrifugal pump, a first drying tank and a high-temperature tubular furnace which are sequentially arranged between the outlet of the first stirred reactor and the second inlet of the second stirred reactor, the centrifugal pump being used for centrifugally removing moisture from the precursor slurry to obtain solid slag, the first drying tank being used for drying and dehydrating the solid slag to obtain solid powder, and the high-temperature tubular furnace being used for calcining the solid powder.

[0008] Preferably, the cobalt-nitrogen-carbon carrier production system further comprises a second drying tank arranged between the outlet of the second stirred reaction tank and the second inlet of the third stirred reaction tank, and the second drying tank is used for drying to obtain the cobalt-nitrogen-carbon carrier.

[0009] Preferably, the platinum-loaded cobalt-nitrogen-carbon-carrier catalyst production system further comprises: a freeze drying tank, the inlet of the freeze drying tank being connected to the outlet of the third stirred reaction tank, the freeze drying tank being used to freeze-dry the platinum-loaded cobalt-nitrogen-carbon-carrier catalyst to obtain a solid powder; a platinum-loaded cobalt-nitrogen-carbon-carrier catalyst storage tank, the inlet of the platinum-loaded cobalt-nitrogen-carbon-carrier catalyst storage tank being connected to the outlet of the freeze drying tank, the platinum-loaded cobalt-nitrogen-carbon-carrier catalyst storage tank being used to store the platinum-loaded cobalt-nitrogen-carbon-carrier catalyst solid powder.

[0010] Preferably, the first inlets of the first reaction tank and the second reaction tank are connected to the outlets of the zinc nitrate hexahydrate storage tank and the dimethylimidazole storage tank respectively through the first flow regulating valve and the second flow regulating valve, and the second inlets of the first reaction tank and the second reaction tank are connected to the outlet of the methanol storage tank through the three-way flow regulating valve.

[0011] Preferably, the first inlet and the second inlet of the first stirred reactor are connected to the outlets of the first reactor and the second reactor respectively through a third flow regulating valve and a fourth flow regulating valve, and the first inlet of the second stirred reactor is connected to the outlet of the dilute sulfuric acid solution storage tank through a fifth flow regulating valve.

[0012] Preferably, the first inlet of the third stirred reactor is connected to the outlet of the chloroplatinic acid solution storage tank through a sixth flow regulating valve, and the second inlet of the third stirred reactor is connected to the outlet of the second stirred reactor through a seventh flow regulating valve.

[0013] Preferably, the inlet of the platinum-loaded cobalt-nitrogen-carbon-supported catalyst storage tank is connected to the outlet of the freeze-drying tank via an eighth flow regulating valve.

[0014] Preferably, a first temperature controller is provided in the second stirred reaction tank, and the first temperature controller is used to heat the second stirred reaction tank and control the temperature to be no higher than 80°C.

[0015] Preferably, a second temperature controller is arranged in the third stirred reaction tank, and the second temperature controller is used to heat the third stirred reaction tank and control the temperature to be no higher than 70°C.

[0016] The utility model adopts the above technical solution, which has the following advantages:

[0017] The utility model provides a production system for platinum-loaded cobalt-nitrogen-carbon carrier catalysts for hydrogen production by electrolysis of water. The catalyst production process provided is short and fully functional. A precursor is processed by a connected centrifugal pump, a drying tank, and a high-temperature tubular furnace to obtain a cobalt-nitrogen-carbon carrier. Platinum is impregnated into the cobalt-nitrogen-carbon carrier by low-temperature stirring, so that platinum-loaded cobalt-nitrogen-carbon carrier catalysts for hydrogen production by electrolysis of water can be mass-produced. BRIEF DESCRIPTION OF THE DRAWINGS

[0018] By reading the detailed description of the preferred embodiment below, various other advantages and benefits will become clear to those of ordinary skill in the art. The accompanying drawings are only used for the purpose of illustrating the preferred embodiment and are not considered to be limiting of the present invention. The same reference numerals are used throughout the accompanying drawings to represent the same components. In the accompanying drawings:

[0019] Figure 1 A schematic structural diagram of a production system for a platinum-loaded cobalt-nitrogen-carbon-supported catalyst for hydrogen production by electrolysis of water provided in one embodiment of the utility model.

[0020] The reference numerals in the figures are as follows:

[0021] 1. Hexahydrate zinc nitrate storage tank; 2. Methanol storage tank; 3. Dimethylimidazole storage tank; 4. First flow regulating valve; 5. Three-way flow regulating valve; 6. Second flow regulating valve; 7. First reaction tank; 8. Second reaction tank; 9. Third flow regulating valve; 10. Fourth flow regulating valve; 11. First stirring reaction tank; 12. Centrifugal pump; 13. First drying tank; 14. High-temperature tubular furnace; 15. Second stirring reaction tank; 16. Fifth flow regulating valve; 17. Dilute sulfuric acid solution storage tank; 18. Second drying tank; 19. Sixth flow regulating valve; 20. Third stirring reaction tank; 21. Seventh flow regulating valve; 22. Chloroplatinic acid solution storage tank; 23. Freeze drying tank; 24. Eighth flow regulating valve; 25. Platinum-loaded cobalt nitrogen carbon carrier catalyst storage tank; 26. First temperature controller; 27. Second temperature controller. DETAILED DESCRIPTION

[0022] In order to make the purpose, technical solution and advantages of the utility model clearer, the technical solution of the utility model will be clearly and completely described below in conjunction with the accompanying drawings. Obviously, the described embodiments are part of the embodiments of the utility model, not all of the embodiments. Based on the embodiments of the utility model, all other embodiments obtained by ordinary technicians in this field without creative work are within the scope of protection of the utility model.

[0023] In the description of the present invention, it should be understood that the terms "center", "longitudinal", "lateral", "length", "width", "thickness", "up", "down", "front", "back", "left", "right", "vertical", "horizontal", "top", "bottom", "inside", "outside", "clockwise", "counterclockwise", "axial", "radial", "circumferential" and the like indicate orientations or positional relationships based on the orientations or positional relationships shown in the accompanying drawings, and are only for the convenience of describing the present invention and simplifying the description, and do not indicate or imply that the referred device or element must have a specific orientation, be constructed and operated in a specific orientation, and therefore should not be understood as a limitation on the present invention.

[0024] In addition, the terms "first" and "second" are used for descriptive purposes only and should not be understood as indicating or implying relative importance or implicitly indicating the number of the indicated technical features. Therefore, the features defined as "first" and "second" may explicitly or implicitly include one or more of the features. In the description of the present utility model, the meaning of "plurality" is more than two, unless otherwise clearly and specifically defined.

[0025] In the present invention, unless otherwise clearly specified and limited, the terms "install", "connect", "connect", "fix" and the like should be understood in a broad sense, for example, it can be a fixed connection, a detachable connection, or an integral connection; it can be a mechanical connection or an electrical connection; it can be a direct connection or an indirect connection through an intermediate medium, it can be the internal connection of two elements or the interaction relationship between two elements. For ordinary technicians in this field, the specific meanings of the above terms in the present invention can be understood according to specific circumstances.

[0026] In the present utility model, unless otherwise clearly specified and limited, a first feature being "above" or "below" a second feature may mean that the first and second features are in direct contact, or the first and second features are in indirect contact through an intermediate medium. Moreover, a first feature being "above", "above" or "above" a second feature may mean that the first feature is directly above or obliquely above the second feature, or simply means that the first feature is higher in level than the second feature. A first feature being "below", "below" or "below" a second feature may mean that the first feature is directly below or obliquely below the second feature, or simply means that the first feature is lower in level than the second feature.

[0027] In the description of this specification, the description with reference to the terms "one embodiment", "some embodiments", "example", "specific example", or "some examples" etc. means that the specific features, structures, materials or characteristics described in conjunction with the embodiment or example are included in at least one embodiment or example of the utility model. In this specification, the schematic representations of the above terms do not necessarily refer to the same embodiment or example. Moreover, the specific features, structures, materials or characteristics described may be combined in any one or more embodiments or examples in a suitable manner. In addition, those skilled in the art may combine and combine the different embodiments or examples described in this specification and the features of the different embodiments or examples, without contradiction.

[0028] The production system of platinum-loaded cobalt-nitrogen-carbon carrier catalyst for electrolysis of water for hydrogen production provided by the utility model includes a cobalt-nitrogen-carbon carrier production system and a platinum-loaded cobalt-nitrogen-carbon carrier catalyst production system; the cobalt-nitrogen-carbon carrier production system includes a raw material storage tank and a reaction tank, and the material flows to a stirring reaction tank after being mixed evenly, and then flows to a stirring reaction tank with a temperature controller for acid washing through a connected centrifugal pump, a drying tank, and a high-temperature tubular furnace, and the cobalt-nitrogen-carbon carrier is treated in a drying tank to obtain a cobalt-nitrogen-carbon carrier; the production system of platinum-loaded cobalt-nitrogen-carbon carrier catalyst includes a raw material storage tank and a stirring reaction tank, and a low-temperature impregnation reaction is carried out with the cobalt-nitrogen-carbon carrier in a stirring reaction tank with a temperature controller, and a platinum-loaded cobalt-nitrogen-carbon carrier catalyst is treated in a freeze drying tank. The catalyst production process provided by the utility model is short and fully functional, and can be used for mass production of platinum-loaded cobalt-nitrogen-carbon carrier catalyst for electrolysis of water for hydrogen production.

[0029] Below, the production system of platinum-loaded cobalt-nitrogen-carbon-supported catalyst for hydrogen production by electrolysis of water provided by the embodiment of the utility model is described in detail with reference to the accompanying drawings.

[0030] Embodiment 1

[0031] See also Figure 1 The present embodiment provides a production system for a platinum-loaded cobalt-nitrogen-carbon carrier catalyst for hydrogen production by electrolysis of water, including a cobalt-nitrogen-carbon carrier production system and a platinum-loaded cobalt-nitrogen-carbon carrier catalyst production system.

[0032] The cobalt-nitrogen-carbon carrier production system comprises: a zinc nitrate hexahydrate storage tank 1, a methanol storage tank 2, a dimethylimidazole storage tank 3 and a dilute sulfuric acid solution storage tank 17; a first reaction tank 7 and a second reaction tank 8, wherein the first inlets of the first reaction tank 7 and the second reaction tank 8 are respectively connected to the outlets of the zinc nitrate hexahydrate storage tank 1 and the dimethylimidazole storage tank 3 through a first flow regulating valve 4 and a second flow regulating valve 6, and the second inlets of the first reaction tank 7 and the second reaction tank 8 are connected to the outlet of the methanol storage tank 2 through a three-way flow regulating valve 5; a first stirring reaction tank 11, wherein the first inlet and the second inlet of the first stirring reaction tank 11 are connected to the outlet of the methanol storage tank 2 through a three-way flow regulating valve 5; and a first stirring reaction tank 11. The flow regulating valve 9 and the fourth flow regulating valve 10 are connected to the outlets of the first reaction tank 7 and the second reaction tank 8 respectively. The first stirring reaction tank 11 is used to stir the zinc nitrate slurry and the dimethylimidazole slurry and react to obtain a cobalt nitrogen carbon precursor solution; the second stirring reaction tank 15, the first inlet of the second stirring reaction tank 15 is connected to the outlet of the dilute sulfuric acid solution storage tank 17 through the fifth flow regulating valve 16, the second inlet of the second stirring reaction tank 15 is connected to the outlet of the first stirring reaction tank 11, and the second stirring reaction tank 15 is used to stir the cobalt nitrogen carbon precursor slurry and the dilute sulfuric acid solution and perform a pickling reaction to obtain a cobalt nitrogen carbon carrier.

[0033] The platinum-loaded cobalt-nitrogen-carbon-supported catalyst production system comprises: a chloroplatinic acid solution storage tank 22; a third stirred reactor 20, wherein a first inlet of the third stirred reactor 20 is connected to an outlet of the chloroplatinic acid solution storage tank 22 via a sixth flow regulating valve 21, and a second inlet of the third stirred reactor 20 is connected to an outlet of the second stirred reactor 15 via a seventh flow regulating valve 19, and the third stirred reactor 20 is used for stirring the cobalt-nitrogen-carbon support and the chloroplatinic acid solution and performing a low-temperature impregnation reaction to obtain a platinum-loaded cobalt-nitrogen-carbon-supported catalyst.

[0034] In the above embodiment, preferably, the cobalt-nitrogen-carbon carrier production system also includes a centrifugal pump 12, a first drying tank 13 and a high-temperature tubular furnace 14, which are sequentially arranged between the outlet of the first stirred reactor 11 and the second inlet of the second stirred reactor 15. The centrifugal pump 12 is used to centrifugally separate moisture from the precursor slurry to obtain solid slag, the first drying tank 13 is used to dry and dehydrate the solid slag to obtain solid powder, and the high-temperature tubular furnace 14 is used to calcine the solid powder.

[0035] In the above embodiment, preferably, the cobalt nitrogen carbon carrier production system also includes a second drying tank 18 arranged between the outlet of the second stirred reaction tank 15 and the second inlet of the third stirred reaction tank 20, and the second drying tank 18 is used for drying to obtain the cobalt nitrogen carbon carrier.

[0036] In the above embodiment, preferably, the platinum-loaded cobalt-nitrogen-carbon-supported catalyst production system also includes: a freeze drying tank 23, the inlet of the freeze drying tank 23 is connected to the outlet of the third stirred reaction tank 20, and the freeze drying tank 23 is used to freeze-dry the platinum-loaded cobalt-nitrogen-carbon-supported catalyst to obtain a solid powder; a platinum-loaded cobalt-nitrogen-carbon-supported catalyst storage tank 25, the inlet of the platinum-loaded cobalt-nitrogen-carbon-supported catalyst storage tank 25 is connected to the outlet of the freeze drying tank 23 through an eighth flow regulating valve 24, and the platinum-loaded cobalt-nitrogen-carbon-supported catalyst storage tank 25 is used to store the platinum-loaded cobalt-nitrogen-carbon-supported catalyst solid powder.

[0037] In the above embodiment, preferably, a first temperature controller 26 is provided in the second stirred reaction tank 15, and the first temperature controller 26 is used to heat the second stirred reaction tank 15 and control the temperature to be no higher than 80°C.

[0038] In the above embodiment, preferably, a second temperature controller 27 is provided in the third stirred reaction tank 20, and the second temperature controller 27 is used to heat the third stirred reaction tank 20 and control the temperature to be no higher than 70°C.

[0039] Embodiment 2

[0040] When the production system of platinum-loaded cobalt-nitrogen-carbon carrier catalyst for electrolysis of water for hydrogen production provided by the utility model is used, firstly, the cobalt-nitrogen-carbon carrier is produced by the cobalt-nitrogen-carbon carrier production system, specifically: the hexahydrate zinc nitrate in the hexahydrate zinc nitrate storage tank 1 is transported to the first reaction tank 7 through the first flow regulating valve 4, the dimethylimidazole in the dimethylimidazole storage tank 3 is transported to the second reaction tank 8 through the second flow regulating valve 6, and the methanol in the methanol storage tank 2 is transported to the first reaction tank 7 and the second reaction tank 8 through the three-way flow regulating valve 5. After uniform mixing, the raw material slurry stored in the first reaction tank 7 and the second reaction tank 8 are respectively transported to the first stirring reaction tank 11 through the third flow regulating valve 9 and the fourth flow regulating valve 10. After sufficient stirring, the obtained cobalt-nitrogen-carbon precursor solution is centrifuged and separated from the water through the centrifugal pump 12 to obtain solid slag, the solid slag enters the first drying tank 13, and after drying and dehydration, a solid powder is obtained, and the solid powder enters the high-temperature tubular furnace 14, and after calcination treatment, it is transported to the second stirring reaction tank 15. At the same time, the dilute sulfuric acid solution in the dilute sulfuric acid solution storage tank 17 is transported to the second stirring reaction tank 15 through the fifth flow regulating valve 16 for stirring and pickling, and the temperature is controlled by the first temperature controller 26 to be no higher than 80° C. to obtain a cobalt nitrogen carbon carrier solution. After pickling and cooling, the cobalt nitrogen carbon carrier solution enters the second drying tank 18 for drying, and the cobalt nitrogen carbon carrier is obtained after drying and dehydration.

[0041] Subsequently, a platinum-loaded cobalt-nitrogen-carbon-carrier catalyst is obtained through a platinum-loaded cobalt-nitrogen-carbon-carrier catalyst production system, specifically: the chloroplatinic acid solution storage tank 22 is transported to the third stirring reaction tank 20 through the sixth flow regulating valve 21, and the cobalt-nitrogen-carbon carrier is transported to the third stirring reaction tank 20 through the seventh flow regulating valve 19, and a stirring low-temperature impregnation reaction is performed, and the reaction temperature is controlled by the second temperature controller 27 to be no higher than 70°C to obtain a platinum-loaded cobalt-nitrogen-carbon-carrier catalyst solution. After the reaction is completed, the platinum-loaded cobalt-nitrogen-carbon-carrier catalyst solution is transported to a freeze drying tank 23, and a platinum-loaded cobalt-nitrogen-carbon-carrier catalyst solid powder is obtained after freeze drying, and is transported to a platinum-loaded cobalt-nitrogen-carbon-carrier catalyst storage tank 25 for storage through the eighth flow regulating valve 24.

[0042] In summary, the utility model is a production system for a platinum-loaded cobalt-nitrogen-carbon carrier catalyst for hydrogen production by electrolysis of water. The catalyst production process provided is short and fully functional. A precursor is treated with a connected centrifugal pump, a drying tank, and a high-temperature tubular furnace to obtain a cobalt-nitrogen-carbon carrier; platinum is impregnated into the cobalt-nitrogen-carbon carrier by low-temperature stirring, and platinum-loaded cobalt-nitrogen-carbon carrier catalysts for hydrogen production by electrolysis of water can be mass-produced.

[0043] Finally, it should be noted that the above embodiments are only used to illustrate the technical solutions of the present invention, rather than to limit it. Although the present invention has been described in detail with reference to the aforementioned embodiments, those skilled in the art should understand that they can still modify the technical solutions described in the aforementioned embodiments, or make equivalent replacements for some of the technical features therein. However, these modifications or replacements do not deviate the essence of the corresponding technical solutions from the spirit and scope of the technical solutions of the embodiments of the present invention.

Claims

1. A production system for platinum-supported cobalt-nitrogen-carbon catalyst for hydrogen production by electrolysis of water, characterized in that: Including cobalt nitrogen carbon carrier production system and platinum-loaded cobalt nitrogen carbon carrier catalyst production system; The cobalt nitrogen carbon carrier production system comprises: Zinc nitrate hexahydrate storage tank, methanol storage tank, dimethylimidazole storage tank and dilute sulfuric acid solution storage tank; A first reaction tank and a second reaction tank, wherein the first inlets of the first reaction tank and the second reaction tank are respectively connected to the outlets of the zinc nitrate hexahydrate storage tank and the dimethylimidazole storage tank, and the second inlets of the first reaction tank and the second reaction tank are connected to the outlet of the methanol storage tank; a first stirring reaction tank, wherein a first inlet and a second inlet of the first stirring reaction tank are respectively connected to outlets of the first reaction tank and the second reaction tank, and the first stirring reaction tank is used to stir and react zinc nitrate slurry and dimethylimidazole slurry to obtain a cobalt nitrogen carbon precursor solution; a second stirring reaction tank, wherein the first inlet of the second stirring reaction tank is connected to the outlet of the dilute sulfuric acid solution storage tank, the second inlet of the second stirring reaction tank is connected to the outlet of the first stirring reaction tank, and the second stirring reaction tank is used to stir the cobalt nitrogen carbon precursor slurry and the dilute sulfuric acid solution and perform an acid washing reaction to obtain the cobalt nitrogen carbon carrier; The platinum-loaded cobalt-nitrogen-carbon carrier catalyst production system comprises: Chloroplatinic acid solution storage tank; A third stirred reactor, wherein the first inlet of the third stirred reactor is connected to the outlet of the chloroplatinic acid solution storage tank, the second inlet of the third stirred reactor is connected to the outlet of the second stirred reactor, and the third stirred reactor is used to stir the cobalt nitrogen carbon carrier and the chloroplatinic acid solution and perform a low-temperature impregnation reaction to obtain a platinum-loaded cobalt nitrogen carbon carrier catalyst.

2. The production system according to claim 1, characterized in that: The cobalt-nitrogen-carbon carrier production system also includes a centrifugal pump, a first drying tank and a high-temperature tubular furnace, which are sequentially arranged between the outlet of the first stirred reactor and the second inlet of the second stirred reactor. The centrifugal pump is used to centrifugally separate moisture from the precursor slurry to obtain solid slag, the first drying tank is used to dry and dehydrate the solid slag to obtain solid powder, and the high-temperature tubular furnace is used to calcine the solid powder.

3. The production system according to claim 2, characterized in that: The cobalt-nitrogen-carbon carrier production system further includes a second drying tank disposed between the outlet of the second stirred reaction tank and the second inlet of the third stirred reaction tank, and the second drying tank is used for drying to obtain the cobalt-nitrogen-carbon carrier.

4. The production system according to claim 1, characterized in that: The platinum-loaded cobalt-nitrogen-carbon-supported catalyst production system further comprises: A freeze drying tank, the inlet of which is connected to the outlet of the third stirring reaction tank, and the freeze drying tank is used to freeze dry the platinum-loaded cobalt-nitrogen-carbon carrier catalyst to obtain a solid powder; A platinum-loaded cobalt-nitrogen-carbon-carrier catalyst storage tank, wherein the inlet of the platinum-loaded cobalt-nitrogen-carbon-carrier catalyst storage tank is connected to the outlet of the freeze-drying tank, and the platinum-loaded cobalt-nitrogen-carbon-carrier catalyst storage tank is used to store platinum-loaded cobalt-nitrogen-carbon-carrier catalyst solid powder.

5. The production system according to claim 1, characterized in that: The first inlets of the first reaction tank and the second reaction tank are connected to the outlets of the zinc nitrate hexahydrate storage tank and the dimethylimidazole storage tank respectively through the first flow regulating valve and the second flow regulating valve, and the second inlets of the first reaction tank and the second reaction tank are connected to the outlet of the methanol storage tank through the three-way flow regulating valve.

6. The production system according to claim 1, characterized in that: The first inlet and the second inlet of the first stirred reaction tank are connected to the outlets of the first reaction tank and the second reaction tank respectively through the third flow regulating valve and the fourth flow regulating valve, and the first inlet of the second stirred reaction tank is connected to the outlet of the dilute sulfuric acid solution storage tank through the fifth flow regulating valve.

7. The production system according to claim 1, characterized in that: The first inlet of the third stirred reaction tank is connected to the outlet of the chloroplatinic acid solution storage tank through a sixth flow regulating valve, and the second inlet of the third stirred reaction tank is connected to the outlet of the second stirred reaction tank through a seventh flow regulating valve.

8. The production system according to claim 4, characterized in that: The inlet of the platinum-loaded cobalt-nitrogen-carbon-supported catalyst storage tank is connected to the outlet of the freeze-drying tank through an eighth flow regulating valve.

9. The production system according to any one of claims 1 to 8, characterized in that: A first temperature controller is arranged in the second stirred reaction tank, and the first temperature controller is used to heat the second stirred reaction tank and control the temperature to be no higher than 80°C.

10. The production system according to any one of claims 1 to 8, characterized in that: A second temperature controller is arranged in the third stirred reaction tank, and the second temperature controller is used to heat the third stirred reaction tank and control the temperature to be no higher than 70°C.