The invention discloses a coal gasification grey water dispersing agent and a preparation method thereof, the coal gasification grey water dispersing agent comprises 5%-15% of phosphoric acid tricarboxylic acid butane, 5%-15% of polymaleic anhydride, 5%-15% of acrylic acid-acrylamide sulfonate biopolymer and tap water, and the preparation method comprises the steps of material picking, feeding, standing and filtering. According to the present invention, the high-temperature scale inhibition dispersion effect is excellent, the scale inhibition dispersion rate of more than 80% at the high temperature of more than 200 DEG C is still maintained, the scale inhibition dispersion agent has been applied to a variety of gasification furnaces such as coal water slurry gasification, pulverized coal gasification and the like, can be used for a long enough period, can not be stopped for more than 6 months, and can ensure the continuous and stable operation of the device.