Low-foamability surfactant composition and production method thereof
Through the surfactant composition of specific components, the foam problems caused by traditional surfactants in the development of high-tech materials and water recycling are solved, low-foam or bubble-free production is achieved, the process is simplified and the wastewater treatment burden is reduced. , comply with environmental protection standards.
Patent Information
- Application Number
- CN202411155250.2
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- Filing Date
- 2024-08-22
- Publication Date
- 2024-12-31
AI Technical Summary
In the zero-emission industrialization of high-tech materials development and water recycling, the foaming properties of traditional surfactants lead to poor material performance, interruption of production and processing or process water pollution, increasing the burden of sewage treatment.
Low foaming or non-foaming surfactant compositions, including active agent components A, B, C, D and E, are prepared by combining and mixing processes in a specific proportion of components, and are used to prepare low foaming or non-foaming surfactant. Meet industrial needs and avoid three waste emissions during the production process.
The production of surfactants with low foam or no foam is achieved, the process is simplified, and the environmentally friendly production requirements are met, and the material performance degradation and water pollution caused by foam are avoided.
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Figure CN119220271A_ABST
Abstract
Description
Technical Field
[0001] The invention relates to the technical field of surfactants, in particular to a low-foaming surfactant composition and a production method thereof. Background Art
[0002] The main functions of surfactants include emulsification, dispersion, foaming, solubilization, washing and wetting. Surfactants can reduce the interfacial tension between two immiscible liquids, so that one liquid is evenly dispersed in the other liquid in the form of extremely small droplets to form a stable emulsion. This effect is very useful in food processing, medicine, cosmetics and other fields. For example, when making foods such as milk and cream, surfactants can help fat globules to be evenly distributed in water to form a stable emulsion. Surfactants can make solid particles or droplets evenly distributed in liquids to prevent them from aggregating and precipitating. This effect is very important in the fields of coatings, paints, pigments, etc., which can ensure the uniformity of color and the stability of products. Surfactants can reduce the surface tension of water, so that insoluble gases form stable foam in liquids. This effect is very useful in products such as detergents, shampoos, and foam fire extinguishers. Some water-insoluble substances, such as oils and fats or some drugs, have very low solubility in water. After adding surfactants, the solubility of these substances will be greatly increased to form a transparent solution. This effect is particularly important in pharmaceutical preparations and cosmetics, as it can help improve the bioavailability of drugs and the stability of products. The wetting, penetration, emulsification, dispersion and foaming effects of surfactants are combined to form a washing effect, which is very important in products such as detergents and laundry detergents and can help remove stains and grease. Surfactants can reduce the surface tension of solid surfaces, making it easier for liquids to spread on solid surfaces. This effect is very important in industries such as paint and printing, as it can improve the wettability and adhesion of coatings. In addition, the molecular structure of surfactants is amphiphilic, with a hydrophilic group at one end and a hydrophobic group at the other. This special molecular structure gives surfactants the multiple functions mentioned above.
[0003] Comparative document, application number CN201610363576.3, the present invention provides a surfactant compound composition and its preparation method and application, belonging to the field of chemical additives for oil fields. The surfactant compound composition, based on the total mass of the raw materials as 100%, includes 0.3wt%-2wt% of anionic-nonionic surfactants, 0.05wt%-0.5wt% of amine surfactants, 0.01wt%-2wt% of high molecular polymers, and the balance of water. The surfactant compound composition provided by the present invention has low concentration, small dosage, and a solution pH value close to neutral. It is harmless to the formation and non-corrosive to equipment and pipelines; when the oil saturation is 50%, it still has more than five times the foaming volume, the foam is continuously stable for more than 360 minutes under normal temperature conditions, and the foam half-life can reach 80 minutes at a reservoir temperature of 55°C, which is suitable for foam flooding of high-temperature and high-salinity reservoirs.
[0004] The comparative document, application number is CN202310284812.2, the present invention discloses a low foaming surfactant and a preparation method thereof, which is composed of the following components in weight proportion: 10-20 parts of isooctyl alcohol, 10-20 parts of ethoxylated fatty acid methyl ester, 5-20 parts of phospholipids, 15-23 parts of choline, 20-30 parts of alkylbenzene sulfonate, 5-10 parts of alkyl phosphate monoester salt, 5-10 parts of alkyl phosphate diester salt and 0-3 parts of fragrance, and the remainder is added with a PH regulator to adjust the pH value between 7.5-8.5. The mixing of isooctyl alcohol and ethoxylated fatty acid methyl ester can effectively reduce the foaming property of the surfactant, and the alkyl phosphate monoester salt and the alkyl phosphate diester salt cooperate with each other to achieve reduced bubble performance and superior detergency. And the addition of fragrance can further improve the fragrance of the surfactant, thereby improving the applicability of the surfactant.
[0005] However, the above surfactants have the following disadvantages:
[0006] Although the above-mentioned surfactants are added with low-foaming materials and surfactants generally have foaming properties, this foaming property contributes to their application in daily chemicals such as toothpaste, shower gel, laundry detergent, shampoo and other fields. However, in many industrial fields, especially in the field of high-tech material development, or in zero-emission industrial production of water recycling, this foam can bring fatal harm, resulting in the deterioration of the application performance of the material, or the interruption of the production and processing of the material due to the foam, or the foam causing the pollution of the material production process water, thereby increasing the burden of sewage treatment. Summary of the invention
[0007] The object of the present invention is to provide a low-foaming surfactant composition and a production method thereof, so as to solve the problem that although the above-mentioned surfactant proposed in the above-mentioned background technology is added with low-foaming materials and the surfactant generally has foaming properties, this foaming property is conducive to its application in the fields of daily chemicals such as toothpaste, shower gel, laundry detergent, shampoo, etc., but in many industrial fields, especially in the field of high-tech material development, or in zero-emission industrial production of water recycling, this foam will bring fatal harm, resulting in the deterioration of the application performance of the material, or the interruption of the production and processing of the material due to the foam, or the foam causes the material production process water pollution, increasing the burden of sewage treatment.
[0008] To achieve the above object, the present invention provides the following technical solution: a low-foaming surfactant composition, comprising a surfactant, wherein the surfactant comprises an active agent component A, an active agent component B, an active agent component C, an active agent component D and an active agent component E, wherein the active agent component A comprises the following components: by weight, 10 to 30 parts of ethoxylated fatty alcohol sodium sulfate, 10 to 30 parts of oleamide MEA, 10 to 30 parts of EO / PO block polyether, 10 to 30 parts of isooctyl phosphate derivatives and 10 to 30 parts of ethoxylated fatty acid methyl ester derivatives, and the active agent component B comprises the following components The invention is prepared from the following components: 20-40 parts of polyethylene glycol monooleate, 20-40 parts of nonylphenol polyoxyethylene ether and 20-40 parts of RM2020, by weight; the active agent component C comprises the following components: 30-60 parts of stearic acid and 30-60 parts of sodium dodecylbenzene sulfonate, by weight; the active agent component D comprises the following components: 25-40 parts of fatty acid glyceride, 25-40 parts of Span and 25-40 parts of Tween, by weight; and the active agent component E comprises the following components: 30-70 parts of tuberose extract and 30-70 parts of osmanthus essential oil, by weight.
[0009] As a preferred technical solution of the present invention, the active agent component A comprises the following components: by weight, 20 parts of ethoxylated fatty alcohol sodium sulfate, 20 parts of oleamide MEA, 20 parts of EO / PO block polyether, 20 parts of isooctyl phosphate derivatives and 20 parts of ethoxylated fatty acid methyl ester derivatives; the active agent component B comprises the following components: by weight, 20 parts of polyethylene glycol monooleate, 40 parts of nonylphenol polyoxyethylene ether and 40 parts of RM2020; the active agent component C comprises the following components: by weight, 40 parts of stearic acid and 60 parts of sodium dodecylbenzene sulfonate; the active agent component D comprises the following components: by weight, 30 parts of fatty acid glyceride, 35 parts of Span and 35 parts of Tween; the active agent component E comprises the following components: by weight, 50 parts of tuberose extract and 50 parts of osmanthus essential oil.
[0010] As a preferred technical solution of the present invention, the active agent component A comprises the following components: by weight, 15 parts of ethoxylated fatty alcohol sodium sulfate, 15 parts of oleamide MEA, 15 parts of EO / PO block polyether, 25 parts of isooctyl phosphate derivatives and 30 parts of ethoxylated fatty acid methyl ester derivatives; the active agent component B comprises the following components: by weight, 30 parts of polyethylene glycol monooleate, 30 parts of nonylphenol polyoxyethylene ether and 40 parts of RM2020; the active agent component C comprises the following components: by weight, 50 parts of stearic acid and 50 parts of sodium dodecylbenzene sulfonate; the active agent component D comprises the following components: by weight, 35 parts of fatty acid glyceride, 35 parts of Span and 30 parts of Tween; the active agent component E comprises the following components: by weight, 40 parts of tuberose extract and 60 parts of osmanthus essential oil.
[0011] As a preferred technical solution of the present invention, the active agent component A comprises the following components: by weight, 30 parts of ethoxylated fatty alcohol sodium sulfate, 10 parts of oleamide MEA, 30 parts of EO / PO block polyether, 10 parts of isooctyl phosphate derivatives and 20 parts of ethoxylated fatty acid methyl ester derivatives; the active agent component B comprises the following components: by weight, 25 parts of polyethylene glycol monooleate, 35 parts of nonylphenol polyoxyethylene ether and 40 parts of RM2020; the active agent component C comprises the following components: by weight, 60 parts of stearic acid and 40 parts of sodium dodecylbenzene sulfonate; the active agent component D comprises the following components: by weight, 35 parts of fatty acid glyceride, 25 parts of Span and 40 parts of Tween; the active agent component E comprises the following components: by weight, 70 parts of tuberose extract and 30 parts of osmanthus essential oil.
[0012] As a preferred technical solution of the present invention, the active agent component A comprises the following components: by weight, 30 parts of ethoxylated fatty alcohol sodium sulfate, 30 parts of oleamide MEA, 10 parts of EO / PO block polyether, 10 parts of isooctyl phosphate derivatives and 20 parts of ethoxylated fatty acid methyl ester derivatives; the active agent component B comprises the following components: by weight, 40 parts of polyethylene glycol monooleate, 40 parts of nonylphenol polyoxyethylene ether and 20 parts of RM2020; the active agent component C comprises the following components: by weight, 55 parts of stearic acid and 45 parts of sodium dodecylbenzene sulfonate; the active agent component D comprises the following components: by weight, 25 parts of fatty acid glyceride, 35 parts of Span and 40 parts of Tween; the active agent component E comprises the following components: by weight, 30 parts of tuberose extract and 70 parts of osmanthus essential oil.
[0013] The present invention provides a method for producing a low-foaming surfactant composition, comprising the following steps:
[0014] Step 1, liquid preparation: add active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into a reaction kettle respectively, heat to 60-70° C. to make active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into transparent flowing liquids and store them in different containers;
[0015] Step 2: Product mixing: Add the active agent component A into the reaction kettle, and then dropwise add the active agent component B, the active agent component C, the active agent component D and the active agent component E in sequence, and control the speed and stir evenly.
[0016] As a preferred technical solution of the present invention, the rotation speed in step 2 is 80-100 r / min.
[0017] As a preferred technical solution of the present invention, the liquid preparation in step 1 is specifically as follows: 10-30 parts of ethoxylated fatty alcohol sodium sulfate, 10-30 parts of oleamide MEA, 10-30 parts of EO / PO block polyether, 10-30 parts of isooctyl phosphate derivatives and 10-30 parts of ethoxylated fatty acid methyl ester derivatives are added to a reaction kettle, heated to 60-70° C. to obtain solution A, 20-40 parts of polyethylene glycol monooleate, 20-40 parts of nonylphenol polyoxyethylene ether and RM2020 are added. 20-40 parts of glycerol are added into a reaction kettle and heated to 60-70°C to obtain solution B; 30-60 parts of stearic acid and 30-60 parts of sodium dodecylbenzene sulfonate are added to obtain solution C; 25-40 parts of fatty acid glyceride, 25-40 parts of Span and 25-40 parts of Tween are added into a reaction kettle and heated to 60-70°C to obtain solution D; 30-70 parts of tuberose extract and 30-70 parts of osmanthus essential oil are added into a reaction kettle and heated to 60-70°C to obtain solution E.
[0018] Compared with the prior art, the beneficial effects of the present invention are as follows: by adding an active agent component A and an active agent component B to the surfactant, the prepared surfactant is low-foam or even foam-free, which meets people's needs for using surfactants, and the production process is simple and easy, and no three wastes are discharged during the production process, which is in line with the concept of environmentally friendly production. BRIEF DESCRIPTION OF THE DRAWINGS
[0019] Figure 1 is a component diagram of the surfactant of the present invention;
[0020] Figure 2 It is a component diagram of the active agent component A of the present invention;
[0021] Figure 3It is a component diagram of the active agent component B of the present invention;
[0022] Figure 4 is a component diagram of the active agent component C of the present invention;
[0023] Figure 5 is a component diagram of the active agent component D of the present invention;
[0024] Figure 6 It is a component diagram of the active agent component E of the present invention;
[0025] Figure 7 It is a flow chart of the present invention. DETAILED DESCRIPTION
[0026] The following will be combined with the embodiments of the present invention to clearly and completely describe the technical solutions in the embodiments of the present invention. Obviously, the described embodiments are only part of the embodiments of the present invention, not all of the embodiments. Based on the embodiments of the present invention, all other embodiments obtained by ordinary technicians in this field without making creative work are within the scope of protection of the present invention.
[0027] Embodiment 1:
[0028] See also Figure 1-7 The present invention provides a low-foaming surfactant composition, comprising a surfactant, wherein the surfactant comprises an active agent component A, an active agent component B, an active agent component C, an active agent component D and an active agent component E, wherein the active agent component A comprises the following components: by weight, 10 to 30 parts of ethoxylated fatty alcohol sodium sulfate, 10 to 30 parts of oleamide MEA, 10 to 30 parts of EO / PO block polyether, 10 to 30 parts of isooctyl phosphate derivatives and 10 to 30 parts of ethoxylated fatty acid methyl ester derivatives, and the active agent component B comprises the following components: by weight, 20 to 40 parts of polyethylene glycol monooleate, 20 to 40 parts of nonylphenol polyoxyethylene ether and RM2020 The active agent component C comprises the following components: by weight, 30-60 parts of stearic acid and 30-60 parts of sodium dodecylbenzene sulfonate; the active agent component D comprises the following components: by weight, 25-40 parts of fatty acid glyceride, 25-40 parts of Span and 25-40 parts of Tween; the active agent component E comprises the following components: by weight, 30-70 parts of tuberose extract and 30-70 parts of osmanthus essential oil.
[0029] A method for producing a low-foaming surfactant composition comprises the following steps:
[0030] Step 1, liquid preparation: add active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into a reaction kettle respectively, heat to 60-70° C. to make active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into transparent flowing liquids and store them in different containers;
[0031] Step 2: Product mixing: Add the active agent component A into the reaction kettle, and then dropwise add the active agent component B, the active agent component C, the active agent component D and the active agent component E in sequence, and control the speed and stir evenly.
[0032] In step 2, the rotation speed is 80-100r / min.
[0033] In step 1, the liquid preparation is specifically as follows: 10-30 parts of ethoxylated fatty alcohol sodium sulfate, 10-30 parts of oleamide MEA, 10-30 parts of EO / PO block polyether, 10-30 parts of isooctyl phosphate derivatives and 10-30 parts of ethoxylated fatty acid methyl ester derivatives are added to a reaction kettle, heated to 60-70° C. to obtain solution A, 20-40 parts of polyethylene glycol monooleate, 20-40 parts of nonylphenol polyoxyethylene ether and RM2020 are added. 20-40 parts of glycerol are added into a reaction kettle and heated to 60-70°C to obtain solution B; 30-60 parts of stearic acid and 30-60 parts of sodium dodecylbenzene sulfonate are added to obtain solution C; 25-40 parts of fatty acid glyceride, 25-40 parts of Span and 25-40 parts of Tween are added into a reaction kettle and heated to 60-70°C to obtain solution D; 30-70 parts of tuberose extract and 30-70 parts of osmanthus essential oil are added into a reaction kettle and heated to 60-70°C to obtain solution E.
[0034] Embodiment 2:
[0035] See also Figure 1-7The present invention provides a low-foaming surfactant composition, comprising a surfactant, wherein the surfactant comprises an active agent component A, an active agent component B, an active agent component C, an active agent component D and an active agent component E, wherein the active agent component A comprises the following components: by weight, 20 parts of ethoxylated fatty alcohol sodium sulfate, 20 parts of oleamide MEA, 20 parts of EO / PO block polyether, 20 parts of isooctyl phosphate derivatives and 20 parts of ethoxylated fatty acid methyl ester derivatives, and the active agent component B comprises the following components: by weight, 20 parts of polyethylene glycol monooleate, 40 parts of nonylphenol polyoxyethylene ether and 20 parts of RM2020 40 parts, the active agent component C comprises the following components: by weight, 40 parts of stearic acid and 60 parts of sodium dodecylbenzene sulfonate, the active agent component D comprises the following components: by weight, 30 parts of fatty acid glyceride, 35 parts of Span and 35 parts of Tween, and the active agent component E comprises the following components: by weight, 50 parts of tuberose extract and 50 parts of osmanthus essential oil.
[0036] A method for producing a low-foaming surfactant composition comprises the following steps:
[0037] Step 1, liquid preparation: add active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into a reaction kettle respectively, heat to 60-70° C. to make active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into transparent flowing liquids and store them in different containers;
[0038] Step 2: Product mixing: Add the active agent component A into the reaction kettle, and then dropwise add the active agent component B, the active agent component C, the active agent component D and the active agent component E in sequence, and control the speed and stir evenly.
[0039] In step 2, the rotation speed is 80-100r / min.
[0040] In step 1, the liquid preparation is specifically as follows: 10-30 parts of ethoxylated fatty alcohol sodium sulfate, 10-30 parts of oleamide MEA, 10-30 parts of EO / PO block polyether, 10-30 parts of isooctyl phosphate derivatives and 10-30 parts of ethoxylated fatty acid methyl ester derivatives are added to a reaction kettle, heated to 60-70° C. to obtain solution A, 20 parts of polyethylene glycol monooleate, 40 parts of nonylphenol polyoxyethylene ether and RM2020 are added. 40 parts of 1,2-dimethoxy-2-nitropropene was added into a reactor and heated to 60-70°C to obtain solution B; 40 parts of stearic acid and 60 parts of sodium dodecylbenzene sulfonate were added into a reactor and heated to 60-70°C to obtain solution C; 30 parts of fatty acid glyceride, 35 parts of Span and 35 parts of Tween were added into a reactor and heated to 60-70°C to obtain solution D; 50 parts of tuberose extract and 50 parts of osmanthus essential oil were added into a reactor and heated to 60-70°C to obtain solution E.
[0041] Embodiment 3:
[0042] See also Figure 1-7 The present invention provides a low-foaming surfactant composition, comprising a surfactant, wherein the surfactant comprises an active agent component A, an active agent component B, an active agent component C, an active agent component D and an active agent component E, wherein the active agent component A comprises the following components: by weight, 15 parts of ethoxylated fatty alcohol sodium sulfate, 15 parts of oleamide MEA, 15 parts of EO / PO block polyether, 25 parts of isooctyl phosphate derivatives and 30 parts of ethoxylated fatty acid methyl ester derivatives, and the active agent component B comprises the following components: by weight, 30 parts of polyethylene glycol monooleate, 30 parts of nonylphenol polyoxyethylene ether and RM2020 40 parts, the active agent component C comprises the following components: by weight, 50 parts of stearic acid and 50 parts of sodium dodecylbenzene sulfonate, the active agent component D comprises the following components: by weight, 35 parts of fatty acid glyceride, 35 parts of Span and 30 parts of Tween, and the active agent component E comprises the following components: by weight, 40 parts of tuberose extract and 60 parts of osmanthus essential oil.
[0043] A method for producing a low-foaming surfactant composition comprises the following steps:
[0044] Step 1, liquid preparation: add active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into a reaction kettle respectively, heat to 60-70° C. to make active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into transparent flowing liquids and store them in different containers;
[0045] Step 2: Product mixing: Add the active agent component A into the reaction kettle, and then dropwise add the active agent component B, the active agent component C, the active agent component D and the active agent component E in sequence, and control the speed and stir evenly.
[0046] In step 2, the rotation speed is 80-100r / min.
[0047] In step 1, the liquid preparation is specifically as follows: 15 parts of sodium ethoxylated fatty alcohol sulfate, 15 parts of oleamide MEA, 15 parts of EO / PO block polyether, 25 parts of isooctyl phosphate derivatives and 30 parts of ethoxylated fatty acid methyl ester derivatives are added to a reactor, and heated to 60-70°C to obtain solution A; 30 parts of polyethylene glycol monooleate, 30 parts of nonylphenol polyoxyethylene ether and 40 parts of RM2020 are added to a reactor, and heated to 60-70°C to obtain solution B; 50 parts of stearic acid and 50 parts of sodium dodecylbenzene sulfonate are added to obtain solution C; 35 parts of fatty acid glyceride, 35 parts of Span and 30 parts of Tween are added to a reactor, and heated to 60-70°C to obtain solution D; 40 parts of tuberose extract and 60 parts of osmanthus essential oil are added to a reactor, and heated to 60-70°C to obtain solution E.
[0048] Embodiment 4:
[0049] See also Figure 1-7 The present invention provides a low-foaming surfactant composition, comprising a surfactant, wherein the surfactant comprises an active agent component A, an active agent component B, an active agent component C, an active agent component D and an active agent component E, wherein the active agent component A comprises the following components: by weight, 30 parts of ethoxylated fatty alcohol sodium sulfate, 10 parts of oleamide MEA, 30 parts of EO / PO block polyether, 10 parts of isooctyl phosphate derivatives and 20 parts of ethoxylated fatty acid methyl ester derivatives, and the active agent component B comprises the following components: by weight, 25 parts of polyethylene glycol monooleate, 35 parts of nonylphenol polyoxyethylene ether and RM2020 40 parts, the active agent component C comprises the following components: by weight, 60 parts of stearic acid and 40 parts of sodium dodecylbenzene sulfonate, the active agent component D comprises the following components: by weight, 35 parts of fatty acid glyceride, 25 parts of Span and 40 parts of Tween, and the active agent component E comprises the following components: by weight, 70 parts of tuberose extract and 30 parts of osmanthus essential oil.
[0050] A method for producing a low-foaming surfactant composition comprises the following steps:
[0051] Step 1, liquid preparation: add active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into a reaction kettle respectively, heat to 60-70° C. to make active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into transparent flowing liquids and store them in different containers;
[0052] Step 2: Product mixing: Add the active agent component A into the reaction kettle, and then dropwise add the active agent component B, the active agent component C, the active agent component D and the active agent component E in sequence, and control the speed and stir evenly.
[0053] In step 2, the rotation speed is 80-100r / min.
[0054] In step 1, the liquid preparation is specifically as follows: 30 parts of sodium ethoxylated fatty alcohol sulfate, 10 parts of oleamide MEA, 30 parts of EO / PO block polyether, 10 parts of isooctyl phosphate derivatives and 20 parts of ethoxylated fatty acid methyl ester derivatives are added to a reactor, and heated to 60-70°C to obtain solution A; 25 parts of polyethylene glycol monooleate, 35 parts of nonylphenol polyoxyethylene ether and 40 parts of RM2020 are added to a reactor, and heated to 60-70°C to obtain solution B; 60 parts of stearic acid and 40 parts of sodium dodecylbenzene sulfonate are added to a reactor to obtain solution C; 35 parts of fatty acid glyceride, 25 parts of Span and 40 parts of Tween are added to a reactor, and heated to 60-70°C to obtain solution D; 70 parts of tuberose extract and 30 parts of osmanthus essential oil are added to a reactor, and heated to 60-70°C to obtain solution E.
[0055] Embodiment 5:
[0056] See also Figure 1-7 The present invention provides a low-foaming surfactant composition, comprising a surfactant, wherein the surfactant comprises an active agent component A, an active agent component B, an active agent component C, an active agent component D and an active agent component E, wherein the active agent component A comprises the following components: by weight, 30 parts of ethoxylated fatty alcohol sodium sulfate, 30 parts of oleamide MEA, 10 parts of EO / PO block polyether, 10 parts of isooctyl phosphate derivatives and 20 parts of ethoxylated fatty acid methyl ester derivatives, and the active agent component B comprises the following components: by weight, 40 parts of polyethylene glycol monooleate, 40 parts of nonylphenol polyoxyethylene ether and 20 parts of RM2020 The active agent component C comprises the following components: by weight, 55 parts of stearic acid and 45 parts of sodium dodecylbenzene sulfonate; the active agent component D comprises the following components: by weight, 25 parts of fatty acid glyceride, 35 parts of Span and 40 parts of Tween; the active agent component E comprises the following components: by weight, 30 parts of tuberose extract and 70 parts of osmanthus essential oil.
[0057] A method for producing a low-foaming surfactant composition comprises the following steps:
[0058] Step 1, liquid preparation: add active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into a reaction kettle respectively, heat to 60-70° C. to make active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into transparent flowing liquids and store them in different containers;
[0059] Step 2: Product mixing: Add the active agent component A into the reaction kettle, and then dropwise add the active agent component B, the active agent component C, the active agent component D and the active agent component E in sequence, and control the speed and stir evenly.
[0060] In step 2, the rotation speed is 80-100r / min.
[0061] In step 1, the liquid preparation is specifically as follows: 30 parts of sodium ethoxylated fatty alcohol sulfate, 30 parts of oleamide MEA, 10 parts of EO / PO block polyether, 10 parts of isooctyl phosphate derivatives and 20 parts of ethoxylated fatty acid methyl ester derivatives are added to a reactor, and heated to 60-70°C to obtain solution A; 40 parts of polyethylene glycol monooleate, 40 parts of nonylphenol polyoxyethylene ether and 20 parts of RM2020 are added to a reactor, and heated to 60-70°C to obtain solution B; 55 parts of stearic acid and 45 parts of sodium dodecylbenzene sulfonate are added to a reactor to obtain solution C; 25 parts of fatty acid glyceride, 35 parts of Span and 40 parts of Tween are added to a reactor, and heated to 60-70°C to obtain solution D; 30 parts of tuberose extract and 70 parts of osmanthus essential oil are added to a reactor, and heated to 60-70°C to obtain solution E.
[0062] In the present invention, 10-30 parts of sodium ethoxylated fatty alcohol sulfate, 10-30 parts of oleic acid amide MEA, 10-30 parts of EO / PO block polyether, 10-30 parts of isooctyl phosphate derivatives and 10-30 parts of ethoxylated fatty acid methyl ester derivatives are added to a reaction kettle, heated to 60-70° C. to prepare solution A, 20-40 parts of polyethylene glycol monooleate, 20-40 parts of nonylphenol polyoxyethylene ether and RM2020 are added. 20-40 parts of glycerol are added into a reaction kettle, and heated to 60-70°C to obtain solution B; 30-60 parts of stearic acid and 30-60 parts of sodium dodecylbenzene sulfonate are added to obtain solution C; 25-40 parts of fatty acid glyceride, 25-40 parts of Span and 25-40 parts of Tween are added into a reaction kettle, and heated to 60-70°C to obtain solution D; 30-70 parts of tuberose extract and 30-70 parts of osmanthus essential oil are added into a reaction kettle, and heated to 60-70°C to obtain solution E; active agent component A is added into the reaction kettle, and active agent component B, active agent component C, active agent component D and active agent component E are added dropwise in sequence, and the rotation speed is controlled to 80-100 r / min and stirred evenly to obtain the product.
[0063] Although the present invention has been described in detail with reference to the aforementioned embodiments, it is still possible for those skilled in the art to modify the technical solutions described in the aforementioned embodiments, or to make equivalent substitutions for some of the technical features therein. Any modifications, equivalent substitutions, improvements, etc. made within the spirit and principles of the present invention should be included in the protection scope of the present invention.
Claims
1. A low-foaming surfactant composition comprising a surfactant, characterized in that: The surfactant comprises an active agent component A, an active agent component B, an active agent component C, an active agent component D and an active agent component E. The active agent component A comprises the following components: by weight, 10-30 parts of ethoxylated fatty alcohol sodium sulfate, 10-30 parts of oleamide MEA, 10-30 parts of EO / PO block polyether, 10-30 parts of isooctyl phosphate derivatives and 10-30 parts of ethoxylated fatty acid methyl ester derivatives; the active agent component B comprises the following components: by weight, 20-40 parts of polyethylene glycol monooleate, 20-40 parts of nonylphenol polyoxyethylene ether and RM2020 The active agent component C comprises the following components: by weight, 30-60 parts of stearic acid and 30-60 parts of sodium dodecylbenzene sulfonate; the active agent component D comprises the following components: by weight, 25-40 parts of fatty acid glyceride, 25-40 parts of Span and 25-40 parts of Tween; the active agent component E comprises the following components: by weight, 30-70 parts of tuberose extract and 30-70 parts of osmanthus essential oil.
2. A low foaming surfactant composition according to claim 1, characterized in that: The active agent component A comprises the following components: by weight, 20 parts of ethoxylated fatty alcohol sodium sulfate, 20 parts of oleamide MEA, 20 parts of EO / PO block polyether, 20 parts of isooctyl phosphate derivatives and 20 parts of ethoxylated fatty acid methyl ester derivatives; the active agent component B comprises the following components: by weight, 20 parts of polyethylene glycol monooleate, 40 parts of nonylphenol polyoxyethylene ether and 40 parts of RM2020; the active agent component C comprises the following components: by weight, 40 parts of stearic acid and 60 parts of sodium dodecylbenzene sulfonate; the active agent component D comprises the following components: by weight, 30 parts of fatty acid glyceride, 35 parts of Span and 35 parts of Tween; the active agent component E comprises the following components: by weight, 50 parts of tuberose extract and 50 parts of osmanthus essential oil.
3. A low foaming surfactant composition according to claim 1, characterized in that: The active agent component A comprises the following components: 15 parts of ethoxylated fatty alcohol sodium sulfate, 15 parts of oleamide MEA, 15 parts of EO / PO block polyether, 25 parts of isooctyl phosphate derivatives and 30 parts of ethoxylated fatty acid methyl ester derivatives, by weight; the active agent component B comprises the following components: 30 parts of polyethylene glycol monooleate, 30 parts of nonylphenol polyoxyethylene ether and 40 parts of RM2020, by weight; the active agent component C comprises the following components: 50 parts of stearic acid and 50 parts of sodium dodecylbenzene sulfonate, by weight; the active agent component D comprises the following components: 35 parts of fatty acid glyceride, 35 parts of Span and 30 parts of Tween, by weight; and the active agent component E comprises the following components: 40 parts of tuberose extract and 60 parts of osmanthus essential oil, by weight.
4. A low foaming surfactant composition according to claim 1, characterized in that: The active agent component A comprises the following components: 30 parts of ethoxylated fatty alcohol sodium sulfate, 10 parts of oleamide MEA, 30 parts of EO / PO block polyether, 10 parts of isooctyl phosphate derivatives and 20 parts of ethoxylated fatty acid methyl ester derivatives, by weight; the active agent component B comprises the following components: 25 parts of polyethylene glycol monooleate, 35 parts of nonylphenol polyoxyethylene ether and 40 parts of RM2020, by weight; the active agent component C comprises the following components: 60 parts of stearic acid and 40 parts of sodium dodecylbenzene sulfonate, by weight; the active agent component D comprises the following components: 35 parts of fatty acid glyceride, 25 parts of Span and 40 parts of Tween, by weight; and the active agent component E comprises the following components: 70 parts of tuberose extract and 30 parts of osmanthus essential oil, by weight.
5. The low foaming surfactant composition according to claim 1, characterized in that: The active agent component A comprises the following components: by weight, 30 parts of ethoxylated fatty alcohol sodium sulfate, 30 parts of oleamide MEA, 10 parts of EO / PO block polyether, 10 parts of isooctyl phosphate derivatives and 20 parts of ethoxylated fatty acid methyl ester derivatives; the active agent component B comprises the following components: by weight, 40 parts of polyethylene glycol monooleate, 40 parts of nonylphenol polyoxyethylene ether and 20 parts of RM2020; the active agent component C comprises the following components: by weight, 55 parts of stearic acid and 45 parts of sodium dodecylbenzene sulfonate; the active agent component D comprises the following components: by weight, 25 parts of fatty acid glyceride, 35 parts of Span and 40 parts of Tween; the active agent component E comprises the following components: by weight, 30 parts of tuberose extract and 70 parts of osmanthus essential oil.
6. A method for producing a low-foaming surfactant composition according to any one of claims 1 to 5, characterized in that: The following steps are involved: Step 1, liquid preparation: add active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into a reaction kettle respectively, heat to 60-70° C. to make active agent component A, active agent component B, active agent component C, active agent component D and active agent component E into transparent flowing liquids and store them in different containers; Step 2: Product mixing: Add the active agent component A into the reaction kettle, and then dropwise add the active agent component B, the active agent component C, the active agent component D and the active agent component E in sequence, and control the speed and stir evenly.
7. The method for producing a low-foaming surfactant composition according to claim 6, characterized in that: The rotation speed in step 2 is 80-100 r / min.
8. The method for producing a low-foaming surfactant composition according to claim 6, characterized in that: In the step 1, the liquid preparation is specifically as follows: 10-30 parts of ethoxylated fatty alcohol sodium sulfate, 10-30 parts of oleamide MEA, 10-30 parts of EO / PO block polyether, 10-30 parts of isooctyl phosphate derivatives and 10-30 parts of ethoxylated fatty acid methyl ester derivatives are added into a reaction kettle, heated to 60-70° C. to obtain solution A, 20-40 parts of polyethylene glycol monooleate, 20-40 parts of nonylphenol polyoxyethylene ether and RM2020 are added into a reaction kettle, and the mixture is stirred for 2 hours. 20-40 parts of glycerol are added into a reaction kettle and heated to 60-70°C to obtain solution B; 30-60 parts of stearic acid and 30-60 parts of sodium dodecylbenzene sulfonate are added to obtain solution C; 25-40 parts of fatty acid glyceride, 25-40 parts of Span and 25-40 parts of Tween are added into a reaction kettle and heated to 60-70°C to obtain solution D; 30-70 parts of tuberose extract and 30-70 parts of osmanthus essential oil are added into a reaction kettle and heated to 60-70°C to obtain solution E.
