Fixing film with thermal shrinkage effect and preparation method thereof

By combining modified silica with high-performance resin, a fixing film tube sleeve with heat shrinkage effect is formed, which solves the problems of complex preparation and poor printing effect caused by the use of adhesives in the prior art, and achieves a more efficient and flatter fixing film performance.

CN119668066AActive Publication Date: 2025-03-21SHENZHEN HUAZHIMEI TECH CO LTD
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Patent Information

Application Number
CN202411719833.3
Authority / Receiving Office
CN · China
Patent Type
Applications(China)
Current Assignee / Owner
Filing Date
2024-11-28
Publication Date
2025-03-21
Estimated Expiration
2044-11-28

AI Technical Summary

Technical Problem

The existing fixing film needs to be added to the coating layer and the tube sleeve layer for tight connection, resulting in complex preparation process, cumbersome drying process, and easy introduction of bubbles, affecting the printing effect.

Method used

Materials such as PFA resin, polyethylene, polyurethane, etc. are used as the matrix resin, and silica is modified by perfluoric acid, unsaturated carboxylic acid and acrylic acid to form a release layer tube sleeve with a heat shrinkage effect, avoiding the use of adhesive.

Benefits of technology

The flat surface of the fixing film is achieved, the mechanical properties and production efficiency are improved, the bubbles and wrinkles are avoided, and the printing effect is significantly improved.

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Abstract

The invention relates to a photographic fixing film with a heat shrinkage effect and a preparation method thereof. The photographic fixing film is of a multi-layer structure and sequentially comprises a base material, a bottom coating layer, a silica gel layer, a surface coating layer and a heat shrinkage layer from inside to outside. The heat shrinkage layer is prepared from the following components in parts by mass: 30 to 50 parts of PFA resin, 40 to 50 parts of polyethylene, 10 to 30 parts of polyurethane, 5 to 10 parts of polytetrafluoroethylene, 5 to 8 parts of modified silicon dioxide particles and 1 to 5 parts of auxiliaries; wherein the modified silicon dioxide particles are a product obtained by copolymerizing hydroxylated silicon dioxide, silicon dioxide partially grafted with perfluorinated acid and silicon dioxide partially grafted with unsaturated carboxylic acid with acrylate. The release layer pipe sleeve with the thermal shrinkage effect prepared by the invention not only has good mechanical properties, but also can uniformly shrink after being heated, avoids the formation of defects such as bubbles and wrinkles, has a smoother surface, improves the production efficiency, and overcomes the defects in the prior art.
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