Ultrasonic device for cleaning deposition wrinkles of flexible reversible metal electro-deposition device

The ultrasonic device uses the high-frequency vibration and microbubble impact force of the piezoelectric ceramic sheet to clean the reversible metal electrodeposition device, which solves the complex operation problems in the prior art, and realizes the cleaning effect without opening the seal and replacing the electrolyte, which significantly improves the device performance and stability.

CN222306678UActive Publication Date: 2025-01-07哈尔滨工业大学国家大学科技园发展有限公司
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Patent Information

Application Number
CN202420993687.2
Authority / Receiving Office
CN · China
Patent Type
Utility models(China)
Current Assignee / Owner
Filing Date
2024-05-09
Publication Date
2025-01-07
Estimated Expiration
2034-05-09

AI Technical Summary

Technical Problem

Existing reversible metal electrodeposition devices require unpacking and replacing the electrolyte or using chemical solvents during cleaning, which is complicated and inconvenient to operate.

Method used

Using ultrasonic devices including power supply, ultrasonic generator and piezoelectric ceramic ultrasonic transducer, the deposited film on the surface of the device is cleaned through high-frequency vibration and tiny bubble impact force, and the piezoelectric effect is used to generate dense ultrasonic beams, so that the cleaning does not require opening and replacement of the electrolyte. Or use chemical reagents.

Benefits of technology

The cleaning effect of simple operation is achieved, and no deposition wrinkles occur in multiple cycles in a short period of time, which significantly improves the performance and stability of the device.

✦ Generated by Eureka AI based on patent content.

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Abstract

The utility model provides an ultrasonic device for cleaning deposition wrinkles of a flexible reversible metal electro-deposition device, and belongs to the field of reversible metal electro-deposition device cleaning. The problems that when a film deposited on the surface of a reversible metal electro-deposition device is cleaned, an unsealing device needs to be used for opening the device and then electrolyte or chemical solvent needs to be used, and operation is complex are solved. Comprising a power supply, an ultrasonic generator and a piezoelectric ceramic ultrasonic transducer which are connected in sequence, the piezoelectric ceramic ultrasonic transducer comprises a plurality of uniformly distributed piezoelectric ceramic piece units and peripheral edge sealing connecting pieces, each piezoelectric ceramic piece unit comprises a piezoelectric ceramic piece in the center, an insulation nesting sleeve is arranged outside the piezoelectric ceramic piece, and the piezoelectric ceramic piece units are arranged in the insulation nesting sleeve. Every two adjacent piezoelectric ceramic pieces are connected through a flexible connecting piece. The device is subjected to ultrasonic treatment based on the piezoelectric effect and the vibration effect of ultrasonic waves, and the surface of the reversible metal electro-deposition device can be effectively cleaned. Experiments prove that after the device is used for cleaning, similar wrinkles cannot appear in short-term multiple cycles.
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Description

Technical Field

[0001] The utility model relates to the technical field of reversible metal electrodeposition device auxiliary internal wrinkle elimination, in particular to an ultrasonic device for cleaning deposited wrinkles of a flexible reversible metal electrodeposition device. Background Art

[0002] Electrochromic devices are materials that can change their optical properties through an external electric field. They are often used to adjust transparency or change color, such as electric car skylight glass, smart glasses and smart dimming glass. Reversible metal electrodeposition devices are one type of electrochromic devices. However, with the long-term use of reversible metal electrodeposition devices, especially after multiple cycles, the thin film deposited on the surface of the device will be difficult to dissolve, which seriously affects the performance and stability of the device. It can be understood that the reversible metal electrodeposition device is made of two conductive glass conductive surfaces facing each other, and the electrolyte is filled in the middle. The electrolyte will react when the voltage is applied. When used for a short time, the wrinkles formed on the reversible metal electrodeposition device will fade when the power is not connected or the reverse voltage is connected. However, as the use time increases, the silver film deposited on the conductive surface of one of the conductive glasses will not fade when the power is turned off or the reverse voltage is connected, causing the conductive glass to have persistent "wrinkles". Not only will it cause a decline in appearance, but it will also cause wrinkles in the subsequent deposition, which will continue to accumulate, resulting in a serious decline in the device's aesthetics and cyclic reversibility. Through data research and analysis, we know that the growth process of the silver film generates compressive growth stress. When the growth stress exceeds the critical value of the system, the silver film buckles and becomes unstable under the compressive stress, forming micro-wrinkles. In addition, the annular stress caused by the surface tension difference can also lead to the formation of wrinkles.

[0003] At present, some solutions have been proposed for the problem of thin film deposition in reversible metal electrodeposition devices, including the use of chemical solvents or electrolytes to clean the device surface. However, these methods usually require opening the device and replacing the electrolyte, which is complicated. Therefore, there is an urgent need for a new technology that can effectively reset the reversible metal electrodeposition device and restore its performance without opening the device or replacing the electrolyte. Utility Model Content

[0004] The technical problems to be solved by the utility model are:

[0005] In order to solve the problem that when cleaning the deposited film on the surface of the existing reversible metal electrodeposition device, it is necessary to use an opener to open the device and then replace the electrolyte or use chemical solvents, which is a complicated operation.

[0006] The utility model adopts the following technical solutions to solve the above technical problems:

[0007] The utility model provides an ultrasonic device for cleaning deposited wrinkles of a flexible reversible metal electrodeposition device, comprising a power supply, an ultrasonic generator and a piezoelectric ceramic ultrasonic transducer, wherein the power supply is connected to the ultrasonic generator, and the ultrasonic generator is used to convert industrial frequency electricity into a high-frequency alternating current signal that matches the piezoelectric ceramic ultrasonic transducer; the ultrasonic generator is connected to the piezoelectric ceramic ultrasonic transducer, and the piezoelectric ceramic ultrasonic transducer is used to be placed on the surface of the reversible metal electrodeposition device, and the piezoelectric ceramic ultrasonic transducer is used to convert the high-frequency alternating current signal into ultrasonic waves so as to use ultrasonic waves to vibrate and clean the deposited film on the surface of the reversible metal electrodeposition device;

[0008] The piezoelectric ceramic ultrasonic transducer includes a plurality of evenly distributed piezoelectric ceramic sheet units and surrounding edge-sealed connectors. Each piezoelectric ceramic sheet unit includes a piezoelectric ceramic sheet at the center. The piezoelectric ceramic sheet is provided with an insulating nest outside. Two adjacent piezoelectric ceramic sheets are connected by a flexible connector.

[0009] Furthermore, the flexible connectors of the piezoelectric ceramic sheet units located at the edges are all connected to the corresponding edge sealing connectors.

[0010] Furthermore, the edge sealing connector is a flexible edge sealing connector.

[0011] Furthermore, the insulating nesting is a plastic nesting.

[0012] Furthermore, the plastic nesting is a flexible plastic nesting, and the flexible connecting piece is connected to the piezoelectric ceramic sheet in the flexible plastic nesting.

[0013] Furthermore, the insulating nest comprises an upper insulating nest and a lower insulating nest, and the piezoelectric ceramic sheet connected with a flexible connector is arranged between the upper insulating nest and the lower insulating nest.

[0014] Furthermore, the upper insulating nest and the lower insulating nest are fixed by gluing or hot pressing.

[0015] Furthermore, two adjacent piezoelectric ceramic sheet units in each row of piezoelectric ceramic sheet units are connected via a flexible connecting line, and two adjacent piezoelectric ceramic sheet units in each column of piezoelectric ceramic sheet units are connected via a flexible connecting piece.

[0016] Furthermore, the flexible connecting member is a flexible connecting line.

[0017] Furthermore, the flexible connecting line includes at least two conducting wires.

[0018] Compared with the prior art, the beneficial effects of the utility model are:

[0019] The utility model discloses an ultrasonic device for cleaning wrinkles of deposited flexible reversible metal electrodeposition devices, comprising a power supply, an ultrasonic generator and a piezoelectric ceramic ultrasonic transducer connected in sequence, wherein the piezoelectric ceramic ultrasonic transducer comprises a plurality of evenly distributed piezoelectric ceramic sheet units and edge-sealed connectors around the piezoelectric ceramic sheet units, wherein each piezoelectric ceramic sheet unit comprises a piezoelectric ceramic sheet at the center, an insulating nest is arranged outside the piezoelectric ceramic sheet, and two adjacent piezoelectric ceramic sheets are connected by a flexible connector; the device is ultrasonically processed based on the piezoelectric effect and the vibration of ultrasonic waves; when the external power supply is applied to the electrode through the ultrasonic generator, the piezoelectric ceramic sheet is deformed under the action of the electric field, high-frequency vibration is generated, and a dense ultrasonic beam is formed to clean the wrinkles on the surface of the device; at the same time, the ultrasonic wave also has a cavitation effect, which can form a large number of tiny bubbles with impact force in the cleaning liquid, further improving the cleaning effect, and there is no need to open the flexible reversible metal electrodeposition device to replace the electrolyte or use chemical reagents, and the operation is simpler. It has been proved by experiments that after cleaning with the device, similar wrinkles will not appear in a short-term multiple cycles. BRIEF DESCRIPTION OF THE DRAWINGS

[0020] Figure 1 This is a structural diagram of a flexible ultrasonic patch in an embodiment of the utility model;

[0021] Figure 2 A three-dimensional diagram of a portion of the flexible ultrasonic patch in an embodiment of the utility model;

[0022] Figure 3 The three-dimensional piezoelectric ceramic unit in the embodiment of the utility model Figure 1 ;

[0023] Figure 4 The three-dimensional piezoelectric ceramic unit in the embodiment of the utility model Figure 2 .

[0024] Description of reference numerals:

[0025] 1. Edge-sealing connector; 2. Piezoelectric ceramic unit; 210. Insulation nesting; 220. Piezoelectric ceramic; 230. Flexible connector; 211. Upper insulation nesting; 212. Lower insulation nesting. DETAILED DESCRIPTION

[0026] In the description of the present utility model, it should be noted that the terminology nouns in the various embodiments, such as words indicating directions such as "upper", "lower", "front", "back", "left", "right", etc., are only for simplifying the description of the positional relationship based on the drawings in the specification, and do not mean that the referred elements and devices must be operated according to the specific directions and specified operations and methods and structures in the specification. Such directional nouns do not constitute limitations on the present utility model.

[0027] In order to make the above-mentioned objects, features and advantages of the present invention more obvious and understandable, the specific embodiments of the present invention are described in detail below with reference to the accompanying drawings.

[0028] Specific implementation plan 1: Combine Figures 1 to 4 As shown, the utility model provides an ultrasonic device for cleaning deposited wrinkles of a flexible reversible metal electrodeposition device, comprising a power supply, an ultrasonic generator and a piezoelectric ceramic ultrasonic transducer, wherein the power supply is connected to the ultrasonic generator, and the ultrasonic generator is used to convert industrial frequency electricity into a high-frequency alternating current signal that matches the piezoelectric ceramic ultrasonic transducer; the ultrasonic generator is connected to the piezoelectric ceramic ultrasonic transducer, and the piezoelectric ceramic ultrasonic transducer is used to be placed on the surface of the reversible metal electrodeposition device, and the piezoelectric ceramic ultrasonic transducer is used to convert the high-frequency alternating current signal into ultrasonic waves so as to use ultrasonic waves to vibrate and clean the deposited film on the surface of the reversible metal electrodeposition device;

[0029] The piezoelectric ceramic ultrasonic transducer includes a plurality of evenly distributed piezoelectric ceramic sheet units 2 and surrounding edge-sealing connectors 1. Each piezoelectric ceramic sheet unit 2 includes a piezoelectric ceramic sheet 220 at the center. An insulating nest 210 is provided outside the piezoelectric ceramic sheet 220. Two adjacent piezoelectric ceramic sheets 220 are connected by a flexible connector 230.

[0030] Preferably, the flexible connectors 230 of the piezoelectric ceramic sheet unit 2 located at the edge are all connected to the corresponding edge-sealing connectors 1 , and the edge-sealing connectors 1 are flexible edge-sealing connectors 1 .

[0031] Preferably, the insulating nest 210 may be a plastic nest, and the plastic nest is a flexible plastic nest, and the flexible connector 230 is connected to the piezoelectric ceramic sheet 220 in the flexible plastic nest.

[0032] Preferably, the insulating nest 210 includes an upper insulating nest 211 and a lower insulating nest 212, and a piezoelectric ceramic sheet 220 connected with a flexible connector 230 is arranged between the upper insulating nest 211 and the lower insulating nest 212. The upper insulating nest 211 and the lower insulating nest 212 can be fixed by gluing or hot pressing.

[0033] Preferably, the flexible connector 230 is a flexible connecting wire, and the edge sealing connector 1 is a flexible connecting wire.

[0034] Preferably, the flexible connecting line includes at least two conducting wires. During use, each piezoelectric ceramic sheet 220 is connected to a power supply with an ultrasonic generator, and the power supply with an ultrasonic generator is an existing device.

[0035] Preferably, two adjacent piezoelectric ceramic sheet units 2 in each row of piezoelectric ceramic sheet units 2 are connected via a flexible connecting line, and two adjacent piezoelectric ceramic sheet units 2 in each column of piezoelectric ceramic sheet units 2 are connected via a flexible connecting line.

[0036] The piezoelectric ceramic ultrasonic cleaning transducer used in the utility model performs ultrasonic treatment on the device based on the piezoelectric effect and the vibration action of ultrasonic waves. When an external power source is applied to the electrode through an ultrasonic generator, the piezoelectric ceramic sheet 220 is deformed under the action of the electric field to generate high-frequency vibrations, which are transmitted to the liquid through the outer shell to form a dense ultrasonic beam. At the same time, ultrasonic waves also have a cavitation effect, which can form a large number of tiny bubbles in the cleaning liquid. These bubbles will generate a strong impact force when they burst, further improving the cleaning effect.

[0037] After 5 experiments, it was found that when deposition wrinkles appeared on the reversible metal electrodeposition device, the device was attached to the surface of the reversible metal electrodeposition device, the power was turned on, and ultrasonic treatment was performed for 1 minute. After ultrasonic coupling-assisted digestion, the device would not show similar wrinkles for at least 30 cycles. The actual effect can be clearly seen that there are no obvious wrinkles on the surface of the reversible metal electrodeposition device.

[0038] Although the utility model is disclosed as above, the protection scope of the utility model is not limited thereto. Those skilled in the art of the utility model may make various changes and modifications without departing from the spirit and scope of the utility model, and these changes and modifications will fall within the protection scope of the utility model.

Claims

1. An ultrasonic device for cleaning deposited wrinkles of a flexible reversible metal electrodeposition device, characterized in that: The invention comprises a power supply, an ultrasonic generator and a piezoelectric ceramic ultrasonic transducer, wherein the power supply is connected to the ultrasonic generator, and the ultrasonic generator is used to convert the industrial frequency electricity into a high-frequency alternating current signal matching the piezoelectric ceramic ultrasonic transducer; the ultrasonic generator is connected to the piezoelectric ceramic ultrasonic transducer, and the piezoelectric ceramic ultrasonic transducer is used to be placed on the surface of the reversible metal electrodeposition device, and the piezoelectric ceramic ultrasonic transducer is used to convert the high-frequency alternating current signal into ultrasonic waves so as to use ultrasonic waves to vibrate and clean the deposited film on the surface of the reversible metal electrodeposition device; The piezoelectric ceramic ultrasonic transducer comprises a plurality of evenly distributed piezoelectric ceramic sheet units (2) and surrounding edge-sealing connectors (1), each piezoelectric ceramic sheet unit (2) comprises a piezoelectric ceramic sheet (220) at the center, an insulating nest (210) is provided outside the piezoelectric ceramic sheet (220), and two adjacent piezoelectric ceramic sheets (220) are connected via a flexible connector (230).

2. The ultrasonic device for cleaning deposited wrinkles of a flexible reversible metal electrodeposition device according to claim 1, characterized in that: The flexible connectors (230) of the piezoelectric ceramic sheet units (2) located at the edges are all connected to the corresponding edge sealing connectors (1).

3. The ultrasonic device for cleaning deposited wrinkles of a flexible reversible metal electrodeposition device according to claim 2, characterized in that: The edge sealing connector (1) is a flexible edge sealing connector.

4. The ultrasonic device for cleaning deposited wrinkles of a flexible reversible metal electrodeposition device according to claim 3, characterized in that: The insulating nest (210) is a plastic nest.

5. The ultrasonic device for cleaning deposited wrinkles of a flexible reversible metal electrodeposition device according to claim 4, characterized in that: The plastic nest is a flexible plastic nest, and the flexible connecting piece (230) is connected to the piezoelectric ceramic sheet (220) in the flexible plastic nest.

6. The ultrasonic device for cleaning deposited wrinkles of a flexible reversible metal electrodeposition device according to claim 5, characterized in that: The insulating nest (210) comprises an upper insulating nest (211) and a lower insulating nest (212), and a piezoelectric ceramic sheet (220) connected to a flexible connector (230) is arranged between the upper insulating nest (211) and the lower insulating nest (212).

7. The ultrasonic device for cleaning deposited wrinkles of a flexible reversible metal electrodeposition device according to claim 6, characterized in that: The upper insulating nest (211) and the lower insulating nest (212) are fixed by gluing or hot pressing.

8. The ultrasonic device for cleaning deposited wrinkles of a flexible reversible metal electrodeposition device according to claim 7, characterized in that: Two adjacent piezoelectric ceramic sheet units (2) in each row of piezoelectric ceramic sheet units (2) are connected via a flexible connector (230), and two adjacent piezoelectric ceramic sheet units (2) in each column of piezoelectric ceramic sheet units (2) are connected via a flexible connector (230).

9. The ultrasonic device for cleaning deposited wrinkles of a flexible reversible metal electrodeposition device according to claim 8, characterized in that: The flexible connecting member (230) is a flexible connecting line.

10. The ultrasonic device for cleaning deposited wrinkles of a flexible reversible metal electrodeposition device according to claim 9, characterized in that: The flexible connecting line includes at least two conducting wires.